KR102665115B1 - Sheet type laundry detergent manufacturing method - Google Patents
Sheet type laundry detergent manufacturing method Download PDFInfo
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- KR102665115B1 KR102665115B1 KR1020230087794A KR20230087794A KR102665115B1 KR 102665115 B1 KR102665115 B1 KR 102665115B1 KR 1020230087794 A KR1020230087794 A KR 1020230087794A KR 20230087794 A KR20230087794 A KR 20230087794A KR 102665115 B1 KR102665115 B1 KR 102665115B1
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- laundry detergent
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- 239000003599 detergent Substances 0.000 title claims abstract description 94
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000004744 fabric Substances 0.000 claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- 238000001035 drying Methods 0.000 claims abstract description 25
- 238000005187 foaming Methods 0.000 claims abstract description 25
- 239000008213 purified water Substances 0.000 claims abstract description 20
- 229920002472 Starch Polymers 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 235000019698 starch Nutrition 0.000 claims abstract description 13
- 239000008107 starch Substances 0.000 claims abstract description 13
- 230000032683 aging Effects 0.000 claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 238000010030 laminating Methods 0.000 claims abstract description 5
- 238000005507 spraying Methods 0.000 claims abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 16
- 239000003945 anionic surfactant Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 12
- 239000000284 extract Substances 0.000 claims description 10
- 239000001509 sodium citrate Substances 0.000 claims description 8
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 8
- 102000004190 Enzymes Human genes 0.000 claims description 7
- 108090000790 Enzymes Proteins 0.000 claims description 7
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 238000003475 lamination Methods 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 238000007127 saponification reaction Methods 0.000 claims description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 6
- 239000004299 sodium benzoate Substances 0.000 claims description 6
- 235000010234 sodium benzoate Nutrition 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 5
- 230000035800 maturation Effects 0.000 claims description 5
- 239000000344 soap Substances 0.000 claims description 5
- 229920000858 Cyclodextrin Polymers 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 3
- 238000006460 hydrolysis reaction Methods 0.000 claims description 3
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 3
- 101001136034 Homo sapiens Phosphoribosylformylglycinamidine synthase Proteins 0.000 claims description 2
- 150000005857 PFAS Chemical class 0.000 claims description 2
- 102100036473 Phosphoribosylformylglycinamidine synthase Human genes 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 230000005070 ripening Effects 0.000 claims description 2
- 230000007774 longterm Effects 0.000 claims 1
- 238000003860 storage Methods 0.000 claims 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 21
- 229920002451 polyvinyl alcohol Polymers 0.000 description 21
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 15
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 15
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 15
- 238000003912 environmental pollution Methods 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 235000019645 odor Nutrition 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 201000004384 Alopecia Diseases 0.000 description 1
- 206010003645 Atopy Diseases 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 231100000507 endocrine disrupting Toxicity 0.000 description 1
- 208000024963 hair loss Diseases 0.000 description 1
- 230000003676 hair loss Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명의 일 실시예에 따른 시트형 세탁세제 제조방법은 정제수에 PVA, PVP, 전분 및 계면활성제를 포함하여 제조되는 세탁세제조성물을 Aging room에서 숙성하는 숙성단계, 상기 숙성단계를 거친 상기 세탁세제조성물의 밀도는 0.1 내지 0.9g/, 점도는 25,000 내지 55,000cps가 되도록 발포기를 이용하여 발포하는 발포단계, 상기 발포단계를 거쳐 발포된 상기 세탁세제조성물을 콤마코팅기의 코팅액 함에 담고 이형필름에 일정한 두께로 도포하는 도포단계, 상기 도포단계를 거친 상기 이형필름과 상기 세탁세제조성물을 건조기에 넣어 상기 정제수만을 건조시켜 상기 이형필름에 도포된 상기 세탁세제조성물을 원단화하는 건조단계, 상기 건조단계를 거쳐 원단 형태로 유지되고 상기 정제수가 제거된 상기 세탁세제조성물을 상기 이형필름으로부터 박리하는 박리단계 및 상기 박리단계를 거쳐 원단 형태가 된 상기 세탁세제조성물에 물을 안개분사하여 1~10개 겹친 후, 상기 건조기에 넣어 복수개의 원단형태 세탁세제조성물을 합지하는 합지단계를 포함할 수 있다.A method for manufacturing a sheet-type laundry detergent according to an embodiment of the present invention includes an aging step of maturing a laundry detergent composition prepared by containing PVA, PVP, starch and a surfactant in purified water in an aging room, and the laundry detergent composition that has undergone the aging step. The density is 0.1 to 0.9g/ , a foaming step of foaming using a foaming machine so that the viscosity is 25,000 to 55,000 cps, an application step of placing the laundry detergent composition foamed through the foaming step into a coating liquid box of a comma coating machine and applying it to a release film at a constant thickness, the application step. A drying step of converting the laundry detergent composition applied to the release film into fabric by putting the release film and the laundry detergent composition in a dryer and drying only the purified water. Through the drying step, the laundry detergent composition is maintained in the form of fabric and the purified water is removed. A peeling step of peeling the laundry detergent composition from the release film, spraying water on the laundry detergent composition in the form of fabric through the peeling step, stacking 1 to 10 layers, and then placing them in the dryer to wash a plurality of fabrics. It may include a laminating step of laminating the detergent composition.
Description
본 발명은 시트형 세탁세제 제조방법에 관한 것이다.The present invention relates to a method for manufacturing sheet-type laundry detergent.
일반적으로, 세탁기에 넣어 사용하는 세제로는 분말 세제 또는 액상 세제가 사용되어왔다. In general, powder detergents or liquid detergents have been used as detergents used in washing machines.
다만, 액상 세제의 경우 상대적으로 무거워 소비자가 사용을 꺼리는 단점이 있으며, 분말 세제의 경우 사용 시 분말이 날리고 세탁 후 잔여물이 남는 현상이 발생하여 새로운 타입의 세제에 대한 필요성이 끊임없이 제기되어 왔다.However, liquid detergents have the disadvantage that consumers are reluctant to use them because they are relatively heavy, and in the case of powder detergents, powder flies when used and residues remain after washing, so the need for new types of detergents has been constantly raised.
종래의 세제를 개량하여 새로운 세탁용 시트인 시트형 고형 세제가 개발되었으나 알칼리성을 띄어 피부에 대한 자극과 손상을 초래한다는 문제점이 있고, 시트 자체의 용해성이 충분하지 않다는 문제점이 있었다. A new laundry sheet, a sheet-type solid detergent, was developed by improving the conventional detergent, but there was a problem that it was alkaline, causing irritation and damage to the skin, and the solubility of the sheet itself was insufficient.
상기와 같은 기술적 배경으로 안출 된 것으로 본 발명은 세척성이 우수하고 용해성이 우수하고 보관과 사용이 간편한 시트형 세탁세제 제조방법을 제공하고자 한다.The present invention, which was conceived with the above technical background, seeks to provide a method for manufacturing a sheet-type laundry detergent that has excellent cleaning properties, excellent solubility, and is easy to store and use.
