KR102168208B1 - A Compositions For The Health Aid Device - Google Patents
A Compositions For The Health Aid Device Download PDFInfo
- Publication number
- KR102168208B1 KR102168208B1 KR1020190127214A KR20190127214A KR102168208B1 KR 102168208 B1 KR102168208 B1 KR 102168208B1 KR 1020190127214 A KR1020190127214 A KR 1020190127214A KR 20190127214 A KR20190127214 A KR 20190127214A KR 102168208 B1 KR102168208 B1 KR 102168208B1
- Authority
- KR
- South Korea
- Prior art keywords
- composition
- silicone rubber
- added
- mixed
- phr
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F5/00—Orthopaedic methods or devices for non-surgical treatment of bones or joints; Nursing devices; Anti-rape devices
- A61F5/41—Devices for promoting penis erection
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F5/00—Orthopaedic methods or devices for non-surgical treatment of bones or joints; Nursing devices; Anti-rape devices
- A61F5/41—Devices for promoting penis erection
- A61F2005/411—Penile supports
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Orthopedic Medicine & Surgery (AREA)
- Nursing (AREA)
- Reproductive Health (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
본 발명은 건강 보조 기구용 조성물에 관한 것이다. 더욱 상세하게는 건강 보조 기구의 물리 화학적인 성능 개선을 위한 건강 보조 기구용 조성물에 관한 것이다.The present invention relates to a composition for a health aid. More specifically, it relates to a composition for a health aid for improving the physicochemical performance of the health aid.
예컨대, 남성의 신진대사촉진 및 지속시간을 연장하기 위한 건강 보조 기구로 머리카락, 세라믹, 금속, 및 탄성을 가진 실리콘이나 고무 등의 탄성 재료를 고리형태로 개발하여 사용하여 왔다.For example, hair, ceramics, metals, and elastic materials such as silicone or rubber having elasticity have been developed and used in a ring shape as a health aid for promoting men's metabolism and extending the duration.
특히 최근에는 금속제품이나 고분자 탄성 재료를 이용한 보조기구에 관하여 많은 연구결과로 여러 가지 제품이 생산되고 있다.In particular, in recent years, various products have been produced as a result of many studies on auxiliary devices using metal products or polymer elastic materials.
하나의 예로서, 금속제품으로 만들어져 있으며, 그 크기를 조절할 수 있는 체결장치를 부착한 제품에 관한 특허가 개시되어 있다(특허문헌 1). 여기서 상기 금속은 대부분 순수한 금속 은이나 그 합금으로 제조되고 있다.As an example, a patent is disclosed regarding a product made of a metal product and attached with a fastening device capable of adjusting its size (Patent Document 1). Here, the metal is mostly made of pure metallic silver or an alloy thereof.
그러나 이러한 금속제품은 착용시 그 구경을 조절해야 하는 번거로움이 있을 뿐만 아니라 제조비용이 상대적으로 고가인 단점이 있다.However, such a metal product has a disadvantage in that it is cumbersome to adjust its aperture when worn, and the manufacturing cost is relatively high.
다른 하나의 예로는 고분자 탄성 재료인 실리콘이나 고무제품으로 제조된 탄성 보조 링이 개발되고 있다.As another example, an elastic auxiliary ring made of a high molecular elastic material such as silicone or rubber is being developed.
이러한 보조 링은 착용시 탄력적인 수축작용으로 혈액의 역류를 지연시키는 역할을 한다.This auxiliary ring plays a role in delaying the backflow of blood by elastic contraction when worn.
따라서 이러한 보조 링은 위생적이어야 하나 어떤 외부적인 힘에 의해 찰과상이 발생하여 사용 후에 이 부분에 박테리아가 남아 있을 염려가 있으며, 과도하게 강한 탄력이 가해지는 경우 여러 가지 부작용을 발생할 수 있다.Therefore, these auxiliary rings should be hygienic, but there is a risk that bacteria may remain in this area after use due to abrasion caused by some external force, and when excessively strong elasticity is applied, various side effects may occur.
