KR100868262B1 - Rice bread premix manufacturing method using gelling of rice flour cell wall - Google Patents
Rice bread premix manufacturing method using gelling of rice flour cell wall Download PDFInfo
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- KR100868262B1 KR100868262B1 KR1020070081335A KR20070081335A KR100868262B1 KR 100868262 B1 KR100868262 B1 KR 100868262B1 KR 1020070081335 A KR1020070081335 A KR 1020070081335A KR 20070081335 A KR20070081335 A KR 20070081335A KR 100868262 B1 KR100868262 B1 KR 100868262B1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
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- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D10/00—Batters, dough or mixtures before baking
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/104—Fermentation of farinaceous cereal or cereal material; Addition of enzymes or microorganisms
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/109—Types of pasta, e.g. macaroni or noodles
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2200/00—Function of food ingredients
- A23V2200/20—Ingredients acting on or related to the structure
- A23V2200/222—Emulsifier
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Abstract
본 발명은 쌀가루 세포벽의 젤화를 이용한 쌀빵 프리믹스 제조방법에 관한 것으로 보다 상세하게는 쌀가루 전분의 세포벽에 존재하는 펜토산(pentosan) 또는 헤미셀룰로오스(hemicellulose)를 수용화하고 쌀가루전분의 세포벽을 복합효소(glucose oxidase)에 의해 생성된 과산화수소(H2O2)로 산화적 겔화시켜 발효가스가 외부로 방출되는 것을 차단하여 쌀빵의 부풀기를 개선하고 또한 난백과 식용유를 첨가하여 거칠고, 쉽게 부셔지는 조직감을 개선하여 밀가루 빵과 유사한 쌀빵의 용적밀도와 조밀한 기공을 얻을 수 있는 쌀빵 프리믹스의 제조방법에 관한 것 있다. The present invention relates to a method for preparing a rice bread premix using gelation of rice flour cell walls, and more specifically, pentosan or hemicellulose, which is present in the cell wall of rice flour starch, is solubilized and the cell wall of rice flour starch is synthesized (glucose). Oxidative gelation with hydrogen peroxide (H 2 O 2 ) produced by oxidase prevents the release of fermentation gas to the outside, thereby improving the swelling of rice bread and improving the coarse and easily broken texture by adding egg white and cooking oil. The present invention relates to a method for preparing a rice bread premix which can obtain a bulk density and dense pores of a rice bread similar to wheat bread.
Description
본 발명은 쌀가루 세포벽의 젤화를 이용한 쌀빵 프리믹스 제조방법에 관한 것으로 보다 상세하게는 쌀가루 전분의 세포벽에 존재하는 펜토산(pentosan) 또는 헤미셀룰로오스(hemicellulose)를 수용화하고 쌀가루전분의 세포벽을 복합효소(glucose oxidase)에 의해 생성된 과산화수소(H2O2)로 산화적 겔화시켜 발효가스가 외부로 방출되는 것을 차단하여 쌀빵의 부풀기를 개선하고 또한 난백과 식용유를 첨가하여 거칠고, 쉽게 부셔지는 조직감을 개선하여 밀가루 빵과 유사한 쌀빵의 용적밀도와 조밀한 기공을 얻을 수 있는 쌀빵 프리믹스의 제조방법에 관한 것 있다. The present invention relates to a method for preparing a rice bread premix using gelation of rice flour cell walls, and more specifically, pentosan or hemicellulose, which is present in the cell wall of rice flour starch, is solubilized and the cell wall of rice flour starch is synthesized (glucose). Oxidative gelation with hydrogen peroxide (H 2 O 2 ) produced by oxidase prevents the release of fermentation gas to the outside, thereby improving the swelling of rice bread and improving the coarse and easily broken texture by adding egg white and cooking oil. The present invention relates to a method for preparing a rice bread premix which can obtain a bulk density and dense pores of a rice bread similar to wheat bread.