본 발명의 일 실시예에 따른 시트형 세탁세제 제조방법은 정제수에 PVA, PVP, 전분 및 계면활성제를 포함하여 제조되는 세탁세제조성물을 Aging room에서 숙성하는 숙성단계, 상기 숙성단계를 거친 상기 세탁세제조성물의 밀도는 0.1 내지 0.9g/, 점도는 25,000 내지 55,000cps가 되도록 발포기를 이용하여 발포하는 발포단계, 상기 발포단계를 거쳐 발포된 상기 세탁세제조성물을 콤마코팅기의 코팅액 함에 담고 이형필름에 일정한 두께로 도포하는 도포단계, 상기 도포단계를 거친 상기 이형필름과 상기 세탁세제조성물을 건조기에 넣어 상기 정제수만을 건조시켜 상기 이형필름에 도포된 상기 세탁세제조성물을 원단화하는 건조단계, 상기 건조단계를 거쳐 원단 형태로 유지되고 상기 정제수가 제거된 상기 세탁세제조성물을 상기 이형필름으로부터 박리하는 박리단계 및 상기 박리단계를 거쳐 원단 형태가 된 상기 세탁세제조성물에 물을 안개분사하여 1~10개 겹친 후, 상기 건조기에 넣어 복수개의 원단형태 세탁세제조성물을 합지하는 합지단계를 포함할 수 있다.A method for manufacturing a sheet-type laundry detergent according to an embodiment of the present invention includes an aging step of maturing a laundry detergent composition prepared by containing PVA, PVP, starch and a surfactant in purified water in an aging room, and the laundry detergent composition that has undergone the aging step. The density is 0.1 to 0.9g/ , a foaming step of foaming using a foaming machine so that the viscosity is 25,000 to 55,000 cps, an application step of placing the laundry detergent composition foamed through the foaming step into a coating liquid box of a comma coating machine and applying it to a release film at a constant thickness, the application step. A drying step of converting the laundry detergent composition applied to the release film into fabric by putting the release film and the laundry detergent composition in a dryer and drying only the purified water. Through the drying step, the laundry detergent composition is maintained in the form of fabric and the purified water is removed. A peeling step of peeling the laundry detergent composition from the release film, spraying water on the laundry detergent composition in the form of fabric through the peeling step, stacking 1 to 10 layers, and then placing them in the dryer to wash a plurality of fabrics. It may include a laminating step of laminating the detergent composition.
상기 세탁세제조성물은 전체 중량 대비, 상기 PVA는 7 내지 17 중량%, 상기 PVP는 2 내지 8 중량% 및 상기 전분은 2 내지 8 중량%를 포함할 수 있다.The laundry detergent composition may contain 7 to 17% by weight of PVA, 2 to 8% by weight of PVP, and 2 to 8% by weight of starch, based on the total weight.
상기 계면활성제는 음이온계면활성제인 AOS-1416가 40~60 중량%, 음이온계면활성제인 PCG가 2~8 중량% 및 비이온계면활성제인 APG가 6~14 중량%를 포함할 수 있다.The surfactant may include 40 to 60% by weight of AOS-1416, an anionic surfactant, 2 to 8% by weight of PCG, an anionic surfactant, and 6 to 14% by weight of APG, a nonionic surfactant.
안식향산소다 0.1 내지 0.6중량%, 구연산소다 0.3 내지 1.5 중량%, 구연산 0.3 내지 1.5 중량% 및 소금 1 내지 6 중량%을 더 포함할 수 있다.It may further include 0.1 to 0.6% by weight of sodium benzoate, 0.3 to 1.5% by weight of sodium citrate, 0.3 to 1.5% by weight of citric acid, and 1 to 6% by weight of salt.
천연비누성분 0.3 내지 3 중량%, 실크추출물 0.3 내지 3 중량%, 싸이크로 덱스트린 0.5 내지 6 중량% 및 복수개의 효소 0.5 내지 6 중량%을 더 포함할 수 있다.It may further include 0.3 to 3% by weight of natural soap ingredients, 0.3 to 3% by weight of silk extract, 0.5 to 6% by weight of cyclodextrin, and 0.5 to 6% by weight of a plurality of enzymes.
상기 숙성단계는 상기 세탁세제조성물을 2 내지 50시간, 25 내지 70도로 숙성할 수 있다.In the maturing step, the laundry detergent composition may be aged at 25 to 70 degrees for 2 to 50 hours.
상기 도포단계는 0.3 내지 3.8mm 두께로 도포할 수 있다.The application step can be applied to a thickness of 0.3 to 3.8 mm.
상기 건조단계는 상기 건조기 온도는 40 내지 210도, 건조 속도는 0.3 내지 6m/min로 설정하여 정제수를 건조시킬 수 있다.In the drying step, purified water can be dried by setting the dryer temperature to 40 to 210 degrees and the drying speed to 0.3 to 6 m/min.
상기 박리단계는 박리된 상기 원단은 두께 0.3 내지 3.8mm, 밀도 0.03 내지 0.35g/일 수 있다.In the peeling step, the peeled fabric has a thickness of 0.3 to 3.8 mm and a density of 0.03 to 0.35 g/ It can be.
상기 합지단계는 상기 건조기는 50 내지 130도일 수 있다.The lamination step may be performed at 50 to 130 degrees in the dryer.
본 발명의 일 실시예에 따른 시트형 세탁세제 제조방법은 세착성이 우수하고 용해성이 우수하고 보관과 사용이 간편할 수 있다.The method for manufacturing a sheet-type laundry detergent according to an embodiment of the present invention has excellent adhesion and solubility, and can be easy to store and use.
도 1은 본 발명의 일 실시예에 따른 시트형 세탁세제 제조방법의 순서도이다.
도 2는 본 발명이 일 실시예에 따른 시트형 세탁세제의 사시도이다.1 is a flowchart of a method for manufacturing a sheet-type laundry detergent according to an embodiment of the present invention.
Figure 2 is a perspective view of a sheet-type laundry detergent according to an embodiment of the present invention.
이하, 첨부한 도면을 참고로 하여 본 발명의 실시예에 대하여 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 용이하게 실시할 수 있도록 상세히 설명한다. 본 발명은 여러 가지 상이한 형태로 구현될 수 있으며 여기에서 설명하는 실시예에 한정되지 않는다. 도면에서 본 발명을 명확하게 설명하기 위해서 설명과 관계없는 부분은 생략하였으며, 명세서 전체를 통하여 동일 또는 유사한 구성요소에 대해서는 동일한 참고부호를 붙였다.Hereinafter, with reference to the attached drawings, embodiments of the present invention will be described in detail so that those skilled in the art can easily implement the present invention. The present invention may be implemented in many different forms and is not limited to the embodiments described herein. In order to clearly explain the present invention in the drawings, parts not related to the description are omitted, and identical or similar components are given the same reference numerals throughout the specification.
본 명세서에서, "포함하다" 또는 "가지다" 등의 용어는 명세서상에 기재된 특징, 숫자, 단계, 동작, 구성 요소, 부품 또는 이들을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성 요소, 부분품 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다. 또한, 층, 막, 영역, 판 등의 부분이 다른 부분 "위에" 있다고 할 경우, 이는 다른 부분 "바로 위에" 있는 경우뿐만 아니라 그 중간에 또 다른 부분이 있는 경우도 포함한다. 반대로 층, 막, 영역, 판 등의 부분이 다른 부분 "아래에" 있다고 할 경우, 이는 다른 부분 "바로 아래에" 있는 경우뿐만 아니라 그 중간에 또 다른 부분이 있는 경우도 포함한다. In this specification, terms such as “comprise” or “have” are intended to designate the presence of features, numbers, steps, operations, components, parts, or combinations thereof described in the specification, but are not intended to indicate the presence of one or more other features. It should be understood that it does not exclude in advance the existence or possibility of addition of elements, numbers, steps, operations, components, parts, or combinations thereof. Additionally, when a part of a layer, membrane, region, plate, etc. is said to be “on” another part, this includes not only cases where it is “directly above” the other part, but also cases where there is another part in between. Conversely, when a part of a layer, membrane, region, plate, etc. is said to be “beneath” another part, this includes not only cases where it is “immediately below” another part, but also cases where there is another part in between.
