KR101258045B1 - Method and apparatus for treatment of wastewater - Google Patents

Abstract

It is possible to shorten the incubation period until the microorganism is attached to the adhesion fixing material, and also to keep the microorganisms in the attachment fixation material at a high concentration since the highly active microorganisms leaking from the comprehensive microbial carrier are always supplied to the attachment fixation material. It is possible to obtain stable and good treated water at all times.
Wastewater containing organic or inorganic substances is introduced into the biological treatment tank 12 through the raw water introduction pipe 18. The biological treatment tank 12 is filled with a comprehensive microbial carrier 14 and an attachment carrier 16. As a result, bacteria inside the comprehensive microbial carrier 14 proliferate using the organic or inorganic substance as a substrate, and some of the highly active bacteria that proliferate leak out from the comprehensive microbial carrier 14. A part of leaked leak bacteria is attached to the adhesion fixing material 16, and the highly active leak bacteria are propagated on the surface of the adhesion fixing material 16. As a result, the adherent microbial carrier 16 'is formed.

Description

Wastewater treatment method and apparatus {Method and apparatus for treatment of wastewater}

Wastewater treatment method and apparatus of the present invention relates to a wastewater treatment method and apparatus for biologically treating ammonia nitrogen or BOD components in sewage or wastewater for environmental conservation.

Since the sewage treatment plant was started in 1922 at Samhado treatment plant in Tokyo, not only organic matter but also nitrogen treatment was performed at the sewage treatment plant. In particular, intensive investments have been made in large cities, with sewerage rates reaching over 90%. However, the rate of achievement of environmental standards in closed waters has rarely improved. Internal factors in the water, such as algae abnormal breeding, are said to be the most common, but external factors of incoming wastewater have not been resolved. In particular, the external factors of nitrogen were large and the need for treatment is strongly demanded.

Nitrogen is found in sewage or waste water in the form of ammoniacal nitrogen. Conventionally, in a sewage treatment plant or wastewater treatment plant, ammonia nitrogen is oxidized to nitrous acid or nitric acid in order to use nitrifying bacteria, and nitrous acid or nitric acid is converted to nitrogen gas by denitrification bacteria and removed. However, in order to perform stable nitrogen removal due to the slow growth rate, the nitrided bacterium needs to carry out a low load operation in the range of 0.2 to 0.4 kg-N / m 3 / day. The tank must be designed. As a countermeasure against such a problem, a method of incorporating a comprehensive microbial carrier containing nitrifying bacteria in a gel into a biological treatment tank and generally retaining the nitrifying bacteria at a high concentration is widely used (for example, Japanese Patent No. 3389811 or Japanese Patent). 3514360).

By the way, as a method of maintaining the nitrifying bacteria at a high concentration, a method of attaching and fixing microorganisms to an adhesion fixation material in addition to the above-mentioned comprehensive microbial carrier has been performed for a long time. As the adhesion fixing material, an adhesion carrier or an adhesion filler may be used, for example, a plastic carrier, a corrugated plate, a net sheet, and a honeycone shape. By attaching and propagating nitride bacteria to these adhesion carriers or adhesion fillers, bacteria are retained at a high concentration, and high-speed treatment is performed. Not only nitrided bacteria but also organic material decomposition bacteria, such attachment carriers or fillers have been used for high-speed treatment by retaining bacteria at high concentrations.

However, the adhesion support material of the adhesion carrier or the adhesion filler has a long incubation period until microorganisms are attached, and even after the adhesion, the attached bacteria are often separated from the adhesion fixation material. There is also a drawback that the water quality is not stable.

In view of the above situation, the present invention can shorten the period until the microorganism is attached to the adhesion fixing material, and also supplies the active fixation material with the highly active microorganism leaked from the comprehensive microbial carrier to the adhesion fixing material. It is an object of the present invention to provide a wastewater treatment method and apparatus capable of retaining microorganisms at a high concentration and thus obtaining stable and good treated water at all times.

Claim 1 of the present invention is a wastewater treatment method for biologically removing the substrate contained in the wastewater in order to achieve the above object, the wastewater and the comprehensive microorganism carriers in contact with the comprehensive microorganisms incorporating and fixed the microorganism carrier At the same time as the growth of the microorganism of the microorganism of the carrier, the wastewater containing a highly active microorganism leaked from the inside of the carrier of the comprehensive microorganism carrier to the outside of the carrier is brought into contact with the adhesion fixing material, and the leaked microorganism is fixed It is characterized by proliferation attached to.

According to the invention of claim 1, when the inclusive microorganism carrier containing the microorganisms is fixed and contacted with the wastewater, a part of the microorganisms propagated inside the inclusive microorganism carrier is leaked (released) to the outside of the carrier, and It is possible to shorten the incubation period until the microorganism is attached to the attachment fixation material by contacting the attachment fixation material. Also, by supplying microorganisms leaked from the comprehensive microbial carrier to the attachment fixation material at a high concentration to the attachment fixation material. It is based on the fact that it is possible to retain microorganisms. This makes it possible to obtain stable and good treated water at all times.

Examples of microorganisms immobilized on the comprehensive microbial carrier include, for example, a mixed microorganism or a nitride microorganism in which a plurality of microorganisms are mixed, such as an active sludge group, a denitrifying bacterium group, an anaerobic ammonia oxidizing bacterium, and an organic material decomposition bacterium group that decomposes organic matter. Pure strains such as denitrifying bacteria, anaerobic ammonia oxidizing bacteria, algal powder degrading bacteria, PCB degrading bacteria, dioxin degrading bacteria and environmental hormone degrading bacteria can be suitably used.

 The method of claim 1, wherein the substrate is characterized in that the organic and / or inorganic material.

The microorganisms immobilized on the inclusive microbial carrier according to the present invention are, for example, ammonia and nitrite, which are inorganic substances, such as nitrifying bacteria or anaerobic ammonia oxidizing bacteria, and aoko (fresh water tank) or PCB-degrading bacteria. In some cases, organic substrates such as Aoko (freshwater tank) or PCB may be used as a substrate.

The method according to claim 3, wherein the adhesion fixing material is an adhesion carrier and / or an adhesion filler. Thus, as the adhesion fixing material, it is possible to suitably use a granular adhesion carrier that can flow in the wastewater or an adhesion filler filled as a stationary phase in the wastewater.

The ammonia according to any one of claims 1 to 3, wherein the inclusion microorganism carrier which contains and immobilized the nitride bacteria as the microorganism and the wastewater containing ammonia nitrogen as the substrate are brought into contact with each other. It is characterized by setting the nitrogen loading to 100 (mg-N / h / L-carrier) or more.

This is because by carrying out ammonia nitrogen loading of 100 (mg-N / h / L-carrier) or more, it is possible to efficiently leak the nitride bacteria from the comprehensive microcarrier in which the nitride bacteria are contained and fixed.

The method according to any one of claims 1 to 3, wherein the microorganism carrier comprising an organic substance-degrading bacterium which decomposes an organic substance as the microorganism is fixed and contacted with the wastewater containing the BOD component as the substrate. At the same time, the load of the present BOD component is 100 (mg-BOD / h / L-carrier) or more.

This is because it is possible to efficiently leak the organic material decomposition bacteria from the comprehensive microbial carrier in which the organic material decomposition bacteria have been comprehensively fixed by the BOD component load being 100 (mg-BOD / h / L-carrier) or more.

