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KR20050012875A - A water reclamation and reuse system with an equipment for removing TDS - Google Patents

A water reclamation and reuse system with an equipment for removing TDS

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Publication number
KR20050012875A
KR20050012875A KR1020050003087A KR20050003087A KR20050012875A KR 20050012875 A KR20050012875 A KR 20050012875A KR 1020050003087 A KR1020050003087 A KR 1020050003087A KR 20050003087 A KR20050003087 A KR 20050003087A KR 20050012875 A KR20050012875 A KR 20050012875A
Authority
KR
South Korea
Prior art keywords
water
treated
flow rate
organic matter
biofilter
Prior art date
Application number
KR1020050003087A
Other languages
Korean (ko)
Inventor
김영규
이제근
김경희
Original Assignee
아쿠아셀 주식회사
김영규
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Application filed by 아쿠아셀 주식회사, 김영규 filed Critical 아쿠아셀 주식회사
Priority to KR1020050003087A priority Critical patent/KR20050012875A/en
Publication of KR20050012875A publication Critical patent/KR20050012875A/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025Reverse osmosis; Hyperfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/422Electrodialysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/002Grey water, e.g. from clothes washers, showers or dishwashers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/11Turbidity
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/02Odour removal or prevention of malodour

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Molecular Biology (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nanotechnology (AREA)
  • Urology & Nephrology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

PURPOSE: To provide a wastewater reusing system in which an equipment for removing TDS(total dissolved solid) is installed to maximize a utilization range of the treated wastewater for reusing by utilizing treated wastewater for reusing as water for boilers or sprinklers having a relatively long retention time in pipes. CONSTITUTION: The wastewater reusing system with an equipment for removing TDS(total dissolved solid) comprises a storage tank(10) for collecting and storing supply raw water; a biofilter(20) in which a media(21) for adhesion and inhabitation of microorganisms is filled to simultaneously remove nitrogen, phosphorus, organic matter of low concentration, some turbidity constituents and suspended solid from the supply raw water flown in from the storage tank; a flow equalization tank(30) for constantly maintaining a flow amount of the treated water even when treated water passing through the biofilter is excessively produced and controlling a load variation of contaminants to smoothly treat water afterward; an activated carbon adsorber(40) for adsorbing and removing recalcitrant dissolved organic matter, residual chlorine, color, smell and a trace of harmful inorganic matter remained in treated water of which flow amount and quality are homogenized by the flow equalization tank; a microfilter(50) for removing fine suspended solid, polymeric substance and colloidal substance from the treated water passing through the activated carbon adsorber; an electrodialysis equipment(60) for concentrating and removing ionic TDS from the treated water passing through the microfilter by selective permeation; a chlorination equipment(70) for preventing the propagation of microorganisms and disinfecting the microorganisms by injecting chlorine into the treated water passing through the electrodialysis equipment; and a treated wastewater detention basin(80) for detaining the treated wastewater for reusing.

Description

용존고형물제거장치가 조합된 중수도시스템 { A water reclamation and reuse system with an equipment for removing TDS }A water reclamation and reuse system with an equipment for removing TDS}

본 발명은 저농도의 유기물 및 난분해성 용존물을 함유한 오폐수 또는 하수처리 방류수(이하, 공급원수)를 처리하여 중수(中水)로 재활용하기 위한 중수도시스템에 관한 것으로, 더욱 상세하게는 전기투석장치 또는 역삼투여과장치를 선택적으로 구비하여 공급원수 내의 용존고형물(TDS)의 제거가 함께 이루어지도록 함으로써, 처리된 중수를 청소용수, 화장실용수 등과 같은 통상적인 중수의 활용 용도외에 배관내 체류시간이 긴 보일러용수나 살수용수 등으로 활용하는 것도 가능하도록 하여 중수의 활용범위를 극대화하고 궁극적으로 수자원의 안정적 확보에 기여케 하는 용존고형물제거장치가 조합된 중수도시스템에 관한 것이다.The present invention relates to a sewage water system for treating wastewater or sewage treatment effluent (hereinafter, referred to as source water) containing low concentrations of organic matter and hardly degradable dissolved water and recycling it into heavy water, and more specifically, an electrodialysis apparatus. Alternatively, a reverse osmosis filtration device is provided to selectively remove dissolved solids (TDS) in the feed water, so that the treated heavy water has a long residence time in the pipe in addition to the usual use of heavy water such as cleaning water and toilet water. The present invention relates to a heavy water system in which dissolved solids removal devices are combined to maximize the scope of heavy water use and ultimately contribute to the securement of water resources.

