KR20080096246A - Composition for hair color having an extract of green tea, preparation method thereof and kit for hair colorant - Google Patents

Abstract

A hair-dye kit is provided to prevent scalp trouble in the dyeing, to accelerate generation of hair, to recover rapidly damaged hair and to maintain glossiness for a long time by giving elasticity and a nutrition. A composition for hair-dye includes a 30 - 50 weight% of green tea extract. Additionally, the composition for hair-dye includes a 10 - 20 weight% of herb medicine extract selected from a group consisting of ginseng extract, mori Radicis Cortex extracts, polygoni multiflori Radix extracts, Sophora flavescenes extract, glycyrrhiza extract and a mixture thereof. The dye is selected from para-phenylene diamine, O-phenylenediamine, resorcin, 2- methyl resorcinol, M-phenylenediamine, M-aminophenol, O-aminophenol, P-aminophenol, toluene diamines, aminonitrophenol, diphenylamines, N- phenyl diamines, diaminopyridine class and a salt thereof. The base is beep propylene glycol, cetearyl alcohol, polyoxyethyleneoleylether, polyoxyethylene cetyl ether, stearamide membrane electrode assembly, oleic acid, oleyl alcohol, dimethicone, ascorbate sodium, myristoyl glutamate sodium, behenyl alcohol, poly quaternium-10 or glycerylstearate phosphorus.

Description

Composition for hair dye comprising green tea extract, preparation method thereof and kit for hair dye {COMPOSITION FOR HAIR COLOR HAVING AN EXTRACT OF GREEN TEA, PREPARATION METHOD THEREOF AND KIT FOR HAIR COLORANT}

[Industrial use]

The present invention relates to a hair dye composition comprising a green tea extract, a method for preparing the same, and a kit for hair dye, and more particularly, there is no scalp or eye mucosal irritation during dyeing, and promotes hair production as well as quickly recovers damaged hair. In addition, the present invention relates to a hair dye composition comprising a green tea extract that can give elasticity and nutrition for a long lasting shine, a preparation method thereof, and a kit for hair dye.

[Prior art]

Hair dyes typically have a first component that swells the hair to facilitate diffusion and penetration of the dye into the hair, and a second hair to aid in the generation of the oxygen needed to oxidize the dye to achieve desired hair dye. The agent is mixed and used at a fixed ratio.

Hair dyeing using these hair dyes changes the properties and structure of the hair using melanin pigments, which contain chemical components, and hydrogen peroxide, which are present between the cortical keratin fibers in the hair.

The use of hair dyes is easy to cause allergy to the skin, and not only damages the hair, but also dyes are formed by oxidation polymerization inside the hair, resulting in loss of gloss and gloss and severe damage to the hair. There are drawbacks such as poor texture. In addition, color-generating dyes can cause severe irritation to the mucous membranes and eyes, causing hypersensitivity and rashes from dermatitis.

As the number of consumers who dye their hair has recently increased and the age of starting hair dye for the first time has decreased, the incidence of dermatitis and facial edema is increasing. However, due to the use of hair dyes, mild allergies such as itching and discomfort in the scalp area, or some severe symptoms suddenly appear in hospital, and cases of allergic symptoms are increasing.

In order to solve this problem, hair dyes of various compositions have been developed and researched.

Korean Patent Laid-Open Publication No. 2000-61526 proposes a dyeing agent containing ocher, and is used for dyeing hair by processing ocher soil which is harmless to humans and non-toxic to take advantage of the mineral-rich ocher property.

Korean Patent Publication No. 2002-46100 proposes a permanent hair dye that does not cause skin allergic reactions, and the dye is selected from direct dyes (tar pigments), nitro dyes, and natural dyes for hair dyes without causing skin allergic reactions. It refers to a composition that is easy to penetrate dyes and has excellent dyeing duration.

