KR20160009496A - Heat insulation tape, complex sheet having the same and electronic device - Google Patents
Heat insulation tape, complex sheet having the same and electronic device Download PDFInfo
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- KR20160009496A KR20160009496A KR1020150096585A KR20150096585A KR20160009496A KR 20160009496 A KR20160009496 A KR 20160009496A KR 1020150096585 A KR1020150096585 A KR 1020150096585A KR 20150096585 A KR20150096585 A KR 20150096585A KR 20160009496 A KR20160009496 A KR 20160009496A
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- heat
- adhesive layer
- heat insulating
- filler
- thermally conductive
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- C09J7/026—
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
- Laminated Bodies (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
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Abstract
TECHNICAL FIELD [0001] The present invention relates to a heat insulating tape, a composite sheet having the heat insulating tape, and an electronic apparatus. An insulating filler dispersed in the adhesive layer and blocking heat; And a substrate having the pressure-sensitive adhesive layer formed on one surface or both surfaces thereof.
Description
The present invention relates to a heat insulating tape, and more particularly, to a heat insulating tape capable of suppressing the transfer of heat generated in a heat generating component of an electronic apparatus, a composite sheet having the same, and an electronic apparatus.
Recently, the technology has rapidly developed, and high-performance, light-weighted and shortened electronic devices have appeared on the market and are being commercialized.
If such an electronic device fails to dissipate heat generated internally, excessive heat accumulation may cause image retention, system failure, and shortened product life. In severe cases, it may cause explosion or fire .
Particularly, a portable terminal such as a mobile phone (smart phone) is required to be downsized and lightweight in order to maximize the portability and convenience of the user, and components integrated in smaller and smaller spaces for high performance are mounted. As a result, the parts used in the mobile terminal have higher performance and higher heat generation temperature, and the higher temperature increases the performance of the portable terminal by affecting adjacent components.
On the other hand, a portable terminal such as a mobile phone is often used in contact with a human face in use. Heat generated in the portable terminal is transmitted to the skin, resulting in a low temperature image, It is necessary to lower the heat transmitted to the outside of the mobile terminal to a certain temperature or less.
Various materials have been employed to solve the problem caused by the heat generated by the portable terminal. However, until now, the optimum material having excellent heat insulation and heat dissipation performance has not been developed due to its thin thickness.
On the other hand, Korean Patent Registration No. 10-1034456 discloses a dielectric layer having a composition including pore-forming silica and an organic polymer coated with an organic polymer; A dielectric layer laminated on the lower surface of the dielectric layer and made of at least one selected from the group consisting of a polyethylene terephthalate resin, a polyethylene naphthalate resin, a polybutylene terephthalate resin, a polybutylene naphthalate resin, a polytrimethylene terephthalate resin, a polytrimethylene naphthalate resin, An insulating layer made of at least one selected from the group consisting of phthalate resin and polycyclohexanedimethanol naphthalate polyarylate resin; And a double-sided pressure-sensitive adhesive layer laminated on the upper surface and the lower surface of the dielectric layer and the insulating layer laminate.
However, since the electromagnetic wave shielding and adiabatic tape has a three-layer structure of a dielectric layer, an insulating layer and an adhesive layer, it is not desirable to realize an ultra-thin thickness, It is impossible to solve the heat problem generated in recent high performance portable terminals because there is a limit to insulate the high temperature heat locally generated in the high performance portable terminal.
SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned problems, and an object of the present invention is to provide a heat insulating tape having an ultra-thin structure capable of efficiently insulating heat generated from a heat generating component of an electronic device, To provide a device.
Another object of the present invention is to provide a heat-insulating tape capable of maximizing the heat insulation efficiency by double-blocking heat by the heat-insulating pillar and the heat insulating layer included in the pressure-sensitive adhesive layer, have.
It is still another object of the present invention to provide a heat insulating tape capable of efficiently insulating heat generated from a heat generating component of an electronic device and maintaining the temperature of the front and rear surfaces of the electronic device below a predetermined temperature, .
