KR102086315B1 - Wax-free typed cosmetic composition for eye makeup - Google Patents

Abstract

A cosmetic composition for wax-free eye makeup. Cosmetic composition for wax-free eye makeup including pullulan according to one aspect does not contain wax, and has a cosmetic effect such as volume, curling power, including pullulan, while improving blackness, stability over time, and long lasting. Is excellent. In addition, since it has a peel-off effect, cleansing is easy when contacting with lukewarm water. Therefore, it can be used as a product for eye makeup having excellent performance such as mascara, eyebrow, eyeliner and the like.

Description

Wax-free typed cosmetic composition for eye makeup

A cosmetic composition for wax-free eye makeup.

Mascara has been used for women's eyelash makeup since ancient times. The mascara formulations of the time were extremely limited and have been developed since then. Mascara is essential to make the eyelashes thick, long and raised, and wax is essential for this.

Patent Document 1 discloses a mascara composition comprising a naturally derived hair fixation system including a natural polysaccharide film forming system and a naturally derived plasticizer system, and essentially includes a wax component.

However, due to the characteristics of the wax, the exposure time to the air is increased, so that the crystallization of the wax occurs by liquid evaporation and the like, which greatly affects the usability. This causes many problems such as mascara dryness, eyelashes sticking.

Therefore, it is necessary to develop a cosmetic composition for eye makeup that does not contain wax and has excellent performance as mascara such as volume and curling forces while overcoming the above problems.

United States Patent Application Publication US 2012/0156153 A1

One aspect is a wax-free cosmetic composition for wax-free eye makeup including pullulan, including pullulan and excellent makeup effect such as volume, curling force, while having blackness improvement, stability over time, and long lasting effect. To provide.

One aspect provides a wax-free eye makeup cosmetic composition comprising pullulan.

"Pullulan" is a polysaccharide in which maltotriose has a regular polymerization structure with α-1,6 bonds. Pullulan may be obtained by separating and purifying polysaccharides produced from black yeast (Aureobasidium pullulans (DE BARY) ARN.), But is not limited thereto. The cosmetic composition according to the embodiment includes pullulan, which is superior to the case of containing no pullulan or containing other types of water-soluble film formers such as hydroxyethyl cellulose, polyvinyl alcohol, and the like. can do.

The content of the pullulan may be appropriately selected by those skilled in the art according to desired performance of the cosmetic composition for eye makeup. In one embodiment, the pullulan may be included in an amount of 0.1 to 5.0% by weight, or 0.1 to 5.0% by weight or less based on the total weight of the composition. In another embodiment, the pullulan may be included in an amount of at least 1.0 wt% and less than 5.0 wt% with respect to the total weight of the composition. As the content of pullulan is increased, the effect of eyelash or eyebrow volume may be improved. However, when the content of pullulan is 5% by weight or more, the drying speed is slow and strong stickiness may appear under the eyes or the fixing force may drop. Therefore, the use of pullulan in less than 5% by weight may not only be excellent in volume, application and fixing force, but also hardly any powder dropping or smearing under the eyes.

The cosmetic composition according to one embodiment of the present invention overcomes the cosmetic effect reduction due to the absence of wax by using pullulan, which is a kind of natural polysaccharide polymers, and thus the cosmetic effect such as volume and curling force may be excellent.

As used herein, the term "wax-free" refers to a solid oil component used for forming a firmness such as viscosity and hardness, for example, higher fatty acids and higher alcohol esters, hydrocarbons, and the like. This means a formulation that is not used, but does not deny that a small amount of solid oil component is included within the scope of not impairing the object of the present invention.

Most oil-in-water emulsion type mascaras use two or more wax components to form hardness.Inner wax containing wax is emulsified in the water phase, and the base itself becomes milky or pale yellow. There was a problem that dark blackness does not appear even when a color iron oxide is added. However, since the cosmetic composition according to one embodiment of the present invention does not contain wax, it may exhibit much better blackness even when using a very small amount of iron oxide.

