KR101808114B1 - Natural hair-dye composition comprising of oriental herbs and pearl mineral water - Google Patents

Abstract

The present invention relates to a powder hair dye composition containing a herbal herb and pearlescent mineral water, wherein the hair dye composition according to the present invention comprises a herbal powder, a first agent consisting of a herbal powder, a vegetable powder, a dye, a humectant, ; The hair dye composition according to the present invention comprises a herbal herb and pearl mineral water as main components and an auxiliary chemical dye precursor to make it relatively more hypoallergenic, more environmentally friendly, permanent It is possible to prevent the hair and the scalp from being damaged by excluding the use of the oxidizing agent as used in the hair dye, and it is possible to use not only the high use convenience because there is no disgusting odor due to the alkaline agent such as the ammonia water used in the permanent hair dye, , It is possible to improve the durability of the dye by penetration of the dye into the follicle by the swelling and softening of the layer of the mother lacquer due to the dyeing of the hair, It has a castle.

Description

TECHNICAL FIELD [0001] The present invention relates to a hair dye composition containing a herbal herb and pearlescent mineral water,

The present invention relates to a powder hair dye composition containing herbal herb and pearl mineral water, and more particularly, to a hair dye composition containing a herb and a pearl mineral water, and more particularly, to a use of an oxidizing agent which is a disadvantage in a cream type hair dye using a hair dye as a first agent and an oxidizing agent as a second agent The herbal herb powder as the first agent and the weakly alkaline agent as the second agent, which are environmentally friendly and hypoallergenic because they are natural components as the main component and have excellent stability and storability, The present invention relates to a powder hair dye composition containing pearlescent mineral water.

In recent years, in addition to the conventional hair dyeing behavior in which white hair is dyed with black hair, the number of people who dye black hair in various colors for the purpose of expressing individuality and enjoying fashion is increasing, and the use of hair dye is also increasing. There are also many different types available.

Dyeing agents can be divided into bleaching agents, permanent hair dyeing agents, permanent hair dyeing agents, and temporary hair dyeing agents depending on the purpose of use or duration of dyeing. In addition, depending on the chemical characteristics of the dye, oxidation, acid molding, And can be divided into a synthetic hair dye or a natural hair dye depending on the origin of the hair dye, and can be classified into an oil type, a cream type and a powder type according to the formulation.

On the other hand, when looking at the structure of the hair, the hair is composed of a cuticle or a cuticle stacked in a scaly form, a cortex containing a large amount of melanin pigment, and a medulla in the center of the hair do.

The bleaching agent is a bleaching agent which penetrates the above-mentioned morphosis layer to break down the melanin pigment in the follicle and decolorizes the bleaching agent. The permanent hair dye, which is a basic hair dye, As the most widely used dyestuff of 2 formulations consisting of a basic hair dye as a two-part formulated in a mixed state in use, the swelling and softening of the mother lyophilate layer by an alkaline agent produces an oxidizing agent, such as hydrogen peroxide, , The pigmentation by the destruction of the melanin pigment and the coloring by the generation and growth of the small dye particles in the follicle are performed so that the coloring is permanent but inevitably leads to the damage of the hair due to the destruction of the morpheme layer And a semi-permanent hair dye as an acid hair dye, which is mainly composed of a first agent, Dye pigment is larger than dyes and duration of dyeing is 1 ~ 4 weeks. Therefore, pigmentation on the inner and outer surfaces of the mosfy is achieved and penetration into the fur is not performed. Therefore, there is no change of melanin pigment and thus there is less concern about damage of the hair However, since it is inherently acidic, the hair may become stiff and frizzy. The temporary hair dye is a neutral or acid disposable one. It is used as a coloring agent for the surface of hair which is applied to give a simple change to the hair. Color spray, color gel, color mousse, hair mascara, and the like are typical examples of the hair dye which is not damaged and easily removed by shampoo.

In addition, the most commonly used permanent hair dye has a dye precursor that is oxidized to dye and a formulation that mixes a first agent that contains an alkali and a second agent that contains an excess of hydrogen peroxide, Although the brightness control is somewhat free, there is a change in the hair structure after the hair dyeing by the strong alkali component such as ammonia as the reducing agent contained in the first hair dye and the oxidizing agent such as hydrogen peroxide contained in the second agent, , The hair becomes rough and uneven in gloss, irritation damage to the scalp can not be avoided, and there is a problem that the hair dyeing is disadvantageous in the specific treatment of the alkaline agent including ammonia and amine and hair dyeing method.

