KR101453106B1 - Cleansing composition - Google Patents

Abstract

Provided is a detergent composition having less irritation to the skin, excellent foamability, creamy quality, and good rinsability.

The following components (A), (B) and (C)

And (A) (a ₁₎ phosphoric acid monoester-based surfactants represented by formula (1),

(a ₂ ) a phosphoric acid diester surfactant represented by the general formula (2)

(A ₁ ) / (a ₂ ) = 90/10 to 50/50 in terms of a weight ratio of the phosphate ester surfactant:

(B) a compound represented by the general formula (3)

A sulfuric acid ester surfactant represented by the following formula

(C) (C-1) at least one glyceryl ether having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms, and

(C-2) General formula (4)

≪ / RTI >

≪ / RTI >

Description

CLEANSING COMPOSITION [0001]

The present invention relates to a detergent composition having less irritation to skin and the like, excellent foamability, a creamy quality, and good rinsability.

Heretofore, sulfuric acid ester surfactants such as alkyl sulfate and polyoxyethylene alkyl sulfate have been widely used as detergent surfactants. However, such a sulfuric acid ester surfactant is not suitable as a cleanser for the body because it is light in weight and longevity, but is slippery in rinsing and poor in rinsability.

On the other hand, phosphate ester surfactants are known as mild surfactants with low irritation to skin and the like, but since they are all a mixture of a monoester and a diester or a mixture of mono, di, and triesters, Foam force) is inferior, and when it is used solely as a cleaning agent main component, there is generally a problem in bubble strength.

To improve the problem of the foamability, a detergent composition containing a sulfuric acid ester surfactant and a phosphate ester surfactant has been disclosed (for example, Patent Document 1 and Patent Document 2), the foaming power is not satisfactory , And the rinseability is not mentioned. In addition, a detergent composition containing a phosphate ester surfactant and glyceryl ether has been disclosed (Patent Document 3), but the foaming power is not sufficiently satisfactory.

Patent Document 1: JP-A-2003-313585

Patent Document 2: JP-A-2006-22116

Patent Document 3: JP-A-2005-206804

DISCLOSURE OF INVENTION

The present invention relates to the following components (A), (B) and (C)

And (A) (a ₁₎ phosphoric acid monoester-based surfactants represented by formula (1),

(a ₂₎ as a mixture of a phosphoric acid diester-based surfactants represented by formula (2), in that the content of the weight ratio _{(a 1) / (a 2} ) = 90/10 ~ 50/50 phosphoric acid ester-based surface active agent :

Wherein X ¹ , X ² and Y each represent a hydrogen atom, an alkali metal atom, an alkaline earth metal atom or an alkaline earth metal atom, wherein R ¹ , R ² and R ³ each represent a linear or branched alkyl or alkenyl group having 8 to 18 carbon atoms, An atom, an alkanolamine or ammonium, and the average addition mole number k, m and n each represent a number of 0 to 10;

(Wherein R ⁴ represents an alkyl or alkenyl group having 8 to 18 carbon atoms, M represents an alkali metal atom, an alkaline earth metal atom, an alkanolamine, an ammonium or a basic amino acid, Lt; / RTI >

A sulfuric acid ester surfactant represented by the following formula:

(C) (C-1) at least one glyceryl ether having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms, and

(In the formula, R ⁵ represents an alkyl group or alkenyl group of straight-chain or branched having a carbon number of ⁶ ~ 10, R 6 is a hydrogen atom or a methyl group, AO represents an alkylene oxide having a carbon number of 2-4, an additional average The molar number q represents a number of 0.5 to 3)

≪ / RTI > To provide a detergent composition.

The present invention also provides a method of cleaning the body applying the detergent composition to the body.

The present invention also provides use of the detergent composition for cleaning the body.

DETAILED DESCRIPTION OF THE INVENTION

An object of the present invention is to provide a detergent composition having less irritation to the skin and the like, having excellent foamability, being creamy and having good rinsability.

INDUSTRIAL APPLICABILITY The detergent composition of the present invention is less irritating to the skin and the like, has excellent foamability, is creamy, and has good rinsing properties.