일반적으로 중수도시스템은 오폐수나 빗물 등을 처리하여 상수(上水)와 하수(下水)의 중간에 위치한다는 뜻에서 비롯된 중수(中水)로 만드는 시스템을 말하는 것으로, 상기한 중수는 주로 높은 청정도를 필요로 하지 않는 화장실용수, 청소용수, 세차용수, 조경용수, 소방용수 등으로 활용됨으로써 전체 수돗물 사용량의 상당부분을 대체하게 되므로 결과적으로 수자원의 안정적 확보에 기여하게 될 뿐 아니라 하수 발생량도 감소되어 환경보호에도 기여할 수 있게 된다.In general, the water system refers to a system that makes heavy water originating from the meaning of being disposed between water and sewage by treating waste water or rainwater. As it is used as toilet water, cleaning water, car wash water, landscaping water, firefighting water, etc. that are not needed, it replaces a large part of the total tap water consumption. It can also contribute to protection.

특히, 현대 사회는 생활패턴의 변화, 급속한 산업화와 도시화로 인해 물 사용량이 급격히 증가되고 있어 수자원의 고갈에 따른 용수부족 사태가 갈수록 심화되고 있으며, 아울러 수질오염에 대한 국민의식 향상에 부응코자 정부의 배출허용기준 역시 단계적으로 강화되고 있어, 상수 및 정수 처리비용도 크게 증가되고 있는 추세여서, 최근 정부에서는 비교적 오염물질 농도가 낮은 오폐수 및 하수처리 방류수를 재사용하기 위한 중수도시스템의 보급을 권장코자 세제지원 등의 혜택을 제공하고 있는 실정이며, 이에 따라, 종래 다양한 구성과 기능을 갖는 중수도시스템들이 안출되어 실시되고 있다,In particular, in the modern society, water consumption is rapidly increasing due to changes in living patterns, rapid industrialization and urbanization, and the shortage of water due to the depletion of water resources is intensifying. In addition, the government is trying to meet the public's awareness of water pollution. Emission allowance standards have also been strengthened gradually, and the cost of water and water treatment has also increased significantly. Recently, the government recommended the dissemination of a sewage water system to reuse wastewater and sewage treatment effluent with low concentrations of pollutants. It is a situation that provides the benefits, such as, according to the prior art, the dewatering water systems having various configurations and functions are devised and implemented,

그러나, 종래의 중수도시스템에는 용존고형물(TDS)의 제거를 주목적으로 한 별도의 장치가 구비되지 않으므로, 이에 의해 처리된 중수는 배관내 스케일 발생의 주요인이 되는 용존고형물의 함량이 여전히 높아, 막대한 물소비율을 점유하는 아파트나 다가구주택 등의 보일러 용수나 산업현장에서의 냉각용 살수용수 등과 같이 배관내 체류시간이 상대적으로 긴 용수에는 적합하지 않다는 문제점이 있었다.However, since the conventional water supply system does not have a separate device mainly intended for the removal of dissolved solids (TDS), the treated heavy water still has a high content of dissolved solids, which is a major cause of scale generation in pipes. There was a problem that it is not suitable for water having a relatively long residence time in the piping, such as boiler water such as apartments or multi-family houses occupying the ratio, or cooling water for cooling in industrial sites.

본 발명은 상기와 같은 문제점을 감안하여 안출된 것으로서, 시스템내에 용존고형물의 제거를 위한 장치를 구비함으로써, 처리된 중수가 배관내 체류시간이 비교적 긴 보일러용수나 살수용수 등으로도 활용될 수 있도록 하여 중수의 활용 범위를 극대화한 용존고형물제거장치가 조합된 중수도시스템을 제공함에 그 목적이 있다.The present invention has been made in view of the above problems, by providing a device for the removal of dissolved solids in the system, so that the treated heavy water can be utilized as boiler water or sprinkling water with a relatively long residence time in the pipe. The purpose of the present invention is to provide a sewage water system that combines dissolved solids removal device that maximizes the utilization of heavy water.

도 1은 본 발명의 제1실시예에 따른 용존고형물제거장치가 조합된 중수도시스템의 개략적인 계통도1 is a schematic system diagram of a water-based water system combined with a dissolved solids removing device according to a first embodiment of the present invention

도 2는 본 발명의 제2실시예에 따른 용존고형물제거장치가 조합된 중수도시스템의 개략적인 계통도Figure 2 is a schematic system diagram of a water system combined with dissolved solids removal apparatus according to a second embodiment of the present invention

도 3은 본 발명의 용존고형물제거장치가 조합된 중수도시스템의 바이오필터에 충진, 사용되는 메디아의 사시도Figure 3 is a perspective view of the media used for filling and using the biofilter of the water system with the dissolved solids removal device of the present invention

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

10 : 저장조 20 : 바이오필터10: reservoir 20: biofilter

21 : 메디아 22 : 내부지지대21: Media 22: Internal support

23 : 관체 24 : 배양판23: tube 24: culture plate

25 : 외부지지대 26 : 칸막이25: external support 26: partition

27 : 통수공 30 : 유량조정조27: water hole 30: flow rate adjustment tank

40 : 활성탄흡착기 50 : 정밀여과기40: activated carbon adsorber 50: precision filter

60 : 전기투석장치 70 : 염소소독장치60: electrodialysis device 70: chlorine disinfection device

80 : 중수저류조 90 : 역삼투여과장치80: heavy water storage tank 90: reverse osmosis filtration device

100 : 송풍기 110 : 펌프100: blower 110: pump

이하, 상기의 목적을 달성하기 위한 본 발명의 실시예에 따른 용존고형물제거장치가 조합된 중수도시스템을 첨부 도면에 의거, 상세히 설명하면 다음과 같다.Hereinafter, with reference to the accompanying drawings, the water-based water system combined with the dissolved solids removal apparatus according to an embodiment of the present invention for achieving the above object is as follows.

