KR101941179B1 - Composition for repairing and reinforcing concrete structure comprising high strength mortar, and method of repairing and reinforcing concrete structures using the same - Google Patents

Abstract

The present invention relates to a concrete structure repairing and reinforcing material composition including high strength mortar and a method of repairing and reinforcing a concrete structure using the same, and more specifically, to a mortar composition for repairing and reinforcing a concrete structure and a method of repairing and reinforcing a concrete structure using the same. The mortar composition for repairing and reinforcing a concrete structure has an excellent water repellent effect and is capable of maintaining a low absorption rate when repairing and reinforcing a damaged portion of a deteriorated concrete structure, thereby having excellent durability and physical properties such as compressive strength, bending strength and the like, reducing a unit weight of mortar, and improving initial and long-term adhesion performance, resulting in excellent repairing and reinforcing constructability for a concrete structure. At the same time, since an organic solvent is not used, the mortar composition for repairing and reinforcing a concrete structure is eco-friendly. Also, since mortar can be tightly formed, various stresses are uniformly absorbed, thereby improving repairing and reinforcing performance of a concrete structure, and maintaining effects for a long period of time.

Description

TECHNICAL FIELD The present invention relates to a concrete reinforcing steel reinforced concrete structure comprising a high strength mortar and a reinforcing concrete structure having a high strength mortar,

The present invention relates to a mortar composition for repairing and reinforcing concrete structures and a method of repairing and reinforcing concrete structures using the same. More particularly, the present invention relates to a mortar composition for repairing and reinforcing a damaged portion of a deteriorated concrete structure, It has excellent durability, excellent physical properties such as compressive strength and bending strength, reduces the unit weight of mortar, improves initial and long-term adhesion performance, and has excellent maintenance and reinforcement workability for concrete structures. It is environment- The present invention relates to a method for repairing and reinforcing concrete structures that can uniformly absorb various stresses, thereby improving the repair and reinforcement performance of concrete structures and maintaining the effect for a long period of time.

Concrete structures are subjected to various natural or artificial actions after construction, resulting in physical performance deterioration due to physical and chemical deformation depending on the service years. Especially, in recent years, there has been an increasing effort to restore safety and functionality by carrying out maintenance in terms of securing safety and performance of construction structures. When the aging phenomenon of the construction structure accelerates, it causes the sectional defects in the structure, that is, the concrete due to the expansion pressure caused by the corrosion of steel bars, freezing and thawing, and carbonation phenomenon, Which can cause problems.

Therefore, in order to secure the stability and performance of the reinforced concrete structure, it is necessary to perform maintenance and reinforcement at the beginning of deterioration to further suppress the deterioration progress and improve the durability performance.

In order to restore the section to its original performance and shape after repairing the concrete structure, it is necessary to repair the section by repairing the section by the deterioration factors such as deterioration of the concrete, corrosion of the steel, It is a common practice to repair the material by filling or spraying it.

On the other hand, in order to reinforce concrete structures, properties such as durability, adhesive strength and quick-setting properties of the mortar composition for repair and reinforcement are required, and economical problems of materials are also important factors.

Korean Patent No. 10-0999354 discloses a method of reducing the shrinkage expansion rate and reducing the shrinkage rate of the product by using the cement cement and the alpha type hemispherical gypsum produced by using the artificial marble waste powder, cement sludge, The mortar for repair and reinforcement of concrete structure is proposed to induce rapid hardening, quickness of operation and economical efficiency.

In addition, Korean Patent No. 10-1528120 discloses a reinforced concrete structure which can maintain high physical properties such as bending strength, tensile strength and compressive strength in repairing and reinforcing a damaged concrete structure, has excellent adhesion with concrete structures, And at the same time, it has excellent resistance to salting and shielding of radioactivity, and is excellent in storage stability because it does not harden even during long-term storage, and the components are separated and mixed before use, It is suggested that the repair and reinforcement method of reinforced concrete structure and the concrete structure using this method are suitable for use in the field without any loss of materials and environmental pollution.

However, the mortar composition proposed in this patent is excellent in quick-hardness, workability and economical efficiency, but is somewhat insufficient in terms of adhesion strength and durability to the concrete surface to be applied, and thus needs to be supplemented further. In particular, There is a great need for further improvement of the technology that can improve the resistance to freezing and thawing.

The present invention has been developed in order to overcome the limitations of the conventional technique as described above, and it is an object of the present invention to provide a waterproof concrete structure which is excellent in durability, It has excellent physical properties, reduces the unit weight of mortar, improves initial and long-term adhesion performance, and has excellent repair and reinforcement workability for concrete structures. It does not use organic solvents and is eco-friendly. The present invention provides a method of repairing and reinforcing a concrete structure that can uniformly absorb and uniformly absorb and repair the concrete structure, thereby improving the repairing and reinforcing performance of the concrete structure and maintaining the effect for a long period of time.

As a means for solving the above-mentioned problems,

A. A basic repairing step of finishing the repair surface of the concrete structure to be repaired;

B. applying an alkaline recovery agent to apply the alkaline recovery agent to the trimmed surface to be applied;

C. a reinforcing layer forming step of applying mortar for repairing concrete structure to the surface to which the alkali remover is applied to form a reinforcing layer and then hardening; And

D. forming a coating layer on the surface of the formed reinforcing layer to coat and coat the surface protective material,

In the above B, the alkali remover may be selected from the group consisting of 10 to 50 wt% of potassium silicate, 10 to 40 wt% of an aqueous acrylic emulsion, 0.1 to 5 wt% of potassium methylsiliconate, 0.1 to 5 wt% of a binder resin and 0.1 to 10 wt% And a balance of water is used,

In the C, the mortar for repairing and reinforcing concrete structures

1 to 10 parts by weight of a polymer, 0.1 to 8 parts by weight of silica fume and 0.5 to 5.0 parts by weight of a ceramic composite fiber based on 100 parts by weight of cement; 1 to 8 parts by weight of a strength-increasing agent; 30 to 50 parts by weight of aggregate; 0.5 to 2.0 parts by weight of a shrinkage inhibitor; 3 to 7 parts by weight of a polyvinyl alcohol (PVA) powder resin; 0.1 to 1.0 part by weight of an antifoaming agent; 5 to 10 parts by weight of an expanding agent; 1 to 5 parts by weight of a powdery silicone water repellent; 5 to 15 parts by weight of a durability enhancer; 1 to 15 parts by weight of a limestone powder component; And 0.1 to 2 parts by weight of a nano-metal oxide powder,

The application of the surface protective material in D above

a. A primary surface protection material containing an acrylic resin, a rubber chip, an airgel and a powder component is applied,

b. Applying a secondary surface protective material comprising 100 parts by weight of a liquid component containing methyl methacrylate (MMA) resin and 30 to 300 parts by weight of an inorganic powder component on the surface of the primary surface protective agent; The present invention provides a method of repairing and reinforcing concrete structures.

In one embodiment of the present invention, the potassium silicate used in the step B has a molar ratio of SiO ₂ to K ₂ O of 1: 2.8 to 3.4, a solid content of 30 to 40 wt%, and a pH of 10 to 12 .

In one embodiment of the present invention, the fibers in the step C are at least one selected from glass fibers, steel fibers, polyester fibers, nylon fibers, polypropylene (PP) fibers, cellulose fibers and polyethylene fibers .

Also, in one embodiment of the present invention, the durability enhancer of the step (C) comprises 30 to 40 parts by weight of curing composition, 1 to 3 parts by weight of montmorillonite clay mineral, 1 to 2 parts by weight of aluminum salt, And 5 to 7 parts by weight of a curing accelerator, 12 to 18 parts by weight of a clay mineral, 0.1 to 2 parts by weight of a nano zinc powder, 0.1 to 0.5 parts by weight of a stabilizer and 60 to 70 parts by weight of water, And the second composition is mixed.