또한, 장기간 계속적인 사용 후에 열화되어 탄력성을 상실하여 원래의 기능을 잃어버리게 되기도 한다. 따라서 이러한 탄성 재료는 위생, 안전, 및 내구성 등에 문제점을 발생시키는 단점을 내포하고 있다.In addition, after long-term continuous use, it deteriorates and loses its elasticity, resulting in loss of its original function. Therefore, such an elastic material has disadvantages that cause problems such as hygiene, safety, and durability.
본 발명의 목적은 건강 보조 기구를 사용시에 발생할 수 있는 안정, 위생 및 내구성 등의 문제점을 용이하게 해결할 수 있도록 한 건강 보조 기구용 조성물을 제공하는 데 있다.It is an object of the present invention to provide a composition for a health auxiliary device that can easily solve problems such as stability, hygiene, and durability that may occur when using the health auxiliary device.
상기 과제를 해결하기 위하여,In order to solve the above problem,
본 발명의 일실시 예에 따른 건강 보조 기구용 조성물은 실리콘 고무(Silicone Rubber)에 안정화제(Stabilizer)인 다이큐밀 과산화물(Dicumyl peroxide{bis(1-methyl-1-phenyl) peroxide, C17H34O4})이 첨가되어 혼합되고, 충전제(Filler)로 금속산화물미분말(SiO2, Al2O3, TiO2, ZrO2)이 첨가되어 혼합되며, 기능성 첨가제로 탄소나노분말 및 은나노분말이 첨가되어 혼합되고, 이들의 분산을 위한 계면활성제, 실란커플링제를 첨가하여 실리콘 고무 배합물(Silicone Rubber Compound)을 구성할 수 있다.The composition for a health aid according to an embodiment of the present invention is dicumyl peroxide (bis(1-methyl-1-phenyl) peroxide, C 17 H 34 , which is a stabilizer in silicone rubber). O 4 }) is added and mixed, and metal oxide fine powder (SiO 2 , Al 2 O 3 , TiO 2 , ZrO 2 ) is added and mixed as a filler, and carbon nano powder and silver nano powder are added as functional additives. And mixed, and a surfactant and a silane coupling agent for their dispersion are added to form a silicone rubber compound.
또한, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물에 있어서, 상기 실리콘 고무는 메틸 비닐 실리콘 고무(Methyl vinyl silicone rubber)이고, 기능성 첨가제인 탄소나노분말은 산화그래핀 또는 환원산화그래핀이며, 계면활성제로는 친수성 폴리에틸렌 산화물 체인을 가진 비이온성 계면활성제를 사용할 수 있다.In addition, in the composition for health aids according to an embodiment of the present invention, the silicone rubber is methyl vinyl silicone rubber, and the carbon nanopowder as a functional additive is graphene oxide or graphene reduced oxide. , As the surfactant, a nonionic surfactant having a hydrophilic polyethylene oxide chain may be used.
또한, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물에 있어서, 상기 건강 보조 기구용 조성물의 구성비는 메틸 비닐 실리콘 고무에 안정화제 0.5 phr, 산화그래핀 또는 환원산화그래핀 0.1∼1.0 phr, 은나노분말 0.01∼0.1 phr, 흄드 실리카 0.1∼1.0 phr, 실란커플링제 0.01∼0.1 phr 및 계면활성제 100ppm 이하 범위로 배합하여 구성할 수 있다.In addition, in the composition for a health aid according to an embodiment of the present invention, the composition ratio of the composition for a health aid is 0.5 phr of a stabilizer in methyl vinyl silicone rubber, 0.1 to 1.0 phr of graphene oxide or graphene reduced, Silver nanopowder 0.01 to 0.1 phr, fumed silica 0.1 to 1.0 phr, silane coupling agent 0.01 to 0.1 phr, and surfactant 100 ppm or less can be formulated and composed.
또한, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물에 있어서, 상기 충전제는 입자크기가 10∼20㎛인 파이로제닉 실리카(Pyrogenic silica), 입자크기가 5∼10㎛인 산화알루미늄(Al2O3), 이산화티타늄(TiO2), 또는 지르코늄(ZrO2) 분말로 구성될 수 있다.In addition, in the composition for a health aid device according to an embodiment of the present invention, the filler is pyrogenic silica having a particle size of 10 to 20 μm, aluminum oxide having a particle size of 5 to 10 μm (Al 2 O 3 ), titanium dioxide (TiO 2 ), or zirconium (ZrO 2 ) may be composed of powder.