도 1은 본 발명의 제1실시예에 따른 용존고형물제거장치가 조합된 중수도시스템의 개략적인 계통도이고, 도 2는 본 발명의 제2실시예에 따른 용존고형물제거장치가 조합된 중수도시스템의 개략적인 계통도이며, 도 3은 본 발명의 용존고형물제거장치가 조합된 중수도시스템의 바이오필터에 충진, 사용되는 메디아의 사시도로서,1 is a schematic system diagram of a combined water removal system according to a first embodiment of the present invention with a dissolved solids removal device, and FIG. 2 is a schematic diagram of a water supply system with a dissolved solids removal device according to a second embodiment of the present invention. 3 is a perspective view of a media used for filling and used in a biofilter of a water system in which the dissolved solids removing device of the present invention is combined.

본 발명의 제1실시예에 따른 용존고형물제거장치가 조합된 중수도시스템은, 저농도의 유기물 및 난분해성 용존물을 함유한 공급원수인 오폐수 또는 하수처리 방류수를 중수로 처리하여 재활용하기 위한 중수도시스템에 있어서,The water purification system combined with the dissolved solids removal device according to the first embodiment of the present invention is a wastewater system for treating wastewater or sewage treatment effluent, which is a feed water containing low concentrations of organic matter and hardly decomposable dissolved matter, with heavy water for recycling. ,

공급원수를 집수, 저장하는 저장조(10)와; 미생물의 부착, 서식을 위한 메디아(21)가 충진되어 상기 저장조(10)로부터 유입된 공급원수로부터 질소, 인, 저농도의 유기물과 일정량의 탁도 성분 및 부유물질 제거를 동시에 수행하는 바이오필터(20)와; 상기 바이오필터(20)를 통과한 처리수가 과도하게 발생시에도 유량을 일정하게 유지시키고 원활한 이후 처리를 위해 오염물의 부하변동을 조정하는 유량조정조(30)와; 상기 유량조정조(30)에 의해 유량 및 수질이 균질화된 처리수로부터 잔존하는 난분해성 용존 유기물, 잔류염소, 색깔, 냄새 및 미량의 유해 무기물을 흡착, 제거하는 활성탄흡착기(40)와; 상기 활성탄흡착기(40)를 통과한 처리수로부터 미세 부유물질과 고분자 물질 및 콜로이드상의 물질을 제거하는 정밀여과기(50)와; 상기 정밀여과기(50)를 통과한 처리수로부터 이온성의 용존고형물을 선택적 투과에 의해 농축, 제거하는 전기투석장치(60)와; 상기 전기투석장치(60)를 통과한 처리수에 염소를 투입하여 미생물의 번식을 방지하고 살균토록 하기 위한 염소소독장치(70)와; 처리가 완료된 중수를 저류하는 중수저류조(80);로 이루어짐을 특징으로 한다.A storage tank 10 for collecting and storing supply water; The biofilter 20 is filled with a media 21 for attaching and culturing microorganisms and simultaneously removing nitrogen, phosphorus, and low concentrations of organic matter and a certain amount of turbidity components and suspended solids from the feedwater introduced from the reservoir 10. Wow; A flow rate adjustment tank 30 which maintains a constant flow rate even when excessively generated water passing through the biofilter 20 and adjusts load variation of contaminants for smooth after-treatment; An activated carbon adsorber (40) for adsorbing and removing hardly decomposable dissolved organic matter, residual chlorine, color, odor and trace amounts of harmful inorganic substances remaining from the treated water in which the flow rate and water quality are homogenized by the flow rate adjusting tank 30; A precision filter (50) for removing fine suspended solids, polymer materials, and colloidal materials from the treated water passing through the activated carbon adsorber (40); An electrodialysis apparatus (60) for concentrating and removing ionic dissolved solids by selective permeation from the treated water passing through the precision filter (50); A chlorine disinfection device 70 for putting chlorine into the treated water passing through the electrodialysis device 60 to prevent the growth of microorganisms and to sterilize it; Characterized in that consisting of; heavy water storage tank (80) for storing the treated heavy water.

그리고, 본 발명의 제2실시예에 따른 용존고형물제거장치가 조합된 중수도시스템은 상기 제1실시예에 따른 중수도시스템에 있어서, 상기 정밀여과기(50) 및 전기투석장치(60)가 미세 부유물질, 고분자 물질, 콜로이드상의 물질 및 용존고형물을 동시에 제거하는 역삼투여과장치(90)로 대체되어 이루어짐을 특징으로 한다.In addition, in the water-based water system combined with the dissolved solids removal device according to the second embodiment of the present invention, in the water-based water system according to the first embodiment, the precision filter 50 and the electrodialysis apparatus 60 are fine suspended solids. , It is characterized by consisting of a reverse osmosis filtration device 90 to remove the polymer material, colloidal material and dissolved solids at the same time.

