KR20040076000A - Variegation design pool cover tarpaulin using pvc compound and manufacturing method thereof - Google Patents
Variegation design pool cover tarpaulin using pvc compound and manufacturing method thereof Download PDFInfo
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- KR20040076000A KR20040076000A KR1020030011287A KR20030011287A KR20040076000A KR 20040076000 A KR20040076000 A KR 20040076000A KR 1020030011287 A KR1020030011287 A KR 1020030011287A KR 20030011287 A KR20030011287 A KR 20030011287A KR 20040076000 A KR20040076000 A KR 20040076000A
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- tarpaulin
- pvc
- speckled
- blend
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 150000001875 compounds Chemical class 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000004744 fabric Substances 0.000 claims abstract description 23
- 229920000728 polyester Polymers 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 8
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 8
- 239000012963 UV stabilizer Substances 0.000 claims abstract description 8
- 239000008029 phthalate plasticizer Substances 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000010030 laminating Methods 0.000 claims abstract description 6
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 claims abstract description 6
- 235000010215 titanium dioxide Nutrition 0.000 claims abstract description 6
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 5
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 5
- 239000011147 inorganic material Substances 0.000 claims abstract description 5
- 239000011120 plywood Substances 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 29
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 8
- 239000012463 white pigment Substances 0.000 claims description 4
- 239000001055 blue pigment Substances 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims description 2
- 238000003490 calendering Methods 0.000 claims 1
- 238000009472 formulation Methods 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 abstract description 2
- 230000009182 swimming Effects 0.000 abstract description 2
- 230000000007 visual effect Effects 0.000 abstract description 2
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 description 47
- 229920000915 polyvinyl chloride Polymers 0.000 description 47
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000004049 embossing Methods 0.000 description 6
- 239000011247 coating layer Substances 0.000 description 5
- 238000004898 kneading Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000000396 iron Nutrition 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 241001550224 Apha Species 0.000 description 1
- TWDJIKFUVRYBJF-UHFFFAOYSA-N Cyanthoate Chemical compound CCOP(=O)(OCC)SCC(=O)NC(C)(C)C#N TWDJIKFUVRYBJF-UHFFFAOYSA-N 0.000 description 1
- NEHDRDVHPTWWFG-UHFFFAOYSA-N Dioctyl hexanedioate Chemical compound CCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC NEHDRDVHPTWWFG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
Landscapes
- Laminated Bodies (AREA)
Abstract
본 발명은 옥내외의 간이 수영장에 사용되는 풀-용 타포린 제품으로 PVC 배합물을 이용한 단면(상부)층 얼룩무늬 타포린 및 그 제조방법에 관한 것이다. 본 발명에 따른 얼룩무늬 타포린 제조과정은 아래 배합 1과정과 배합 2 과정으로 이루어지고, 배합 1 과정은 PVC 수지 100 중량%, 프탈레이트 가소제 40∼65중량%, 무기물 10∼40 중량%, 바륨-징크 타입의 복합 액상안정제 2∼4중량%, 자외선 안정제 0.5∼0.8중량%의 원료를 배합(혼합)하여 시아닌 블루 마스터배치 안료를 5∼25중량% 첨가하여 반바리 믹서에 130∼180도 5∼10분 혼련하고, 다시 2본 믹서 롤에 투입후 배합물을 3∼5분 155∼165℃에서 혼련한다. 배합 2 과정은 PVC 수지 100 중량%, 프탈레이트 가소제 40∼65중량%, 무기물 10∼40 중량%, 바륨-징크 타입의 복합 액상안정제 2∼4 중량%, 자외선 안정제 0.5∼0.8중량%의 원료를 배합(혼합)하여 티탄 화이트 마스터배치 5∼25중량% 첨가하여 반바리 혼합기에 배합물을 혼련하고, 혼련된 배합물을 2본 믹서 롤에 투입후 배합물을 3∼5분 155∼165도에서 혼련한다. 배합 1과정과 배합 2과정에 의해 혼련된 배합물은 카렌더 기기에 혼련을 부분적으로 하고 카렌더 장치부를 통하여 냉각 후 PVC 얼룩무늬 필름을 제작한다. 제작된 PVC 필름을 상부 얼룩무늬 PVC 필름, 중지에 페이스트 코팅된 폴리에스터(POLYESTER) 직물, 하지에는 PVC 필름층을 라미네이트(합판)를 하여 3층 구조의 얼룩무늬 타포린을 제작한다. 제작된 3층 구조 PVC 타포린을 다시 액상타입의 아크릴 수지를 이용하여 표면에 코팅을 하고 코팅의 설정조건은 70∼120도에서1∼2분 건조를 하여 얼룩무늬 타포린 완제품을 제작한다. 