쌀의 소비량이 감소하면서 쌀가루로 빵을 만들어 쌀의 소비를 촉진하고자 하였으나 빵 제조에 필수적인 발효과정에서 가스의 외부유출을 차단시켜 빵을 부풀게 하는 반죽의 망사조직을 형성시키지 못하여 쌀가루 단독으로는 밀가루 빵과 유사한 빵의 조직을 얻을 수 없다. 이는 밀에 포함되어 있는 11∼14% 정도인 글루텐이 존재하지 않기 때문이다. 따라서 밀에서 분리한 글루텐을 밀가루 글루텐 함량 보다 높은 약 20%를 쌀가루에 첨가하여 쌀빵을 제조하는 것이 일반적인 쌀빵 제조방법으로 이용되어 왔다. As the consumption of rice decreased, bread was made from rice flour to promote the consumption of rice, but flour was not used alone to make bread meshes to block the outflow of gas in the fermentation process, which is essential for bread production, to make bread swell. You can not get a tissue of bread similar to that. This is because 11 to 14% of the gluten in wheat is absent. Therefore, the manufacture of rice bread by adding about 20% of the gluten separated from wheat to wheat flour, which is higher than the flour gluten content, has been used as a general method of making rice bread.
종래 밀에서 분리한 글루텐을 첨가하여 제조한 쌀빵은 외관적으로는 밀가루빵과 거의 유사한 모양을 보이나 쌀 고유의 향기가 없을뿐더러 과잉으로 첨가되는 글루텐 냄새로 특이성을 없고, 밀가루 알레르기에 민감한 소비자에겐 밀가루 빵과 같은 현상을 유발하는 등 문제점을 내포하고 있다.Conventionally, rice bread made by adding gluten isolated from wheat looks similar to wheat bread in appearance, but it does not have the inherent scent of rice and the gluten smell that is added excessively, has no specificity, and is flour to consumers who are sensitive to flour allergy. It causes problems such as bread.
최근에 쌀가루만을 이용하여 밀가루 식빵과 유사한 조직을 형성하고 부드러운 촉감을 갖는 쌀 식빵을 얻기 위하여 셀룰로오즈 에스테르와 1종 이상의 검류를 이용하는 쌀빵 제조방법이 소개되고 있으나 발효가스의 외부차단을 위한 충분한 망사조직이 형성되지 못해 빵의 외형 크기 즉, 용적밀도가 낮고, 단면의 기공(氣孔)이 클뿐더러 균일하지 못하며 조직감이 떨어지고, 저장 중에 쉽게 노화되는 특성 때문에 상품성이 낮은 단점이 있다. 이러한 단점을 보완개선하기 위해 단백질과 크로스 링킹(cross linking) 효소인 트랜스글루타미나아제(transglutaminase)를 넣는 방법이 제안되었으나 이 방법에서는 주로 대두단백질, 유청(乳淸)단백질 및 카제인을 단백질 소스로 1∼6%와 분유 10% 넣어 주재료인 쌀가루 중량기준으로 단백질 함량을 최대 16%을 사용하고 있으며, 유지 역시 12∼13%를 첨가하여 쌀빵의 조직을 개선하고 있다. 또한, 쌀가루 제조도 수침과 탈수로 쌀알의 수분함량을 30∼50 %로 범위로 조절하여 습식 분쇄한 후에 40∼50℃의 항온기에서 6∼18시간 열 처리한 후 실온에서 풍건한 후 45-160매쉬 체로 제조한 쌀가루를 요구하고 있어, 쌀빵용 쌀가루 제조방법도 매우 복잡해, 많은 노동력과 시간이 요구되고 있다. Recently, a rice bread production method using cellulose ester and one or more types of gums has been introduced to form a tissue similar to flour bread using only rice flour, and to obtain a rice bread having a soft touch. However, there is a sufficient mesh structure for external blocking of fermentation gas. Since the bread is not formed, that is, the breadth density, the bulk density is low, the pores of the cross section is large, the uniformity, the texture is poor, and the merchandising property is low because of the characteristics that easily aging during storage. In order to make up for the shortcomings, a method of adding protein and a transglutaminase, a cross linking enzyme, has been proposed, but the soy protein, whey protein and casein are mainly used as protein sources. 1 ~ 6% and 10% milk powder are used to make the protein content up to 16% based on the weight of rice powder, which is the main ingredient, and 12 ~ 13% of fats and fats are also added to improve the structure of the bread. In addition, the production of rice flour was also adjusted to the water content of the rice grains in the range of 30 to 50% by immersion and dehydration, and then wet pulverized, and then heat-treated at a temperature of 40 to 50 ° C. for 6 to 18 hours, followed by air drying at room temperature, followed by 45 to 160 Since rice flour made from mash sieve is required, the method of making rice flour for rice bread is also very complicated, requiring a lot of labor and time.