Korean Patent No. 10-0453679 discloses a hair dye composition containing henna, indigo, centaurea, rhubarb powder, Leichen or litmus. The patent mentions the use of natural dyes and natural materials instead of chemical dyes to protect hair from the violent action of alkali and oxidants, helping to color, condition and hair.

In addition, Korean Laid-Open Patent No. 2005-26759 also relates to a natural vegetable hair dye, by mixing a henna leaf powder and indigo leaf powder with natural plants in an appropriate ratio can be dyed hair by changing the dyeing color according to the mixing ratio It is mentioned.

In addition to hair dyes using natural dyes, research has recently been conducted on hair dyes containing organic ingredients or herbal ingredients.

Korean Laid-Open Patent Publication No. 2005-115530 discloses red ginseng extract 0.01-5.00 wt%, sugar extract 0.01-5.00 wt%, Cheongung extract 0.01-5.00 wt%, licorice extract 0.01-5.00 wt%, dye 0.001-5.00 wt%, base 17.00 It contains-30.00% by weight to propose a hair dye composition excellent in dyeing, dyeing fastness, hair conditioning, hair protection effect.

In addition, Korean Patent No. 10-0625180 discloses the extract of the upper leaf, the extract of the leaf fermentation, the extract of the lettuce extract, the fermentation extract of the fermentation extract, the fermentation extract of licorice, the extract of Sasam fermentation, the extract of the Seomoktae fermentation, the extract of the fermented soybean, the sulfur, the dye, the base and the purified water. The present invention relates to a hair dye composition comprising the same, and a method for preparing the same, wherein the composition has no irritation to the scalp, relieves itching, quickly recovers damaged hair, gives elasticity and nutrition, and lasts a long period of shine.

Korean Registered Patent No. 10-0569788 and Korean Patent Publication No. 2006-66150 manufacture a composition for hair dye comprising a core, upper leaf or lettuce leaf, and the composition eliminates side effects such as skin irritation by a conventional chemical dye. It says it can.

However, none of these patents mentions green tea extracts at all.

In order to solve the above problems, the present inventors have developed a hair dye composition using green tea as a natural material that is not harmful to the human body, and by using various herbal extracts in addition to the green tea extract, it prevents scalp problems during dyeing and prevents hair generation. It not only promotes fast recovery of damaged hair, but also gives elasticity and nourishment for long lasting shine.

An object of the present invention is to provide a hair dye composition and a method for producing the same without scalp or eye mucosal irritation.

Another object of the present invention is to provide a kit for hair dyes comprising the composition for hair dyes.

In order to achieve the above object, the present invention

In the hair dye composition comprising a dye, a base and purified water,

The hair dye composition provides a hair dye composition containing 30 to 50% by weight of green tea extract.

In this case, the hair dye composition includes 0.001 to 5.0 wt% of the dye, 10 to 50 wt% of the base, and the balance of purified water.

In addition, the hair dye composition includes a herbal extract, and in particular, one or more herbal extracts selected from the group consisting of ginseng extract, lettuce extract, sewage extract, ginseng extract, licorice extract, and mixtures thereof is contained in the total composition of 10 to 20 It is included by weight.

At this time, the green tea extract and herbal extract

a) extracting the primary extraction solution using water, a lower alcohol or a mixed solvent of 5 to 30 times by weight ratio of each component,

b) concentrating the primary extraction solution after filtration,

c) extracting a secondary extraction solution using water, alkylene glycol, or a mixed solvent of 5 to 30 times the weight ratio of the obtained concentrated solution,

d) The secondary extraction solution is obtained by filtration and concentration.

In addition, the present invention

Purified water, base and dye are mixed at 80 to 85 캜,

Provided herein is a method for preparing a hair dye composition prepared by adding green tea extract.

The present invention also provides a kit for a hair dye comprising a first agent comprising the composition for the hair dye, and a second agent containing an oxidizing agent.

Hereinafter, the present invention will be described in more detail.

