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KR20040002077A - Power Steering Hose Composition for a low pressure - Google Patents

Power Steering Hose Composition for a low pressure Download PDF

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Publication number
KR20040002077A
KR20040002077A KR1020020037436A KR20020037436A KR20040002077A KR 20040002077 A KR20040002077 A KR 20040002077A KR 1020020037436 A KR1020020037436 A KR 1020020037436A KR 20020037436 A KR20020037436 A KR 20020037436A KR 20040002077 A KR20040002077 A KR 20040002077A
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South Korea
Prior art keywords
weight
parts
rubber
carbon black
power steering
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KR1020020037436A
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Korean (ko)
Inventor
남상욱
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현대자동차주식회사
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Priority to KR1020020037436A priority Critical patent/KR20040002077A/en
Publication of KR20040002077A publication Critical patent/KR20040002077A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L11/00—Compositions of homopolymers or copolymers of chloroprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C08L15/02—Rubber derivatives containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L11/00—Hoses, i.e. flexible pipes
    • F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
    • F16L11/08—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall
    • F16L11/085—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising one or more braided layers
    • F16L11/086—Hoses, i.e. flexible pipes made of rubber or flexible plastics with reinforcements embedded in the wall comprising one or more braided layers two layers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

PURPOSE: A power steering hose composition for a low pressure is provided, to improve the heat resistance and the durability by employing a chlorinated polyethylene rubber to inner and outer side rubbers. CONSTITUTION: The hose composition comprises an inner side rubber(1) comprising a nitrile butadiene rubber; a polyethylene-based flaky fiber layer(2); and an outer side rubber(3) comprising a chloroprene rubber, wherein the inner side rubber and the outer side rubber contain the chlorinated polyethylene rubber whose Cl content is 35-40 wt% as a main component. Preferably the inner side rubber comprises 100 parts by weight of the chlorinated polyethylene rubber; 50-65 parts by weight of carbon black; 28-32 parts by weight of a process oil; 23-27 parts by weight of zinc oxide; 18-22 parts by weight of an antiaging agent; 2.5-3.5 a vulcanizing accelerator; and 0.5-0.6 parts by weight of a vulcanizing agent. Preferably the outer side rubber comprises 100 parts by weight of the chlorinated polyethylene rubber; 50-65 parts by weight of carbon black; 28-32 parts by weight of a process oil; 18-22 parts by weight of zinc oxide; 18-22 parts by weight of an antiaging agent; 2.5-3.5 a vulcanizing accelerator; and 0.5-0.6 parts by weight of a vulcanizing agent. Preferably the carbon black is the fast extrusion furnace carbon black.

Description

저압용 파워 스티어링 호스 조성물{Power Steering Hose Composition for a low pressure}Power Steering Hose Composition for a low pressure

본 발명은 저압용 파워 스티어링 호스 조성물에 관한 것으로서, 더욱 상세하게는 파워 스티어링 호스 조성물을 구성하는 내면고무 및 외면고무의 주성분으로 클로리네이티드 폴리에틸렌 러버(Chlorinated polyethylene rubber)를 사용함으로써 내열성 및 내구력이 매우 우수한 저압용 파워 스티어링 호스 조성물에 관한 것이다.The present invention relates to a low pressure power steering hose composition, and more particularly, by using chlorinated polyethylene rubber as a main component of the inner rubber and outer rubber constituting the power steering hose composition, the heat resistance and durability are very high. An excellent low pressure power steering hose composition.

파워 스티어링 호스(Power steering hose)는 자동차의 조향 장치를 위해서 사용하는 것이다. 상기 저압용 파워 스티어링 호스(Power steering hose)는 도1에 나타낸 바와 같이, 내면고무가 중심에 있고 그 위에 폴리에틸렌계 편상섬유층이 둘러싸고 있으며, 이를 외면고무가 감싸고 있는 구조로 이루어져 있다. 상기 내면고무는 주성분으로 니트릴부타디엔러버(NBR)를 사용하고, 외면 고무는 클로로프렌 러버(CR)를 주성분으로 사용하여 각각 카본블랙, 프로세스 오일 등을 포함하고 있다.Power steering hoses are used for steering devices in automobiles. The low pressure power steering hose (Power steering hose), as shown in Figure 1, the inner rubber is in the center and surrounded by a polyethylene-based flake fiber layer, it consists of a structure that surrounds the outer rubber. The inner rubber uses nitrile butadiene rubber (NBR) as a main component, and the outer rubber contains carbon black and process oil, respectively, using chloroprene rubber (CR) as a main component.