Also, in one embodiment of the present invention, the nano-metal oxide powder of the step C is a graphite oxide coated surface.

Also, in one embodiment of the present invention, the powder component of the a in the step (D) comprises 30 to 50% by weight of mica having a particle diameter of 1 to 100 μm, 30 to 50% by weight of a mica, 5 to 20% Are mixed with each other.

Further, in one embodiment of the present invention, the inorganic powder component of b in step D comprises silica powder, alumina cement and bentonite powder.

By using the repair and reinforcement method of the concrete structure according to the present invention, it is possible to maintain the initial and long-term durability, water resistance and weatherability by incorporating the water repellent component into the mortar composition so as to increase the water repellency and lower the water absorption rate to improve the durability By constructing a mortar composition using lightweight aggregate to improve the workability of a concrete structure, it is possible to perform a rapid construction even in the case of a bridge or a building to which shock or vibration is applied, so that the workability and workability are excellent , The shrinkability of the composition can be lowered and the strength can be exhibited within a short period of time. By incorporating the fiber and the PVA powder resin in the mortar composition, the initial and long-term adhesion performance and crack resistance can be improved and the durability can be further improved. And aluminum salts and Na Since the durability enhancer based on zinc powder is included, the adhesion and binding force between the constituents are enhanced and the nano metal oxide powder can be used to fill the nano-sized gap. Therefore, the durability of the concrete structure can be further improved have.

In addition, since the industrial by-products can be recycled at the final stage, it can be used as a surface protecting material containing environment-friendly, MMA-based reactive resin, and is excellent in properties such as chemical resistance, water resistance, anti- It has an advantage of being excellent in resistance to salting and also capable of increasing anti-neutralization effect and waterproofing effect.

Hereinafter, the present invention will be described in detail.

The method for repairing and reinforcing a concrete structure according to the present invention proceeds in the following order. In other words,

A. A basic repairing step of finishing the repair surface of the concrete structure to be repaired;

B. applying an alkaline recovery agent to apply the alkaline recovery agent to the trimmed surface to be applied;

C. a reinforcing layer forming step of applying mortar for repairing concrete structure to the surface to which the alkali remover is applied to form a reinforcing layer and then hardening; And

D. A coating layer forming step of applying a surface protecting material to the surface of the formed reinforcing layer to coat the surface protecting material.

Hereinafter, each step of the present invention will be described in detail.

First, the damaged surface of the damaged concrete structure is chipped, and the surface or section is trimmed until the undamaged portion is removed. That is, chipping is performed on the section of the damaged concrete or the high pressure washing water is sprayed to remove the deteriorated portion and then trim the damaged portion.

Subsequently, an alkaline recovery agent is applied to the surface of the trimmed concrete structure to be applied.

Wherein the alkali recovery agent comprises 10 to 50% by weight of potassium silicate, 10 to 40% by weight of an aqueous acrylic emulsion, 0.1 to 5% by weight of potassium methylsiliconate, 0.1 to 5% by weight of a binder resin and 0.1 to 10% by weight of dimethylammonium chloride, And a mixture of water may be used. More specifically, the alkaline recovery agent is preferably used in an amount of 10 to 50% by weight of potassium silicate, 10 to 40% by weight of an aqueous acrylic emulsion having a nonvolatile content of 40% by weight or more, 0.1 to 5% by weight of a binder resin, 0.1 to 10% by weight of dimethyl ammonium chloride, Of water.

The potassium silicate reacts with lime in the concrete to form potassium silicate hydrate by crosslinking. It enhances the mechanical properties and strengthens the water resistance, and is excellent in prevention of salting and neutralization. The potassium silicate reacts with carbon dioxide Less white matter and less carbonate formation. The potassium silicate preferably has a K ₂ O molar ratio of 1: 2.8 to 1: 3.4 relative to SiO ₂ , a solid content of 35 to 45 wt%, and a pH of 10 to 12. It is more preferable that the solid content is 40 to 45% by weight. When potassium silicate in the above range is used, the bonding strength with the aqueous acrylic emulsion according to the present invention, the binder resin, potassium methylsiliconate and dimethyl ammonium chloride is improved .

The alkali remover of the present invention includes potassium silicate in the range of 10 to 50 wt%. If the content of the potassium silicate is less than 10% by weight, the effect of preventing saltiness or neutralization hardly occurs. If the content of potassium silicate is more than 50% by weight, the strength of the concrete surface may be decreased and the bonding strength with other compositions may be decreased.

In the present invention, the aqueous acrylic emulsion imparts water resistance, penetrates the concrete surface to fill the voids in the concrete, improves the water tightness, and improves the durability, strength and mechanical properties of the concrete.

The content of the aqueous acrylic emulsion in the composition is preferably 10 to 40% by weight. If the content is less than 10% by weight, it is difficult to expect the effect of improving the physical properties of concrete. If the content is more than 40% by weight, water resistance, anti-neutralization and preservative effect are deteriorated. At this time, the aqueous acrylic emulsion used is preferably an aqueous alkaline solution having a nonvolatile content of 40% or more, a viscosity of 200 cps at room temperature, and a pH of 8 or more so as to improve compatibility with the inorganic strengthening agent.

The alkali recovery agent of the present invention may contain the binder resin in the range of 0.1 to 5% by weight. The binder resin improves the bonding force between the compositions and can be hardened with time, thereby improving the mechanical strength and watertightness of the inside of the concrete. The composition according to the present invention can simultaneously exhibit improvements in mechanical properties such as water resistance, chemical resistance, abrasion resistance, durability and strength, and antimicrobial properties due to the addition of the binder resin. The binder resin of the present invention may be selected from the group consisting of an epoxy resin, an acrylic resin, a polydimethylsiloxane resin, a petroleum resin, a polyurethane resin, an amino resin, and a polyester resin.

The potassium methylsiliconate serves to penetrate the surface reinforcing component into the concrete structure and to impart water repellency, and preferably has a solid content of 40 to 45% by weight and a pH of 12 to 14. The amount of potassium methylsiliconate is preferably in the range of 0.1 to 5% by weight. When the content is less than 0.1% by weight, the effect of water repellency is insignificant. When the content is more than 5% by weight, miscibility decreases.

In addition, the dimethyl ammonium chloride of the present invention is intended to prevent various environmental pollution caused by concrete containing cement and various chemical products and to inhibit harmful bacteria to human body, and it is contained in a range of 0.1 to 10 wt% . If the content is less than 0.1% by weight, the antibacterial property is lowered to occur on the concrete surface to cause pollution, and the effect of inhibiting bacteria that threaten the health of the human body is insignificant. When the content exceeds 10% by weight, the compatibility becomes poor.

The present invention has the effect of applying the above-mentioned alkali remover to the concrete surface to make the structure of the concrete dense, suppress neutralization, and improve the performance.

Subsequently, mortar for reinforcing concrete structures is applied to the surface to which the alkali remover is applied to form a reinforcing layer and then cured.