The method according to any one of claims 1 to 5, characterized in that the volume ratio (comprehensive microbial carrier / adhesive fixation material) of the comprehensive microbial carrier is 1/10 or more with respect to the adhesion fixing material. do. This is because it is possible to shorten the culture period in which the attached and fixed microorganisms adhere.

The method according to any one of claims 1 to 5, wherein the volume ratio (comprehensive microbial carrier / adhesive fixation material) of the comprehensive microbial carrier relative to the adhesion fixing material is in the range of 1/10 to 1/5. It is characterized by that. This is because it is possible to effectively shorten the incubation period even in the case of special bacteria that are expensive microorganisms without increasing the cost.

The method according to any one of claims 1 to 7, wherein the comprehensive microcarrier and the adhesion fixing material are mixed in the same biological treatment tank. This makes it possible to treat the wastewater in two places: the inclusion microorganism carrier and the adhesion fixation material can be mixed in the biological treatment tank at the same time, so that the inclusion microorganism carrier and the attachment and fixation material which attach and multiply the microorganisms leaked from the inclusion microcarrier carrier. It is possible to remarkably improve the treatment performance of the biological treatment tank.

The method according to any one of claims 1 to 8, wherein the comprehensive microbial carrier and the adhesion-fixing material is put into a separate biological reaction tank, the comprehensive microbial carrier is introduced into the first biological treatment tank Inflow from the water is introduced into a second biological treatment tank to which the adhesion fixing material is introduced. Thereby, when the 2nd biological treatment tank in which the adhesion fixation material was thrown in starts operation, it can start for a short time. In the case of the normal operation in the second biological treatment tank, the effluent containing the microorganisms leaked from the comprehensive microbial carrier of the first biological treatment tank is introduced into the second biological treatment tank to retain the microorganisms at a high concentration in the attachment fixing material. It is possible to maintain a high treatment performance of the second biological treatment tank.

10. The method according to any one of claims 1 to 9, wherein the proliferating previously encompassing microbial carrier encompasses and immobilizes the microorganisms attached to the adhesion fixing material at a concentration of 10 ⁵ (cells / cm 3) or more. Characterized in that. Since the microorganism concentration in the carrier expresses the activity at 10 ⁶ (cells / cm 3) or more, it proliferates to 10 ⁸ (cells / cm 3) or more in the carrier by immobilization at a concentration of 10 ⁵ (cells / cm 3) or more. This is because the leakage of microorganisms from the comprehensive microbial carrier is promoted.

Claim 11 of the present invention is a wastewater treatment apparatus for biologically removing a substrate contained in wastewater in order to achieve the above object, Comprehensive microbial carriers and microorganisms in which the microorganisms are immobilized in a biological treatment tank for the biological treatment It is characterized in that it is made by mixing the attachment immobilization material for attaching.

As such, the inclusion microorganism carrier and the adhesion fixation material are mixed in the same biological treatment tank, so that the wastewater can be treated in two places: the inclusion microorganism carrier and the attachment fixation material to which the microorganism leaked from the inclusion microorganism carrier is attached. It is possible to remarkably improve the treatment performance of the wastewater treatment apparatus.

The method according to claim 11, characterized in that the biological treatment tank is provided in multiple stages in series. It is thereby possible to remarkably improve the treatment performance of the wastewater treatment apparatus again.

Claim 13 of the present invention in the wastewater treatment apparatus for biologically removing the substrate contained in the wastewater in order to achieve the above object,

The first biological treatment tank into which the comprehensive microbial carrier containing the microorganisms is immobilized at the same time as the waste water flows in, and at least the effluent water of the first biological treatment tank is introduced from the waste water and the effluent from the first biological treatment tank and attached And a second biological treatment tank into which the immobilization material is introduced.

Thereby, when the 2nd biological treatment tank to which the adhesion | attachment fixation material was thrown in starts operation, it can start for a short time. In the case of the normal operation in the second biological treatment tank, the effluent containing the microorganisms leaked from the comprehensive microbial carrier of the first biological treatment tank is introduced into the second biological treatment tank to retain the microorganisms at a high concentration in the attachment fixing material. It is possible to maintain a high treatment performance of the second biological treatment tank.

The method according to claim 13, characterized in that a plurality of stages of a biological treatment tank comprising the first biological treatment tank and the second biological treatment tank are provided. It is thereby possible to improve the treatment performance of the wastewater treatment apparatus.

According to the wastewater treatment method and apparatus of the present invention, it is possible to shorten the culturing period until the microorganisms are attached to the adhesion fixation material, and also by supplying microorganisms leaked from the comprehensive microbial carrier to the attachment fixation material. It is possible to retain microorganisms at high concentrations, which makes it possible to obtain stable and good treated water at all times.

1 is a diagram illustrating the leak rate of nitride bacteria leaking from a comprehensive microbial carrier.
FIG. 2 is a diagram illustrating the leak rate of organic degradation bacteria leaking from a comprehensive microbial carrier.
FIG. 3 is a diagram showing a culture period in nitriding treatment when the volume ratio of the comprehensive microbial carrier and the adhesion fixation material is changed.
Fig. 4 is a diagram showing the incubation period in the BOD treatment when changing the volume ratio of the comprehensive microbial carrier and the adhesion fixation material.
FIG. 5 is a view showing one biological treatment tank as one embodiment of the wastewater treatment apparatus of the present invention.
6 is a view showing that the biological treatment tank is designed in multiple stages as another embodiment of the wastewater treatment apparatus of the present invention.
7 is a view showing that the wastewater treatment apparatus of the present invention is configured to fill a comprehensive microbial carrier in a first tank installed in multiple stages, and to attach an attachment carrier to a second tank and a third tank.
8 is a view showing that another embodiment of the wastewater treatment apparatus of the present invention is configured to fill the microorganism carrier and the adhesion fixing material with each other in each tank of the biological treatment tank installed in multiple stages.
9 is a view showing that the wastewater treatment apparatus of the present invention is configured to install a biological treatment tank and a useful bacterial culture tank.
FIG. 10 is a view showing that the wastewater treatment apparatus of the present invention is configured as a suitable apparatus for wastewater containing a BOD component and ammonia.
11 is a view showing that the wastewater treatment apparatus of the present invention is configured as an apparatus suitable for wastewater containing no ammonia and containing a BOD component.
12 is a view showing that the wastewater treatment apparatus of the present invention is configured as an apparatus suitable for wastewater containing only BOD components.
FIG. 13 is a view showing that the wastewater treatment apparatus of the present invention is configured as an apparatus suitable for wastewater containing a BOD component and ammonia.

EMBODIMENT OF THE INVENTION Hereinafter, with reference to an accompanying drawing, preferable embodiment is described about the wastewater treatment method and apparatus which concern on this invention.

According to the present invention, when a comprehensive microbial carrier containing microorganisms is immobilized on the wastewater, a part of the microorganisms propagated inside the comprehensive microbial carrier is leaked (released) to the outside of the carrier, and the wastewater containing the leaked microorganism is brought into contact with the attachment fixing material. Based on the fact that it is possible to shorten the culture period until the microorganisms adhere to the adhesion fixing material, and also to obtain a carrier or filler in the form of adhesion fixation, in which the attached microorganisms are difficult to detach from the adhesion fixing material. It is complete.

