[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

KR101228724B1 - Hose for preventing water waste, and preparation method thereof - Google Patents

Hose for preventing water waste, and preparation method thereof Download PDF

Info

Publication number
KR101228724B1
KR101228724B1 KR1020100120888A KR20100120888A KR101228724B1 KR 101228724 B1 KR101228724 B1 KR 101228724B1 KR 1020100120888 A KR1020100120888 A KR 1020100120888A KR 20100120888 A KR20100120888 A KR 20100120888A KR 101228724 B1 KR101228724 B1 KR 101228724B1
Authority
KR
South Korea
Prior art keywords
foam
water
water supply
hose
present
Prior art date
Application number
KR1020100120888A
Other languages
Korean (ko)
Other versions
KR20120059225A (en
Inventor
김진국
Original Assignee
경상대학교산학협력단
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 경상대학교산학협력단 filed Critical 경상대학교산학협력단
Priority to KR1020100120888A priority Critical patent/KR101228724B1/en
Priority to PCT/KR2011/008047 priority patent/WO2012074205A2/en
Publication of KR20120059225A publication Critical patent/KR20120059225A/en
Application granted granted Critical
Publication of KR101228724B1 publication Critical patent/KR101228724B1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/04Condition, form or state of moulded material or of the material to be shaped cellular or porous
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03Extrusion of the foamable blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

본 발명은 수압에 의하여 자연스럽게 물이 스며나오게 되어 물 공급을 위한 별도의 구성이 필요없고, 물 공급량을 낭비하지 않을 수 있는 물 공급호스를 제공하기 위하여, 평균 발포셀 크기가 50 ㎛ 이상 500 ㎛이하의 크기를 가지는 발포체의 제조방법, 상기 제조방법에 의하여 제조된 발포체 및 상기 발포체로 구성되는 물 공급호스를 제공한다.The present invention does not need a separate configuration for the water supply is naturally exuded by the water pressure, in order to provide a water supply hose that can not waste the water supply, the average foam cell size is 50 ㎛ or more and 500 ㎛ or less It provides a method for producing a foam having a size of, a foam prepared by the manufacturing method and a water supply hose consisting of the foam.

Description

물 낭비 방지용 호스 및 이의 제조방법{Hose for preventing water waste, and preparation method thereof}Hose for preventing water waste, and preparation method thereof

본 발명은 수압에 의하여 자연스럽게 물이 스며나오는 물 공급호스에 관한 것이다. The present invention relates to a water supply hose which naturally leaks water by water pressure.

일반적으로 지구상에 존재하는 물은 96% 정도의 해수와 빙하로 이루어지며, 4% 정도만이 육상에 존재하는 청정수로 이루어진다. 4 % 정도의 청정수 중에서도 인류가 사용할 수 있는 물은 0.007%에 불과하다. 또한 세계적으로 사막화가 심화되고 있고, 특히 우리나라의 경우 집중적인 강우현상에 따른 여름철 홍수와 겨울철 가뭄으로 인하여 물을 효과적으로 관리하는데 어려움이 따르고 있다. 이에 향후 물 부족 문제는 더욱 심화될 것으로 예상되며, 이에 따라 물의 낭비를 억제하는 것이 중요한 과제가 된다.
In general, water on earth is composed of 96% of seawater and glaciers, and only 4% of fresh water is on land. Of the 4% of pure water, only 0.007% of humankind can use it. In addition, desertification is intensifying around the world, and in Korea, especially in Korea, it is difficult to effectively manage water due to summer floods and winter droughts due to intensive rainfall. As a result, the problem of water shortage is expected to intensify in the future, and therefore, it is important to suppress waste of water.

한편, 사용할 수 있는 물의 양은 지극히 한정되어 있으나, 산업의 발전과 더불어 물 사용량이 급속하게 증가하고 있으며, 이는 농업 분야에서도 예외가 아니다. 최근 농업 분야에서는 물 공급을 위한 호스를 사용하여 대규모 또는 소규모로 물 공급이 이루어지고 있으며, 대부분 플라스틱 계열의 호스에 구멍을 내어 호스 속의 물이 구멍을 통하여 공급되는 방식을 취하고 있다.
On the other hand, the amount of water that can be used is extremely limited, but with the development of the industry, water consumption is increasing rapidly, which is not an exception in the agricultural field. Recently, in the agricultural sector, water supply is made on a large scale or small scale by using a hose for water supply. Most of the holes are made of holes in plastic hoses to supply water through the holes.