The hair dye composition according to the present invention contains green tea extracts to prevent scalp problems during dyeing, promotes hair production, quickly restores damaged hair, gives elasticity and nutrition, and lasts a long time of shine.

Thea sinensis ) contains caffeine, purine base, tannic acid, protein, amino acid, amide, and the like, and carbohydrates include sugar, dextrin, starch, cellulose, and pectin, and as plant pigments, chlorophyll, carotenoids, flavonoid derivatives, anthocyanins In addition, it is composed of essential oils, lead, resins, organic acids, enzymes, vitamins, and inorganic components.

When the green tea is used in hair dyes, tannins that tighten pores and flavonoids have strong cleansing properties, resulting in less dandruff, acting as a bactericidal and shampoo and rinse to prevent scalp health. In addition, green tea has excellent skin soothing and regenerating effects, and the green tea's vitamin D ingredient makes the hair shiny and soft and suppresses dandruff on the scalp.

In addition, testosterone encounters a 5-alpha reducing element and is converted to dihydrotestosterone (DHT), which causes DHT to affect the hair root, causing hair loss, and green tea prevents the production of the DHT, thereby preventing hair loss.

Green tea having such an effect is used in the present invention for the hair dye composition in the form of green tea extract.

The hair dye composition according to the present invention typically comprises a dye, a base, and purified water, wherein the green tea extract is mixed and used to be 30 to 50% by weight, preferably 35 to 40% by weight of the total composition.

The green tea extract may be any known extraction method is not particularly limited in the present invention.

As an example the green tea extract is

a) extracting the primary extraction solution using water, a lower alcohol or a mixed solvent of 5 to 30 times by weight ratio of each component,

b) concentrating the primary extraction solution after filtration,

c) extracting a secondary extraction solution using water, alkylene glycol, or a mixed solvent of 5 to 30 times the weight ratio of the obtained concentrated solution,

d) The secondary extraction solution is obtained by filtration and concentration.

Specifically, in step a), after washing in order to remove the foreign substances present on the surface, cut, dried in the shade or dried in a dryer, crushed or used to prepare dried green tea, and then added to the extraction solvent and hot water extraction or ultrasonic The extraction method is first extracted to obtain a primary extraction solution.

At this time, the dried green tea is mixed with 5 to 30 times, preferably 10 to 15 times (weight ratio) water, lower alcohol or a mixed solvent thereof with respect to the weight of the dried green tea.

The lower alcohol may be one selected from the group consisting of ethanol, propanol, butanol and mixtures thereof, and preferably water / ethanol is used in a weight ratio of 1:10 to 10: 1.

The resulting mixture is then hydrothermally extracted for 1 to 48 hours, preferably 10 to 20 hours, at an extraction temperature of 40 to 120 ° C., preferably 60 to 90 ° C. Or the mixture is applied at 500 to 1500 W by applying ultrasound for about 5 to 20 minutes.

In step b), the supernatant obtained by the primary extraction is filtered or centrifuged to separate the supernatant, preferably filtered, and then concentrated or dried until the volume is 1/10 to 1/3. The primary extract in liquid or dry state is obtained.

In step c), the primary extract obtained from the extraction step is filtered, and water or alkylene glycol, or these mixed solvents are added again, and the preparation is repeated under the same conditions as above to obtain a secondary extract solution.

In this case, the alkylene glycol may be one selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, and mixtures thereof. Preferably, water / butylene glycol is used in a weight ratio of 1:10 to 10: 1. do.

In step d), the secondary extract obtained by the secondary extraction is filtered or centrifuged to separate the supernatant to obtain a green tea extract as a secondary extract.

Green tea extract obtained through this step is mixed to 30 to 50% by weight, preferably 35 to 40% by weight of the total composition to prevent scalp problems during dyeing, promotes hair production, and also quickly recovers damaged hair In addition to providing elasticity and nutrition, it lasts a long time for shine. If the content of the green tea extract is less than or above the range, it is difficult to obtain the effects described above.