In addition, general oil-in-water (O / W) emulsifying type mascara that essentially contains a wax component attempts stabilization using a plurality of emulsifier components for a stabilized emulsified state, and improves dispersibility of the pigment, and emulsification power and hardness Soap base is made by combining fatty acid and neutralizing agent to make prescription, so it contains a large amount of ingredients that can lead to water bleeding or long lasting power. However, since the cosmetic composition according to one embodiment of the present invention does not contain wax, it is not necessary to use a large number of emulsifiers, thereby minimizing bleeding due to water or sebum, and the problem of hardness increase due to wax ( There is little change of powder due to no change over time, so the long lasting effect can be excellent.

The cosmetic composition according to an embodiment of the present invention does not contain wax and thus includes pullulan, thereby easily absorbing water upon contact with lukewarm water and having a peel off effect, thus making it easy to cleanse.

In one embodiment, the cosmetic composition may further include an emulsion or dispersion type film forming agent containing an acrylic monomer other than pullulan.

The emulsion or dispersion type film forming agent containing the acrylic monomer is an acrylate copolymer, an acrylate / ethylhexyl acrylate copolymer, styrene / acrylate copolymer, ammonium acrylate copolymer, styrene / acrylate / ammonium meta Acrylate copolymers, FV, polyvinyl alcohol, acrylate / V copolymers, acrylate / octylacrylamide copolymers, octylacrylamide / acrylates / butylaminoethylmethacrylate copolymers, gum arabic, maltodextrin And, and may be one or more of maltodextrin / V copolymer, but is not limited thereto.

The emulsion or dispersion type film forming agent containing the acrylic monomer is 10 to 60% by weight, 20 to 60% by weight, 30 to 60% by weight, 40 to 60% by weight, 10 to 50% by weight, based on the total weight of the composition 20 to 50 wt%, 30 to 50 wt%, 40 to 50 wt%, 10 to 40 wt%, 20 to 40 wt%, 30 to 40 wt%, 10 to 30 wt%, or 20 to 30 wt% But it is not limited thereto. If the content of the film-forming agent is out of the above range, the drying rate of the cosmetic composition is too fast, there may be a problem in the application, problems such as falling powder may occur.

In one embodiment, the cosmetic composition may further comprise a viscosity modifier.

The viscosity modifier is an acrylate copolymer, polyacrylate, sodium polyacrylate, carbomer, acrylamide, cellulose gum, cellulose, hydroxyethyl cellulose, magnesium aluminum silicate, xanthan gum, bentonite, montmorillonite, hydroxypropylmethyl cellulose , Hydroxypropylmethylcellulose stearoxy ether, acrylamide / sodium acryloyl dimethyl taurate copolymer, hydroxyethyl acrylate / sodium acryloyl dimethyl taurate copolymer, sodium acrylate / sodium acryloyl dimethyl tau At least one of a late copolymer, and sodium acrylate / acryloyl dimethyl tartrate / dimethylacrylamide crosspolymer may be used, but is not limited thereto.

The viscosity modifier may be included in 0.1 to 10% by weight, or 1.0 to 10% by weight based on the total weight of the composition, but is not limited thereto. If the content of the viscosity modifier is less than 0.1% by weight, the hardness may not be formed and cosmetic effects such as mascara may not appear or may not be dried well. If the content exceeds 10% by weight, the cosmetic composition may be easily dried or applied. Falling problems can occur.

In one embodiment, the cosmetic composition is pullulan; Emulsion or dispersion type film formers containing acrylic monomers; And it may include a viscosity modifier.

In one embodiment, the cosmetic composition is 0.1 to 5.0% by weight of pullulan based on the total weight of the composition; An emulsion or dispersion type film former containing 10 to 60% by weight of an acrylic monomer; And it may include 0.1 to 10% by weight of viscosity regulator.