In the present invention, the microorganism immobilized on the comprehensive microbial carrier may be a complex microorganism such as pure strain or activated sludge. Examples of the composite microorganisms include activated sludge, nitrifying bacteria group, denitrifying bacteria group and anaerobic ammonia oxidizing bacteria group. As pure strains, for example, nitrifying bacteria, denitrifying bacteria, anaerobic ammonia bacteria, aoko (freshwater bath) bacteria, PCB bacteria, dioxins bacteria, environmental hormone bacteria and the like. The concentration of the total microbial count of the microorganisms immobilized on the comprehensive microbial carrier is preferably 10 ⁵ (cells / cm 3) or more. This is because the activity of the microorganism in the carrier is expressed at 10 ⁶ (cells / cm 3) or more. Therefore, the growth rate is increased to 10 ⁸ (cells / cm 3) or more inside the carrier rather than immobilized at a concentration of 10 ⁵ (cells / cm 3) or more. This is because the leakage of microorganisms from the comprehensive microbial carrier is promoted. Therefore, it is a principle to comprehensively fix microorganisms to be attached to a carrier or filler in the form of adhesion fixation.

The inclusive microbial carrier used refers to a carrier obtained by incorporating a monomer material or a prepolymer material with a microorganism and polymerizing the mixed solution to comprehensively fix the microorganism. As the monomer material, it is possible to suitably use acrylamide, methylenebisacrylamide, triacryl formal, and the like. As a prepolymer material, polyethyleneglycol diacrylate or polystyrene glycol methacrylate is good, and its derivative can also be used. It is possible to use a cubic (cubic), spherical, ordinary, string, nonwoven, or the like form of a comprehensive microbial carrier appropriately, and in particular, the surface of the carrier having a large unevenness has good contact efficiency with wastewater and is further improved. desirable. If it is a cube or spherical comprehensive microbial carrier, the range of 1-10 mm is preferable as a diameter corresponding to a sphere.

On the other hand, as the adhesion fixing material in contact with the wastewater containing the microorganisms leaked from the comprehensive microbial carrier, it is possible to suitably use an adherent filler filled as a fixed phase in the wastewater or a granular adhesion carrier that can flow in the wastewater. As the material of the adhesion carrier or the adhesion filler, for example, a plastic carrier, a wave plate, a reticulated sheet, or a honeycomb-like thing can be suitably used. The adhesion carrier may be spherical, cylindrical, macaroni or the like, and it is possible to facilitate the attachment of microorganisms by forming irregularities on the foamed surface. The initial state of the adhesion carrier or adhesion filler is an inanimate carrier or filler without microorganisms attached thereto, forming irregularities on the surface to increase the specific surface area to facilitate adhesion of the microorganisms, as well as contact with the attached microorganisms and wastewater. Efficiency is also made good. For example, it is also a good idea to use the same specific surface area as the above-mentioned comprehensive microbial carrier.

Next, the leak test result which carried out by the nitride cell and organic substance decomposition bacteria as an example of the microorganism leaked from the comprehensive microorganism carrier is demonstrated.

The leak rate of nitride bacteria leaking from the inclusion microbial carrier when the inclusion microbial carrier having the composition shown in Table 1 was made and the ammonia nitrogen load on the inclusion microbial carrier was changed was investigated. In the same manner, the leak rate of the organic biodegradable bacteria leaked from the comprehensive microbial carrier when the BOD load was changed to the comprehensive microbial carrier was investigated. Nitriding bacteria immobilized on the comprehensive microbial carrier was used as a concentrated solution of ammonia oxidizing bacteria that nitrate ammonia with nitrite.

Furtherance Weight portion a b c d e Ammonia Oxidizing Bacteria Concentrate (10 ⁹ cells / cm 3) 30 30 30 30 30 Polyethylene Glycol Diacrylate 4 6 8 10 15 NNN'N'tetramethylethylenediamine 0.5 0.5 0.5 0.5 0.5 Potassium persulfate 0.25 0.25 0.25 0.25 0.25 water 65.25 63.25 61.25 59.25 54.25

In addition, when the ammonia nitrogen load of the comprehensive microbial carrier having the composition shown in Table 1 was increased from 50 to 600 (mg-N / h / L-carrier), the leak rate of the nitride bacteria leaked from the comprehensive microbial carrier was measured. Is shown in FIG.

1 represents the ammonia nitrogen load (mg-N / h / L-carrier) and the vertical axis represents the number of leaked nitride bacteria per inclusive microbial carrier (cm 3), that is, the leak rate of the nitride bacteria do. As can be seen from Fig. 1, when the ammonia nitrogen load is 50, the leak rate is slow to 1.00 × 10 ⁴ (cells / cm 3 / day), but as the ammonia nitrogen load is increased, the leak rate is increased and the ammonia nitrogen load is increased. The leak rate reaches a maximum near 300 to 400 (mg-N / h / L-carrier). The leak rate at this time is 1.00 × 10 ⁸ (cells / cm 3 / day). In this way, in the case of the leak of bacterial nitride, it is possible to increase the leak rate by increasing the load of ammonia nitrogen, which is a substrate of the nitride bacteria. In this case, in order to efficiently attach the nitrided bacteria leaked from the comprehensive microbial carrier to the adhesion fixation material, the leak rate is preferably 1.00 × 10 ⁶ (cells / cm 3 / day) or higher. N / h / L-carrier) or higher, preferably 300 (mg-N / h / L-carrier) or higher.

In addition, the leakage of organic biodegrading bacteria leaking from the comprehensive microbial carrier when the BOD load on the comprehensive microbial carrier is increased from 50 (mg-N / h / L-carrier) to 600 (mg-N / h / L-carrier). The result of measuring the speed is shown in FIG.

2 represents the BOD load (mg-N / h / L-carrier) and the vertical axis represents the number of leaked organic hydrolysis bacteria per inclusive microbial carrier (cm 3), that is, the leak rate of the organic decomposition bacteria. do. As can be seen from Fig. 2, when the BOD load is 50 (mg-N / h / L-carrier), the leak rate is slow in the range of 1.00 × 10 ⁵ to 10 ⁶ (cells / cm 3 / day), but the BOD load is increased. As a result, the leak rate increases and the leak rate reaches a maximum at a BOD load of around 300 to 400 (mg-N / h / L-carrier). The leak rate at this time is 1.00 × 10 ¹⁰ (cells / cm 3 / day). In this way, in the case of the leakage of organic decomposition bacteria that decomposes organic substances, it is possible to increase the leak rate by increasing the load of the BOD component which is a substrate of the organic decomposition bacteria. In this case, in order to efficiently attach the organic biodegradable bacteria leaked from the comprehensive microbial carrier to the attachment fixing material, the leak rate is preferably 1.00 × 10 ⁸ (cells / cm 3 / day) or more, and the BOD load is 100 (mg-N) for this purpose. / h / L-carrier) or higher, preferably 300 (mg-N / h / L-carrier) or higher.

In this leak test, when the concentration of polyethyleneglycol diacrylate, which is an immobilization material in the case of producing a comprehensive microbial carrier, was lowered, it was considered easy to leak bacteria, and as shown in Table 1, the concentration of polyethyleneglycol diacrylate was shown. Was changed in 5 steps of 4, 6, 8, 10, 15 (parts by weight). However, as can be seen from Figs. 1 and 2, the leak rate was almost similar in the range of 4 to 15 parts by weight. From this, it can be seen that the leak rate is greatly affected by the substrate load of the bacteria to be leaked.

3 and 4 show that when the bacteria leaked from the comprehensive microbial carrier are attached to the attachment fixation material, the culture period of the attachment fixation material is shortened when the volume ratio of the inclusion microbial carrier and the attachment fixation material has some relation. Test is performed by varying the load.