In this case, the hair dye composition includes 0.001 to 5.0% by weight of the dye, 10 to 50% by weight of the base, and the remainder of the purified water, and the dye and the base may be any composition known in the art.

The dye used in the present invention may be an oxidizing dye commonly used, and is not particularly limited in its kind. For example, p-phenylenediamine, o-phenylenediamine, resorcin, 2-methyl Resorcinol, m-phenylenediamine, m-aminophenol, o-aminophenol, p-aminophenol, toluenediamine, aminonitrophenols, diphenylamines, N-phenyldiamines, diaminopyridines and the like 1 type, or 2 or more types are mixed and used in salt. At this time, the content of the dye is used within the conventional range, for example, 0.001 to 5.0% by weight in the total hair dye composition.

The base is propylene glycol, cetearyl alcohol, polyoxyethylene oleyl ether, polyoxyethylene cetyl ether, stearamide M, oleic acid, oleyl alcohol, dimethicone, ascorbate sodium, myristoyl It may be one or a mixture of two or more selected from glutamate sodium, behenyl alcohol, cocoyl isionionate sodium, cocamidophorophyll betamin, polyquaternium-10, glyceryl stearate. At this time, the content of the base is used in 10 to 50% by weight, preferably 10 to 30% by weight in the total hair dye composition.

In addition, the present invention uses various herbal extracts in addition to the green tea extract in the hair dye composition.

The herbal extract may be one selected from the group consisting of ginseng extract, lettuce extract, sewage extract, ginseng extract, licorice extract and mixtures thereof, 10 to 20% by weight, preferably 10 to 15% by weight in the total composition Use to be%.

More detailed description of these herbal extracts is as follows.

Panax ginseng ginseng CA Meyer) is a perennial herb of hawthorn arboraceae and has been known as a medicinal herb for many years. The ginseng is used as a medicine in tonic, strong heart, healthy, correction, soothing, nourishment, etc. in oriental medicine, it is used as an activator to reduce metabolism function due to weakness of the stomach, etc., stomach identity of the sick, indigestion, vomiting, chest pain It is also applied to laxative diarrhea and loss of appetite. The effect of ginseng in the external application of skin has a direct effect on the scalp, which is effective in treating and preventing skin wounds and troubles with its excellent anti-inflammatory and detoxification effect. In particular, saponins contained in abundant ginseng promote collagen synthesis in the skin, not only to prevent skin aging delay, but also to soothe the scalp and have an excellent antioxidant effect.

Morus , Morus alba root ) is a root bark belonging to the Mulberry family, which contains hypoglycemic substances and substances such as mulberryfuran and phenylflavonoid, and tannin, spororetin, and insect hormones. It contains a kind of exosterone, incosterone and the like. It contains these ingredients to activate the hair cells to promote hair production, thereby improving the scalp.

Shao (何首烏, Pleuropterus multiflours TURCZ has many names, such as wild horse, designation, bridge, Jinjibaek, sanong, and mountain peak. Perennial is herbaceous. These sewage contains red sewage and white sewage, and contains lecithin, anthratinone derivatives (lane, chrysophanor, pischion, etc.), fat, starch, styrebene, glycosides, etc. It is widely used. As it contains these ingredients, sewage has the effect of delaying or preventing skin aging with excellent antioxidant effects, strengthening skin blood circulation to maintain healthy skin, and promoting blood circulation of the scalp to help prevent hair loss and hair growth. .

S ophora angustifolia Sieb . et Zucc.) is a perennial herb that is about 1 m high and has alkaloids throughout the plant. Specifically, the ginseng contains alkaloids and sugars such as matrin (sofocarpidine), oxymatrine, sophoranol, anagiline, methylcytizin, barbtipurin, sopocarpine, allomatrine, and nourish hair roots. It serves to strengthen the hair roots. In addition, it has anti-inflammatory and antibacterial effects, which inhibit inflammation proliferation and damage to skin tissues, as well as suppress skin itching and hypersensitivity reactions.