In one embodiment, the cosmetic composition may further comprise a powder. Powders may be selected in the appropriate type and content to improve drying speed or volume. The powder may be one or more of silica, mica, and nylon, but is not limited thereto.

In one embodiment, the cosmetic composition may have a formulation of any one of mascara, eyebrow, and eyeliner, but is not limited thereto.

Cosmetic compositions according to one embodiment also contain additional ingredients commonly used in cosmetics such as purified water, thickeners, dispersants, pigments, flavors, fillers, preservatives, preservatives, neutralizing agents, sunscreens, sweeteners, vitamins, free-radical scavengers It may further comprise any conventional cosmetic ingredients that may be selected from metal ion sequestrants, and mixtures thereof.

Those skilled in the art can select any additional ingredients and / or amounts thereof such that the advantageous properties of the compositions according to the present disclosure are not adversely or substantially affected by the expected addition.

Cosmetic composition for wax-free eye makeup including pullulan according to one aspect does not contain wax, and has a cosmetic effect such as volume, curling power, including pullulan, while improving blackness, stability over time, and long lasting. Is excellent. In addition, since it has a peel-off effect, cleansing is easy when contacting with lukewarm water. Therefore, it can be used as a product for eye makeup having excellent performance such as mascara, eyebrow, eyeliner and the like.

FIG. 1 is a graph in which the mascara compositions of Example 1, Comparative Example 2 and Comparative Example 3 are applied to actual eyelashes, and then the volume is measured, and the average volume change rate is obtained to evaluate the effect of improving eyelash volume.
FIG. 2 is a graph in which the mascara compositions of Examples 1 to 3 and Comparative Example 1 are applied to the actual eyelashes, the volume is measured, and the average volume change rate is obtained to evaluate the effect of improving the eyelash volume.
3 is a picture of the volume measurement before (up) and after (down) the mascara composition of Example 1 is applied to the actual eyelashes.
4 is a picture of the volume measurement before (up) and after (down) the mascara composition of Example 2 is applied to the actual eyelashes.
5 is a photograph showing the blackness evaluation results of the general oil-in-water (O / W) emulsion type mascara (left) and the mascara composition (right) of Example 2. FIG.
6 is a photograph showing the appearance after 10 minutes of shaking of the mascara composition of Examples 1 to 3 and the mascara composition of Comparative Example 1.
7 is a photograph showing a state after 10 minutes of shaking of a general oil-in-water (O / W) emulsion type mascara.
Figure 8 is a photograph confirming the peel off effect of the samples of Examples 1 to 3 and Comparative Example 1 after the shaking test.
Figure 9 shows the time of the mascara compositions of Examples 1 to 3 and Comparative Examples 1 to 3 (immediately, after 1 day, after 3 days, after 7 days, after 14 days, after 30 days, after 60 days, after 90 days) It is a graph showing the hardness (Hardness) according to.

Hereinafter, the present invention will be described in more detail with reference to Examples. However, these examples are for illustrative purposes only and the scope of the present invention is not limited to these examples.

Examples 1-3 and Comparative Examples 1-3: Preparation of Mascara Composition

Examples 1 to 3 prepared mascara compositions including pullulan and no wax by varying the amount of pullulan. First, each raw material was weighed in a beaker and then uniformly dispersed and mixed at room temperature (RT, ° C.) using a disper and a homo mixer. Specifically, the disperser was uniformly dispersed for about 20 minutes at 1,000 rpm with a disper, and then preservative and viscosity regulator were added in the last step and mixed at about 6,000 rpm or more with a homomixer for about 10 minutes. The viscosity modifier was used polyacrylate. Each bubble was then removed and cooled when the temperature rose by the frictional force to prepare each composition.

Comparative Example 1 was prepared in the same manner as in Examples 1 to 3, except that pullulan was not included.

Comparative Example 2 was prepared in the same manner as in Example 1 except for using hydroxyethyl cellulose instead of pullulan.