In the present invention, the mortar for repairing and reinforcing concrete structures comprises the following components. In other words,

1 to 10 parts by weight of a polymer, 0.1 to 8 parts by weight of silica fume and 0.5 to 5.0 parts by weight of a ceramic composite fiber based on 100 parts by weight of cement; 1 to 8 parts by weight of a strength-increasing agent; 30 to 50 parts by weight of aggregate; 0.5 to 2.0 parts by weight of a shrinkage inhibitor; 3 to 7 parts by weight of a polyvinyl alcohol (PVA) powder resin; 0.1 to 1.0 part by weight of an antifoaming agent; 5 to 10 parts by weight of an expanding agent; 1 to 5 parts by weight of a powdery silicone water repellent; 5 to 15 parts by weight of a durability enhancer; 1 to 15 parts by weight of a limestone powder component; And 0.1 to 2 parts by weight of a nano-metal oxide powder.

In the present invention, the cement may be one or more mixed cements selected from the group consisting of portland cement, slag cement, alumina cement and ultra fast cement. Preferably, the cement is Portland cement. Specifically, in the case of portland cement, the major components are C ₃ S 51%, C ₂ S 25%, C ₃ A 9%, C ₄ AF 9% and CaSO ₄ 4%, and the specific surface area is around 3,300 cm ² / g Is preferably used.

When mixed cement is used, it may include 40 to 70% by weight of portland cement, 20 to 40% by weight of slag cement, 5 to 25% by weight of alumina cement, and a remaining amount of quick hardening cement.

Among them, slag cement suppresses temperature rise due to heat of hydration due to the stimulation action of calcium hydroxide or sulfate, inhibits alkali silica reaction, improves chemical resistance to sulfate and seawater, and improves chloride ion and oxygen penetration resistance.

Alumina cement is a cement having relatively high alumina content as compared with Portland cement. It is excellent in chemical resistance and can be used in an acidic atmosphere. It is a type of crude steel cement having a short curing time. Usually, .

In addition, it is preferable that the ultra fast cement contains anhydrous gypsum and at least 50% by weight of alumina or calcium sulfoaluminate (CSA) and has excellent initial adhesion.

In the present invention, the polymer serves to improve the physical properties of the mortar by increasing the compatibility and adherence between the mortar components. The polymer improves the physical properties of the mortar, and includes polyvinyl acetate, polyvinyl acetate silane end-shrinkable polymer, polyvinyl alcohol, polyvinyl ester silane end- , Methyl methacrylate-butyl acrylate and styrene-butadiene rubber latex, and preferably at least one selected from polyvinyl acetate, polyvinyl alcohol, methyl methacrylate-butyl acrylate, and styrene-butadiene rubber latex One or more species can be used. The amount of the polymer used in the present invention is preferably in the range of 1 to 10 parts by weight based on 100 parts by weight of the cement.

In the present invention, the silica fume is an amorphous activated silica having an average particle diameter of about 0.1 to 0.5 mm, which is an amorphous active silica. The silica fume reacts with calcium hydroxide and changes to calcium hydrate at room temperature to have a super pozzolanic property.

The reason for adding the silica fume to the mortar composition in the present invention is to improve the dispersibility and water reducing effect by the ball bearing effect by the spherical particles and improve the watertightness and strength of the shotcrete due to the charging effect of silica fume between the cement particles, This is because an improvement in adhesion improves the reduction of the ground amount, the inhibition of the reaction of the alkali silica, and the improvement of the chemical resistance.

In the present invention, since the fiber can reduce the surface crack (crack) during curing as well as the flexural strength and tensile strength, it is effective for the initial construction stability after the mortar application and is used for the purpose of increasing initial dispersibility. In the present invention, it is preferable to use a fiber having a certain degree of hydrophilicity. For example, the fiber may be selected from among glass fiber, steel fiber, polyester fiber, nylon fiber, polypropylene (PP) fiber, cellulose fiber and polyethylene fiber But it is not limited to these.

In the present invention, the strength-increasing agent acts to improve concrete properties before and after curing by physicochemical action. Specific examples thereof include a nitrate salt having an alkali metal, a nitrate salt having an alkaline earth metal, A nitrate salt, an Al ₂ O ₃ powder and an Al ₂ Si ₂ O ₇ powder may be used.

In the present invention, it is preferable to use the porous lightweight aggregate having an average diameter of 50 to 200 탆 and a specific gravity of 0.7 to 1.4. Specifically, the lightweight aggregate is preferably made of porous phyllite, and the porous filler lightweight aggregate may have increased water content due to porosity and flowability, so that the concrete structure through the water-repellent mortar composition It is possible to mechanize construction at the time of construction of the building.

In the present invention, neopentyl glycol is preferably used as the shrinkage inhibitor. The neopentyl glycol has two alcohol groups symmetrically and two methyl groups at the alpha carbon position, thus showing excellent reactivity to the esterification reaction. In the present invention, the neopentyl glycol may be used in the form of a flake consisting of 100% white crystals or a slurry composed of 90% neopentyl glycol and 10% water.

The polyvinyl alcohol (PVA) powder resin of the present invention not only improves the flowability of the mortar composition due to the ball bearing effect of the polymer particles but also increases the viscosity of the mortar composition to prevent separation, It increases the bending strength and the surface hardness of the mortar while improving the adhesion with the concrete structure, while preventing the deterioration of neutralization, the prevention of chemical erosion and the corrosion of reinforcing bars after repair by lowering various deterioration factors and moisture penetration due to film formation. . In the present invention, the PVA powder resin is a colorless powder obtained by hydrolyzing polyvinyl acetate resin, which is soluble in water and does not dissolve in a common organic solvent.

In the present invention, the antifoaming agent is a component used to remove the macropores in the mortar to improve the strength and appearance of the mortar. In general, an oil-like substance or a water-soluble surfactant having low volatility and high diffusing power is used, , Liquid paraffin and the like; Retentive defoamers such as animal and vegetable oils, sesame oil, castor oil and their alkylene oxide adducts; Fatty acid defoaming agents such as oleic acid, stearic acid and alkylene oxide adducts thereof; Fatty acid ester defoaming agents such as glycerin monoricinolate, alkenyl succinic acid liquid, sorbitol monolaurate, sorbitol trioleate, natural wax and the like; (Poly) oxyalkylene sorbitan fatty acid esters, (poly) oxyalkylene alkyl (aryl) ethers, polyoxyalkylene polyoxyalkylene ethers, polyoxyalkylene ethers, acetylene ethers, Oxyalkylene antifoaming agents such as sulfuric acid ester salts, (poly) oxyalkylene alkyl phosphoric acid esters, (poly) oxyalkylene alkylamines and (poly) oxyalkylene amides; Alcohol-based antifoaming agents such as octyl alcohol, hexadecyl alcohol, acetylene alcohol, glycols and the like; Amide-based antifoaming agents such as acrylate polyamines and the like; Phosphoric acid ester antifoaming agents such as tributyl phosphate, sodium octyl phosphate and the like; Metal soap defoamers such as aluminum stearate, calcium oleate and the like; Silicone antifoaming agents such as dimethyl silicone oil, silicone paste, silicone emulsion, organic modified polysiloxane (polyorganosiloxane such as dimethyl polysiloxane), fluorosilicone oil and the like can be used.

In the present invention, the swelling agent may be a mixture of calcium sulfoaluminate (CSA) and gypsum in a weight ratio of 4 to 9: 1 to 6, and the gypsum may be selected from anhydrous gypsum phosphate or anhydrous gypsum have.

In addition, in the present invention, the powdery silicone water repellent agent plays a role in improving the water repellency and decreasing the water absorption of the mortar composition, thereby improving the workability and workability, and specifically, n-octyltriethoxysilane (n -octyltriethoxysilane) is preferably used.