Licorice (甘草), Glycyrrhiza uralensis ) is a sun-dried root of perennial herb, belonging to the legume, and is widely used as a herbal medicine or folk medicine. The licorice includes various components such as glycyrrhizin, triterpenoids, glycon, polyphenols, glabridin, and polysaccharides. By containing these components, licorice has anti-inflammatory action by promoting anti-allergic action, NK cell activation and interferon release, as well as soothing the scalp during staining.

Ginseng, lettuce, red ginseng, and licorice as described above are used in the composition for hair dyes in the form of extracts, wherein the extraction method is the same as the method for obtaining the green tea extract.

The hair dye composition according to the present invention having such a composition may be added, if necessary, components that can be blended in general external preparations for hair. For example, hair protecting agents, chelating agents, surfactants, pH adjusting agents, alkalis, humectants, thickeners, preservatives, antioxidants, fungicides, anti-inflammatory agents, antimicrobial agents, solvents, flavoring agents, pigments and the like are possible. Such additives are suitably used by those skilled in the art within a conventional range.

Hair protectors help fix dyes on the surface of the hair, form a water-repellent thin film on the hair to slow the discoloration of the dye due to water washing and sunlight to give excellent conditioning effect on the surface of the hair to prevent hair damage as well as emulsion Also helps stabilize. Hair protectants that can be used include sodium methylstearoyl taurate, hydrolyzed keratin, tocopheryl acetate, cetrimonium chloride, glyceryl stearate, Fiji-11 methyl ether dimethicone, cyclomethicone, ammonium glycylizate It may be one or a mixture of two or more selected from glyceryl linoleate, linoleic acid, ceramide, mineral oil, polyquaternium-10, camellia oil and the like.

Chelating agents include disodium ethane (EDTA), tetrasodium ethane, etc. and act as metal blockers.

Specifically, the pH adjusting agent may be any of organic acids such as citric acid, succinic acid, tartaric acid, lactic acid, malic acid, fumaric acid, maleic acid, glycolic acid, and inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid, sodium salts of these acids, Potassium salt or ammonium salt can be used in combination, and sodium hydroxide and potassium hydroxide can also be used.

Alkaline agents use monoethanolamine or strong ammonia water to swell the hair and facilitate the penetration of dye molecules into the hair.

Dissolution aids may specifically be isopropyl myristate, polyethylene glycol, medium chain fatty acid triglycerides, hydrocarbons, glycols, and the like.

Among the surfactants, anionic surfactants are specifically ammonium lauryl sulfosuccinate, ammonium lauryl sulfate, sodium cocoyl isionate, sodium lauryl isceionate, sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium Lauryl ether sulfate (1-3 ethylene oxide) and the like.

Moisturizing agent may be specifically glycerin, propylene glycol, 1,3-butylene glycol, dipropylene glycol, sorbitol and the like.

The thickener is specifically methylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, carrageenan, carboxymethylcellulose, carboxymethylhydroxyguanine, cetearyl alcohol, stearic acid, polyquaternium-7, polyquaternium-10, and the like. It can be a high molecular compound, the amount used may be used in various ways.

Preservatives may specifically be benzoic acid, paraoxybenzoic acid esters, mixtures of methylchloroisochi azolinone, phenoxyethanol, DMDM hydantoin and the like.

Antioxidants may specifically be ammonium thioglycolate, dibutylhydroxytoluene, ascorbic acid, or the like.

Fungicides may specifically be chlorhexidine gluconate, quaternary ammonium salts, pyroxtonolamines, zinc pyrithione suspensions, iodopropynyl butylcarbamate, salicylic acid and the like.

Anti-inflammatory agents may specifically be monoammonium glycyrrhinate, dipotassium glycyrizine, stearylglycirizinate, chamomile, alpha bisabolol, allantoin and mixtures thereof and the like.

