KR102371153B1 - Lip cosmetic composition - Google Patents
Lip cosmetic composition Download PDFInfo
- Publication number
- KR102371153B1 KR102371153B1 KR1020150014986A KR20150014986A KR102371153B1 KR 102371153 B1 KR102371153 B1 KR 102371153B1 KR 1020150014986 A KR1020150014986 A KR 1020150014986A KR 20150014986 A KR20150014986 A KR 20150014986A KR 102371153 B1 KR102371153 B1 KR 102371153B1
- Authority
- KR
- South Korea
- Prior art keywords
- oil
- composition
- cosmetic composition
- lips
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 87
- 239000002537 cosmetic Substances 0.000 title claims abstract description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims description 32
- 229930195733 hydrocarbon Natural products 0.000 claims description 32
- 150000002430 hydrocarbons Chemical class 0.000 claims description 31
- -1 polyethylene Polymers 0.000 claims description 26
- 239000004698 Polyethylene Substances 0.000 claims description 20
- 229920000573 polyethylene Polymers 0.000 claims description 20
- 229940008099 dimethicone Drugs 0.000 claims description 18
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 18
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 18
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 15
- 229920002545 silicone oil Polymers 0.000 claims description 15
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 9
- 229920006007 hydrogenated polyisobutylene Polymers 0.000 claims description 8
- 229940057874 phenyl trimethicone Drugs 0.000 claims description 7
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 claims description 7
- 229920006037 cross link polymer Polymers 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229920001083 polybutene Polymers 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 41
- 235000019198 oils Nutrition 0.000 description 41
- 230000000052 comparative effect Effects 0.000 description 30
- 239000001993 wax Substances 0.000 description 21
- 239000000463 material Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000002210 silicon-based material Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- 238000005070 sampling Methods 0.000 description 7
- 238000011161 development Methods 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 230000002688 persistence Effects 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- YYGNTYWPHWGJRM-FLHYQJCXSA-N (6z,10e,14e,18e)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C\CC\C=C(/C)CC\C=C(/C)CCC=C(C)C YYGNTYWPHWGJRM-FLHYQJCXSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- HGKOWIQVWAQWDS-UHFFFAOYSA-N bis(16-methylheptadecyl) 2-hydroxybutanedioate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(O)C(=O)OCCCCCCCCCCCCCCCC(C)C HGKOWIQVWAQWDS-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- DBZJJPROPLPMSN-UHFFFAOYSA-N bromoeosin Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 DBZJJPROPLPMSN-UHFFFAOYSA-N 0.000 description 1
- DHAZIUXMHRHVMP-UHFFFAOYSA-N butyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCC DHAZIUXMHRHVMP-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- LQJVOKWHGUAUHK-UHFFFAOYSA-L disodium 5-amino-4-hydroxy-3-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].OC1=C2C(N)=CC(S([O-])(=O)=O)=CC2=CC(S([O-])(=O)=O)=C1N=NC1=CC=CC=C1 LQJVOKWHGUAUHK-UHFFFAOYSA-L 0.000 description 1
- IVKWXPBUMQZFCW-UHFFFAOYSA-L disodium;2-(2,4,5,7-tetraiodo-3-oxido-6-oxoxanthen-9-yl)benzoate;hydrate Chemical compound O.[Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IVKWXPBUMQZFCW-UHFFFAOYSA-L 0.000 description 1
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 229940100524 ethylhexylglycerin Drugs 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- QAKXLTNAJLFSQC-UHFFFAOYSA-N hexadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC QAKXLTNAJLFSQC-UHFFFAOYSA-N 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007934 lip balm Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- ZYIBVBKZZZDFOY-UHFFFAOYSA-N phloxine O Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 ZYIBVBKZZZDFOY-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229940105297 polyglyceryl-2 diisostearate Drugs 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
본 발명은 사용감이 가벼운 고발색의 입술 화장료 조성물에 관한 것으로서, 보다 상세하게는 입술에 얇고 부드럽게 발려 사용감은 가벼우면서 밀착감이 우수하여 잘 지워지지 않고 지속력이 뛰어난 입술 화장료 조성물에 관한 것이다.The present invention relates to a lip cosmetic composition with a light feeling of use, and more particularly, to a lip cosmetic composition that is applied thinly and softly on the lips and has a light feeling and excellent adhesion, so that it is not easily erased and has excellent durability.
Description
본 발명은 사용감이 가벼운 고발색의 입술 화장료 조성물에 관한 것으로서, 보다 상세하게는 입술에 얇고 부드럽게 발려 사용감은 가벼우면서 밀착감이 우수하여 잘 지워지지 않고 지속력이 뛰어난 입술 화장료 조성물에 관한 것이다.
The present invention relates to a lip cosmetic composition with a light feeling of use, and more particularly, to a lip cosmetic composition that is applied thinly and softly on the lips and has a light feeling and excellent adhesion, so that it is not easily erased and has excellent durability.
최근에는 고발색의 입술 화장이 유행하면서 색소 함량은 높지만 과거와 같이 두껍고 답답한 사용감은 기피하게 되면서 얇고 가볍지만 색상지속과 밀착력이 높은 입술 화장을 선호하는 추세이다. 하지만 얇고 가벼운 사용감의 입술 화장료 조성물은 색상의 지속력과 밀착력이 약하고 쉽게 지워지는 문제가 있어 이러한 문제를 해결하기 위한 다양한 시도가 이루어지고 있다.Recently, as high-color lip makeup has become popular, lip makeup with high pigment content but thick and stuffy feel like in the past is avoided. However, since the thin and light lip cosmetic composition has weak color durability and adhesion, and is easily erased, various attempts are being made to solve these problems.