In the phosphoric acid ester represented by the general formulas (1) and (2) of the component (A) as the hypothetical base used in the present invention, R ¹ , R ² and R ³ are preferably an alkyl group having 10 to 16 carbon atoms and 12 to 14 carbon atoms X ¹ , X ² and Y are preferably alkali metal atoms such as potassium or sodium, or triethanolamine, and potassium is particularly preferred in view of solubility in water. The average addition mole number k, m and n of the ethylene oxide is 0 to 4 mols, more preferably 0 to 2 mols, and still more preferably 0 to 1 moles in terms of foaming power.

Component (A) The content of the alkyl phosphate monoesters (a ₁₎ and the alkyl diester (a ₂₎ of, in terms of ease of formulation, the weight ratio _{(a 1) / (a 2} ) = 90/10 ~ 50 / 50, preferably 85/15 to 60/40, more preferably 80/20 to 70/30.

When the weight ratio (a ₁ ) / (a ₂ ) is less than 50/50, the foaming property is poor. When the weight ratio (a ₁ ) / (a ₂ ) is more than 90/10, the melting point of the alkyl phosphate ester mixture becomes high and the mixing becomes difficult.

The content of the phosphate ester surfactant of the component (A) is preferably from 1 to 15% by weight, more preferably from 2 to 10% by weight, based on the cleanser composition of the present invention, from the viewpoints of foam generation, , More preferably 3 to 10 wt%.

The component (A) can be prepared by, for example, adding ethylene oxide to the corresponding aliphatic alcohol or the corresponding aliphatic alcohol to obtain an ethoxylate having an average addition molar number of more than 0 to 10 and an anhydride selected from the group consisting of anhydrous phosphoric acid, orthophosphoric acid, polyphosphoric acid, A phosphoric acid ester obtained by reacting a phosphoric acid such as phosphoric acid chloride or the like or a phosphoric acid ester obtained by partially or completely neutralizing the phosphoric acid ester with an alkali such as sodium hydroxide or potassium hydroxide. (a ₁ ) / (a ₂ ) Can be controlled by the ratio of the aliphatic alcohol and the water contained in the phosphorylating agent.

As a method for obtaining (a ₁ ) / (a ₂ ) = 90/10 to 50/50, for example, by using orthophosphoric acid containing anhydrous phosphoric acid and water at the time of the reaction, with (a ₁₎ / method for controlling the ratio of (a _{2) or, (a 1) / (a} 2) = 100/0 - 95/5 of the phosphoric acid ester with _{(a 1) / (a 2} ) = 50 / 50 phosphoric acid ester is mixed at an appropriate ratio.

In the sulfuric acid ester surfactant represented by the general formula (3) of the component (B), R ⁴ is preferably a straight chain alkyl group having an average carbon number of 8 to 18, preferably 10 to 16, more preferably 10 to 14, Chain or branched chain alkyl or alkenyl group.

In addition, M is preferably an alkali metal such as potassium or sodium, triethanolamine or ammonium, and potassium, sodium or ammonium is preferable from the viewpoint of solubility in water and foaming.

The content of the component (B) is preferably from 5 to 40% by weight, more preferably from 5 to 35% by weight, still more preferably from 5 to 20% by weight, from the viewpoints of cleaning property and foaming property of the detergent composition of the present invention .

In the detergent composition of the present invention, the preferable contents of the components (A) and (B) are as described above, but the content ratio of the component (A) A) is preferably 0.5 to 20, more preferably 1 to 10, from the viewpoints of washing power, foaming power, gage quality and rinsability, more preferably 2 to 5.

The glyceryl ether of the component (C-1) has an alkyl group or an alkenyl group of a linear or branched chain having 6 to 12 carbon atoms, and examples thereof include an n-hexyl group, an isohexyl group, An octyl group, a 2-ethylhexyl group, an n-nonyl group, an n-decyl group and an n-lauryl group, and further preferably an alkyl group having 6 to 12 carbon atoms and further having a carbon number of 6 to 10, Especially 1 or 2, more preferably 1, alkyl group having 8 carbon atoms.

The glyceryl ether of the component (C-1) may be used in an amount of 0.1 to 20% by weight, more preferably 0.1 to 10% by weight and further 0.1 to 5% by weight in the total composition, .

Component (C-1) can be obtained, for example, by hydrolyzing the corresponding glycidyl ether and water at 100 to 230 ° C.

In the alkylene oxide adduct of the alcohol represented by the general formula (3) of the component (C-2), R ⁵ is a linear or branched alkyl group or alkenyl group having 6 to 10 carbon atoms, preferably 8 to 10 carbon atoms More preferably an alkyl group having 8 carbon atoms. AO is an alkyleneoxy group having 2 to 4 carbon atoms, more preferably an alkyleneoxy group having 2 to 3 carbon atoms, and still more preferably an alkyleneoxy group having 3 carbon atoms. Specific examples include an ethyleneoxy group, a propyleneoxy group and a butyleneoxy group, and an ethyleneoxy group and a propyleneoxy group are preferable, and a propyleneoxy group is further preferable. The average addition mole number q represents a number of 0.5 to 3, preferably 1 to 3, more preferably 2 to 3. From the viewpoint of economical efficiency of reducing the production cost such as purification when AO _max is the component with the highest molar number of addition of AO in the component (C-2), AO _max is 70 By weight or less, more preferably 60% by weight or less, still more preferably 50% by weight or less. When AO is an oxyalkylene group having 2 carbon atoms, that is, an oxyethylene group, AO _max is 60% by weight or less, more preferably 50% by weight or less, still more preferably 40% by weight or less, Respectively. Further, when AO is an oxyalkylene group having 3 carbon atoms, that is, an oxypropylene group, AO _max is 70% by weight or less, more preferably 60% by weight or less, still more preferably 50% by weight or less, By weight or less. R ⁶ represents a hydrogen atom or a methyl group, more preferably a hydrogen atom. The component (C-2) may be used in an amount of 0.1 to 20% by weight, more preferably 0.1 to 15% by weight, further preferably 0.1 to 10% by weight based on the total composition in terms of rinsing property and bubble strength Do.

The component (C-2) can be obtained, for example, by reacting a corresponding aliphatic alcohol with propylene oxide and / or ethylene oxide and then distilling off the raw alcohol.

The total amount of the component (C) is preferably from 0.1 to 20% by weight, more preferably from 0.1 to 15% by weight, and even more preferably from 0.1 to 10% by weight, based on the detergent composition of the present invention.

The detergent composition of the present invention is a detergent composition useful as a body cleansing agent such as a skin cleansing agent or a hair cleansing agent such as a cleanser, a shampoo, a body shampoo and the like, and is more preferably used as a skin cleansing agent such as a cleanser or body shampoo. These detergent compositions may contain optional components depending on the purpose. Examples of the optional components include other anionic surfactants, nonionic surfactants, amphoteric surfactants, cationic surfactants, and conditioning components, which are usually blended with these cleaning agents.

Examples of other anionic surfactants include fatty acid salts, sulfosuccinic acid surfactants, sulfosuccinate surfactants, polyoxyalkylene alkylamide ether sulfates, monoglyceride sulfates, olefin sulfonates, alkanesulfonates, Examples of the nonionic surfactant include alkyl polyglucosides, sucrose fatty acid esters, polyglycerin fatty acid esters, fatty acid alkanolamides, fatty acid alkanolamides, polyoxyethylene alkyl ether phosphates, , Alkylamine oxides, fatty acid polyhydric alcohol esters, and the like. Examples of the cationic surfactant include a mono or di-long chain alkyl quaternary ammonium salt of a linear or branched chain, a mono or di-long chain alkyl tertiary amine, and the like; Examples of the amphoteric surfactant include amide amino acid-based activators, carbobetaine-based activators, sulfobetaine-based activators, amidosulfobetaine-based activators, imidazolinium betaine-based activators, amino acid betaine activators, phosphobetaine- .

Examples of the conditioning component include emulsions such as higher alcohols, silicones and silicone derivatives, lanolin, squalene, hydrocarbons, protein derivatives and fatty acid esters of polyethylene glycol, cationized cellulose, cationic guar gum or Makoto 550 (manufactured by Naruko) KG-301W (manufactured by Kao Corporation) and the like.

Other components commonly used in the detergent composition include water-soluble polymers such as polysaccharides such as methyl cellulose, hydroxyethyl cellulose, carboxyvinyl polymer and xanthan gum; Viscosity regulators such as polyoxyalkylene sorbitan esters, polyoxyethylene glycol distearate, and ethanol; Chelating agents such as ethylenediaminetetraacetic acid (EDTA), phosphonates; Preservatives such as methylparaben and butylparaben; Active ingredients such as vitamins and their precursors; Plant and animal extracts such as lecithin and gelatin, or derivatives thereof; Polymer fine powder such as nylon or polyethylene; Anti-inflammatory agents such as dipotassium glycyrrhizinate; Antiseptics such as triclosan, trichlorocarbane, octopirox, and zinc pyrithione; antidandruff agents; Antioxidants such as dibutylhydroxytoluene; Ultraviolet absorber, pH adjuster, coloring agent, perfume, and water may be added as needed within a range not to impair the effects of the present invention.

The detergent composition of the present invention preferably has a pH of 4 to 8.

The detergent composition of the present invention is preferably used with water having a hardness of 1 to 30 DEG DH.

It is preferable that the pH of the water used herein is 4 to 9.

The detergent composition of the present invention can be prepared by a conventional method. There is no particular limitation on the formulation of the detergent composition of the present invention, and various known formulations, for example, liquid body shampoo, cream-based anti-pigment, and the like can be used. The detergent composition of the present invention is particularly preferable as a detergent for the body such as skin, hair and the like.

Production Example 1

Represents the reaction vessel of an atmosphere of nitrogen 500㎖ raw material alcohol (lauryl alcohol) 187.3g (1.0 mol) as added, and orthophosphoric acid 31.9g [P ₂ O ₅ nH ₂ O and 85% by weight of P ₂ O ₅ 19.6 g (0.14 mol) of H ₂ O (12.3 g, 0.68 mol)] was added and stirred and mixed at 35 ° C. 62.1 g (0.43 mol) of phosphorus pentoxide (effective amount: 98.5% by weight) was gradually added thereto with stirring for 60 minutes. The temperature was raised to 65 ° C, and the temperature was further raised to carry out a reaction at 80 ° C for 12 hours. Further, 10.0 g of water was added, and hydrolysis was carried out at 80 DEG C for 3 hours. The resulting phosphate ester was neutralized with potassium hydroxide to give a salt of lauryl phosphate K (monolaurylate / dilaurylate = 80/20) shown in Table 1, ≪ / RTI >

Production Example 2

In the same manner as in Preparation Example 1, the reaction was conducted by adjusting the amount of water relative to the lauryl alcohol so that the monolauryl / di-lauryl form was 60/40, and the lauryl phosphate K salt (monolauryl formate / Dilauryl form = 60/40).

Production Example 3

In the same manner as in Preparation Example 1, the reaction was conducted by adjusting the amount of water relative to the lauryl alcohol so as to be monolauryl / diarylate = 70/30. The resulting phosphoric acid ester was neutralized with triethanolamine, Lauryl phosphate triethanolamine salt (monolauryl / diarylate = 70/30) was obtained.

Production Example 4

230.4 g (1.0 mol) of a raw alcohol (lauryl alcohol, EO = 1 mol per one mole added on average) was added to a 500 ml reaction vessel under a nitrogen atmosphere, and 31.9 g of 85% by weight orthophosphoric acid [P ₂ O ₅ .nH ₂ 19.6 g (0.14 mol) of P ₂ O _{5 and} 12.3 g (0.68 mol) of H ₂ O were added thereto, and the mixture was stirred and mixed at 35 ° C. 62.1 g (0.43 mol) of phosphorus pentoxide (effective amount: 98.5% by weight) was gradually added thereto with stirring for 60 minutes. The temperature was raised to 65 ° C, and the temperature was further raised to carry out a reaction at 80 ° C for 12 hours. Further, 10.0 g of water was added, and hydrolysis was carried out at 80 캜 for 3 hours. The obtained phosphate ester was neutralized with potassium hydroxide to prepare a salt of polyoxyethylene (1) lauryl ether phosphate K (monolaurylether / dilauryl Sieve = 80/20).