한편, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물을 이용한 건강 보조 기구 제조방법은 실리콘 고무와 안정화제, 충전제 및 각종 첨가제를 롤-밀(Roll Mill)에서 약 200℃, 200bar의 압력으로 일정시간 배합하여 실리콘 고무 배합물(Silicone Rubber Compound)을 제조하고, 상기 실리콘 고무 배합물을 사용하여 여러 구경 및 형상을 가진 금형을 사용하여 사출성형하는 건강 보조 기구로 제조할 수 있다.On the other hand, the method of manufacturing a health aid device using a composition for a health aid device according to an embodiment of the present invention comprises silicone rubber, a stabilizer, a filler, and various additives at a pressure of about 200°C and 200 bar in a roll mill. It can be mixed for a certain period of time to prepare a silicone rubber compound, and the silicone rubber compound can be used to manufacture a health aid that is injection-molded using a mold having several diameters and shapes.
이러한 해결 수단은 다음의 발명을 실시하기 위한 구체적인 내용으로부터 더욱 명백해질 것이다.This solution will become more apparent from the detailed contents for carrying out the following invention.
이에 앞서, 본 명세서 및 청구범위에 사용된 용어나 단어는 통상적이고 사전적인 의미로 해석되어서는 아니 되며, 발명자가 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합되는 의미와 개념으로 해석되어야만 한다.Prior to this, terms or words used in the present specification and claims should not be interpreted in a conventional and dictionary meaning, and the inventor should appropriately define the concept of terms in order to explain his own invention in the best way. It should be interpreted as a meaning and concept consistent with the technical idea of the present invention based on the principle that it can be.
본 발명의 일실시 예에 따르면, 건강 보조 기구의 위생을 위한 항균, 항생제, 기계적인 강도 및 내구성 증진 등을 위한 여러 가지 첨가제가 혼입된 제품을 저렴한 비용으로 생산 가능하고, 장기적인 사용에도 본래의 기능을 오랫동안 유지할 수 있는 효과가 있다.According to an embodiment of the present invention, it is possible to produce a product in which various additives are mixed for hygiene of health aids, antibiotics, and mechanical strength and durability improvement, etc., and the original function even for long-term use. There is an effect that can be maintained for a long time.
본 발명의 특이한 관점, 특정한 기술적 특징들은 첨부된 도면들과 연관되는 이하의 구체적인 내용과 일실시 예로부터 더욱 명백해 질 것이다. 본 명세서에서 각 도면의 구성요소들에 참조 부호를 부가함에 있어, 동일한 구성요소들에 대해서는 비록 다른 도면상에 표시되더라도 가능한 동일한 부호를 가지도록 하고 있음에 유의해야 한다. 또한, 본 발명의 일실시 예를 설명함에 있어, 관련된 공지 구성 또는 기능에 대한 구체적인 설명이 본 발명의 요지를 흐릴 수 있다고 판단되는 경우에는 그 상세한 설명은 생략한다.Specific aspects and specific technical features of the present invention will become more apparent from the following specific content and one embodiment associated with the accompanying drawings. In the present specification, in adding reference numerals to elements of each drawing, it should be noted that the same elements are assigned the same numerals as possible even if they are indicated on different drawings. In addition, in describing an embodiment of the present invention, when it is determined that a detailed description of a related known configuration or function may obscure the subject matter of the present invention, a detailed description thereof will be omitted.
또한, 본 발명의 구성요소를 설명하는 데 있어서, 제1, 제2, A, B, (a), (b) 등의 용어를 사용할 수 있다. 이러한 용어는 그 구성요소를 다른 구성 요소와 구별하기 위한 것일 뿐, 그 용어에 의해 해당 구성요소의 본질이나 차례 또는 순서 등이 한정되지 않는다. 어떤 구성요소가 다른 구성요소에 "연결", "결합" 또는 "접속"된다고 기재된 경우, 그 구성요소는 그 다른 구성요소에 직접적으로 연결되거나 또는 접속될 수 있지만, 각 구성요소 사이에 또 다른 구성요소가 "연결", "결합" 또는 "접속"될 수도 있다고 이해되어야 할 것이다.In addition, in describing the constituent elements of the present invention, terms such as first, second, A, B, (a), (b) may be used. These terms are only for distinguishing the component from other components, and the nature, order, or order of the component is not limited by the term. When a component is described as being "connected", "coupled" or "connected" to another component, the component may be directly connected or connected to that other component, but another component between each component It should be understood that elements may be “connected”, “coupled” or “connected”.