도 1은 본 발명의 일 실시예에 따른 시트형 세탁세제의 사시도이다.Figure 1 is a perspective view of a sheet-type laundry detergent according to an embodiment of the present invention.
도 1을 참고하면, 시트형 세탁세제(1)는 정제수에 PVA(Polyvinyl Alcohol), PVP(Polyvinylpyrrolidone) 및 전분을 사용하여 제조되고, 계면활성제를 함유할 수 있다. 계면활성제는 세탁시트의 세정 활성 성분일 수 있다.Referring to Figure 1, the sheet-type laundry detergent (1) is manufactured using PVA (Polyvinyl Alcohol), PVP (Polyvinylpyrrolidone), and starch in purified water, and may contain a surfactant. Surfactants may be the cleaning active ingredients in laundry sheets.
시트형 세탁세제(1)는 전체 중량 대비, PVA는 7 내지 17 중량%, PVP는 2 내지 8 중량% 및 전분은 2 내지 8 중량%를 포함할 수 있고, 계면활성제를 함유할 수 있다. 예를 들어, 시트형 세탁세제()는 전체 중량 대비, PVA는 10중량%, PVP는 5중량%, 전분은 6중량%, 천연계면활성제인 APG와 PCG를 포함할 수 있다. Sheet-type laundry detergent (1) may contain 7 to 17% by weight of PVA, 2 to 8% by weight of PVP, and 2 to 8% by weight of starch, based on the total weight, and may contain a surfactant. For example, a sheet-type laundry detergent () may contain 10% by weight of PVA, 5% by weight of PVP, 6% by weight of starch, and natural surfactants APG and PCG, based on the total weight.
이하 본 발명의 이해를 돕기 위하여 하기의 실시예를 제시한다. 그러나, 하기의 실시예는 본 발명을 보다 쉽게 이해하기 위하여 제공되는 것일 뿐, 실시예에 의해 본 발명의 내용이 한정되는 것은 아니다.Hereinafter, the following examples are presented to aid understanding of the present invention. However, the following examples are provided only to make the present invention easier to understand, and the content of the present invention is not limited by the examples.
실시예 : 세탁용 시트 성능 시험Example: Laundry sheet performance test
<실시예 1><Example 1>
전체중량 대비, PVA는 10중량%, PVP는 5중량%, 전분은 6중량%, 천연계면활성제인 APG와 PCG를 48중량% 포함한 세탁용 시트를 제작하였다.Based on the total weight, a laundry sheet was produced containing 10% by weight of PVA, 5% by weight of PVP, 6% by weight of starch, and 48% by weight of natural surfactants APG and PCG.
<실시예 2><Example 2>
전체중량 대비, PVA는 15중량%, PVP는 5중량%, 전분은 5중량%, 천연계면활성제인 APG와 PCG를 50중량% 포함한 세탁용 시트를 제작하였다.Based on the total weight, a laundry sheet was produced containing 15% by weight of PVA, 5% by weight of PVP, 5% by weight of starch, and 50% by weight of natural surfactants APG and PCG.
<실시예 3><Example 3>
전체중량 대비, PVA는 30중량%, 전분은 5중량%, 화학적 계면활성제인 SLS(Sodium Lauryl Surface)와 SLES(Sodium Laureth Surface)의 혼합물 60중량%을 포함한 세탁용 시트를 제작하였다.Based on the total weight, a laundry sheet was manufactured containing 30% by weight of PVA, 5% by weight of starch, and 60% by weight of a mixture of chemical surfactants SLS (Sodium Lauryl Surface) and SLES (Sodium Laureth Surface).
<실험예 1><Experimental Example 1>
인장강도란 재료의 강도를 나타내는 것 중 하나로 인장강도가 '10'이상이면 시트가 단단하고 형태유지가 안정적이지만 찢기에 큰 힘이 필요하며, 인장강도가 '4~9'이면 시트가 단단하고 형태 유지가 안정적이며 사람의 힘에 의해 찢기 쉬우며, 인장강도가 '3'미만이면 시트가 단단하지 않고 형태 유지가 어려워 부서지는 상태를 의미함.Tensile strength is one of the measures of the strength of a material. If the tensile strength is over 10, the sheet is hard and its shape is stable, but a lot of force is required to tear it. If the tensile strength is 4 to 9, the sheet is hard and its shape is not strong. It is stable and easy to tear by human force. If the tensile strength is less than '3', it means that the sheet is not strong and it is difficult to maintain its shape and breaks.
<실험예 2><Experimental Example 2>
재부착 방지력이란 세탁시트(1)로 세탁을 마친 세탁물에 먼지, 오염물 등이 부착되는 것을 방지하는 것을 의미하며, 먼지가 잘 부착되지 않으면'높음', 먼지가 잘 부착되면 '낮음'임.Re-adhesion prevention means preventing dust and contaminants from attaching to laundry that has been washed with the laundry sheet (1). If dust does not adhere well, it is 'high', and if dust adheres well, it is 'low'.
상기 표 1의 작업조건은 다음과 같다.The working conditions in Table 1 above are as follows.
(1)시트의 규격: 가로10mm, 세로 10mm, 두께 0.03mm(1) Sheet specifications: width 10mm, height 10mm, thickness 0.03mm
(2) 인장강도 측정기: Frankpti사의 종이 인장강도 시험기(2) Tensile strength meter: Frankpti’s paper tensile strength tester
(3) 방법: 세탁기에 상기 세탁물과 실시예를 넣고 세탁시간 1시간, 물 높이 40cm로 설정하여 세탁기를 작동한 후, 세탁물을 말려 먼지, 오염물을 세탁물에 뿌려 보았음.(3) Method: The laundry and the examples were placed in the washing machine, the washing time was set to 1 hour, the water height was set to 40 cm, and the washing machine was operated. Then, the laundry was dried and dust and contaminants were sprinkled on the laundry.
표 1에 나타난 바와 같이, PVA를 15중량%를 초과하여 다량으로 함유하고 있고 PVP는 포함하고 있지 않은 세탁용 시트는 인장강도가 낮고 먼지가 잘 붙어 적절하지 않고 PVA가 15중량% 이하, PVP를 포함하는 세탁용 시트는 인장강도가 높고 먼지가 잘 붙지 않아 세탁용 시트로 가장 바람직하다. 보다 구체적으로는, 전체중량 대비, PVA는 10중량%, PVP는 5중량%, 전분은 6중량%, 천연계면활성제인 APG와 PCG를 48중량% 포함한 세탁용 시트가 가장 바람직할 수 있다.As shown in Table 1, laundry sheets containing a large amount of PVA exceeding 15% by weight but not PVP are not suitable as they have low tensile strength and attract dust easily. PVA is less than 15% by weight and PVP is not suitable. The included laundry sheet has high tensile strength and does not easily attract dust, so it is most desirable as a laundry sheet. More specifically, a laundry sheet containing 10% by weight of PVA, 5% by weight of PVP, 6% by weight of starch, and 48% by weight of natural surfactants APG and PCG, based on the total weight, may be most desirable.
