KR20040052584A - A composition of multi-functional cement terrazzo using ceramic materials and preparation method thereof - Google Patents
A composition of multi-functional cement terrazzo using ceramic materials and preparation method thereof Download PDFInfo
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- KR20040052584A KR20040052584A KR1020040023910A KR20040023910A KR20040052584A KR 20040052584 A KR20040052584 A KR 20040052584A KR 1020040023910 A KR1020040023910 A KR 1020040023910A KR 20040023910 A KR20040023910 A KR 20040023910A KR 20040052584 A KR20040052584 A KR 20040052584A
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F15/00—Safety arrangements for slowing, redirecting or stopping errant vehicles, e.g. guard posts or bollards; Arrangements for reducing damage to roadside structures due to vehicular impact
- E01F15/003—Individual devices arranged in spaced relationship, e.g. buffer bollards
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/60—Upright bodies, e.g. marker posts or bollards; Supports for road signs
- E01F9/604—Upright bodies, e.g. marker posts or bollards; Supports for road signs specially adapted for particular signalling purposes, e.g. for indicating curves, road works or pedestrian crossings
- E01F9/608—Upright bodies, e.g. marker posts or bollards; Supports for road signs specially adapted for particular signalling purposes, e.g. for indicating curves, road works or pedestrian crossings for guiding, warning or controlling traffic, e.g. delineator posts or milestones
- E01F9/61—Special features of delineator posts, e.g. with parts cantilevered toward the roadway or fixed vertically on a tilted surface
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/60—Upright bodies, e.g. marker posts or bollards; Supports for road signs
- E01F9/604—Upright bodies, e.g. marker posts or bollards; Supports for road signs specially adapted for particular signalling purposes, e.g. for indicating curves, road works or pedestrian crossings
- E01F9/619—Upright bodies, e.g. marker posts or bollards; Supports for road signs specially adapted for particular signalling purposes, e.g. for indicating curves, road works or pedestrian crossings with reflectors; with means for keeping reflectors clean
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/60—Upright bodies, e.g. marker posts or bollards; Supports for road signs
- E01F9/623—Upright bodies, e.g. marker posts or bollards; Supports for road signs characterised by form or by structural features, e.g. for enabling displacement or deflection
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Abstract
Description
본 발명은 천연 세라믹 재료를 사용하여 건축물의 바닥에 사용되는 내마모성, 고강도, 수축에 의한 균열발생이 없는 슬립 캐스팅(slip casting)형 또는 유압 프레스 형 시멘트 테라죠의 제조에 관한 것으로서 보다 상세하게는 일반적인 시멘트 테라죠에 특수한 성분의 세라믹 재료를 일정비율 혼합 사용함으로서 음이온 및 원적외선 방사량이 우수하고 향균, 항곰팡이 성능이 우수한 기능성 시멘트 테라죠의 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the manufacture of slip casting type or hydraulic press type cement terrazzo, which is made of natural ceramic material, which is used in the floor of a building for wear resistance, high strength, and no cracking due to shrinkage. The present invention relates to a method for producing a functional cement terrazzo having excellent anion and far-infrared radiation, excellent antibacterial and anti-fungal performance by using a specific ratio of a ceramic material of a special component to cement terrazzo.
테라조는 오랜 시간 바닥의 마감에 이용되어 왔다. 그 견고성과 아름다움 그리고 관리의 편리성 등으로 인해 상업용이나 대규모 인원이 출입하는 건물에는 거의 표준으로 시공되어 왔다고 해도 과언이 아니다. 이런 테라조는 다른 건축자재와 마찬가지로 그 기술이 발달해 왔으며 자재의 개선도 뚜렷이 변화하여 왔으며, 원료의 배합 방법이나 시공 방법에 있어서도 매우 광범위하게 발달하여 왔으며 아름다움과 용도의 충족을 동시에 만족시킬 만큼 기술이 발달한 오늘날, 그 사용의 범위또한 대단히 확대되고 있다.Terrazzo has been used for floor finishing for a long time. Because of its robustness, beauty, and ease of management, it is no exaggeration to say that it has been almost standardly installed in commercial and large-scale buildings. Like other building materials, these terrazzos have developed their technology, and the improvement of materials has also been clearly changed. The terrazzo has also been developed extensively in the method of mixing raw materials and construction, and the technology is sufficient to satisfy both beauty and use. In today's development, the scope of its use is also greatly expanded.