그러나, 상기의 물 공급호스는 물 공급량은 구멍의 크기 등으로 조절할 수 있지만, 농업 분야에서 사용되는 물 공급호스는 땅에 묻어서 사용하는 경우가 많아 구멍의 크기를 결정하면 향후 이를 다시 조절하는 것은 거의 불가능하다. 이에 물 공급량을 효과적으로 조절할 수 없고, 이에 따라 물이 과잉공급되는 문제점이 있다. 물이 과잉공급되는 점 이외에도, 호스의 구멍을 통하여 물이 공급되기 때문에 구멍의 위치에 따라 일부에만 물이 공급되는 문제점이 있다. 또한, 흙 등의 이물질이 구멍을 막음으로서 물의 공급이 원할치 못한 문제점도 있다.
However, although the water supply hose can adjust the water supply amount by the size of the hole, etc., the water supply hose used in the agricultural field is often used by burying the ground. impossible. As a result, the water supply cannot be effectively adjusted, and thus there is a problem in that the water is excessively supplied. In addition to the excessive supply of water, since water is supplied through the hole of the hose, only a part of the water is supplied depending on the position of the hole. In addition, there is a problem that the supply of water is undesired because foreign matter such as soil blocks the hole.

이에 본 발명자는 상기 물 공급호스의 물 공급방식을 획기적으로 전환하여, 물 공급호스를 구성하는 고분자를 발포체로 구성하고, 이러한 발포체에 발포셀의 크기를 50 ㎛ 내지 500 ㎛로 조절할 경우, 물 공급호스에 공급되는 수압에 의하여 발포셀을 통하여 물이 자연스럽게 스며나오는 것을 착안하였다. 이에 따라 물 공급호스에 구멍을 뚫지 않아도 물이 공급될 수 있으며, 수압을 통하여 물이 스며나오는 양을 조절할 수 있고, 물 공급호스 전체에서 물이 스며나오게 되므로, 물의 과잉공급을 억제할 수 있음을 확인하고 본 발명을 완성하였다. 본 발명에 따른 물 공급호스는 흙 속에 묻어 물을 공급하게 되므로, 온실이나 농장 등의 식물재배에 사용될 수 있으며, 잔디밭의 스프링 쿨러 대신 물 공급을 쉽게 할 수 있다. 특히 골프장 그린의 천연잔디를 관리하기 위하여 다량의 농약을 사용하게 됨으로서 환경문제를 일으키게 되는 문제점 또한 방지할 수 있다.Accordingly, the present inventors significantly switch the water supply method of the water supply hose, and when the polymer constituting the water supply hose is composed of a foam, and when the size of the foam cell to the foam is adjusted to 50 ㎛ to 500 ㎛, water supply It was conceived that water naturally bleeds through the foam cell by the water pressure supplied to the hose. Accordingly, water can be supplied without drilling a hole in the water supply hose, and the amount of water seeping through the water pressure can be controlled, and water can seep out from the entire water supply hose, thereby suppressing the oversupply of water. It confirmed and completed this invention. Since the water supply hose according to the present invention is buried in the soil to supply water, it can be used for plant cultivation, such as a greenhouse or a farm, it is possible to easily supply water instead of the sprinkler of the lawn. In particular, by using a large amount of pesticides in order to manage the natural grass of the golf course green can also prevent problems that cause environmental problems.

본 발명은 수압에 의하여 자연스럽게 물이 스며나오게 되어 물 공급을 위한 별도의 구성이 필요없고, 물 공급량을 낭비하지 않을 수 있는 물 공급호스를 제공하기 위한 것으로, 평균 발포셀 크기가 50 ㎛ 이상 500 ㎛이하의 크기를 가지는 발포체의 제조방법 및 상기 제조방법에 의하여 제조된 발포체를 제공하기 위한 것이다. The present invention is to provide a water supply hose that does not need a separate configuration for the water supply is naturally exuded by the water pressure, and does not waste the water supply, the average foam cell size is 50 ㎛ or more 500 ㎛ It is to provide a method for producing a foam having the following size and a foam produced by the production method.