It is still another object of the present invention to provide a composite material which can be laminated on a heat insulating tape to have a heat insulating or heat-dissipating function to provide a very thin thickness so as not to increase the thickness of electronic equipment, Sheet.
According to an aspect of the present invention, there is provided a heat insulating tape comprising: an adhesive layer; An insulating filler dispersed in the adhesive layer and blocking heat; And a substrate having the pressure-sensitive adhesive layer formed on one surface or both surfaces thereof.
Here, the substrate may be composed of a heat insulating layer which inhibits heat transfer.
In the adiabatic pressure-sensitive adhesive according to an embodiment of the present invention, the pressure-sensitive adhesive layer may be formed of an acrylic adhesive, an epoxy adhesive, a urethane adhesive, a polyamide adhesive, a polyethylen adhesive, an EVA adhesive, It can be one of PVC system.
In the adiabatic pressure-sensitive adhesive according to an embodiment of the present invention, the pressure-sensitive adhesive layer may be a hot melt adhesive layer sheet in a web state or an inorganic ball state in which thermally adhesive fibers are accumulated and have a plurality of pores.
In the adiabatic adhesive according to an embodiment of the present invention, the adiabatic filler may be a plate-shaped adiabatic filler arranged in the horizontal direction of the adhesive layer so as to block the transmitted heat.
The heat insulating adhesive according to an embodiment of the present invention may further include a spherical heat insulating filler dispersed in the region of the adhesive layer between the plate-like heat insulating fillers and shielding the transmitted heat.
In the adiabatic pressure-sensitive adhesive according to an embodiment of the present invention, the pressure-sensitive adhesive layer is formed by accumulating heat-stickable fibers obtained by electrospinning a thermosensitive material, a thermal spraying solution mixed with the heat-insulating filler and a solvent, The pore size of the web can be reduced.
In the adiabatic pressure-sensitive adhesive according to an embodiment of the present invention, the heat insulating layer may be a porous substrate or a graphite layer having a plurality of micropores forming air pockets capable of trapping air.
In the adiabatic adhesive according to an embodiment of the present invention, the adhesive layer has a structure in which the first and second adiabatic adhesive layers are laminated,
The heat insulating filler may be a heat insulating filler having different sizes or different shapes dispersed in the first and second heat insulating adhesive layers.
According to an aspect of the present invention, there is provided an electronic device including: a main body including a plurality of components including a heat generating component; And the aforementioned heat insulating tape adhered to the heat generating component or adhered to the component adjacent to the heat generating component.
Another object of the present invention is to provide a composite sheet comprising: a heat-insulating tape including a base material and an adhesive layer formed on one or both sides of the base material and having a heat-insulating filler dispersed therein; And a heat radiation sheet which is adhered to one side of the heat insulating tape adhesive layer to diffuse and radiate heat.
The composite sheet according to an embodiment of the present invention may further include a heat-radiating adhesive layer formed on the other surface of the heat-radiating sheet.
In the composite sheet according to an embodiment of the present invention, a first thermally conductive filler for horizontally diffusing heat dispersed in the heat-radiating adhesive layer and a second thermally conductive filler for transmitting the heat to the first thermally conductive filler And may further include a filler.
In the composite sheet according to an embodiment of the present invention, the first thermally conductive filler may have a plate-like structure and the second thermally conductive filler may have a spherical structure.
In the composite sheet according to an embodiment of the present invention, the first thermally conductive filler may include at least one of graphite nano fiber (GNF), carbon nanotube (CNT), metal fiber, AlN, . ≪ / RTI >
In the composite sheet according to an embodiment of the present invention, the second thermally conductive filler may be made of at least one of MgO, Al 2 O 3 , SiC, and diamond.
In the composite sheet according to an embodiment of the present invention, the first thermally conductive filler may have a shape having an aspect ratio of 1: 100.
In the composite sheet according to an embodiment of the present invention, the heat-radiating adhesive layer may contain 5 to 15 wt% of the first and second thermally conductive fillers.
