KR102174547B1 - 멀티―코트 컬러 및/또는 효과 페인트 시스템의 제조 및 보수 방법 - Google Patents
멀티―코트 컬러 및/또는 효과 페인트 시스템의 제조 및 보수 방법 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
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- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
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- B05D7/572—Three layers or more the last layer being a clear coat all layers being cured or baked together
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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- C09D175/06—Polyurethanes from polyesters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
[식 중, 라디칼 R1 ~ R3 은 지방족 또는 방향족 탄화수소의 군에서 선택됨].
구조식 (I) 의 모든 포스핀 옥시드의 중량% 분율의 합계는 베이스코트 물질의 총 중량을 기준으로 0.1 중량% 내지 5 중량% 이다. 본 발명은 또한, 상응하는 베이스코트 물질, 상응하는 멀티코트 컬러 및/또는 효과 페인트 시스템, 및 유색 수성 페인트에서의 포스핀 옥시드의 용도에 관한 것이다. 또한 본 발명은 상기 본 발명의 방법에 의해 제조된 멀티코트 컬러 및/또는 효과 페인트 시스템 상의 결함 보수 방법에 관한 것이다.
Description
Claims (15)
- 하기에 의해 멀티코트 컬러, 효과, 또는 컬러 및 효과 페인트 시스템을 제조하는 방법으로서:
(1) 유색 수성 베이스코트 물질을 기질에 적용하고,
(2) 중합체 필름을 단계 (1) 에서 적용된 코팅 물질로부터 형성시키고,
(3) 클리어코트 물질을 생성된 베이스코트 필름에 적용한 후,
(4) 베이스코트 필름을 클리어코트 필름과 함께 경화시킴,
단계 (1) 에서 하기 구조식 (I) 의 하나 이상의 포스핀 옥시드를 포함하는 유색 수성 베이스코트 물질이 사용되는 것을 특징으로 하는 제조 방법:
[식 중, 라디칼 R1 ~ R3 은 지방족 탄화수소의 군에서 선택되고, 추가로, 구조식 (I) 의 모든 포스핀 옥시드의 중량% 분율의 총합계는 단계 (1) 에서 적용된 수성 베이스코트 물질의 총 중량을 기준으로 0.1 중량% 내지 5 중량% 임]. - 제 1 항에 있어서, 구조식 (I) 의 모든 포스핀 옥시드의 중량% 분율의 총합계가 단계 (1) 에서 적용된 수성 베이스코트 물질의 총 중량을 기준으로 0.1 중량% 내지 4.5 중량% 인 것을 특징으로 하는 제조 방법.
- 제 1 항에 있어서, 단계 (1) 에서 하나 이상의 포화 또는 불포화 폴리우레탄 수지를 결합제로서 포함하는 유색 수성 베이스코트 물질을 사용하는 것을 특징으로 하는 제조 방법.
- 제 1 항에 있어서, 단계 (1) 에서 아미노 수지 및 폴리이소시아네이트로 이루어지는 군에서 선택되는 하나 이상의 가교제를 포함하는 유색 수성 베이스코트 물질이 사용되는 것을 특징으로 하는 제조 방법으로서, 여기서 폴리이소시아네이트는 차단 또는 미차단된 폴리이소시아네이트인 제조 방법.
- 삭제
- 제 1 항에 있어서, 상기 포스핀 옥시드의 혼합물이 사용되고, 이때 라디칼 R1 ~ R3 이 C3 ~ C16 알킬 라디칼이고 정확히 2 가지 상이한 종류의 라디칼, R 및 R' 가 존재하여, 상기 혼합물이 종류 R3P(O), R2R'P(O), RR'2P(O) 및 R'3P(O) 를 포함하는 것을 특징으로 하는 제조 방법.
- 삭제
- 제 1 항 내지 제 4 항 및 제 6 항 중 어느 한 항에 따른 방법에 의해 제조가능한 멀티코트 컬러, 효과, 또는 컬러 및 효과 페인트 시스템.
