KR102488475B1 - Multipurpose Water-Based Cleaner Composition - Google Patents

Abstract

The present invention relates to a multi-purpose water-based cleansing agent composition which contains: vegetable oil including palm oil; a pine resin extract; an alkaline substance; sodium hydrogen carbonate; fragrance; and water of the remainder. By including the multi-purpose water-based cleansing agent composition according to the present invention, there is an effect that can significantly improve the cleaning performance for various contaminants.

Description

Multipurpose water-based cleaner composition {Multipurpose Water-Based Cleaner Composition}

The present invention relates to multi-purpose water-based cleaner compositions.

Detergents can be classified into household and industrial use depending on the application field, and in particular, household is subdivided into kitchen, laundry, and washing.

Detergents for washing can be largely divided into water-based, semi-hydrogen-based, alternative chlorine-based, hydrocarbon-based, alcohol-based, or fluorine-based detergents.

The main component of water-based detergent is water, and water is a solvent with the longest history and has excellent cleaning properties especially for inorganic substances or polar substances. However, the cleaning efficiency of water-based detergents is increased by additives such as surfactants, which may have harmful effects on the human body.

On the other hand, detergents such as bleach, which are mainly used for sterilization and cleaning, are known to be able to sterilize about 50 kinds of bacteria, but are reluctant to use them due to their strong pungent smell and toxicity to the human body when ingested.

Accordingly, there is an urgent need to develop detergents that do not use surfactants and have excellent cleaning power as well as antibacterial properties and safety.

Korean Registered Patent Publication No. 10-2298092 Korean Patent Publication No. 10-2008-0089891

An object of the present invention is to provide a multi-purpose water-based detergent composition that combines antimicrobial properties and safety as well as excellent cleaning power without using a surfactant.

The multi-purpose water-based detergent composition of the present invention is characterized in that it includes vegetable oil including palm oil, rosin extract, an alkali substance, sodium bicarbonate, fragrance and water as the balance.

Based on the total weight of the multipurpose water-based detergent composition, the vegetable oil is 0.1 to 5% by weight, the rosin extract is 0.1 to 5% by weight, the alkali substance is 10 to 30% by weight, and the sodium bicarbonate is 5 to 15% by weight , It is characterized in that the fragrance is included in 0.1 to 5% by weight.

The multi-purpose water-based detergent composition is characterized in that it further comprises a shellfish extract extracted from shellfish powder.

The shellfish powder is characterized in that the calcined shell is powdered.

The multi-purpose water-based detergent composition further comprises a vegetable extract, wherein the vegetable extract is at least any one of green tea extract, sylvia leaf extract, rooibos extract, madonna lily flower extract, chamomile flower extract, borage extract, cornflower flower extract, and subsystem extract. Characterized in that it is configured to further include one or more.

The alkali material is characterized by including at least one or more of sodium polyphosphate, sodium hydrogen phosphate, and sodium silicate.

The vegetable oil is characterized in that it further comprises at least one or more of coconut oil, castor oil, grapefruit seed extract oil.

It is characterized by providing a multi-purpose water-based cleaner comprising any one or more of the above-mentioned multi-purpose water-based cleaner compositions.

By including the multi-purpose water-based detergent composition according to the present invention, there is an effect that can significantly improve the cleaning performance for various contaminants.

In addition, the present invention has the effect of providing a multi-purpose water-based detergent composition that combines antibacterial and safety as well as excellent cleaning power.

In addition, the present invention has the effect of providing a multi-purpose water-based detergent composition that combines antibacterial and safety as well as excellent cleaning power.

In addition, the multi-purpose water-based detergent composition of the present invention has an effect of enabling to simultaneously exhibit excellent aromatic effects without skin irritation by using natural ingredients.

Since the present invention can make various changes and have various embodiments, specific embodiments are illustrated in the drawings and will be described through detailed description.

However, this is not intended to limit the present invention to specific embodiments, and should be understood to include all modifications, equivalents, or substitutes included in the spirit and technical scope of the present invention.

In one embodiment of the present invention, the multi-purpose water-based detergent composition is characterized in that it includes vegetable oil including palm oil, rosin extract, an alkali substance, sodium bicarbonate, fragrance and water as the balance.

The vegetable oil, as a natural detergent, is emulsified together with the surfactant to improve the detergency of stubborn stains attached to the object to be washed.