주로 사용하는 방법은 휘발성 오일제를 사용하는 방법으로서, 조성물의 도포 후 오일이 휘발되어 도포면에 색소와 왁스성분만 남게 하는 방법이다. 또한 다른 방법으로는 폴리머를 통한 피막형성제를 이용하여 입술 표면에 폴리머 피막을 형성하는 방법이 있다. 그러나, 이들 방법은 적용시, 조성물의 색상 지속력은 좋지만 도포시 입술의 답답함과 심한 건조함을 유발한다는 문제점이 있다.
The method mainly used is a method of using a volatile oil agent, and after application of the composition, the oil is volatilized, leaving only the pigment and wax components on the coated surface. Also, as another method, there is a method of forming a polymer film on the surface of the lips using a film forming agent through a polymer. However, when these methods are applied, although the color persistence of the composition is good, there is a problem in that they cause stuffy lips and severe dryness when applied.
이에 본 발명자들은 종래 고발색의 입술 화장료 조성물이 가지는 문제점을 해결하고자 하였으며, 점증제를 사용하지 않으면서 폴리에틸렌 왁스, 탄화수소계 오일, 실리콘계 오일을 적절하게 조합하여 사용하게 되면 기존 제품에 비하여 입술에 상당히 얇게 도포되어 사용감은 가벼우면서 우수한 발색력을 보이며, 또한 입술에의 밀착감이 뛰어나 지속성이 긴 조성물을 제공할 수 있음을 발견하여 본 발명을 완성하게 되었다.Accordingly, the present inventors tried to solve the problems of the conventional high-color lip cosmetic composition, and when using a suitable combination of polyethylene wax, hydrocarbon-based oil, and silicone-based oil without using a thickener, it is significantly improved on the lips compared to existing products. The present invention was completed by discovering that it was possible to provide a composition that is applied thinly, has a light feeling of use, shows excellent color development, and has excellent adhesion to the lips and has a long lasting effect.
따라서, 본 발명은 사용감이 가벼우면서 발색력이 높고 색상 지속성이 긴 입술용 화장료 조성물을 제공하는 것을 목적으로 한다.
Accordingly, an object of the present invention is to provide a cosmetic composition for lips that is light in use, has high color development, and has long color durability.
상기한 목적을 달성하기 위하여, 본 발명은 조성물 총 중량에 대하여 폴리에틸렌 왁스 2.3~3.0중량%; 탄화수소계 오일 10.0~60.0중량%; 및 실리콘계 오일 10.0~40.0중량%를 포함하는 입술용 화장료 조성물을 제공한다.
In order to achieve the above object, the present invention is polyethylene wax 2.3 to 3.0% by weight based on the total weight of the composition; 10.0 to 60.0 wt% of hydrocarbon-based oil; And it provides a cosmetic composition for lips comprising 10.0 to 40.0% by weight of silicone oil.
본 발명의 입술용 화장료 조성물은 부드럽고 매끄럽게 도포되어 사용감이 가벼우면서, 색상 발색력이 우수하고 밀착력이 높아 색상 지속성이 길다.
The cosmetic composition for lips of the present invention is applied softly and smoothly so that the feeling of use is light, and the color development power is excellent and the color durability is long due to high adhesion.
본 발명은 사용감은 가벼우면서 발색력이 우수하고 지속성이 뛰어난 입술용 화장료 조성물, 특히 립글로스 형태의 화장료 조성물에 관한 것이다.The present invention relates to a cosmetic composition for lips, in particular, a lip gloss type cosmetic composition, which has a light feeling of use, excellent color development, and excellent durability.
립글로스 형태와 같은 액상 형태의 조성물은 장기간 보관 시 제형이 분리되는 문제점이 생길 수 있으므로, 일반적으로 점증제를 포함하여 제조된다. 그러나, 점증제를 사용하게 되면 조성물의 점도 증가에 따라서 입술에 얇게 도포하는 것이 어렵고 따라서 사용자가 입술에 조성물을 도포한 다음 답답함을 느낄 수 있게 된다. 이러한 문제점을 해결하기 위하여, 본 발명의 조성물은 입술에 얇게 도포될 수 있게 하여 사용감을 개선시키기 위해, 폴리에틸렌 왁스를 탄화수소계 오일 및 실리콘계 오일과 적절하게 조합하여 사용하고, 이에 의하여 상온에서는 유동성이 감소된 형태를 취함으로써 저장 안정성을 확보할 수 있다.A liquid composition, such as a lip gloss, may have a problem in that the formulation is separated when stored for a long period of time, so it is generally prepared with a thickener. However, when a thickener is used, it is difficult to apply a thin layer to the lips according to the increase in the viscosity of the composition, and thus, the user can feel stuffy after applying the composition to the lips. In order to solve this problem, the composition of the present invention can be applied thinly to the lips to improve the feeling of use, and polyethylene wax is used in appropriate combination with hydrocarbon-based oil and silicone-based oil, whereby fluidity is reduced at room temperature. Storage stability can be ensured by taking the prescribed form.
본 발명에 따른 입술용 화장료 조성물은 일정 수준의 경도 또는 점도를 확보하기 위하여 폴리에틸렌 왁스를 사용한다. 폴리에틸렌 왁스는 적은 양의 사용으로도 조성물의 경도 또는 점도를 크게 증가시킬 수 있는 물질이며, 본 발명에서 폴리에틸렌 왁스는 조성물 총 중량에 대하여 2.3~3.0중량%의 양으로 사용된다. 함량이 2.3중량% 미만이면 조성물의 원하는 정도의 경도 또는 점도를 얻을 수 없고, 함량이 3.0중량%를 초과하면 조성물의 경도 또는 점도가 너무 높아져서 발림성이 나빠져서 사용감이 오히려 감소하게 된다.The cosmetic composition for lips according to the present invention uses polyethylene wax to secure a certain level of hardness or viscosity. Polyethylene wax is a material that can greatly increase the hardness or viscosity of the composition even when used in a small amount, and in the present invention, the polyethylene wax is used in an amount of 2.3 to 3.0% by weight based on the total weight of the composition. If the content is less than 2.3% by weight, it is not possible to obtain the desired degree of hardness or viscosity of the composition, and if the content exceeds 3.0% by weight, the hardness or viscosity of the composition becomes too high, so that the spreadability deteriorates, and the feeling of use is rather reduced.