이를 통해, 본 발명의 시트형 세탁세제()는 종래의 시트형 세제에 함유된 PVA 15 내지 30중량% 보다 적게 함유되어 있음으로써 세탁에 필요한 유효성분이 보다 많이 함유될 수 있어 세척력이 보다 향상되고 시트를 소형화시킬 수 있어 보관과 사용에 보다 편리할 수 있다. 또한, PVP를 추가하여 시트에 인장강도를 보다 강화할 수 있으며 시트의 장기간 보관 시에도 형태를 안정적으로 유지할 수 있고 시트를 뜯어 사용할 때 원하는 부위만을 찢을 수 있어서 사용에 용이할 수 있으며 재부착이 방지되어 세탁을 마친 의류, 세탁물에 먼지나 오염물이 붙는 것을 방지할 수 있다. 더해서, 천연계면활성제 사용으로 세제 사용 시 환경오염을 감소시킬 수 있다.Through this, the sheet-type laundry detergent () of the present invention contains less PVA than 15 to 30% by weight of the conventional sheet-type detergent, so it can contain more active ingredients necessary for washing, thereby improving cleaning power and miniaturizing the sheet. This makes it more convenient to store and use. In addition, the tensile strength of the sheet can be further strengthened by adding PVP, and the sheet can maintain its shape stably even when stored for a long period of time. When tearing and using the sheet, only the desired area can be torn, making it easy to use, and re-attachment is prevented. It can prevent dust or contaminants from attaching to washed clothes or laundry. In addition, the use of natural surfactants can reduce environmental pollution when using detergents.
계면활성제는 음이온계면활성제인 AOS-1416가 44~46 중량%, 음이온계면활성제인 PCG가 2~4 중량% 및 비이온계면활성제인 APG가 6~14 중량%를 포함할 수 있다. 예를 들어, 계면활성제는 전체 중량 대비, 음이온계면활성제인 AOS-1416가 45 중량%, 음이온계면활성제인 PCG가 3 중량% 및 비이온계면활성제인 APG가 12 중량%를 포함할 수 있다. The surfactant may include 44 to 46% by weight of AOS-1416, an anionic surfactant, 2 to 4% by weight of PCG, an anionic surfactant, and 6 to 14% by weight of APG, a nonionic surfactant. For example, the surfactant may include 45% by weight of AOS-1416, an anionic surfactant, 3% by weight of PCG, an anionic surfactant, and 12% by weight of APG, a nonionic surfactant, based on the total weight.
이하 본 발명의 이해를 돕기 위하여 하기의 실시예를 제시한다. 그러나, 하기의 실시예는 본 발명을 보다 쉽게 이해하기 위하여 제공되는 것일 뿐, 실시예에 의해 본 발명의 내용이 한정되는 것은 아니다.Hereinafter, the following examples are presented to aid understanding of the present invention. However, the following examples are provided only to make the present invention easier to understand, and the content of the present invention is not limited by the examples.
실시예 : 환경 오염 시험Example: Environmental pollution test
<실시예 1><Example 1>
전체중량 대비, 음이온계면활성제인 AOS-1416가 40 중량%, 음이온계면활성제인 PCG가 3 중량% 및 비이온계면활성제인 APG가 12 중량%를 포함한 천연계면활성제를 적용한 세탁시트를 제작하였다.A laundry sheet was manufactured using natural surfactants including 40% by weight of AOS-1416, an anionic surfactant, 3% by weight of PCG, an anionic surfactant, and 12% by weight of APG, a nonionic surfactant, based on the total weight.
<실시예 2><Example 2>
전체중량 대비, 음이온계면활성제인 AOS-1416가 45 중량%, 음이온계면활성제인 PCG가 3 중량% 및 비이온계면활성제인 APG가 10 중량%를 포함한 천연계면활성제를 적용한 세탁시트를 제작하였다.A laundry sheet was manufactured using natural surfactants including 45% by weight of AOS-1416, an anionic surfactant, 3% by weight of PCG, an anionic surfactant, and 10% by weight of APG, a nonionic surfactant, based on the total weight.
<실시예 3><Example 3>
전체중량 대비, SLS(Sodium Lauryl Surface)와 SLES(Sodium Laureth Surface) 혼합물 60중량%을 포함한 화학 기반 계면활성제를 적용한 세탁시트를 제작하였다.A laundry sheet was manufactured using a chemical-based surfactant containing 60% by weight of a mixture of SLS (Sodium Lauryl Surface) and SLES (Sodium Laureth Surface) based on the total weight.
<실험예 1><Experimental Example 1>
세탁물이 피부에 닿아 피부에 노출되는 발암물질인 나트로사민의 정도, 나트로사민의 정도가 높을수록 인체에 미치는 위협이 높으며 나트로사민의 정도가 낮을수록 인체에 미치는 위협이 낮음. 세탁물의 5군데를 임의로 설정하여 4군데 이상에서 나트로사민이 검출되면 '위험', 4군데 미만으로 검출되면 '경고', 1군데에만 검출되면 '양호'임.The level of natrosamine, a carcinogen exposed to the skin when laundry touches the skin. The higher the level of natrosamine, the higher the threat to the human body, and the lower the level of natrosamine, the lower the threat to the human body. Five places in the laundry are randomly set. If natrosamine is detected in four or more places, it is 'dangerous', if it is detected in less than four places, it is 'warning', and if it is detected in only one place, it is 'good'.
<실험예 2><Experimental Example 2>
세탁을 마치고 빠져나가는 세정수에서 검출된 화학적 축적물의 정도, 정도가 높을수록 환경오염에 악영향을 끼치며 정도가 낮을수록 환경오염에 영향을 끼치지 않음. 상기 세정수에 분해되지 않는 화학물질인 PFAS, Sb(안토미노) 등이 검출되면 '유해', 검출되지 않으면 '무해'임.The degree of chemical accumulation detected in the washing water discharged after washing. The higher the degree, the more adversely affects environmental pollution. The lower the degree, the less it has an effect on environmental pollution. If non-decomposing chemicals such as PFAS and Sb (anthomino) are detected in the washing water, it is 'harmful', and if not detected, it is 'harmless'.
상기 표 2의 작업조건은 다음과 같다.The working conditions in Table 2 above are as follows.
(1) 세탁물의 무게: 10kg(1) Weight of laundry: 10kg
(2) 방법: 세탁기에 상기 세탁물과 실시예를 넣고 1시간, 물 높이 40cm로 설정하여 세탁기를 작동하였음(2) Method: The above-described laundry and examples were placed in the washing machine, and the washing machine was operated for 1 hour, with the water height set to 40 cm.
표 2에 나타난 바와 같이, 화학 기반 계면활성제를 포함하고 있는 세탁용 시트는 나트로사민이 과다 검출되어 적절하지 않고, 천연계면활성제를 포함하고 있는 세탁용 시트는 나트로사민이 미세검출되고 물과 섞여 화학적 방출물을 적게 배출하여 세탁용 시트로 가장 바람직하다. 보다 구체적으로는, 전체중량 대비, 음이온계면활성제인 AOS-1416가 45 중량%, 음이온계면활성제인 PCG가 3 중량% 및 비이온계면활성제인 APG가 10 중량%를 포함한 천연계면활성제를 적용한 세탁용 시트가 가장 바람직할 수 있다.As shown in Table 2, laundry sheets containing chemical-based surfactants are not suitable due to excessive detection of natrosamine, and laundry sheets containing natural surfactants have trace amounts of natrosamine detected and are not suitable for use with water and water. It is most desirable as a laundry sheet because it mixes and emits less chemical emissions. More specifically, a laundry product using natural surfactants including 45% by weight of AOS-1416, an anionic surfactant, 3% by weight of PCG, an anionic surfactant, and 10% by weight of APG, a nonionic surfactant, based on the total weight. Sheets may be most preferred.