그러나, 종래 파워 스티어링 호스 조성물은 엔진 고출력화로 인한 엔진룸의 온도 상승으로 내열성에 문제가 발생하게 되어 누설문제를 초래한다.However, the conventional power steering hose composition causes a problem in heat resistance due to an increase in the temperature of the engine room due to the high engine power output, causing a leakage problem.

따라서, 최근 자동차의 엔진고출력화 추세로 엔진룸 온도 상승에 대응할 수 있는 내열성 및 내구력이 우수한 새로운 호스 조성물의 개발이 요구되고 있다.Therefore, the development of a new hose composition excellent in heat resistance and durability that can cope with the engine room temperature rise due to the recent trend of increasing engine power output of automobiles is required.

이에, 본 발명은 종래 문제점을 해결하기 위하여, 내면고무 및 외면고무의 주성분으로 클로리네이티드 폴리에틸렌 고무를 사용하여 내열성 및 내구력을 크게 향상시킨 저압용 파워 스티어링 호스 조성물을 제공하는데 그 목적이 있다.Accordingly, an object of the present invention is to provide a low pressure power steering hose composition which greatly improves heat resistance and durability by using a polyethylene rubber as a main component of the inner rubber and the outer rubber in order to solve the conventional problems.

도 1은 호스의 전체 구성도를 나타낸 것이다.Figure 1 shows the overall configuration of the hose.

[도면 주요부분에 대한 부호의 설명][Description of Symbols for Major Parts of Drawing]

1: 내면 고무2: 편상섬유층3: 외면 고무DESCRIPTION OF SYMBOLS 1: Inner rubber 2: The flaky fiber layer 3: Outer rubber

본 발명은 니트릴부타디엔러버를 주성분으로 하는 내면고무, 폴리에틸렌계 편상섬유층, 및 클로로프렌 러버를 주성분으로 하는 외면고무로 이루어진 파워 스티어링 호스 조성물에 있어서,The present invention relates to a power steering hose composition comprising an inner rubber mainly composed of nitrile butadiene rubber, a polyethylene-based fibrous layer, and an outer rubber mainly composed of chloroprene rubber,

상기 내면고무 및 외면고무는 Cl 함량이 35∼40 중량%인 클로리네이티드 폴리에틸렌 고무를 주성분으로 함유하는 저압용 파워 스티어링 호스 조성물을 그 특징으로 한다.The inner rubber and the outer rubber are characterized by a low pressure power steering hose composition containing a chlorinated polyethylene rubber having a Cl content of 35 to 40% by weight as a main component.

이하, 본 발명을 더욱 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.

본 발명은 내열성 및 내구성이 우수한 저압용 파워 스티어링 호스 조성물을 제공하는 것이다.The present invention provides a low pressure power steering hose composition having excellent heat resistance and durability.

이러한 본 발명의 호스 조성물은 내면고무, 폴리에틸렌계 편상섬유층 및 외면고무로 구성되어 있다.The hose composition of the present invention is composed of an inner rubber, a polyethylene-based fibrous layer and an outer rubber.

상기 내면고무 및 외면고무는 모두 Cl 함량이 35∼40 중량%인 클로리네이티드 폴리에틸렌 러버(Chlorinated Polyethylene Rubber)를 주성분으로 사용하는 특징이 있다. 이로써, 내열성 및 내구성을 향상시켜 자동차의 고출력으로 인한 온도 상승문제를 해결할 수 있다. 이때, 상기 Cl의 함량이 35 중량% 미만이면 내열성 (135℃)이 취약한 문제가 있고, 40 중량%를 초과하면 내열성은 우수하지만 저온 (-40℃)에서 열세를 나타낸다.The inner rubber and the outer rubber are both characterized by the use of chlorinated polyethylene rubber (Chlorinated Polyethylene Rubber) having a Cl content of 35 to 40% by weight. As a result, it is possible to improve the heat resistance and durability to solve the temperature rise problem due to the high power of the vehicle. At this time, if the Cl content is less than 35% by weight, there is a problem that the heat resistance (135 ℃) is weak, if it exceeds 40% by weight is excellent in heat resistance but low temperature (-40 ℃) is poor.

상기 내면고무는 상기 주성분으로 사용하는 클로리네이티드 폴리에틸렌 고무 외에 카본블랙, 프로세스 오일, 산화아연, 노화방지제, 가류촉진제, 및 가류제를 함유하고 있다.The inner rubber contains carbon black, process oil, zinc oxide, antioxidant, vulcanization accelerator, and vulcanizing agent in addition to the chlorinated polyethylene rubber used as the main component.

또한, 상기 외면고무 역시 상기 주성분으로 사용하는 클로리네이티드 폴리에틸렌 고무 외에 카본블랙, 프로세스 오일, 산화아연, 노화방지제, 가류촉진제, 및 가류제를 함유하고 있다.The outer rubber also contains carbon black, process oil, zinc oxide, antioxidant, vulcanization accelerator, and vulcanizing agent in addition to the chlorinated polyethylene rubber used as the main component.

상기 내면고무 및 외면고무에 사용되는 카본블랙은 보강성 및 고충진을 위해사용하며, 바람직하게는 고속 압출로(Fast Extrusion Furnace)를 사용한다. 이때 상기 카본 블랙으로 만약 종래의 카본 블랙인 세미-강화로(semi-resinforcing furnace)를 사용하면 혼합(Mixing)이 불안정하여 품질 문제가 발생한다. 상기 카본블랙의 함량은 클로리네이티드 폴리에틸렌 러버 100 중량부에 대하여 50 ∼ 65 중량부로 사용하는 것이 바람직하며, 그 함량이 50 중량부 미만이면 강도가 떨어져서 내충격성이 취약하고, 65 중량부를 초과하면 강도가 우수하여 내충격성은 유리하지만, 고무의 특성인 탄성력이 떨어져 내구력에서 균열발생 등의 기능 저하가 발생한다.The carbon black used for the inner rubber and the outer rubber is used for reinforcement and high filling, and preferably, a fast extrusion furnace is used. In this case, if the carbon black is a semi-resinforcing furnace, which is a conventional carbon black, the mixing is unstable and a quality problem occurs. The content of the carbon black is preferably used in an amount of 50 to 65 parts by weight based on 100 parts by weight of the chlorinated polyethylene rubber, and if the content is less than 50 parts by weight, the strength is poor and the impact resistance is weak. It is excellent in impact resistance, but the elastic force, which is a characteristic of rubber, is poor, resulting in functional degradation such as cracking in durability.

또한, 상기 내면고무 및 외면고무에 사용되는 프로세스 오일은 저점도 오일을 사용하는 것이 바람직하며, 그 함량은 클로리네이티드 폴리에틸렌 러버 100 중량부에 대하여 28 ∼ 32 중량부로 사용한다.In addition, the process oil used for the inner rubber and the outer rubber is preferably to use a low viscosity oil, the content is used in 28 to 32 parts by weight based on 100 parts by weight of the chlorinated polyethylene rubber.

상기 내면고무 및 외면고무에 사용되는 산화아연(ZnO)은 고무류의 물성, 특히 탄성, 영구변형율 및 내열성을 더욱 촉진시키기 위한 가교촉진제로 사용한다. 상기 산화아연(ZnO)의 함량은 클로리네이티드 폴리에틸렌 러버 100 중량부에 대하여 내면고무는 23 ∼ 27 중량부로, 외면고무는 18 ∼ 22 중량부로 사용할 수 있다.Zinc oxide (ZnO) used for the inner rubber and the outer rubber is used as a crosslinking accelerator for further promoting physical properties of rubbers, particularly elasticity, permanent strain and heat resistance. The zinc oxide (ZnO) may be used in an amount of 23 to 27 parts by weight of the inner rubber and 18 to 22 parts by weight of the outer rubber with respect to 100 parts by weight of the chlorinated polyethylene rubber.