On the other hand, the above-mentioned temporary hair dyeing agent has an advantage of high usability, but it is easily removed by shampoo so that it is inconvenient to repeat troublesome dyeing every time.

On the other hand, since the conventional semi-permanent hair dye is mostly composed of only the first agent, it is advantageous in ease of use, but it is difficult to dye the desired color tone and difficult to control brightness because it is the same as the color of the acid dye added with dye color.

On the other hand, the degree of dyeing is influenced by the quality of hair, color, thickness of hair, degree of damage of hair, temperature, distance from hair root, time of dye application, concentration of formulation, blending amount and time of application.

As a conventional semi-permanent hair dyeing agent, as described in Korean Patent Laid-Open Publication No. 10-2014-0034593 (Apr. 20, 2014), an oxidizing agent such as ammonia or hydrogen peroxide is not used, and a porous silica, an acidic dye and a water- The present invention relates to a semi-permanent hair dye composition comprising only 1 component, but the above-described conventional semi-permanent hair dye composition has a pH of 2 to 5 and is inherently an acidic hair dye, Benzyl alcohol having an unpleasant odor for improving the bonding strength thereof, and silica for improving the durability, so that the usability is also unsatisfactory.

Korean Patent Publication No. 10-2014-0034593 (2014.03.20.)

Accordingly, a first object of the present invention is to provide a relatively more hypoallergenic and environmentally friendly powder hair dye composition by using a herbal herb and a pearl mineral water as main components and additionally using a chemical dye precursor.

A second object of the present invention is to provide a powder hair dye composition capable of preventing damage to hair and scalp by eliminating the use of an oxidizing agent as used in a permanent hair dye.

A third object of the present invention is to provide a powder hair dye composition having high usability because there is no discomfort due to an alkaline agent such as ammonia water used in a permanent hair dye.

The fourth object of the present invention is to improve the durability of dyes by enhancing the durability of dyes by swelling and softening of the dyes by the weakly alkaline agent, And to provide a powder hair dye composition which enables the powder hair dye composition to be used.

A fifth object of the present invention is to provide a powder hair dye composition in which the hair dye has excellent stability and storage property.

According to a preferred aspect of the present invention for attaining the above objects of the present invention, 0.3 to 4.0% by weight of a flour based on the total weight of the first agent, 0.02 to 2.0% by weight of a powder, 0.1 to 2.0% by weight of a green tea powder, 0.01 to 0.5% by weight of a licorice powder, 0.01 to 0.5% Based on the total weight of the first agent, 5 to 25% by weight of grain, 5 to 25% by weight of starch and 1 to 5% by weight of dextrin; 0.4 to 20% by weight of a dye based on the total weight of the first agent; A first agent comprising 16 to 30% by weight of a wetting agent, 5 to 20% by weight of a viscous agent, 5 to 20% by weight of sodium perborate as a binder, and 1 to 10% by weight of anhydrous sodium sulfate, based on the total weight of the first agent, : 80 to 120 parts by weight of a second pearl mineral water based on 100 parts by weight of the first pearl mineral. The pearl mineral water is obtained by crushing the pearl layer inside the pearl shell, After the mixture is dissolved by heating and stirring, an alkaline agent is added to elute the protein, and an acidic aqueous solution is added thereto to neutralize the solution to pH 7.5 to 8 to stabilize it, followed by filtration to obtain a hair dye composition.

In the above, the grains may be at least one kind of grains selected from the group consisting of wheat flour, rice flour, barley flour, and soybean flour.

Meanwhile, the starch may be at least one kind of starch selected from the group consisting of corn starch, potato starch, and sweet potato starch.

The viscosifying agent may be at least one viscous agent selected from the group consisting of sodium carboxymethylcellulose, sodium carboxymethylcellulose, guar gum, and gum arabic.

In the above, the dye may be composed of 0.1-5.0% by weight of p-phenylenediamine, 0.1-5.0% by weight of p-aminophenol, 0.1-5% by weight of o-aminophenol and 0.1-5% by weight of resorcinol have.

On the other hand, the number of the pearl mineral as the second agent may be nanoized and magnetized.

The hair dye composition according to the present invention is characterized by using a dye component of a natural herbal herb as a main component and additionally using a chemical dye precursor to obviate the use of an oxidizing agent which is relatively hypoallergenic and environmentally friendly and used for a permanent hair dye The hair and scalp can be prevented from being damaged, and there is no discomfort due to the alkaline agent such as ammonia water used in the permanent hair dyeing agent, so that it is highly usable. Further, the swelling of the hair- The dye penetration of the dye by softening improves the durability of the dye, imparts shine to the hair, enables natural color dyeing, and has excellent stability and storage properties.

Figs. 1A to 1D are actual views of a first agent as a powder state according to Examples 1 to 4, respectively.
Figs. 2A and 2B are photographs showing the constructions of the second agent, and photographs showing the equimolar mixture state of the first agent and the second agent, respectively.
Fig. 3 is a photograph showing the state of the untreated gum.
Figs. 4A to 4D are photographs of dyed state of dyed kumo with a first agent as a powder state and a second agent as a pearl mineral water according to Examples 1 to 4, respectively.
5 and 6 are photographs showing the dyed state using the first agent of Example 1, respectively.
Figs. 7 and 8 are photographs showing the dyed state using the first agent of Example 2, respectively.
9 is a photograph showing a state of staining using the first agent of Example 3. Fig.
10 is a photograph showing a state of staining using the first agent of Example 4. Fig.

Hereinafter, the present invention will be described in detail.

The hair dye composition according to the present invention is a two-part formulation. The hair dye composition according to the present invention is characterized by comprising 0.3 to 4.0% by weight of a zest pulp powder, 0.0 to 2.0% by weight of hemp powder, 0.1 to 2.0% by weight of a green tea powder, 0.01 to 0.5% by weight of the powder, 0.01 to 0.5% by weight of the sphagnum flower powder; Based on the total weight of the first agent, 5 to 25% by weight of grain, 5 to 25% by weight of starch and 1 to 5% by weight of dextrin; 0.4 to 20% by weight of a dye based on the total weight of the first agent; A first agent comprising 16 to 30% by weight of a wetting agent, 5 to 20% by weight of a viscous agent, 5 to 20% by weight of sodium perborate as a binder, and 1 to 10% by weight of anhydrous sodium sulfate, based on the total weight of the first agent, : 80 to 120 parts by weight of a second pearl mineral water based on 100 parts by weight of the first pearl mineral. The pearl mineral water is obtained by crushing the pearl layer inside the pearl shell, After solubilization with heating, an alkaline agent is added to elute the protein, and an acidic aqueous solution is added to neutralize the solution to pH 7.5 to 8 to stabilize it, followed by filtration.

Herein, the herbal herb powder is used for reducing hair damage and skin irritation during dyeing, and for oxidizing a chemical dye precursor, which will be described later, by the action of a natural enzyme contained in a plant powder to produce a dye .

In addition, the above-mentioned Hwasungcho is called "ten 药" in Japan, and it is called "outpost" or "above ground" in Korea and has antimicrobial action. Therefore, in the present invention, Which contributes to the stability of the hair dye after storage.

The present invention also relates to a powder of leaves and tails of Perilla frutescens Britton var. Acuta Kudo or Perilla frutescens Britton var. Crispa Decaisne, which has antibacterial and anti-inflammatory action and antiallergic action, Contributes to the storage stability and the mending polarity and anti-allergic properties.

In addition, the above-mentioned green tea powder is obtained by processing leaves of the tea tree (Thea sinensis L.), which is a tea plant, and imparts the anti-inflammatory property and the feeling of sadness when using the hair dye according to the present invention.

On the other hand, the Glycyrrhiza uralensis FISCH powder contributes to the anti-inflammatory action, anti-allergic action and antiseptic action of the hair dye according to the present invention, and neutralizing and detoxifying action of the artificial dye.

Lastly, the centella asiatica powder contains centella asiatica, a substance of madecasol, soothing the skin weakened by stimulation and inducing a soothing effect to enhance the self-sustaining ability.

The herbal herb powder contains various natural pigments such as cyanine, cyanine p-coumarate glycoprotein, Pf-gp6, flavonoid, luteolin, apigenin and the like, And is used for oxidizing and coloring a dye chemical dye precursor to be described later by oxidation of various natural enzymes contained in the herbal herb powder.

On the other hand, the vegetable powder used in an amount of 5 to 25% by weight of grain, 5 to 25% by weight of starch and 1 to 5% by weight of dextrin has a function of imparting a point composition to a hair dyeing agent when mixed with a weakly alkaline pearl mineral water as a second And absorbs moisture when mixed with the first agent as a powder state to inhibit the growth of microorganisms with high osmotic pressure and low water activity and to prevent corruption.

When the content of the above-mentioned vegetable powder is less than the above-mentioned range, the viscosity is low and the feeling of use becomes poor. On the contrary, when the above-mentioned range is exceeded, the viscosity becomes too high and the feeling of use is lowered.