Fig. 3 is a culturing period when the start-up operation of the adhesion fixation material is carried out while the wastewater from which the nitrifying bacteria are leaked from the comprehensive microbial carrier is brought into contact with the adhesion fixation material. Fig. 4 is a culture period when the BOD treatment start-up operation of the adherent immobilization material is carried out while contacting the adherent material with the wastewater that has leaked the organic decomposition bacteria from the comprehensive microbial carrier. In this experiment, the wastewater treatment apparatus 10 shown in FIG. 5 is used, and both the carrier microorganism carrier 14 and the adhesion fixing material 16 are mixed in the biological treatment tank 12 so that the carrier volume ratio and the incubation period of both The relationship with

In Fig. 3, the incubation period is the number of days until the nitrogen removal rate or BOD removal rate of the treated water reaches 90%. Further, the load in the nitriding treatment was four of 0.1, 0.3, 0.5, 1.0 (kg-N / m 3 / day), and the load in the BOD treatment was 0.1, 0.3, 0.5, 0.8 (kg-N / m 3 / day). Four). 3 and 4, the total filling rate of the comprehensive microbial carrier and the adhesion fixing material was performed at 10%.

As a result, as can be seen from Figs. 3 and 4, when the incubation period is different depending on the load, when the total volume of the adhesion-fixing material is A and the total volume of the inclusion-microbial carrier is B, the comprehensive micro-carrier for the adhesion-fixing material It is possible to significantly shorten the incubation period by setting the volume ratio (A / B) to 0.1 (1/10) or more, more preferably 0.2 (1/5) or more. This suggests that if the amount of inclusion microbial carriers is too small in the relationship between the cell concentration leaked from the inclusion microbial carrier and the volume of the attachment fixation material, the amount of the leakage microbial carrier is too small and cannot provide the amount of cells required for the activation of the attachment fixation material. It is done. However, in the case of special microorganisms in which the microorganism is expensive, the comprehensive microbial carrier becomes expensive, so that the amount of the comprehensive microbial carrier introduced into the biological treatment tank is reduced as little as possible. In this case, therefore, the inflection point in Figs. 3 and 4, that is, the volume ratio (A / B) of the inclusion microorganism carrier to the fixation material is in the range of 0.1 (1/10) to 0.2 (1/5). It is desirable to. This makes it possible to shorten the cultivation period even in the case of special bacteria that are expensive microorganisms without increasing the cost.

5 to 13 show various forms in the wastewater treatment apparatus of the present invention, and the immobilization material will be described as an example of the particulate support carrier that can flow in the wastewater. In addition, the microorganism is described as a bacterium at the same time that the microorganism is attached to the surface of the attachment carrier is called an attachment microbial carrier.

The wastewater treatment apparatus 10 of FIG. 5 is a case in which a plurality of comprehensive microbial carriers 14 and a plurality of attachment carriers 16 coexist in the same biological treatment tank 12. It is introduced into the biological treatment tank 12 through (18). The biological treatment tank 12 is filled with a comprehensive microbial carrier 14 and an attachment carrier 16. As a result, bacteria inside the comprehensive microbial carrier 14 are propagated using organic or inorganic substances as a substrate, and a part of the multiplied bacteria is leaked from the comprehensive microbial carrier 14. A part of the leaked bacteria is adhered to the adhesion fixing material 16 and the bacteria are grown on the surface of the adhesion fixing material 16. As a result, the adherent microbial carrier 16 'is formed. Therefore, in the biological treatment tank 12, wastewater containing organic or inorganic substances is biologically purified by the comprehensive microbial carrier 14 in which the bacteria are fixed and the attached microbial carrier 16 'on which the bacteria are proliferated on the surface. . Thus, by allowing the comprehensive microbial carrier 14 and the attachment carrier 16 to coexist in the biological treatment tank 12 at the same time, it is possible to attach the leaked bacteria from the comprehensive microbial carrier 14 to the attachment carrier 16. Therefore, it is possible to retain useful bacteria useful in the treatment of the biological treatment tank 12 into the biological treatment tank 12 at a high concentration, as compared with the case where only the comprehensive microbial carrier 14 is filled in the biological treatment tank 12. Therefore, it is possible to improve the biological treatment performance of the biological treatment tank 12. Leaked bacteria have high activity, and the adherent microbial carrier 16 'to which these bacteria are attached tends to be higher than the comprehensive microbial carrier 14.

The treated water purified by the biological treatment tank 12 is separated into a comprehensive microbial carrier 14 and an attached microbial carrier 16 ′ in a carrier separation means, for example, the screen 20, and flows out into the outlet pipe 22. Although not shown in FIG. 5, in the case of an aerobic reaction, an aerated air is supplied to the biotreatment tank 12 to supply oxygen, and in the case of the anaerobic reaction, the agitator for flowing the comprehensive microbial carrier 14 and the attached microbial carrier 16 ′ or Stirring by blowing anaerobic gas is necessary, and the same is true in FIGS. 6, 7, 8, and 9.

According to the wastewater treatment apparatus 30 of FIG. 6, wastewater containing organic or inorganic substances flows into the biological treatment tank 12 through the raw water introduction pipe 18. The biological treatment tank 12 is composed of a first biological treatment tank 12A, a second biological treatment tank 12B, and a third biological treatment tank 12C. Thus, the first microbial treatment tank 12A to the third biological treatment tank 12C are put in order for the comprehensive microbial carrier 14 and the adhesion carrier 16 to coexist, and each of the biological treatment tanks 12A to 12C. In the case of the organic or inorganic substance as a substrate, bacteria inside the comprehensive microbial carrier 14 proliferate and some of the multiplied bacteria are leaked from the comprehensive microbial carrier 14. A part of the leaked bacteria is adhered to the adhesion fixing material 16 and the bacteria are grown on the surface of the adhesion fixing material 16. Accordingly, when the comprehensive microbial carrier 14 and the attachment carrier 16 coexist in the whole biological treatment tanks 12A to 12C designed in multiple stages, the leak from the comprehensive microbial carrier 14 of the first biological treatment tank 12A. Part of the leaked bacteria is not attached to the attachment carrier 16 and flows to the second or third biotreatment tanks 12B and 12C on the downstream side and part of the leaked bacteria to the second biotreatment tank 12B. It is preferable that the amount of filling of the adherent carrier 16 is increased in the degree of the biological treatment tank on the downstream side rather than the upstream side by flowing into the third biological treatment tank 12C. Thus, by installing the biological treatment tank 12 in multiple stages, it is possible to efficiently remove wastewater containing high concentrations of organic or inorganic substances.

The wastewater treatment apparatus 40 of the present invention of FIG. 7 is another embodiment, and the multi-stage design of the biological treatment tank 12 is the same as that of FIG. 6, but the comprehensive microbial carrier 14 is placed in the first biological treatment tank 12A. After filling, the attachment carrier 16 is filled in the second and third biological treatment tanks 12B and 12C.