이러한 방법으로 제조되는 기존의 글루텐이 없는 쌀빵 제조방법은 쌀가루 이외의 단백질 첨가물을 최대 16%이고 유지함량이 13% 정도로 순수한 쌀빵이라고 할 수 없고, 제품도 용적중 밀도가 낮아 크기가 밀빵의1/2 정도로 작으며 쉽게 노화하는 단점을 내포하고 있어 실용화되지 못하고 있다. The conventional gluten-free rice bread manufacturing method produced in this way is not a pure rice bread with up to 16% of protein additives other than rice flour and a holding content of 13%, and the product also has a low density in volume, making the size of wheat bread 1 / It is small to about 2 and has a disadvantage of easily aging, and thus has not been put to practical use.
본 발명은 종래 글루텐이 없는 쌀빵 제조방법에서 나타나는 문제점을 개선하기 하고자 연구를 거듭한 끝에 안출된 것으로써, 쌀빵 제조시 발생되는 발효가스의 외부차단을 위해 쌀가루전분의 세포벽을 복합효소로 산화적 젤화시켜 발효가스를 차단토록 하여 쌀빵의 부풀기를 해결하였다. 또한 난백, 설탕과 식용유(4% 내외)를 첨가하여 거칠고, 쉽게 부셔지는 조직감을 개선하여 밀가루 빵과 유사한 쌀빵의 용적밀도와 조밀한 기공의 쌀빵 프리믹스를 간편하게 제조하여 중소공장이나 가정에서 누구나 쉽게 쌀빵을 제조할 수 있도록 쌀빵 프로믹스를 제공하여 쌀의 소비촉진에 기여하는 데 있다.The present invention has been made after repeated studies to improve the problems appearing in the conventional gluten-free rice bread manufacturing method, oxidative gelation of the cell wall of rice flour starch with a complex enzyme for the external blocking of fermentation gas generated during rice production By blocking the fermentation gas to solve the swelling of the rice bread. In addition, by adding egg white, sugar and cooking oil (approximately 4%), it improves the rough and easily broken texture, making it easy to manufacture the bulk density of wheat bread and the dense pore of rice bread premix, making it easy for anyone in small and medium-sized factories or homes. It provides rice bread promix so that it can be manufactured to contribute to the promotion of rice consumption.
본 발명은 쌀가루전분의 세포벽을 복합효소로 산화적 젤화시켜 발효가스를 차단하도록 하여 쌀빵의 부풀기 문제를 해결하고, 난백, 설탕과 식용유를 첨가하여 거칠고 쉽게 부셔지는 조직감을 개선하여 밀가루 빵과 유사한 쌀빵의 용적밀도와 조밀한 기공을 얻을 수 있는 쌀빵 프리믹스 개발하는 데 있다. The present invention solves the problem of swelling of rice bread by blocking the fermentation gas by oxidative gelling the cell wall of rice flour starch with a complex enzyme, and improves the texture of coarse and easily broken by adding egg white, sugar and cooking oil, similar to wheat bread. It is to develop a rice bread premix that can get the bulk density and dense pores of rice bread.