본 발명에 따른 PVC 얼룩무늬 타포린 제품은 시각적인 효과와 풀 커버의 미관을 보다 고급화 할 수 있는 효과가 있고, 제품 제조 방법의 개발로 인한 공정의 인건비, 노무비, 재료비, 제조경비를 절감하는 효과가 있다.The present invention relates to a cross-sectional (top) layered speckled tarpaulin using a PVC compound as a pool tarpaulin product used for indoor and outdoor simple swimming pools, and a method of manufacturing the same. According to the present invention, the process for preparing a speckled tarpaulin consists of the following formulation 1 and formulation 2, wherein the formulation 1 is 100% by weight of PVC resin, 40 to 65% by weight of phthalate plasticizer, 10 to 40% by weight of inorganic material, barium-zinc 2 to 4% by weight of the composite liquid stabilizer of the type and 0.5 to 0.8% by weight of UV stabilizer were mixed (mixed), and 5 to 25% by weight of cyanine blue masterbatch pigment was added. The mixture is kneaded for 2 minutes, and the mixture is kneaded at 155 to 165 ° C for 3 to 5 minutes after feeding into two mixer rolls. The compounding 2 process mixes 100% by weight of a PVC resin, 40 to 65% by weight of a phthalate plasticizer, 10 to 40% by weight of an inorganic substance, 2 to 4% by weight of a barium-zinc-type composite liquid stabilizer, and 0.5 to 0.8% by weight of an UV stabilizer. (Mixing), 5-25 weight% of titanium white masterbatches are added, the blend is knead | mixed in a half-barrier mixer, the blended blend is put into two mixer rolls, and a blend is kneaded at 155-165 degree | times for 3 to 5 minutes. The blend kneaded by the blending process 1 and blending process 2 is partially kneaded in a calender machine and cooled through the calender unit to produce a PVC speckle film. The produced PVC film is made of a three-layered speckled tarpaulin by laminating (plywood) the upper speckled PVC film, a polyester (POLYESTER) fabric coated on the middle finger, and a PVC film layer on the lower surface. The three-layer PVC tarpaulin fabricated is then coated on the surface using a liquid-type acrylic resin and dried for 1 to 2 minutes at 70 to 120 ° C to produce a speckled tarpaulin. PVC speckled tarpaulin product according to the present invention has the effect of improving the visual effect and aesthetics of the full cover more, and the effect of reducing labor costs, labor costs, material costs, manufacturing costs of the process due to the development of the product manufacturing method have.
Description
본 발명은 옥내외의 간이 수영장에 사용되는 풀용 타포린 및 그 제조방법에 관한 것으로, 특히 PVC 배합물을 이용하여 PVC 필름층을 형성하고 이 PVC 필름층을 폴리에스터 직물 코팅층에 얼룩무늬 PVC 필름을 라미네이트(합판)로 제조함으로써 내구성 및 내마모성이 탁월하고 옥외 사용시 장기간 무늬가 보존될 수 있는 특징으로 가진 PVC 배합물을 이용한 얼룩무늬 풀-커버용 타포린 및 그 제조방법에 관한 것이다.The present invention relates to a tarpaulin for pools used in indoor and outdoor simple swimming pools and a method of manufacturing the same, and in particular, to form a PVC film layer using a PVC compound, the PVC film layer is laminated with a stained PVC film on the polyester fabric coating layer (plywood) The present invention relates to a tarpaulin for stained full-cover using a PVC blend, which is characterized by excellent durability and abrasion resistance and can be preserved for a long time in outdoor use, and a method of manufacturing the same.
기존 PVC 타포린 제품은 표면에 잉크를 이용한 그라비아 롤타입의 처리 방법으로 표면의 얼룩무늬를 사용하였다.Existing PVC tarpaulin products used stains on the surface as a gravure roll type treatment method using ink on the surface.
그러나 이러한 방식의 타포린 제품은 일정시간이 경과하게 되면 무늬가 쉽게 손상되어 보기 흉하게 되고 이에 따라 장기간 옥외 사용시 불편한 문제점이 있었다.However, this type of tarpaulin product is easily damaged after a certain period of time the pattern is unsightly, there was a problem inconvenient when using outdoor for a long time.
본 발명은 상기한 바와 같은 종래 기술에서의 문제점을 해결하고자 한 것으로, 종래 타포린 제품에 비해 내구성 및 내마모성이 우수하여 장기적으로 무늬가 보존될 수 있는 PVC 배합물을 이용한 얼룩무늬 풀-커버용 타포린 및 그 제조방법을 제공함에 그 목적이 있다.The present invention is to solve the problems in the prior art as described above, stained full-cover tarpaulin using a PVC compound that can be preserved in the long-term pattern and excellent durability and wear resistance compared to conventional tarpaulin products and its The purpose is to provide a manufacturing method.