- 하기에 의해 제 8 항에 따른 멀티코트 컬러, 효과, 또는 컬러 및 효과 페인트 시스템 상의 결함을 보수하는 방법으로서:
(1) 유색 수성 베이스코트 물질을 결함에 적용하고,
(2) 중합체 필름을 단계 (1) 에서 적용된 코팅 물질로부터 형성시키고,
(3) 클리어코트 물질을 생성된 베이스코트 필름에 적용한 후,
(4) 베이스코트 필름을 클리어코트 필름과 함께 경화시킴,
단계 (1) 에서 하기 구조식 (I) 의 하나 이상의 포스핀 옥시드를 포함하는 유색 수성 베이스코트 물질을 사용하는 것을 특징으로 하는 보수 방법:
[식 중, 라디칼 R1 ~ R3 은 지방족 탄화수소의 군에서 선택되고, 추가로, 구조식 (I) 의 모든 포스핀 옥시드의 중량% 분율의 총합계는 단계 (1) 에서 적용된 수성 베이스코트 물질의 총 중량을 기준으로 0.1 중량% 내지 5 중량% 임]. - 제 9 항에 있어서, 단계 (1) 에서 하나 이상의 포화 또는 불포화 폴리우레탄 수지를 결합제로서 포함하는 유색 수성 베이스코트 물질을 사용하는 것을 특징으로 하는 보수 방법.
- 제 9 항에 있어서, 단계 (1) 에서 아미노 수지 및 폴리이소시아네이트로 이루어지는 군에서 선택되는 하나 이상의 가교제를 포함하는 유색 수성 베이스코트 물질을 사용하는 것을 특징으로 하는 보수 방법으로서, 여기서 폴리이소시아네이트는 차단 또는 미차단된 폴리이소시아네이트인 보수 방법.
- 삭제
- 삭제
- 삭제
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PCT/EP2013/069606 WO2014044811A1 (de) | 2012-09-21 | 2013-09-20 | Verfahren zur herstellung und ausbesserung einer farb- und/oder effektgebenden mehrschichtigen lackierung |
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WO2017140540A1 (de) * | 2016-02-18 | 2017-08-24 | Basf Coatings Gmbh | Verwendung von niedermolekularen carbonsäuren in wässrigen basislacken |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5792806A (en) * | 1992-07-23 | 1998-08-11 | Kansai Paint Company, Limited | Aqueous coating composition |
JP2001523572A (ja) * | 1997-11-20 | 2001-11-27 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 被塗物の多層塗装法 |
US6583214B1 (en) * | 1999-04-01 | 2003-06-24 | Basf Coatings Ag | Aqueous coating material that is cured thermally and/or by actinic radiation, and its use |
JP2004508181A (ja) * | 2000-09-04 | 2004-03-18 | ビーエーエスエフ コーティングス アクチェンゲゼルシャフト | 色付与及び/又は効果付与する塗装系の製造方法 |
JP2008521981A (ja) * | 2004-12-01 | 2008-06-26 | ビーエーエスエフ コーティングス アクチェンゲゼルシャフト | 耐引掻性放射線硬化性塗料 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3984500A (en) * | 1974-01-08 | 1976-10-05 | Ford Motor Company | Radiation polymerizable coating composition containing an unsaturated phosphoric ester |
DE3545618A1 (de) | 1985-12-21 | 1987-06-25 | Basf Lacke & Farben | Wasserverduennbares ueberzugsmittel zur herstellung der basisschicht eines mehrschichtueberzuges |
DE4009858C2 (de) | 1990-03-28 | 1998-02-05 | Basf Lacke & Farben | Wäßriger pigmentierter Basislack enthaltend als Bindemittel ein wasserverdünnbares Polyacrylatharz und Verwendung eines solchen Basislacks |
DE4010176A1 (de) | 1990-03-30 | 1991-10-02 | Basf Lacke & Farben | Verfahren zur herstellung einer mehrschichtigen lackierung und waessriger lack |
DE4107136A1 (de) | 1991-03-06 | 1992-09-10 | Basf Lacke & Farben | Verfahren zur herstellung einer mehrschichtigen, schuetzenden und/oder dekorativen lackierung |
CA2127761C (en) | 1993-07-16 | 2005-10-18 | Armin Gobel | An aqueous dispersion of polyurethane resins, a method of manufacturing them, coating agents containing them and use thereof |