또한, 본 발명은 상기 발포체로 구성되는 물 공급호스를 제공하기 위한 것이다.In addition, the present invention is to provide a water supply hose composed of the foam.

상기의 과제를 해결하기 위하여, 본 발명은 폴리에틸렌, 폴리프로필렌 및 발포제를 혼합하여 혼합물을 제조하는 단계(단계 1); 및 상기 혼합물을 160℃ 내지 240℃의 온도에서 압출기로 발포하여 발포체를 제조하는 단계(단계 2)를 포함하는 발포체의 제조방법을 제공한다.
In order to solve the above problems, the present invention comprises the steps of preparing a mixture by mixing polyethylene, polypropylene and blowing agent (step 1); And foaming the mixture with an extruder at a temperature of 160 ° C to 240 ° C to produce a foam (step 2).

상기 단계 1은, 발포체를 만들기 위하여 발포의 대상이 되는 혼합물을 제조하기 위한 것으로, 폴리에틸렌, 폴리프로필렌 및 발포제를 혼합하여 본 발명의 용도에 적절한 혼합물을 제조하는 단계이다.
Step 1 is to prepare a mixture to be foamed in order to make a foam, to prepare a mixture suitable for the use of the present invention by mixing polyethylene, polypropylene and blowing agent.

본 발명에서는 발포체의 기본적인 구성으로서 폴리에틸렌과 폴리프로필렌을 함께 사용한다. 폴리에틸렌과 폴리프로필렌을 함께 사용할 경우 발포체가 유연성과 내구성을 동시에 가질 수 있어, 물 공급호스로 사용할 수 있다. 본 발명에서 사용되는 폴리프로필렌은 폴리에틸렌과 폴리프로필렌의 공중합체를 포함한다.
In the present invention, polyethylene and polypropylene are used together as the basic structure of the foam. When polyethylene and polypropylene are used together, the foam can have both flexibility and durability, and can be used as a water supply hose. Polypropylene used in the present invention includes a copolymer of polyethylene and polypropylene.

본 발명에 사용되는 용어 "발포제"란, 폴리프로필렌 및 폴리에틸렌과 함께 배합되어 기포를 만들어내는 물질을 의미한다. 발포제를 사용하는 발포방식을 화학적 발포방법이라고 하며, 본 발명에서는 발포체의 셀의 크기를 적절히 조절하기 위하여 아조디카본아미드 또는 소디움 바이카보네이트를 사용할 수 있다.
As used herein, the term "foaming agent" refers to a material that is combined with polypropylene and polyethylene to create a bubble. A foaming method using a blowing agent is called a chemical foaming method, and in the present invention, azodicarbonamide or sodium bicarbonate may be used to appropriately control the size of the cell of the foam.

상기 혼합물의 혼합비는 발포체의 셀 크기를 조절하기 위하여 중요하며, 상기 폴리에틸렌, 폴리프로필렌 및 발포제는 각각 60 내지 90 중량부, 10 내지 30 중량부, 1 내지 5 중량부의 비율로 포함되는 것이 바람직하다. 발포제의 혼합비를 조절하여 발포셀의 크기를 조절할 수 있다.
The mixing ratio of the mixture is important for controlling the cell size of the foam, and the polyethylene, polypropylene and the blowing agent are preferably included in the ratio of 60 to 90 parts by weight, 10 to 30 parts by weight, and 1 to 5 parts by weight, respectively. The size of the foam cell can be adjusted by adjusting the mixing ratio of the blowing agent.

상기 단계 2는, 상기 혼합물을 발포하여 발포체를 제조하기 위한 단계로서, 상기 혼합물을 160℃ 내지 240℃의 온도에서 압출기에서 발포하여 발포체를 호스 또는 파이프 모양의 물 공급호스를 제조하는 단계이다.
Step 2 is a step for producing a foam by foaming the mixture, the mixture is foamed in an extruder at a temperature of 160 ℃ to 240 ℃ to produce a foam hose or pipe-shaped water supply hose.