본 발명은 글루텐을 첨가하지 않고, 복합효소에 의해 산화적으로 겔화시켜 발효가스가 외부로 방출되는 것을 차단하여 쌀빵의 부풀기를 개선하고, 전분분해효 소에 의하여 전분의 아밀로펙틴을 말토스 단위로 분해하여 망사조직을 형성시켜 노화현상을 지연시킨다. 또한 난백과 식용유를 첨가하여 거칠고 쉽게 부셔지는 조직감을 개선하여 밀가루 빵과 유사한 쌀빵의 용적밀도와 조밀한 기공을 얻을 수 있는 쌀빵 프리믹스를 제공하는 데 있다.The present invention improves the swelling of rice bread by blocking the release of fermentation gas to the outside by gluing oxidatively gelled by a complex enzyme without adding gluten, and decomposing amylopectin of starch by maltose unit by starch digestion enzyme. Delays aging by forming mesh tissue. In addition, the addition of egg whites and cooking oil improves the texture of rough and easily broken to provide a rice bread premix that can obtain the bulk density and dense pores of the bread similar to wheat bread.
본 발명은 쌀빵 프리믹스의 제조에 있어서, 쌀가루에 복합효소와 프리믹스를 첨가하고 교반하여 쌀전분의 세포벽을 분해시키고, 발효가스의 차단에 의해 쌀빵의 부풀기를 유지시킬 수 있는 쌀빵 프리믹스의 제조방법을 나타낸다.The present invention, in the preparation of the rice bread premix, adds a complex enzyme and premix to the rice flour and stirred to decompose the cell wall of the rice starch, and shows a method for producing a rice bread premix which can maintain the swelling of the rice bread by blocking the fermentation gas .
본 발명은 쌀가루에 복합효소와 프리믹스를 첨가하고 교반하여 쌀전분의 세포벽을 분해시키고, 발효가스의 차단에 의해 쌀빵의 부풀기를 유지시킬 수 있는 쌀빵 프리믹스의 제조방법을 나타낸다.The present invention shows a method for preparing a rice bread premix which can add a complex enzyme and a premix to rice flour and stir to decompose the cell walls of the rice starch and maintain the swelling of the rice bread by blocking fermentation gas.
본 발명은 쌀빵 프리믹스의 제조에 있어서, 쌀가루에 복합효소와 프리믹스를 첨가하여 650∼800rpm으로 10∼20분간 교반하여 쌀전분의 세포벽을 분해시키고, 발효가스의 차단에 의해 쌀빵의 부풀기를 유지시킬 수 있는 쌀빵 프리믹스의 제조방법을 나타낸다.The present invention, in the preparation of the rice bread premix, by adding a complex enzyme and premix to the rice flour and stirred for 10 to 20 minutes at 650 ~ 800rpm to decompose the cell wall of the rice starch, it is possible to maintain the swelling of the rice bread by blocking the fermentation gas A method of making a rice bread premix is shown.
본 발명은 쌀가루에 복합효소와 프리믹스를 첨가하여 650∼800rpm으로 10∼20분간 교반하여 쌀전분의 세포벽을 분해시키고, 발효가스의 차단에 의해 쌀빵의 부풀기를 유지시킬 수 있는 쌀빵 프리믹스의 제조방법을 나타낸다.The present invention adds a complex enzyme and premix to the rice flour and stirred for 10-20 minutes at 650 ~ 800rpm to decompose the cell wall of the rice starch, and a method for producing a rice bread premix which can maintain the swelling of the rice bread by blocking the fermentation gas Indicates.
본 발명의 쌀빵 프리믹스는 주재료인 쌀가루에 복합효소, 난백분, 식용유, 설탕과, 부재료인 효모, 유화제, 소금을 포함하여 구성될 수 있다.Rice bread premix of the present invention may be composed of the main ingredient in the rice flour complex enzyme, egg white powder, cooking oil, sugar, and an ingredient of yeast, emulsifier, salt.
본 발명의 쌀빵 프리믹스는 주재료인 쌀가루에 쌀가루 중량을 기준으로 복합효소 0.001∼0.05%, 난백분 1∼6%, 식용유 3∼9%, 설탕 6∼14%와, 부재료인 효모 1∼3%, 유화제 0.2∼1.0%, 소금 1∼3% 첨가하여 구성될 수 있다.The rice bread premix of the present invention is based on the weight of rice flour as the main ingredient, 0.001 to 0.05% of complex enzyme, 1 to 6% of egg white powder, 3 to 9% of cooking oil, 6 to 14% of sugar, and 1 to 3% of yeast as an ingredient, and an emulsifier. It can be comprised by adding 0.2 to 1.0% and 1 to 3% of salt.
상기에서 복합효소는 헤미셀루라제:글루코스 옥시다제, 자일라나제:글루코스 옥시다제, α-아밀라제:글루코스 옥시다제 또는 자일라나제:헤미셀루라제가 1:1∼8:1의 중량비로 구성된 것을 사용할 수 있다.In the above-described complex enzyme, hemicellulase: glucose oxidase, xylanase: glucose oxidase, α-amylase: glucose oxidase or xylanase: hemicellulase may be used in a weight ratio of 1: 1 to 8: 1. Can be.
상기에서 유화제는 소디움 스테아로일 락틸레이트(Sodium Stearoyl Lactylate) 또는 솔비탄 모노스테아레이트(Sorbitan monostearate) 중에서 선택된 어느 하나 이상을 사용할 수 있다. In the emulsifier may be used any one or more selected from sodium stearoyl lactylate (Sodium Stearoyl Lactylate) or sorbitan monostearate (Sorbitan monostearate).
본 발명의 쌀빵 프리믹스의 제조시 부재료인 건조효모, 유화제 및 식용유는 반죽시 혼합할 수 있다. Dry yeast, an emulsifier and cooking oil which are subsidiary materials in the preparation of the rice bread premix of the present invention may be mixed during kneading.
본 발명은 상기에서 언급한 방법에 의해 제조한 쌀빵 프리믹스를 포함한다.The present invention includes a rice bread premix prepared by the above-mentioned method.
이하 본 발명을 보다 상세히 설명하고자 한다.Hereinafter, the present invention will be described in more detail.
본 발명은 반죽 이후에 효모에 의해 발생되는 발효가스의 외부유출을 차단할 수 있도록 밀 글루텐(wheat gluten)과 유사한 망사조직을 얻을 수 있도록 쌀가루전분의 세포벽에 존재하는 펜토산(pentosan) 혹은 헤미셀룰로오스(hemicellulose)를 수용화시켜 산화적 젤화현상을 이용하였다. 또한 가스를 보유 또는 차단할 수 있는 반죽시스템을 특징으로 대부분의 글루텐을 첨가하지 않는 쌀빵 제조에 있어서 습식으로 분쇄한 쌀가루를 사용하는 것이 필수적이지만, 본 발명은 건식쌀가루를 포함한 모든 쌀가루에 적용할 수 있다.The present invention provides a pentosan or hemicellulose present in the cell wall of rice flour starch to obtain a mesh structure similar to wheat gluten to block external leakage of fermentation gas generated by yeast after kneading. ) Was used to oxidize gelation. In addition, it is essential to use wet milled rice flour in the manufacture of the most gluten-free rice bread, characterized by a dough system that can hold or block the gas, the present invention can be applied to all rice flour, including dry rice flour .
종래 글루텐이 포함되지 않은 쌀빵의 경우 부피가 작고 저장 중 쉽게 단단해지는 문제점을 가진 반면 본 발명에 의한 복합효소를 사용한 쌀빵의 경우 복합효소에 의해 전분의 주된 요소인 아밀로펙틴을 말토오스(maltose) 단위로 분해하여 노화의 속도를 억제하는 효과를 얻을 수 있다. 본 발명은 종래 쌀빵 제조에서 일반적으로 이용하던 버터를 식용유로 대체하여 트랜스 지방에 대한 문제를 해결하였고, 식용유 사용량도 종래의 1/2로 감소시켜 건강 지향적인 쌀빵 제조방법을 확립하였으며, 외관 및 조직감도 밀가루 빵과 유사한 쌀빵을 얻을 수 있다.The conventional gluten-free rice bread has a problem of being small in volume and easily hardened during storage, whereas in the rice bread using the complex enzyme according to the present invention, amylopectin, which is a major component of starch, is broken down into maltose units by the complex enzyme. The effect of suppressing the rate of aging can be obtained. The present invention solved the problem of trans fats by replacing butter commonly used in the manufacture of conventional rice bread with cooking oil, reducing the amount of cooking oil to 1/2 of the conventional method to establish a health-oriented rice bread manufacturing method, appearance and texture You can also get rice bread similar to wheat bread.
쌀빵 프리믹스는 쌀가루, 복합효소, 난백, 설탕, 유화제 등을 혼합하여 진공 포장하여 유통시키도록 고안하였으며, 쌀 식빵, 케익 및 쿠키 등 베이커리 제품 제조시 공장 또는 가정에서 누구나 쉽게 물을 가수하여 반죽한 후에 쌀빵을 구울 수 있다.Rice bread premix is designed to be distributed by vacuum packing by mixing rice powder, complex enzyme, egg white, sugar, emulsifier, etc.In the manufacture of bakery products such as rice bread, cake and cookies You can bake the bread.
<쌀빵 프리믹스의 제조> <Preparation of rice bread premix>
시중에 유통되는 쌀을 습식 또는 건식으로 100∼120매쉬 입도로 분쇄하여 함수율 13∼15% 정도인 쌀가루를 제조하여 주원료로 한다. 주원료인 쌀가루의 중량기준으로 복합효소(hemicellulase:glucose oxidase, xylanase :glucose oxidase, α-amylase:glucose oxidase, xylanase:hemicellulase)는 Enzyme Tech에서 제공받아 1:1 ∼ 8:1의 비율로 하여 0.001∼0.05% 사용하고, 부드러움과 촉촉한 조직을 갖도록 난백파우더를 1∼6%, 그리고 트랜스 지방이 없는 식용유를 3∼9%, 설탕 6∼14%를 기본배합으로 하여, 건조효모 1∼3%, 소금 1∼3% 및 유화제 0.2∼1.0% 등을 시중에서 구입하여 사용한다. 단 이때의 각 재료의 비율은 쌀가루의 중량을 기준으로 하며, 목적하는 제품의 종류에 따라 소량 일정비율 넣고 교반기에서 충분히 혼합시켜 쌀빵 프리믹스를 제조한다. Commercially available rice is pulverized by wet or dry to 100 to 120 mesh particle size to prepare rice flour having a water content of about 13 to 15% as a main raw material. Complex enzymes (hemicellulase: glucose oxidase, xylanase: glucose oxidase, α-amylase: glucose oxidase, xylanase: hemicellulase) are based on the weight of rice flour, which is the main raw material. 1% to 6% of egg white powder, 3% to 9% of cooking oil without trans fat, 6% to 14% of sugar are used as basic formulations, and 1% to 3% of dry yeast, and salt is used to make it soft and moist. 1-3%, emulsifier 0.2-1.0%, etc. are commercially available and used. However, the ratio of each material at this time is based on the weight of the rice flour, and put a small amount in proportion according to the type of the desired product to sufficiently mix in a stirrer to prepare a rice bread premix.
<쌀빵의 제조예><Production example of rice bread>
쌀빵 프리믹스 교반기(Kichen aid K5SS)를 이용하여 저속교반에서 1분간 교반 후 발효시간을 단축하기 위해 40℃ 정도의 따뜻한 물을 첨가하여 30초 정도 중속교반 후에 10분간 고속 교반한 다음 1차 반죽을 한다.After stirring for 1 minute in a slow stirring using a rice bread premix stirrer (Kichen aid K5SS), in order to shorten the fermentation time, warm water of 40 ℃ is added. .
1차 반죽을 용기에 담아 온도 30∼40℃, 상대습도 75∼80%의 발효기에 넣어 30∼60분간 1차 발효시킨다.The primary dough is placed in a container and placed in a fermenter having a temperature of 30 to 40 ° C. and a relative humidity of 75 to 80%, and then fermented for 30 to 60 minutes.
상기의 1차 발효한 것을 4∼6분간 2차 반죽을 실시한다.The secondary fermentation is carried out for 4 to 6 minutes in the above fermented primary.