한편, 상기 메디아(21)는 '+' 형상으로 교차된 내부지지대(22)에 의해 견고히 지지되는 관체(23)의 외주면에 다수개의 배양판(24)이 외부지지대(25)로써 부착되고, 상기 관체(23) 종단면의 중간부에 원판링 형상의 칸막이(26)가 배양판(24)의 내측으로 환설되어 관체(23)의 외측 벽면과 칸막이(26) 사이에 통수공(27)이 뚫린 구조의 세공질임을 특징으로 한다.On the other hand, the media 21 is a plurality of culture plates 24 are attached to the outer peripheral surface of the tubular body 23 is firmly supported by the inner support 22 crossed in a '+' shape, the outer support 25, A circular ring-shaped partition 26 is formed in the middle of the tubular body 23 in the middle of the culture plate 24, and a water hole 27 is drilled between the outer wall of the tubular body 23 and the partition 26. It is characterized by the pore quality.

이와 같이 된 본 발명의 제1실시예에 따른 용존고형물제거장치가 조합된 중수도시스템의 중수처리 과정을 상세히 살펴보면 다음과 같다.Looking at the water treatment process of the water system in combination with the dissolved solids removal apparatus according to the first embodiment of the present invention as described above are as follows.

먼저, 오폐수 처리장으로부터 1차 처리되어 저농도의 유기물 및 난분해성 용존물을 함유한 오폐수 처리 방류수는 다음 처리를 위한 장치인 바이오필터(20)에 공급될 수 있도록 상기 저장조(10)에 집수, 저장된다.First, the wastewater treatment effluent, which is first treated from the wastewater treatment plant and contains low concentrations of organic matter and hardly decomposable dissolved matter, is collected and stored in the reservoir 10 to be supplied to the biofilter 20 which is a device for subsequent treatment. .

상기 바이오필터(20)는 미생물의 부착, 서식을 위한 메디아(21)가 충진되어 생물막 형성에 의해 공급원수로부터 질소, 인 및 유기물의 분해가 이루어지도록 한 것으로, 여기서, 상기 메디아(21)는 본원 출원인이 선출원하여 등록받은 등록번호 제 20-0289920호의 대한민국 등록실용신안공보에 그 상세한 구성 및 작용이 개시된 바와 같은 비표면적이 넓고 미생물 부착능이 탁월하며 여과기능도 갖는 특수 구조의 것을 이용함으로써, 본 바이오필터(20)에서 상기 메디아(21)에 부착 서식하는 미생물에 의한 공급원수 내의 질소, 인 및 유기물의 분해와 함께 상기 특수 구조의 메디아(21)에 의해 공급원수 내의 탁도성분과 부유물질도 상당량 제거되도록 하고, 이에 따라 후처리 장치들의 부하가 덜어지게 되어 장치의 수명이 향상되게 함은 물론 시스템 전체를 컴팩트화 하는 것이 용이하도록 하는 것이 바람직하다. 도 3에 상기 메디아(21)의 구조가 도시되어 있다.The biofilter 20 is a media 21 for the attachment and habitat of microorganisms is filled so that the decomposition of nitrogen, phosphorus and organics from the source water by the formation of a biofilm, wherein the media 21 is By using a special structure having a large specific surface area, excellent microbial adhesion ability, and filtration function as disclosed in the Korean Utility Model Utility Model Publication No. 20-0289920, filed by the applicant, and registered in Korean Registered Utility Model Publication No. 20-0289920, In addition to the decomposition of nitrogen, phosphorus and organic matter in the feed water by the microorganisms attached to the media 21 in the filter 20, the media 21 of the special structure removes a considerable amount of turbidity components and suspended solids in the feed water. This reduces the load on the post-treatment units, thus improving the life of the units as well as compacting the entire system. So that it is easy to screen are preferred. The structure of the media 21 is shown in FIG.

상기 바이오필터(20) 내부로는 필요에 따라 산소 농도를 일정하게 유지시키고 호기성세균의 생장 및 활동을 활발하게 하기 위해 송풍기(110)에 의해 폭기가 이루어지게 할 수도 있다.Inside the biofilter 20 may be aeration by the blower 110 to maintain a constant oxygen concentration as needed and to actively grow and activity aerobic bacteria.

