KR20150132116A - Shampoo composition - Google Patents

Abstract

(A) a surfactant containing a sulfuric acid residue, (B) a gallic acid glycoside, (C) a gloss-imparting agent, (D) a cationic polymer, and (E) (B + C) / (A + D) of the component (A) and the component (C) to the component (A) and the component (D) is 0.05 to 0.6 and the component (D) Wherein the component (D1) and the component (D2) have a specific mass ratio and the component (E) comprises a dimethylpolysiloxane (E1) and an amino-modified silicone (E2) E1) and (E2) are a specific mass ratio.

Description

Shampoo composition {SHAMPOO COMPOSITION}

The present invention relates to a shampoo composition.

In Southeast Asia, where the average temperature is over 25 ℃ and the average relative humidity is about 70% throughout the year, a habit of using air conditioners has been formed in Southeast Asia, which is characterized by high temperature and high humidity. Therefore, it is strongly demanded to provide a shampoo composition which is excellent in both lightness and softness, and which is good in lightness, in the environment where the temperature and humidity are largely different between indoor and outdoor, in any circumstance.

Conventionally, it is common to use conditioners and treatments after use of shampoo for the purpose of improving the finish feeling after hair washing. In addition, many techniques relating to a shampoo composition having an effect of improving the feel of hair after drying by shampooing have been proposed and marketed as conditioner shampoo. For example, it has been proposed to incorporate a cationization polymer, various silicones, oil components, cationic surfactants, and the like into a shampoo composition as a tactile agent (for example, , See Patent Documents 1 to 4).

It has also been proposed to incorporate a molybdate acid glycoside into a shampoo composition in order to improve the stiffness of damaged hair and hair (see, for example, Patent Documents 5 and 6) .

However, the technology of these proposals is that, in a conditioning shampoo under high temperature and high humidity, the hair becomes sticky, the hair sticks to each other, so that it is difficult to stylize, and the hairiness, smoothness and smoothness of the hair may be damaged.

Therefore, it is possible to provide a shampoo composition which is easy to be styled without spreading of hair even in a region where the environment of high humidity and high air humidity is well heard and low humidity, and which is smoothly finished and smoothly finished without sticking to each other, Is desired.

Japan Specification No. 2010-512406 Japanese Patent Application Laid-Open No. 2007-45726 Japanese Patent Application Laid-Open No. 2006-219449 Japan Specification No. 2005-506989 Japanese Patent Application Laid-Open No. 2000-319116 Japanese Patent Application Laid-Open No. 2004-059560

SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned conventional problems and to achieve the following objects. That is, the present invention relates to a hair styling composition which does not spread hair even in a region where high temperature and high humidity and air conditioning are well received, and low humidity and high environmental change, and smoothly and smoothly finished, It is an object of the present invention to provide a shampoo composition excellent in usability.

The shampoo composition of the present invention as means for solving the above-

(A) an anionic surfactant having a sulfuric acid residue,

(B) a molybdate acid glycoside,

(C) a gloss-imparting agent,

(D) a cationic polymer, and

(E) 0.15% by mass to 5.0% by mass of a silicone compound,

(B + C) / (A + D) of the component (B) and the component (C) to the component (A) and the component (D) is 0.05 to 0.6,

Wherein the component (A) contains a polyoxyethylene alkyl ether sulfate (A1) and an alkyl sulfate (A2)

Wherein the component (D) comprises cationized guar gum (D1) and cationized cellulose (D2), and the mass ratio (D1 / D2) of the component (D1) 2 to 20,

Wherein the component (E) comprises a dimethylpolysiloxane (E1) and an amino-modified silicone (E2), and the mass ratio (E1 / E2) of the component (E1) to the component (E2) is 2 to 30.

According to the present invention, it is possible to solve the above-mentioned conventional problems, to achieve the above object, to prevent hair from spreading even in a region where a high humidity environment with a high temperature and a high humidity are well heard, It is possible to provide a shampoo composition excellent in usability because the hair does not adhere to each other and is finely finished and combines smoothness and softness.

(Shampoo composition)

The shampoo composition of the present invention contains an anionic surfactant having a sulfuric acid residue (hereinafter may be referred to as "component (A)"), a molybdate acid glycoside (glycoside) (Hereinafter may be referred to as "component (B)"), a gloss-imparting agent (hereinafter, may be referred to as "component (C)"), a cationic polymer (Hereinafter may be referred to as "component (E)"), and a silicone compound (hereinafter, may be referred to as "component (E)").

<Component (A): Anionic surfactant having sulfuric acid residue>

The anionic surfactant as the component (A) is a component that forms a suitable foam and also serves as a cleansing base to remove contaminants adhering to the hair.

The component (A) is not particularly limited as long as it has a sulfuric acid residue and can be appropriately selected in accordance with the purpose. Examples thereof include an alkylsulfate, an alkenylsulfate, a polyoxyalkylene alkylether sulfate, a polyoxyalkylenealkenylether Sulfates, polyoxyalkylenephenyl ether sulfates, amide ether sulfates, and the like.

The salt is not particularly limited, can be appropriately selected in accordance with the purpose, and includes, for example, alkali metals such as sodium and potassium; Ammonium; Alkanolamine, and the like.

Among these, polyoxyalkylene alkyl ether sulfate, polyoxyalkylenealkenyl ether sulfate and alkyl sulfate are preferable as the component (A), and anionic surfactants represented by the following general formula (A1) (Hereinafter may be referred to as &quot; component (A1)) &quot;, and more preferably an anionic surfactant represented by the following general formula (A2)

R ¹ O (CH ₂ CH ₂ O) _m SO ₃ M ¹ ... In formula (A1)

(Wherein, in the general formula (A1), R ¹ represents an alkyl or alkenyl group having 10 to 18 carbon atoms, M ¹ represents any one of an alkali metal, ammonium and alkanolamine, and m represents an average Represents an integer of 1 to 5 as an additional moles.]

R ² OSO ₃ M ² ... In general formula (A2)

[Wherein, in the general formula (A2), R ² represents an alkyl group having 10 to 18 carbon atoms, and M ² represents any one of an alkali metal, ammonium, and alkanolamine.