In the present invention, the durability enhancer plays a role of enhancing the adhesive force and binding force between each component of the mortar composition and filling fine gaps to tighten the structure, thereby improving physical properties such as strength and durability. In the present invention, Specifically, a first composition comprising 30 to 40 parts by weight of a curing composition, 1 to 3 parts by weight of a montmorillonite-based clay mineral, 1 to 2 parts by weight of an aluminum salt, and 50 to 60 parts by weight of water, and a curing accelerator 5 to 7 A mixture of a second composition containing 12 to 18 parts by weight of clay mineral, 0.1 to 2 parts by weight of a nano zinc powder, 0.1 to 0.5 parts by weight of a stabilizer and 60 to 70 parts by weight of water is used.

In the present invention, the first composition comprises a montmorillonoidalite-based clay mineral, an aluminum salt and water at the time of curing.

In the present invention, the hardening phase present in the first composition is formed by mixing 50 to 80% by weight of boiler ashes, 10 to 30% by weight of blast furnace slag powder and 3 to 20% by weight of accelerator.

Here, boiler ash is preferably used ash [ash] (lime or coke fuel shell) generated from a thermal power plant. It is preferable that the boiler ash is produced from a boiler using a circulating fluidized bed combustion boiler using petroleum coke containing petroleum coke and anthracite coal singly or in combination as one or more fuels.

The blast furnace slag is preferably pulverized by a crushing means such as a ball mill or a vibrating mill.

The quick-setting agent serves to accelerate the rapid curing of the mortar according to the present invention. The quick-setting agent is a solid quick-setting agent, for example, sodium carbonate (Na ₂ CO ₃ ), sodium aluminate (NaAlO ₂ ), calcium hydroxide and sodium silicate (Na ₂ SiO ₃ ), more preferably at least one selected from the group consisting of sodium carbonate, sodium aluminate and sodium silicate at a ratio of 1: 1.5 to 2: 0.5 to 1 Can be used.

In the present invention, the montmorillonyaluril clay mineral and the aluminum salt serve to compact the voids in the mortar.

In the present invention, the second composition is formed by mixing 5 to 7 parts by weight of a curing accelerator, 12 to 18 parts by weight of a clay mineral, 0.1 to 2 parts by weight of a nano zinc powder, 0.1 to 0.5 parts by weight of a stabilizer and 60 to 70 parts by weight of water .

In the present invention, the curing accelerator has a function of shortening the curing time and completing the work in an early stage. The curing accelerator may be a mixture of DMA (dimethyl aniline), Co-octate (cobalt octate) -toluidine) and the like can be used.

In the present invention, montmorillonite clay minerals may be used as the clay minerals.

The above-mentioned nano zinc powder plays a role of controlling the hardening time and compacting the tissue.

In the present invention, as the stabilizer, it is preferable to use sodium triphosphate so as to lower the viscosity of the second composition and to obtain uniform dispersion and stable homogeneous strength. In addition, sodium carbonate, May be used. The stabilizer also serves to prevent material separation.

In the present invention, it is preferable that the first composition and the second composition contained in the durability enhancer are mixed in a weight ratio of 5 to 8: 2 to 5, more preferably 7: 3 .

It is preferable that the first composition and the second composition are composed of a two-component type and are injected into the mortar and mixed therein immediately before the mortar is inserted.

Further, in the present invention, the durability enhancer may further include a fluidizing agent for regulating flowability.

The fluidizing agent included at this time is preferably included in the range of about 0.1 to 5 parts by weight based on 100 parts by weight of the first composition.

Examples of preferred fluidizing agents that can be used in the present invention include polycarboxylic acid type (PCA type), melamine type and naphthalene type fluidizing agents, and one kind or a mixture of two or more kinds of the fluidizing agents may be used.

In the present invention, since the limestone powder component is included in the mortar composition to improve the heat shielding performance, the fire resistance of the mortar composition as well as the durability can be further improved.

In the present invention, the nanostructured metal oxide powder has a porous structure having an internal structure having a large absorption cross-sectional area, and induces weight reduction in the tissue, thereby making the tissue compact.

In the present invention, the nano-metal oxide powder may be at least one selected from palladium oxide, iridium oxide, ruthenium oxide, osmium oxide, rhodium oxide, platinum oxide, iron oxide, nickel oxide, cobalt oxide, indium oxide, aluminum oxide, tungsten oxide, Magnesium, and mixtures of two or more thereof.

Also, in the present invention, the nano-metal oxide powder may be used in a form not processed, but it is preferable to use a coated one to prevent fusion with each other in the composition. Specifically, Is preferably used.

In the present invention, the graphite oxide is obtained by treating at least one graphite selected from natural graphite, graphite graphite, artificial graphite and expanded graphite with an oxidizing agent such as sulfuric acid, nitric acid, potassium permanganate and calcium chlorate, In the method of coating the surface with the oxide, a nanometer metal oxide powder and graphite oxide are mixed at a predetermined ratio and a small amount of water is added to form a slurry, and then the graphite oxide is combined with the nanometer metal oxide powder by irradiating ultraviolet rays A method of forming a coating layer on the surface is used.

The nano-metal oxide powder having a coating layer formed on the surface thereof is not likely to be re-fused with each other, thereby improving dispersion stability.

The present invention may further comprise at least one additive selected from the group consisting of 0.1 to 1.0 parts by weight of a dispersant, 0.01 to 1.0 parts by weight of a retarder and 0.1 to 1.0 part by weight of an alkali activator, if necessary, have.

The dispersant adsorbs on the surface of the particles of the mortar to impart charge to the particle surface, causing mutual reaction between the particles, so that the aggregated particles are dispersed to increase the flow, thereby making it possible to increase the strength due to the water reducing effect. As the dispersing agent, a conventional water reducing agent can be used, and it can be used singly or in a mixture of two or more thereof, for example, from the group consisting of lignin sulfonate, polynaphthalene sulfonate, polymelamine sulfonate or polycarboxylate type water reducing agent. The content of the dispersant is preferably 0.1 to 1.0 part by weight based on 100 parts by weight of the cement.

The retarder may be added for the purpose of ensuring workability for a certain period of time by adjusting the hydration rate of the mortar. Examples of the retarder include boric acid salts such as boric acid and borax, boric acid salts such as sodium borate and potassium borate, gluconic acid, citric acid, tartaric acid, glucoheptonic acid, arabic acid, malic acid or citric acid and sodium, potassium, calcium, magnesium, An oxycarboxylic acid such as an inorganic salt or an organic salt; There may be mentioned monosaccharides such as glucose, fructose, galactose, saccharose, xylose, avitose, lipoose and isomerized sugar, oligosaccharides such as 2 sugars and 3 sugars, oligosaccharides such as dextrin, polysaccharides such as dextran, Saccharides such as molasses and the like containing them; Sugar alcohols such as sorbitol; Magnesium styrenesulfonate; Phosphoric acid and its salts or boric acid esters; Aminocarboxylic acids and their salts; Alkali-soluble proteins; Fumic acid; Tannic acid; phenol; Polyhydric alcohols such as glycerin; Aminotri (methylenephosphonic acid), 1-hydroxyethylidene-1,1-diphosphonic acid, ethylenediamine tetra (methylenephosphonic acid), diethylenetriamine penta (methylenephosphonic acid) and their alkali metal salts, And phosphonic acid and derivatives thereof such as earth metal salts. The content thereof is preferably 0.01 to 1.0 part by weight based on 100 parts by weight of the cement.

The alkali activating agent may be one or two or more selected from the group consisting of alkali metal hydroxides, chlorides, sulfur oxides and carbonates, preferably sodium carbonate and sodium hydrogencarbonate Which is advantageous in terms of strength development. In the present invention, the content of the alkali activator is preferably 0.1 to 1.0 part by weight based on 100 parts by weight of the cement.