도 1 은 본 발명에 따른 PVC 배합물을 이용한 얼룩무늬 타포린 제조 공정을 구체적으로 나타낸 흐름도이다.1 is a flow chart showing in detail the process for producing a speckled tarpaulin using a PVC compound according to the present invention.
도 2 는 본 발명에 따른 얼룩무늬 타포린의 PVC 필름 제조에 필요한 카렌더 장치를 개략적으로 나타낸 도면이다.Figure 2 is a schematic view showing a calender apparatus required for the production of PVC film of the mottled tarpaulin according to the present invention.
도 3 은 본 발명에 따른 폴리에스터 직물을 PVC 페이스트 수지로 스크린 코팅하는 제조 공정에 사용되는 스크린 코팅장치를 개략적으로 나타낸 도면이다.3 is a view schematically showing a screen coating apparatus used in the manufacturing process of screen coating a polyester fabric with PVC paste resin according to the present invention.
도 4 는 본 발명에 따른 얼룩무늬 타포린 라미네이트 제조 공정에 사용되는 라미네이트 장치를 개략적으로 나타낸 도면이다.Figure 4 is a schematic view showing a laminate apparatus used in the process of producing a speckled tarpaulin laminate according to the present invention.
도 5 는 본 발명에 따른 얼룩무늬 타포린 표면 액상코팅을 위한 공정을 개략적으로 나타낸 도면이다.Figure 5 is a view schematically showing a process for the liquid-coated tarpaulin surface coating according to the present invention.
* 도면의 주요 부분에 대한 부호의 설명** Explanation of symbols for main parts of the drawing
10: 믹서기 12: 반바리 믹서기10: blender 12: shorty blender
16: 카렌더 장치 30: 코팅장치16: calendar apparatus 30: coating apparatus
72: 히팅 드럼 84: 메쉬 롤72: heating drum 84: mesh roll
상기한 바와 같은 목적을 달성하기 위한 본 발명의 바람직한 실시예에 따르면, PVC 얼룩무늬 타포린 제조에 있어서,According to a preferred embodiment of the present invention for achieving the object as described above, in the production of PVC speckled tarpaulin,
배합 구성이 PVC 수지 100 중량%, 프탈레이트 가소제 40∼65중량%, 무기물 10∼40 중량%, 바륨-징크 타입의 복합 액상안정제 2∼4량%, 자외선 안정제 0.5∼0.8중량%의 원료를 배합(혼합)하고, 시아닌 블루 마스터배치 안료 첨가된 배합물과 티탄 화이트 안료 첨가된 배합을 반바리 믹서에 혼련하고, 혼련된 각각(블루 배합물과 화이트 배합물)의 배합물을 카렌더라인에 공급하여 시트를 제작하고, 라미네이트 합판기에 상부층 PVC 필름, 중지층 페이스트 수지를 코팅된 직물, 하지층 PVC 필름을 합판하여 타포린 제품을 가공하고, 다시 가공된 타포린 제품을 아크릴 수지로 된 액상타입으로 타포린 표면층에 코팅하는 완성된 것을 특징으로 하는 PVC 배합물을 이용한 얼룩무늬 풀 커버 타포린 제조방법이 제공된다.The composition is composed of 100% by weight of PVC resin, 40 to 65% by weight of phthalate plasticizer, 10 to 40% by weight of inorganic substance, 2 to 4% by weight of barium-zinc-type complex liquid stabilizer, and 0.5 to 0.8% by weight of UV stabilizer. And cyanine blue masterbatch pigmented blend and titanium white pigment blended blend in a half-barrier mixer, and each blended blend (blue blend and white blend) is fed to the calender line to produce a sheet. Finishing the tarpaulin product by laminating the upper layer PVC film, the middle layer paste resin coated fabric and the base layer PVC film on the laminate plywood, and then applying the processed tarpaulin product to the tarpaulin surface layer in the liquid type of acrylic resin. Provided is a method for producing a speckled full cover tarpaulin using a PVC blend.
바람직하게는, 제품의 구조가 상부층을 아크릴 수지를 이용하여 코팅을 하고, 중지 1층은 pvc 필름 얼룩무늬, 중지 2층은 폴리에스터 코팅직물, 하지 층은 pvc 필름의 3층 구조로 된 것을 특징으로 한다.Preferably, the structure of the product is the upper layer is coated with acrylic resin, the middle layer of the first layer is pvc film speckle, the middle layer of the polyester coating fabric, the lower layer is a three-layer structure of pvc film It is done.