발포체의 셀 크기를 조절하기 위하여 온도, 발포제량 및 수지량을 조절하는 것이 중요하다. 이 중 온도는 가장 중요한 변수로서, 발포제의 기포의 생성여부와 관련이 있으며, 사용되는 수지의 용융온도(Tm; melting temperature) 이상이 바람직하며, 본 발명에서는 160℃ 내지 240℃의 온도로 발포하는 것이 바람직하다.
It is important to control the temperature, the amount of blowing agent and the amount of resin in order to control the cell size of the foam. Among these, the temperature is the most important variable, which is related to the foaming of the foaming agent, and is preferably higher than the melting temperature (Tm; melting temperature) of the resin used, and in the present invention, foaming is performed at a temperature of 160 ° C to 240 ° C. It is preferable.

상기 제조방법에 의하여 제조된 발포체는, 물 공급에 의하여 물이 자연스럽게 스며나올 수 있도록, 발포체의 평균 발포셀 크기는 50 ㎛ 이상 500 ㎛이하의 크기를 가지고 있다. 이러한 발포체를 이용하여 물을 공급하게 될 경우, 호스 또는 파이프 내부에 물이 있는 경우 수압에 의하여 조금씩 발포체의 기공을 통하여 스며나오게 된다. 종래의 물 공급호스의 구멍은 크기가 너무 크기 때문에 물이 그냥 빠져나오게 되므로 물이 과잉공급된다는 문제점이 있으나, 본 발명에서는 미세한 발포체의 기공을 통하여 물의 과잉공급을 방지할 수 있다. 따라서, 발포셀의 크기는 발포체로 구성된 물 공급호스의 물 공급량을 조절하기 위하여 중요하며, 평균 발포셀의 크기가 50 ㎛ 미만일 경우에는 수압이 높아도 물이 충분히 물 공급호스 밖으로 새어 나오지 않으며, 평균 발포셀의 크기가 500 ㎛를 초과하는 경우에는 수압이 낮아도 물이 물 공급 호스 밖으로 새어 나와 물이 과잉공급될 수 있다.
The foam produced by the above production method has an average foaming cell size of 50 µm or more and 500 µm or less so that the water can naturally flow out by the water supply. When water is supplied using the foam, if water is present in the hose or the pipe, the water is exuded through the pores of the foam little by little. The hole of the conventional water supply hose has a problem that the water is excessively supplied because the water is just released because the size is too large, in the present invention can prevent the excessive supply of water through the pores of the fine foam. Therefore, the size of the foam cell is important to control the water supply amount of the water supply hose composed of foam, when the average foam cell size is less than 50 ㎛, even if the water pressure is high, the water does not sufficiently leak out of the water supply hose, the average foaming If the size of the cell exceeds 500 μm, even if the water pressure is low, water may leak out of the water supply hose and the water may be oversupplied.

또한, 본 발명은 상기 발포체의 제조방법으로 제조된 발포체를 제공한다. 본 발명에 따른 발포체는 폴리에틸렌 및 폴리프로필렌을 주성분으로 하는 것으로, 구부러지더라도 꺾이지 않을 정도의 유연성을 가지고 있으며, 땅속에 묻을 경우에도 찢어지지 않는 내구성을 가지고 있다는 특징이 있다.
The present invention also provides a foam produced by the method for producing the foam. The foam according to the present invention is mainly composed of polyethylene and polypropylene, has flexibility to bend even when bent, and has a durability that does not tear even when buried in the ground.

또한 본 발명은 상기 발포체로 구성되는 물 공급 호스 또는 파이프를 제공한다. 본 발명에 따른 물 공급 호스 또는 파이프는 평균 발포셀 크기가 50 ㎛ 이상 500 ㎛이하인 발포체로 구성되는바, 물 공급 호스 또는 파이프 내부로 물을 공급할 경우, 수압에 의하여 자연스럽게 물이 스며나오게 되어 물 공급을 위한 별도의 구성이 필요없고, 물 공급량을 낭비하지 않을 수 있다. The present invention also provides a water supply hose or pipe composed of the foam. The water supply hose or pipe according to the present invention is composed of a foam having an average foam cell size of 50 μm or more and 500 μm or less. When water is supplied into the water supply hose or pipe, water is naturally exuded by water pressure to supply water. There is no need for a separate configuration, and may not waste water supply.

종래에는 물 공급을 위하여 고분자 호스에 구멍을 내어 호스 속의 물이 구멍을 통하여 공급되는 방식을 취하였으나, 이러한 방식은 물 공급량을 조절할 수 없어 물을 낭비하는 단점이 있었다. 본 발명은 종래 물 공급방식을 탈피하여, 발포체의 발포셀을 물 공급수단으로 응용하고, 특히 수압에 의하여 물이 스며나오는 방식을 채택함으로서, 물을 낭비하지 않고 공급할 수 있다는 특징이 있다. 특히, 본 발명은 발포고분자, 발포체, 발포온도, 회전수 등을 고려하여 발포체의 발포셀이 50 μm 내지 500 μm 정도를 가질 수 있도록 제조하였다. 본 발명의 발포체로 구성되는 물 공급호스는 물 공급이 필요한 분야에 활용될 수 있다.Conventionally, a hole is made in the polymer hose to supply water, and water in the hose is supplied through the hole. However, this method has a disadvantage in that it is not possible to adjust the amount of water to waste water. The present invention is characterized by being able to supply water without wasting by applying a foaming cell of the foam as a water supply means, in particular, by introducing a foaming cell of the foam as a water supply means, and away from the conventional water supply method. In particular, the present invention was prepared so that the foamed cell of the foam may have about 50 μm to 500 μm in consideration of foamed polymer, foam, foaming temperature, rotational speed, and the like. The water supply hose composed of the foam of the present invention can be utilized in fields requiring water supply.

도 1은, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Cellcom 2 g, RPM 5 min-1의 조건으로 제조한 것이다.
도 2는, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Cellcom 2 g, RPM 10 min-1의 조건으로 제조한 것이다.
도 3은, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Cellcom 4 g, RPM 5 min-1의 조건으로 제조한 것이다.
도 4는, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Kycerol 4 g, RPM 5 min-1의 조건으로 제조한 것이다.
도 5는, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Kycerol 4 g, RPM 40 min-1의 조건으로 제조한 것이다.
도 6은, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Kycerol 9.6 g, RPM 10 min-1의 조건으로 제조한 것이다.
도 7은, 본 발명의 일 실시예에 따른 발포체의 현미경 사진을 나타낸 것으로, 발포체는 폴리에틸렌 180 g, 폴리프로필렌 20 g, Kycerol 9.6 g, RPM 40 min-1의 조건으로 제조한 것이다.
도 8은, 본 발명의 일 실시예에 따른 발포체로 구성된 호스를 개략적으로 나타낸 것이다.
Figure 1 shows a micrograph of the foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 2 g Cellcom, RPM 5 min -1 polyethylene.
Figure 2 shows a micrograph of a foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 2 g Cellcom, RPM 10 min -1 .
Figure 3 is a micrograph of the foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 4 g Cellcom, RPM 5 min -1 polyethylene.
Figure 4 shows a micrograph of the foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 4 g Kycerol, RPM 5 min -1 .
Figure 5 shows a micrograph of the foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 4 g Kycerol, RPM 40 min -1 .
Figure 6 shows a micrograph of the foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 9.6 g Kycerol, RPM 10 min -1 .
Figure 7 shows a micrograph of a foam according to an embodiment of the present invention, the foam is prepared under the conditions of 180 g polyethylene, 20 g polypropylene, 9.6 g Kycerol, RPM 40 min -1 .
Figure 8 schematically shows a hose composed of a foam according to an embodiment of the present invention.

이하,본 발명의 이해를 돕기 위하여 바람직한 실시예를 제시한다. 그러나 하기의 실시예는 본 발명을 더욱 쉽게 이해하기 위하여 제공되는 것일 뿐,실시예에 의하여 본 발명의 내용이 한정되는 것은 아니다.
Hereinafter, preferred embodiments of the present invention will be presented to assist in understanding the present invention. However, the following examples are merely provided to more easily understand the present invention, and the contents of the present invention are not limited by the examples.

실시예 1Example 1

폴리에틸렌(High Density Polyethylene Grade(PH150); LG화학) 180g, 폴리프로필렌(VISTAMAXX™; 85% PP, 13~15% PE, 메탈로센 촉매 합성; Exxon Mobil 사) 20g, 및 아조디카본아미드(Cellcom-AC Series; 금양) 2g을 압출기(Plastic Corder; Brabender 사)에 첨가하였다. 압출기의 온도 설정은 공급부/압출부/다이 순으로 각각 190℃/230℃/240℃으로 설정하였다.
180 g polyethylene (High Density Polyethylene Grade (PH150); LG Chem), polypropylene (VISTAMAXX ™; 85% PP, 13-15% PE, metallocene catalyst synthesis; Exxon Mobil) 20 g, and azodicarbonamide (Cellcom 2 g of AC Series (Kumyang) was added to an extruder (Plastic Corder, Brabender). The temperature setting of the extruder was set to 190 ° C./230° C./240° C. in the order of feed part / extrusion part / die.

발포시간은 압출기의 스크류 회전속도(RPM)를 5 min-1로 설정하여 발포하였으며, 제조된 발포체의 현미경 사진을 도 1에 나타내었다.
Foaming time was foamed by setting the screw rotational speed (RPM) of the extruder to 5 min -1 , the micrograph of the prepared foam is shown in FIG.

실시예 2Example 2

실시예 1과 동일한 방법으로 발포체를 제조하되, 스크류 회전속도(RPM)를 10 min-1로 설정하여 발포하였으며, 제조된 발포체의 현미경 사진을 도 2에 나타내었다.
Foam was prepared in the same manner as in Example 1, but was foamed by setting the screw rotational speed (RPM) to 10 min -1 , the micrograph of the prepared foam is shown in FIG.

실시예 3Example 3

실시예 1과 동일한 방법으로 발포체를 제조하되, 아조디카본아미드를 4g으로 사용하여 발포체를 제조하였으며, 제조된 발포체의 현미경 사진을 도 3에 나타내었다.
A foam was prepared in the same manner as in Example 1, but a foam was prepared using 4 g of azodicarbonamide, and a micrograph of the prepared foam was shown in FIG. 3.

실시예 4Example 4

폴리에틸렌(High Density Polyethylene Grade(PH150); LG화학) 180g, 폴리프로필렌(VISTAMAXX™; 85% PP, 13~15% PE, 메탈로센 촉매 합성; Exxon Mobil 사) 20g, 및 소디움 바이카보네이트(Kycerol; 금양) 4g을 압출기(Plastic Corder; Brabender 사)에 첨가하였다. 압출기의 온도 설정은 공급부/압출부/다이 순으로 각각 180℃/185℃/195℃로 설정하였다. 180 g polyethylene (High Density Polyethylene Grade (PH150); LG Chem), polypropylene (VISTAMAXX ™; 85% PP, 13-15% PE, metallocene catalyst synthesis; Exxon Mobil) 20 g, and sodium bicarbonate (Kycerol; Geumyang) 4g was added to an extruder (Plastic Corder, Brabender). The temperature setting of the extruder was set to 180 ° C./185° C./195° C. in the order of feed part / extrusion part / die.

발포시간은 압출기의 스크류 회전속도(RPM)를 5 min-1로 설정하여 발포하였으며, 제조된 발포체의 현미경 사진을 도 4에 나타내었다.
Foaming time was foamed by setting the screw rotational speed (RPM) of the extruder to 5 min -1 , the micrograph of the prepared foam is shown in FIG.

실시예 5Example 5

실시예 4와 동일한 방법으로 제조하되, 스크류 회전속도(RPM)를 40 min-1로 설정하여 발포체를 제조하였으며, 제조된 발포체의 현미경 사진을 도 5에 나타내었다.
Prepared in the same manner as in Example 4, the foam was prepared by setting the screw rotational speed (RPM) to 40 min -1 , the micrograph of the prepared foam is shown in FIG.

실시예 6Example 6

실시예 4와 동일한 방법으로 제조하되, 소디움 바이카보네이트를 9.6g을 사용하고, 스크류 회전속도(RPM)를 10 min-1로 설정하여 발포체를 제조하였으며, 제조된 발포체의 현미경 사진을 도 6에 나타내었다.
A foam was prepared in the same manner as in Example 4, except that 9.6 g of sodium bicarbonate was used and the screw rotation speed (RPM) was set to 10 min −1 , and a micrograph of the prepared foam was shown in FIG. 6. It was.

실시예 7Example 7

실시예 4와 동일한 방법으로 제조하되, 소디움 바이카보네이트를 9.6g을 사용하고, 스크류 회전속도(RPM)를 40 min-1로 설정하여 발포체를 제조하였으며, 제조된 발포체의 현미경 사진을 도 7에 나타내었다.
A foam was prepared in the same manner as in Example 4, except that 9.6 g of sodium bicarbonate was used and the screw rotational speed (RPM) was set to 40 min −1 , and a micrograph of the prepared foam was shown in FIG. 7. It was.

도 1 내지 도 7에 나타난 바와 같이, 본 발명에 따른 발포체는 평균 발포셀 크기가 50 ㎛ 이상 500 ㎛이하의 크기를 가지고 있음을 확인할 수 있었다. 또한 아조디카본아미드를 사용한 경우에는 낮은 RPM에서 발포가 잘 되었으며, 소디움 디카보네이트를 사용한 경우에는 높은 RPM에서 발포가 잘 되었음을 확인할 수 있었다. As shown in Figures 1 to 7, it was confirmed that the foam according to the present invention has an average foam cell size of 50 ㎛ or more and 500 ㎛ or less. In addition, when azodicarbonamide was used, foaming was well performed at low RPM, and when sodium dicarbonate was used, it was confirmed that foaming was good at high RPM.

Claims (7)

폴리에틸렌, 폴리프로필렌, 및 발포제를 각각 60 내지 90 중량부, 10 내지 30 중량부, 1 내지 5 중량부의 비율로 혼합하여 혼합물을 제조하는 단계;
상기 혼합물을 160℃ 내지 240℃의 온도에서 압출기로 발포하여 발포체를 제조하는 단계를 포함하는 발포체의 제조방법.
Preparing a mixture by mixing polyethylene, polypropylene, and a blowing agent at a ratio of 60 to 90 parts by weight, 10 to 30 parts by weight, and 1 to 5 parts by weight, respectively;
Foaming the mixture with an extruder at a temperature of 160 ° C to 240 ° C to produce a foam.
삭제delete 제1항에 있어서, 상기 발포제는 아조디카본아미드 또는 소디움 바이카보네이트인 것을 특징으로 하는 발포체의 제조방법.
The method of claim 1, wherein the blowing agent is azodicarbonamide or sodium bicarbonate.
제1항에 있어서, 상기 발포체의 평균 셀 크기는 50 ㎛ 내지 500 ㎛인 것을 특징으로 하는 발포체의 제조방법.
The method of claim 1, wherein the foam has an average cell size of 50 μm to 500 μm.
제1항, 제3항 또는 제4항의 제조방법에 의하여 제조된 발포체.
Foam produced by the method of claim 1, 3 or 4.
제5항의 발포체로 구성되는 물 낭비 방지용 호스 또는 파이프.
Water waste prevention hose or pipe consisting of the foam of claim 5.
제6항에 있어서, 상기 물 낭비 방지용 호스에 공급되는 수압에 의하여 발포셀을 통하여 물이 스며나오는 것을 특징으로 하는 물 낭비 방지용 호스 또는 파이프.The water waste prevention hose or pipe according to claim 6, wherein water is extruded through the foam cell by the water pressure supplied to the water waste prevention hose.
KR1020100120888A 2010-11-30 2010-11-30 Hose for preventing water waste, and preparation method thereof KR101228724B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1020100120888A KR101228724B1 (en) 2010-11-30 2010-11-30 Hose for preventing water waste, and preparation method thereof
PCT/KR2011/008047 WO2012074205A2 (en) 2010-11-30 2011-10-26 Hose for preventing water waste and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020100120888A KR101228724B1 (en) 2010-11-30 2010-11-30 Hose for preventing water waste, and preparation method thereof

Publications (2)

Publication Number Publication Date
KR20120059225A KR20120059225A (en) 2012-06-08
KR101228724B1 true KR101228724B1 (en) 2013-02-01