In addition, the mortar composition according to the present invention may further include a water-reducing agent in the range of 0.1 to 3 parts by weight for maintenance and reinforcement of the underwater concrete structure.

The underwater bleaching agent is added to prevent the degradation of the mortar composition by improving the viscosity of the mortar composition. Examples thereof include methylcellulose such as methylcellulose, hydroxymethylcellulose and carboxymethylcellulose; Ethyl celluloses such as ethyl cellulose, hydroxyethyl cellulose and carboxyethyl cellulose; Cellulose type thickeners selected from propyl cellulose such as hydroxypropyl cellulose can be used. The content thereof is preferably 0.1 to 3 parts by weight based on 100 parts by weight of the cement, because it exhibits an appropriate viscosity. If necessary, a water-soluble acrylic resin powder may be further added to further increase viscosity in water, and the water-soluble acrylic resin powder is preferably used in an amount of 1 to 30 wt% of the water-decomposable agent.

In the present invention, the mortar composition for repairing and reinforcing a concrete structure according to the present invention is applied to the surface of a work to reinforce the concrete structure. When the work is repeated one or more times, the surface is polished for adhesion with the target surface, It is preferable that the application is performed and sprayed with spray or trowel at 5 ~ 15 mm for primary casting, 20 ~ 50 mm for secondary and tertiary casting and 5 ~ 15 mm at final casting, Can be changed depending on the thickness of the chipped concrete.

In this way, the maintenance work can be completed by curing the mortar composition for repairing and reinforcing concrete structures laid on the concrete structure.

Meanwhile, in the present invention, if the thickness of the concrete structure to be repaired is as thin as 5 mm or less, the step of forming the reinforcing layer by applying the mortar for repairing and reinforcing the concrete structure may be omitted.

Subsequently, a coating agent (surface protective material) is coated on the surface of the formed reinforcing layer and coated.

At this time, the application of the coating agent (surface protective material)

a. A primary surface protection material containing an acrylic resin, a rubber chip, an airgel and a powder component is applied,

b. Applying a secondary surface protective material comprising 100 parts by weight of a liquid phase component containing methyl methacrylate (MMA) resin and 30 to 300 parts by weight of an inorganic powder component onto the primary surface protective material, .

Hereinafter, the first surface protection material and the second surface protection material will be described in detail.

First, the primary surface protective member comprises an acrylic resin, a rubber chip, an airgel and a powder component. The composition of the primary surface protective material comprises 30 to 50 parts by weight of the acrylic resin, 10 to 30 parts by weight of a rubber chip, 5 to 20 parts by weight of an airgel and 20 to 50 parts by weight of a powder component.

Specifically, as the acrylic resin, specifically, acrylic latex can be used as a copolymer of one or more kinds selected from butyl acrylate, acrylic acid, methyl methacrylate (MMA) and 2-ethylhexyl acrylate.

The rubber chip may be a natural rubber chip or a recycled rubber chip such as a waste tire. Specifically, a rubber chip having a diameter of about 0.2 to 0.8 mm may be used. The rubber chip is mixed with an acrylic resin to impart heat insulation and anti-condensation effect to the intermediate layer, to prevent damage and lifting of the intermediate layer, and to absorb external impact.

The airgel may be a silica airgel powder. The powder may be a transparent nanoporous material having a particle diameter of about 10 to 2000 μm, having a density of about 0.05 to 0.1 g / cm ³ , a porosity of 90 to 99% 200 to 2000 m ² / g, and a pore volume of 2 to 10 cm ³ / g. The aerogels serve to reduce the influence of the flooring due to the external environment by providing the heat insulating effect due to the pores existing in the particles.

In the present invention, it is preferable to use a mixture of 30 to 50% by weight of mica having a particle diameter of 1 to 100 μm, 30 to 50% by weight of a fine powder and 5 to 20% by weight of titanium oxide.

The mica is used in the coating film to strengthen the elasticity, elongation and adhesion strength.

The above-mentioned stone powder plays a role of strengthening abrasion resistance, slip resistance, adhesion and the like.

The titanium oxide serves to improve the heat insulating performance by suppressing the transmission of the radiant light, and blocks ultraviolet rays and imparts antifouling properties.

The primary surface protection material imparts various properties such as waterproofness, anticorrosive property, antifouling property, durability, water resistance and weather resistance of the object to be applied.

The secondary surface protection material comprising MMA resin is then top-coated on top of the primary surface protection material.

The secondary surface protective material uses a mixture of a liquid component and an inorganic powder component including an MMA resin. Specifically, 30 to 300 parts by weight of the inorganic powder component is mixed with 100 parts by weight of the liquid component.

The liquid component is preferably an acrylic aqueous solution containing an MMA resin and having a pH in the range of about 8 to 10.

The inorganic powder component is preferably composed of silica powder, alumina cement and bentonite powder.

Specifically, the inorganic powder component preferably comprises 40 to 70 parts by weight of silica powder, 1 to 5 parts by weight of alumina powder, and 0.5 to 5 parts by weight of bentonite powder.

The silica powder serves to promote curing of the coating film, and it is preferable to use a powder having a particle diameter of about 0.05 to 0.1 mm.

The alumina powder serves to reduce drying shrinkage and it is preferable to use a powder having a particle size of about 0.05 to 2.0 mm.

The bentonite powder plays a role of absorbing water and moisture and adjusting the viscosity, and preferably has a particle diameter of about 0.05 to 1.0 mm.

The secondary surface protective material according to the present invention is excellent in weatherability, surface strength and water resistance by coating only once, but may be re-coated 2-3 times in order to exhibit its function optimally. In the present invention, it is preferable that the secondary surface protective material is applied to the cured surface of the primary surface protective material at 20 to 200 g / m ² , and the coating thickness is applied at a thickness of 50 to 300 탆 in the pre-drying step.

The method for repairing and reinforcing concrete structures according to the present invention has been described in detail.

The repair and reinforcement method of a concrete structure according to the present invention can be used for maintenance and reinforcement of civil engineering structures such as emergency repair and repair of a deteriorated concrete structure.

The repair and reinforcement method of a concrete structure according to the present invention improves the durability of a concrete structure by suppressing permeation of deteriorating substances such as salts and acidic substances, and is excellent in compatibility with cement.

In addition, the concrete structure repairing and reinforcing method according to the present invention is excellent in adhesion to existing base materials, does not have a neutralization reaction with concrete, and is resistant to aging due to water resistance, ozone resistance, chemical resistance, water resistance, air permeability, There is an advantage not to occur.

Also, the concrete structure repairing and reinforcing method according to the present invention is excellent in air permeability, does not cause condensation, does not oxidize the surface of the structure, has excellent permeability, hardens the infiltrated product and has high density, durability, And particularly, it has an advantage of being excellent in workability of a vibration part because it is excellent in stretchability and prevents cracking of a mother body in which shrinkage and expansion are repeated due to temperature change.

Also, the concrete structure repairing and reinforcing method according to the present invention can obtain a good structure with excellent strength, inhibits the infiltration of carbon dioxide, and prevents water infiltration. The concrete structure repair and rebuilding method according to the present invention is environmentally friendly, has no air pollution, has high strength development, has excellent early strength, and has fine particles, It is excellent and suppresses cracking. The repair and reinforcement method of concrete structure according to the present invention is excellent in water resistance, weather resistance, chemical resistance, and stain resistance and can protect the matrix and finish surface from chemical gas, exhaust gas, rainwater, etc., and has a great effect on the protection of exposed concrete structures And there is no environmental pollution because organic solvents (thinner, etc.) are not used for construction and equipment cleaning.