From the viewpoint that both the dissolution stability in the shampoo composition and the favorable passage between the fingers of the hair at the time of shaving are satisfied, R ¹ in the formula (A1) and / or R ² in the formula (A2) , And an alkyl group having from 12 to 16 carbon atoms are preferable. Further, m in the general formula (A1) is preferably 2 to 3 since it is possible to impart smoothness to the hair during rinsing. M ¹ in the general formula (A1) or M ² in the general formula (A2) is preferably at least one selected from the group consisting of the following: from the viewpoint of smoothness of the hair during rinsing, Is particularly preferable.

As the component (A), a commercially available product may be used, or a properly synthesized product may be used.

Specific examples of the commercially available products include Texapon ALES 70 (POE (3) ammonium lauryl ether sulfate, BASF), Sinorin SPE-1250 (POE (2) lauryl ether sodium sulfate, Of component (A1); (A2) such as Texapon ALS 70 (ammonium lauryl sulfate, BASF), Texapon K12 (sodium lauryl sulfate, BASF), and the like.

Of these, Texapon ALES 70 (POE (3) lauryl ether sulfate ammonium, Texapon ALS 70 (ammonium lauryl ammonium sulfate, as the component (A2)) is used as the component (A1) BASF).

As the component (A), it is particularly preferable to use the component (A1) and the component (A2) in combination. When the component (A) is only the component (A1), the convenience of styling of the hair under high humidity and the smoothness of the hair at the time of rinsing may be lowered and a sufficient bubble diary may not be obtained. When the component (A) is only the component (A2), the convenience of styling of the hair under high humidity and the smoothness of the hair at the time of rinsing are lowered and the smoothness of the hair at the time of rinsing becomes insufficient have.

The content of the component (A1) is not particularly limited and may be appropriately selected in accordance with the purpose. The content is preferably 3% by mass to 24% by mass, more preferably 5% by mass to 22% , And particularly preferably from 7% by mass to 15% by mass. When the content of the component (A1) is less than 3 mass%, the smoothness of the hair during rinsing may be lowered. When the content is more than 24 mass%, the foam off during rinsing is deteriorated, There is something worse.

The content of the component (A2) is not particularly limited and may be appropriately selected in accordance with the purpose. The content is preferably 1% by mass to 15% by mass, more preferably 2% by mass to 12% by mass, based on the total amount of the shampoo composition , And particularly preferably from 3% by mass to 10% by mass. If the content of the component (A2) is less than 1% by mass, the foam off during rinsing may deteriorate. When the content exceeds 15% by mass, the smoothness of the hair during rinsing may be reduced.

The content of the component (A) (the total content of the component (A1) and the component (A2)) is not particularly limited and may be appropriately selected in accordance with the intended use. Examples thereof include a good bubble diary, Is preferably 5% by mass to 30% by mass, more preferably 10% by mass to 25% by mass, still more preferably 12% by mass to 20% by mass relative to the total amount of the shampoo composition, Is particularly preferable. If the content of the component (A) is less than 5% by mass, the foaming diarrhea may deteriorate, and the smoothness of the hair upon rinsing may decrease. When the content exceeds 30% by mass, The foam off during rinsing may deteriorate, and the smoothness of the hair during rinsing may be reduced.

The mass ratio (A1 / A2) of the component (A1) to the component (A2) is not particularly limited and can be appropriately selected in accordance with the purpose. The foamability and smoothness of the hair during rinsing, 1 to 7, and more preferably 1.3 to 4, from the viewpoint of preventing sticky of the hair after drying at a high humidity (e.g., a humidity of 70% RH). When the mass ratio (A1 / A2) is less than 1, the smoothness of the hair at the time of rinsing may deteriorate. When the mass ratio (A1 / A2) is more than 7, the hair after drying at high temperature and high humidity (temperature 27 ° C and humidity 70% RH) Tacky, sticky, hard to be styled, light in hair, and smoothness of hair after drying may be deteriorated.

&Lt; Component (B): gallate acid glycosides >

The gallic acid acid glycosides as the component (B) can obtain the softness of the hair after drying, and the hair does not spread even under a low humidity (at a temperature of 25 캜 and a humidity of 40% RH), and is easy to stylize, It is a component that can give the function that the hair is not sticky and the hair is finely finished.

The gallic acid gypsum is not particularly limited and can be appropriately selected in accordance with the purpose. Examples thereof include gallic acid methyl ester-3-glucoside, gallic acid methyl ester-4-glucoside, gallic acid propyl ester-3-glucoside, Methyl ester-3-maltoside, gallic acid-3-glucoside, gallic acid-3-maltoside, octyl-3-maltosyl gallate, gallic acid-3-glucuronide, galacturonyl gallate, , 5-diglucoside, gallic acid-3, 4-diglucoside, gallic acid-3,5-diglucoside and the like. These may be used alone, or two or more kinds may be used in combination. Of these, from the viewpoint of softness of the hair after drying, gallic acid-3, 4-diglucoside and gallic acid-3, 5-diglucoside are particularly preferable.

As the gallic acid acid glycoside as the component (B), a commercially available product may be used, or a properly synthesized product may be used. Examples of commercially available products include commercially available products such as gallic acid-3, 4-diglucoside (DGA, manufactured by Mitsui Chemicals, Inc.) and gallic acid-3,5-diglucoside (DGA, manufactured by Mitsui Chemicals, Inc.).

The content of the gallic acid glycosides as the component (B) is not particularly limited and may be appropriately selected in accordance with the purpose. The content is preferably from 0.01% by mass to 7.5% by mass, more preferably from 0.05% by mass to 3% By mass, and more preferably 0.1% by mass to 1% by mass. If the content is less than 0.01% by mass, the softness of the hair can not be obtained, and the hair may spread too much under high temperature and high humidity (at a temperature of 27 캜 and a humidity of 70% RH). When the content is more than 7.5% by mass, the amount of adsorption to hair becomes excessive, and the hair (hair) becomes too hot under high temperature and high humidity (temperature 27 ° C and humidity 70% RH) and low temperature and low humidity (temperature 25 ° C and humidity 40% RH) It is difficult for the hair to stick to each other and styling of the hair, and the hair may become sticky and the hairiness may be reduced.

&Lt; Component (C): Glossing agent >

The shampoo composition may be given a pearl-like gloss by the gloss-imparting agent (the "gloss agent", the "pearlizing agent", the "pearlizing agent", etc.) as the component (C). This is advantageous in that the value of the product can be increased.

The component (C) not only imparts a pearly luster to the shampoo composition but also prevents the hair from sticking to each other without spreading the hair under high temperature and high humidity (temperature 27 ° C and humidity 70% RH) Hair styling is easy and hair is not sticky, so it is finished lightly.