JPH0810690A (ja) * | 1994-06-29 | 1996-01-16 | Basf Lacke & Farben Ag | 多層塗膜の形成方法、ベースコート組成物および塗装方法 |
DE69521870T2 (de) * | 1994-09-29 | 2001-11-08 | Hitachi Chemical Co., Ltd. | Antibewuchs-Beschichtungszusammensetzung |
DE19635447C1 (de) * | 1996-08-31 | 1997-11-20 | Herberts Gmbh | Verfahren zur Herstellung einer Reparaturlackierung |
WO1999026728A2 (de) * | 1997-11-20 | 1999-06-03 | E.I. Du Pont De Nemours And Company, Inc. | Verfahren zur mehrschichtigen lackierung von substraten |
DE59801811D1 (de) * | 1997-11-20 | 2001-11-22 | Du Pont | Verfahren zur mehrschichtigen reparaturlackierung von substraten |
DE19930665A1 (de) | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Basislack und seine Verwendung zur Herstellung von farb- und/oder effektgebenden Basislackierungen und Mehrschichtlackierung |
DE19948004B4 (de) | 1999-10-06 | 2006-05-11 | Basf Coatings Ag | Polyurethane und Pfropfmischpolymerisate auf Polyurethanbasis sowie ihre Verwendung zur Herstellung von Beschichtungsstoffen, Klebstoffen und Dichtungsmassen |
DE60006210T2 (de) * | 1999-12-08 | 2004-07-15 | Ciba Specialty Chemicals Holding Inc. | Neues Photoinitiatorsystem aus Phosphinoxidverbindungen und wenig gefärbte härtbare Zusammensetzungen |
US6592998B2 (en) * | 2001-07-31 | 2003-07-15 | Ppg Industries Ohio, Inc. | Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto |
DE102005051238A1 (de) * | 2005-10-26 | 2007-05-03 | Basf Coatings Ag | Physikalisch, thermisch oder thermisch und mit aktinischer Strahlung härtbare, wässrige Gemische, Verfahren zu ihrer Herstellung und ihre Verwendung |
US20120301703A1 (en) * | 2011-05-27 | 2012-11-29 | Joseph Labock | Labock fire resistant paint |
-
2013
- 2013-09-20 EP EP13765738.3A patent/EP2898023B1/de active Active
- 2013-09-20 US US14/429,413 patent/US9862858B2/en active Active
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- 2013-09-20 MX MX2015002023A patent/MX358937B/es active IP Right Grant
- 2013-09-20 CN CN201380049064.4A patent/CN104662104B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5792806A (en) * | 1992-07-23 | 1998-08-11 | Kansai Paint Company, Limited | Aqueous coating composition |
JP2001523572A (ja) * | 1997-11-20 | 2001-11-27 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 被塗物の多層塗装法 |
US6583214B1 (en) * | 1999-04-01 | 2003-06-24 | Basf Coatings Ag | Aqueous coating material that is cured thermally and/or by actinic radiation, and its use |
JP2004508181A (ja) * | 2000-09-04 | 2004-03-18 | ビーエーエスエフ コーティングス アクチェンゲゼルシャフト | 色付与及び/又は効果付与する塗装系の製造方法 |
JP2008521981A (ja) * | 2004-12-01 | 2008-06-26 | ビーエーエスエフ コーティングス アクチェンゲゼルシャフト | 耐引掻性放射線硬化性塗料 |
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