In particular, palm oil is extracted from the fruit pulp of palm trees. The palm oil is vegetable oil, but because it is composed of saturated fatty acids and unsaturated fatty acids in a ratio of about 1: 1, it is similar to animal oil to increase absorption by the skin and contains oleic acid, an unsaturated fatty acid. It is possible to further accelerate the detergency of staining by the emulsification reaction.

Depending on the method, the vegetable oil may further include at least one of coconut oil, castor oil, and grapefruit seed extract oil to further promote detergency. In particular, grapefruit seed extract oil contains a large amount of flavanones such as naringin, narirutin, hesperidin, naringenin, and hesperetin. , Antibacterial effect, antioxidant effect, and heavy metal removal effect can be secured by these components.

The rosin extract is extracted from pine resin, and the rosin extract contains high-purity turpentine oil and various enzymes present in pine pulp, so that it can play an auxiliary role in promoting cleaning and cleaning action.

The alkali material is characterized by including at least one or more of sodium polyphosphate, sodium hydrogen phosphate, and sodium silicate. The alkaline substance has low solubility and is completely soluble in water, and can realize remarkable cleaning performance. (Completely soluble in water means completely soluble in water at 20 ° C based on the standard amount of laundry detergent.),

More preferably, the alkali material may be made of a mixture of sodium polyphosphate and sodium silicate. In addition to functioning as a dispersant for relieving aggregation of each material and improving fluidity, it is possible to perform a cleaning action and remove metallic particles.

The sodium bicarbonate (sodium carbonate) has the chemical formula NaHCO ₃ .

The fragrance may be a commonly used aromatic compound, and it is preferable to use a substance extracted from natural materials, more preferably at least one or more from the group consisting of apricot seed oil, lemon essential oil, and pine needle extract oil. It is preferable to use a mixed one.

Based on the total weight of the multipurpose water-based detergent composition, the vegetable oil is 0.1 to 5% by weight, the rosin extract is 0.1 to 5% by weight, the alkali substance is 10 to 30% by weight, and the sodium bicarbonate is 5 to 15% by weight , It is characterized in that the fragrance is included in 0.1 to 5% by weight.

The multi-purpose water-based detergent composition is characterized in that it further comprises a shellfish extract extracted from shellfish powder.

Preferably, the shellfish extract may be included in an amount of 0.1 to 5% by weight based on the total weight of the multi-purpose water-based detergent composition.

More specifically, the shellfish extract is obtained by impregnating shellfish powder in distilled water and then hot water extraction at a high temperature (about 100 degrees).

The component of the shell is calcium carbonate (CaCO3), and when it is fired, it turns into quicklime (CaO). When this quicklime comes in contact with water, an aqueous solution of calcium hydroxide (Ca(OH)2) is produced. Then, this aqueous solution is an aqueous solution. Hydroxide ion (HO-) in the bacteria permeates the cell membrane and hydrolyzes the cytoplasm, thereby exerting a strong antibacterial action.That is, the shellfish powder is added to maximize the antibacterial performance of the water-based detergent.

The shellfish may be shells such as oysters, clams, abalone, conch, cockles, ramie clams, mussels, key clams and taste clams.

The shellfish powder is characterized in that the calcined shell is powdered. When shells are calcined, high-purity shellfish powder is obtained, so that cleaning power and antibacterial power can be further improved.

The multi-purpose water-based detergent composition further comprises a vegetable extract, wherein the vegetable extract is at least any one of green tea extract, sylvia leaf extract, rooibos extract, madonna lily flower extract, chamomile flower extract, borage extract, cornflower flower extract, and subsystem extract. Characterized in that it is configured to further include one or more. The vegetable extract may be included in an amount of 0.1 to 3% by weight based on the total composition.

Most preferably, the vegetable extract may be green tea extract, borage extract, or subsystem extract. The green tea extract, borage extract, and bovine extract have an effect of realizing antibacterial performance in the detergent, and may be included in a weight ratio of 1:1:1, respectively, with respect to the entire composition.

If the composition range is less than the above, the cleaning action when it is dirty is deteriorated, and if it is exceeded, the stability of the product is deteriorated.

Depending on the method, the multi-purpose water-based cleaner of the present invention may further comprise an organic acid. The organic acid is for effectively removing fat and oil stains, and as a specific example, it may be any one or two or more selected from the group consisting of citric acid, malic acid, lactic acid, tartaric acid, succinic acid, and fumaric acid, and preferably, citric acid is used. When combined with other compositions, the best cleaning effect can be achieved. Preferably, the organic acid may be included in an amount of 0.1 to 3% by weight based on the total weight of the multi-purpose water-based detergent composition.