The component (C) is not particularly limited and can be appropriately selected in accordance with the purpose. For example, stearic esters of ethylene glycol, diethylene glycol or triethylene glycol are preferable. Specific examples thereof include hydroxystearate, Polyethylene glycol monostearate, polyethylene glycol distearate, ethylene glycol monostearate, ethylene glycol distearate, stearic acid monoethanolamide, stearic acid monoethanol stearate, and the like. These may be used alone, or two or more kinds may be used in combination. Among them, in view of smoothness of hair, smoothness of hair after drying, and stability of pearl, it is preferable to use an ethylene glycol diisocyanate such as ethylene glycol diisocyanate Tealate is particularly preferred.

The component (C) is generally dispersed as a crystalline material in a shampoo composition, so that a pearly shine can be imparted to the shampoo composition.

The method for preparing the dispersion of the crystalline product is not particularly limited and can be appropriately selected in accordance with the purpose. For example, the component (C) is melted and the aqueous solution of the surfactant in which the component (C) And the component (C) is dispersed and mixed, followed by cooling.

By adding the dispersion of the crystalline material of the component (C) to the shampoo composition so that the component (C) is in a predetermined concentration, the shampoo composition can be appropriately provided with a pearl-like luster.

The median particle size of the dispersion of the crystalline material of the component (C) is not particularly limited and may be appropriately selected depending on the purpose. The particle diameter is preferably 0.5 m to 6 m, more preferably 1 m to 3 m. If the median particle diameter is less than 0.5 mu m, the smoothness of the hair at the time of rinsing may be lowered, and the pearl-like luster may not be imparted, and the feeling of luxury may be lost. If the median grain size exceeds 6 mu m, the hairiness after hair drying may be reduced, and the feeling of being prone to hairbrushing may be lowered, which may result in deteriorated washing sensation.

The dispersed form of the crystalline material of the component (C) is preferably acicular crystals. By forming acicular crystals, the smoothness of the hair at the time of rinsing is improved.

The above-mentioned median particle diameter is generally expressed as D50, which means that when the dispersion liquid is divided into two particles having a certain particle size, the larger side and the smaller side are equivalent diameters. Specifically, the relative refractive index with respect to water was adjusted to 1.08 by using a laser diffraction particle size distribution analyzer (LA-920, manufactured by Horiba Ltd.), and the above-mentioned (C) By measuring the particle size distribution of the dispersion of the crystalline material of the component, the median particle size can be calculated.

The content of the gloss-imparting agent as the component (C) is not particularly limited and can be appropriately selected in accordance with the purpose. From the viewpoint of imparting a pearl luster, the content is preferably 1% by mass to 5% by mass relative to the total amount of the shampoo composition , And more preferably 1.2% by mass to 4.5% by mass. If the content is less than 1% by mass, the appearance of the pear becomes weak, and the hair tends to adhere to each other under high temperature and high humidity (temperature of 27 ° C and humidity of 70% RH), styling of the hair is difficult to be performed, The smoothness may be deteriorated. When the content exceeds 5% by mass, the smoothness of the hair after drying is lowered, and the usability (ease of coming out of the bottle) may be poor.

&Lt; Component (D): cationic polymer >

The cationic polymer as the component (D) is a cationically polymerizable compound which is cationized (hereinafter sometimes referred to as "component (D1)") and cationized cellulose (hereinafter referred to as "component (D2) .

&Lt; Component (D1): &lt; RTI ID = 0.0 &gt;

The cationic guar gum as the component (D1) is also called guar hydroxypropyl trimonium chloride, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum and the like.

The nitrogen content of the component (D1) is not particularly limited and can be appropriately selected in accordance with the purpose. From the viewpoint of imparting smoothness to the hair during rinsing, the nitrogen content is preferably 1% by mass to 1.8% by mass, more preferably 1.1% By mass to 1.45% by mass.

The nitrogen content can be measured by the Kjeldahl method by decomposing the component (D1) into sulfuric acid to make ammonium sulfate, and quantifying the ammonia. Specifically, it can be measured by the method described in General Test Methods 44. Nitrogen Determination Method of "Quasi-drug Material Specification 2006 (Yakushi Daily)".

As the component (D1), a commercially available product or a properly synthesized product may be used. Specific examples of the commercial product include JAGUAR C14S (nitrogen content: 1.3% by mass to 1.7% by mass), JAGUAR Excel (nitrogen content: 1.0% by mass to 3.0% by mass), Jaguar C-500 (nitrogen content: % By mass to 1.45% by mass), such as JAGUAR series (manufactured by Rhodia); N-Hance CG14 (nitrogen content: 1.15 mass% ~ 1.45 mass%), N-Hance 3299 (nitrogen content: 1.15 mass% ~ 1.45 mass%) and N-Hance CGG45 N-Hance series (Ashland, Aqualon division); CATHIOLAL G-100S (nitrogen content: 1.0 mass% to 1.7 mass%) (Toho Chemical Industry Co., Ltd.); Guarsafe JK140 (nitrogen content: 1.3 mass% to 1.7 mass%) (manufactured by JINGKIN CHEMISTRY COMPANY). Of these, N-Hance 3299, N-Hance CCG45 and Jaguar C-500 are particularly preferable in terms of smoothness of the hair during rinsing and smoothness of the hair after drying.

The content of the component (D1) is not particularly limited and can be appropriately selected in accordance with the purpose. From the standpoint of good foam off during rinsing, smoothness of hair during rinsing, and smoothness of hair after drying, Is preferably 0.075 mass% to 4.5 mass%, more preferably 0.1 mass% to 1.1 mass%, and even more preferably 0.2 mass% to 0.6 mass% with respect to the whole amount. When the content of the component (D1) is less than 0.075 mass%, the smoothness of the hair at the time of rinsing may decrease. When the content exceeds 4.5 mass%, the softness of the hair after drying, the foam off at the time of rinsing, There is something worse.

Component (D2): Cationic cellulose

The cationic cellulose as the component (D2) is reacted with a trimethyl ammonium substituted epoxide, also called polyquaternium-10, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose, Lt; RTI ID = 0.0 &gt; hydroxyethylcellulose. &Lt; / RTI &gt;

The nitrogen content of the component (D2) is not particularly limited and can be appropriately selected in accordance with the purpose. The bubble off at the time of rinsing is good. It is preferably 1.5% by mass to 2.2% by mass, more preferably 1.6% by mass to 2.0% by mass in that smoothness can be imparted to the hair during rinsing.