이를 통해, 본 발명의 세탁용 시트(1)는 환경오염을 보다 감소시킬 수 있고 화학 기반 계면활성제의 고질적인 문제였던 잠재적 발암물질 나트로사민를 해결할 수 있다. 또한, 화학적 계면활성제로 인해 옷, 침구류 등 세탁물에 남아 있는 화학제품 축적물과 화학대사산물에 피부가 노출되어 내분비계의 교란, 두피염, 탈모, 피부염, 아토피 등 유발하는 문제점을 보다 예방할 수 있으며 세탁물을 세척하는 세정수에 화학 물질이 보다 적게 유출되어 환경오염을 보다 감소시킬 수 있다.Through this, the laundry sheet (1) of the present invention can further reduce environmental pollution and solve the potential carcinogen natrosamine, which has been a chronic problem with chemical-based surfactants. In addition, chemical surfactants can help prevent problems such as endocrine disruption, scalpitis, hair loss, dermatitis, and atopy by exposing the skin to chemical product accumulation and chemical metabolites remaining in laundry such as clothes and bedding. And less chemicals are leaked into the washing water used to wash laundry, which can further reduce environmental pollution.
시트형 세탁세제(1)는 전체중량 대비, 안식향산소다 0.1 내지 0.6중량%, 구연산소다 0.3 내지 1.5 중량%, 구연산 0.3 내지 1.5 중량% 및 소금 1 내지 6 중량%을 더 포함할 수 있다.The sheet-type laundry detergent (1) may further include 0.1 to 0.6% by weight of sodium benzoate, 0.3 to 1.5% by weight of sodium citrate, 0.3 to 1.5% by weight of citric acid, and 1 to 6% by weight of salt, based on the total weight.
시트형 세탁세제(1)는 전체중량대비, 천연비누성분 0.3 내지 3 중량%, 실크추출물 0.3 내지 3 중량%, 싸이크로 덱스트린 0.5 내지 6 중량% 및 복수개의 효소 0.5 내지 6 중량%을 포함할 수 있다.Sheet-type laundry detergent (1) may contain 0.3 to 3% by weight of natural soap ingredients, 0.3 to 3% by weight of silk extract, 0.5 to 6% by weight of cyclodextrin, and 0.5 to 6% by weight of a plurality of enzymes, based on the total weight. .
이하 본 발명의 이해를 돕기 위하여 하기의 실시예를 제시한다. 그러나, 하기의 실시예는 본 발명을 보다 쉽게 이해하기 위하여 제공되는 것일 뿐, 실시예에 의해 본 발명의 내용이 한정되는 것은 아니다.Hereinafter, the following examples are presented to aid understanding of the present invention. However, the following examples are provided only to make the present invention easier to understand, and the content of the present invention is not limited by the examples.
실시예 : 세탁물의 결과Example: Results of Laundry
<실시예 1><Example 1>
전체중량 대비, 안식향산소다 0.3중량%, 구연산소다 0.7중량%, 구연산 0.7중량%, 소금 4중량%, 무환자추출물 1중량%, 실크추출물 1중량%, 싸이크론 덱스트린 3중량%, 7종효소 3중량%를 포함한 세탁용 시트를 제작하였다. Compared to the total weight, 0.3% by weight of sodium benzoate, 0.7% by weight of sodium citrate, 0.7% by weight of citric acid, 4% by weight of salt, 1% by weight of patient extract, 1% by weight of silk extract, 3% by weight of cyclone dextrin, 3% by weight of 7 types of enzymes. A laundry sheet containing was produced.
<실시예 2><Example 2>
전체중량 대비, 안식향산소다 0.3중량%, 구연산소다 0.7중량%, 구연산 0.7중량%, 소금 4중량%, 실크추출물 1중량%를 포함한 세탁시트를 제작하였다.A laundry sheet containing 0.3% by weight of sodium benzoate, 0.7% by weight of sodium citrate, 0.7% by weight of citric acid, 4% by weight of salt, and 1% by weight of silk extract was produced based on the total weight.
<실험예 1><Experimental Example 1>
복합악취란 1분동안 단위 공간 (1)당 발생하는 복합악취희석배수(OU)를 의미하며 세탁이 완료된 세탁물의 악취를 공기희석관능법으로 측정하였음. 복합악취가 20이상이면 '보통', 복합악취가 20미만이면 '양호'임.Complex odor refers to a unit space (1 minute) ) refers to the complex odor dilution factor (OU) generated per unit, and the odor of washed laundry was measured using the air dilution sensory method. If the composite odor is more than 20, it is 'average', and if the composite odor is less than 20, it is 'good'.
<실험예 2><Experimental Example 2>
세탁이 완료된 세탁물의 보풀 및 실밥의 정도를 측정하였음. 보풀 및 실밥의 정도가 세탁물 면적의 60% 이상을 차지하면 '미미', 보풀 및 실밥의 정도가 세탁물 면적의 20 이상 60% 미만을 차지하면 '보통', 보풀 및 실밥의 정도가 세탁물 면적의 20% 미만을 차지하면 '탁월'임The degree of fluff and lint in the washed laundry was measured. If the degree of fluff and lint occupies more than 60% of the laundry area, it is 'slight'; if the degree of lint and lint occupies between 20 and 60% of the laundry area, it is 'normal'; and if the degree of lint and lint occupies more than 20% of the laundry area, it is 'normal'. If it accounts for less than %, it is ‘excellent’.
상기 표 3의 작업조건은 다음과 같다.The working conditions in Table 3 above are as follows.
(1) 세탁물: 10kg(1) Laundry: 10kg
(2) 방법: 세탁기에 상기 세탁물과 실시예를 넣고 1시간, 물 높이 40cm로 설정하여 세탁기를 작동하였음(2) Method: The above-described laundry and examples were placed in the washing machine, and the washing machine was operated for 1 hour, with the water height set to 40 cm.
표 3에 나타난 바와 같이, 안식향산소다, 구연산소다, 구연산, 소금, 실크추출물로만 이루어진 세탁용 시트는 악취가 보다 제거되지 않고 보풀 제거 능력이 미미하여 적절하지 않고, 천연비누성분인 무환자 추출물과 싸이크로 덱트린 및 효소를 더 포함하는 세탁용 시트는 탈취 기능이 첨가되고 효소로 인한 보풀제거 기능, 천연비누성분으로 인한 환경오염 감소 효과가 있어 세탁용 시트로 가장 바람직하다. As shown in Table 3, laundry sheets made only of sodium benzoate, sodium citrate, citric acid, salt, and silk extract are not suitable as they do not remove bad odors and have minimal fluff removal ability. Laundry sheets that further contain trilin and enzymes are most desirable as laundry sheets because they have a deodorizing function, a fluff removal function due to enzymes, and an environmental pollution reduction effect due to natural soap ingredients.
이를 통해, 본 발명의 세탁용 시트(1)는 탈취기능이 보다 뛰어나고 효소가 첨가되어 세탁물의 보풀을 보다 효과적으로 제거할 수 있으며 천연비누성분인 무환자 추출물의 사용으로 환경오염이 보다 감소할 수 있다.Through this, the laundry sheet (1) of the present invention has a superior deodorizing function, can more effectively remove fluff from laundry due to the addition of enzymes, and can further reduce environmental pollution due to the use of lint extract, a natural soap ingredient.
상기 실시예에 의해 제조되는 가장 바람직한 세탁용 시트(1)는 다음과 같은 조성비를 가질 수 있다.The most preferred laundry sheet (1) manufactured according to the above example may have the following composition ratio.
도 2는 본 발명이 일 실시예에 따른 시트형 세탁세제 제조방법의 순서도이다.Figure 2 is a flowchart of a method for manufacturing a sheet-type laundry detergent according to an embodiment of the present invention.
도 2를 참고하면, 시트형 세탁세제 제조방법은 숙성단계(S10), 발포단계(S20), 도포단계(S30), 건조단계(S40), 박리단계(S50) 및 합지단계(S60)를 포함할 수 있다.Referring to Figure 2, the sheet-type laundry detergent manufacturing method includes a ripening step (S10), a foaming step (S20), an application step (S30), a drying step (S40), a peeling step (S50), and a lamination step (S60). You can.