Depending on the method, the multipurpose water-based cleaner of the present invention may further include an antifoaming agent. It is intended to suppress the generation of bubbles in the water-based detergent and to maintain an excellent washing effect, and can be used without particular limitation as long as it is commonly used in the art. As a specific example, it may be polydimethylsiloxane, etc., but is not limited thereto. Preferably, the antifoaming agent may be included in an amount of 0.001 to 1% by weight based on the total weight of the multipurpose water-based detergent composition.

Depending on the method, the multi-purpose water-based detergent of the present invention may further improve detergency by further including 0.01 to 3% by weight of the yeast fermented liquid relative to the total composition.

Depending on the method, the multi-purpose water-based cleaner of the present invention further includes 0.01 to 3% by weight of fermented vinegar relative to the total composition, so that it can play a role of strong deodorization and realize cleaning and antibacterial properties. Fermented vinegar may be obtained by washing and drying a vegetable mixture of peppermint, spearmint, sage, bergamot, and hibiscus, mixing it with excess vinegar and sugar solution, and fermenting it for 3 to 7 days. In addition, the sugar solution may contain various sugars such as glucose, sucrose, fructose, oligosaccharide, or starch syrup.

According to another embodiment of the present invention, a multi-purpose water-based cleaner comprising the above-mentioned multi-purpose water-based cleaner composition is provided, sharing technical features and avoiding excessive complexity of the description in this specification with respect to redundant content. In order to avoid, omit it.

The present invention will be described in more detail through the following examples. These examples are illustrative of the present invention, and the scope of the present invention is not limited thereto.

■ Preparation of Examples

After preparing a multi-purpose water-based cleaner according to the composition and ratio shown in Table 1, a multi-purpose water-based cleaner was prepared by mixing according to a conventional water-based cleaner manufacturing method.

division
Example 1 Example 2 Example 3 sodium polyphosphate
15 15 15 sodium silicate
- 3 3 palm oil
7 7 7 vegetable
oil coconut oil - One One Grapefruit Seed Extract Oil - One One vegetable extract rosin extract 2 2 2 green tea extract - 0.5 0.5 borage extract - 0.5 0.5 subtotal extract - 0.5 0.5 yeast fermented liquid - - 0.1 fermented vinegar 0.1 sodium bicarbonate 10 10 10 Spices pine needle extract oil 0.3 0.3 0.3 shellfish extract
- - One citric acid One One One antifoam 0.01 0.01 0.01 water to 100 to 100 to 100

Fermented vinegar was obtained by washing and drying a vegetable mixture of peppermint, spearmint, sage, bergamot, and hibiscus, mixing it with excess vinegar and sugar solution, and fermenting it for 3 to 7 days.

■ Experimental Example 1: Evaluation of detergency

1) Washability: To evaluate the washability, a sensory evaluation of bathroom cleaning was performed on 10 adults, and the scores were scored from 10 points for cleaning very well to 0 points for not cleaning, and the scores were added (out of 100 points). ) and are shown in Table 2 below.

2) Scale inhibition: To evaluate scale inhibition ability, 10 adults who tested the above cleaning ability were left unattended for a week after cleaning the bathroom, and then evaluated according to the degree of scale occurrence. Scale inhibition was very good 10 Point ~ Scale inhibition was scored as 0 points, and the scores were summed (out of 100 points) and shown in Table 2 below.

3) Safety: Designation of household chemical products subject to safety confirmation and safety labeling standards (Ministry of Environment Notification No. 2020-117, 2020.6.5.) and regulations on test inspection standards and methods for household chemical products subject to safety confirmation (National Institute of Environmental Research Notification No. 2019- 70, 2019.12.31.), the stability was inspected, and conformity or nonconformity was determined according to the inspection results.

division Example 1 Example 2 Example 3 cleaning power 85 91 96 deterrent when biting 80 85 90 stability fitness fitness fitness

■ Experimental Example 2: Antibacterial activity test

In accordance with the KS 0693 - 1990 test method, Staphylococcus aureus was used as a strain and 106 animals were inoculated on cotton and PET, and the antimicrobial activity of the fabric was measured. The antibacterial effect was determined as shown in Table 3 below, and the results were shown in Table 4.