이하, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물을 구체적으로 설명하면 다음과 같다.Hereinafter, a detailed description of a composition for a health aid according to an embodiment of the present invention is as follows.
먼저, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물은 주원료가 실리콘 고무이다. 그리고 상기 실리콘 고무에 안정화제 및 충전제를 첨가하고 혼합하여 구성하고, 기타 기능성 첨가제 및 이들의 분산을 위한 계면활성제, 실란커플링제를 소량 첨가하여 실리콘 고무 배합물(Silicone Rubber Compound)을 구성하게 된다.First, in the composition for a health aid according to an embodiment of the present invention, the main raw material is silicone rubber. In addition, a stabilizer and a filler are added and mixed to the silicone rubber, and a small amount of other functional additives, a surfactant for dispersion thereof, and a silane coupling agent are added to form a silicone rubber compound.
상기한 주원료인 실리콘 고무는 메틸비닐 실리콘 고무(Methyl vinyl silicone rubber)이고, 안정화제는 다이큐밀 과산화물(Dicumyl peroxide{bis(1-methyl-1-phenyl) peroxide, C17H34O4})이며, 충전제(Filler)는 금속산화물미분말(SiO2, Al2O3, TiO2, ZrO2 등)이다. 그리고 기타 기능성 첨가제는 탄소나노분말 및 은나노분말을 사용하게 된다.The silicone rubber, which is the main raw material, is methyl vinyl silicone rubber, and the stabilizer is Dicumyl peroxide (bis (1-methyl-1-phenyl) peroxide, C 17 H 34 O 4 }). , Filler is a fine metal oxide powder (SiO 2 , Al 2 O 3 , TiO 2 , ZrO 2, etc.). In addition, as other functional additives, carbon nano powder and silver nano powder are used.
여기서 금속산화물미분말인 SiO2는 파이로제닉 실리카(Pyrogenic silica) 일명 흄드 시리카(에어로실)이고, 입자크기는 10∼20㎛이다. 이외에 입자크기 5∼10㎛의 마이크로 Al2O3, TiO2, ZrO2 분말 등을 금속산화물미분말로 사용할 수 있다.Here, the metal oxide fine powder, SiO 2, is pyrogenic silica, aka fumed silica (aerosil), and has a particle size of 10 to 20 μm. In addition, micro Al 2 O 3 , TiO 2 , ZrO 2 powder having a particle size of 5 to 10 μm can be used as the fine metal oxide powder.
또한, 기능성 첨가제인 탄소나노분말은 산화그래핀 또는 환원산화그래핀(인편 크기 약 1∼5㎛)을 사용하고, 은나노분말의 입자 크기는 약 50∼100㎚인 것을 사용하게 된다. 그리고 계면활성제는 예컨대, 친수성 폴리에틸렌 산화물 체인을 가진 비이온성 계면활성제{(C14H22)(C2H4)n, 상품명 TritonX-100}를 사용하고, 실란커플링제는 예컨대, APTES, VTES 등을 사용할 수 있다.In addition, the carbon nanopowder, which is a functional additive, uses graphene oxide or reduced graphene oxide (scale size of about 1-5㎛), and the particle size of silver nanopowder is about 50-100nm. And as a surfactant, for example, a nonionic surfactant {(C 14 H 22 ) (C 2 H 4 ) n, trade name TritonX-100} having a hydrophilic polyethylene oxide chain is used, and the silane coupling agent is, for example, APTES, VTES, etc. You can use
여기서 충전제인 금속산화물의 제조방법은 에어로실(Aerosil)을 예로 하여 설명하면, SiCl4를 불꽃에서 산소-수소와 반응시켜 복합반응으로 생성된다. 즉 산소-수소반응으로 물이 생성되고 이 물이 SiCl4와의 가수분해 반응으로 SiO2가 생성된다.Here, the method of manufacturing a metal oxide as a filler is described by taking Aerosil as an example, and SiCl 4 is reacted with oxygen-hydrogen in a flame to generate a complex reaction. That is, water is produced by oxygen-hydrogen reaction, and SiO 2 is produced by hydrolysis reaction of this water with SiCl 4 .