숙성단계(S10)는 정제수에 PVA, PVP, 전분 및 계면활성제를 포함하여 제조되는 세탁세제조성물을 Aging room에서 숙성할 수 있다.In the aging step (S10), a laundry detergent composition prepared by containing PVA, PVP, starch, and surfactant in purified water can be aged in an aging room.
숙성단계(S10)는 세탁세제조성물을 2 내지 50시간, 25 내지 70도로 숙성할 수 있다. 예를 들어, 숙성단계(S10)는 세탁세제조성물을 25시간, 55도로 숙성할 수 있다.In the aging step (S10), the laundry detergent composition may be aged at 25 to 70 degrees for 2 to 50 hours. For example, in the maturation step (S10), the laundry detergent composition may be aged at 55 degrees for 25 hours.
세탁세제조성물은 정제수, 계면활성제, PVA, PVP 및 전분을 넣고 가온한 용액에 안삭향산소다, 구연산소다, 추출물 및 향을 혼합한 용액일 수 있다. 예를 들어, 세탁세제조성물은 정제수, 계면활성제, PVA, PVP, 옥수수전분을 혼합하여 가온한 용액에 안삭향산소다, 구연산소다, 추출물, 향을 넣고 PH를 맞춰 증점한 용액일 수 있다.The laundry detergent composition may be a solution in which purified water, surfactant, PVA, PVP, and starch are added and heated, and then sodium ansaccharide, sodium citrate, extract, and fragrance are mixed. For example, the laundry detergent composition may be a solution obtained by mixing purified water, surfactant, PVA, PVP, and corn starch, adding sodium ansaccharide, sodium citrate, extract, and fragrance to a heated solution and adjusting the pH to thicken the solution.
발포단계(S20)는 숙성단계(S10)를 거친 세탁세제조성물의 밀도는 0.1 내지 0.9g/, 점도는 25,000 내지 55,000cps가 되도록 발포기를 이용하여 발포할 수 있다.In the foaming step (S20), the density of the laundry detergent composition that has passed the maturation step (S10) is 0.1 to 0.9 g/ , the viscosity can be foamed to 25,000 to 55,000 cps using a foamer.
발포단계(S20)는 숙성단계(S10)를 거친 세탁세제조성물을 발포기에 넣어 세탁세제조성물의 밀도를 맞출 수 있다. 예를 들어, 발포단계(S20)는 숙성단계(S10)를 거쳐 숙성된 세탁세제조성물을 발포기에 넣어 밀도를 설정할 수 있다.In the foaming step (S20), the density of the laundry detergent composition can be adjusted by putting the laundry detergent composition that has undergone the maturation step (S10) into a foaming machine. For example, in the foaming step (S20), the density can be set by putting the aged laundry detergent composition through the maturation step (S10) into a foamer.
발포단계(S20)는 세탁세제조성물의 밀도를 0.1 내지 0.9g/, 점도는 25,000 내지 55,000cps로 발포할 수 있다. 예를 들어, 발포단계(S20)는 세탁세제조성물의 밀도를 0.6g/, 점도는 40,000cps일 수 있다.The foaming step (S20) increases the density of the laundry detergent composition to 0.1 to 0.9 g/ , the viscosity can be foamed at 25,000 to 55,000 cps. For example, the foaming step (S20) increases the density of the laundry detergent composition to 0.6g/ , the viscosity may be 40,000 cps.
이하 본 발명의 이해를 돕기 위하여 하기의 실시예를 제시한다. 그러나, 하기의 실시예는 본 발명을 보다 쉽게 이해하기 위하여 제공되는 것일 뿐, 실시예에 의해 본 발명의 내용이 한정되는 것은 아니다.Hereinafter, the following examples are presented to aid understanding of the present invention. However, the following examples are provided only to make the present invention easier to understand, and the content of the present invention is not limited by the examples.
실시예 : PVA의 중화도 및 검화도Example: Degree of neutralization and saponification of PVA
<실시예 1><Example 1>
발포단계에서 발포된 세탁세제조성물의 밀도가 0.6 g/, 점도가 10,000cps인 세탁용 시트를 제작하였다. The density of the foamed laundry detergent composition in the foaming step is 0.6 g/ , a laundry sheet with a viscosity of 10,000 cps was produced.
<실시예 2><Example 2>
발포단계에서 발포된 세탁세제조성물의 밀도가 0.6 g/, 점도가 40,000cps인 세탁용 시트를 제작하였다.The density of the foamed laundry detergent composition in the foaming step is 0.6 g/ , a laundry sheet with a viscosity of 40,000 cps was produced.
<실시예 3><Example 3>
발포단계에서 발포된 세탁세제조성물의 밀도가 0.6 g/, 점도가 80,000cps인 세탁용 시트를 제작하였다. The density of the foamed laundry detergent composition in the foaming step is 0.6 g/ , a laundry sheet with a viscosity of 80,000 cps was produced.
<실험예 1><Experimental Example 1>
중합도란 중합 분자내에서 일어나는 반복적인 유닛의 숫자로 본 실험예에서는 점도의 정도를 의미함. 벨트 상에 일정한 양의 세탁세제조성물을 부어 점도를 확인하였으며, 고중합도는 점도가 높고 중중합도는 점도가 적당하고 저중합도는 점도가 낮다는 의미.The degree of polymerization refers to the number of repetitive units that occur within a polymerization molecule, and in this experimental example, it refers to the degree of viscosity. The viscosity was checked by pouring a certain amount of laundry detergent composition onto the belt. A high degree of polymerization means high viscosity, a medium degree of polymerization means an appropriate viscosity, and a low degree of polymerization means low viscosity.
<실험예 2><Experimental Example 2>
검화도란 PVA의 가수분해도를 나타내는 수치를 의미함. PVA는 중간 생성물인 PVAc를 가수분해하여 제조하는데 완전 가수분해 시 상온에선 물에 녹지 않기 때문에 가수분해를 조절하여 상온에서도 용해가 잘되는 PVA를 추출하는 것이 좋으며 검화도가 높으면(98%초과) 상온에서 물에 용해되기 어렵고 적당한 수치(88 내지 98%)에서 물에 대한 용해도가 좋음.Saponification degree refers to a value indicating the degree of hydrolysis of PVA. PVA is manufactured by hydrolyzing PVAc, an intermediate product. Since it is insoluble in water at room temperature when completely hydrolyzed, it is recommended to control the hydrolysis to extract PVA that is easily soluble even at room temperature. If the degree of saponification is high (over 98%), it is insoluble in water at room temperature. It is difficult to dissolve in water and has good solubility in water at moderate levels (88 to 98%).
표 5에 나타난 바와 같이, 점도가 30,000cps 미만이면 세탁세제조성물이 흐르는 속도가 빨라 일정 두께를 만드는데 어려움이 있어 적절하지 않고 점도가 50,000cps 초과이면 흐름성이 나빠 컨베이어 벨트에서 시트 형성에 어려움이 있어 적절하지 않으며 점도가 30,000~50,000cps가 가장 바람직하다.As shown in Table 5, if the viscosity is less than 30,000 cps, the laundry detergent composition flows quickly and is difficult to create a certain thickness, which is not appropriate. If the viscosity is more than 50,000 cps, the flow is poor and it is difficult to form a sheet on the conveyor belt. It is not appropriate, and a viscosity of 30,000 to 50,000 cps is most desirable.
이를 통해, 본 발명의 세탁용 시트 제조방법은 PVA의 중합도와 검화도가 적절하게 유지되어 일정한 두께의 시트를 형성하는데 보다 수월하고 세탁용 시트의 적절한 검화도인 88~98%를 유지할 수 있어 세척력, 용해성, 유연성이 보다 뛰어나 만족스러울 수 있다. Through this, the method of manufacturing a laundry sheet of the present invention maintains an appropriate degree of polymerization and saponification of PVA, making it easier to form a sheet of a certain thickness, and maintains an appropriate degree of saponification of 88 to 98% for a laundry sheet, thereby increasing the cleaning power. , solubility and flexibility can be superior and satisfactory.