Evaluation results Excellent (◎) Excellent (○) Normal (△) Bad (×) amount of microbes 10 ³ or less 10 ⁴ or less 10 ⁵ or less no change

division Example 1 Example 2 Example 3 cleaning power ○ ○ ◎

■ Experimental Example 3: Deodorant effect test

The deodorizing effect of each composition was evaluated three times or more repeatedly for unpleasant odors such as basic odor, volatilizing odor, and acid odor that can be easily encountered in daily life. Experiments were conducted on typical ammonia and trimethylamine as a basic odor, acetaldehyde as a volatilizing odor, and methyl mercaptan as an acidic odor. The detector tubes used in this experiment were manufactured by GASTEC, no. The deodorizing effect was determined as shown in Table 5 below, and the results were shown in Table 6.

Evaluation results Excellent (◎) Excellent (○) Normal (△) Bad (×) odor removal rate 80% or more 60% or more 40% or more less than 20%

division Example 1 Example 2 Example 3 cleaning power ○ ◎ ◎

■ Experimental Example 4: Skin irritation test

In the skin irritation test conducted in the present invention, a multipurpose liquid cleanser sample was patched on the upper arm of 10 healthy men and women for 10 hours every day, and then skin irritation at the patch site was evaluated. All skin irritation test values were compared with the skin irritation values caused by water, and skin irritation caused by water was set as a criterion having a 'very good' value and determined as shown in Table 7 below, and the results are shown in Table 8.

Evaluation results Excellent (○) Normal (△) Bad (×) odor removal rate few traces mild erythema severe erythema

division Example 1 Example 2 Example 3 cleaning power ○ ○ ○

■ Experimental Example 5: Biodegradability test

In order to examine the degree of biodegradability of the water-based detergent composition obtained in the above example and the commercially available detergent, the following was carried out.

Using activated sludge as a decomposition source, shake culture at 23 ± 3 ° C for 8 days in a shaking incubator containing detergent, collect samples according to the passage of time, and evaluate the biodegradability by analyzing the surfactant component of the collected samples by the bubble volume method Activated sludge is activated sludge collected from the Jungnang sewage treatment plant using the activated sludge method and prepared to have a concentration of 10,000 to 20,000 mg/L of suspended matter and used within 5 hours after collection. At this time, the composition of the incubator for the biodegradability test is as shown in Table 9 below, and the obtained results are shown in Table 10.

Raw material Composition (g/L) Ammonium Chloride 3.0 dipotassium phosphate 1.0 magnesium sulfate 0.25 potassium chloride 0.25 Yeast Axis 0.1 ferrous sulfate 0.002 honey 11 The concentration of the surfactant used is a concentration of 30 mg/L

division Example 1 Example 2 Example 3 Samples of commercial cleaners Day 2 85.1 87.5 90.1 65.1 Day 4 99.9 99.9 99.9 79.1 Day 6 99.9 99.9 99.9 87.5

Claims (8)

In the multi-purpose water-based detergent composition containing vegetable oil including palm oil, rosin extract, alkaline substance, sodium bicarbonate, fragrance and the balance of water,
Based on the total weight of the multipurpose water-based detergent composition, the vegetable oil is 0.1 to 5% by weight, the rosin extract is 0.1 to 5% by weight, the alkali substance is 10 to 30% by weight, and the sodium bicarbonate is 5 to 15% by weight , The fragrance is included in 0.1 to 5% by weight,
The alkaline material is a multi-purpose water-based detergent composition, characterized in that it comprises sodium polyphosphate and sodium silicate delete According to claim 1,
The multi-purpose water-based detergent composition further comprises a shellfish extract extracted from shellfish powder According to claim 3,
The shellfish powder is a multi-purpose water-based detergent composition, characterized in that the calcined shell is powdered According to claim 1,
The multi-purpose water-based detergent composition further comprises a vegetable extract, wherein the vegetable extract is at least any one of green tea extract, sylvia leaf extract, rooibos extract, madonna lily flower extract, chamomile flower extract, borage extract, cornflower flower extract, and subsystem extract. A multi-purpose water-based detergent composition, characterized in that it further comprises one or more delete According to claim 1,
The vegetable oil is a multi-purpose water-based detergent composition, characterized in that it further comprises at least one or more of coconut oil, castor oil, grapefruit seed extract oil A multi-purpose water-based cleaner comprising the multi-purpose water-based cleaner composition of any one of claims 1, 3, 4, 5, and 7