The nitrogen content can be determined by the Kjeldahl method by decomposing the component (D2) into sulfuric acid and using ammonium sulfate as the ammonia. Specifically, it can be measured by the method described in "General Substance Standards for Pharmaceutical Quasi-Drugs 2006 (Yakushi Daily)", General Test Methods 44. Nitrogen Determination Method.

As the component (D2), a commercially available product or a suitably synthesized product may be used. Specific examples of the commercially available products include UCARE Polymer JR series such as UCARE Polymer JR400 (nitrogen content: 1.5 mass% to 2.2 mass%) and UCARE Polymer JR-30M (nitrogen content: 1.5 mass% to 2.2 mass% (Manufactured by Dauga Chemical); (For example, CATICHANOL HC 100, CATILNELL HC 200 and the like) (manufactured by Toho Chemical Industry Co., Ltd.); Leo grade series (manufactured by Lion Corporation) of Leo Gado GP, Leo Gado KGP, and Leo Gado MGP (nitrogen content: 1.6 mass% to 2.0 mass%); And MICONIUM (registered trademark) PQ10-J-400 (nitrogen content: 1.5 mass% to 2.2 mass%) (manufactured by MIWON). Among them, bubble off at the time of rinsing is good. MICONIUM (registered trademark) PQ10-J-400, Leo G. GP, and Leo G. KGP are particularly preferred because they can impart smoothness to the hair during rinsing.

The content of the component (D2) is not particularly limited and may be appropriately selected in accordance with the purpose. From the viewpoint of good foam off during rinsing and smoothness of the hair during rinsing, the content of the component (D2) By mass to 1% by mass, more preferably 0.03% by mass to 0.7% by mass, and still more preferably 0.09% by mass to 0.5% by mass. When the content of the component (D2) is less than 0.01% by mass, the smoothness of the hair at the time of rinsing may be lowered. When the content is more than 1% by mass, the softness of the hair after drying and the foam off during rinsing There is work.

The total content of the component (D1) and the component (D2) (hereinafter sometimes referred to as "content of the component (D)") is not particularly limited and can be appropriately selected in accordance with the purpose. By mass, more preferably from 0.2% by mass to 1.5% by mass, and still more preferably from 0.3% by mass to 0.8% by mass. If the content of the component (D) is less than 0.1% by mass, smoothness of the hair after drying may not be obtained, and if it exceeds 5% by mass, the softness of the hair after drying may deteriorate, Viscosity may increase and usability may deteriorate.

The mass ratio (D1 / D2) of the component (D1) and the component (D2) is preferably 2 to 20, more preferably 3 to 15, and more preferably 3 to 15, from the viewpoints of smoothness of the hair during rinsing and smoothness of the hair after drying. 9 is more preferable. When the mass ratio (D1 / D2) is less than 2, the smoothness of the hair at the time of rinsing may be lowered. When the mass ratio is more than 20, the smoothness of the hair after drying may be lowered.

&Lt; Component (E): Silicone compound >

The silicone compound as the component (E) is composed of dimethylpolysiloxane (hereinafter may be referred to as "component (E1)") and amino-modified silicone (hereinafter referred to as "component (E2)").

&Lt; Component (E1): Dimethylpolysiloxane >

The component (E1) is not particularly limited as long as it is a dimethylpolysiloxane and can be appropriately selected in accordance with the purpose. Examples thereof include trimethylsilyl group (terminal) dimethylpolysiloxane, silanol group terminal dimethylpolysiloxane, . Among these, trimethylsilyl-terminated dimethylpolysiloxane is preferable in view of lightness of the hair after drying, smoothness of hair after drying, and a sense of hairiness can be imparted.

The kinematic viscosity (kinematic viscosity) of the dimethylpolysiloxane at 25 캜 is preferably in the range of from 10,000 mm 2 / s to 30,000,000 mm 2 / s (kinematic viscosity) at the point that the hair after drying, smoothness of the hair after drying, More preferably 100,000 mm2 / s to 10,000,000 mm2 / s, and particularly preferably 100,000 mm2 / s to 1,000,000 mm2 / s.

The kinematic viscosity of the dimethylpolysiloxane at 25 캜 can be measured, for example, by the following method.

A toluene solution of dimethylpolysiloxane having a concentration of 1 g / 100 ml is prepared, and the specific viscosity (specific viscosity) ( ? Sp) (25 占 폚) is determined by the following equation (1). Subsequently, the intrinsic viscosity [ eta ] is obtained by substituting into the relational expression of Huggins expressed by the following formula (2). The Huggins constant uses the one described in Nakamuda, anecdote, 77, 588, 1956. Next, [ ? ] Is substituted into A. Kolorlov's equation represented by the following formula (3), and the molecular weight is obtained. Finally, the kinematic viscosity ( ? ) Of the dimethylpolysiloxane can be obtained by substituting M into the equation of AJ Barry shown in the following formula (4).

? sp = ( ? / ? ₀ ) -1 ... Equation (1)

? sp = [ ? ] + K '[ ? ] ² ... Equation (2)

^{[Η] = 0.215 × 10 -4} M 0 .65 ... Equation (3)

^{log η = 1.00 + 0.0123M 0 .5} ... Equation (4)

In the above formula (1), & quot ;? ₀ &quot; represents the viscosity of toluene, and & quot ;? &Quot;

The above ? ₀ and ? Are measured in accordance with Method 1 of General Methods for Viscosity Measurement of Cosmetics Raw Materials.

The component (E1) is preferably emulsified in advance with an emulsifier in view of the efficiency of production of the shampoo composition and dispersion stability. The emulsifying agent and the emulsifying method when the component (E1) is emulsified are not particularly limited and can be appropriately selected in accordance with the purpose.

The number average particle size of the component (E1) in the emulsion is not particularly limited and can be appropriately selected in accordance with the purpose. It is preferably from 0.5 mu m to 60 mu m, more preferably from 10 mu m to 50 mu m, and particularly preferably from 15 mu m to 40 mu m, from the viewpoint of rapid drying of hair after hair firing. If the number average particle diameter is less than 0.5 탆, the hair tends to adhere to each other under high temperature and high humidity (at a temperature of 27 캜 and a humidity of 70% RH), styling becomes difficult and stickiness occurs, If it exceeds 60 탆, the smoothness of the hair at the time of rinsing may be lowered.