The composite sheet according to an embodiment of the present invention may further include an electrically conductive adhesive layer formed on the other surface of the heat-radiating sheet.
In the composite sheet according to an embodiment of the present invention, the electrically conductive adhesive layer may include at least one of electrical conduction of at least one of an electrically conductive metal, carbon black, carbon nanotube, graphene, and conductive polymer (PDOT) And may be made of an adhesive material containing a substance.
According to the present invention, it is possible to maximize the heat insulation efficiency by realizing an ultra-thin insulating tape made of an adhesive layer and a heat insulating layer and having excellent adhesiveness and double heat shielding by the heat insulating filler and heat insulating layer included in the adhesive layer.
In the present invention, a reinforcing sheet is laminated on a heat insulating tape to insulate the heat insulating tape, and the heat generated from the heat generating component of the electronic device is prevented from being transmitted to the outside of the electronic device by heat insulation or heat radiation from the reinforcing sheet, The temperature of the rear surface can be kept below the specified temperature.
The composite sheet of the present invention can prevent the heat generated from the heat generating component from being transmitted to the outside, so that it is possible to prevent a user who is in close contact with the electronic device from wearing a low temperature image.
According to the present invention, it is possible to manufacture a tape and a heat insulating sheet having excellent insulation performance without increasing the thickness of electronic equipment and having an ultra-thin thickness.
1A and 1B are sectional views of a heat insulating tape according to the present invention,
2A to 2C are sectional views showing a state in which a heat insulating tape according to the present invention is adhered to an electronic device part,
3 is a sectional view of a composite sheet provided with a heat insulating tape according to a first embodiment of the present invention,
4 is a sectional view of a composite sheet provided with a heat insulating tape according to a second embodiment of the present invention,
5 is a cross-sectional view of a heat-sensitive adhesive layer applied to a composite sheet according to the present invention,
6 is a sectional view of a composite sheet provided with a heat insulating tape according to a third embodiment of the present invention,
7 is a cross-sectional view of a composite sheet provided with a heat insulating tape according to a fourth embodiment of the present invention.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Referring to FIGS. 1A and 1B, the
The
The
The
That is, the
In this case, since the size of the thermally adherable fiber can be reduced to a nano-size of 1 μm or less, the pore size becomes small in this case, and the air of the pore is suppressed from being convected to become a fine pocket for heat- .
Therefore, the
Further, when the
At this time, the fibers fall down with the
Therefore, in the present invention, the thermally adherable fibers having the
The
The size of the
As described above, the
Here, the
Therefore, in the present invention, the
If the spherical heat insulating filler is further dispersed in the
Meanwhile, in the present invention, the
That is, if the heat insulating fillers of different sizes or different shapes are dispersed in the first and second adiabatic adhesive layers, the heat blocking path of the first adiabatic adhesive layer and the heat blocking path of the second adiabatic adhesive layer are different, The efficiency can be improved.
For example, when the plate-like heat insulating filler is dispersed in the first adiabatic adhesive layer and the spherical adiabatic filler is dispersed in the second adiabatic adhesive layer, the heat transferred to the first adiabatic adhesive layer is partially blocked by the plate- The heat which is not blocked by the heat insulating filler is transmitted to the second heat insulating adhesive layer and is blocked by the spherical heat insulating filler, thereby increasing the heat insulating efficiency.
In the present invention, a first web having a plurality of pores formed by accumulating fibers capable of thermo-sticking obtained by electrospinning a spinning solution mixed with a thermosensitive material, a first heat-insulating filler and a solvent, Heat-sealable layer obtained by electrospinning a spinning solution in which a thermally adhesive material, a second heat-insulating filler and a solvent are mixed, and fibers in which a second heat-insulating filler is embedded are accumulated in a first web An adiabatic pressure-sensitive adhesive can be realized as a second adiabatic adhesive layer made of a second web having a plurality of pores.