Comparative Example 3 was prepared in the same manner as in Example 1, except that polyvinyl alcohol was used instead of pullulan.

Table 1 shows the specific components and contents of the mascara composition prepared according to Examples 1 to 3 and Comparative Examples 1 to 3. Unless stated otherwise herein, the component content is percent by weight.

ingredient Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 2 Purified water to 100 to 100 to 100 to 100 to 100 to 100 Pullulan 1.0 3.0 5.0 - - - Hydroxyethyl cellulose - - - - 1.0 - Polyvinyl alcohol - - - - - 1.0 Polysorbate 80 0.1 0.1 0.1 0.1 0.1 0.1 Butylene glycol 3.0 3.0 3.0 3.0 3.0 3.0 Iron oxide 10.0 10.0 10.0 10.0 10.0 10.0 Microcrystalline Cellulose One One One One One One Acrylate copolymer 10-60 10-60 10-60 10-60 10-60 10-60 ethanol 0.1 ~ 5.0 0.1 ~ 5.0 0.1 ~ 5.0 0.1 ~ 5.0 0.1 ~ 5.0 0.1 ~ 5.0 antiseptic Quantity Quantity Quantity Quantity Quantity Quantity Polyacrylate 0.1-10.0 0.1-10.0 0.1-10.0 0.1-10.0 0.1-10.0 0.1-10.0

As a result of the production, black cream-like mascara compositions of Examples 1-3 and Comparative Examples 1-3 were obtained.

Experimental Example 1 Evaluation of Volume by Different Kinds of Water-Soluble Film Forming Agent

The type of water-soluble film-forming agent is very diverse, and may exhibit various performances depending on the content of use and purpose. In order to evaluate the volume force according to the type of water-soluble film forming agent, the experiment was performed on the mascara composition prepared according to Example 1 and Comparative Examples 2-3.

Specifically, five healthy adult women (average age 28.8 years) were photographed before and after using mascara products. After the photographs were obtained, the volume of the eyelashes was measured before and after using the product using an image pro analysis, and the average volume change rate of the eyelashes after use was evaluated to evaluate the effect of improving the eyelash volume. The measuring device used Sony, A7R.

FIG. 1 is a graph in which the mascara compositions of Example 1, Comparative Example 2, and Comparative Example 3 are applied to actual eyelashes, and then the volume is measured, and the average volume change rate is obtained to evaluate the effect of improving eyelash volume.

As shown in FIG. 1, the mascara composition of Example 1 using pullulan as a water-soluble film forming agent was confirmed that the eyelash volume improving effect was superior to Comparative Example 2 using hydroxyethyl cellulose or Comparative Example 3 using polyvinyl alcohol. Could.

Experimental Example 2: Evaluation of the volume force according to the presence and content of pullulan

Pullulan is a water-soluble polysaccharide, forms a unique viscoelasticity and a coating, and is widely used as a coating agent in food and pharmaceutical products. In order to evaluate the volume force according to the presence and content of pullulan, the experiment was performed on the mascara composition prepared according to Examples 1 to 3 and Comparative Example 1. Experimental method was carried out in the same manner as in Experiment 1.

FIG. 2 is a graph in which the mascara compositions of Examples 1 to 3 and Comparative Example 1 were applied to the actual eyelashes, and then the volume was measured, and the average volume change rate was obtained to evaluate the effect of improving the eyelash volume.

Figure 3 is a picture of the volume (pixel) measurement before (top) and after (bottom) of applying the mascara composition of Example 1 to the actual eyelashes.

4 is a picture of the volume measurement before (up) and after (down) the mascara composition of Example 2 is applied to the actual eyelashes.

As shown in FIG. 2, the mascara compositions of Examples 1 to 3 containing pullulan were found to have a very good volume improvement effect compared to Comparative Example 1 containing no pullulan. In addition, it was confirmed that the volume effect is improved as the content of pullulan is increased through Examples 1 to 3. However, the difference between the results of Example 2 and Example 3 was not large.