The number average particle size can be determined by taking an image of particles observed with an optical microscope in a computer at arbitrary number of 100 locations to obtain the same magnification ratio and then performing image processing (for example, two-dimensional image analysis software WinROOF ).

As the component (E1), a commercially available product may be used, or a properly synthesized product may be used. Specific examples of the component (E1) sold as an emulsion include BY22-029 (kinematic viscosity: 100,000 mm 2 / s, number average particle diameter: 0.5 탆) (Dow Corning Co., Ltd.), DC-7137 : 600,000 mm &lt; 2 &gt; / s, number average particle diameter: 35 mu m) (manufactured by Dow Corning); KM-902 (kinematic viscosity: 500,000 mm &lt; 2 &gt; / s, number average particle diameter: 0.5 m) (manufactured by Shin-Etsu Chemical Co., Ltd.); (Dynamic viscosity: 100,000 mm 2 / s, number average particle size: 0.5 탆), Leofro DMS-60 [kinematic viscosity: 10,000,000 mm 2 / s: 4,000,000 mm 2 / s: 1,000 mm 2 / s = 15:15:70 Mass ratio), number average particle diameter: 0.9 占 퐉] (the above, manufactured by Shibo Kasei Kogyo Co., Ltd.); EMU120 (kinematic viscosity: 900,000 mm &lt; 2 &gt; / s, number average particle diameter: 20 mu m) (manufactured by Momento Toshiba). Of these, DC-7137 and EMU120 are preferable in terms of smoothness of hair after drying, lightness of hair under high temperature and high humidity (at a temperature of 27 DEG C and humidity of 70% RH), and convenience of styling.

The content of the component (E1) is preferably from 0.1% by mass to 4.8% by mass, and more preferably from 0.5% by mass to 3% by mass, relative to the total amount of the shampoo composition, from the viewpoint of obtaining smoothness of the hair after drying. When the content of the component (E1) is less than 0.1% by mass, smoothness of the hair at the time of rinsing and smoothness of the hair after drying may not be obtained. When the content exceeds 4.8% by mass, And humidity of 70% RH), the hair tends to adhere to each other, and the convenience of styling of the hair is deteriorated, stickiness is caused to the hair, and the hairiness of the hair is lowered.

<Component (E2): Amino-modified silicone>

The amino-modified silicone as the component (E2) is not particularly limited and can be appropriately selected in accordance with the purpose. For example, aminoethylaminopropylsiloxane-dimethylsiloxane copolymer (hereinafter referred to as "amodimicicon" Aminoethylaminopropylmethylsiloxane-dimethylsiloxane copolymer (hereinafter may be referred to as "aminoethylaminopropylmethicone dimethicone copolymer"), an amino-modified organopolysiloxane chain and a polyoxyalkylene chain, (Hereinafter may be referred to as &quot; linear aminopolyether-modified silicone &quot;), aminopropyldimethicone, and the like. These may be used alone, or two or more kinds may be used in combination. Of these, amodimethicone and a straight chain aminopolyether-modified silicone are preferable because they can impart smoothness of hair during rinsing.

As the component (E2), a commercially available product may be used or a suitably synthesized product may be used.

Specific examples of commercially available products of the component (E2) include SM8904CE, BY22-079, FZ-4671 (manufactured by Dow Corning Toray Co., Ltd., Dow Corning Co., Ltd.), DC2-8194 -8004, KF-867S, KF-880 (manufactured by Shin-Etsu Chemical Co., Ltd.); Aminoethylaminopropylmethicone dimethicone copolymer such as KF-8005 (manufactured by Shin-Etsu Chemical Co., Ltd.); SILSTYLE 201 (bisisobutyl PEG-14 / amodimetercon) copolymer, SILSTYLE 401 (bis-butyloxyamidodimicon / PEG-60 / ) Copolymer (manufactured by Dow Corning Toray Co., Ltd.), and other straight-chain aminopolyether-modified silicones; And aminopropyldimethicone such as KF-8015, KF-865, KF-8017, KF-8018 and KF-8020 (manufactured by Shin-Etsu Chemical Co., Ltd.). Of these, SILSTYLE 401 is preferred.

The content of the component (E2) is not particularly limited and may be appropriately selected in accordance with the purpose. It is preferably 0.01% by mass to 1.5% by mass, more preferably 0.1% by mass to 1% by mass relative to the total amount of the shampoo composition Do. When the content of the component (E2) is less than 0.01% by mass, smoothness of the hair after drying may not be obtained. When the content exceeds 1.5% by mass, hair The hair is likely to stick to each other, the convenience of styling deteriorates, the hair tends to stick, and the hairiness of the hair may be lowered.

The total content of the component (E1) and the component (E2) (hereinafter sometimes referred to as "content of the component (E)") Is preferably 0.15 mass% to 5.0 mass% and more preferably 0.8 mass% to 3.8 mass% with respect to the total amount of the shampoo composition in view of preventing the convenience of the shampoo composition from spreading. When the content of the component (E) is less than 0.15% by mass, smoothness of the hair at the time of rinsing and smoothness of the hair after drying can not be obtained. When the content exceeds 5.0% by mass, And the humidity is 70% RH, the hair tends to adhere to each other, the convenience of styling deteriorates, the hair tends to stick, the hair becomes light and the usability decreases. When the component (E) is an emulsion, The emulsion particles may coalesce and the stability may deteriorate.

The mass ratio (E1 / E2) of the component (E1) to the component (E2) is preferably 2 to 30, and more preferably 5 to 27. If the mass ratio (E1 / E2) is less than 2, the hair tends to adhere to each other after drying at a high temperature and a high humidity (at a temperature of 27 DEG C and a humidity of 70% RH), and the convenience of styling deteriorates, There is a possibility that the shampoo composition may be poor in the feeling of washing feeling and the lightness of the hair may be lowered. When the mass ratio (E1 / E2) exceeds 30, the smoothness and usability of the hair after drying may be deteriorated.

&Lt; Mass ratio (B + C) / (A + D) >

The mass ratio (B + C) / (A + D) of the components (B) and (C) to the components (A) and (D) % RH), 0.05 to 0.6, preferably 0.06 to 0.5, more preferably 0.08 to 0.4 in terms of hair styling convenience and hairiness. If the mass ratio (B + C) / (A + D) is less than 0.05, the hair tends to adhere to each other under high temperature and high humidity (temperature 27 ° C and humidity 70% RH) , The hair tends to become sticky and the hairiness may be lowered. On the other hand, if it exceeds 0.6, the hair tends to adhere to each other under high temperature and high humidity (temperature of 27 ° C and humidity of 70% RH) The hair tends to stick, the lightness of the hair decreases, and the smoothness of the hair after drying may deteriorate.