상기 바이오필터(20)를 거친 피처리수는 유량조정조(30)에 의해 유량 및 수질이 균등화되어 다음 처리를 위한 활성탄흡착기(40)로 유입되게 된다. 즉, 상기 유량조정조(30)는 유입수의 유량 및 수질의 변동에 의해 발생할 수 있는 중수도시스템의 처리 효율 저하를 방지하고 운전비용을 절감할 수 있도록 하는 역할을 하게 된다.The treated water that has passed through the biofilter 20 is equalized in flow rate and water quality by the flow rate adjusting tank 30 to be introduced into the activated carbon adsorber 40 for the next treatment. That is, the flow rate adjustment tank 30 serves to prevent a decrease in processing efficiency of the water supply system, which may occur due to the flow rate of the inflow water and the water quality, and to reduce the operating cost.

상기 유량조정조(30)에 의해 유량 및 수질이 균등화된 피처리수는 활성탄흡착기(40)로 유입되어 강한 흡착력을 갖는 활성탄에 의해 잔존하는 난분해성 용존 유기물, 잔류염소, 맛, 색깔, 냄새 및 미량의 유해 무기물 등이 흡착, 제거되게 된다.Treated water in which the flow rate and water quality are equalized by the flow rate adjusting tank 30 is introduced into the activated carbon adsorber 40, and the remaining hardly decomposable dissolved organic matter, residual chlorine, taste, color, odor and trace amount of the activated carbon having strong adsorption power. Hazardous minerals and the like will be adsorbed and removed.

상기 활성탄흡착기(40)를 통과한 피처리수는 정밀여과기(50)로 유입되어 함유되어 있던 미세 부유물질과 고분자 물질 및 콜로이드상의 물질이 제거되어진 후 유출되게 된다.The water to be treated passing through the activated carbon adsorber 40 flows into the precision filter 50 after the fine suspended matter, the polymer material, and the colloidal material are removed.

상기 정밀여과기(50)를 통과한 피처리수에는 부유물질 및 미세입자들이 대부분 제거된 상태이나 칼슘, 마그네슘과 같이 이온상태로 존재하여 배관내 스케일 형성의 주요인이 되는 용존고형물(TDS)은 대부분 상기 정밀여과기(50)의 여과막을 통과하게 되므로 여전히 피처리수 내에 잔존하게 되는바, 상기 정밀여과기(50)를 통과한 피처리수는 전기투석장치(60)로 유입되어 이들 용존고형물이 선택적으로 투과, 농축되어 제거되게 된다.Most of the dissolved solids (TDS), which are the main factors for the formation of scale in the pipe, are present in the treated water passing through the precision filter 50 in the state in which suspended substances and fine particles are mostly removed or in an ionic state such as calcium and magnesium. Since it passes through the filtration membrane of the microfilter 50 still remains in the water to be treated, the water to be passed through the microfilter 50 is introduced into the electrodialysis apparatus 60 and these dissolved solids selectively permeate Concentrated and removed.

여기서, 상기 전기투석장치(60)는 이온교환막을 사용하여 양이온 또는 음이온을 선택적으로 투과시켜 이온종의 분류 및 농축을 행하도록 한 장치로, 양극과 음극 사이에 교대 배열된 다수의 양이온교환막 및 음이온교환막에 의해서 이온이 제거된 희석수와 농축된 농축수로 분리되도록 한 것이다.Here, the electrodialysis apparatus 60 is a device for selectively permeating cations or anions using an ion exchange membrane to classify and concentrate ion species, and a plurality of cation exchange membranes and anions alternately arranged between an anode and a cathode. The separation membrane was separated into dilute water and concentrated concentrated water from which ions were removed.

상기 전기투석장치(60)를 통과한 피처리수는 수관을 따라 흐르는 과정에서 그 관로중에 구비되는 염소소독장치(70)로부터 투입되는 염소에 의해 내부에 함유되어 있던 미생물이 살균 처리되게 된다.The treated water that has passed through the electrodialysis apparatus 60 is sterilized by the microorganisms contained therein by the chlorine introduced from the chlorine disinfection device 70 provided in the pipeline during the flow along the water pipe.

이상의 처리과정을 마친 피처리수는 질소, 인, 저농도 유기물, 탁도 성분,난분해성 용존 유기물 및 기타 용존고형물 등의 오염성분이 제거된 적합한 수질을 갖는 중수로 되어 중수저류조(80)에 유입 저류되게 된다.The treated water that has completed the above process becomes heavy water having suitable water from which contaminants such as nitrogen, phosphorus, low concentration organics, turbidity components, hardly decomposable dissolved organics, and other dissolved solids are removed, and are stored in the heavy water storage tank 80. .

이와 같이 본 실시예에서는 피처리수가 상기 전기투석장치(60)를 통과할 때, 피처리수 내에 존재하던 배관내 스케일 발생의 주요인이 되는 이온상의 용존고형물이 농축되어 분리 제거되게 되므로, 본 실시예에 의해 처리된 중수는 종래의 방식에 의해 처리된 중수로는 사용이 부적합하였던 보일러용수나 살수용수 등으로의 활용이 가능하게 되어 결과적으로 중수의 활용 범위를 한층 넓힐 수 있게 되는 것이다.As described above, in the present embodiment, when the water to be treated passes through the electrodialysis apparatus 60, the dissolved ionic solids, which are the main cause of the generation of scale in the pipes existing in the water to be treated, are concentrated and removed. The heavy water treated by is able to be used as boiler water or sprinkling water, which is not suitable for use in the heavy water treated by the conventional method, and consequently, the use of heavy water can be further expanded.