본 발명에 따른 입술용 화장료 조성물은 탄화수소계 오일을 사용한다. 본 발명에서 사용되는 탄화수소계 오일은 폴리에틸렌 왁스의 사용에 따라서 조성물의 경도 또는 점도가 크게 변화하는 정도를 완화시킬 수 있는 역할을 제공하며, 폴리에틸렌 왁스와의 조합 사용에 의하여 조성물을 매끄러우면서도 얇게 도포할 수 있게 한다. 본 발명에서 사용되는 탄화수소계 오일은 그 종류가 특별히 한정되는 것은 아니지만, 액상 형태, 페이스트 형태 등의 물질을 모두 포함할 수 있으며, 예를 들어 하이드로제네이티드 폴리이소부텐, 폴리부텐, 피토스쿠알란 등으로 이루어진 군에서 선택되는 1종 이상이 사용될 수 있고, 바람직하게는 하이드로제네이티드 폴리이소부텐이 사용될 수 있다. 바람직하게, 본 발명에서 사용되는 탄화수소계 오일의 총 양은 조성물 총 중량에 대하여 10.0~60.0중량%이다. 본 발명의 입술용 화장료 조성물에는 액상 형태 및/또는 페이스트 형태인 탄화수소계 오일이 사용될 수 있다. 특히 본 발명에서 액상 형태의 탄화수소계 오일은 조성물 총 중량에 대하여 10.0~30.0중량%의 양으로 사용된다. 함량이 10.0중량% 미만이면 보습감이 감소하고, 함량이 30.0중량% 초과이면 입술에의 밀착력이 감소하여 지속성이 떨어지게 된다. 본 발명에서 페이스트 형태의 탄화수소계 오일은 조성물 총 중량에 대하여 10.0~30.0중량%의 양으로 사용된다. 함량이 10.0중량% 미만이면 밀착력이 감소하고, 함량이 30.0중량% 초과이면 끈적임으로 인해 사용감이 저하된다.The cosmetic composition for lips according to the present invention uses hydrocarbon-based oil. The hydrocarbon-based oil used in the present invention provides a role that can alleviate the degree of greatly changing the hardness or viscosity of the composition according to the use of polyethylene wax, and applies the composition smoothly and thinly by use in combination with polyethylene wax make it possible The hydrocarbon-based oil used in the present invention is not particularly limited in its type, but may include all substances such as liquid form and paste form, for example, hydrogenated polyisobutene, polybutene, phytosqualane, etc. At least one selected from the group consisting of may be used, preferably hydrogenated polyisobutene may be used. Preferably, the total amount of the hydrocarbon-based oil used in the present invention is 10.0 to 60.0% by weight based on the total weight of the composition. In the cosmetic composition for lips of the present invention, hydrocarbon-based oil in liquid form and/or paste form may be used. In particular, in the present invention, the hydrocarbon-based oil in liquid form is used in an amount of 10.0 to 30.0% by weight based on the total weight of the composition. If the content is less than 10.0% by weight, the moisturizing feeling is reduced, and if the content is more than 30.0% by weight, the adhesion to the lips is reduced and the durability is deteriorated. In the present invention, the hydrocarbon-based oil in the form of a paste is used in an amount of 10.0 to 30.0% by weight based on the total weight of the composition. When the content is less than 10.0% by weight, the adhesion is reduced, and when the content is more than 30.0% by weight, the feeling of use is reduced due to stickiness.
또한, 본 발명에 따른 입술용 화장료 조성물은 실리콘계 오일을 사용한다. 본 발명에서 사용되는 실리콘계 오일은 입술에 도포시 밀착감을 증진시키면서 윤기가 나게 하는 역할을 한다. 본 발명에서 사용되는 실리콘계 오일은 그 종류가 특별히 한정되는 것은 아니지만, 액상 형태, 페이스트 형태 등의 실리콘계 물질을 모두 포함할 수 있으며, 예를 들어 디메치콘, 페닐 트리메치콘, 디메치콘/디메치콘/비닐 디메치콘 크로스폴리머, 아크릴레이트/스테아릴아크릴레이트/디메치콘/메타아크릴레이트 코폴리머 등으로 이루어진 군에서 선택되는 1종 이상이 사용될 수 있다. 바람직하게, 본 발명에서 사용되는 실리콘계 오일의 총 양은 조성물 총 중량에 대하여 10.0~40.0중량%이다. 본 발명의 입술용 화장료 조성물에는 액상 형태 및/또는 페이스트 형태인 실리콘계 오일이 사용될 수 있다. 특히 본 발명에서 액상 형태의 실리콘계 오일은 조성물 총 중량에 대하여 10.0~20.0중량%의 양으로 사용된다. 함량이 10.0중량% 미만이면 색상 지속성이 감소하고, 함량이 20.0중량% 초과하면 건조함을 느끼게 된다. 본 발명에서 페이스트 형태의 실리콘계 오일은 조성물 총 중량에 대하여 10.0~20.0중량%의 양으로 사용된다. 함량이 10.0중량% 미만이면 색상 지속성이 감소하고, 함량이 20.0중량% 초과이면 다른 원료와의 상용성 저하로 인하여 제품의 장기 안정성에 영향을 주게 된다.In addition, the cosmetic composition for lips according to the present invention uses a silicone-based oil. The silicone-based oil used in the present invention serves to enhance a feeling of adhesion when applied to the lips and to make them shiny. The silicone oil used in the present invention is not particularly limited in its type, but may include all silicone-based materials such as liquid form and paste form, for example, dimethicone, phenyl trimethicone, dimethicone/dimethicone/ At least one selected from the group consisting of vinyl dimethicone crosspolymer, acrylate/stearylacrylate/dimethicone/methacrylate copolymer, and the like may be used. Preferably, the total amount of the silicone oil used in the present invention is 10.0 to 40.0% by weight based on the total weight of the composition. Silicone oil in liquid form and/or paste form may be used in the cosmetic composition for lips of the present invention. In particular, in the present invention, the silicone oil in liquid form is used in an amount of 10.0 to 20.0% by weight based on the total weight of the composition. When the content is less than 10.0% by weight, color persistence is reduced, and when the content exceeds 20.0% by weight, dryness is felt. In the present invention, the silicone-based oil in the form of a paste is used in an amount of 10.0 to 20.0% by weight based on the total weight of the composition. When the content is less than 10.0% by weight, color durability is reduced, and when the content is more than 20.0% by weight, the long-term stability of the product is affected due to deterioration of compatibility with other raw materials.