Production Example 5

In the same manner as in Production Example 1, lauryl alcohol, EO = the average 1 mole addition product was changed to myristyl alcohol and EO = 1 mole average addition product, and the amount of monomyrstillate / (1) myristyl ether phosphate K salt (monomyrstillate / dimyristyl ester = 85/1) shown in Table 1 was prepared by adjusting the amount of water to myristyl alcohol and EO = 15).

Production Example 6

In the same manner as in Production Example 1, lauryl alcohol, EO = lauryl alcohol with an average of 1 mole of the product, EO = average 2 mole of the product, and lauryl (2) lauryl ether phosphate K salt (monolauryl formate / dilauryl formate = 75/25) shown in Table 1 was prepared by reacting the reaction product by adjusting the amount of water to alcohol and EO = .

Production Example 7

208 g of 2-ethylhexyl glycidyl ether, 104.8 g of water, 5.82 g of lauric acid and 18.5 g of potassium hydroxide were placed in an autoclave and stirred at 140 DEG C for 5 hours. After dehydration at 100 占 폚 under reduced pressure (6.67 kPa), 9.7 g of lauric acid and 2.72 g of potassium hydroxide were added and reacted at 160 占 폚 for 15 hours and then subjected to vacuum distillation (53 to 67 Pa, 120 to 123 占 폚) Ethylhexyl glyceryl ether shown in Table 1 was obtained.

Production Example 8

In the same manner as in Production Example 7, 2-ethylhexyl glycidyl ether was changed to n-octyl glycidyl ether to obtain n-octyl glyceryl ether shown in Table 1. [

Production Example 9

1615.0 g (12.35 mol) of 1-octanol (Carcor 0898, manufactured by Kao Corporation) and 6.9 g (0.12 mol) of potassium hydroxide were introduced into an autoclave and dehydrated at 110 ° C and 13.3 kPa, Addition reaction was carried out while 1434 g (24.69 mol) of propylene oxide was pressurized to 0.3 MPa.

After completion of the reaction, aging was carried out at the same reaction temperature for 6 hours, and then the mixture was cooled to 80 캜.

55 g of a synthetic adsorbent (Kyowaud 600S, Kyowa Chemical Industry Co., Ltd.) was added to the reaction composition obtained as a post-treatment, treated at 4.0 kPa for 1 hour, and then the catalyst was removed by filtration.

Subsequently, 1-octanol was distilled off at 1000 占 폚 under the condition of 130 占 폚 and 1.3 kPa. Further, steam treatment was performed by blowing 100 g of water vapor at 145 캜 and 6.0 kPa for 5 hours to obtain dipropylene glycol mono octyl ether shown in Table 1.

Production Example 10

In the same manner as in Production Example 9, diethylene glycol 2-ether hexyl ether shown in Table 1 was obtained by changing 1-octanol to 2-ethylhexyl alcohol and propylene oxide to ethylene oxide.

Examples 1 to 20 and Comparative Examples 1 to 6

The cleaning composition having the composition shown in Table 1 was prepared by mixing each component at 70 캜 according to the conventional method (adjusting the pH to 6 to 7), applying 1 g thereof to the palm of a hand, The quality and rinsability were evaluated by 10 professional panelists according to the following evaluation criteria. The results are shown in Table 1.

(Foaming)

4: There is a lot of foam.

3: There is a lot of foam.