2H2 + O2 → 2H2O2H 2 + O 2 → 2H 2 O
SiCl4 + 2H2O → SiO2 + HClSiCl 4 + 2H 2 O → SiO 2 + HCl
이러한 금속산화물 미립자는 실리콘 고무 제조에 있어, 충전제로 필수적으로 첨가되는 물질이다.These metal oxide fine particles are a material that is essentially added as a filler in the manufacture of silicone rubber.
한편, 탄소나노분말인 산화그래핀 또는 환원산화그래핀은 변성 하머스 공법(Modified Hymmer's process)을 이용하여, 그 제조비용이 비교적 저렴한 자연산 인상흑연을 이용하여 황산(H2SO4), 질산염(NaNO3), 과망간산칼륨(KMnO4), 과산화수소(H2O2), 및 환원제인 하이드라진(N2H4) 등을 사용하여 제조하게 된다.On the other hand, graphene oxide or reduced graphene, which is a carbon nanopowder, uses a modified Hymmer's process, and uses sulfuric acid (H 2 SO 4 ), nitrate ( NaNO 3 ), potassium permanganate (KMnO 4 ), hydrogen peroxide (H 2 O 2 ), and hydrazine (N 2 H 4 ) as a reducing agent are prepared using.
또한, 본 발명의 일실시 예에 따른 건강 보조 기구용 조성물의 구성비는 메틸 비닐 실리콘 고무(Methyl vinyl silicone rubber)에 안정화제(Dicumyl peroxide) 0.5 phr, 산화그래핀 또는 환원산화그래핀 0.1∼1.0 phr, 은나노분말 0.01∼0.1 phr, 충전제 0.1∼1.0 phr, 실란커플링제 0.01∼0.1 phr 및 계면활성제(Triton X-100) 100ppm 이하 범위로 배합하게 된다.In addition, the composition ratio of the composition for health aids according to an embodiment of the present invention is 0.5 phr of dicumyl peroxide in methyl vinyl silicone rubber, 0.1 to 1.0 phr of graphene oxide or graphene reduced. , Silver nanopowder 0.01 to 0.1 phr, filler 0.1 to 1.0 phr, silane coupling agent 0.01 to 0.1 phr, and surfactant (Triton X-100) 100 ppm or less.
참고로 상기 phr은 part per hundred rubber(주원료 100중량부에 대한 첨가제의 중량부, 실리콘 고무 100중량부에 대한 첨가제 등의 중량부)의 약어이다.For reference, phr is an abbreviation for part per hundred rubber (parts by weight of additives for 100 parts by weight of main raw material, parts by weight of additives for 100 parts by weight of silicone rubber).
이하에서는 본 발명의 일실시 예에 따른 첨가제의 종류, 첨가량 변화에 관하여 구체적으로 설명하게 된다.Hereinafter, a change in the type and amount of additives according to an embodiment of the present invention will be described in detail.
※ 습도 90%, 온도 35℃, 30일 후 곰팡이발생: x=100% 발생, △=10% 발생, ○=1% 발생, ◎=발생하지 않음.※ Humidity 90%, temperature 35℃, mold occurrence after 30 days: x=100% occurrence, △=10% occurrence, ○=1% occurrence, ◎=no occurrence.
상기 [표 1]은 그래핀 및 은나노분말의 첨가량에 따른 실리콘 고무의 인장강도 및 항균성을 나타낸 것이다.Table 1 shows the tensile strength and antimicrobial properties of the silicone rubber according to the amount of graphene and silver nanopowder added.