Experimental Example 3: Sensory Evaluation

Pullulan is strongly sticky and can increase the volume effect when it is contained in the mascara liquid, but it can also bring a decrease in the drying rate, so to determine the optimal pullulan content through content-specific experiments. Therefore, sensory evaluation was performed on the mascara compositions prepared according to Examples 1 to 3 and Comparative Examples 1 to 3.

Specifically, 10 adult women were to use each mascara composition, and then evaluated for applicability, dripping powder, under-eye burial, fixation force. The applicability was evaluated to be excellent if the mascara composition was gently applied to the eyelashes and there was no clumping. Powder fall was evaluated to be excellent if there was no drop of mascara powder after applying the mascara composition to the eyelashes and drying. The under eyelid mascara composition was applied to the eyelashes and dried, and after 3 hours, there was no under eyelid evaluation. Fixing power was evaluated as excellent if the curling of the eyelashes is maintained well over time after applying the mascara composition to the eyelashes and dried.

- Evaluation standard

◎: excellent, ○: good, △: normal, X: bad

Application Powder falling Buried under eyes Holding force Example 1 ◎ ◎ ◎ ○ Example 2 ◎ ◎ ◎ ○ Example 3 ○ ◎ △ X Comparative Example 1 ◎ ○ ○ ○ Comparative Example 2 ○ ○ △ △ Comparative Example 3 ○ ○ ○ △

As shown in Table 2, it was confirmed that the mascara composition of the Example using pullulan was excellent in the overall sensory evaluation compared with Comparative Example 1 which does not contain pullulan or Comparative Examples 2 and 3 which use another kind of water-soluble film forming agent. . On the other hand, Example 3, the content of pullulan is 5% by weight, compared to Examples 1 and 2, rather than the drying speed was slow and sticky appeared strong it could be confirmed that under-eye smear occurs or the fixing force is lowered. Therefore, when using pullulan at less than 5% by weight, it was found that not only the volume, application property and fixation force were excellent, but also powder dropping and under-eye staining hardly occurred.

Experimental Example 4: Evaluation of Blackness Enhancement

When the wax is used in the mascara composition or designed as an emulsified type having a high content of the internal phase, the color of the base is milky or pale yellow so that a dark blackness does not appear even when black iron oxide is added. Therefore, the effect of increasing the blackness of the mascara by not using a wax can be expected, so experiments were made to confirm this.

Specifically, the mascara composition prepared according to Example 2 and a general oil-in-water (O / W) emulsion type mascara were applied to the skin and sufficiently dried, and then the colors were compared. General oil-in-water (O / W) emulsified type mascara composition was prepared according to the components and contents of Table 3 below. In the case of general oil-in-water (O / W) emulsifying type mascara, the total content of the oily component including the wax was about 20% by weight, and iron oxide was used in the same manner as in Example 2.

General oil-in-water (O / W) oil painting type mascara ingredient Content (wt%) Carnauba Wax 3.00 Beeswax 8.00 Cetearyl Alcohol 1.00 Polysorbate 60 0.50 Sorbitan sesquioleate 0.50 Stearic acid 6.00 Iron oxide 10.00 Purified water To 100 Pullulan 3.00 Tromethamine 2.00 Butylene glycol 5.00 antiseptic Quantity Acrylate copolymer 20.00

5 is a photograph showing the blackness evaluation results of the general oil-in-water (O / W) emulsion type mascara (left) and the mascara composition (right) of Example 2. FIG.

As shown in Fig. 5, the general oil-in-water (O / W) emulsion type mascara was not good in blackness. This is a phenomenon in which the black color of iron oxide appears bluish as the inner phase including the wax is emulsified in the water phase and the color of the base itself becomes milky or pale yellow. On the contrary, since the mascara composition of Example 2 did not use wax, it was easy to confirm that the blackness appeared more simply by applying the skin.