도포단계(S30)는 발포단계(S20)를 거쳐 발포된 세탁세제조성물을 콤마코팅기의 코팅액 함에 담고 이형필름에 일정한 두께로 도포할 수 있다.In the application step (S30), the laundry detergent composition foamed through the foaming step (S20) can be placed in the coating liquid box of the comma coating machine and applied to the release film at a constant thickness.
도포단계(S30)는 발포단계(S20)를 거친 세탁세제조성물을 코팅기를 이용하여 도포할 수 있다. 예를 들어, 도포단계(S30)는 발포단계(S20)를 거친 세탁세제조성물을 콤마코터, 나이프코터, 롤코터, 스핀코터, 다이렉트코터 및 3롤리버스코터 중 하나의 코팅기를 이용하여 도포할 수 있다.In the application step (S30), the laundry detergent composition that has passed the foaming step (S20) can be applied using a coater. For example, in the application step (S30), the laundry detergent composition that has undergone the foaming step (S20) can be applied using one of the following coaters: a comma coater, a knife coater, a roll coater, a spin coater, a direct coater, and a three-roll reverse coater. there is.
도포단계(S30)는 0.3 내지 3.8mm 두께로 도포하고 이형필름을 사용하여 도포할 수 있다. 예를 들어, 도포단계(S30)는 2.0mm의 갭을 유지하도록 적용시켜 이형필름을 사용하여 도포할 수 있다. 이를 통해, 세탁용 시트(1) 층을 외부로부터 보호할 수 있으며 제품 사용 시 쉽게 박리가 쉽게 가능할 수 있어 세탁형 시트의 제조과정에서 원단 형태를 잘 유지할 수 있게하고 이후에 박리할 때 보다 편리하게 박리할 수 있다.The application step (S30) can be applied to a thickness of 0.3 to 3.8 mm and using a release film. For example, the application step (S30) can be applied using a release film by maintaining a gap of 2.0 mm. Through this, the layer of the laundry sheet (1) can be protected from the outside and can be easily peeled off when using the product, allowing the fabric to maintain its shape well during the manufacturing process of the washable sheet and making peeling more convenient afterwards. It can be peeled off.
건조단계(S40)는 도포단계(S30)를 거친 이형필름과 세탁세제조성물을 건조기에 넣어 정제수만을 건조시켜 이형필름에 도포된 세탁세제조성물을 원단화할 수 있다.In the drying step (S40), the release film and the laundry detergent composition that have gone through the application step (S30) are placed in a dryer and only purified water is dried to transform the laundry detergent composition applied to the release film into fabric.
건조단계(S40)는 도포단계(S30)를 거친 세탁세제조성물을 건조기에 넣어 건조시켜 세탁세제조성물을 원단화할 수 있다. 예를 들어, 건조단계(S40)는 도포단계(S30)를 거친 세탁세제조성물을 건조기에 넣어 세탁세제조성물 중 정제수를 건조시켜 세탁세제조성물을 원단화할 수 있다.In the drying step (S40), the laundry detergent composition that has passed the application step (S30) can be put into a dryer and dried to turn the laundry detergent composition into fabric. For example, in the drying step (S40), the laundry detergent composition that has gone through the application step (S30) is placed in a dryer and the purified water in the laundry detergent composition is dried to turn the laundry detergent composition into fabric.
건조단계(S40)는 건조기 온도는 40 내지 210도, 건조 속도는 0.3 내지 6m/min로 설정하여 정제수를 건조시킬 수 있다. 예를 들어, 건조단계(S40)는 온도 100도, 건조 속도 5m/min으로 세탁세제조성물 중 정제수를 건조 시킬 수 있다.In the drying step (S40), the purified water can be dried by setting the dryer temperature to 40 to 210 degrees and the drying speed to 0.3 to 6 m/min. For example, in the drying step (S40), purified water in the laundry detergent composition can be dried at a temperature of 100 degrees and a drying speed of 5 m/min.
박리단계(S50)는 건조단계(S40)를 거쳐 원단 형태로 유지되고 정제수가 제거된 세탁세제조성물을 이형필름으로부터 박리할 수 있다.In the peeling step (S50), the laundry detergent composition, which is maintained in fabric form and has had purified water removed through the drying step (S40), can be peeled from the release film.
박리단계(S50)는 건조단계(S40)를 거쳐 나온 원단을 이형필름과 박리할 수 있다. 예를 들어, 박리단계(S50)는 건조단계(S40)를 거쳐 원단이 된 세탁세제조성물에서 이형필름을 박리할 수 있다. In the peeling step (S50), the fabric that has gone through the drying step (S40) can be peeled off from the release film. For example, in the peeling step (S50), the release film can be peeled from the laundry detergent composition that has been turned into fabric through the drying step (S40).
이형필름은 실리콘계 이형필름일 수 있다. The release film may be a silicone-based release film.
박리단계(S50)는 박리된 상기 원단은 두께 0.3 내지 3.8mm, 밀도 0.03 내지 0.35g/일 수 있다. 예를 들어, 박리단계(S50)에서 이형필름이 박리된 원단의 두께는 2.0mm, 밀도 0.2 g/일 수 있다. In the peeling step (S50), the peeled fabric has a thickness of 0.3 to 3.8 mm and a density of 0.03 to 0.35 g/ It can be. For example, in the peeling step (S50), the thickness of the fabric from which the release film was peeled off was 2.0 mm and the density was 0.2 g/ It can be.
합지단계(S60)는 박리단계(S50)를 거쳐 원단 형태가 된 세탁세제조성물에 물을 안개분사하여 원단형태의 세탁세제조성물을 1~10개 겹친 후, 건조기에 넣어 복수개의 원단형태 세탁세제조성물을 합지할 수 있다. 예를 들어, 합지단계(S60)는 복수개의 원단의 일면에 물을 안개분사하여 2~8개의 원단을 겹쳐 롤로 만든 후, 건조기를 사용하여 물을 건조시키면서 서로 합지할 수 있다.In the lamination step (S60), water is sprayed on the laundry detergent composition in the form of fabric through the peeling step (S50), overlapping 1 to 10 pieces of the laundry detergent composition in the form of fabric, and then placed in a dryer to form a plurality of laundry detergent compositions in the form of fabric. can be combined. For example, in the lamination step (S60), water can be sprayed on one side of a plurality of fabrics to form a roll by overlapping 2 to 8 fabrics, and then laminated together while drying the water using a dryer.
합지단계(S60)의 건조기는 50 내지 130도일 수 있다.The dryer in the lamination step (S60) may be 50 to 130 degrees.
이상에서 본 발명의 실시예에 대하여 설명하였으나, 본 발명의 사상은 본 명세서에 제시되는 실시 예에 제한되지 아니하며, 본 발명의 사상을 이해하는 당업자는 동일한 사상의 범위 내에서, 구성요소의 부가, 변경, 삭제, 추가 등에 의해서 다른 실시 예를 용이하게 제안할 수 있을 것이나, 이 또한 본 발명의 사상범위 내에 든다고 할 것이다.Although the embodiments of the present invention have been described above, the spirit of the present invention is not limited to the embodiments presented in this specification, and those skilled in the art who understand the spirit of the present invention will understand the spirit of the present invention within the scope of the same spirit, including addition of components, Other embodiments can be easily proposed by changes, deletions, additions, etc., but these are also within the scope of the present invention.