Antimicrobial agents are specifically phenoxyethanol, chlorhexidine, chlorhexidine gluconate, pyroxtonolamine, ketoconazole, arnica extract, iodopropynylbutylcarbamate, benzalkonium chloride, benzenetonium chloride, benzoic acid and salts thereof, benzyl alcohol, lavender, rosemary , Salicylic acid, triclocarban, zinc pyrithione suspensions and mixtures thereof and the like.

The solvent may be specifically ethanol, purified water, Tween 20, cyclomethicone, mineral oil, dimethicone, and the like.

Flavoring agents and pigments may use ingredients used in general scalp and hair preparations.

The hair dye composition according to the present invention is not particularly limited in its preparation method in the present invention, it is carried out by a known method.

In one embodiment, purified water, base and dye are mixed at 80 to 85 ℃,

Green tea extract is added thereto to prepare a hair dye composition.

At this time, ginseng extract, lettuce extract, sewage extract, ginseng extract, licorice extract and mixtures thereof are further added to the green tea extract.

The present invention also provides a kit for a hair dye comprising a first agent comprising the composition for the hair dye and a second agent containing an oxidizing agent.

When the hair dye composition of the present invention is an oxidation hair dye, the oxidation hair dye may be a two-part type comprising a first agent containing an oxidizing dye and a second agent containing an oxidizing agent. Such a two-part hair dye composition is used by mixing a first agent and a second agent immediately before use.

As the oxidant which is the second agent, hydrogen peroxide, urea peroxide and the like are usually used. The second agent may be formulated with known compounding agents such as stabilizers such as EDTA, phenacetin, sodium stannate, oily components such as liquid paraffin, vegetable oil, pH adjusters, and flavorings, for example.

Formulation of such a hair dye composition is preferably a cream type, liquid type, powder type, jelly type, aerosol type.

The amount of the hair dye composition may be appropriately adjusted according to the condition of the hair, the age of the user, the length of the hair, and the like, and the application time may also be appropriately adjusted according to the individual.

Looking at the actual use of the hair dye composition according to the present invention, the hair dye (first agent) according to the present invention and hydrogen peroxide-containing oxidizing agent (second agent) is mixed 1: 1 and applied to the hair, after application Approximately 50 to 200 ml of the contents once, left for about 5 to 60 minutes, then rinsed well with water and triturated again with shampoo or rinse.

Hereinafter, preferred examples are provided to aid in understanding the present invention. However, the following examples are merely provided to more easily understand the present invention, and the contents of the present invention are not limited by the examples.

Production Example  1: Preparation of Green Tea Extract

100 g of green tea dried leaves were washed with water, and then mixed with 1 kg of purified water / ethanol mixed solvent (1: 1, weight ratio) and extracted at 60 ° C. for 24 hours in an extractor equipped with a cooling condenser to obtain an extraction solution (900 g). The extraction solution was concentrated under reduced pressure until the volume became 300 g.

700 g of purified water / butylene glycol mixed solvent (7: 3, weight ratio) was added to the obtained extract, and the mixture was left to stand for 3 days, after which the supernatant was filtered to obtain 900 g of green tea extract.

Production Example  2: Preparation of Green Tea Extract

100 g of green tea dried leaves were washed with water, and then mixed with 1 kg of purified water / ethanol mixed solvent (1: 1, weight ratio), and placed in an ultrasonic extraction apparatus for 10 minutes at 1000 W to obtain an extraction solution (900 g). The extraction solution was concentrated under reduced pressure until the volume became 300 g.

700 g of purified water / butylene glycol mixed solvent (7: 3, weight ratio) was added to the obtained extract, and the mixture was left to stand for 3 days, after which the supernatant was filtered to obtain 900 g of green tea extract.

Production Example  3: herbal extract manufacture

Ginseng extract, lettuce extract, sesame extract, ginseng extract and licorice extract were obtained using ginseng, lettuce, red ginseng, and licorice instead of green tea dried leaves.