Experimental Example 5: Long Lasting Effect

Experiments for evaluating the long lasting effect on the mascara composition prepared according to Examples 1 to 3 and Comparative Example 1 and the mascara liquid of the general oil-in-water (O / W) type.

Specifically, each mascara solution was evenly applied about 20 times to the false eyelashes and dried at room temperature for 8 hours. After that, the mascara-coated artificial eyelashes were fixed to an experimental dish and filled with 300 g of purified water at about 30 ° C. A laboratory dish with artificial eyelashes was placed on a Lab Shaker (Laboratory Instruments, WiseShake, SHO-1D), shaken at 100 rpm, checked for 10 minutes, and measured up to 120 minutes.

Table 4 shows the results of evaluation of the long lasting effect of the mascara compositions of Examples 1 to 3 and Comparative Example 1 and general oil-in-water (O / W) type mascara. The number of mascara deviated from the false eyelashes was confirmed and evaluated according to the following evaluation criteria.

- Evaluation standard

◎: Good, ○: 1 to 5 departures, △: 6 to 10 departures, X: Many departures

10 minutes 20 minutes 30 minutes 60 minutes 90 minutes 120 minutes Example 1 ◎ ◎ ◎ ◎ ◎ ◎ Example 2 ◎ ◎ ◎ ◎ ◎ ◎ Example 3 ◎ ◎ ◎ ◎ ◎ ◎ Comparative Example 1 ◎ ◎ ◎ ◎ ◎ ◎ General O / W ○ △ X X X X

6 is a photograph showing the appearance after 10 minutes of shaking of the mascara composition of Examples 1 to 3 and the mascara composition of Comparative Example 1.

7 is a photograph showing a state after 10 minutes of shaking of a general oil-in-water (O / W) emulsion type mascara.

As shown in Table 4 and Figures 6 and 7, the wax-free formulations of Examples 1 to 3 and Comparative Example 1 were all shaken under purified water for 120 minutes. As a result, mascara lumps were not attached at all on the false eyelashes. It was confirmed. On the other hand, regular oil-in-water (O / W) emulsifying type mascara was able to confirm that the mascara liquid was deviated or released from the false eyelashes after 10 minutes. On the basis of this, it was concluded that the wax-free formulation has a long lasting effect. Therefore, the wax-free mascara formulation was considered to be a very satisfactory result for the consumers who enjoy leisure activities.

Experimental Example 6: Peel off effect

Mascara should be easy to cleanse. Difficult or uncomfortable cleansing is an important factor in selecting mascara because eyelashes may fall out or become irritated around the eyes. Since the wax-free formulation is resistant to friction such as water or moisture, and is easily peeled off like a sticker, an experiment was conducted to confirm this.

Specifically, in the Experimental Example 5, the samples having completed the shaking tests for Examples 1 to 3 and Comparative Example 1 were placed on a glass plate, and the strands were extracted one by one from the false eyelashes.

Figure 8 is a photograph confirming the peel off effect of the samples of Examples 1 to 3 and Comparative Example 1 after the shaking test.

As shown in FIG. 8, the mascara compositions of Examples 1 to 3 and Comparative Example 1 were easily removed from artificial eyelashes, and thus, the peel off effect was confirmed to be excellent. In Experimental Example 2, the effect of improving the volumetric power by increasing the pullulan content was already confirmed, and the water resistance or the peel-off effect on the water was reduced or other problems occurred due to the increase in the pullulan content according to the improvement of the volumetric power. It was found that not.

Experimental Example 7: Change over time

When wax is contained in the constituents of mascara, crystallization of the wax occurs first, and the concentration of the inner phase increases as the water evaporates. Secondly, the mascara hardens as a result of this process. This may cause problems such as roughness and powder fall. However, if the wax does not contain a wax in the inner phase does not have a problem of crystallization as a primary cause is expected to exhibit a great effect on the stability of the product, it was confirmed through experiments.