상기 [표 1]에서 알 수 있는 바와 같이, 그래핀 및 은나노분말 첨가량의 증가에 따라 인장강도는 약 20∼90% 정도 증가하고 항균성은 그래핀 0.3 phr, 은나노 0.05 phr 첨가할 경우 곰팡이 발생을 거의 완전히 방지할 수 있음을 알 수 있다.As can be seen from [Table 1], as the amount of graphene and silver nanopowder added increases, the tensile strength increases by about 20-90%, and the antibacterial property is, when 0.3 phr of graphene and 0.05 phr of silver nanopowder are added, the occurrence of mold is almost reduced. You can see that it can be completely prevented.
한편, 본 발명의 일실시 예에 따른 건강 보조 기구 조성물인 실리콘 고무와 안정화제, 충전제 및 각종 첨가제는 롤-밀(Roll Mill)에서 약 200℃, 200bar의 압력으로 일정시간 배합하여 실리콘 고무 배합물로 제조하고, 상기 실리콘 고무 배합물을 사용하여 여러 구경 및 형상을 가진 금형을 사용하여 사출성형하는 건강 보조 기구, 예컨대 고기능성 음경 발기 보조 기구로 제조할 수 있다.Meanwhile, silicone rubber, a stabilizer, filler, and various additives, which are health aid compositions according to an embodiment of the present invention, are mixed in a roll mill at a pressure of about 200°C and 200 bar for a certain period of time to form a silicone rubber compound. It can be manufactured and manufactured by using the silicone rubber compound to be injection-molded using a mold having several diameters and shapes, such as a high-functional penile erection aid.
이상 본 발명을 일실시 예를 통하여 상세히 설명하였으나, 이는 본 발명을 구체적으로 설명하기 위한 것으로, 본 발명에 따른 건강 보조 기구용 조성물은 이에 한정되지 않는다. 그리고 이상에서 기재된 "포함하다", "구성하다", 또는 "가지다", 등의 용어는 특별히 반대되는 기재가 없는 한 해당 구성요소가 내재될 수 있음을 의미하는 것이므로, 다른 구성요소를 제외하는 것이 아니라 다른 구성요소를 더 포함할 수 있는 것으로 해석되어야 하며, 기술적이거나 과학적인 용어를 포함한 모든 용어들은, 다르게 정의되지 않는 한, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가진다.Although the present invention has been described in detail through an embodiment, this is for explaining the present invention in detail, and the composition for a health aid device according to the present invention is not limited thereto. And the terms such as "comprise", "comprise", or "have" described above mean that the corresponding component may be included unless otherwise stated, so excluding other components It should be construed as that it may further include other components, and all terms including technical or scientific terms are generally understood by those of ordinary skill in the technical field to which the present invention belongs, unless otherwise defined. It has the same meaning as being.
또한, 이상의 설명은 본 발명의 기술 사상을 예시적으로 설명한 것에 불과한 것으로서, 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자라면 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 다양한 수정 및 변형 가능하다. 따라서, 본 발명에 개시된 일실시 예들은 본 발명의 기술 사상을 한정하기 위한 것이 아니라 설명하기 위한 것이고, 이러한 일실시 예에 의하여 본 발명의 기술 사상의 범위가 한정되는 것은 아니다. 본 발명의 보호 범위는 아래의 청구범위에 의하여 해석되어야 하며, 그와 동등한 범위 내에 있는 모든 기술 사상은 본 발명의 권리범위에 포함되는 것으로 해석되어야 할 것이다.In addition, the above description is merely illustrative of the technical idea of the present invention, and those of ordinary skill in the art to which the present invention pertains can various modifications and variations without departing from the essential characteristics of the present invention. Accordingly, the exemplary embodiments disclosed in the present disclosure are not intended to limit the technical idea of the present invention, but to explain the technical idea, and the scope of the technical idea of the present disclosure is not limited by this exemplary embodiment. The scope of protection of the present invention should be interpreted by the following claims, and all technical ideas within the scope equivalent thereto should be interpreted as being included in the scope of the present invention.
Claims (4)
상기 실리콘 고무는 메틸 비닐 실리콘 고무이고, 기능성 첨가제인 탄소나노분말은 산화그래핀 또는 환원산화그래핀이며, 계면활성제로는 친수성 폴리에틸렌 산화물 체인을 가진 비이온성 계면활성제를 사용하는 것을 특징으로 하는 건강 보조 기구용 조성물.