1: 시트형 세탁세제1: Sheet-type laundry detergent
Claims (10)
벨트 상에 부어지는 상기 세탁세제조성물의 점도가 적당하여 흐름성이 좋아 0.3 내지 3.8mm 두께를 만드는데 용이하도록 상기 숙성단계를 거친 상기 세탁세제조성물의 밀도는 0.1 내지 0.9g/, 점도는 25,000 내지 55,000cps가 되도록 발포기를 이용하여 발포하는 발포단계;
상기 발포단계를 거쳐 발포된 상기 세탁세제조성물을 콤마코팅기의 코팅액 함에 담고 이형필름에 0.3 내지 3.8mm 두께로 도포하는 도포단계;
상기 도포단계를 거친 상기 이형필름과 상기 세탁세제조성물을 되도록 건조기에 넣어 상기 정제수만을 건조시켜 상기 이형필름에 도포된 상기 세탁세제조성물을 원단화하는 건조단계;
상기 건조단계를 거쳐 원단 형태로 유지되고 상기 정제수가 제거된 상기 세탁세제조성물을 상기 이형필름으로부터 박리하는 박리단계; 및
상기 박리단계를 거쳐 원단 형태가 된 상기 세탁세제조성물에 물을 안개분사하여 1~10개 겹친 후, 상기 건조기에 넣어 복수개의 원단형태 세탁세제조성물을 합지하는 합지단계를 포함하고,
상기 계면활성제는,
세탁이 완료된 세탁물에 임의로 설정된 5군데에서 1군데 이하로 나트로사민이 검출되며 세정수에 분해되지 않는 화학물질인 PFAS, SB(안토미노)가 검출되지 않도록 음이온계면활성제인 AOS-1416가 40~60 중량%;
음이온계면활성제인 PCG가 2~8 중량%; 및
비이온계면활성제인 APG가 6~14 중량%을 포함하고,
1분 동안 단위공간 1당 발생하는 복합악취희석배수(OU)가 20 미만이고 세탁이 완료된 세탁물의 보풀 및 실밥의 정도가 세탁물 면적의 20% 미만이도록, 안식향산소다 0.1 내지 0.6중량%;
구연산소다 0.3 내지 1.5 중량%;
구연산 0.3 내지 1.5 중량%; 및
소금 1 내지 6 중량%을 더 포함하고,
천연비누성분 0.3 내지 3 중량%;
실크추출물 0.3 내지 3 중량%;
싸이크로 덱스트린 0.5 내지 6 중량%; 및
복수개의 효소 0.5 내지 6 중량%을 더 포함하고,
상기 PVA는,
PVAc의 가수분해를 조절할 수 있도록 검화도가 88 내지 98%의 수치가 나오는 것을 특징으로 하는 시트형 세탁세제 제조방법.
It has a tensile strength of 4 to 9 that allows for long-term storage and adequate tearing. A maturation step of maturing a laundry detergent composition prepared by containing 7 to 17% by weight of PVA, 2 to 8% by weight of PVP, 2 to 8% by weight of starch and a surfactant in purified water in an aging room so that;
The viscosity of the laundry detergent composition poured on the belt is appropriate and has good flowability, so that the density of the laundry detergent composition that has undergone the aging step is 0.1 to 0.9 g/ , a foaming step of foaming using a foaming machine so that the viscosity is 25,000 to 55,000 cps;
An application step of putting the laundry detergent composition foamed through the foaming step into the coating liquid of a comma coating machine and applying it to a release film to a thickness of 0.3 to 3.8 mm;
A drying step of putting the release film and the laundry detergent composition that have undergone the application step into a dryer and drying only the purified water to transform the laundry detergent composition applied to the release film into fabric;
A peeling step of peeling off the laundry detergent composition from the release film, which is maintained in a fabric form through the drying step and from which the purified water has been removed; and
A laminating step of spraying water on the laundry detergent composition, which has been in the form of a fabric through the peeling step, to overlap 1 to 10 pieces, and then placing them in the dryer to laminate a plurality of fabric-shaped laundry detergent compositions,
The surfactant is,
Natrosamine is detected in less than 1 place out of 5 arbitrarily set locations in the laundry after washing, and AOS-1416, an anionic surfactant, is added from 40 to 40% to prevent PFAS and SB (Antomino), chemicals that do not decompose in washing water, from being detected. 60% by weight;
2 to 8% by weight of PCG, an anionic surfactant; and
Contains 6 to 14% by weight of APG, a nonionic surfactant,
Unit space 1 for 1 minute 0.1 to 0.6% by weight of sodium benzoate so that the complex odor dilution factor (OU) generated per unit is less than 20 and the degree of fluff and lint in the washed laundry is less than 20% of the laundry area;
0.3 to 1.5% by weight of sodium citrate;
0.3 to 1.5% by weight of citric acid; and
Further comprising 1 to 6% by weight of salt,
0.3 to 3% by weight of natural soap ingredients;
0.3 to 3% by weight of silk extract;
0.5 to 6% by weight of cyclodextrin; and
It further comprises 0.5 to 6% by weight of a plurality of enzymes,
The PVA is,
A method of manufacturing a sheet-type laundry detergent, characterized in that the degree of saponification is 88 to 98% to control the hydrolysis of PVAc.
상기 숙성단계는,
상기 세탁세제조성물을 2 내지 50시간, 25 내지 70도로 숙성하는 것을 특징으로 하는 시트형 세탁세제 제조방법.According to claim 1,
The ripening step is,
A method of manufacturing a sheet-type laundry detergent, characterized in that the laundry detergent composition is aged at 25 to 70 degrees for 2 to 50 hours.
상기 건조단계는,
상기 건조기 온도는 40 내지 210도, 건조 속도는 0.3 내지 6m/min로 설정하여 정제수를 건조시키는 것을 특징으로 하는 시트형 세탁세제 제조방법.According to claim 1,
The drying step is,
A method for manufacturing a sheet-type laundry detergent, characterized in that purified water is dried by setting the dryer temperature to 40 to 210 degrees and the drying speed to 0.3 to 6 m/min.
상기 박리단계는,
박리된 상기 원단은 두께 0.3 내지 3.8mm, 밀도 0.03 내지 0.35g/인 것을 특징으로 하는 시트형 세탁세제 제조방법.According to claim 1,
The peeling step is,
The peeled fabric has a thickness of 0.3 to 3.8 mm and a density of 0.03 to 0.35 g/ A method for manufacturing a sheet-type laundry detergent, characterized in that:
상기 합지단계는,
상기 건조기는 50 내지 130도인 것을 특징으로 하는 시트형 세탁세제 제조방법.According to claim 1,
The lamination step is,
A method of manufacturing a sheet-type laundry detergent, characterized in that the dryer is operated at a temperature of 50 to 130 degrees.
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Patent Citations (6)
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KR870002242A (en) * | 1985-08-05 | 1987-03-30 | 에이취 에스 실베스터 | Low phosphate or phosphate free liquid non-aqueous nonionic laundry detergent composition |
US20040071755A1 (en) * | 2002-10-09 | 2004-04-15 | Fox Priscilla S. | Water soluble sheet composition |
US20130178407A1 (en) * | 2006-10-04 | 2013-07-11 | Henkel AG & KGaA | Washing- or cleaning-agent delivery system |
KR20200079334A (en) * | 2018-01-26 | 2020-07-02 | 더 프록터 앤드 갬블 캄파니 | Single laundry detergent article with fibrous substrate |
JP7084165B2 (en) * | 2018-03-08 | 2022-06-14 | 日本精化株式会社 | Detergent composition |
KR102073817B1 (en) * | 2018-07-20 | 2020-02-05 | 김대송 | Liquid detergent composition |
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