When the mass ratio (B + C) / (A + D) is within the above-mentioned numerical range, the hair does not spread even under high temperature and high humidity (temperature 27 ° C and humidity 70% RH) The hair is hard to stick to each other, the hair is not sticky, and the hair is advantageous in terms of the lightness.

&Lt; Other components >

The other ingredients are not particularly limited as long as they do not impair the effect of the present invention and can be appropriately selected in accordance with the purpose. Examples thereof include oils, alcohols, moisturizers, thickeners, preservatives, A chelating agent, a pH adjusting agent, an ultraviolet absorbing / scattering agent, vitamins, amino acids, a flavoring agent, a coloring matter, water (water), and the like. These may be used alone, or two or more kinds may be used in combination.

Examples of the oil include vegetable fats such as castor oil, olive oil, cacao oil, hardened palm oil, camellia oil, palm oil, wood oil, jojoba oil, grape seed oil and avocado oil or their ester compounds, mink oil, A liquid paraffin, a squalene, a microcrystalline wax, a ceresin wax, a paraffin wax, a petroleum jelly such as petroleum jelly, etc .; an animal fat such as an animal oil such as an egg yolk oil, a beeswax, a waxy lanolin, a hydrogenated lanolin, Natural and synthetic fatty acids such as lauric acid, myristic acid, myristic acid, stearic acid, oleic acid, isostearic acid, and behenic acid, glycerol tri-2-ethylhexane ester, 2-ethylhexyl stearate, butyl stearate, myristic acid Esters such as isopropyl myristate, isopropyl myristate, isopropyl myristate, octyldodecyl myristate, octyldodecyl oleate, cholesterol oleate, dimethyl polysiloxane, etc. There.

Examples of the alcohols include natural and synthetic higher alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, hexyldecanol, octyldodecanol, and lauryl alcohol.

Examples of the moisturizing agent include 1,3-butanediol, isoprene glycol, 1,2-pentanediol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, diethylene glycol monoalkyl ether, polyethylene glycol Polypropylene glycol, polyethylene glycol-polypropylene glycol, hardened castor oil (30E.O.), glycerin, diglycerin, triglycerin, polyglycerin, sorbitol, etc., such as 200, 300, 400, 600, 1,000 or 1,500 .

Examples of the thickening agent include natural polymers such as sodium alginate, xanthan gum, aluminum silicate, quince extract, tragacanth gum and starch; cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, Synthetic polymers such as semisynthetic polymers such as soluble starch, carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, methacryloylethylbetaine methacrylate copolymer, etc. .

Examples of the preservative include benzoic acid salts, sorbic acid salts, dihydro acetic acid salts, paraoxybenzoic acid esters, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, 3,4,4 ' (Trade name: Kayo CG, manufactured by Rohm and Haas Company, Ltd.), salicylic acid, pentanediol, phenoxybenzenesulfonic acid, benzalkonium chloride, hinokitiol, resorcin, methylchloroisothiazolone, methylisothiazolone Ethanol, ethanol, and the like.

Examples of the antioxidant include dibutylhydroxytoluene, butylhydroxyanisole, ascorbic acid, and the like.

Examples of the chelating agent include disodium edetate, ethylenediamine tetraacetate, hexametaphosphate, gluconic acid, and the like.

Examples of the pH adjuster include sodium hydroxide, potassium hydroxide, citric acid, succinic acid, triethanolamine, ammonia water, triisopropanolamine, phosphoric acid and glycolic acid.

Examples of the ultraviolet ray absorbing and scattering agent include 2-hydroxy-4-methoxybenzophenone, octyldimethyl p-aminobenzoate, ethylhexylparamethoxycinnamate, titanium oxide, kaolin, have.

Examples of the vitamins include vitamin A, vitamin B group, vitamin C, vitamin D, vitamin E, vitamin F, vitamin K, vitamin P, vitamin U, carnitine, ferulic acid, Tosylic acid or a derivative thereof, and the like.

Examples of the amino acids include glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophan, cystine, cysteine, methionine, proline, hydroxyproline, aspartic acid, glutamic acid, arginine, histidine, lysine or derivatives thereof .

Examples of the perfume include perfume ingredients described in paragraphs [0021] to [0035] of Japanese Patent Application Laid-Open No. 2003-300811, perfume solvents described in paragraph [0050], and the like.

<pH>

The pH of the shampoo composition is not particularly limited and may be appropriately selected in accordance with the purpose. It is preferably 5.0 to 6.0 at 25 占 폚.

For example, the pH of the shampoo composition can be measured at 25 ° C using a pH meter (HM-30G, manufactured by Dow Chemical).

The pH of the shampoo composition can be adjusted using a desired pH adjusting agent. The pH adjuster is not particularly limited and may be appropriately selected in accordance with the purpose. Examples of the pH adjuster include citric acid, succinic acid, sulfuric acid, 2-amino-2-methyl-1-propanol, monoethanolamine, .

<Viscosity>

The viscosity of the shampoo composition is not particularly limited and may be appropriately selected depending on the purpose. It is preferably 1 Pa · s to 30 Pa · s at 25 ° C.

The viscosity can be measured by using, for example, a viscometer (BM type viscometer, manufactured by TOKIMEC). 4 rotor at 30 rpm for 20 seconds and then at 25 캜.

<Container>

The container of the shampoo composition is not particularly limited and may be appropriately selected in accordance with the purpose. For example, in addition to a tube such as an aluminum laminate tube, an EVAL tube, an aluminum tube, and a glass evaporated plastic tube, A dispenser container and a squeeze container, a laminate film container, a spotter container, a stick container, a bottle container, and the like.

The laminated film usually has a multilayer structure of two or more layers, and the material thereof is selected from the group consisting of a polyethylene resin, a polyethylene terephthalate resin, a polyester resin, a biaxially oriented polypropylene resin, an unleaded polypropylene resin, a polyacrylonitrile resin, Vinyl acetate copolymer, vinyl acetate copolymer, vinyl acetate copolymer, vinyl acetate copolymer, vinyl acetate copolymer, vinyl acetate copolymer, and vinyl acetate copolymer. Of these, in consideration of strength, flexibility and weather resistance, it is generally preferable to use a layer having a thickness of 2 to 5 layers.

The material of the bottle is not particularly limited and may be appropriately selected in accordance with the purpose. Examples of the material include polyethylene resin, A resin such as acrylonitrile-styrene copolymer resin, ABS resin, and polyamide, glass, or the like can be used as a single layer or a combination of two or more layers.

<Applications>

The shampoo composition can be used in a wide range of environments such as high temperature and high humidity (temperature 27 ° C and humidity 70% RH) and low humidity and air conditioning, and it is easy to stylize, And can be suitably used for shampoo for mansard cleansing, shampoo for damage care, mild shampoo, and rinse-in shampoo, for example, because it has smoothness and softness and is excellent in usability. In addition to human hair, it can also be used for hair of animals such as pets.

Example

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail by way of examples of the present invention, but the present invention is not limited at all by these examples. In the following examples and comparative examples, unless otherwise specified, "%" represents "% by mass", and the blending amount of each component represents a pure component.

(Examples 1 to 50 and Comparative Examples 1 to 18)

The components (A), (B), (C), (D), (E) and optional components described in the examples and comparative examples shown in Tables 1 to 12 were added, Lt; / RTI &gt; for 30 minutes. With respect to the gloss-imparting agent (ethylene glycol distearate) as the component (C), a 4.5 mass% gloss-imparting agent dispersion was prepared in advance by the following preparation method, and the gloss-imparting agent in the shampoo composition was added in a predetermined amount. For example, in the case of 1.5% by mass of the gloss-imparting agent as the component (C), 33.3% by mass of the 4.5% by mass gloss-imparting agent dispersion was added. The gloss-imparting agent dispersion contains polyoxyethylene lauryl sulfate and lauryl sulfate as components (A), and the compounding amount described in the examples is described as the sum of the amount added with the amount added in the glossing agent dispersion. After the dispersion of the gloss-providing agent was added, the mixture was thoroughly stirred, and the pH was adjusted to 5.8 with citric acid to obtain a shampoo composition.

(Article 1)

- Preparation of aqueous dispersion of ethylene glycol distearate crystals -

The ethylene glycol distearate crystal water dispersion as the gloss-providing agent which is the component (C) was prepared by the following method.

(Final concentration) of 10% by mass and ammonium lauryl sulfate (Texapon ALS 70, BASF) in polyoxyethylene (3) ammonium lauryl ether sulfate (Texapon ALES 70, BASF) The dissolved aqueous solution was maintained at 80 DEG C and stirred in a 2 L beaker. Ethylene glycol distearate (Tegin EGS, Evonik) dissolved at 80 캜 was slowly added to the aqueous solution so as to have a final concentration of 4.5% by mass while stirring the aqueous solution, and the mixture was stirred at 80 캜 using a Sreenan motor (FBL1200, HEIDEN Ltd.) and 4 pieces of slant paddles were homogeneously mixed at 100 rpm for 30 minutes and dispersed and mixed at 4,500 rpm for 10 minutes using a homomixer (manufactured by FuraiMex Co., Ltd.).

Subsequently, the resulting dispersion mixture was immersed in a water bath and cooled in a dispersion tank at 35 DEG C (cooling rate: 1 DEG C / minute) while stirring at 100 rpm using four sheets of warp paddles, thereby obtaining 4.5 mass% ethylene glycol distearate To prepare a water dispersion of a rate crystal.

In Example 21, 4.5% by mass ethylene glycol distearate crystal water dispersion was prepared in the same manner as above using polyoxyethylene (2) lauryl ether sodium sulfate / sodium lauryl sulfate.

The median particle size of the 4.5 mass% ethylene glycol distearate crystal aqueous dispersion was measured using a laser diffraction particle size analyzer (LA-920, manufactured by Horiba Ltd.) with a relative refractive index to water of 1.08. The median particle diameter was 2.0 탆. The dispersed form of the crystal was a needle bed.

With respect to each of the obtained shampoo compositions, 20 female specialist panelists were used for about 7 days at a dose of about 6 ml / hour. Based on the following evaluation method and criteria, "the lightness of hair after drying at 27 ° C and 70% RH" , "Lightness of hair after drying at 25 ° C and 40% RH", "convenience of styling of hair after drying at 27 ° C and 70% RH", and "hairiness of hair after drying at 25 ° C and 40% RH" , "Smoothness of hair at the time of rinsing", "smoothness of hair after drying", "smoothness of hair after drying", and "usability (ease of coming out of the bottle)" were evaluated. The results are shown in Tables 1 to 12.

<Evaluation method>

6 ml of each shampoo composition was applied to the hair which was insufficiently wet. After thoroughly foaming and shaking, the hair was washed with a shower of tap water temperature of 40 캜 and a flow rate of 250 ml / 3 seconds and towel-dried. % RH for 12 hours, and stabilized for 12 hours in a room at a temperature of 25 DEG C and a humidity of 40% RH was repeated 7 times (the following cycle was repeated seven times).

[Equation 1]

At the time of the 7th cleaning, the "smoothness of the hair at the time of rinsing" was evaluated. After the towel was dried, it was stabilized for 12 hours in a room temperature of 27 ° C. and a humidity of 70% RH, "" Ease of styling of hair after drying at 27 ° C and 70% RH "," smoothness of hair after drying ", and" softness of hair after drying "were evaluated.

Then, after that, the hair was stabilized for 12 hours in a room at a temperature of 25 占 폚 and a humidity of 40% RH, and the hairiness after drying at 25 占 폚 and 40% RH and the hair after drying at 25 占 폚 and 40% RH Convenience of hair styling ".

(1) Viscosity of hair after drying at 27 DEG C and 70% RH

The "lightness of hair after drying at 27 ° C and 70% RH" was evaluated according to the following criteria. We indicated by the number of people who answered good and expressed by the following judgment criterion. Here, &quot; lightness of hair &quot; means that the hair is light, one hair is scattered, and the hair is visible.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(2) Viscosity of hair after drying at 25 ° C, 40% RH

&Quot; Lightness of hair after drying at 25 DEG C and 40% RH &quot; was evaluated according to the following criteria. We indicated by the number of people who answered good and expressed by the following judgment criterion. Here, &quot; lightness of hair &quot; means that the hair is light, one hair is scattered, and the hair is visible.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(3) Convenient styling of hair after drying at 27 ° C and 70% RH

"Convenience of styling of hair after drying at 27 ° C and 70% RH" was evaluated according to the following criteria. We indicated by the number of people who answered good and expressed by the following judgment criterion. Here, &quot; Convenience of styling of hair &quot; indicates that hair is easily passed between hair combs and is easy to be trimmed.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(4) Convenient styling of hair after drying at 25 ° C and 40% RH

Convenience of styling of hair after drying at 25 캜 and 40% RH &quot; was evaluated according to the following criteria. We indicated by the number of people who answered good and expressed by the following judgment criterion. Here, &quot; Convenience of styling of hair &quot; indicates that hair is easily passed between hair combs and is easy to be trimmed.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(5) Smoothness of hair during rinsing

"Smoothness of hair at the time of rinsing" was evaluated according to the following criteria. We indicated by the number of people who answered good and expressed by the following judgment criterion. Here, "smoothness of hair during rinsing" means that the finger slides without resistance when the hair is touched while washing the shampoo.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(6) Smoothness of hair after drying

&Quot; Smoothness of hair after drying &quot; was evaluated according to the following criteria. We indicated by the number of people who answered good and expressed by the following judgment criterion. Here, &quot; smoothness of hair after drying &quot; means that the finger slides without resistance when the hair is touched after drying.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(7) Softness of the hair after drying

&Quot; Softness of hair after drying &quot; was evaluated according to the following criteria. It was indicated by the following evaluation criteria according to the number of people who replied well and answered. Here, &quot; softness of hair after drying &quot; means that the skin is lightly lighter when touching hair after drying.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

(8) Usability

&Quot; Usability &quot; of the shampoo composition was evaluated according to the following criteria. It was indicated by the following evaluation criteria according to the number of people who replied well and answered. Here, &quot; usability &quot; indicates that the shampoo composition from the bottle tends to come out.

[Criteria]

◎: Reply that 16 or more were good

◎ ~ ○: More than 13 and less than 15 responded that it was good

○: Responded that 11 or more and 12 or less were good

[Delta]: More than 6 persons and less than 10 persons answered that it was good

X: The number of respondents was less than 5

[Table 1]

[Table 2]

[Table 3]

[Table 4]

[Table 5]

[Table 6]

[Table 7]

[Table 8]

[Table 9]

[Table 10]

[Table 11]

[Table 12]

Details of the components used in the examples of Tables 1 to 12 and comparative examples are as shown in Table 13 below.

[Table 13]

* 1: Dimethylpolysiloxane B (emulsion) in Table 13 was prepared by the following method.

Highly polymerized methylpolysiloxane having a kinematic viscosity of 10,000,000 mm 2 / s: Highly polymerized methylpolysiloxane having a kinematic viscosity of 4,000,000 mm 2 / s: Methylpolysiloxane having a kinematic viscosity of 1,000 mm 2 / s = 15: 15: 70 (Product name: NPO-97, manufactured by Lion Chemical Co., Ltd.) as an emulsifier was added to the emulsion and dispersed in water.

Examples of the embodiment of the present invention include the following.

&Lt; 1 > A surfactant composition comprising (A) an anionic surfactant having a sulfuric acid residue,

(B) a gallic acid acid glycoside,

(C) a gloss-imparting agent,

(D) a cationic polymer,

(E) 0.15% by mass to 5.0% by mass of a silicone compound,

(B + C) / (A + D) of the component (B) and the component (C) to the component (A) and the component (D) is 0.05 to 0.6,

Wherein the component (A) contains a polyoxyethylene alkyl ether sulfate (A1) and an alkyl sulfate (A2)

Wherein the component (D) comprises a cationic guar gum (D1) and a cationic cellulose (D2), and the mass ratio (D1 / D2) of the component (D1) ,

Characterized in that the component (E) comprises a dimethylpolysiloxane (E1) and an amino-modified silicone (E2) and the mass ratio (E1 / E2) of the component (E1) . &Lt; / RTI &gt;

&Lt; 2 > (A) 10% to 25% by mass of an anionic surfactant having a sulfuric acid residue,

(B) 0.05% by mass to 3% by mass of gallic acid glycosides,

(C) 1.2% by mass to 4.5% by mass of a gloss-imparting agent,

(D) 0.2% by mass to 1.5% by mass of a cationic polymer.

<3> The shampoo according to any one of <1> to <2>, wherein the nitrogen content of the component (D1) is 1 mass% to 1.8 mass% and the nitrogen content of the component (D2) is 1.5 mass% to 2.2 mass% .

<4> The shampoo composition according to any one of <1> to <3>, wherein the mass ratio (A1 / A2) of the component (A1) to the component (A2) is 1 to 7.

[Industrial applicability]

The shampoo composition of the present invention does not spread the hair even in a region where the environment change of high humidity and low humidity and air condition is good and the environment is severe, it is easy to stylize, the hairs do not adhere to each other, the hair is smoothly finished, And can be suitably used for, for example, mansard cleansing shampoo, damage care shampoo, mild shampoo, and rinse-in shampoo.

Claims (4)

(A) an anionic surfactant having a sulfuric acid residue,
(B) a gallic acid acid glycoside,
(C) a gloss-imparting agent,
(D) a cationic polymer,
(E) 0.15% by mass to 5.0% by mass of a silicone compound,
(B + C) / (A + D) of the component (B) and the component (C) to the component (A) and the component (D) is 0.05 to 0.6,
Wherein the component (A) contains a polyoxyethylene alkyl ether sulfate (A1) and an alkyl sulfate (A2)
Wherein the component (D) comprises a cationic guar gum (D1) and a cationic cellulose (D2), and the mass ratio (D1 / D2) of the component (D1) ,
Characterized in that the component (E) comprises a dimethylpolysiloxane (E1) and an amino-modified silicone (E2) and the mass ratio (E1 / E2) of the component (E1) Lt; / RTI &gt; The method according to claim 1,
(A) 10% by mass to 25% by mass of an anionic surfactant having a sulfuric acid residue,
(B) 0.05% by mass to 3% by mass of gallic acid glycosides,
(C) 1.2% by mass to 4.5% by mass of a gloss-imparting agent,
(D) 0.2% by mass to 1.5% by mass of the cationic polymer. 3. The method according to claim 1 or 2,
Wherein the nitrogen content of the component (D1) is from 1% by mass to 1.8% by mass, and the nitrogen content of the component (D2) is from 1.5% by mass to 2.2% by mass. 4. The method according to any one of claims 1 to 3,
Wherein the mass ratio (A1 / A2) of the component (A1) to the component (A2) is 1 to 7.