In addition, the concrete structure repairing and reinforcing method according to the present invention is excellent in compatibility between a liquid component and a powder component, and is easy to form because of easy mixing and excellent workability. The concrete structure repairing and reinforcing method according to the present invention is excellent in high elasticity, smoothness, low-temperature stability (no cracking) and odorlessness, exhibits good dispersing action with a small mixing ratio with water, and maintains uniform strength and high strength at the same time. In addition, due to the good dispersing action of the binder, a high-density dense textured body is formed, which is excellent in chemical resistance (salt resistance and acid resistance) and inhibits penetration of water, oil and the like.

In addition, since the repair and reinforcement method of concrete structure according to the present invention is an inorganic material such as concrete, it is excellent in adhesion force due to affinity of similar materials and excellent in both short-term bond strength and long-term stability. Low rebound rate is economical. In addition, when the concrete structure repairing and reinforcing method according to the present invention is used, there is an advantage that cracks are not generated due to proper balance of strength and stability.

In addition, since the industrial by-products can be recycled at the final stage, it can be used as a surface protecting material containing environment-friendly, MMA-based reactive resin, and is excellent in properties such as chemical resistance, water resistance, anti- It has an advantage of being excellent in resistance to salting and also capable of increasing anti-neutralization effect and waterproofing effect.

Hereinafter, the present invention will be described in more detail with reference to examples. However, the scope of the present invention is not limited by the following examples.

[Example]

Preparation Example 1 (Preparation of an alkaline recovery agent)

20% by weight of potassium silicate having a solids content of 40% by weight and a molar ratio of K ₂ O to SiO ₂ of 1: 3 was mixed with 41% by weight of water to prepare a uniform aqueous solution of potassium silicate and then an aqueous acrylic emulsion (Daeyang Chemical, 5% by weight of potassium methylsiliconate (Dow Corning, IE 6683) was added thereto, and 4% by weight of dimethyl ammonium chloride (KCI) was added thereto. An alkali recovery agent composition was prepared.

Production Example 2 ( Mortar Composition Preparation)

1.0 part by weight of a mixture of 100 parts by weight of Portland cement, 5 parts by weight of polyvinyl acetate polymer, 5.0 parts by weight of silica fume, a mixture of fused silica fibers, porous silica fibers and quartz fibers at a ratio of 1: 1: 1, 5 parts by weight of a strength enhancer, 45 parts by weight of a porous fillite having an average diameter of about 100 탆 and a grain specific gravity of 0.9, 1.0 part by weight of neopentyl glycol shrinkage inhibitor, 5.0 parts by weight of a polyvinyl alcohol powder resin, 0.3 parts by weight of a defoamer, 8 parts by weight of an expanding agent mixed with alumina (CSA) and gypsum in a ratio of 6: 4, and 2.5 parts by weight of n-octyltriethoxysilane powdered silicone waterproofing agent were mixed to obtain a mixture. Subsequently, a first composition comprising 35 parts by weight of a cured product, 2 parts by weight of a montmorillonite-based clay mineral, 1.5 parts by weight of an aluminum salt and 61.5 parts by weight of water, 6 parts by weight of a curing accelerator, 15 parts by weight of a clay mineral, 0.5 part by weight of powder, 0.5 part by weight of stabilizer and 65 parts by weight of water were mixed and mixed at a weight ratio of 7: 3 to obtain a composition, which was mixed as a durability enhancer to about 10 parts by weight, 10 parts by weight of a limestone powder component and 1.0 part by weight of a nano-metal oxide powder composed of a mixture of iron oxide and cobalt oxide were uniformly mixed with an appropriate amount of water to prepare a mortar composition.

Comparative Manufacturing Example  1 (Mortar composition according to Korean Patent No. 10-1528120)

7 parts by weight of methyl methacrylate, 8 parts by weight of styrene monomer, 10 parts by weight of n-butyl acrylate, 10 parts by weight of methyl acrylate and 5 parts by weight of isobornyl acrylate were mixed to prepare a liquid component, 3 parts by weight of glycerin fatty acid ester and 3 parts by weight of glycerin fatty acid ester were mixed to prepare a second liquid component. Then, 100 parts by weight of portland cement, 5 parts by weight of clinker, 5 parts by weight of plaster, 5 parts by weight of plaster, 3 parts by weight of silica fume, 3 parts by weight of fly ash, 7 parts by weight of limestone, 3 parts by weight of slag, 7 parts by weight of calcined pozzolanas and 3 parts by weight of micro silica were mixed to prepare a first powder component, 10 weight parts of purified water sludge powder, 20 weight parts of waste glass powder, and 40 weight parts of waste stone powder were mixed to prepare a second powder component.

Then, the liquid component and the second liquid component were mixed at a weight ratio of 90:10 to prepare a liquid component. Then, based on 100 parts by weight of the liquid component, 5 parts by weight of the first powder component, 5 parts by weight of the second powder component And 3 parts by weight of long fiber of cellulose were mixed to prepare a binder composition.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Comparative Manufacturing Example  2 (mortar composition)

5 parts by weight of clinker, 5 parts by weight of gypsum, 5 parts by weight of plaster, 5 parts by weight of anhydrous gypsum, 3 parts by weight of silica fume, and 3 parts by weight of fly ash 3 7 parts by weight of limestone, 3 parts by weight of slag, 7 parts by weight of calcined pozzolanas, 3 parts by weight of microsilica and 2 parts by weight of long fiber of cellulose were mixed to prepare a binder composition.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Comparative Manufacturing Example  3 (mortar composition)

30 parts by weight of styrene monomer, 5 parts by weight of t-butyl peroxybenzoate, and 5 parts by weight of glycerin fatty acid ester were mixed, and then 100 parts by weight of portland cement, 5 parts by weight of clinker, 5 parts by weight of gypsum, 5 parts by weight of anhydrous gypsum, 3 parts by weight of silica fume, 3 parts by weight of fly ash, 7 parts by weight of limestone, 3 parts by weight of slag, 7 parts by weight of calcined pozzolan, 3 parts by weight of microsilica and 2 parts by weight of cellulose long fiber, A composition was prepared.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Comparative Manufacturing Example  4 (mortar composition)

30 parts by weight of normal butyl acrylate and 5 parts by weight of glycerin fatty acid ester were mixed and then 100 parts by weight of portland cement, 5 parts by weight of clinker, 5 parts by weight of gypsum, 5 parts by weight of plaster, 5 parts by weight of anhydrous gypsum, 3 parts by weight of fly ash, 7 parts by weight of limestone, 3 parts by weight of slag, 7 parts by weight of calcined pozzolanas, 3 parts by weight of microsilica and 2 parts by weight of cellulose long fibers were mixed to prepare a binder composition.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Comparative Manufacturing Example  5 (mortar composition)

30 parts by weight of isobornyl acrylate and 5 parts by weight of glycerin fatty acid ester were mixed, and 100 parts by weight of portland cement, 5 parts by weight of clinker, 5 parts by weight of gypsum, 5 parts by weight of plaster, 5 parts by weight of anhydrous gypsum, 3 parts by weight of fly ash, 7 parts by weight of limestone, 3 parts by weight of slag, 7 parts by weight of calcined pozzolanas, 3 parts by weight of microsilica and 2 parts by weight of cellulose long fibers were mixed to prepare a binder composition.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Comparative Manufacturing Example  6 (mortar composition)

5 parts by weight of methyl methacrylate, 10 parts by weight of styrene monomer, 5 parts by weight of n-butyl acrylate, 5 parts by weight of methyl acrylate, 5 parts by weight of isobornyl acrylate, 0.1 part by weight of t-butyl peroxybenzoate, And 5 parts by weight of plaster, 5 parts by weight of gypsum, 5 parts by weight of anhydrous gypsum, 3 parts by weight of silica fume and 3 parts by weight of fly ash were mixed with 100 parts by weight of portland cement, 5 parts by weight of clinker, 5 parts by weight of plaster, 7 parts by weight of limestone, 3 parts by weight of slag, 7 parts by weight of calcined pozzolanas, 3 parts by weight of microsilica and 2 parts by weight of cellulose long fibers were mixed to prepare a binder composition.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Comparative Manufacturing Example  7 (mortar composition)

5 parts by weight of methyl methacrylate, 10 parts by weight of styrene monomer, 5 parts by weight of n-butyl acrylate, 5 parts by weight of methyl acrylate, 5 parts by weight of isobornyl acrylate, 0.1 part by weight of t-butyl peroxybenzoate, And 0.1 part by weight of ester were mixed. Then, 100 parts by weight of portland cement and 46 parts by weight of limestone were mixed to prepare a binder composition.

100 parts by weight of the binder composition prepared above was mixed with 100 parts by weight of filler consisting of stoneware and talc and 150 parts by weight of silica sand to prepare a mortar composition.

Manufacturing example  3 ( Surface protection material  Produce)

20 parts by weight of a waste tire rubber chip having a particle diameter of about 0.3 mm, 10 parts by weight of a silica airgel powder, 40 parts by weight of mica having a particle diameter of about 20 to 50 占 퐉, 40 parts by weight of a mica, And 20 parts by weight of titanium oxide were mixed and stirred to prepare a primary surface protective material.

Subsequently, a liquid surface component composed of an acrylic aqueous solution having a pH of about 9 and a mixture of inorganic powder components (a mixture of silica, alumina, and bentonite powder) were mixed and stirred in a ratio of 100: 50 parts by weight, respectively, to prepare a secondary surface protective material.

Comparative Manufacturing Example  8 (coating agent)

A commercially available acrylic resin-based coating agent was used as Comparative Production Example 8.

Comparative Manufacturing Example  9 (coating agent)

A commercially available polyester resin-based coating agent was used as Comparative Production Example 9.

Example

[Example 1]

The damaged concrete structure was chipped and crushed to remove the rusted reinforcing bars. The alkali remover prepared in Preparation Example 1 was applied to the refinished surface to be applied, and the mortar composition prepared in Preparation Example 2 was applied And the surface of the concrete structure was smoothly coated and cured. The surface of the cured mortar was coated once with a primary surface protective material prepared in Preparation 3 in a thickness of 100 쨉 m and dried, and then the secondary surface protective material prepared in Preparation Example 3 was again applied to the surface of the cured mortar twice 100 탆 thick twice and dried to finish the repair and reinforcement work.

[Comparative Example 1]

Except that the mortar composition prepared in Comparative Preparation Example 1 and the coating composition prepared in Comparative Preparation Example 8 were applied in the same manner as in Example 1.

[Comparative Example 2]

Except that the mortar composition prepared in Comparative Preparation Example 2 and the coating material prepared in Comparative Preparation Example 8 were applied in the same manner as in Example 1.

[Comparative Example 3]

Except that the mortar composition prepared in Comparative Preparation Example 3 and the coating material prepared in Comparative Preparation Example 8 were applied in the same manner as in Example 1.

[Comparative Example 4]

Except that the mortar composition prepared in Comparative Production Example 4 and the coating material prepared in Comparative Production Example 8 were applied in the same manner as in Example 1.

Performance evaluation

end. Properties of Mortar Composition

1. Bending strength, compressive strength, tensile strength, bond strength and volume change rate test

The flexural strength, compressive strength, tensile strength, volume change rate and adhesion strength of the mortar composition for repair and reinforcement prepared according to Production Example 2 and Comparative Production Examples 1 to 7 were measured.

The bending strength, the compressive strength, the tensile strength and the adhesion strength were measured according to the standard of KS F 4042-02 28 days after the concrete repair reinforcing agent was applied. The volume change rate was calculated by dividing the volume of the mortar composition for maintenance and reinforcement after 28 days To 35 < 0 > C. The results are shown in Table 1 below.

Sample Flexural strength
(N / mm < 2 & Compressive strength
(N / mm < 2 & The tensile strength
(N / mm < 2 & Bond strength
(MPa) Volume change rate
(%) Production Example 2 24.1 64.8 9.9.0 3.1 0.0001 Comparative Preparation Example 1 17.2 50.0 5.0 2.0 0.0005 Comparative Production Example 2 15.5 35.5 3.5 0.5 0.0009 Comparative Production Example 3 10.6 40.0 4.0 1.2 0.0012 Comparative Production Example 4 8.5 30.5 3.8 1.0 0.0008 Comparative Preparation Example 5 11.2 35.0 2.9 0.8 0.0009 Comparative Preparation Example 6 8.9 35.5 4.4 0.9 0.0010 Comparative Preparation Example 7 10.8 38.0 4.2 1.1 0.0015

Referring to Table 1, the mortar composition for repair and reinforcement according to the present invention shows that the mortar composition of the present invention is superior in strength and adhesion performance compared to conventional materials.

2. Waterproof and chemical resistance test

The waterproofing and chemical resistance of the mortar composition for repair and reinforcement prepared according to Preparation Example 2 and Comparative Preparation Examples 1 to 7 were measured.

The waterproofness was evaluated by applying the repair mortar composition on the concrete structure to a thickness of 1 cm and installing a cylindrical water tank on the mortar composition layer to check whether the water penetrated into the concrete structure for 6 months.

The chemical resistance was evaluated by treating the mortar composition layer having a salt concentration of 35 ‰ and the sulfuric acid solution having a concentration of 2% on the mortar composition layer after 28 days of curing on the concrete structure for 1 hour each day, And was confirmed for 60 days.

The results are shown in Table 2 below.

Sample Water resistance test
(month) Chemical resistance test (days) Brine Sulfuric acid solution Production Example 2 - - 39 Comparative Preparation Example 1 One 5 15 Comparative Production Example 2 One 20 5 Comparative Production Example 3 2 35 10 Comparative Production Example 4 One 40 15 Comparative Preparation Example 5 2 26 8 Comparative Preparation Example 6 One 39 12 Comparative Preparation Example 7 One 27 9

As shown in Table 2, in the case of Production Example 2, moisture was not penetrated at all for 6 months, while in Comparative Production Examples 1 to 7, water was infiltrated after 1 to 2 months. This is interpreted as a result of showing the excellent waterproof performance of the mortar composition for repair and reinforcement according to the present invention.

As shown in Table 2, in the case of Production Example 2, surface damage was not caused at all by the brine treated for 60 days, and when the sulfuric acid solution was treated, surface damage did not occur for 45 to 52 days. On the other hand, in the case of Comparative Production Examples 1 to 7, surface damage occurred 20 to 40 days after the saline treatment, and surface damage was observed within 5 to 15 days after the treatment with the sulfuric acid solution.

This is interpreted as a result of supporting the excellent chemical resistance of the mortar composition for repair and reinforcement according to the present invention.

3. Freeze-thaw resistance, crack resistance and dry shrink resistance

The freeze-thaw resistance, crack resistance and shrinkage resistance of the mortar composition for repair and reinforcement prepared according to Preparation Example 2 and Comparative Preparation Examples 1 to 7 were measured.

The freeze-thaw resistance was tested by the freeze-thaw resistance test according to KS F 2456.

Crack resistance was tested according to AASHTO PP34-98.

Dry shrinkage resistance was tested according to KS F 2424.

The results are shown in Table 3.

Sample Freeze-thaw resistance (%) Crack resistance Dry shrinkage resistance Reference value: 80% or more Reference value: No crack up to 56 days Reference value: 0.15 or less Production Example 2 94 No crack 0.01 Comparative Preparation Example 1 88 No crack 0.02 Comparative Production Example 2 87 No crack 0.03 Comparative Production Example 3 82 No crack 0.03 Comparative Production Example 4 82 No crack 0.05 Comparative Preparation Example 5 80 No crack 0.05 Comparative Preparation Example 6 80 No crack 0.04 Comparative Preparation Example 7 80 No crack 0.04

As shown in Table 3, it can be seen that the mortar composition for repair and reinforcement of Production Example 2 according to the present invention is superior in terms of freezing-thawing resistance, cracking resistance and drying shrinkage resistance than conventional materials.

I. Temperature and humidity change evaluation

The internal temperature and humidity changes after the repair and reinforcement work performed through the above-described Examples and Comparative Examples were measured, and the results shown in Table 4 were obtained.

Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Temperature change Humidity change Temperature change Humidity change Temperature change Humidity change Temperature change Humidity change Temperature change Humidity change 1 time +11 +0.05 +18 +0.14 +21 +0.15 +26 +0.12 +31 +0.22 Episode 2 +10 +0.05 +20 +0.15 +21 +0.23 +29 +0.15 +33 +0.25 Condition External: Maintains temperature 80 ℃, relative humidity 100%
Internal (initial): start test at 20 ° C and 20% relative humidity
Measurement of internal temperature and humidity change after 48 hours

From the results shown in Table 4, it can be seen that when the maintenance and reinforcement method according to the present invention is used, the moisture shielding performance is excellent because there is little temperature change and humidity change.

All. Weatherability evaluation

ASTM G 155 for 200 hours. The measurement conditions are as follows.

1) Light Sourse: 6500w Xenone Arc, Irradance: 0.35W / ㎡

2) B.P.T. : 63 ° C ± 3 ° C, Humidity: 50% ± 5% RH

3) Inner / Outer Filter: Borosilicate / borosilicate

4) Spray Cycle: After 102 minutes light irradiation, 18 minutes light irradiation and water spray

la. Evaluation of surface hardness

Pencil hardness: measured according to KS D 6711.

hemp. Water resistance evaluation

The time at which surface deformation (cracks, blisters, etc.) occurred continuously in 90 ° C hot water was measured.

The results of evaluation of weather resistance, surface hardness and water resistance in Example 1 and Comparative Example 1-4 are shown in Table 5.

Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Weatherability (white) E1.1 E3.5 E4.1 E3.8 E4.2 Surface hardness 4H 1H 1H 1H 2H Water resistance 400hr 200hr 250hr 260 hr 190hr

From the results of Tables 3 to 5, it can be seen that when the repair and reinforcement method according to the present invention is used, the performance of the mortar is excellent, the waterproofing performance is excellent, the weatherability, surface hardness and water resistance are excellent, In addition, it can be confirmed that the effect of maintenance reinforcement can be maintained for a long period of time.

Claims (7)

A. A basic repairing step of finishing the repair surface of the concrete structure to be repaired;
B. applying an alkaline recovery agent to apply the alkaline recovery agent to the trimmed surface to be applied;
C. a reinforcing layer forming step of applying mortar for repairing concrete structure to the surface to which the alkali remover is applied to form a reinforcing layer and then hardening; And
D. forming a coating layer on the surface of the formed reinforcing layer to coat and coat the surface protective material,
In the above B, the alkali remover may be selected from the group consisting of 10 to 50 wt% of potassium silicate, 10 to 40 wt% of an aqueous acrylic emulsion, 0.1 to 5 wt% of potassium methylsiliconate, 0.1 to 5 wt% of a binder resin and 0.1 to 10 wt% And a balance of water is used,
In the C, the mortar for repairing and reinforcing concrete structures
1 to 10 parts by weight of a polymer, 0.1 to 8 parts by weight of silica fume and 0.5 to 5.0 parts by weight of a ceramic composite fiber based on 100 parts by weight of cement; 1 to 8 parts by weight of a strength-increasing agent; 30 to 50 parts by weight of aggregate; 0.5 to 2.0 parts by weight of a shrinkage inhibitor; 3 to 7 parts by weight of a polyvinyl alcohol (PVA) powder resin; 0.1 to 1.0 part by weight of an antifoaming agent; 5 to 10 parts by weight of an expanding agent; 1 to 5 parts by weight of a powdery silicone water repellent; 5 to 15 parts by weight of a durability enhancer; 1 to 15 parts by weight of a limestone powder component; And 0.1 to 2 parts by weight of a nano-metal oxide powder,
The application of the surface protective material in D above
a. A primary surface protection material containing an acrylic resin, a rubber chip, an airgel and a powder component is applied,
b. Applying a secondary surface protective material comprising 100 parts by weight of a liquid component containing methyl methacrylate (MMA) resin and 30 to 300 parts by weight of an inorganic powder component on the surface of the primary surface protective agent; , ≪ / RTI >
The durability enhancer of step (C) comprises 30 to 40 parts by weight of a curing composition, 1 to 3 parts by weight of a montmorillonite clay mineral, 1 to 2 parts by weight of an aluminum salt and 50 to 60 parts by weight of water, A second composition comprising 5 to 7 parts by weight of an accelerator, 12 to 18 parts by weight of a clay mineral, 0.1 to 2 parts by weight of a nano zinc powder, 0.1 to 0.5 parts by weight of a stabilizer, and 60 to 70 parts by weight of water
The nano-metal oxide powder of the step (C) has a porous structure and is coated with a graphite oxide. The nano-metal oxide powder may be palladium oxide, iridium oxide, ruthenium oxide, osmium oxide, Wherein the graphite oxide is at least one selected from the group consisting of natural graphite, platelet graphite, artificial graphite, graphite, graphite, and mixtures thereof. The graphite oxide may be at least one selected from the group consisting of iron oxide, nickel oxide, cobalt oxide, indium oxide, aluminum oxide, titanium oxide, tungsten oxide, And expanded graphite is treated with sulfuric acid, nitric acid, potassium permanganate, or calcium chlorate,
The nano-metal oxide powder and the graphite oxide are mixed at a predetermined ratio, water is added to form a slurry, and ultraviolet rays are irradiated to bond the graphite oxide to the nano-metal oxide powder to form a coating layer on the surface , A nano-metal oxide powder surface-coated with graphite oxide is used
Repair and Reinforcement Methods for Concrete Structures.
The method according to claim 1, potassium silicate is used in the B stage is that the molar ratio of SiO ₂ and K ₂ O 1: a 2.8 ~ 3.4, and 30 to 40% by weight of solid content, characterized in that in that the pH 10 ~ 12 Repair and Reinforcement Methods for Concrete Structures.
The method according to claim 1, wherein the fibers in step C are at least one selected from the group consisting of glass fiber, steel fiber, polyester fiber, nylon fiber, polypropylene (PP) fiber, cellulose fiber and polyethylene fiber. Reinforcement method.
delete delete [3] The method according to claim 1, wherein the powder component of the a in step D is a mixture of 30 to 50 wt% of mica having a particle size of 1 to 100 mu m, 30 to 50 wt% of a stone powder, and 5 to 20 wt% A method of repairing and reinforcing concrete structures.
The method for repairing and reinforcing concrete structures according to claim 1, wherein the inorganic powder component of b in step D comprises silica powder, alumina cement, and bentonite powder.