상기 내면고무 및 외면고무에 사용되는 노화방지제는 주성분으로 사용하는 고분자외에 내열성을 향상시키기 위해 사용한다. 상기 노화방지제로는 2-하이드로(2D)를 사용할 수 있으며, 그 함량은 클로리네이티드 폴리에틸렌 러버 100 중량부에 대하여 18∼22 중량부로 사용한다. 상기 노화방지제의 함량이 18 중량부 미만이면 내열성이 불리해지고, 22 중량부를 초과하면 내열성은 우수하지만 저온 및 장기 내구력이 불리하다.The anti-aging agent used for the inner rubber and the outer rubber is used to improve heat resistance in addition to the polymer used as the main component. As the anti-aging agent, 2-hydro (2D) may be used, and the content thereof is used in an amount of 18 to 22 parts by weight based on 100 parts by weight of the chlorinated polyethylene rubber. If the content of the anti-aging agent is less than 18 parts by weight, the heat resistance is disadvantageous, if it exceeds 22 parts by weight, the heat resistance is excellent but low temperature and long-term durability is disadvantageous.

상기 내면고무 및 외면고무에 사용되는 가류촉진제는 고무의 경화속도를 조절하기 위해 사용한다. 상기 가류촉진제로는 테트라-디하이드로(TD)를 사용할 수 있으며, 그 함량은 클로리네이티드 폴리에틸렌 러버 100 중량부에 대하여 2.5 ∼ 3.5 중량부로 사용할 수 있다.The vulcanization accelerator used for the inner rubber and the outer rubber is used to control the curing rate of the rubber. Tetra-dihydro (TD) may be used as the vulcanization accelerator, and the content thereof may be 2.5 to 3.5 parts by weight based on 100 parts by weight of the cloned polyethylene rubber.

상기 내면고무 및 외면고무에 사용되는 가류제는 경화성 향상을 위해 사용한다. 상기 가류제로는 SO4를 사용할 수 있으며, 그 함량은 클로리네이티드 폴리에틸렌 러버 100 중량부에 대하여 0.5 ∼ 0.6 중량부로 사용한다.The vulcanizing agent used for the inner rubber and the outer rubber is used to improve the hardenability. SO 4 may be used as the vulcanizing agent, and the content thereof may be used in an amount of 0.5 to 0.6 parts by weight based on 100 parts by weight of the cloned polyethylene rubber.

그밖에, 통상의 파워 스티어링 호스 조성물에 사용될 수 있는 첨가제를 필요에 따라 선택하여 사용할 수 있다.In addition, additives that can be used in conventional power steering hose compositions can be selected and used as necessary.

이와 같이, 본 발명의 호스 조성물은 내면고무 및 외면고무의 주성분으로 Cl이 특정량 함유된 클로리네이티드 폴리에틸렌 러버를 사용함으로써 내열성 및 내구성을 크게 향상시켜 자동차의 엔진에 적용시 온도상승을 방지하여 비용절감을 꾀할 수 있다.As described above, the hose composition of the present invention uses a cloned polyethylene rubber containing Cl as a main component of the inner rubber and the outer rubber, thereby greatly improving heat resistance and durability, thereby preventing a temperature increase when applied to an engine of a vehicle. Savings can be made.

이하, 본 발명을 다음의 실시예 및 비교예를 통하여 상세히 설명하겠는바, 본 발명이 이들에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to the following examples and comparative examples, but the present invention is not limited thereto.

실시예 및 비교예Examples and Comparative Examples

다음 표 1과 같은 조성과 함량으로 저압용 파워 스티어링 호스 조성물을 제조하였다.To prepare a low pressure power steering hose composition in the composition and content as shown in Table 1.

상기 실시예 및 비교예의 호스 조성물에 대한 물성을 다음과 같은 방법으로 측정하여 그 결과를 다음 표 2에 나타내었다.Physical properties of the hose compositions of the Examples and Comparative Examples were measured by the following method, and the results are shown in Table 2 below.

<경도> : JIS 규격인 JIS K 6301의 5.2.3항에 따름.<Hardness>: According to JIS K 6301 which is a JIS standard.

<인장강도> : JIS 규격인 JIS K 6301의 3.4항에 따름.<Tensile strength>: According to JIS 3.4 of JIS K 6301 which is JIS standard.

<신율> : JIS 규격인 JIS K 6301의 3.4항에 따름.<Elongation>: According to JIS 3.4 of JIS K 6301 which is a JIS standard.

<내열성> : JIS 규격인 JIS K 6301의 6.6.3항에 따름.<Heat resistance>: According to JIS K 6301 which is a JIS standard.

<내압성> : 매분 1700 ±700 kgf/㎠의 압력을 3분간 호스에 가압하여 HOSE에서 물이 새는 시점에서의 압력을 측정한다.<Pressure Resistance>: A pressure of 1700 ± 700 kgf / cm2 per minute is applied to the hose for 3 minutes and the pressure at the time of leaking water from the hose is measured.

<임펄스 평가> : 135℃의 분위기 온도에서 (작동유 온도 : 150℃) 1초동안 0 ↔15 kgf/㎠의 압력을 가해 진동폭은 ±25 mm, 단위시간당 진동회수는 1.16 Hz로 하여 몇회에서 새는 지를 평가함.<Impulse evaluation>: The pressure of 0 ↔ 15 kgf / ㎠ for 1 second at the ambient temperature of 135 ℃ (working oil temperature: 150 ℃), the vibration width is ± 25 mm and the frequency of vibration is 1.16 Hz. Evaluated.

상기 표 2의 결과에서 알 수 있듯이, 본 발명의 호스 조성물은 종래 비교예의 호스 조성물에 비하여 크랙이 발생하지 않고, 누수 발생이 없어 내열성 및 내구성이 우수하였다.As can be seen from the results of Table 2, the hose composition of the present invention was excellent in heat resistance and durability because there was no cracking and no leakage occurred compared to the hose composition of the conventional comparative example.

이상에서 설명한 바와 같이, 본 발명의 저압용 파워 스티어링 호스 조성물은 내면고무 및 외면고무의 주성분으로 클로리네이티드 폴리에틸렌 러버(Chlorinated polyethylene rubber)를 사용함으로써 내열성 및 저온에서의 내구성이 매우 우수하여 자동차 엔진에 적용하기에 매우 효과적이다.As described above, the low-pressure power steering hose composition of the present invention is used as a main component of the inner rubber and the outer rubber by using chlorinated polyethylene rubber (Chlorinated polyethylene rubber) is excellent in heat resistance and low temperature durability in the automotive engine Very effective to apply.

Claims (4)