최근, 우리 나라에서는 각종 유해물질에 노출되어 있는 인간의 생활환경을 개선하기 위하여 실내공기 정화법 등을 제정하며, 보다 낳은 친환경성 생활을 요구하게 되었다. 이는 건축물에 사용되는 여러 가지 화학물질 등에 의해 손쉽게 노출되어 있는 현재의 생활환경을 개선하기 위한 노력으로서 건강을 위한 필수 불가결한 조치이다. 건축물 등 주거공간에서의 생활환경파괴는 건축물의 여러 공정에 사용되는 각종 화학물질에 의한 것으로서, 주로 벽지의 접착제, 목재에 함유되어 있는 포름알데히드와 휘발성 유기화합물 등이 생활환경파괴의 주범이라 할 수 있다. 이러한 시대적인 요청에 의해 여러 가지 바이오 기능성 재료가 개발되고 있으나 이러한 시도는 단순히 콘크리트 구조물의 벽체에 바르는 것으로서 수 마이크로 미터 단위의 코팅만으로는 그 실효성에 대해 의문이 제기 되고 있다. 더구나 코팅된 표면 위에 다시 접착제에 의해 벽지가 도배되기 때문에 충분한 효과가 발휘되기 어렵다. 더구나 이에 사용되는 재료는 옥 광석의 분말이나 맥반석 분말을 주로 이용한 것으로서 이들이 원적외선 방사율 기능을 발휘할 수는 있으나 흡착에 의한 탈취효과는 기대하기가 어렵다.In recent years, in order to improve the living environment of human beings exposed to various harmful substances, our country has enacted indoor air purification methods and demanded more eco-friendly living. This is an indispensable measure for health as an effort to improve the current living environment that is easily exposed by various chemicals used in buildings. The destruction of the living environment in residential spaces, such as buildings, is caused by various chemicals used in various processes of the building. The main culprit behind the destruction of the living environment is the adhesive of wallpaper and formaldehyde and volatile organic compounds contained in wood. have. Many bio-functional materials have been developed at the time of this request. However, this attempt is simply applied to the walls of concrete structures, and the effectiveness of the coatings on the order of several micrometers is questioned. Moreover, since the wallpaper is wallpapered by the adhesive again on the coated surface, sufficient effect is hardly exerted. In addition, the materials used are mainly jade ore powder or elvan powder, they can exhibit the far-infrared emissivity function, but the deodorization effect by adsorption is difficult to expect.
본 발명자는 국내의 일부에서 출토되는 스코리어(scoria) 광물이 원적외선 방사율과 음이온 방출량이 우수한 것을 발견하고 이를 기능성 시멘트 테라죠에 적용하였다. 또한 스코리어는 내부에 미세한 독립기공을 함유하고 있어 흡착에 의한 탈취효과가 우수한 특성이 있으며, 광촉매의 주원료인 이산화 티탄을 중량비로 약 3%이상 함유하고 있어 악취 분해능까지 있음을 확인하였다.The present inventors have found that the scoria minerals excavated in parts of Korea are excellent in far-infrared emissivity and anion emission, and applied them to the functional cement terrazzo. In addition, the scorier contained fine independent pores inside, which had excellent deodorizing effect by adsorption, and contained about 3% or more of titanium dioxide, which is the main raw material of the photocatalyst, by weight ratio, resulting in odor resolution.
스코리어는 기생 화산지역에 분포되어 있는 광물이며 화산이 폭발할 때 분출된 여러물질 가운데 다공질의 화산암, 화산재, 화산 모래 등이 함유되어 있어 중금속의 흡착효과가 우수하여 일반적으로는 경량골재 등으로 활용되고 있다. 또한 화산분출시 함유된 여러 성분에 의해 원적외선 음이온 등의 방사량이 높은 특성을 갖고 있으며 연속적인 미세 독립기공의 확보로 인하여 기체 성분의 흡착효과가 매우 뛰어나다.Skorier is a mineral distributed in parasitic volcanic areas. Porous volcanic rocks, volcanic ash, and volcanic sand are contained among the various substances emitted when the volcano erupts. It is becoming. In addition, due to the various components contained in the volcanic eruption, it has a characteristic of high radiation rate such as far infrared anion.
본 발명자는 스코리어의 이러한 광물학적 및 화학적 흡착 특성을 적극 활용하여 건축물 바닥용 시멘트 테라죠에 활용하고자 하였으며, 다공질의 스코리어를 사용함으로 인하여 기능성을 부여하여 친환경성 시멘트 테라죠를 제조하기에 이르렀으며, 부가적으로는 스코리어를 사용하는 만큼의 경량화를 이루게 되어 건축물의 하중을 경감하게 되어 건축물 수명을 연장시킬 수 있는 다기능의 시멘트 테라죠의 발명을 완성하게 되었다.The inventors of the present invention have tried to utilize the mineral and chemical adsorption characteristics of the scorer to utilize the cement terrazzo for building floors. In addition, the weight of the building is reduced as much as the use of a scorer, thereby reducing the load of the building, and thus completing the invention of the multifunctional cement terrazzo, which can extend the life of the building.