That is, the laminated structure of the first and second adiabatic adhesive layers can be easily formed by electrospinning, and each of the first and second adiabatic adhesive layers can have a plurality of pores of the heat-generating micropockets, It is possible to provide a heat shielding capability.
The
Here, the porous substrate traps air in a plurality of micropores to suppress air convection, thereby making it possible to use air as a heat insulating material.
The porous substrate may be, for example, a nano-web having a plurality of pores by an electrospinning method, a nonwoven fabric having a plurality of pores, or the like, and may have a stacked structure thereof. Any material can be applied if it is possible. Here, it is preferable that the pore size of the porous substrate is less than 5 mu m at most from several tens nm.
Preferably, the porous substrate may be one of a nanofiber web having a plurality of pores formed by accumulation of nanofibers, a nonwoven fabric, and a laminated structure thereof.
Here, the nanofiber web is prepared by preparing a spinning solution by mixing a polymer material having excellent heat resistance and a solvent at a predetermined ratio, forming a nanofiber by electrospinning the spinning solution, accumulating the nanofiber, And is formed in the form of a nano web having fine pores.
As the diameter of the nanofibers is smaller, the specific surface area of the nanofibers is increased and the air trapping ability of the nanofiber web having a plurality of micropores is increased, so that the heat insulating performance is improved. Therefore, it is preferable that the diameter of the nanofiber is in the range of 0.3 to 5 um and the porosity of the micropores is in the range of 50 to 80%.
In general, air is known as an excellent thermal insulation material with low thermal conductivity, but it can not be used as a thermal insulation material by convection or the like. However, since the heat insulating sheet according to the present invention is formed in the form of a nanoweb having a plurality of micropores, air is not convected in each micropores and trapped (trapped). It is.
The spinning method applied to the present invention can be applied to a variety of spinning processes including general electrospinning, air-electrospinning (AES), electrospray, electrobrown spinning, centrifugal electrospinning, Any one of flash-electrospinning may be used.
Polymer materials used to make nanofiber webs include, for example, low polymer polyurethanes, high polymer polyurethanes, polystyrene (PS), polyvinylalcohol (PVA), polymethyl methacrylate (PMMA), polylactic acid (PLA) (PVA), polyvinylpyrrolidone (PVP), polyvinylchloride (PVC), nylon (Nylon), polyacrylonitrile (PAN) ), Polycarbonate (PC), polyetherimide (PEI), polyvinylidene fluoride (PVdF), polyetherimide (PEI), and polyestheresulphone (PES).
The solvent is selected from the group consisting of DMA (dimethyl acetamide), N, N-dimethylformamide, N-methyl-2-pyrrolidinone, DMSO, THF, DMAc, ethylene carbonate, DEC, dimethyl carbonate, ethyl methyl carbonate, propylene carbonate, water, acetic acid, and acetone. .
Since the nanofiber web is manufactured by the electrospinning method, the thickness is determined according to the spinning amount of the spinning solution. Therefore, there is an advantage in that it is easy to make the thickness of the nanofiber web to a desired thickness.
As described above, since the nanofiber web is formed as a nanofiber web in which the nanofibers are accumulated by the spinning method, it can be formed into a form having a plurality of micropores without any additional process, and the size of the micropores It is also possible to control. Therefore, it is possible to finely form a large number of pores, so that the heat transfer inhibiting performance is excellent and the heat insulating performance can be improved.
2A to 2C are sectional views showing a state in which a heat insulating tape according to the present invention is adhered to an electronic device part.
The above-described heat insulating tape according to the present invention can be directly adhered to a heat generating component of an electronic device or adhere to a component adjacent to the heat generating component to perform a heat insulating function.
That is, the
The double-sided
3 and 4 are sectional views of a composite sheet provided with a heat insulating tape according to the first and second embodiments of the present invention.
In the present invention, a composite sheet can be realized by bonding a reinforcing sheet to the above-mentioned heat insulating tape. Here, the reinforcing sheet may be a heat insulating member or a heat dissipating member, and the heat insulating sheet and the reinforcing sheet may be adhered to the adhesive layer interposed between the heat insulating sheet and the reinforcing sheet.