한편, 본 발명의 제2실시예에서는 도 2에 도시된 바와 같이 상기 정밀여과기(50) 및 전기투석장치(60)가 역삼투여과장치(90)에 의해 대체되어 구성되는데, 이러한 역삼투여과장치(90)는 자연상에 존재하는 삼투현상을 압력을 가하여 역으로 밀어내는 원리를 이용한 것으로서, 5∼15Å(옹스트롱) 정도의 미세 기공(pore)을 갖는 반투막에 의해 미세 부유물질과 고분자 물질 그리고 콜로이드상의 물질외에 공급원수중의 고형물질(이온물질 포함)을 99% 이상 제거하게 되므로, 상술한 정밀여과기(50)와 전기투석장치(60)의 역할을 모두 수행하게 된다.Meanwhile, in the second embodiment of the present invention, the precision filter 50 and the electrodialysis apparatus 60 are replaced by the reverse osmosis filtration apparatus 90 as shown in FIG. 2, and the reverse osmosis filtration apparatus 90 is configured. ) Is based on the principle of reverse osmosis by applying pressure to the osmotic phenomena existing in nature.The semi-permeable membrane with fine pores of about 5 ~ 15Å (Angstrom) In addition to the material is removed more than 99% of the solid matter (including ionic material) in the source water, and thus serves as both the above-described precision filter 50 and the electrodialysis device (60).

따라서, 본 실시예에서와 같이 역삼투여과장치(90)를 구비하는 경우에도 상술한 제1실시예에서와 마찬가지로 보일러용수나 살수용수 등으로도 활용이 가능한 중수를 얻을 수 있게 되어 중수의 활용 범위를 극대화하게 되는 것은 물론이며 아울러 시스템을 한층 더 간소화하는 효과도 가져올 수 있게 된다.Therefore, even when the reverse osmosis filtration device 90 is provided as in the present embodiment, it is possible to obtain heavy water that can be utilized as boiler water or sprinkling water, as in the above-described first embodiment, thereby increasing the application range of heavy water. Not only will this be maximized, but it will also simplify the system even further.

다만, 상기 역삼투여과장치(90)는 그 설비비가 고가이고, 운전시 역삼투압을가하여야 하며, 반투막의 오염에 따른 잦은 세정이 필요한 등 그 운전에도 많은 비용이 소모되는 단점도 갖는 바, 부유물질(suspended solids, SS)의 초기 함량이 50 ∼ 150 ppm 범위인 공급원수를 주로 처리하는 경우에는 부유물질의 제거효과가 상대적으로 높은 역삼투여과장치(90)를 구비한 본 발명의 제2실시예를 적용하고, 부유물질의 초기함량이 5 ∼ 100 ppm 범위인 공급원수를 주로 처리하는 경우에는 설비 및 운전비용 측면에 더 비중을 두어 정밀여과기(50) 및 전기투석장치(60)를 구비한 본 발명의 제1실시예를 적용하는 것이 보다 바람직하다. 여기서 상기 부유물질의 초기함량이 중복되는 범위인 50 ∼ 100 ppm 범위인 경우에는 상기 제1실시예 또는 제2실시예 중 어느 실시예를 적용하여도 무방하다.However, the reverse osmosis filtration device 90 has a disadvantage that the equipment cost is high, and the reverse osmosis pressure must be applied during operation, and a lot of cost is consumed even in the operation such as frequent cleaning due to the contamination of the semi-permeable membrane. In the case of mainly treating feed water having an initial content of suspended solids (SS) in the range of 50 to 150 ppm, the second embodiment of the present invention having a reverse osmosis filtration device 90 having a relatively high effect of removing suspended solids is applied. In the case of mainly processing the feed water in the initial content of the suspended solids range of 5 to 100 ppm, the precision filter 50 and the electrodialysis apparatus 60 of the present invention are provided with more emphasis on equipment and operating costs. It is more preferable to apply the first embodiment. In the case where the initial content of the suspended solids is in the range of 50 to 100 ppm, the first embodiment or the second embodiment may be applied.

이와 같이 된 본 발명은 최소화된 규모의 시스템으로써 적합한 목적 수질을 얻을 수 있게 되므로 그 설치와 유지에 소요되는 비용을 최대한 절감시킬 수 있으며, 나아가 각종 오염성분에 대한 우수한 제거능과 높은 효율에 의해, 상술한 바와 같은 중수처리의 목적 외에도 정수처리의 고도처리용이나 공업용수의 고도처리용으로도 활용이 가능하게 된다.The present invention as described above is able to obtain a suitable target water quality as a system of a minimized scale, so that the cost required for installation and maintenance can be reduced as much as possible, and furthermore, by excellent removal ability and high efficiency for various contaminants, In addition to the purpose of heavy water treatment as described above, it can be utilized for advanced treatment of purified water treatment or for advanced treatment of industrial water.