Dicumyl peroxide, a stabilizer, is added to and mixed with silicone rubber, and fine metal oxide powder is added and mixed as a filler, and carbon nano-powder and silver nano-powder are added and mixed as a functional additive, and a surfactant and silane couple for their dispersion A composition for health aids comprising a silicone rubber compound by adding a ring agent,
The silicone rubber is methyl vinyl silicone rubber, the carbon nanopowder as the functional additive is graphene oxide or graphene reduced oxide, and a nonionic surfactant having a hydrophilic polyethylene oxide chain is used as the surfactant. Composition for devices.
상기 건강 보조 기구용 조성물의 구성비는 메틸 비닐 실리콘 고무에 안정화제 0.5 phr, 산화그래핀 또는 환원산화그래핀 0.1∼1.0 phr, 은나노분말 0.01∼0.1 phr, 충전제 0.1∼1.0 phr, 실란커플링제 0.01∼0.1 phr 및 계면활성제 100ppm 이하 범위로 배합하는 것을 특징으로 하는 건강 보조 기구용 조성물.
The method according to claim 1,
The composition ratio of the composition for health aids is methyl vinyl silicone rubber, stabilizer 0.5 phr, graphene oxide or reduced graphene oxide 0.1 to 1.0 phr, silver nano powder 0.01 to 0.1 phr, filler 0.1 to 1.0 phr, silane coupling agent 0.01 to A composition for health aids, characterized in that blended in the range of 0.1 phr and 100 ppm or less of surfactant.
상기 충전제는 입자크기가 10∼20㎛인 파이로제닉 실리카, 입자크기가 5∼10㎛인 산화알루미늄, 이산화티타늄, 또는 지르코늄 분말로 구성된 것을 특징으로 하는 건강 보조 기구용 조성물.The method of claim 3,
The filler composition for health aids, characterized in that consisting of pyrogenic silica having a particle size of 10 to 20 μm, aluminum oxide, titanium dioxide, or zirconium powder having a particle size of 5 to 10 μm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020190127214A KR102168208B1 (en) | 2019-10-14 | 2019-10-14 | A Compositions For The Health Aid Device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020190127214A KR102168208B1 (en) | 2019-10-14 | 2019-10-14 | A Compositions For The Health Aid Device |
Publications (1)
Publication Number | Publication Date |
---|---|
KR102168208B1 true KR102168208B1 (en) | 2020-10-21 |
Family
ID=73034611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020190127214A KR102168208B1 (en) | 2019-10-14 | 2019-10-14 | A Compositions For The Health Aid Device |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR102168208B1 (en) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0373228U (en) * | 1989-11-20 | 1991-07-24 | ||
KR20000038283A (en) * | 1998-12-05 | 2000-07-05 | 김준한 | Silicone rubber containing nephrite powder and method for preparing thereof |
KR20050114182A (en) * | 2004-05-31 | 2005-12-05 | 양원동 | Nano silver contain condom |
JP2006307008A (en) * | 2005-04-28 | 2006-11-09 | Ge Toshiba Silicones Co Ltd | Composition for silicone rubber foam having continuous foams |
KR20070015668A (en) * | 2005-08-01 | 2007-02-06 | 주영산업개발(주) | Silicon Formation Material with Anion Radiation and Sterilization Function and Goods Thereby |
KR20080107028A (en) * | 2007-06-05 | 2008-12-10 | 박명찬 | Health apparatus for man |
KR20110001409U (en) | 2009-08-03 | 2011-02-10 | 공승환 | Sexual assistance tool |
KR20120124736A (en) * | 2011-05-04 | 2012-11-14 | 강경완 | Device for strengthening of sexual function |
JP2019047963A (en) * | 2017-09-11 | 2019-03-28 | 東洋紡株式会社 | Body mounting structure |
KR20190036301A (en) * | 2017-09-27 | 2019-04-04 | 코오롱플라스틱 주식회사 | The Silicone-based thermoplastic elastomer composition, Method of manufacturing thereof and Article produced form the same |
-
2019
- 2019-10-14 KR KR1020190127214A patent/KR102168208B1/en active IP Right Grant
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0373228U (en) * | 1989-11-20 | 1991-07-24 | ||