또한 바람직하게는, 가공된 타포린 제품 원료 구성이 PVC 수지 100 중량%, 프탈레이트 가소제 40∼65중량%, 무기물 10∼40 중량%, 바륨-징크 타입의 복합 액상안정제 2∼4 중량%, 자외선 안정제 0.5∼0.8중량%, 티탄 화이트 안료 5∼25 중량%, 시아닌 블루 안료 3∼25중량%로 혼합한 것을 특징으로 한다.Also preferably, the processed tarpaulin product raw material composition is 100% by weight of the PVC resin, 40 to 65% by weight of the phthalate plasticizer, 10 to 40% by weight of the inorganic material, 2 to 4% by weight of the composite liquid stabilizer of barium-zinc type, UV stabilizer 0.5 It is characterized by mixing at -0.8 weight%, titanium white pigment 5-25 weight%, and cyanine blue pigment 3-25 weight%.
이하 본 발명에 따른 PVC 배합물을 이용한 얼룩무늬 풀-커버 타포린 및 그 제조방법에 대하여 첨부도면을 참조로 상세히 설명한다.Hereinafter, a speckled full-cover tarpaulin using a PVC compound according to the present invention and a manufacturing method thereof will be described in detail with reference to the accompanying drawings.
도 1 은 본 발명에 따른 PVC 배합물을 이용한 얼룩무늬 타포린 제조 공정을 구체적으로 나타낸 흐름도이고, 도 2 는 본 발명에 따른 얼룩무늬 타포린의 PVC 필름 제조에 필요한 카렌더 장치를 개략적으로 나타낸 도면이다.1 is a flow chart showing in detail a process for producing a speckled tarpaulin using a PVC formulation according to the present invention, Figure 2 is a schematic view showing a calender apparatus required for the production of a PVC film of the speckled tarpaulin according to the present invention.
본 발명에 따른 PVC 배합물을 이용한 얼룩무늬 풀-커버 타포린 제조방법은 도 1에 도시한 바와 같이, 먼저, 원료를 혼합하는 과정(S2)이 수행된다. 상기 원료는 본 발명의 실시예에서는 배합물 1과 배합물 2의 두가지의 원료를 통한 배합과정이 진행된다. 먼저 배합물 1의 성분을 살펴보면, PVC 수지 100 중량%, 프탈레이트 가소제 40∼65중량%, 무기물 10∼40 중량%, 바륨-징크 타입의 복합 액상안정제 2∼4량%, 자외선 안정제 0.5∼0.8중량%이다.As shown in Figure 1, the method for producing a speckled full-cover tarpaulin using the PVC compound according to the present invention, first, the process of mixing the raw material (S2) is performed. In the embodiment of the present invention, the raw material is blended through two raw materials, Formula 1 and Formula 2. First, looking at the components of the formulation 1, 100% by weight of the PVC resin, 40 to 65% by weight of the phthalate plasticizer, 10 to 40% by weight of the inorganic material, 2 to 4% by weight of the complex liquid stabilizer of barium-zinc type, 0.5 to 0.8% by weight UV stabilizer to be.
또한 배합물 2의 성분을 살펴보면, 배합 2는 PVC 수지 100 중량%, 프탈레이트 가소제 40∼65중량%, 무기물 10∼40 중량%, 바륨-징크 타입의 복합 액상안정제 2∼4량%, 자외선 안정제 0.5∼0.8중량%의 원료를 배합(혼합)한다.In addition, looking at the components of Formulation 2, Formulation 2 is 100% by weight of PVC resin, 40 to 65% by weight of phthalate plasticizer, 10 to 40% by weight of inorganic material, 2 to 4% by weight of barium-zinc type complex liquid stabilizer, 0.5 to UV stabilizer 0.8 wt% of raw materials are blended (mixed).
상기 배합물 1이 배합과정을 통해 배합(혼합)되는데, 이때 믹서기(10)가 사용된다. 이후, 시아닌 블루 마스터배치 안료를 5∼25중량% 첨가하여 반바리 믹서기(12)에 130∼180도 5∼10분 혼련하는 과정이 수행된다. 이후 혼련된 배합물을 다시 2본 믹서 롤(14)에 투입후 배합물을 3∼5분 155∼165도에서 혼련한다. 이 과정이 배합물 혼련 과정이다(S4).Formulation 1 is blended (mixed) through the blending process, where a blender 10 is used. Thereafter, 5 to 25% by weight of the cyanine blue masterbatch pigment is added, and a process of kneading 130 to 180 degrees for 5 to 10 minutes is performed in the half-barrier mixer 12. Thereafter, the kneaded compound is added to the two mixer rolls 14, and the compound is kneaded at 155 to 165 degrees for 3 to 5 minutes. This process is the compound kneading process (S4).
또한 배합물 2가 배합과정을 통해 배합(혼합)되는데, 이때도 역시 믹서기(10)가 사용되고, 이후 티탄 화이트 마스터배치 5∼25중량% 첨가하여 반바리 믹서기(12)에서 배합물이 혼련된다. 이후 혼련된 배합물 2본 믹서 롤(14)에 투입후 배합물을 3∼5분 155∼165도에서 혼련한다. 이 과정은 또 다른 배합물 혼련 과정이다(S4).In addition, the compound 2 is blended (mixed) through the blending process, and in this case, the blender 10 is also used, and then the blend is kneaded in the half-barrier blender 12 by adding 5 to 25 wt% of the titanium white masterbatch. Thereafter, the mixture is kneaded into two mixer rolls 14, and then the mixture is kneaded at 155 to 165 degrees for 3 to 5 minutes. This process is another compound kneading process (S4).
상기 반바리 믹서기(Banbury mixer)(12)에 대해서 대략적으로 설명하면, 개폐식으로 재료를 혼련실에 공급한 후 위에서부터 플로팅 웨이트(도시안됨)로 하중을 걸어 재료를 누르면서 로터(도시안됨)를 다른 방향으로 회전시켜 혼련하는 장치이다.The Banbury mixer 12 is roughly described, and after supplying the material to the kneading chamber in an open and closed manner, the rotor (not shown) is loaded while pressing the material with a floating weight (not shown) from above. It is a device that rotates in the direction to knead.
상기 반바리 믹서기(12)에 투입되기전의 배합물은 분말 형태이지만, 열매유등이 그 표면에 유지되어 있는 상기 반바리 믹서기(12)내에서 약 160℃ 정도의 열이 가해지면서 녹아서 떡처럼 된다.The blend before being put into the short-barrier mixer 12 is in powder form, but heat is about 160 ° C. in the short-barrier mixer 12 in which fruit oil and the like are held on the surface thereof, and melts to form rice cakes.
한편 상기 2본 믹서 롤(14)은 두 개의 롤이 회전하면서 배합물에 열을 165℃정도로 가해서 배합물을 녹여서 혼합시키는 장치이다.On the other hand, the two mixer roll 14 is a device that melts and mixes the compound by applying heat to the compound to about 165 ℃ while rotating the two rolls.
상기 PVC 필름 제작과정을 거친 제작된 블루 및 화이트 PVC 필름은 이후 카렌더(CALENDER) 장치(16)를 통해 얼룩무늬 PVC 필름 제작과정이 수행된다(S6).The blue and white PVC film produced through the PVC film manufacturing process is then carried out a stained PVC film manufacturing process through a calender (CALENDER) device (16) (S6).
상기 카렌더 장치(16)에 대해 간단히 설명하면, 이 장치는 제품의 표면을 매끈하게 함과 동시에 광택을 내는 장치이다. 4개 정도의 주철로 만든 중공 롤러를 포개놓고 그 사이를 제품이 차례로 통과하는 동안에, 롤러 내부에서 보내진 열매유로 열과 롤러 상호간의 누르는 압력이 작용하게 되어있다. 상기 카렌더 장치(16)에서 4본의 주철로 만든 중공 롤러 내부에 약 200∼250도 온도를 유지하며 열매유가 공급되고 롤과 롤 사이의 압연을 통해 얼룩무늬 PVC 필름이 제작된다. 즉 도시되지는 않았지만, 배합과정을 통해 제작된 블루 및 화이트 PVC 필름이 상기 카렌더 장치(16)에 공급되면서 엠보 롤(17), 냉각 롤(18)을 거쳐 결국 얼룩무늬 PVC 필름이 제작 완성되고 와인더(19)에 감겨진다.Briefly, the calendar device 16 is a device that smoothes and polishes the surface of a product. While the hollow rollers made of about 4 cast irons are stacked and the products are sequentially passed between them, the heat oil and the pressing pressure between the rollers are acted on by the fruit oil sent from inside the rollers. The calender device 16 maintains a temperature of about 200 to 250 degrees inside a hollow roller made of four cast irons, is supplied with fruit oil, and a speckled PVC film is produced by rolling between rolls. That is, although not shown, the blue and white PVC film produced through the compounding process is supplied to the calender device 16, through the embossing roll 17, the cooling roll 18, and finally the stained PVC film is produced and finished wine It is wound in the 19 more.
한편, 도 3 은 본 발명에 따른 폴리에스터 직물을 PVC 페이스트 수지로 스크린 코팅하는 제조 공정에 사용되는 스크린 코팅장치를 개략적으로 나타낸 도면이고, 도 4 는 본 발명에 따른 얼룩무늬 타포린 라미네이트 제조 공정에 사용되는 라미네이트 장치를 개략적으로 나타낸 도면이고, 도 5 는 본 발명에 따른 얼룩무늬 타포린 표면 액상코팅을 위한 공정을 개략적으로 나타낸 도면이다.On the other hand, Figure 3 is a schematic view showing a screen coating apparatus used in the manufacturing process for screen coating the polyester fabric with PVC paste resin according to the present invention, Figure 4 is used in the stained tarpaulin laminate manufacturing process according to the present invention FIG. 5 is a view schematically showing a laminating device, and FIG. 5 is a view schematically showing a process for liquid-phase coating of a tartan tarpaulin surface according to the present invention.
도 3을 참고로 설명하면, 직물 코팅방식은 스크린과 스크린(SCREEN TO SCREEN) 공정으로 코팅 작업을 한다. 스크린 코팅 작업시 작업 조건은 200∼350도에서 시간은 1∼5분을 설정조건으로 한다. 작업의 순서는 폴리에스터 직물을 언와인더(20)에 걸고 PVC 페이스트 배합물을 스크린 코팅에 투입하여 스크린 장치를 통해 PVC 직물 코팅을 한다. 언와인딩된 폴리에스터 직물이 다수개의 이송장치를 거쳐 이동되면서 스크린 코팅기(22)를 거치면서 PVC 페이스트 배합물을 통해 코팅되어, 이후 IR 히터(30)를 거치면서 경화되고 이후 챔버(40)내에서 경화되어 엠보장치(50)를 거치면서 폴리에스터 직물 코팅층이 완성된 폴리에스터 직물이 다시 와인딩 장치(60)를 통해 와인딩된다. 이 과정이 도 2에 도시된 스크린 직물코팅(S8)과정이며, 이 과정을 통해 PVC 코팅된 폴리에스터 직물이 준비된다.Referring to Figure 3, the fabric coating method is the screen and the screen (SCREEN TO SCREEN) process the coating work. In the screen coating operation, the working conditions are 200 to 350 degrees and the time is 1 to 5 minutes. The sequence of operations is to hang the polyester fabric on the unwinder 20 and to apply the PVC paste formulation to the screen coating to coat the PVC fabric through the screen device. The unwinded polyester fabric is coated through a PVC paste formulation as it is passed through a plurality of transfer devices, passing through a screen coater 22, then cured through an IR heater 30 and then cured in the chamber 40. Then, the polyester fabric with the polyester fabric coating layer completed while passing through the embossing device 50 is again wound through the winding device 60. This process is a screen fabric coating (S8) process shown in Figure 2, through this process a PVC coated polyester fabric is prepared.
이후의 과정은 라미네이트 가공과정(S10)으로서, 스크린 코팅처리된 폴리에스터 직물을 언와인더(70)로부터 엠보싱(라미네이트) 장치부로 이송하고, 상기 카렌더 장치(16)에서 생산된 PVC 얼룩무늬 필름을 히팅 드럼(72)을 거치고, 이후 엠보롤(74)을 거치면서 폴리에스터 직물에 라미네이팅 된다. 상기 엠보롤(74), 냉각롤(76)을 거쳐 완성된 라미네이트 가공물이 와인더(78)에 감겨진다. 가공된 라미네이트(합판)는 상지 PVC 얼룩무늬 필름, 중지 층은 폴리에스터(POLYESTER) 직물코팅층, 하지층은 PVC 필름층으로 구성된다. 한편 상기 언와인더(70)에서 언와인딩되는 것은 PVC 얼룩무늬 필름, PVC 필름, 폴리에스터 직물코팅인 3개가 동시에 각각의 롤러를 통해 언와인딩되어 이송된다.The subsequent process is a laminating process (S10), and transfers the screen-coated polyester fabric from the unwinder 70 to the embossing (laminating) unit, and the PVC stained film produced in the calender device 16 After passing through the heating drum 72, and then through the embossing roll 74 is laminated to the polyester fabric. The finished laminate is wound on the winder 78 via the embossing roll 74 and the cooling roll 76. The processed laminate (plywood) consists of an upper PVC stained film, a middle layer of polyester fabric coating layer, and an underlying layer of PVC film layer. On the other hand, the unwinded in the unwinder 70 is three uneven winding PVC film, PVC film, polyester fabric coating is unwinded through each roller at the same time and transported.