본 발명에서와 같은 화산 분출물을 이용한 기능성 시멘트 테라죠 제조방법은 종래에 알려진바 없다.Functional cement terrazzo manufacturing method using volcanic eruptions as in the present invention is not known in the prior art.
본 발명의 목적은 시멘트를 주원료하고 각종 부원료를 혼합한 시멘트 테라죠 조성물에 화산 분출물에 의한 광물인 스코리어를 포함한 기능성 시멘트 테라죠를 제조하고, 이것을 건축물에 사용하여 탈취 등의 효과에 의하여 실내의 공기환경을 정화하고, 항균 항곰팡이 성능을 발휘하고 원적외선 및 음이온 방사량을 높여 인체에 유익한 생활환경을 제공할 수 있는 건축용 기능성 시멘트 테라죠를 제공하는 것이다.An object of the present invention is to prepare a functional cement terrazzo including a scourier, which is a mineral by volcanic eruptions, in a cement terrazzo composition comprising cement as a main raw material and various subsidiary materials, and using the same in a building to deodorize indoors. It is to provide functional cement terrazzo for building which can purify air environment, show antibacterial antifungal performance and increase far-infrared ray and negative ion radiation to provide beneficial living environment for human body.
본 발명의 목적에 따라서, 시멘트 및 종석으로 구성된 시멘트 테라죠 기본 구성물에 화산 분출물에 의해 생성된 스코리어, 광촉매 특성을 갖는 일라이트 광물, 및 시멘트의 포조란 반응을 활성화 시키는 포조란성 광물 등의 부원료를 일정량 설계의 범위로 구성되는 기능성을 갖는 시멘트 테라죠가 제공된다.According to the object of the present invention, secondary raw materials such as scoria produced by volcanic eruptions, illite minerals having photocatalytic properties, and pozzoranite minerals for activating the pozzoran reaction of cement to a cement terrazzo base constituent composed of cement and feldspar. A cement terrazzo is provided that has the functionality configured in a range of design quantities.
본 발명에 따른 기능성 시멘트 테라죠 조성은, 일반 시멘트 약 18 내지 25 중량%, 입자 크기가 구분된 백운석계 종석 65 내지 70 중량%, 스코리어 광물 3 내지 5 중량%, 일라이트 광물 2 내지 4 중량%, 포조란 3 내지 5 중량 % 로 구성된다.The functional cement terrazzo composition according to the present invention is about 18 to 25% by weight of general cement, 65 to 70% by weight of dolomite-based stones separated by particle size, 3 to 5% by weight of scoria minerals and 2 to 4% by weight of illite minerals. % And pozzoran are comprised from 3 to 5 weight%.
본 발명의 제조방법에 따라 제조된 기능성 시멘트 테라죠는 주택, 학교 등의 복도 등의 건축물 바닥에 사용되는 건축용 바닥재로서, 접착제나 방부 처리한 목재등에서 발생되는 포름 알데히드의 흡착, 분해 성능을 가지며, 원적외선 , 음이온 발생 등으로 청정한 생활환경을 제공하며, 항곰팡이 및 항균성능을 발휘한다.The functional cement terrazzo manufactured according to the manufacturing method of the present invention is a building flooring material used for building floors, such as a corridor of a house, a school, etc., and has an adsorption and decomposition performance of formaldehyde generated from adhesive or antiseptic wood. It provides a clean living environment with far-infrared rays and negative ions, and exhibits antifungal and antibacterial performance.
이하 본 발명을 하기 실시예에 의하여 더욱 상세하게 설명하고자 한다. 단, 하기 실시예는 본 발명을 예시하기 위한 것일 뿐, 본 발명의 범위가 이들만으로 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following examples. However, the following examples are only for illustrating the present invention, and the scope of the present invention is not limited thereto.