In addition, dextrin, which occurs during the hydrolysis of starch, is used for improving solubility with the second agent and contributes to the long-term preservability of the powder hair dye according to the present invention.

In the above, the above-mentioned grains may be flour, rice flour, barley flour, soy flour, or any mixture thereof, although the invention is not limited thereto.

The starches described above may also be corn starch, potato starch, sweet potato starch, or a mixture thereof, although not limited in the present invention.

Also, the above-mentioned dextrins can be used in the present invention either as maltodextrin or cyclodextrin or a mixture thereof.

As the dye (precursor), a dye precursor known in the art can be used. The dye precursor is not limited to the present invention but may be selected from 0.1 to 5% by weight of p-phenylenediamine, 0.1 to 5% 5% by weight, o-aminophenol 0.1 to 5% by weight, and resorcinol 0.1 to 5% by weight.

These dyes (precursors) are provided so as to exhibit various dye colors with different proportions of each component.

Since these dyes (precursors) are well known in the art, a detailed description thereof will be omitted, but they are not developed by an oxidizing agent such as hydrogen peroxide as in the case of a conventional permanent hair dye, but in the present invention, It is gently colored.

Meanwhile, the wetting agent used in the powder hair dyeing agent according to the present invention is used for absorbing or preserving moisture, and its content range is limited to 16 to 30% by weight in order to obtain an excellent effect in the hair dyeing agent. As the wetting agent used in the present invention, At least one wetting agent selected from the group consisting of sorbitol, xylitol, mannitol and maltitol can be used.

The above-mentioned viscous agent is a gel-forming agent for forming a viscous solution or gel by binding with water. In order to obtain an excellent viscous action effect in the present invention, the content is limited to a range of 5 to 20% by weight.

As the viscous agent, at least one viscous agent selected from the group consisting of carboxymethylcellulose sodium, carboxymethylcellulose sodium, guar gum, and gum arabic can be used.

Sodium perborate and anhydrous sodium sulfate are used as a binder, and their contents are limited to 5 to 20% by weight and 1 to 10% by weight, respectively, for good binding force in a hair dye.

On the other hand, the number of the above-mentioned pearl mineral as the second agent is very similar to that of the natural moisturizing factor (NMF) existing in the stratum corneum of the skin and provides nutrition and moisturizing to the hair and shows the shine and smoothness of the hair It is used to lose the shine after dyeing and to exhibit the effect of preventing roughness of hair. By setting the pH to 7 to 9, preferably 7.5 to 8, and particularly to about 7.9, the swelling ) And softening, the dye (precursor) penetrates into the inside of the follicle, thereby enhancing the durability of the dye.

The pearl mineral water is produced from powder obtained by crushing a pearl layer inside the shell of a pearl shellfish. The pearl layer is composed of about 90-95% by weight of calcium carbonate and about 5% by weight of organic matter, Most of them are made up of skeletal proteins. The pearl protein is mainly known as Conchiolin protein. It is layered with pearl luster that is formed by crossing with conchiolin and aragonite type calcium carbonate crystals.

The above-mentioned conchiolin is an amino acid component which is close to NMF (natural moisturizing factor) contained in each layer of the skin. It is reported that the conkioline maintains the moisturization of the skin, supplies whitening factors and provides shine of hair, and magnesium, It is known to have useful effects on skin including 20 kinds of elemental minerals such as iron, manganese, sodium, calcium, zinc, and silicon and various physiological substances.

The pearl mineral water used as the second agent of the hair dye composition according to the present invention is obtained by pulverizing the above-mentioned pearl powder into fine powders of 400 mesh or less which are easily absorbed by the human body and then pulverizing the pulverized pearl powder with purified water For about 10 to about 20 hours, and then the protein is eluted together with about 20% of the solubilized pearl powder. The acidified aqueous solution is added to the solubilized reactant to adjust pH to 7-9, Neutralize to a range of 7.5 to 8 and stabilize.

Then, after filtration to remove the precipitate formed in the stabilization process, the filtrate is obtained by the nanoization step of nano-depositing the high-frequency vibrator and the high speed propeller cutting device, and magnetizing the nano-sized solution by using the magnetizing device.

Example  1 to 4

The hair dye composition according to the present invention was formulated into compositional components and composition ratios as shown in the following Table 1, and a real image of the first agent as a powder state according to Examples 1 to 4 is shown in Figs. 1A to 1D, , The constructions of the second agent, and the equimetric mixing states of the first agent and the second agent are shown in Figs. 2A and 2B, respectively.