이후, 도 5에 도시한 바와 같이, 아크릴 수지의 액상 코팅과정(S12)이 수행되는데, 상기 얼룩무늬 타포린을 언와인더(80)를 통해 언와인딩시키고 이송롤(82)을 통해 이송시켜 메쉬롤 코팅장치(84)를 통해 액상 코팅을 수행하되, 코팅조건은 70∼120도에서 1∼2분 건조를 하며, 이후 챔버(86)를 거쳐 경화시키고 엠보롤(88)을 거쳐 액상 코팅된 얼룩무늬 타포린 완제품을 가공하며 와인더(90)에 감겨진다. 이와같은 과정을 통해 얼룩무늬 타포린이 완성된다(S14).Thereafter, as shown in Figure 5, the liquid coating process (S12) of the acrylic resin is carried out, the uneven winding tarpaulin unwinding through the unwinder 80 and transported through a transfer roll 82 mesh roll Perform liquid coating through the coating device 84, the coating conditions are dried for 1 to 2 minutes at 70 to 120 degrees, then cured through the chamber 86, and the liquid coating stained through the embossing 88 Process the finished tarpaulin and is wound on the winder (90). Through this process, the speckled tarpaulin is completed (S14).
다음은 얼룩무늬 타포린 제조시 기본 원료에 대한 설명이다.The following is a description of basic raw materials for the production of speckled tarpaulin.
폴리염화비닐(polyvinyl chloride) 수지는 크게 스트레이트 수지(straight resin)와 페이스트 수지(paste resin)로 구성되어있고, 스트레이트 수지는 현탁중합(Suspension Polymerization)과 괴상중합(Bulk Polymerization)으로 제조하고, 페이스트 수지는 유화중합(Emulsion Polymerization)과 MSP(Microsuspension Seeded Polymerization)방식으로 제조한다.Polyvinyl chloride resin is mainly composed of straight resin and paste resin, the straight resin is prepared by suspension polymerization and bulk polymerization, and paste resin Is prepared by Emulsion Polymerization and MSP (Microsuspension Seeded Polymerization).
상기 페이스트 수지와 스트레이트 수지의 특징은 단가, 입자차이, 가소제 흡수 속도, 광택 및 투명성, 가공성, 전기절연성, 내구성, 제조방법에 따른 가공성의차이등이 있다.Characteristics of the paste resin and the straight resin include unit cost, particle difference, plasticizer absorption rate, gloss and transparency, processability, electrical insulation, durability, and processability difference according to the manufacturing method.
본 발명에 따른 실시예에 사용된 수지는 스트레이트 수지와 페이스트 수지를 이용하였고, PVC 스트레이트 수지는 카렌더 장치에 적용하여 얼룩무늬 필름을 제작하고, PVC 페이스트 수지는 스크린 장치에 적용하여 중지층의 직물 층에 코팅하였다. 수지의 기본적 물성은 중합도 1000∼1700, 조성은 호모폴리머(homopolymer), 비중은 1.4, 인화점 391도, 자연발화점 454도이다.The resin used in the embodiment according to the present invention used a straight resin and a paste resin, PVC straight resin is applied to the calender device to produce a speckle film, PVC paste resin is applied to the screen device fabric layer of the stop layer Coated on. The basic physical properties of the resin are polymerization degree 1000-1700, composition homopolymer, specific gravity 1.4, flash point 391 degree, spontaneous ignition point 454 degree.
프탈레이트 가소제(Phthalate Plasticizers) 사용목적은 PVC 재료에 혼합하여 유연성과 신축성, 전기절연성, 가공성을 용이하게 도와준다. 가소제의 종류는 DOP(Di-Octyl-Phthalate),DINP(Di-Isononyl-Phthalate),DIDP (Di-Isodecyl-Phthalate), DOA(Di-Octyl-Adipate) 등이 있고, 가소제의 기본적 물성은 분자량 390∼447, 비중(20/20도)0.975∼0.987, 굴절율(25도) 1.485∼1.487, 산가 0.04∼0.07이하, 색상(APHA) 30이하의 조건이다.Phthalate Plasticizers can be blended into PVC materials to facilitate flexibility, stretch, electrical insulation and processability. Types of plasticizers include DOP (Di-Octyl-Phthalate), DINP (Di-Isononyl-Phthalate), DIDP (Di-Isodecyl-Phthalate), and DOA (Di-Octyl-Adipate). It is a condition of -447, specific gravity (20/20 degree) 0.975-0.987, refractive index (25 degree) 1.485-1.487, acid value 0.04-0.07 or less, and hue (APHA) 30 or less.