본 발명에서 사용되는 상기 3가지 성분, 즉 폴리에틸렌 왁스, 탄화수소계 오일 및 실리콘계 오일은 기재된 함량 범위의 양으로 사용될 수 있으나, 바람직하게는 조성물의 점도와 발림성의 관점에서 1:4~15:2~11 범위의 조합비로 사용될 수 있으며, 특히 실리콘계 오일로서 액체 형태인 디메치콘, 페닐 트리메치콘 등이 사용될 경우에는 바람직하게는 1:4~7:2~5의 조합비로 사용될 수 있다. 보다 구체적으로, 탄화수소계 오일로서 액상 형태인 하이드로제네이티드 폴리이소부텐, 실리콘계 오일로서 액상 형태인 페닐 트리메치콘이 사용될 경우에는 바람직하게는 1:5~6:3~4, 보다 바람직하게는 1:5.5~6:3.3~3.8의 조합비로 사용될 수 있다.The three components used in the present invention, ie, polyethylene wax, hydrocarbon-based oil and silicone-based oil, may be used in an amount within the range described, but preferably from 1:4 to 15:2 from the viewpoint of viscosity and spreadability of the composition. It can be used in a combination ratio in the range of 11, and in particular, when dimethicone in liquid form, phenyl trimethicone, etc. are used as silicone oil, it can be preferably used in a combination ratio of 1:4-7:2-5. More specifically, when hydrogenated polyisobutene in liquid form as hydrocarbon oil and phenyl trimethicone in liquid form as silicone oil are used, preferably 1:5 to 6:3 to 4, more preferably 1 It can be used in a combination ratio of :5.5~6:3.3~3.8.
본 발명의 입술용 화장료 조성물은 상기 유효성분 이외에 본 발명의 효과를 손상시키지 않는 범위 내에서 왁스, 오일, 파우더, 안료, 영양성분, 휘발성 용해제, 산화방지제, 방부제 및 향 등과 같은 통상의 입술 화장료 조성물에 함유되는 성분(이하 "기타 성분"이라 한다)을 포함할 수 있다. 상기 기타 성분은 조성물 총 중량에 대하여 1~90중량%의 양으로 포함될 수 있다.The cosmetic composition for lips of the present invention is a conventional lip cosmetic composition such as wax, oil, powder, pigment, nutritional component, volatile solubilizer, antioxidant, preservative and fragrance within the range that does not impair the effects of the present invention in addition to the above active ingredients It may include a component contained in (hereinafter referred to as "other components"). The other components may be included in an amount of 1 to 90% by weight based on the total weight of the composition.
상기 왁스로는 고상(固相)의 왁스가 바람직하며, 마이크로크리스탈린왁스, 오조케라이트, 밀납, 칸데릴라왁스, 카나우바왁스, 세레신, 파라핀, 몬탄왁스 및 합성왁스로 이루어진 군에서 선택될 수 있으나, 이들에만 한정되는 것은 아니다.The wax is preferably a solid wax, and may be selected from the group consisting of microcrystalline wax, ozokerite, beeswax, candelilla wax, carnauba wax, ceresin, paraffin, montan wax, and synthetic wax. However, the present invention is not limited thereto.
상기 오일 성분으로는 리퀴드 파라핀과 같은 광물성 오일; 스쿠알렌 및 하이드로 스쿠알렌 등의 동물성 오일; 팜오일, 아보카도 오일, 호호바오일, 세사미오일, 올리브오일 및 피마자유 등의 식물성 오일; 부틸 미리스테이트, 이소프로필 미리스테이트, 세틸 미리스테이트, 이소프로필팔미테이트, 부틸스테아레이트, 폴리이소부텐, 각종 폴리올, 트리-2-에틸헥실산 글리세린, 트리글리세라이드계 오일, 젖산 미리스틸, 옥틸 도데칸올 및 디이소스테아릴 말레이트 등의 합성 오일;을 사용할 수 있으나, 이들에만 한정되는 것은 아니다.Examples of the oil component include mineral oil such as liquid paraffin; animal oils such as squalene and hydrosqualene; vegetable oils such as palm oil, avocado oil, jojoba oil, sesame oil, olive oil and castor oil; Butyl myristate, isopropyl myristate, cetyl myristate, isopropyl palmitate, butyl stearate, polyisobutene, various polyols, tri-2-ethylhexyl glycerin, triglyceride oil, myristyl lactate, octyl dodecanol and synthetic oils such as diisostearyl malate, but not limited thereto.
상기 파우더 성분으로는 통상적으로 화장료에 사용되는 파우더, 예를 들면 카올린, 백운모, 합성운모, 견운모, 이산화티탄, 산화티탄피복 운모, 알루미늄 파우더, 황산화철, 흑산화철, 카본블랙, 황산바륨, 실리카 및 제올라이트 등의 무기 파우더; 및 나일론, PMMA, 폴리스틸렌 파우더, 폴리에틸렌 파우더 및 셀룰로오스 파우더 등의 유기 파우더를 사용할 수 있으나, 이들에만 한정되는 것은 아니다.As the powder component, powders commonly used in cosmetics, for example, kaolin, muscovite, synthetic mica, sericite, titanium dioxide, titanium oxide coated mica, aluminum powder, iron sulfate, black iron oxide, carbon black, barium sulfate, silica and inorganic powders such as zeolite; and organic powders such as nylon, PMMA, polystyrene powder, polyethylene powder, and cellulose powder, but is not limited thereto.
상기 안료로는 황색 203호, 황색 4호, 황색 5호, 황색 201호, 황색 204호, 적색 103호, 적색 201호, 적색 202호, 적색 218호, 적색 220호, 적색 223호, 적색 226호, 적색 227호, 청색 1호, 청색 2호 등의 바륨 또는 알루미늄 레이크의 유기 안료 및 진주 안료 등을 사용할 수 있으나, 이들에만 한정되는 것은 아니다.As the pigment, Yellow No. 203, Yellow No. 4, Yellow No. 5, Yellow No. 201, Yellow No. 204, Red No. 103, Red No. 201, Red No. 202, Red No. 218, Red No. 220, Red No. 223, Red No. 226 Arc, Red No. 227, Blue No. 1, Blue No. 2, etc. may be used, such as organic pigments and pearl pigments of barium or aluminum lake, but is not limited thereto.
본 발명의 입술용 화장료 조성물은 통상의 제조방법에 의하여 가열, 혼합 및 교반 등의 처리를 거침으로써 제형화될 수 있으며, 특히 립스틱, 립밤, 립크림, 립펜슬, 액상루즈 또는 립글로스, 바람직하게는 립글로즈로 제형화될 수 있으나, 이에 한정되는 것은 아니다.
The cosmetic composition for lips of the present invention may be formulated by undergoing treatment such as heating, mixing and stirring by a conventional manufacturing method, and in particular, lipstick, lip balm, lip cream, lip pencil, liquid rouge or lip gloss, preferably lip gloss It may be formulated as, but is not limited thereto.
이하, 실시예 및 비교예를 들어 본 발명을 보다 구체적으로 설명하지만, 본 발명의 범위가 이들 예로만 한정되는 것은 아니다.
Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the scope of the present invention is not limited only to these examples.
[시험예 1] 폴리에틸렌 왁스와 이와 혼합되는 오일 종류에 따른 조성물의 경도 평가[Test Example 1] Evaluation of hardness of the composition according to the type of polyethylene wax and oil mixed therewith
조성물의 경도 또는 점도는 조성물의 안정성과 관련된 물성으로서, 조성물의 경도 또는 점도를 높이기 위하여 일반적으로 폴리에틸렌 왁스를 사용하여 왔다. 그러나, 경도 또는 점도가 높으면 도포 용이성이 떨어지게 되고, 폴리에틸렌 왁스를 소량 사용하더라도 경도 또는 점도의 상승 정도가 매우 크다. 따라서, 본 시험에서는 상기 문제점을 보완하기 위한 수단으로서 일정 수준의 경도 또는 점도를 나타내도록 하여 안정성을 확보하면서, 경도 또는 점도가 너무 상승하지 않도록 할 수 있는 추가적인 성분을 찾고자 하였으며, 이를 위해 에스터계 오일, 탄화수소계 오일 또는 실리콘계 오일을 폴리에틸렌 왁스와 배합하여 사용함으로써 조성물의 경도에 미치는 영향을 알아보았다. 다만, 본 시험은 시험의 용이성을 위하여 일반적인 립스틱 제형의 형태로 성형하여 경도를 측정하는 것으로 진행하였다.The hardness or viscosity of the composition is a physical property related to the stability of the composition, and polyethylene wax has generally been used to increase the hardness or viscosity of the composition. However, if the hardness or viscosity is high, the ease of application is deteriorated, and even if a small amount of polyethylene wax is used, the degree of increase in hardness or viscosity is very large. Therefore, in this test, as a means to compensate for the above problems, it was attempted to find an additional component that can exhibit a certain level of hardness or viscosity to ensure stability and prevent the hardness or viscosity from increasing too much, for this purpose, ester-based oil , the effect on the hardness of the composition by using a hydrocarbon-based oil or silicone-based oil in combination with polyethylene wax was investigated. However, this test was carried out to measure hardness by molding in the form of a general lipstick formulation for ease of testing.
하기 표 1에 제시된 조성으로 립스틱 제형의 샘플을 준비하였다(단위: 중량%).A sample of the lipstick formulation was prepared with the composition shown in Table 1 below (unit: wt%).
wax
(제조사: NEW PHASE TECHNOLOGI)polyethylene
(Manufacturer: NEW PHASE TECHNOLOGI)
(제조사: Witco)microcrystallin
(Manufacturer: Witco)
(제조사: The Nisshin OilliO, Ltd.)Polyglyceryl-2 Diisostearate
(Manufacturer: The Nisshin OilliO, Ltd.)
(제조사: Lipo Chemical Inc.)Hydrogenated polyisobutene
(Manufacturer: Lipo Chemical Inc.)
(제조사: Shin Etsu)Phenyltrimethicone
(Manufacturer: Shin Etsu)
(제조사: Kahl & CO.)Bis-diglyceryl polyacyl adipate-2
(Manufacturer: Kahl & CO.)
(제조사: Lipo Chemicals)Hydrogenated polyisobutene
(Manufacturer: Lipo Chemicals)
상기 조성으로 각 성분을 비커에 넣고 가열하여 녹여 호모지나이져로 균일하게 혼합시킨 후, 성형 틀(스테인리스, 외경 12.7mm, 두께 1mm, 높이 3cm)에 부어 성형하였다. 상기와 같이 제조한 스틱의 내부를 절단하여 경도를 SUN RHEOMETER CR-200D(SUN SCIENTIFIC CO., LTD., 일본)를 사용하여 측정하였다(속도 20mm/분, 침입 깊이 20mm, 반복 sw : 1회(반복 측정하지 않음)). 구체적으로 상기 장비의 어댑터 No.31을 고정대로 하고, 어댑터 No.8을 센서부에 부착하였다. 스틱의 중심을 맞추어서 절단하고, 기기의 기록계로 스틱 상부에서 5.0~15.0mm 지점의 경도값 평균을 기록하였다. 동일 조건의 시료를 3개 이상 측정하여 평균값을 측정값으로 이용하였다. 측정 결과는 하기 표 2에 나타내었다. With the above composition, each component was put into a beaker, melted by heating, and uniformly mixed with a homogenizer, and then poured into a mold (stainless steel, outer diameter 12.7mm, thickness 1mm, height 3cm) and molded. The inside of the stick prepared as described above was cut and the hardness was measured using SUN RHEOMETER CR-200D (SUN SCIENTIFIC CO., LTD., Japan) (speed 20mm/min, penetration depth 20mm, repetition sw: 1 time ( No repeated measurements)). Specifically, adapter No. 31 of the above equipment was used as a stationary table, and adapter No. 8 was attached to the sensor unit. Cut by aligning the center of the stick, and recording the average of the hardness values at 5.0~15.0mm from the top of the stick with the recorder of the device. Three or more samples under the same conditions were measured, and the average value was used as the measured value. The measurement results are shown in Table 2 below.
상기 표 2에 나타낸 결과를 살펴보면, 에스터계 오일을 포함하는 샘플 1의 경우에는 경도가 높은 반면, 탄화수소계 오일 또는 실리콘계 오일을 사용하는 샘플 2 및 샘플 3의 경우에는 에스터계 오일을 사용하는 샘플에 비하여 경도가 현저하게 낮은 것으로 나타났으며, 특히 탄화수소계 오일을 사용하는 경우 경도가 매우 낮게 나타난다는 것을 확인할 수 있다. 이러한 결과는 에스터계 오일은 폴리에틸렌 왁스의 사용에 의한 경도 상승을 보완하기에 불충분한 반면, 탄화수소계 오일 또는 실리콘계 오일이 폴리에틸렌 왁스와 조합되기에 적합한 오일임을 시사한다.
Looking at the results shown in Table 2, in the case of Sample 1 containing the ester-based oil, the hardness is high, whereas in the case of Samples 2 and 3 using the hydrocarbon-based oil or the silicone-based oil, the samples using the ester-based oil. It can be seen that the hardness is significantly lower than that, especially when hydrocarbon-based oil is used, the hardness is very low. These results suggest that ester-based oils are insufficient to compensate for the increase in hardness caused by the use of polyethylene wax, while hydrocarbon-based oils or silicone-based oils are suitable oils to be combined with polyethylene wax.
[참고예 1] 실시예 1 및 비교예 1~4의 제조[Reference Example 1] Preparation of Example 1 and Comparative Examples 1-4
하기 표 3에 나타낸 조성으로 립글로스 제형의 실시예 1 및 비교예 1~4를 하기 방법에 따라서 제조하였다(단위: 중량%).Examples 1 and Comparative Examples 1 to 4 of lip gloss formulations with the composition shown in Table 3 below were prepared according to the following method (unit: wt%).
비교예 1은 실시예 1의 탄화수소계 물질을 전부 실리콘계 물질로 대체한 것이고, 비교예 2는 탄화수소계 물질을 실시예 1에 비하여 30%의 양으로 처방하고 나머지는 실리콘계 물질로 대체한 것이다. 또한, 비교예 3은 실리콘계 물질을 실시예 1에 비하여 30%의 양으로 처방하고 나머지는 실리콘계 물질로 대체한 것이며, 비교예 4는 실시예 1의 실리콘계 물질을 전부 탄화수소계 물질로 대체한 것이다.In Comparative Example 1, all of the hydrocarbon-based material of Example 1 was replaced with a silicone-based material, and Comparative Example 2 was formulated with a hydrocarbon-based material in an amount of 30% compared to that of Example 1, and the remainder was replaced with a silicone-based material. In Comparative Example 3, the silicone-based material was prescribed in an amount of 30% compared to that of Example 1, and the rest was replaced with a silicone-based material, and Comparative Example 4 is that the silicone-based material of Example 1 was all replaced with a hydrocarbon-based material.
(페이스트 형태의 탄화수소계 오일)Hydrogenated polyisobutene
(hydrocarbon-based oil in the form of paste)
(액상 형태의 탄화수소계 오일)Hydrogenated polyisobutene
(hydrocarbon oil in liquid form)
(액상 형태의 실리콘계 오일)Phenyltrimethicone
(liquid silicone oil)
(페이스트 형태의 실리콘계 오일)Dimethicone/Vinyl Dimethicone Crosspolymer
(Silicone-based oil in paste form)
<제조방법><Production method>
(1) 원료 1~4를 평량하여 90℃ 이상으로 가열하여 용해한 후, 호모지나이져로 교반시켜 혼합물을 분산하여 제조하였다.(1) Raw materials 1 to 4 were weighed and dissolved by heating to 90° C. or higher, followed by stirring with a homogenizer to disperse the mixture.
(2) 원료 5~8을 평량하였다.(2) Raw materials 5 to 8 were weighed.
(3) 상기 (1)의 혼합물의 온도를 75~85℃로 조절한 후 상기 (2)의 혼합물을 서서히 가하면서 호모지나이져로 균일하게 혼합시킨 후, 탈기, 부향의 과정을 거쳐 립글로스를 제조하였다.
(3) After adjusting the temperature of the mixture of (1) to 75-85°C, gradually adding the mixture of (2) to uniformly mixing with a homogenizer, and then degassing and blowing to prepare lip gloss did
[시험예 2] 조성물의 점도 측정[Test Example 2] Viscosity measurement of the composition
립글로스 제품의 경우 점도가 높을수록 저장 안정성이 높다는 점에서는 유리하지만, 입술에 도포시 발림성이 좋지 않고 두껍게 발려 답답함을 유발하여 사용감을 저하시킨다는 문제가 있다. 따라서, 본 시험에서는 본 발명의 립글로스의 점도를 측정함으로써 저장 안정성 및 사용감을 평가하고자 한다. 특히 샘플병에 조성물을 붓는 온도(샘플링 온도)에 따라서 조성물의 점도가 크게 달라지게 되므로, 2가지 샘플링 온도에서 점도를 측정하였다.In the case of lip gloss products, the higher the viscosity, the better the storage stability. Therefore, in this test, storage stability and feeling of use are evaluated by measuring the viscosity of the lip gloss of the present invention. In particular, since the viscosity of the composition varies greatly depending on the temperature at which the composition is poured into the sample bottle (sampling temperature), the viscosity was measured at two sampling temperatures.
상기 참고예 1에 나타낸 실시예 1 및 비교예 1~4의 조성물을 70℃에서 점도 샘플병(100ml)에 목선까지 내용물을 채운 다음(샘플링 온도: 70℃), 30℃ 항온조에 12시간 이상 방치한 후 점도를 측정하였다. 또한, 사용시의 조성물의 점도를 평가하기 위하여 상기 항온조에 방치한 조성물을 어플리케이터로 15회 휘저은 후 이를 동일한 점도 샘플병에 동일한 방식으로 내용물을 채운 다음(샘플링 온도: 30℃), 30℃ 항온조에 12시간 이상 방치한 후 점도를 측정하였다. 점도는 Brookfield DV-Ⅲ ULTRA(Brookfield, 미국)를 사용하고, 스핀들 64, 12rpm에서 1분 동안 측정하였다. 결과는 하기 표 4에 나타내었다.The compositions of Examples 1 and Comparative Examples 1 to 4 shown in Reference Example 1 were filled in a viscosity sample bottle (100 ml) at 70° C. up to the neck line (sampling temperature: 70° C.), and then left in a 30° C. thermostat for at least 12 hours. After that, the viscosity was measured. In addition, in order to evaluate the viscosity of the composition at the time of use, the composition left in the thermostat was stirred 15 times with an applicator, and then filled with the same viscosity sample bottle in the same manner (sampling temperature: 30°C), then placed in a 30°C thermostat After standing for 12 hours or more, the viscosity was measured. Viscosity was measured using a Brookfield DV-III ULTRA (Brookfield, USA) for 1 minute at a spindle 64, 12 rpm. The results are shown in Table 4 below.
상기 표 4에 나타낸 바와 같이, 실리콘계 물질이 다량 사용된 비교예 1 및 2의 조성물은 실리콘계 물질의 함량이 증가할수록 점도가 급격하게 상승하여 점도가 매우 높으며, 이는 고객이 사용하는 조건으로 만들었을 때에도 점도가 떨어지는 폭이 매우 낮은 것으로 나타났다. 반면, 탄화수소계 물질이 다량 사용된 비교예 3 및 4의 조성물은 탄화수소계 물질의 함량이 증가할수록 점도가 감소한다는 것을 나타낸다. As shown in Table 4, the compositions of Comparative Examples 1 and 2 in which a large amount of the silicone-based material was used had a very high viscosity due to a sharp increase in the viscosity as the content of the silicone-based material increased, which is even when made under the conditions used by the customer. It was found that the decrease in viscosity was very low. On the other hand, the compositions of Comparative Examples 3 and 4 in which a large amount of the hydrocarbon-based material was used showed that the viscosity decreased as the content of the hydrocarbon-based material increased.
또한, 비교예 3 및 4의 조성물, 및 본 발명에 따른 실시예 1의 조성물은 70℃에서 샘플링을 진행한 경우 점도가 높아서 조성물의 저장 안정성이 높은 반면, 사용자가 실제 사용하는 조건(어플리케이터로 15회 휘저은 후)에서 샘플링을 진행한 경우 점도가 현저하게 낮아서 조성물을 얇고 부드럽게 도포하는 것이 가능하다는 것을 알 수 있다.In addition, the compositions of Comparative Examples 3 and 4, and the composition of Example 1 according to the present invention, when sampling at 70 ° C., had a high viscosity, so that the storage stability of the composition was high, whereas the conditions actually used by the user (15 with an applicator) It can be seen that when sampling is carried out in ash agitation), the viscosity is remarkably low, so that it is possible to apply the composition thinly and gently.
이는 제품이 시중에서 유통 중인 경우에는 높은 저장 안정성을 유지하면서, 고객이 사용을 위해 외부 자극, 구체적으로 어플리케이터에 조성물을 묻히기 위해 힘을 가하게 되면 점도가 낮아져 입술에의 도포가 용이하면서 얇게 이루어질 수 있다는 것을 시사한다.
This means that when the product is in circulation, high storage stability is maintained, and when the customer applies a force to apply the composition to the applicator for use, the viscosity is lowered, so that it can be easily applied to the lips and made thin. suggest that
[시험예 3] 사용감 평가(패널 블라인드 테스트)[Test Example 3] Usability evaluation (panel blind test)
본 발명에 따른 조성물의 사용감을 평가하기 위하여, 상기 실시예 1 및 비교예 1~4의 조성물을 도포한 후의 사용감에 대하여 하기 방법으로 평가하였다.In order to evaluate the feeling of use of the composition according to the present invention, the feeling after application of the compositions of Example 1 and Comparative Examples 1 to 4 was evaluated by the following method.
구체적으로, 25세~30세 사이의 여성 10명의 패널을 모집하여 테스트를 진행하였다. 실시예 1, 비교예 1~4의 각각의 조성물을 손등에 3회씩 도포하여 상대적인 사용감을 비교하도록 하였다. 그리고 입술에 각 조성물을 2회 도포한 뒤, 손등에서의 사용감과 입술에의 사용감을 모두 고려하여 0~5점으로 점수를 매기도록 하였다. 이때, 1가지 조성물을 도포한 후에는 물티슈로 1차로 지우고, 마른 티슈로 2차로 지운 후 다음 조성물을 도포하여 테스트를 진행하도록 하였다.Specifically, a test was conducted by recruiting a panel of 10 women between the ages of 25 and 30. Each composition of Example 1 and Comparative Examples 1 to 4 was applied three times on the back of the hand to compare the relative feeling of use. Then, after each composition was applied to the lips twice, it was scored on a scale of 0 to 5 in consideration of both the feeling of use on the back of the hand and the feeling of use on the lips. At this time, after applying one composition, wipe with a wet tissue first, and then with a dry tissue secondarily, apply the next composition to proceed with the test.
사용감은 하기 표 5에 나타낸 항목에 대하여 평가하도록 하였으며, 결과는 10명의 패널이 매긴 점수의 평균값을 구하여 나타내었다. 이때, 도포량, 끈적임, 답답함은 수치가 높을수록 사용감에 부정적인 영향을 미치는 것이며, 나머지 항목에 대해서는 수치가 높을수록 사용감에 긍정적인 영향을 미치는 것이다.The feeling of use was evaluated for the items shown in Table 5 below, and the results were presented by obtaining the average value of the scores given by the 10 panelists. In this case, the application amount, stickiness, and stuffiness have a negative effect on the feeling of use as the numerical value is higher, and for the remaining items, the higher the numerical value, the higher the numerical value, the more positive effect on the feeling of use.
(0:적다, 5:많다)application amount
(0: few, 5: many)
(0:적다, 5:높다)stickiness
(0: low, 5: high)
(0:적다, 5:높다)heaviness
(0: low, 5: high)
(0:적다, 5:높다)adhesion
(0: low, 5: high)
(0:적다, 5:높다)color development
(0: low, 5: high)
(0:낮다, 5:높다)Polish
(0: low, 5: high)
(0:낮다, 5:높다)moisturizing power
(0: low, 5: high)
(0:낮다, 5:높다)color persistence
(0: low, 5: high)
상기 표 5에 나타낸 바와 같이, 본 발명에 따른 실시예 1은 색상 지속력을 높은 수준으로 유지하면서, 밀착감과 높은 보습력을 가지며, 특히 끈적임이 적으면서도 동시에 도포량이 적어 답답함이 적어 전반적으로 사용감이 우수한 것으로 평가되었다.As shown in Table 5, Example 1 according to the present invention has a high level of adhesion and high moisturizing power while maintaining a high level of color persistence. was evaluated.
반면, 비교예 1의 경우는 실리콘 계열 물질의 함량이 높기 때문에, 색상 지속력은 좋은 반면, 높은 점도 때문에 도포량이 많아서 패널들로 하여금 선호도가 가장 낮게 평가되었다. 또한, 비교예 4의 경우는 탄화수소 계열 물질의 함량이 높아서 비교예 1 및 2에 비하여 점도가 현저하게 낮은 것으로 나타났고, 사용된 탄화수소 계열 물질 중 페이스트 형태의 물질은 밀착감을 부여하는 특성이 있기 때문에, 밀착력 항목에서 높은 점수를 받았지만, 밀착감을 부여하는 탄화수소 계열 물질의 사용에 따른 끈적임과 답답함을 동시에 느끼게 하여 선호도가 낮은 것으로 평가되었다.On the other hand, in Comparative Example 1, since the content of the silicone-based material was high, the color lasting power was good, but the panelists had the lowest preference due to the high viscosity due to the large amount of application. In addition, in the case of Comparative Example 4, the content of the hydrocarbon-based material was high, and thus the viscosity was significantly lower than that of Comparative Examples 1 and 2, and among the hydrocarbon-based materials used, the paste-type material has a property of imparting a sense of adhesion. , but received a high score in the adhesion category, but it was evaluated as having a low preference because it felt sticky and stuffy at the same time according to the use of a hydrocarbon-based material that gives a feeling of adhesion.
한편, 비교예 2 및 3의 경우는 비교예 1 및 4에 비해서 사용감에 부정적인 영향을 미치는 요인들은 상대적으로 보완되었지만, 전반적인 사용감 및 선호도가 본 발명에 따른 실시예 1의 정도에는 미치지 못하는 것으로 나타났다.On the other hand, in Comparative Examples 2 and 3, compared to Comparative Examples 1 and 4, factors negatively affecting the usability were relatively supplemented, but the overall feeling of use and preference did not reach the level of Example 1 according to the present invention.
Claims (9)
상기 폴리에틸렌 왁스, 탄화수소계 오일 및 실리콘계 오일은 1:4~15:2~11의 중량비로 포함되되, 탄화수소계 오일은 실리콘계 오일보다 다량으로 존재하는, 립글로스 제형의 입술용 화장료 조성물.2.3 to 3.0% by weight of polyethylene wax based on the total weight of the composition; 10.0 to 60.0 wt% of hydrocarbon-based oil; and 10.0 to 40.0 wt% of silicone-based oil,
The polyethylene wax, hydrocarbon-based oil and silicone-based oil are included in a weight ratio of 1:4-15:2-11, wherein the hydrocarbon-based oil is present in a larger amount than the silicone-based oil, a lip gloss type cosmetic composition for lips.
상기 액상 형태의 실리콘계 오일과 페이스트 형태의 실리콘계 오일은 1:1.6의 중량비로 존재하는 입술용 화장료 조성물.5. The method of claim 4, wherein the silicone oil is at least one liquid silicone oil selected from dimethicone and phenyl trimethicone, and dimethicone/dimethicone/vinyl dimethicone crosspolymer and acrylate/stearyl acrylate/ It is a mixture of silicone oil in the form of one paste selected from dimethicone / methacrylate copolymer,
The silicone oil in the liquid form and the silicone oil in the paste form are present in a weight ratio of 1:1.6 cosmetic composition for lips.
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