2: Few little foam

1: Few bubbles

(High quality)

4: smooth, also very creamy and good quality

3: Creamy and good quality

2: slightly creamy quality

1: Lightweight and poor quality

(Rinseability)

4: No slippery, good rinseability

3: No slippery, slightly better rinsing property

2: slightly slippery, slightly rinseable

1: slippery, poor rinseability

Rank

A: Average rating of 3.5 or higher

B: Average rating is 2.5 or more, less than 3.5

C: Average rating of 1.5 or more, less than 2.5

D: Average rating less than 1.5

Examples 21 to 24

As a result of the following recipe, a three-color pigment and a general cleaning agent having a pH of 5.0 to 7.0 were prepared. The pH was adjusted with citric acid and potassium hydroxide. Even in all regions where the pH of the water to be used is less than 4 to 5, less than 5 to 8, and 8 to 9 and the hardness of water to be used is 1 to 30 DH, Good quality, good cream quality and good rinsability.

Example 21 (Tri Pigment)

(Component) (% by weight)

Lauryl phosphate K salt

(Monolauryl form / dilauryl form = 75/25) 0.5

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl form / dilauryl form = 75/25) 1.5

Polyoxyethylene (2) lauryl sulfate Na b) 24.0

Dipropylene glycol 0.5

Dipropylene glycol monooctyl ether 0.4

Lauroyl hydroxysporobetaine 1.2

N, N-dimethylaminoethyl methacrylate diethylsulfate N, N-dimethylacrylamide / dimethacrylic acid polyethylene glycol copolymer 4 wt% aqueous solution c) 2.5

Acrylic acid alkyl methacrylate copolymer d) 0.5

Sodium Chloride 1.0

Sodium Sulfate 3.0

Ethylene glycol distearate 2.0

Methyl paraben 0.2

Propyl paraben 0.1

BHT 0.2

Fragrance 0.05

Purified water balance

Total 100.00

(a) represents the average addition mole number of ethylene oxide, and k = m = n = 1 in the general formulas (1) and (2).

b) the compound in parentheses represents the average addition mole number of ethylene oxide, and p = 2 in the general formula (3).

c) SOFACARE KG-301W; Manufactured by Kao Corporation

d) Carbopol ETD2020; Manufactured by BFGoodrich

Example 22 (Tri Pigment)

(Component) (% by weight)

Lauryl phosphate K salt

(Monolauryl form / dilauryl form = 75/25) 0.5

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl form / dilauryl form = 75/25) 1.5

Polyoxyethylene (1) ammonium lauryl sulfate b) 24.0

Dipropylene glycol 10.0

2-ethylhexyl glyceryl ether 0.2

Lauroyl hydroxysporobetaine 1.2

N, N-dimethylaminoethyl methacrylate diethylsulfate N, N-dimethylacrylamide / dimethacrylic acid polyethylene glycol copolymer 4 wt% aqueous solution c) 2.5

Acrylic acid alkyl methacrylate copolymer d) 0.5

Sodium Chloride 1.0

Sodium Sulfate 3.0

Ethylene glycol distearate 2.0

Methyl paraben 0.2

Propyl paraben 0.1

BHT 0.2

Fragrance 0.05

Purified water balance

Total 100.00

(a) represents the average addition mole number of ethylene oxide, and k = m = n = 1 in the general formulas (1) and (2).

b) the compound in parentheses represents an average addition mole number of ethylene oxide, and p = 1 in the general formula (3).

c) SOPCKER KG-301W manufactured by CAO Corporation

d) Carbopol ETD2020: manufactured by BFGoodrich

Example 23 (body shampoo)

(Component) (% by weight)

Lauryl phosphate K salt

(Monolauryl form / dilauryl form = 75/25) 1.3

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl form / dilauryl form = 75/25) 3.8

Polyoxyethylene (2) lauryl ether sulfate Na b) 15.0

Dipropylene glycol 0.7

Dipropylene glycol monooctyl ether 0.6

Lauroylhydroxysulfobetaine 10.0

Polyoxyethylene sorbitan triisostearate

(160EO) 2.0

Sorbit solution 5.0

N, N-dimethylaminoethyl methacrylate diethylsulfate N, N-dimethylacrylamide / dimethacrylic acid polyethylene glycol copolymer 4 wt% aqueous solution c) 2.5