Specifically, the hardness (Hardness) change over time for three months for the mascara composition prepared according to Examples 1-3 and Comparative Examples 1-3.

-Hardness measuring device: Rheo Meter SUN CR-3000EX-L

Table 5 is a table which shows the hardness measurement result with time of the mascara composition of Examples 1-3 and Comparative Examples 1-3.

Immediately 1 day 3 days 7 days 14 days 30 days 60 days 90 days Example 1 107 109 112 113 111 113 112 110 Example 2 109 115 122 117 123 121 120 122 Example 3 112 115 128 126 128 128 127 127 Comparative Example 1 99 101 105 104 103 103 105 104 Comparative Example 2 113 119 120 127 125 126 127 126 Comparative Example 3 135 140 145 144 142 141 144 142

Figure 9 shows the time of the mascara compositions of Examples 1 to 3 and Comparative Examples 1 to 3 (immediately, after 1 day, after 3 days, after 7 days, after 14 days, after 30 days, after 60 days, after 90 days) It is a graph showing the hardness (Hardness) according to.

As shown in Table 5 and FIG. 9, the mascara compositions of Examples 1 to 3 and Comparative Examples 1 to 3 did not have a large difference in hardness change with time. On the basis of this, it could be concluded that containing no wax component or less wax component significantly improved the quality of the product in terms of changes over time.

Claims (10)

Cosmetic composition for wax-free eye makeup comprising pullulan. The cosmetic composition of claim 1, wherein the pullulan is included in an amount of 0.1 to 5.0 wt% based on the total weight of the composition. The cosmetic composition for wax-free eye makeup of claim 1, further comprising a film forming agent, wherein the film forming agent comprises a copolymer containing an acrylic monomer-derived repeating unit. The method of claim 3, wherein the copolymer is an acrylate copolymer, an acrylate / ethylhexyl acrylate copolymer, styrene / acrylate copolymer, ammonium acrylate copolymer, styrene / acrylate / ammonium methacrylate copolymer, VP, polyvinyl alcohol, acrylate / V copolymer, acrylate / octyl acrylamide copolymer, octyl acrylamide / acrylate / butylaminoethyl methacrylate copolymer, gum arabic, maltodextrin, and maltodextrin / VP Cosmetic composition for wax-free eye makeup, which is at least one of copolymers. The wax-free eye makeup cosmetic composition of claim 3, wherein the film former is included in an amount of 10 to 60 wt% based on the total weight of the composition. The cosmetic composition for wax-free eye makeup of claim 1, further comprising a viscosity modifier. The method of claim 6, wherein the viscosity modifier is an acrylate copolymer, polyacrylate, sodium polyacrylate, carbomer, acrylamide, cellulose gum, cellulose, hydroxyethyl cellulose, magnesium aluminum silicate, xanthan gum, bentonite, montmorillonite, Hydroxypropylmethylcellulose, hydroxypropylmethylcellulose stearoxyether, acrylamide / sodium acryloyldimethyltaurate copolymer, hydroxyethylacrylate / sodium acryloyldimethyltaurate copolymer, sodium acrylate / sodium Cosmetic composition for wax-free eye makeup, which is at least one of acryloyldimethyl taurate copolymer and sodium acrylate / acryloyl dimethyl tartrate / dimethylacrylamide crosspolymer. The wax-free eye makeup cosmetic composition of claim 6, wherein the viscosity modifier is included in an amount of 0.1 to 10 wt% based on the total weight of the composition. The method of claim 1, wherein the total weight of the composition, 0.1 to 5.0% by weight pullulan; 10 to 60% by weight of a film forming agent comprising a copolymer containing an acrylic monomer-derived repeating unit; And 0.1 to 10% by weight of a wax-free eye makeup cosmetic composition comprising a viscosity modifier. The cosmetic composition for wax-free eye makeup of claim 1, which has a formulation of any one of mascara, eyebrow, and eyeliner.

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