KR20000038283A (en) * | 1998-12-05 | 2000-07-05 | 김준한 | Silicone rubber containing nephrite powder and method for preparing thereof |
KR20050114182A (en) * | 2004-05-31 | 2005-12-05 | 양원동 | Nano silver contain condom |
KR20060044965A (en) * | 2004-05-31 | 2006-05-16 | 양원동 | Nano silver contain condom |
JP2006307008A (en) * | 2005-04-28 | 2006-11-09 | Ge Toshiba Silicones Co Ltd | Composition for silicone rubber foam having continuous foams |
KR20070015668A (en) * | 2005-08-01 | 2007-02-06 | 주영산업개발(주) | Silicon Formation Material with Anion Radiation and Sterilization Function and Goods Thereby |
KR20080107028A (en) * | 2007-06-05 | 2008-12-10 | 박명찬 | Health apparatus for man |
KR20110001409U (en) | 2009-08-03 | 2011-02-10 | 공승환 | Sexual assistance tool |
KR20120124736A (en) * | 2011-05-04 | 2012-11-14 | 강경완 | Device for strengthening of sexual function |
JP2019047963A (en) * | 2017-09-11 | 2019-03-28 | 東洋紡株式会社 | Body mounting structure |
KR20190036301A (en) * | 2017-09-27 | 2019-04-04 | 코오롱플라스틱 주식회사 | The Silicone-based thermoplastic elastomer composition, Method of manufacturing thereof and Article produced form the same |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Wang et al. | Recent applications of nanomaterials in prosthodontics | |
WO2004108099A3 (en) | Hair or skin conditioning composition comprising hydrophobically modified cationic thickening polymer | |
EP3400929A1 (en) | Dental zirconia restoration material with uniform transition of strength and color, and preparation method thereof | |
Kaur et al. | Silver nanoparticles in dentistry: An emerging trend | |
GB0124967D0 (en) | Cosmetic and personal care compositions | |
MY153658A (en) | Methods of making compositions comprising films | |
KR102168208B1 (en) | A Compositions For The Health Aid Device | |
HUP0400856A2 (en) | Antifungal composition | |
Abadi et al. | Silver nanoparticles as active ingredient used for alcohol-free mouthwash | |
KR102198915B1 (en) | Composition for antivirus and antibacterial containing iron-copper alloy nano powder | |
EP1483366A4 (en) | Antimicrobial composition | |
DE502007006052D1 (en) | DENTALS, IN PARTICULAR REMINERALIZING AND AGAINST PAINFUL TEETH, EFFECTIVE COMPOSITION AND DENTAL PARTICLES, IN PARTICULAR FOR COMPOSITION | |
US20240189072A1 (en) | Dental aligner | |
AU7696396A (en) | Diaminopyrimidines, pharmaceutical compositions containing them and their use as antibacterial | |
Mamidi et al. | Metallic and carbonaceous nanoparticles for dentistry applications | |
US20220030874A1 (en) | Wide spectrum microbicidal and microbiostatic nanoproducts and formulations, preparations, and methods for the use thereof | |
AU2012338341B2 (en) | Hearing aid mold | |
MX2023010872A (en) | New topical composition free of sulfate derived surfactants. | |
EP1777264B1 (en) | Production and use of antimicrobial polymerisable compositions useful in medical fields, in particluar in the area of hearing aid systems | |
Ghiciuc et al. | Antibacterial effects of metal oxides-containing nanomaterials in dentistry | |
WO2022117133A3 (en) | Terpenoid derivatives, pharmaceutical preparations containing these derivatives and their use in neuroprotection | |
KR102661420B1 (en) | Anti-microbial banded glove | |
Changxing et al. | Application on the advancements in nanomaterial-based antimicrobial photodynamic therapy in oral infectious diseases | |
CN115382015A (en) | Novel multifunctional biological nano composite coating material with antibacterial activity | |
KR101218068B1 (en) | Manufacture of functional non-slip sheet for antifungi, deoderant and antibacteria |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant |