KR101212684B1 - Hot water supply device associated with heat pump and control method thereof - Google Patents
Hot water supply device associated with heat pump and control method thereof Download PDFInfo
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- KR101212684B1 KR101212684B1 KR1020100139326A KR20100139326A KR101212684B1 KR 101212684 B1 KR101212684 B1 KR 101212684B1 KR 1020100139326 A KR1020100139326 A KR 1020100139326A KR 20100139326 A KR20100139326 A KR 20100139326A KR 101212684 B1 KR101212684 B1 KR 101212684B1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/12—Hot water central heating systems using heat pumps
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Abstract
The present invention relates to a heat pump interlocking hot water supply device, and in particular, a deficiency of heating water due to a shortage of defrosting time during defrost mode operation and a decrease in heating water due to a decrease in ambient temperature during heating mode operation. It solves by replenishing the hot water supply through it provides an advantage to improve the customer satisfaction.
Description
The present invention relates to a heat pump interlocking hot water supply device and a control method thereof, and more particularly, a lack of heating water due to a long defrost time during defrost mode operation and a shortage of heating water due to a decrease in ambient temperature during heating mode operation. The present invention relates to a heat pump interlocking hot water supply device capable of improving consumer satisfaction by solving the phenomenon by supplementing hot water through a bypass replenishment flow passage.
In general, a hot water supply device is a device that provides hot water to a user by heating water with a heating source. At this time, the water is heated by the heat pump, the device for providing hot water to the user may be referred to as a heat pump interlocking hot water supply device.
1 is a structural diagram showing a flow of a refrigerant by a binary refrigerant refrigeration cycle according to the prior art.
As shown in FIG. 1, the dual refrigerant refrigeration cycle according to the related art includes a first compressor 5 compressing the first refrigerant and a first condenser in which the first refrigerant discharged from the first compressor 5 is condensed. 20, the
In addition, the binary refrigerant refrigeration cycle according to the prior art, as shown in Figure 1, the
Here, the first condenser and the second evaporator have the same configuration, and constitute a so-called dual refrigerant refrigeration cycle in which one refrigerant evaporates while the other refrigerant condenses while intersecting the first refrigerant and the second refrigerant. It is a kind of heat exchanger.
On the other hand, the
In the course of the refrigerant flowing in the binary refrigerant refrigeration cycle, the refrigerant eventually absorbs heat in the evaporator to release heat from the condenser. The heat pump interlocked hot water supply device is capable of performing hot water supply in such a manner that a refrigerant transfers heat to the use water of the hot water supply device.
However, the heat pump interlocking hot water supply apparatus according to the prior art temporarily stops the heating mode operation as a result of temporarily operating the heat pump in the cooling mode operation for defrosting the outdoor heat exchanger during the defrost mode operation of defrosting the outdoor heat exchanger. There is a problem to be done.
In addition, the heat pump interlocking hot water supply apparatus according to the prior art, when the outdoor air temperature is sharply lowered, the starting efficiency of the compressor does not correspond to the sharply lowered outdoor temperature, causing the indoor residents to feel a relatively cold to achieve a sufficient heating effect There is this.
The present invention has been made to solve the above technical problem, the lack of heating water due to the long defrost time during defrost mode operation and the shortage of heating water due to the decrease in the outside air temperature during heating mode operation as a bypass replenishment oil The purpose of the present invention is to provide a heat pump interlocking hot water supply device and a control method thereof, which can be solved by replenishing hot water through the water supply, thereby improving customer satisfaction.
The heat pump interlocking hot water supply apparatus according to the present invention includes a first compressor for compressing a first refrigerant, a first water circulation unit through which heating water is circulated so as to perform heating in a room, and the first refrigerant and the first water circulation unit. A first use heat exchanger in which the heating water is heat-exchanged with each other, a second compressor for compressing the second refrigerant, a second water circulation unit through which the hot water is flowed to perform a hot water supply, and a water supply water in the second refrigerant and the second water circulation unit A second heat exchanger for heat exchange, a cascade heat exchanger for mutually heat-exchanging a portion of the first refrigerant and the second refrigerant discharged from the first compressor, and a first condensed by the first use heat exchanger and the cascade heat exchanger An outdoor heat exchanger for evaporating a refrigerant, connecting the first water circulation unit and the second water circulation unit, and operating in any one of a heating operation mode, a cooling mode operation, and a defrost operation mode. And optionally, a bypass replenishment passage for replenishing the hot water of the second water circulation part with the heating water of the first water circulation part.
Here, the heating water pump disposed in the first water circulation portion, the heating water pump for pumping the heating water of the first water circulation portion, and the hot water supply disposed in the second water circulation portion, pumping the hot water supply of the second water circulation portion And a water pump, wherein the bypass replenishment flow passage is closer to the heating water pump and the hot water supply pump based on the hot water outlet of the first use heat exchanger and the hot water outlet of the second use heat exchanger. Inlet and outlet may be connected to.
In addition, the pump may further include a replenishment flow passage disposed on the bypass replenishment flow passage.
The inlet and outlet of the bypass replenishment flow passage are connected to the first water circulation part and the second water circulation part by an on / off valve, and each of the on / off valves is a heating operation mode, a cooling mode operation, and a defrost. When operating in any one of the mode operation can be selectively switched.
In addition, the on-off valve connected to the inlet end of the bypass replenishment flow passage is controlled to be opened so that the bypass replenishment flow passage is activated when the outside air temperature is less than or equal to a first predetermined temperature during the heating mode operation of the heat pump interlocking hot water supply device. Do.
In addition, the on-off valve connected to the inlet of the bypass replenishment flow passage is preferably controlled to be opened so that the bypass replenishment flow passage is activated during the defrost mode operation of the heat pump interlocking hot water supply device.
On the other hand, the first refrigerant compressed by the first compressor is a first refrigerant circulating unit for circulating the first use heat exchanger and the outdoor heat exchanger to perform the cooling / heating, and the compressed by the second compressor In the heating mode operation or the defrost mode operation of the second refrigerant circulation unit for circulating the second heat exchanger and the cascade heat exchanger to perform the hot water supply of the second refrigerant, and the defrost mode operation, A first refrigerant injection circuit branched from the first refrigerant circulator so as to be injected into the first compressor and connected to the first compressor, and a gas refrigerant of the second refrigerant injected into the second compressor The apparatus may further include a second refrigerant injection circuit branched from the second refrigerant circulation part and connected to the second compressor.
Here, the first refrigerant injection circuit and the second refrigerant injection circuit are controlled to be activated when the outside air temperature is lower than or equal to the second preset temperature.
In addition, a first gas liquid separator and a second gas liquid separator for separating the refrigerant flowing through the first refrigerant injection circuit and the second refrigerant injection circuit into a liquid refrigerant and an air refrigerant are respectively the first refrigerant injection circuit and the second refrigerant. It can be placed in the injection circuit.
In the control method of the heat pump interlocking hot water supply apparatus according to the present invention, when the power is applied, the first compressor and the second compressor are operated such that the first refrigerant circulates the first refrigerant circulation section and the second refrigerant circulates the second refrigerant circulation section. Comparing the current heating temperature and the target heating temperature with respect to the operation rates of the first compressor and the second compressor according to the outside air temperature after the first step, and circulating the second water circulation unit while circulating the second water circulation unit. And a second opening / closing bypass bypass that connects the first water circulation part and the second water circulation part to replenish the hot water exchanged with the first water circulation part while circulating the first water circulation part. Steps.
Here, in the second step, the target heating temperature is higher than the current heating temperature, the heating water heat-exchanged with the first refrigerant compressed by the first compressor and the second refrigerant compressed by the second compressor When the temperature is lower than the heat exchange hot water supply may be a step of opening the bypass replenishment flow path.
The second step may include opening the bypass supplement flow passage when the first compressor is operated in a defrosting operation mode when the target heating temperature is lower than the current heating temperature.
In addition, the first water circulating unit and the second water circulating unit are connected to recover the heating water from the first water circulating unit to the second water circulating unit at the same time as the opening and closing control of the bypass replenishment passage in the second step. The method may further include a third step of opening and closing the heating water recovery flow path.
In addition, the second step may be a step of opening the bypass replenishment flow passage only when the second compressor is in operation.
The third step may include opening the bypass refill oil and opening the heating water recovery flow passage only when the second compressor is in operation.
In the heat pump interlocking hot water supply device and its control method according to the present invention, in a place such as a cold district where the outdoor air temperature is rapidly lowered during the heating mode operation, the hot water is supplied to the heating water for the heating by-pass to the external air temperature. Because it is supplemented through it has the effect of improving the heating quality of indoor occupants.
In addition, the heat pump interlocking hot water supply device and the control method according to the present invention, even in the defrost mode operation, even if the heating mode operation is stopped, the hot water supply can be supplemented with the heating water through the bypass replenishment flow path, so even if the defrost time is long In addition to preventing the deterioration of the heating quality, it has the effect of achieving a rapid defrost.
1 is a structural diagram showing a flow of a refrigerant by a binary refrigerant refrigeration cycle according to the prior art,
2 is a block diagram showing the entire piping of the heat pump interlocking hot water supply apparatus according to the present invention,
3 is a block diagram showing a refrigerant flow in the heating mode operation of the heat pump interlocking hot water supply apparatus according to the present invention,
4 is a block diagram showing the flow of the refrigerant during the defrost mode operation of the heat pump interlocking hot water supply apparatus according to the present invention,
5 is a block diagram schematically showing a control method of a heat pump interlocking hot water supply device according to the present invention.
Hereinafter, a preferred embodiment of a heat pump interlocking hot water supply device and a control method according to the present invention will be described in detail with reference to the accompanying drawings.
Figure 2 is a block diagram showing the entire piping of the heat pump interlocking hot water supply apparatus according to the present invention.
In the heat pump interlocking hot water supply device according to the present invention, as shown in FIG. 2, the
Here, the first refrigerant is a refrigerant having a boiling point different from that of the second refrigerant described later, and the first refrigerant is easier to be evaporated or compressed under a lower temperature and a lower pressure than the second refrigerant. In particular, in the present invention, a description will be made of R-410A in the case of the first refrigerant, and R-134a in the case of the second refrigerant. It is already known that R-134a evaporates or compresses at higher temperatures and pressures than R-410A.
As described above, the flow of the refrigerant circulated through the
When the
As such, the
The
In addition, the first expansion mechanism (135a) is a first condensing agent that is sufficiently condensed before entering the heat exchanger of any one of the indoor heat exchanger (160) or the outdoor heat exchanger (110) that evaporates after condensing by the condenser 1 serves to expand the refrigerant.
The refrigerant expanded by the
However, the
For example, the first user water may be floor heating water that circulates the indoor
On the other hand, since the heat exchanger that condenses the second refrigerant compressed by the
As described above, the first refrigerant circulating in the first
As shown in FIG. 2, the heating water, which is the first water of the first
In addition, the first
The
Meanwhile, in the heat pump interlocking hot water supply device according to the present invention, as shown in FIG. 2, the
Here, as described above, the
In addition, the second refrigerant compressed by the
However, it should be noted that the evaporator herein is not the
The
The second refrigerant compressed by the
Like the first
For example, the second user water may be hot water circulated for use in a bathroom or a kitchen, not floor heating water circulated for indoor space heating and floor heating. However, the second user heat exchanged immediately by the second
As such, a second cycle of the second refrigerant that is compressed by the
The hot
As shown in FIG. 2, the hot water is introduced into the
Meanwhile, in the heat pump interlocking hot water supply device according to the present invention, as shown in FIG. 2, the hot water supply of the second
Bypass
On the other hand, although the bypass
Bypass
The hot water inlet and outlet of the first open /
In this way, the inlet and outlet of the bypass
However, more preferably, the
The configuration indicated by the
On the other hand, as shown in Figures 2 to 4, the heat pump interlocking hot water supply apparatus according to the present invention, branched from the first refrigerant circulation portion so that the gas refrigerant of the first refrigerant is injected into the
Each of the first
The first
Here, although not shown in the drawing on the first
On the other hand, a preferred embodiment of the heat pump interlocking hot water supply apparatus according to the present invention, the hot water is supplemented through the bypass
The heating water
Such a heating
The operation of each of the heating mode operation and the cooling mode operation (or the defrost mode operation) of the heat pump interlocking hot water supply apparatus according to the present invention configured as described above will be described in detail with reference to the accompanying drawings. .
First, when the heating mode operation signal is input to the heat pump interlocking hot water supply apparatus according to the present invention in the case of a low winter outside temperature, as shown in Figure 3, the first compressed by the high pressure / high pressure by the compressor (105) The first refrigerant is switched to the first
At the same time, a portion of the first refrigerant compressed at high temperature / high pressure by the
Meanwhile, at the same time, the second refrigerant compressed at high temperature / high pressure by the
However, there is no problem in the heating mode operation of the heat pump interlocking hot water supply device at such a normal demand load value, but for example, when the demand load value of the heat pump interlocking hot water supply device is large, such as in a cold district, the consumer has a large demand. There is a problem that can decrease the satisfaction such as indoor floor heating. That is, it is preferable that the temperature of the heating water to perform indoor floor heating corresponding to the outside temperature is also increased, but there is a problem in that it is not possible to start an appropriate required load value by hitting the limit of the standard capacity of the
At this time, a preferred embodiment of the heat pump interlocking hot water supply apparatus according to the present invention, by opening the bypass
In addition, the heat pump interlocking hot water supply apparatus according to the present invention, by adjusting the opening degree of the first opening and closing
The operating principle of the heat pump interlocking hot water supply device according to the present invention as described above can be more usefully applied especially during the defrost mode operation of the hot water supply device.
For example, when defrosting of the
At this time, the first
Next, when the cooling mode operation signal is input to the heat pump interlocking hot water supply apparatus according to the present invention in the summer when the outdoor temperature is high, as shown in FIG. 4, the
At this time, the
Hereinafter, a preferred embodiment of a control method of a heat pump interlocking hot water supply device according to the present invention will be described in detail with reference to the accompanying drawings (particularly, FIG. 5).
FIG. 5 is a block diagram schematically illustrating a control method of a heat pump interlocking hot water supply device according to the present invention. Referring to FIG. 5, the heat pump interlocking hot water supply device according to the present invention may include a first refrigerant when power is applied. A first step S20 of circulating the first refrigerant circulation unit and operating the
Here, although the target heating temperature is generally set to rise in response to the decrease rate of the outside air temperature, the target heating temperature is not necessarily set as such, but the maximum heating temperature may be set, and a certain ratio is assumed that the outside air temperature falls. Note that the furnace is not set to raise the target heating temperature.
Here, the second step (S20), the target heating temperature is higher than the current heating temperature because the outside air temperature is low, the heating water heat exchanged with the first refrigerant compressed by the
However, the second step S20 of opening and closing the bypass
In the present invention, the common condition that the bypass
On the other hand, a preferred embodiment of the control method of the heat pump interlocking hot water supply apparatus according to the present invention, the heating water from the first water circulating unit to the second water circulating unit simultaneously with the opening and closing control of the bypass replenishment passage in the second step (S20) The method may further include a third step (not shown) of controlling the opening and closing of the heating water recovery flow path connecting the first water circulation part and the second water circulation part to recover the water.
Similarly, since the control of the third step is to be linked to the control of the bypass
The control method of the heat pump interlocking hot water supply device according to the present invention, the current heating temperature of the room at the time of defrost mode operation that requires defrosting operation of the outdoor heat exchanger in cold climate mode operation or the outdoor air temperature is rapidly reduced Since the hot water is replenished with heating water so as not to cause inconvenience due to the fall, the user's convenience and product reliability are improved.
In the above, the main configuration and operation of the heat pump interlocking hot water supply apparatus and a control method according to the present invention have been described in detail with reference to the accompanying drawings. However, the embodiment of the present invention is not limited to the above-described preferred embodiment, it is obvious that it can be carried out in various modifications and equivalent ranges by those skilled in the art. Therefore, the true scope of the present invention will be defined by the claims below.