실시예Example
제조예Production Example
분말 혼합기에서 일반 시멘트 약 220 kg, 입자 크기가 조절된 백운석계 종석690 kg, 스코리어 35 kg, 일라이트 14 kg, 포조란 광물 41kg을 회전속도 분당 60회 전으로 5분간 고르게 혼합한다. 고르게 잘 혼합된 혼합물 1,000 kg에 물의 량 120 kg으로 다시 습식 혼합한 후 일정한 크기의 틀에 넣어 성형한다. 성형 후 약 6시간 상온에서 양생한 후 다시 습윤 양생함에서 60 ℃ 조건에서 6시간 양생하고, 양생이 끝난 후 상온에서 12시간 양생한다. 양생이 끝난 후 성형품을 틀에서 꺼낸 후 연마기로 표면을 연마한다.In a powder mixer, approximately 220 kg of normal cement, 690 kg of dolomite-based stones with particle size control, 35 kg of scoria, 14 kg of illite, and 41 kg of pozzolan mineral are evenly mixed for 5 minutes at 60 revolutions per minute. 1,000 kg of a well-mixed mixture is wet mixed again with 120 kg of water and put into a mold of a constant size. After curing at about 6 hours at room temperature and then cured at 60 ° C. for 6 hours in a wet curing state, and curing at room temperature after curing for 12 hours. After curing, remove the molded part from the mold and polish the surface with a grinder.
시험예 1: 본 발명의 기능성 실험Test Example 1 Functional Experiment of the Invention
제조한 기능성 시멘트 테라죠의 특성을 검토한 결과는 다음과 같다.The results of examining the properties of the manufactured functional cement terrazzo are as follows.
시료의 원적외선 방사효능과 음이온 발생효과를 표 1에 나타내었다. 본 실험은 온도 40℃에서 FT-IR 스펙트로 메터에 의해 실험하였다. 또한 표 2에 항균시험 결과를 나타내었으며, 본 측정방법은 ASTM G-21에 의해 실험하였으며, 사용 균주는 Asperillus niger ATCC 9642, penicillium pinophilum ATCC 11797, Chaetomium globosum ATCC 6205. Gliosiadium virens ATCC 9645, Aureobasium pullulans ATCC 15233 의 혼합 균주를 사용하였다. 표 3에는 탈취기능 시험을 한 결과를 나타내었으며, 시험방법은 한국건자재 시험연구원 규정인 KICM-FIR-1004에 의해 시험하였다. 대상 가스는 암모니아 가스로 하였으며, 측정은 가스 검지관에 의해 측정하였다.The far-infrared radiation efficacy and negative ion generating effect of the samples are shown in Table 1. This experiment was carried out by FT-IR spectrometer at a temperature of 40 ℃. In addition, the results of the antimicrobial test in Table 2, this measurement method was tested by ASTM G-21, the strain used was Asperillus niger ATCC 9642, penicillium pinophilum ATCC 11797, Chaetomium globosum ATCC 6205. Gliosiadium virens ATCC 9645, Aureobasium pullulans ATCC A mixed strain of 15233 was used. Table 3 shows the results of the deodorizing function test, and the test method was tested by KICM-FIR-1004, which is the Korea Construction Materials Testing Institute regulation. The object gas was made into ammonia gas, and the measurement was measured by the gas detector tube.
표 1. 본 발명의 원적외선 방사효능 및 음이온 발생 개수Table 1. Far-infrared radiation efficacy and number of anions generated by the present invention
표 2. 항곰팡이 시험 결과Table 2. Antifungal Test Results
결과 판독 : 시료에서 균의 성장을 인지할 수 없음Result reading: no growth of bacteria in the sample
표 3. 탈취 시험 결과Table 3. Deodorization Test Results
이상의 결과로 보아 본 발명의 기능성 시멘트 테라죠는 원적외선 방사율과 음이온 발생개수가 인체에 매우 유익한 물성을 나타내고 있으며, 항균 기능이 매우 우수함을 확인할 수 있었다.In view of the above results, the functional cement terrazzo of the present invention showed far-infrared emissivity and the number of anion generation very beneficial physical properties, it was confirmed that the antibacterial function is very excellent.
본 발명에 따른 기능성 시멘트 테라죠는 일반적인 시멘트계 또는 수지계 테라죠와는 달리 원적외선 방사 및 음이온 발생, 항균, 탈취 등의 바이오 기능을 갖춘 테라죠로서, 페인트 벽이나 마루판, 주택 내부의 벽지 등에서 발생될 수 있는 휘발성 유기화합물이나 곰팡이 등의 세균 제거 등의 효과를 발휘함으로서, 인체에 유익한 신진대사 촉진, 혈액 순환 원활 등의 용도를 위한 청정 생활환경용 재료로 사용될 수 있다.The functional cement terrazzo according to the present invention is a terrazzo with bio functions such as far-infrared radiation and anion generation, antibacterial and deodorization, unlike general cement-based or resin-based terrazzo, and can be generated from paint walls, floorboards, wallpaper inside houses, etc. By exerting the effect of removing bacteria such as volatile organic compounds and molds, it can be used as a material for a clean living environment for the purpose of promoting metabolism beneficial to the human body, smooth blood circulation and the like.
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