That is, in the present invention, a reinforcing sheet is laminated on a heat insulating tape to insulate from a heat insulating tape, and heat generated from a heat generating component of the electronic device is prevented from being transferred to the outside of the electronic device by heat insulation or heat radiation in the reinforcing sheet, There is an advantage that the front and rear temperatures can be kept below the specified temperature.
Therefore, the composite sheet of the present invention can prevent the heat generated from the exothermic component from being transmitted to the outside, so that it is possible to prevent a user who is in close contact with the electronic device from wearing a low temperature image.
Referring to FIG. 3, the composite sheet with the heat insulating tape according to the first embodiment of the present invention includes a
The heat-radiating
The heat-radiating
Referring to FIG. 4, the composite sheet with the heat insulating tape according to the second embodiment of the present invention includes a
Therefore, the composite sheet provided with the heat insulating tape according to the second embodiment of the present invention can perform the heat insulating function in the
5 is a cross-sectional view of a heat-sealable adhesive layer applied to the composite sheet according to the present invention.
5, the heat-
The heat-dissipating
That is, the first and second thermally
The second thermally
The first thermally
The second thermally
Here, the first thermally
The first and second thermally
It is preferable that the first and second thermally
6 and 7 are sectional views of a composite sheet provided with a heat insulating tape according to third and fourth embodiments of the present invention.
Referring to FIG. 6, the composite sheet with the heat insulating tape according to the third embodiment of the present invention includes a
The composite sheet provided with the heat insulating tape according to the third embodiment of the present invention can be adhered to both sides by the
7, the composite sheet with the heat insulating tape according to the fourth embodiment of the present invention includes a
The electrically conductive
In the heat-insulating tape and the composite sheet described above, when the pressure-sensitive adhesive layer is exposed to the outside, the handling properties such as transportation and storage may deteriorate due to the adhesive property of the pressure-sensitive adhesive layer. The releasing member is adhered to the pressure-sensitive adhesive layer exposed on the surface.
That is, the release member is attached to the adhesive layer before adhering to the parts of the heat insulating tape and the composite sheet to perform the function of protecting the adhesive layer, and after separating the release member and attaching the heat insulating tape and the composite sheet to the parts of the electronic device will be.
Such a release member can be made of a resin material such as a PET film, and a fiber material other than a resin material can be used.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is clearly understood that the same is by way of illustration and example only and is not to be construed as limited to the embodiments set forth herein. Various changes and modifications may be made by those skilled in the art.
The present invention provides a heat-insulating tape having an ultra-thin structure capable of efficiently insulating heat generated from a heat-generating component of an electronic device and capable of adhesion.
100a, 100b:
120: Insulating filler 130: Insulating layer
210: heat generating component 220: adjacent component
310: heat radiation sheet 320: heat radiation adhesive layer
321:
330: electrically conductive adhesive layer
Claims (18)
An insulating filler dispersed in the adhesive layer and blocking heat; And
Wherein the adhesive layer is formed on one surface or both surfaces of the substrate.
Wherein the adhesive layer is one of acrylic, epoxy, urethane, polyamide, polyethylen, EVA, polyester, and PVC.
Wherein the adhesive layer is a hot melt adhesive layer sheet in a web state or an inorganic ball state in which fibers capable of thermosetting are accumulated and have a plurality of pores.
Wherein the heat insulating filler is a plate-like heat insulating filler arranged in the horizontal direction of the adhesive layer so as to block the transmitted heat.
Wherein the adhesive layer is a web having a plurality of pores which are formed by accumulating thermosettable fibers obtained by electrospinning a thermosensitive material, a thermosetting material mixed with the thermosetting filler and a solvent, and forming fine pockets for heat transfer.
Wherein the substrate is a porous substrate or graphite layer having a plurality of micropores forming an air pocket capable of trapping air.
The pressure-sensitive adhesive layer has a structure in which the first and second adiabatic pressure-sensitive adhesive layers are laminated,
Wherein the heat insulating filler is an insulating filler dispersed in each of the first and second heat insulating adhesive layers and having different sizes or different shapes.
And a heat insulating tape according to any one of claims 1 to 7, wherein the heat insulating adhesive tape is adhered to the heat generating component or adheres to a component adjacent to the heat generating component.
And a heat radiation sheet which is adhered to one side of the heat insulating tape adhesive layer to diffuse and radiate heat.
And a heat radiation adhesive layer formed on the other surface of the heat radiation sheet.
A first thermally conductive filler for horizontally diffusing heat dispersed in the heat-radiating adhesive layer, and a second thermally conductive filler for transferring the heat to the first thermally conductive filler.
Wherein the first thermally conductive filler is a plate-like structure and the second thermally conductive filler is a spherical structure.
Wherein the first thermally conductive filler comprises at least one material selected from GNF (Graphite Nano Fiber), CNT (Carbon Nano Tube), metal fiber, AlN (Aluminum nitride) and BN (Boron nitride).
Wherein the second thermally conductive filler comprises at least one material selected from the group consisting of MgO, Al 2 O 3 , SiC, and diamond.
Wherein the first thermally conductive filler has a shape having an aspect ratio of 1: 100.
Wherein the heat radiation adhesive layer contains 5 to 15 wt% of the first and second thermally conductive fillers.
And an electrically conductive adhesive layer formed on the other surface of the heat radiation sheet.
Wherein the electrically conductive adhesive layer comprises an adhesive material comprising at least one electrically conductive material selected from the group consisting of an electrically conductive metal, carbon black, carbon nanotube, graphene, and a conductive polymer (PDOT).
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KR20140089037 | 2014-07-15 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102118977B1 (en) * | 2019-01-03 | 2020-06-05 | 주식회사 나노플랜 | Manufacturing method of functional nanofiber fabric |
KR20200084812A (en) * | 2020-02-25 | 2020-07-13 | 주식회사 나노플랜 | Functional nanofiber fabric and its manufacturing apparatus |
KR102142897B1 (en) * | 2019-02-14 | 2020-08-10 | 주식회사 나노플랜 | Functional non-woven fabric |
US11284538B2 (en) | 2019-08-19 | 2022-03-22 | Samsung Electronics Co., Ltd. | Electronic device including composite heat dissipation member and method of manufacturing the same |
US11842945B2 (en) | 2020-10-30 | 2023-12-12 | Samsung Electronics Co., Ltd. | Chip on film package and display apparatus including the same |
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KR101034456B1 (en) | 2010-06-04 | 2011-05-17 | 대원케미칼(주) | Tape for electrowave shielding and heat insulation |
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KR101161735B1 (en) * | 2012-01-31 | 2012-07-03 | (주)메인일렉콤 | Heat-radiation sheet |
JP6072787B2 (en) * | 2012-06-20 | 2017-02-01 | 日本碍子株式会社 | Porous plate filler for heat insulation, coating composition, heat insulation film, and heat insulation film structure |
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2015
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101034456B1 (en) | 2010-06-04 | 2011-05-17 | 대원케미칼(주) | Tape for electrowave shielding and heat insulation |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102118977B1 (en) * | 2019-01-03 | 2020-06-05 | 주식회사 나노플랜 | Manufacturing method of functional nanofiber fabric |
KR102142897B1 (en) * | 2019-02-14 | 2020-08-10 | 주식회사 나노플랜 | Functional non-woven fabric |
US11284538B2 (en) | 2019-08-19 | 2022-03-22 | Samsung Electronics Co., Ltd. | Electronic device including composite heat dissipation member and method of manufacturing the same |
KR20200084812A (en) * | 2020-02-25 | 2020-07-13 | 주식회사 나노플랜 | Functional nanofiber fabric and its manufacturing apparatus |
US11842945B2 (en) | 2020-10-30 | 2023-12-12 | Samsung Electronics Co., Ltd. | Chip on film package and display apparatus including the same |
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