이와 같이 본 발명에 따른 용존고형물제거장치가 조합된 중수도시스템은 용존고형물의 제거를 위한 장치를 구비하여 공급원수로부터 용존고형물의 제거도 이루어지도록 함으로써 본 발명에 의해 처리된 중수가 통상적인 중수의 활용 용도 외에 배관내 체류시간이 비교적 긴 보일러 용수나 냉각용 살수용수 등으로 활용되는것이 가능하도록 하여 중수의 활용범위를 극대화하고 이에 의해 궁극적으로 수자원의 안정적 확보에 기여케 하는 유용한 효과가 있다.Thus, the heavy water system combined with the dissolved solids removing device according to the present invention is equipped with a device for removing the dissolved solids so that the dissolved solids can be removed from the feed water, thereby utilizing the conventional heavy water. In addition to the use, it is possible to be utilized as boiler water or cooling water for cooling water, which has a relatively long residence time in the pipe, thereby maximizing the utilization of heavy water and thereby contributing to the stable securing of water resources.

Claims (2)

저농도의 유기물 및 난분해성 용존물을 함유한 공급원수인 오폐수 또는 하수처리 방류수를 중수로 재활용하기 위한 중수도시스템에 있어서,In the sewage water system for recycling waste water or sewage effluent, which is a feed water containing low concentration of organic matter and hardly decomposable dissolved water, into heavy water, 공급원수를 집수, 저장하는 저장조(10)와; 미생물의 부착, 서식을 위한 메디아(21)가 충진되어 상기 저장조(10)로부터 유입된 공급원수로부터 질소, 인, 저농도의 유기물과 일부 탁도 성분 및 부유물질 제거를 동시에 수행하는 바이오필터(20)와; 상기 바이오필터(20)를 통과한 피처리수가 과도하게 발생시에도 유량을 일정하게 유지시키고 원활한 이후 처리를 위해 오염물의 부하변동을 조정하는 유량조정조(30)와; 상기 유량조정조(30)에 의해 유량 및 수질이 균질화된 피처리수로부터 잔존하는 난분해성 용존 유기물, 잔류염소, 색깔, 냄새 및 미량의 유해 무기물을 흡착, 제거하는 활성탄흡착기(40)와; 상기 활성탄흡착기(40)를 통과한 피처리수로부터 미세 부유물질 및 고분자 물질이나 콜로이드상의 물질을 제거하는 정밀여과기(50)와; 상기 정밀여과기(50)를 통과한 피처리수로부터 이온성의 용존고형물을 선택적 투과에 의해 농축, 제거케 하는 전기투석장치(60)와; 상기 전기투석장치(60)를 통과한 처리수에 염소를 투입하여 미생물의 번식을 방지하고 살균토록 하기 위한 염소소독장치(70)와; 처리가 완료된 중수를 저류하는 중수저류조(80);가 일련되게 구비됨을 특징으로 하는 용존고형물제거장치가 조합된 중수도시스템.A storage tank 10 for collecting and storing supply water; Media filter 21 for the attachment and habitat of microorganisms is filled and the biofilter 20 to simultaneously remove nitrogen, phosphorus, low concentration of organic matter and some turbidity components and suspended solids from the feed water introduced from the reservoir 10 and ; A flow rate adjusting tank 30 which maintains a constant flow rate even when excessively generated water passing through the biofilter 20 and adjusts load variation of contaminants for smooth after-treatment; An activated carbon adsorber (40) for adsorbing and removing hardly decomposable dissolved organic matter, residual chlorine, color, odor and trace amounts of harmful inorganic substances remaining from the treated water having a uniform flow rate and water quality by the flow rate adjusting tank 30; A precision filter (50) for removing fine suspended solids, polymers, and colloidal substances from the water to be treated which has passed through the activated carbon adsorber (40); An electrodialysis apparatus (60) for concentrating and removing ionic dissolved solids by selective permeation from the water to be treated which has passed through the precision filter (50); A chlorine disinfection device 70 for putting chlorine into the treated water passing through the electrodialysis device 60 to prevent the growth of microorganisms and to sterilize it; A heavy water storage system comprising a dissolved solids removal device comprising: a heavy water storage tank (80) for storing the treated heavy water; 저농도의 유기물 및 난분해성 용존물을 함유한 공급원수인 오폐수 또는 하수처리 방류수를 중수로 재활용하기 위한 중수도시스템에 있어서,In the sewage water system for recycling waste water or sewage effluent, which is a feed water containing low concentration of organic matter and hardly decomposable dissolved water, into heavy water, 공급원수를 집수, 저장하는 저장조(10)와; 특수구조의 메디아(21)가 충진되어 상기 저장조(10)로부터 유입된 공급원수로부터 저농도의 유기물과 탁도 성분 및 부유물질 제거를 동시에 수행하는 바이오필터(20)와; 상기 바이오필터(20)를 통과한 피처리수가 과도하게 발생시에도 유량을 일정하게 유지시키고 원활한 이후 처리를 위해 오염물의 부하변동을 조정하는 유량조정조(30)와; 상기 유량조정조(30)에 의해 유량 및 수질이 균질화된 피처리수로부터 잔존하는 난분해성 용존 유기물, 잔류염소, 색깔, 냄새 및 미량의 유해 무기물을 흡착, 제거하는 활성탄흡착기(40)와; 상기 활성탄흡착기(40)를 통과한 피처리수로부터 미세 부유물질, 고분자 물질, 콜로이드상의 물질 및 용존고형물을 제거하는 역삼투여과장치(90)와; 상기 역삼투여과장치(90)를 통과한 피처리수에 염소를 투입하여 미생물의 번식을 방지하고 살균토록 하기 위한 염소소독장치(70)와; 상기 염소소독장치(70)를 통과함으로써 처리가 완료된 중수를 저류하는 중수저류조(80);가 일련되게 구비됨을 특징으로 하는 용존고형물 제거장치가 조합된 중수도시스템.A storage tank 10 for collecting and storing supply water; A biofilter 20 which is filled with a media 21 having a special structure and simultaneously removes low concentrations of organic matter, turbidity components, and suspended solids from the feedwater introduced from the reservoir 10; A flow rate adjusting tank 30 which maintains a constant flow rate even when excessively generated water passing through the biofilter 20 and adjusts load variation of contaminants for smooth after-treatment; An activated carbon adsorber (40) for adsorbing and removing hardly decomposable dissolved organic matter, residual chlorine, color, odor and trace amounts of harmful inorganic substances remaining from the treated water having a uniform flow rate and water quality by the flow rate adjusting tank 30; A reverse osmosis filtration device 90 for removing fine suspended solids, polymer materials, colloidal substances and dissolved solids from the water to be treated which has passed through the activated carbon adsorber 40; A chlorine disinfection device 70 for putting chlorine into the water to be treated that has passed through the reverse osmosis filtration device 90 to prevent the growth of microorganisms and to sterilize it; The heavy water storage tank (80) for storing the treated heavy water by passing through the chlorine disinfection device (70).
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101149296B1 (en) * 2009-03-26 2012-05-24 현대제철 주식회사 Method for removing of perchlorate ion and nitrate ion in underground water
CN103121774A (en) * 2013-01-31 2013-05-29 陕西华祥能源科技集团有限公司 Multi-stage recycling device and method for waste water in semi-coke production
CN104058525A (en) * 2014-07-01 2014-09-24 中国天辰工程有限公司 Method for recovering and treating production wastewater containing high ammonia nitrogen and nitrate nitrogen
KR102073369B1 (en) * 2019-06-27 2020-03-02 주식회사 탑플랜트 Used water reprocessing system
KR20200070888A (en) * 2018-12-10 2020-06-18 한국과학기술연구원 Method for pretreatment of capacitive deionization based on ingredient of raw water
CN112174406A (en) * 2020-10-19 2021-01-05 山东金号家纺集团有限公司 Water treatment process of wastewater advanced treatment device
CN113401983A (en) * 2020-03-16 2021-09-17 佛山市云米电器科技有限公司 Water purification method and separation device
CN113526781A (en) * 2020-04-22 2021-10-22 大连波美科技有限公司 Treatment and recycling system and process for vegetable oil saponin wastewater