According to the wastewater treatment apparatus 40 shown in FIG. 7, wastewater containing organic or inorganic substances flows into the biological treatment tank 12 through the raw water introduction pipe 18. The biological treatment tank 12 is comprised from the 1st biological treatment tank 12A, the 2nd biological treatment tank 12B, and the 3rd biological treatment tank 12C. In addition, the comprehensive microbial carrier 14 is filled in the first biological treatment tank 12A, and the attachment carrier 16 is filled in the second biological treatment tank 12B and the third biological treatment tank 12C. As a result, bacteria inside the comprehensive microbial carrier 14 are propagated in the first biological treatment tank 12A using organic or inorganic substances as substrates, and some of the multiplied bacteria are leaked from the comprehensive microbial carrier 14. A part of organic or inorganic matter in the wastewater of the first biological treatment tank 12A is removed, and the treated water and the leaked bacteria are introduced into the second biological treatment tank 12B. A part of the leak bacteria which flowed into the 2nd biological treatment tank 12B adheres to the attachment carrier 16, and a bacterium multiplies on the surface of the attachment carrier 16. As shown in FIG. In addition, part of the leak bacteria is also attached to the attachment carrier 16 of the third biological treatment tank 12C. The adherent bacteria grow on the surface of the adhesion carrier 16. Therefore, in each of the biological treatment tanks 12A to 12C, wastewater containing organic or inorganic substances is biologically purified by the comprehensive microbial carrier 14 or the attached microbial carrier 16 having bacteria adhered to the surface. The purified treatment water is separated from the comprehensive microbial carrier 14 or the attached microbial carrier 16 'on the carrier separation means, for example, the screen 20, and is discharged to the outlet pipe 22.

The wastewater treatment apparatus 50 of FIG. 8 is a modification of FIG. 7, and is configured such that the comprehensive microbial carrier 14 and the attachment carrier 16 are filled with each other in the biological treatment tanks 12A to 12D designed in multiple stages. In order to do this, as shown in Fig. 7, the concentration of the leak bacteria is not lowered up to the biological treatment tank on the downstream side, so that the leak bacteria can be attached to the attachment carrier 16 more efficiently.

The wastewater treatment apparatus 60 of FIG. 9 is another embodiment, and wastewater containing organic or inorganic substances is introduced into the biological treatment tank 12 and the useful bacterial culture tank 24 through branched raw water pipes 18. The biological treatment tank 12 is filled with an attachment carrier 16, and the useful bacteria culture tank 24 is filled with a comprehensive microbial carrier 14. As a result, in the useful bacterial culture tank 24, the bacteria inside the comprehensive microbial carrier 14 proliferate with the organic or inorganic substance as a substrate, and a part of the multiplied bacteria is leaked from the comprehensive microbial carrier 14. The leaked leak bacteria are introduced into the biological treatment tank 12 and attached to the attachment carrier 16, and the leak bacteria are propagated on the surface of the attachment carrier 16. As a result, the wastewater containing organic or inorganic substances is biologically purified in the biological treatment tank 12 by the adherent microbial carrier 16 'on which the bacteria are proliferated. The purified treatment water is separated by a carrier separating means, for example, the screen 20, and is discharged to the outlet pipe 22. By introducing a part of the wastewater into the biological treatment tank 12 through the useful bacterial culture tank 24, it is possible to shorten the culture period (starting period) of the biological treatment tank 12 filled with the attachment carrier 16. It is possible to stabilize the processing performance in the biological treatment tank 12 to which the leaked bacteria are supplied even after being activated at the same time.

In another aspect, the wastewater treatment apparatus 70 of FIG. 10 is an example that is particularly suitable for wastewater treatment containing BOD components such as sewage and Aoko (fresh water tank).

As shown in FIG. 10, the wastewater treatment device 70 flows into the biological treatment tank 12 through the raw water introduction pipe 18, where the wastewater containing organic matter and ammonia nitrogen. The biological treatment tank 12 is composed of an anaerobic tank 26 disposed on the front end side and an aerobic tank 28 disposed on the rear end side, and the aerobic tank 28 includes a comprehensive microbial carrier 14 and an attachment carrier (including the fixed nitrifying bacteria). 16) is filled. Moreover, the aeration pipe | tube 28 is provided with the aeration pipe 31 which aerators an air, and the aeration pipe 31 is connected to the blower 32. As shown in FIG. As a result, the nitrifying bacteria inside the comprehensive microbial carrier 14 having ammonia nitrogen as a substrate are propagated in the aerobic tank 28, and a part of the expanded microbial bacteria is leaked from the comprehensive microbial carrier 14. A part of the leaked leak bacteria is attached to the adhesion carrier 16, and the microflora propagates on the surface of the adhesion carrier 16. In the aerobic tank 28, ammonia nitrogen is nitrified by the inclusion microbial carrier 14 and the adherent microbial carrier 16 'on which the nitride bacteria leaked on the surface are proliferated to produce nitrous acid or nitric acid. The nitrided nitride liquid is circulated to the anaerobic tank 26 through the nitride liquid circulation line 34. The anaerobic tank 26 is subjected to denitrification which converts nitrous acid or nitric acid into nitrogen gas by denitrification bacteria in floating activated sludge as the nitriding liquid as organic matter or hydrogen donor in wastewater. As a result, the ammonia nitrogen or organic matter in the waste water is removed and purified. At the same time, the purified microorganism carrier 14 or the attached microbial carrier 16 'is separated from the carrier separation means, for example, the screen 20. It is sent to the solid-liquid separation tank 36. In the solid-liquid separation tank 36, the suspended active sludge accompanying the treated water is solid-liquid separated and the supernatant water flows out into the outflow pipe 22. The suspended active sludge settled at the bottom of the solid-liquid separation tank 36 is returned to the anaerobic tank 26 through the sludge conveying pipe 38. In addition, reference numeral 41 denotes a stirrer for stirring the inside of the anaerobic tank 26.

The wastewater treatment apparatus 80 of FIG. 11 is an example suitable for ammonia containing wastewater treatment which does not contain the BOD component in another aspect.

As shown in FIG. 11, the wastewater treatment apparatus 80 flows into the biological treatment tank 12 through the raw water introduction pipe 18. Wastewater containing ammonia nitrogen is introduced. The biological treatment tank 12 is composed of an aerobic tank 28 disposed on the front side and an anaerobic tank 26 disposed on the rear end side, and the aerobic tank 28 is filled with a comprehensive microbial carrier 14 and an attachment carrier 16. . In addition, an aeration pipe 28 is provided with an aeration pipe 31 for aeration of air, and the aeration pipe 31 is connected to the blower 32. As a result, the nitrifying bacteria inside the comprehensive microbial carrier 14 are propagated in the aerobic tank 28 using ammonia nitrogen as a substrate, and a part of the nitrided microorganisms are leaked from the comprehensive microbial carrier 14. A part of the leaked nitride bacteria is attached to the attachment carrier 16 and the nitride bacteria grow on the surface of the attachment carrier 16. As described above, the aerobic tank 28 is nitrified with ammonia nitrogen by the comprehensive microbial carrier 14 and the adherent microbial carrier 16 'on which the nitride microorganisms are proliferated to generate nitrous acid or nitric acid. This nitriding liquid enters the anaerobic tank 26 at the rear stage and is denitrated by denitrification bacteria in suspended active sludge using methanol supplied from the methanol supply line 38 as a hydrogen donor. As a result, the ammonia nitrogen in the waste water is removed and purified, and the purified water is sent to the solid-liquid separation tank 36. In the solid-liquid separation tank 36, the floating activated sludge accompanying the treated water is separated into solid-liquid and the supernatant water flows out into the outflow pipe 22. The suspended active sludge settled at the bottom of the solid-liquid separation tank 36 is conveyed to the aerobic tank 28 through the sludge conveying pipe 38. In addition, the code | symbol 41 is a stirrer which stirs the inside of the anaerobic tank 26. FIG.

The wastewater treatment apparatus 90 of FIG. 12 is an example suitable for BOD-containing wastewater treatment containing only BOD components in another embodiment.