바륨-징크 열안정제는 PVC는 열과 빛에너지에 매우 약하여 안정제 미 첨가시 열에 의해 PVC 분해로 염산이 발생하고 점차적으로 흑변하여 검은색으로 변한다. 이에 열안정제는 염산발생의 억제와 발생염산의 포착 가공시 열 분해를 막고 카렌더 가공성을 용이하게 만든다.Barium-Zink thermal stabilizer is very weak to heat and light energy, so that when the stabilizer is not added, hydrochloric acid is generated by the decomposition of PVC by heat and gradually turns black and turns black. Therefore, the heat stabilizer prevents the generation of hydrochloric acid and prevents thermal decomposition during the capturing processing of generated hydrochloric acid and facilitates calender processability.
도 6 에 도시한 바와 같이, 본 발명에 따른 실시예에서 완성된 얼룩무늬 타포린은 4개의 층으로 이루어진다. 즉, 최상층부터 아크릴 수지층(8), PVC 얼룩무늬 코팅층(6), 폴리에스터 직물코팅층(4) 및 PVC 필름(2)으로 구성된다. 또한 상기 상부층 아크릴 수지층(8)은 PVC 필름(2)하부에도 형성될 수 있고, 이 경우 전부 5개의 층이 형성될 것이다.As shown in FIG. 6, the finished speckled tarpaulin in the embodiment according to the present invention consists of four layers. That is, the top layer is composed of an acrylic resin layer (8), PVC stain pattern coating layer (6), polyester fabric coating layer (4) and PVC film (2). The upper acrylic resin layer 8 may also be formed under the PVC film 2, in which case all five layers will be formed.
상기한 바와 같이, 본 발명에 따른 얼룩무늬 타포린 제품은 기존의 원단과 비교시 탁월한 내마모성, 내구성을 가지며 옥외 사용시 장기적으로 무늬가 보존될 수 있다.As described above, the speckled tarpaulin product according to the present invention has excellent wear resistance and durability when compared to conventional fabrics and the pattern can be preserved in the long term when used outdoors.
상기한 바와 같이, 본 발명은 PVC 배합물(COMPOUND)을 이용하여, 시각적인 효과와 풀커버의 미관을 보다 고급화 할 수 있는 효과가 있고, 제품 제조 방법의 개발로 인한 공정의 인건비, 노무비, 재료비, 제조경비를 절감하는 효과가 있는 유용한 발명이다.As described above, the present invention has the effect of further enhancing the visual effect and aesthetics of the full cover by using a PVC compound (COMPOUND), labor costs, labor costs, material costs, It is a useful invention that has the effect of reducing manufacturing costs.
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| KR1020030011287A KR20040076000A (en) | 2003-02-24 | 2003-02-24 | Variegation design pool cover tarpaulin using pvc compound and manufacturing method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100788821B1 (en) * | 2006-07-27 | 2007-12-27 | 청도교하기공플라스틱유한공사 | Improved Tarpaulin Method |
| KR100884270B1 (en) * | 2007-08-14 | 2009-02-17 | (주)아이앤에스 | Eco-friendly FIVE foam sheet and its manufacturing method |
| KR20180135714A (en) * | 2017-06-13 | 2018-12-21 | 주식회사 서연이화 | Cargo screen synthetic leater for vehicle, method for producing same, and cargo screen for vehicle using the cargo screen synthetic leater |
| CN111231457A (en) * | 2020-01-13 | 2020-06-05 | 浙江宏泰新材料股份有限公司 | Manufacturing method of PVC (polyvinyl chloride) anti-slip heat-insulation tarpaulin |
-
2003
- 2003-02-24 KR KR1020030011287A patent/KR20040076000A/en not_active Ceased
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100788821B1 (en) * | 2006-07-27 | 2007-12-27 | 청도교하기공플라스틱유한공사 | Improved Tarpaulin Method |
| KR100884270B1 (en) * | 2007-08-14 | 2009-02-17 | (주)아이앤에스 | Eco-friendly FIVE foam sheet and its manufacturing method |
| KR20180135714A (en) * | 2017-06-13 | 2018-12-21 | 주식회사 서연이화 | Cargo screen synthetic leater for vehicle, method for producing same, and cargo screen for vehicle using the cargo screen synthetic leater |
| CN111231457A (en) * | 2020-01-13 | 2020-06-05 | 浙江宏泰新材料股份有限公司 | Manufacturing method of PVC (polyvinyl chloride) anti-slip heat-insulation tarpaulin |
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