Example  1-6

A: First agent ( For hair dye  Composition)

Using the green tea extract and the herbal extracts prepared in Preparation Example 1 and Preparation Example 3, a composition for hair dye was prepared with the composition shown in Tables 1 and 2 below.

First, the purified water 18, the metal ion blocker (7), the preservative (8), the antioxidant (9), and the base (10 to 14) were heated to 85 ° C. and mixed with a mixer.

To this, the main components (1) to (6) were added and stirred at 85 ° C. Then, a thickener (15) and an alkali agent (16) were added and mixed uniformly, and green tea extract (17) was added thereto. In Example 3-6, a herbal extract (18-22) was added to the green tea extract (17) to prepare a hair dye composition.

B: Preparation of Second Agent (Oxidant)

An oxidant having a composition of Table 3 was prepared by the following method.

Purified water and a composition of (2) and (4) to (11) were added to the reactor, and the mixture was heated and stirred at 80 ° C.

The resulting mixture was adjusted to 55 ° C., added with phosphoric acid (3), mixed with hydrogen peroxide (1) at 40 ° C., and finally mixed with glycine (12) at 35 ° C. to prepare an oxidant.

Comparative example  One

 Except not using the green tea extract, was carried out in the same manner as in Example 1 to prepare a hair dye composition.

Experimental Example  One: For hair dye  Skin irritation test of composition (the first agent)

The hair dye composition prepared in Examples 1 and 4 was commissioned by the Korea Testing and Research Institute, a national accredited testing institution, and subjected to a skin irritation test using the test method of Notification No. 2005-60 of the Korea Food and Drug Administration, and the results are shown in the following table. 4 is shown.

Referring to Table 4, the hair dye composition obtained according to the present invention was confirmed to be a non-irritating substance on the skin.

Experimental Example  2: For hair dye  Of composition (first agent) Eye mucosa  Irritation test

The hair dye composition prepared in Examples 1 and 4 was commissioned by the Korea Testing and Research Institute, a national accredited testing institution, and subjected to a skin irritation test using the test method of Notification No. 2005-60 of the Korea Food and Drug Administration. 5 is shown.

Referring to Table 5, the composition for the hair dye obtained according to the present invention was confirmed that there is no eye mucosal irritation during hair dyeing.

Experimental Example  3: For hair dye  Heavy metal of the composition (the first agent) Elution  exam

As a result of performing heavy metal dissolution test using the test method of ICP analysis, the raw material composition for hair dyes prepared in Examples 1 and 4 was commissioned by the Korea Testing and Research Institute, a national accredited testing institute, as shown in Table 6 below. It wasn't.

Experimental Example  4: dyeing characteristic test

Hair dyeing properties of the hair dye compositions prepared in Examples and Comparative Examples were examined.

After mixing the first agent and the second agent of the composition of Examples 1 to 6 and Comparative Example 1 in the same ratio, evenly applied to the black hair and white hair of 8 cm in length, 0.7 g in weight and after 20 minutes, the shampoo treatment Then washed 5 times with lukewarm water, wiped off the moisture and dried with a hair dryer. The results obtained by measuring the dyeing to hair and the color fastness after drying are shown in Table 7 below.

The color difference (ΔE) between the dyed hair and the untreated hair was measured using a spectrophotometer (model name Minolta CM-3700d, JAPAN), and the larger the color difference, the better the dyeing property of the hair colorant.

The fastness of the dye was soaked in the acid solution similar to the sweat component of the dyeing hair after a certain time and observed the degree of discoloration.

Experimental Example  5: skin irritation characteristics

Evaluation of allergy incidence and hair damage prevention effect of the hair dye composition prepared in Examples 1, 4 and Comparative Example 1 was evaluated.