As shown in FIG. 12, the wastewater treatment apparatus 90 flows into the biological treatment tank 12 through the raw water introduction pipe 18. The biological treatment tank 12 is composed of an aerobic tank 28 disposed on the front end side and an aerobic tank 40 arranged on the rear end side, and the comprehensive microbial carrier 14 and the attachment carrier 16 are disposed in the aerobic tank 28 on the front end side. It is filled. In addition, the aerobic tank 40 on the rear end side holds floating activated sludge. As a result, in the aerobic tank 28 on the front end side, the BOD component is used as a substrate, and the organic biodegrading bacteria inside the comprehensive microbial carrier 14 are propagated, and some of the expanded organic biodegrading bacteria are leaked from the comprehensive microbial carrier 14. A part of the leaked organic decomposition bacteria is attached to the attachment carrier 16 and the organic decomposition bacteria grow on the surface of the adhesion carrier 16. Therefore, the organic matter is decomposed by the comprehensive microbial carrier 14 and the attached microbial carrier 16 'in which the organic biodegradable bacteria are proliferated on the surface of the aerobic tank 28 on the front side. A part of the organic decomposition bacteria leaked from the comprehensive microbial carrier 14 flows into the aerobic tank 40 on the rear end side and is attached to the suspended active sludge and propagated. Wastewater is highly purified by this multiplying suspended sludge. The purified treatment water is sent to the solid-liquid separation tank 36. In the solid-liquid separation tank 36, the suspended active sludge accompanying the treated water is separated into solid-liquid and the supernatant water flows out into the outflow pipe 22. The suspended active sludge settled at the bottom of the solid-liquid separation tank 36 is conveyed to the aeration tank 40 on the rear end side through the sludge conveying pipe 38.

The wastewater treatment apparatus 100 of FIG. 13 is an example suitable for treating wastewater containing a BOD component and ammonia nitrogen in another aspect.

As shown in Fig. 13, the wastewater treatment apparatus 100 includes an anaerobic tank 42, a nitrous acid production tank 44, an anaerobic ammonia oxidation tank 48, a nitriding tank 51, and a solid-liquid separation tank 36 from an upstream side. To be deployed. The oxygen-free tank 42 is filled with a comprehensive microbial carrier 14A and an attachment carrier 16 that are comprehensively fixed with denitrifying bacteria. The nitrous acid production tank 44 is filled with a comprehensive microbial carrier 14B and an attachment carrier 16 in which ammonia oxidizing bacteria are comprehensively fixed. The anaerobic ammonia oxidizing tank 48 is filled with a comprehensive microbial carrier 14C and an attachment carrier 16 in which the anaerobic ammonia oxidizing bacteria are comprehensively fixed.

According to the wastewater treatment apparatus 100 of the present invention configured as described above, the wastewater containing the BOD component and ammonia nitrogen is introduced into the oxygen-free tank 42 through the raw water introduction pipe 18. The oxygen-free tank 42 removes the BOD component by respiration by nitric acid or nitrous acid in the nitriding liquid circulated from the nitriding liquid purifying line 34. In the anoxic tank 42, a part of the first effluent containing the remaining ammonia nitrogen in the waste water and the remaining ammonia nitrogen flows into the nitrous acid production tank 44, and the remainder is anaerobic ammonia oxidation through the bypass line 46. It flows into the tank 48. The nitrous acid production tank 44 is subjected to nitrous acid-nitriding treatment so that ammonia nitrogen is oxidized to nitrous acid nitrogen. Thus, the second effluent containing nitrous nitrogen from the nitrous acid production tank 44 and the third effluent containing ammonia nitrogen from the bypass line 46 are introduced into the anaerobic ammonia oxidation tank 48 and the ammonia nitrogen and Nitrous acid nitrogen is simultaneously denitrified. The fourth effluent containing the ammonia nitrogen remaining in the anaerobic ammonia oxidation tank 48 flows into the nitriding tank 51 to be nitrided and the remaining ammonia nitrogen is nitrided. A part of the nitride liquid flowing out of the nitriding tank 51 returns to the anoxic tank 42 through the nitriding liquid circulation line 34. The treated water which is the remainder of the nitriding liquid treated in the nitriding tank 51 is fed to the solid-liquid separation tank 36. The suspended active sludge accompanying the treated water is separated into solid and the supernatant is discharged to the outlet pipe 22.

In the treatment in all the tanks concerned, denitrification bacteria inside the comprehensive microbial carrier 14A are propagated in the anoxic tank 42 using nitrous acid or nitric acid as a substrate, and the proliferative denitrification bacteria are leaked and attached to the attachment carrier 16. . In the nitrous acid production tank 44, ammonia oxidizing bacteria inside the comprehensive microbial carrier 14B are propagated using ammonia nitrogen as a substrate, and the expanded ammonia oxidizing bacteria are leaked to attach to the attachment carrier 16. The anaerobic ammonia oxidizing tank (48) proliferates the anaerobic ammonia oxidizing bacteria inside the comprehensive microbial carrier (14C) using ammonia nitrogen and nitrite nitrogen as substrates, and the anaerobic ammonia oxidizing bacteria which are expanded are leaked to the attachment carrier (16). Proliferation. The leaked bacteria from the microbial carrier 14A or 14B or 14C by coexisting the inclusive carrier microorganism carrier 14A or 14B or 14C containing the bacteria useful for the treatment in each tank and the attachment carrier 16. By increasing the adhesion to the attachment carrier 16, it is possible to significantly shorten the incubation period and to improve the stability of the treatment in the normal operation period. This is because the microbial carrier 16 'attached with bacteria to the attachment carrier 16 is found to be peeled off and the degradation of the biofilm and the performance of the attached microbial carrier 16' is likely to occur. It is thought that the recovery of the adherent microbial carrier 16 'is fast because the seed is always supplied from 14).

Example

Examples of the present invention are described below, but are not limited to these examples.

Example 1

In the test of Example 1, the incubation period and the water quality of the treated water were investigated in each wastewater treatment apparatus of FIGS. 5 to 9 using synthetic wastewater containing 50 mg / L ammonia nitrogen. The composition of the comprehensive microbial carrier 14 used in the test is shown in Table 2.

Furtherance Weight portion Activated sludge 4% 50 Polyethylene Glycol Diacrylate 10 NNN'N'tetramethylethylenediamine 0.5 Potassium persulfate 0.25 water 39.25

As shown in Table 2, the composition was gelated by adding potassium persulfate to form a gelled product into a 3 mm square, which was used as a comprehensive microbial carrier 14 for the test.

Each test condition is as follows.

(Invention A) In the case of using the wastewater treatment apparatus 10 of FIG.

-Residence time of the biological treatment tank 12: 2.4 hours

Volume load in biological treatment tank 12: 0.5 kg-N / m 3 / day

Filling rate of the comprehensive microbial carrier 14 in the biological treatment tank 12: 2%

Filling rate of the support carrier 16 to the biological treatment tank 12: 8%

Cylindrical carrier (5mm ø8mm) made of foamed polyethylene is used as attachment carrier

-Aerobic aeration of biological treatment tank 12

(Invention B) In the case of using the wastewater treatment apparatus 30 of FIG.

Total residence time of group -3 (12A, 12B, 12C): 2.4 hours

Volume load of -3 sets (12A, 12B, 12C) total: 0.5㎏-N / ㎥ / day

-Filling rate of comprehensive microcarrier 14 in each tank (12A, 12B, 12C): 1% (volume)

-Filling rate of attachment carrier 16 in each tank 12A, 12B, 12C: 9% (volume)

Cylindrical carrier (5mm ø8mm) made of foamed polyethylene is used as attachment carrier

-Aeration aeration of each bath (12A, 12B, 12C)

(Invention C) In the case of using the wastewater treatment apparatus 40 of FIG.