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101149296B1 (en) * 2009-03-26 2012-05-24 현대제철 주식회사 Method for removing of perchlorate ion and nitrate ion in underground water
CN103121774A (en) * 2013-01-31 2013-05-29 陕西华祥能源科技集团有限公司 Multi-stage recycling device and method for waste water in semi-coke production
CN104058525A (en) * 2014-07-01 2014-09-24 中国天辰工程有限公司 Method for recovering and treating production wastewater containing high ammonia nitrogen and nitrate nitrogen
CN104058525B (en) * 2014-07-01 2016-01-20 中国天辰工程有限公司 Production waste recovery and treatment method containing high ammonia nitrogen and nitric nitrogen
KR20200070888A (en) * 2018-12-10 2020-06-18 한국과학기술연구원 Method for pretreatment of capacitive deionization based on ingredient of raw water
KR102073369B1 (en) * 2019-06-27 2020-03-02 주식회사 탑플랜트 Used water reprocessing system
CN113401983A (en) * 2020-03-16 2021-09-17 佛山市云米电器科技有限公司 Water purification method and separation device
CN113526781A (en) * 2020-04-22 2021-10-22 大连波美科技有限公司 Treatment and recycling system and process for vegetable oil saponin wastewater
CN112174406A (en) * 2020-10-19 2021-01-05 山东金号家纺集团有限公司 Water treatment process of wastewater advanced treatment device
CN112174406B (en) * 2020-10-19 2022-04-19 山东金号家纺集团有限公司 Water treatment process of wastewater advanced treatment device

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