50 males of 25 to 40 years and 50 females of 25 to 40 years of age were selected and dyed by 20 (10 males and 10 females), respectively, and dyed with the compositions of Examples and Comparative Examples. The occurrence of damage was investigated and the results obtained are shown in Table 8 below.

Referring to Table 8, it can be seen that allergy or hair damage hardly occurs even when staining is performed with the composition for hair dyes containing various green tea extracts and herbal extracts according to the present invention. In comparison, it can be seen that hair damage occurs when the composition of Comparative Example 1 containing no green tea or herbal extract is used.

As described above, a hair dye composition and kit containing the green tea extract and the herbal extract were prepared according to the present invention. The hair dye kit prevents scalp problems during dyeing, promotes hair production, quickly restores damaged hair, gives elasticity and nutrition, and lasts a long period of shine.

Claims (12)

In the hair dye composition comprising a dye, a base and purified water, The hair dye composition comprising the hair extract 30 to 50% by weight of the hair dye composition. The method of claim 1, The hair dye composition is a hair dye composition comprising 0.001 to 5.0% by weight of the dye, 10 to 50% by weight of the base and the remainder of the purified water. The method of claim 1, In addition, the hair dye composition is a hair dye comprising 10 to 20% by weight in the total composition of one herbal extract selected from the group consisting of ginseng extract, lettuce extract, sewage extract, ginseng extract, licorice extract and mixtures thereof Composition. The method according to any one of claims 1 to 3, The green tea extract and herbal extract a) extracting the primary extraction solution using water, a lower alcohol or a mixed solvent of 5 to 30 times by weight ratio of each component, b) concentrating the primary extraction solution after filtration, c) extracting a secondary extraction solution using water, alkylene glycol, or a mixed solvent of 5 to 30 times the weight ratio of the obtained concentrated solution, d) A composition for hair dye obtained by concentrating the secondary extraction solution after filtration. The method of claim 4, wherein The first extraction solution is hydrothermal extraction for 1 to 48 hours at 40 to 120 ℃, or 500 to 1500 W to extract for 5 minutes to 20 minutes by applying an ultrasonic wave (microwave) for the composition for hair dyes. The method of claim 1, The dye is p-phenylenediamine, o-phenylenediamine, resorcinol, 2-methylresorcinol, m-phenylenediamine, m-aminophenol, o-aminophenol, p-aminophenol, toluenediamine The composition for hair dyes which is 1 type (s) or 2 or more types selected from the group (s), aminonitrophenols, diphenylamines, N-phenyldiamines, diaminopyridines, and its salts. The method of claim 1, The base may be propylene glycol, cetearyl alcohol, polyoxyethylene oleyl ether, polyoxyethylene cetyl ether, stearamide M, oleic acid, oleyl alcohol, dimethicone, ascorbate sodium, myristo One glutamate sodium, behenyl alcohol, cocoyl isiononate sodium, cocamidophorofil betamin, polyquaternium-10, glyceryl stearate composition for hair dye. The method of claim 1, The hair dye composition further comprises a hair protector, a chelating agent, a surfactant, a pH adjusting agent, an alkali, a moisturizing agent, a thickener, a preservative, an antioxidant, a bactericide, an anti-inflammatory agent, an antimicrobial agent, a solvent, a flavoring agent, and a pigment. A composition for hair dyes containing at least one selected component. The method of claim 1, The hair dye composition is a cream type, liquid type, powder type, jelly type, or aerosol type that is prepared for the hair dye composition. Purified water, base and dye are mixed at 80 to 85 캜, The method for producing a composition for hair dye according to claim 1, wherein the green tea extract is added thereto. The method of claim 10, In addition, ginseng extract, lettuce extract, sewage extract, ginseng extract, licorice extract, and a method of producing a composition for hair dyes to add one herbal extract selected from the group consisting of these. The kit for hair dyes containing the 1st agent containing the composition for hair dyes in any one of Claims 1-9, and the 2nd agent containing an oxidizing agent.