Total residence time of group -3 (12A, 12B, 12C): 2.4 hours

Volume load of -3 sets (12A, 12B, 12C) total: 0.5㎏-N / ㎥ / day

Filling rate of the comprehensive microbial carrier 14 of the first biological treatment tank 12A: 10% (volume)

Filling rate of the comprehensive microbial carrier 16 in the second and third biological treatment tanks 12B and 12C: 10% (volume)

Cylindrical carrier (5mm ø8mm) made of foamed polyethylene is used as attachment carrier

-Aeration aeration of each bath (12A, 12B, 12C)

(Invention D) In the case of using the wastewater treatment apparatus 50 of FIG.

Total residence time of Group 4 (12A, 12B, 12C, 12D): 2.4 hours

Volume load of total 4 sets (12A, 12B, 12C, 12D): 0.5㎏-N / ㎥ / day

Filling rate of the comprehensive microbial carrier 14 in the first and third biological treatment tanks 12A and 12C: 10% (volume)

Filling rate of the comprehensive microbial carrier 16 in the second and fourth biological treatment tanks 12B and 12D: 10% (volume)

Cylindrical carrier (5mm ø8mm) made of foamed polyethylene is used as attachment carrier

-Aeration aeration of each bath (12A, 12B, 12C, 12D)

(Invention E) In the case of using the wastewater treatment apparatus 60 of FIG.

-Total residence time of the biological treatment tank 12 and the useful bacterial culture tank 24: 2.4 hours (biotreatment tank: 2 hours, useful bacterial culture tank: 0.4 hours)

-Total volume load of the biological treatment tank 12 and the useful bacteria culture tank 24: 0.5㎏-N / ㎥ / day

Filling rate of the comprehensive microbial carrier 14 into the lysogenic bacteria culture tank 24: 20% (volume)

Filling rate of the support carrier 16 to the biological treatment tank 12: 10% (volume)

Cylindrical carrier (5mm ø8mm) made of foamed polyethylene is used as attachment carrier

-Aerobic aeration of the biological treatment tank 12 and the useful bacteria culture tank 24

The wastewater treatment system was operated under the test conditions of the present inventions A to E above. Then, it was determined that the culture was terminated when the ammonia nitrogen concentration of the treated water became 2 mg / L or less, and the period was regarded as the culture period. The results are shown in Table 3. In addition, Table 3 shows the results of the tests for the conventional methods. In the conventional method, in the device reference numerals of FIGS. 5, 6, and 7, the comprehensive microbial carrier 14 is replaced with the attachment carrier 16 so that the biological support tank is filled with the entire attachment carrier 16. That is, the attachment carrier 16 was filled at the same filling rate instead of the comprehensive microbial carrier 14. At the start of the experiment of the conventional method, sludge was added.

Test series Device Drawing Number Incubation period Water quality of treated water NH4-N (mg / L) Invention A 5 12th 0.5-1.2 Invention B Figure 6 24th 0.4-0.9 Invention C 7 14 days 0.4-1.0 Inventive D Figure 8 11th 0.5-1.0 Inventive E 9 24th 0.6-1.2 Conventional Method A (Figure 5) 45 days 0.5-13.3 Conventional Method B (Figure 6) 30 days 0.5-5.2 Conventional Method C (Figure 7) 30 days 0.5-9.4 Conventional Method D (Figure 8) 35 days 0.5-7.6 Conventional Method E (Fig. 9) 95 days 1.5-8.2

As can be seen from Table 3, the conventional methods A to E have often been found to have a long incubation period of 30 to 95 days and a tendency of deteriorating the water quality of the treated water even after incubation. This is presumed that bacteria are easily peeled off from the adhesion carrier 16, thereby deteriorating the treated water.

In contrast, the present inventions A to E have a culture period of 12 to 24 days, which is shorter than that of the conventional method, and the water quality after the culture is extremely stable. In particular, the biological treatment tank (12A to 12D) installed in the multi-stage of the present invention D was configured so that the inclusion microorganism carrier 14 and the attachment carrier 16 is filled with each other, the shortest period of culture 11 days. As described above, in the case of the present invention, bacteria are always supplied to the attachment carrier 16 by leaking bacteria from the comprehensive microbial carrier 14, so that the biofilm can be stably formed on the surface of the attachment carrier. This makes it possible to maintain the water quality of the treated water satisfactorily and stably. In addition, as a conventional method, the incubation period of 14 days was required when only 10% of the microorganism carrier 14 was filled in the apparatus of FIG. 5. On the other hand, in the present invention, it was shortened to 12 days, and the reason for this is thought to be that the culture period was shortened due to the high activity of the leaked bacteria attached to the attachment carrier 16.

Example 2

In the test of Example 2, the culture period and the water quality of the treated water were examined in each wastewater treatment apparatus of FIGS. 10 to 13 using various wastewaters. The composition of the comprehensive microbial carrier 14 used for the test is shown in Table 4.

Furtherance Weight portion Activated sludge 4% 50 Polyethylene Glycol Diacrylate 4 Acrylamide One NNN'N'tetramethylethylenediamine 0.5 Potassium persulfate 0.25 water 44.25

The composition was gelated by adding potassium persulfate as shown in Table 4, and the gelled product was molded into a 3 mm square to be used as a comprehensive microbial carrier 14 for the test.

Each test condition is as follows.

(Invention F) In the case of using the wastewater treatment apparatus 70 of FIG.

Wastewater: Wastewater containing BOD 120mg / L, NH ₄ -N 30mg / L

-Retention time of the anaerobic tank (26): 4 hours

-Residence time of Hogi-jo (28): 3 hours

Filling rate of the comprehensive microbial carrier 14 (2% activated sludge carrier) in the aerobic tank 28: 2% (volume)

Filling rate of the support carrier 16 to the aerobic tank 28: 8% (volume)

-A cylindrical carrier made of foamed polypropylene (5mm ø8mm) is used as an attachment carrier.

Mechanical stirring in the anaerobic tank 26

-Aerobic aeration in the aerobic tank 28

-Floating sludge concentration in the aerobic tank (28): inhibited to 3000-4000 mg / L

-Sludge conveyance rate by the sludge conveying pipe 38: 80%

Nitriding liquid circulation rate by the nitriding liquid circulation line 34: 300%

(Invention G) In the case of using the wastewater treatment apparatus 80 of FIG.

Wastewater: inorganic wastewater containing NH ₄ -N 100mg / L

-Residence time of Hogi-jo (28): 4 hours

-Retention time of the anaerobic tank (26): 4 hours

Filling rate of the comprehensive microbial carrier 14 (2% activated sludge carrier) in the aerobic tank 28: 2% (volume)

Filling rate of the support carrier 16 to the aerobic tank 28: 10% (volume)

-8 mm square carrier made of foamed urethane

Mechanically agitate the anaerobic tank (26) and add 340 mg / L equivalency of methanol from the methanol feed line (38).

Aerobic aeration of the aeration tank 28

Suppression of suspended sludge concentration in the anaerobic tank (26) to 3000-4000 mg / L

-Sludge conveyance rate by the sludge conveying pipe 38: 80%

(Invention H) In the case of using the wastewater treatment apparatus 90 of FIG.