104: gas-liquid separator 105: first compressor
107: first switching valve 110: outdoor heat exchanger
120: cascade heat exchanger 135: first, second expansion mechanism
140: second
150b: second water circulation 160: first heat exchanger
170: indoor floor heating unit 180: heat supply unit
210: heating water pump 220: second opening and closing valve
225: second opening and closing valve 300: bypass replenishment flow path
310: replenishment flow path pump 400: heating water recovery flow path
500: first refrigerant injection circuit 600: second refrigerant injection circuit
Claims (15)
A first water circulation unit 150a through which the heating water is circulated so as to perform indoor heating;
The second compressor 125 compresses the second refrigerant, the second condenser 140 condensing the second refrigerant compressed by the second compressor 125, and the second condenser 140 A second expansion mechanism 135b for expanding the second refrigerant, a second evaporator 120 for evaporating the second refrigerant expanded by the second expansion mechanism 135b, and again the second compressor 125 A second refrigerant circulation unit configured to circulate the second refrigerant;
A second water circulation part 150b through which the hot water flows to perform the hot water supply,
The first evaporator 160 is a first use heat exchanger 160 for mutual heat exchange between the first refrigerant and the heating water of the first water circulation unit 150a.
The second condenser 140 is a second use heat exchanger 140 for mutual heat exchange between the second refrigerant and the hot water of the second water circulation part 150b,
The second evaporator 120 is a cascade heat exchanger for exchanging a part of the first refrigerant discharged from the first compressor 105 and the second refrigerant discharged from the second compressor,
An outdoor heat exchanger (110) for evaporating the first refrigerant condensed by the first use heat exchanger (160) and the cascade heat exchanger (120);
The first water circulation unit 150a and the second water circulation unit 150b are connected to each other, and when it is necessary to increase the temperature of the first water circulation unit 150a during operation, the second water circulation unit ( Heat pump interlocking hot water supply apparatus further comprises a bypass replenishment flow path 300 for replenishing the hot water of the water supply (150b) with the heating water of the first water circulation (150a).
A heating water pump disposed in the first water circulation unit and configured to circulate the heating water of the first water circulation unit to the first use heat exchanger to exchange heat with the first refrigerant;
A hot water pump disposed in the second water circulation part and configured to circulate the hot water supply water to the second use heat exchanger to exchange heat with the second refrigerant;
The bypass replenishing flow passage may include an inlet end and an outlet end closer to the heating water pump and the hot water supply pump based on the heating water outlet of the first use heat exchanger and the hot water outlet of the second use heat exchanger. This is connected to the heat pump interlock hot water supply device.
The hot water flowing through the bypass replenishment flow passage,
The heat pump interlocking hot water supply device is supplemented with heating water by the heating water pump or the hot water supply pump, or supplemented with heating water by a replenishment passage pump disposed on the bypass replenishment passage.
The inlet end and the outlet end of the bypass supplement flow passage are connected to the first water circulation part and the second water circulation part by an on / off valve,
Each of the on and off valves is selectively opened and closed when the heat pump is operated in any one of the heating operation mode, cooling mode operation and defrost mode operation.
The on-off valve connected to the inlet end of the bypass refill passage,
And a heat pump interlocking hot water supply device configured to control the bypass replenishment flow path to be activated when the outside air temperature is lower than or equal to a first predetermined temperature during the heating mode operation of the heat pump interlocking hot water supply device or when the defrost mode operation of the heat pump interlocking hot water supply device is activated.
The first water circulation unit before the heating water flows into the first utilization heat exchanger and the second water circulation unit before the hot water supply flows into the second utilization heat exchanger, and the heating water replenished through the bypass replenishment passage And a heating water recovery passage for recovering the water circulation unit from the first water circulation unit to the second water circulation unit.
A first refrigerant circulation unit configured to circulate the first use heat exchanger and the outdoor heat exchanger to perform cooling / heating of the first refrigerant compressed by the first compressor;
A second refrigerant circulation unit configured to circulate the second utilization heat exchanger and the cascade heat exchanger to perform hot water supply of the second refrigerant compressed by the second compressor;
In a heating mode operation or a defrost mode operation of the heat pump interlocking hot water supply device, a first branch which is branched from the first refrigerant circulation part to be connected to the first compressor so that the gas refrigerant of the first refrigerant is injected into the first compressor. A heat pump further includes at least one of a refrigerant injection circuit or a second refrigerant injection circuit branched from the second refrigerant circulation part connected to the second compressor so that the gas refrigerant of the second refrigerant is injected into the second compressor. Peristaltic hot water supply device.
And the first refrigerant injection circuit and the second refrigerant injection circuit are activated when the outside air temperature is lower than or equal to the second predetermined temperature.
A first gas liquid separator and a second gas liquid separator for separating the refrigerant flowing through the first refrigerant injection circuit and the second refrigerant injection circuit into a liquid refrigerant and an air refrigerant are respectively the first refrigerant injection circuit and the second refrigerant injection circuit. Heat pump interlocking hot water supply device disposed in the.
A first water circulation unit 150a through which the heating water is circulated so as to perform indoor heating;
The second compressor 125 compresses the second refrigerant, the second condenser 140 condensing the second refrigerant compressed by the second compressor 125, and the second condenser 140 A second expansion mechanism 135b for expanding the second refrigerant, a second evaporator 120 for evaporating the second refrigerant expanded by the second expansion mechanism 135b, and again the second compressor 125 A second refrigerant circulation unit configured to circulate the second refrigerant;
A second water circulation part 150b through which the hot water flows to perform the hot water supply,
The first evaporator 160 is a first use heat exchanger 160 for mutual heat exchange between the first refrigerant and the heating water of the first water circulation unit 150a.
The second condenser 140 is a second use heat exchanger 140 for mutual heat exchange between the second refrigerant and the hot water of the second water circulation part 150b,
The second evaporator 120 is a cascade heat exchanger for exchanging a part of the first refrigerant discharged from the first compressor 105 and the second refrigerant discharged from the second compressor,
An outdoor heat exchanger (110) for evaporating the first refrigerant condensed by the first use heat exchanger (160) and the cascade heat exchanger (120);
The first water circulation unit 150a and the second water circulation unit 150b are connected to each other, and when it is necessary to increase the temperature of the first water circulation unit 150a during operation, the second water circulation unit ( In the heat pump interlocking hot water supply device further comprises a bypass replenishment flow path 300 for replenishing the hot water of 150b) with the heating water of the first water circulation unit (150a),
The first step (S10) for operating the first compressor 105 and the second compressor 125 so that the first refrigerant circulates the first refrigerant circulation section and the second refrigerant circulates the second refrigerant circulation section when power is applied, respectively. ;
After the first step (S10) by comparing the current heating temperature and the target heating temperature compared to the operation rate of the first compressor 105 and the second compressor 125 according to the outside air temperature, the second water circulation unit (150b) The first water circulator 150a and the second water to circulate the hot water and heat exchanged with the second refrigerant to supplement the first water circulation unit 150a with the heating water heat exchanged with the first refrigerant. Control method of the heat pump interlocking hot water supply device comprising a second step (S20) for opening and closing the bypass replenishment flow path (300) connecting the water circulation (150b).
The second step comprises:
The target heating temperature is higher than the current heating temperature, and the heating water heat exchanged with the first refrigerant compressed by the first compressor is lower than the hot water supply heat exchanged with the second refrigerant compressed by the second compressor. Control method of the heat pump interlocking hot water supply device which is the step of opening the bypass supplement flow passage.
The second step comprises:
And opening the bypass replenishment flow path when the first compressor is operated in a defrosting operation mode when the target heating temperature is lower than the current heating temperature.
Heating water connecting the first water circulating unit and the second water circulating unit to recover the heating water from the first water circulating unit to the second water circulating unit at the same time as the opening and closing control of the bypass replenishment passage in the second step. And a third step of opening and closing the recovery flow path.
The second step is the step of opening the bypass replenishment flow passage only when the second compressor is in operation, the control method of the heat pump interlocking hot water supply apparatus.
The third step is a step of opening the bypass replenishment flow passage and opening the heating water recovery flow passage only when the second compressor is operating.
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Cited By (1)
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CN104406330A (en) * | 2014-11-29 | 2015-03-11 | 江门市达能环保节能科技有限公司 | Heat pump system capable of recycling both gas and wastewater waste heat |
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KR101289828B1 (en) * | 2012-12-12 | 2013-07-24 | 하이에어코리아 주식회사 | Warm water system of cascade cycle heat pump |
CN113357692A (en) * | 2021-06-04 | 2021-09-07 | 中国科学院广州能源研究所 | Circulating water waste heat recovery system of thermal power plant |
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JP2005188879A (en) | 2003-12-26 | 2005-07-14 | Matsushita Electric Ind Co Ltd | Heat pump type hot water supplier |
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