니트릴부타디엔러버를 주성분으로 하는 내면고무, 폴리에틸렌계 편상섬유층, 및 클로로프렌 러버를 주성분으로 하는 외면고무로 이루어진 파워 스티어링 호스 조성물에 있어서,In a power steering hose composition comprising an inner rubber mainly composed of nitrile butadiene rubber, a polyethylene-based fibrous layer, and an outer rubber mainly composed of chloroprene rubber, 상기 내면고무 및 외면고무는 Cl 함량이 35∼40 중량%인 클로리네이티드 폴리에틸렌 고무를 주성분으로 함유하는 것을 특징으로 하는 저압용 파워 스티어링 호스 조성물.The inner rubber and the outer rubber is a low pressure power steering hose composition, characterized in that it contains a chlorinated polyethylene rubber having a Cl content of 35 to 40% by weight. 제 1 항에 있어서, 상기 내면고무는 클로리네이티드 폴리에틸렌 고무 100 중량부에 대하여 카본블랙 50 ∼ 65 중량부, 프로세스 오일 28 ∼ 32 중량부, 산화아연 내면고무 23 ∼ 27 중량부, 노화방지제 18 ∼ 22 중량부, 가류촉진제 2.5 ∼ 3.5 중량부, 및 가류제 0.5 ∼ 0.6 중량부가 함유된 것을 특징으로 하는 저압용 파워 스티어링 호스 조성물.The inner rubber according to claim 1, wherein the inner rubber is 50 to 65 parts by weight of carbon black, 28 to 32 parts by weight of process oil, 23 to 27 parts by weight of zinc oxide inner rubber, and 18 to 18 parts by weight of 100 parts by weight of chlorinated polyethylene rubber. A low pressure power steering hose composition comprising 22 parts by weight, 2.5 to 3.5 parts by weight of vulcanization accelerator, and 0.5 to 0.6 parts by weight of vulcanizing agent. 제 1 항에 있어서, 상기 외면고무는 클로리네이티드 폴리에틸렌 고무 100 중량부에 대하여 카본블랙 50 ∼ 65 중량부, 프로세스 오일 28 ∼ 32 중량부, 산화아연 18 ∼ 22 중량부, 노화방지제 18 ∼ 22 중량부, 가류촉진제 2.5 ∼ 3.5 중량부,및 가류제 0.5 ∼ 0.6 중량부가 함유된 것을 특징으로 하는 저압용 파워 스티어링 호스 조성물.According to claim 1, wherein the outer rubber is 50 to 65 parts by weight of carbon black, 28 to 32 parts by weight of process oil, 18 to 22 parts by weight of zinc oxide, 18 to 22 parts by weight of antioxidant based on 100 parts by weight of chlorinated polyethylene rubber And, 2.5 to 3.5 parts by weight of vulcanization accelerator, and 0.5 to 0.6 parts by weight of vulcanizing agent. 제 2 항 또는 제 3 항에 있어서, 상기 카본블랙은 고속 압출로(Fast Extrusion Furnace) 카본블랙인 것을 특징으로 하는 저압용 파워 스티어링 호스 조성물.4. The low pressure power steering hose composition according to claim 2 or 3, wherein the carbon black is fast extrusion furnace carbon black.
KR1020020037436A 2002-06-29 2002-06-29 Power Steering Hose Composition for a low pressure KR20040002077A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100644339B1 (en) * 2004-05-28 2006-11-10 엘에스전선 주식회사 Automotive rubber hose
KR20160081158A (en) 2014-12-31 2016-07-08 홍천군 Cosmetic moisturizer with the radish leaves and manufacturing method its

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0280880A (en) * 1988-09-17 1990-03-20 Yokohama Rubber Co Ltd:The Low-permeability hose
JPH0753819A (en) * 1993-08-10 1995-02-28 Mitsubishi Chem Mkv Co Vinyl chloride resin-based elastomer composition
US5446064A (en) * 1993-03-30 1995-08-29 Mitsubishi Chemical Mkv Company Thermoplastic elastomer composition
JPH10143164A (en) * 1996-11-07 1998-05-29 Cci Corp Sound absorbing sheet
KR20000060113A (en) * 1999-03-12 2000-10-16 권문구 Rubber Compostion

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0280880A (en) * 1988-09-17 1990-03-20 Yokohama Rubber Co Ltd:The Low-permeability hose
US5446064A (en) * 1993-03-30 1995-08-29 Mitsubishi Chemical Mkv Company Thermoplastic elastomer composition
JPH0753819A (en) * 1993-08-10 1995-02-28 Mitsubishi Chem Mkv Co Vinyl chloride resin-based elastomer composition
JPH10143164A (en) * 1996-11-07 1998-05-29 Cci Corp Sound absorbing sheet
KR20000060113A (en) * 1999-03-12 2000-10-16 권문구 Rubber Compostion

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100644339B1 (en) * 2004-05-28 2006-11-10 엘에스전선 주식회사 Automotive rubber hose
KR20160081158A (en) 2014-12-31 2016-07-08 홍천군 Cosmetic moisturizer with the radish leaves and manufacturing method its

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