Wastewater: Organic wastewater containing BOD 200mg / L

-Retention time of the aerobic tank 28 on the shear side: 1 hour

-Residual time of the aerobic tank (40B) on the rear side: 3.5 hours

Filling rate of the comprehensive microbial carrier 14 (2% activated sludge carrier) in the aerobic tank 28 on the shear side: 2% (volume)

Filling rate of the support carrier 16 to the aerobic tank 28 on the shear side: 10% (volume)

-8 mm square carrier made of foamed urethane

-Aerobic aeration of each exhalation tank (28, 40)

-Inhibition of suspended active sludge concentration in the aerobic tank 40 on the rear side by 3000-4000mg / L

-Sludge conveyance rate by sludge conveying pipe 38: 50%

(Invention I) In the case of using the wastewater treatment apparatus 100 of FIG.

Wastewater: Wastewater containing BOD 50mg / L, NH ₄ -N 200mg / L

Retention time of anoxic tank (42): 1 hour

-Retention time of nitrous acid production tank (44): 6 hours

-Retention time of anaerobic ammonia oxidation tank (48): 4 hours

-Filling rate of comprehensive microbial carrier 14 (active sludge 2% carrier) in anoxic tank 42: 2% (volume)

-Filling rate of comprehensive microcarrier (14, carrier composition see Table 5) in nitrite production tank 44: 2%

-Filling rate of comprehensive microbial carrier (14, carrier composition see Table 6) in anaerobic ammonia oxidation tank 48: 2% (volume)

-Each tank 42, 44, 48 was filled with a nonwoven fabric-like filler 16 as an adhesion fixing material, and this nonwoven fabric-shaped filler 16 was filled so that the filling rate might be 30%.

-Return rate by the nitride liquid circulation line 34: 50%

By-pass 40% of the wastewater to the anaerobic ammonia oxidation tank 48 with respect to the raw water flow rate by the bypass line 46

Furtherance Weight portion Ammonia Oxidizing Bacteria Concentrate (10 ⁹ cells / cm 3) 30 Polyethylene Glycol Diacrylate 10 NNN'N'tetramethylethylenediamine 0.5 Potassium persulfate 0.25 water 59.25

As shown in Table 5, the composition was gelated by adding potassium persulfate, and the gelled product was molded into a 3 mm square, which was introduced into the nitrite production tank 44 as a comprehensive microbial carrier 14.

Furtherance Weight portion Anaerobic Ammonia Oxidizing Bacteria (10 ⁹ cells / cm 3) 30 Polyethylene Glycol Diacrylate 10 NNN'N'tetramethylethylenediamine 0.5 Potassium persulfate 0.25 water 59.25

As shown in Table 6, the composition was gelated by adding potassium persulfate, and the gelled product was molded into a 3 mm square, which was introduced into the anaerobic ammonia oxidation tank 48 as a comprehensive microbial carrier 14.

The wastewater treatment apparatus was operated under the test conditions of the present inventions F to I described above. In addition, when the removal rate of the BOD component and / or NH ⁴ -N component was 85% or more, or when the water quality of the treated water was stabilized, it was determined that the culture was completed, and the period was regarded as the culture period. The results are shown in Table 7. In addition, Table 7 shows the results of the tests for the conventional methods. In the conventional method, as shown in Figs. 10, 11, 12, and 13, the inclusion microorganism carrier 14 is replaced with the attachment carrier 16, and the whole of the biological treatment tank is attached to the attachment carrier 16 or the nonwoven fabric filler. (16) is filled. That is, instead of the comprehensive microbial carrier 14, the adhesion carrier 16 or the nonwoven plate-like filler 16 was filled at the same filling rate. At the start of the experiment of the conventional method, sludge was added.

Test series Device Drawing Number Incubation period Treated water NH ₄ -N (mg / L) Treated Nitrogen (mg / L) Treated water BOD (mg / L) Invention F Figure 10 21st 0.5-1.0 7-10 7-14 Invention G Figure 11 30 days 0.4-0.9 2-8 7-14 Invention H Figure 12 14 days 0.4-0.5 2-5 5-10 Invention I Figure 13 32 days 0.5-1.0 14-29 4-10 Conventional Method F (Fig. 10) 45 days 0.5-2.3 7-14 7-18 Conventional Method G (Figure 11) 62 days 0.5-5.2 2-12 7-18 Conventional Method H (Figure 12) 25th 0.4-0.5 2-10 7-24 Conventional Method I (Fig. 13) 69 days 0.5-7.6 22-60 12-30

As can be seen from Table 7, the conventional methods F to I have often been found to have a long incubation period of 25 to 69 days and a tendency of deterioration of the water quality of the treated water even after incubation. This is presumed that bacteria are easily peeled off from the adhesion carrier 16 or the nonwoven plate-like filler 16, thereby deteriorating the treated water.

In contrast, the present invention F to I have a culture period of 14 to 32 days, which is shorter than the conventional method, and the water quality after the culture is extremely stable.

In addition, when the present invention F and the conventional method F, the present invention G and the conventional method G, the present invention H and the conventional method H, and the present invention I and the conventional method I are compared in the same kind of wastewater, Can be shortened to more than half of the conventional method. In the case of the present invention, it is assumed that bacteria are always supplied to the attachment carrier 16 by leaking the bacteria from the comprehensive microbial carrier 14, thereby stably forming the biofilm on the surface of the attachment carrier. It is thereby possible to maintain the water quality of the treated water satisfactorily and stably.

10, 30, 40, 50, 60, 70, 80, 90, 100 wastewater treatment system
12 Biotreatment Tank 14 Comprehensive Microbial Carriers
16 Fixing fire (attachment carrier, nonwoven fabric filler)
Adhesion Bacteria Carrier Attached and Proliferated by 16 'Comprehensive Microbial Carrier
18 Marginal Introductory Tube 20 Screen
22 Outlet tube 24 Useful bacterial culture tank
26 Anaerobic Unit 28 Unit
31 Aeration tanks 32 Blowers
34 Nitride circulation line 36 Solid-liquid separation tank
38 Sludge return pipe 40 Back end side
42 Anaerobic Tank 44 Nitrous Acid Production Tank
46 Bypass Line 48 Anaerobic Ammonia Oxidizer
51 Nitride Tank

Claims (5)

In the wastewater treatment apparatus for biologically removing the substrate contained in the wastewater,
Comprehensive microbial carriers for proliferating microorganisms in the wastewater,
An attachment fixing material for attaching and propagating microorganisms leaking from the inside of the carrier to the outside of the carrier,
And a volume ratio (comprehensive microbial carrier / adhesive fixation material) of the comprehensive microbial carrier to the adhesion fixing material is 1/10 to 1/5.
The wastewater treatment apparatus according to claim 1, wherein the substrate is at least one of inorganic ammonia, nitrous acid, nitric acid, and organic matter, aoco, PCB, dioxins, and environmental hormone substances.
The wastewater treatment apparatus according to claim 1 or 2, wherein the adhesion fixation material is an adhesion carrier and / or an adhesion filler.
2. The ammonia nitrogen load according to claim 1 is brought into contact with an inclusive microorganism carrier comprising the immobilized microorganisms as the microorganism and wastewater containing ammonia nitrogen as the substrate, and the ammonia nitrogen load is 100 (mg-N / h /). L-carrier) waste water treatment apparatus characterized by the above.
2. The BOD component load according to claim 1, wherein the comprehensive microorganism carrier which comprehensively immobilizes the organic substance-degrading bacteria that decomposes the organic substance as the microorganism and the wastewater containing the BOD component as the substrate is brought into contact with each other and the load of the BOD component is 100 (mg-BOD). / h / L-carrier) or more.

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