Ethylene glycol distearate 2.0

Methyl paraben 0.1

Propylparaben 0.2

BHT 0.2

Fragrance 0.05

Purified water balance

Total 100.00

(a) represents the average addition mole number of ethylene oxide, and k = m = n = 1 in the general formulas (1) and (2).

b) the compound in parentheses represents the average addition mole number of ethylene oxide, and p = 2 in the general formula (3).

c) SOFACARE KG-301W; Manufactured by Kao Corporation

Example 24 (body shampoo)

(Component) (% by weight)

Lauryl phosphate triethanolamine salt

(Monolauryl form / dilauryl form = 75/25) 1.3

Polyoxyethylene (1) lauryl ether phosphate triethanolamine salt a)

(Monolauryl form / dilauryl form = 75/25) 3.8

Polyoxyethylene (2) lauryl ether sulfate Na b) 15.0

Dipropylene glycol 0.7

Diethylene glycol 2-ethylhexyl ether 0.3

Lauroylhydroxysulfobetaine 10.0

Polyoxyethylene sorbitan triisostearate

(160EO) 2.0

Sorbit solution 5.0

N, N-dimethylaminoethyl methacrylate diethylsulfate N, N-dimethylacrylamide / dimethacrylic acid polyethylene glycol copolymer 4 wt% aqueous solution c) 2.5

Ethylene glycol distearate 2.0

Methyl paraben 0.1

Propylparaben 0.2

BHT 0.2

Fragrance 0.05

Purified water balance

Total 100.00

(a) represents the average addition mole number of ethylene oxide, and k = m = n = 1 in the general formulas (1) and (2).

b) the compound in parentheses represents the average addition mole number of ethylene oxide, and p = 2 in the general formula (3).

c) SOFACARE KG-301W; Manufactured by Kao Corporation

Claims (10)

The following components (A), (B) and (C) And (A) (a ₁₎ phosphoric acid monoester-based surfactants represented by formula (1), (a ₂ ) a phosphoric acid diester surfactant represented by the general formula (2) (A ₁ ) / (a ₂ ) = 90/10 to 50/50 in terms of a weight ratio of the phosphate ester surfactant: [Chemical Formula 1]

(Wherein R ¹ , R ² and R ³ each represent a linear or branched alkyl or alkenyl group having 8 to 18 carbon atoms, and X ¹ , X ² and Y each represent a hydrogen atom, an alkali metal atom, An amine or an ammonium, and the average addition mole number k, m and n each represent a number of 0 to 10;

(Wherein R ⁴ represents an alkyl or alkenyl group having 8 to 18 carbon atoms, M represents an alkali metal atom, an alkanolamine, an ammonium or a basic amino acid, and an average addition mole number p represents a number of 0 to 5) A sulfuric acid ester surfactant represented by the following formula: (C) (C-1) at least one glyceryl ether having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms, and

(In the formula, R ⁵ represents an alkyl group or alkenyl group of straight-chain or branched having a carbon number of ⁶ ~ 10, R 6 is a hydrogen atom or a methyl group, AO represents an alkylene oxide having a carbon number of 2-4, an additional average The molar number q represents a number of 0.5 to 3) ≪ / RTI > (B) / component (A) = 0.5 to 20 in terms of a weight ratio of the component (A) and the component (B). The method according to claim 1, A cleaning composition comprising component (A) and component (B) in a weight ratio of component (B) / component (A) = 1 to 10. 3. The method according to claim 1 or 2, Wherein the amount of the component (A) is 1 to 15% by weight. 3. The method according to claim 1 or 2, And the component (B) is 5 to 40% by weight. 3. The method according to claim 1 or 2, And from 0.1 to 20% by weight of component (C). 3. The method according to claim 1 or 2, pH 4 to 8. 3. The method according to claim 1 or 2, Is used with water having a hardness of 1 to 30 DEG DH. 3. The method according to claim 1 or 2, is used with water having a pH of 4-9. A method of cleaning a body applying the cleaning composition according to claim 1 or 2 to the body. 3. The detergent composition according to claim 1 or 2, used for cleaning the body.