Raw material (% by weight) Example 1 Example 2 Example 3 Example 4 1 Grain powder 20 20.8 23 24 Starch 20 20 20 20 dextrin 3 3 3 3 Wetting agent 25 25 25 25 Sodium polyacrylate 0.5 0.5 0.5 0.5 Viscous agent 6.5 6.5 6.5 6.5 And sodium borate 10 10 10 10 Anhydrous sodium sulfate 5 5 5 5 Whitewash powder 0.5 0.5 0.5 0.5 Folding leaf powder One One One One Green tea powder One One One One Licorice Powder 0.5 0.5 0.5 0.5 Lotus powder 0.5 0.5 0.5 0.5 Dye p-phenylenediamine 4.5 3.7 1.5 0.5 p-Aminophenol 0.5 0.5 0.5 0.5 o-Aminophenol One One One One Resorcinol 0.5 0.5 0.5 0.5 Sum 100 100 100 100 2 Number of pearl minerals 100 100 100 100

Test Example  One

The camomile was homogeneously coated with the hair dye composition according to the present invention, which was an equal weight mixture of the first and second agents of Examples 1 to 4, allowed to stand for 15 minutes, washed three times with lukewarm water, and dried.

The untreated gum as a control is shown in Fig. 3, and the gum dyed with the hair dye composition of Examples 1 to 4 is shown in Figs. 4A to 4D, respectively.

As shown in Figs. 4A to 4D, the hair dyed with the hair dye composition according to the present invention of Examples 1 to 4 exhibited both luster and smoothness, showed natural hair color, Was not found.

Test Example  2

5 and 6 show the state before and after dyeing for adult men and women under the same conditions as in Test Example 1 using the natural mineral water as the first agent and the second agent of Example 1, The case where the first agent of 2 is used is shown in Fig. 7 and Fig. 8, respectively.

Fig. 9 shows the case of using the first agent of Example 3, and Fig. 10 shows the case of using the first agent of Example 4. Fig.

5 to 10, the hair dye composition obtained by mixing the first agent comprising the herbal herb powder according to the present invention and the second agent comprising the pearl mineral water has excellent salt strength, It has been found that there is no damage to the scalp, it is not only safe, but also excellent in feeling and excellent in applicability because there is no irritation.

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. Various changes and modifications can be made by those skilled in the art without departing from the spirit and scope of the invention Which is also within the scope of the present invention.

Claims (6)

Wherein the green tea powder is used in an amount of 0.01 to 0.5% by weight, the sperm powder is used in an amount of 0.01 to 0.5% by weight, 0.5% by weight herbal herb powder; Based on the total weight of the first agent, 5 to 25% by weight of grain, 5 to 25% by weight of starch and 1 to 5% by weight of dextrin; 0.4 to 20% by weight of a dye based on the total weight of the first agent; A first agent comprising 16 to 30% by weight of a wetting agent, 5 to 20% by weight of a viscous agent, 5 to 20% by weight of sodium perborate as a binder, and 1 to 10% by weight of anhydrous sodium sulfate, based on the total weight of the first agent, :
And 80 to 120 parts by weight of a second pearl mineral water based on 100 parts by weight of the first part,
The pearl mineral water was obtained by crushing the pearl layer inside the shell of the pearl shell, and the resulting fine powder was dissolved with purified water at 100 ° C by heating and stirring. Then, an alkaline agent was added to elute the protein, and an acidic aqueous solution was added thereto to neutralize Which is then stabilized and then filtered.
Hair dye composition. The hair dyeing composition according to claim 1, wherein the grain is at least one grain selected from the group consisting of wheat flour, rice flour, barley flour and soy flour. The hair dyeing composition according to claim 1, wherein the starch is at least one kind of starch selected from the group consisting of corn starch, potato starch, and sweet potato starch. The hair dyeing composition according to claim 1, wherein the viscous agent is at least one viscous agent selected from the group consisting of sodium carboxymethylcellulose, sodium carboxymethylcellulose, guar gum, and gum arabic. 3. The composition of claim 1, wherein the dye is selected from the group consisting of 0.1-5.0 wt.% Of p-phenylenediamine, 0.1-5.0 wt.% Of p-aminophenol, 0.1-5 wt.% Of o- 0.1 to 5% by weight of resorcinol. The hair dyeing composition according to claim 1, wherein the number of the pearlescent mineral water of the second agent is nanoized and magnetized.

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