Family

ID=46172341

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020100120888A KR101228724B1 (en) 2010-11-30 2010-11-30 Hose for preventing water waste, and preparation method thereof

Country Status (2)

Country Link
KR (1) KR101228724B1 (en)
WO (1) WO2012074205A2 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001078592A (en) * 1999-09-07 2001-03-27 Nagano Nova Form Kk Foamed molded article and its production
JP2001213989A (en) 2000-02-01 2001-08-07 Mitsui Chemicals Inc Polyolefin resin foamed sheet and its manufacturing method
KR100338843B1 (en) 1994-07-15 2002-11-23 스미또모 가가꾸 고오교오 가부시끼가이샤 Polypropylene resin composition, polypropylene resin foamed material and process for procucing the same
WO2007017250A1 (en) 2005-08-08 2007-02-15 Sekisui Alveo Ag Soft polyolefin foams with high heat resistance

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5368235A (en) * 1990-08-09 1994-11-29 Plastic Specialties And Technologies, Inc. Soaker hose assembly
JP3583539B2 (en) * 1996-01-09 2004-11-04 西川ゴム工業株式会社 Method for manufacturing porous hose

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100338843B1 (en) 1994-07-15 2002-11-23 스미또모 가가꾸 고오교오 가부시끼가이샤 Polypropylene resin composition, polypropylene resin foamed material and process for procucing the same
JP2001078592A (en) * 1999-09-07 2001-03-27 Nagano Nova Form Kk Foamed molded article and its production
JP2001213989A (en) 2000-02-01 2001-08-07 Mitsui Chemicals Inc Polyolefin resin foamed sheet and its manufacturing method
WO2007017250A1 (en) 2005-08-08 2007-02-15 Sekisui Alveo Ag Soft polyolefin foams with high heat resistance

Also Published As

Publication number Publication date
WO2012074205A3 (en) 2012-09-07
WO2012074205A2 (en) 2012-06-07
KR20120059225A (en) 2012-06-08

Similar Documents

Publication Publication Date Title
CN102907294B (en) Infiltrating micro-irrigation system
CN101331845B (en) Anti-blocking automatic filtration irrigation method
CN101091448B (en) Irrigation and drainage pipes
CN109618719A (en) Growing surface structure and the module and method for being used to form this growing surface structure
US20220142065A1 (en) Liquid Containment and Focus for Subterranean Capillary Irrigation
CN102742489A (en) Seeping micro-irrigation container and preparation method thereof
JP4666833B2 (en) Seed bed, production method and sowing method
CN103623950A (en) B-type moistube manufactured through one-step forming method, manufacturing method of B-type moistube and application of B-type moistube
CN101151960A (en) Cold resistant film for vine and cold resistant overwintering method using the same
CN103348798A (en) Sand control method using modified sand soil for tree planting
KR101961569B1 (en) Lawn sprouting mat and greening work using the same
KR101228724B1 (en) Hose for preventing water waste, and preparation method thereof
CN105037885A (en) Puncture-resistant saline-alkali land salt-removing subsurface pipe and application thereof
CN103158263A (en) Processing technology of nano-water saving pipe
CN111699953A (en) Novel water-saving irrigation device for agricultural planting and use method thereof
CN207885345U (en) A kind of drip irrigation system suitable for artificial reconstructed side slope landforms
CN105965855A (en) Seam compensation type drip-infiltrating-irrigation pipe machining method and pipe clamp used for drip-infiltrating-irrigation pipe
KR101404142B1 (en) Manufacturing method of permeability
KR20100055780A (en) Vegetation shore protection block and manufacturing method thereof
CN1079189C (en) Agricultural plastic infiltrating irrigation pipe
JP2008271857A (en) Natural grass vegetating structure
JP2010029072A (en) Subirrigation system
CN219352477U (en) Structure for utilizing vine plants and shrubs to compound green side slope
JP2003284429A (en) Method for producing construction material, and method for constructing the material
CN204876017U (en) Side slope drainage device

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20170111

Year of fee payment: 5

FPAY Annual fee payment

Payment date: 20180425

Year of fee payment: 6

FPAY Annual fee payment

Payment date: 20200115

Year of fee payment: 8