상기의 2차 반죽을 분할하여 빵틀에 담아 온도 30∼40℃, 상대습도 80∼95%인 조건에서 10∼50분간 2차 발효를 실시한다. 상기에서 2차 반죽물의 분할은 500g 단위, 바람직하게는 300g 단위, 보다 바람직하게는 100g 단위로 분할할 수 있다. The secondary batter is divided into pieces and placed in a baking pan and subjected to secondary fermentation for 10 to 50 minutes under conditions of a temperature of 30 to 40 ° C and a relative humidity of 80 to 95%. In the above, the secondary dough may be divided into 500 g units, preferably 300 g units, and more preferably 100 g units.
빵틀에 넣어진 2차 발효물을 오븐에 넣어 195∼205℃에서 3∼10분간 구워 윗면에 버터 칠을 한 후 온도를 170∼1850℃으로 낮춰 10∼20분 동안 구워 쌀 식빵을 만든다. Put the second fermented product in the oven in the oven and bake for 3-10 minutes at 195 ~ 205 ℃, and then top the butter and lower the temperature to 170 ~ 1850 ℃ to make rice bread for 10 to 20 minutes.
한편 상기에서 1차 반죽이 끝난 후 1차 발효 및 2반 반죽을 생략하고, 1차 반죽물을 분할하여 식빵 틀에 담고 앞의 조건과 동일한 1차 발효 후에 오븐에 넣어 식빵을 제조할 수 있다(도 1 참조). Meanwhile, after the first dough is finished, the first fermentation and the second half dough are omitted, and the first dough is divided into the bread molds and put into the oven after the first fermentation same as the above conditions to produce the bread ( See FIG. 1).
상기에서 빵틀의 일예로 17×8×5cm인 식빵틀을 사용할 수 있다.As an example of the breadboard in the above it can be used a breadboard of 17 × 8 × 5 cm.
<프리믹스의 혼합속도><Mixing speed of premix>
쌀빵 프리믹스의 혼합에 이용된 교반기(Kichen aid K5SS)의 교반패널 회전속도를 저속(150∼200rpm) 및 고속(650∼800rpm)으로 구분하여 각각 10분 동안 실시하여 쌀빵의 외관, 비용적 및 단면 기공 상태를 분석한 결과, 저속교반에 비해 고속교반한 실험구가 비용적이 크고 단면의 기공도 조밀한 상태로 우수하였다. 이는 주재료와 각종 부재료를 충분히 교반해야 보다 좋은 품질을 얻을 수 있어 고속교반과 교반시간을 10분 정도로 하는 것이 우수하였다(제 2도).Rotation speed of the stirring panel (Kichen aid K5SS) used for mixing the rice bread premix is divided into low speed (150-200rpm) and high speed (650-800rpm) for 10 minutes, respectively, to make the appearance, cost and cross-section pore of the rice bread. As a result of analyzing the state, the experimental zone which was agitated at high speed compared to the low speed agitation was cost-effective and the pore of the cross section was excellent. This is better when the main material and various subsidiary materials are sufficiently stirred to obtain better quality, so that the high speed stirring and the stirring time are about 10 minutes (FIG. 2).
<난(卵)부위별 효과><Effect of each part>
난백, 난황 및 전란으로 구분하여 3∼6%씩을 첨가하여 표면과 단면의 특성을 제3도로 나타냈다. 난의 부위별 쌀빵의 크기, 외관 및 단면의 기공형성 상태 등을 종합적으로 비교한 결과, 표 1과 같이 난백 3%를 첨가한 실험구가 외관, 크기 및 조직감이 가장 좋은 것으로 나타났다.The characteristics of the surface and the cross-section were shown in FIG. 3 by adding 3 to 6% each of egg white, egg yolk and egg eggs. As a result of comprehensive comparison of the size, appearance and pore formation state of the rice bread by the part of the egg, the experimental group to which 3% egg white was added as shown in Table 1 showed the best appearance, size and texture.
표 1. 난의 부위별 쌀빵의 부피 및 조직특성Table 1. Volume and tissue characteristics of rice bread by egg parts
abc; 동일한 알파벳은 동일 수준임 abc ; Same alphabet is the same level
<유화제 효과> <Emulsifier effect>
본 발명에 사용된 유화제 중에 sorbitan monostearate 1%(쌀가루 중량기준)를 첨가함으로써 Sodium Stearoyl Lactylate(SSL)첨가시 보다 외관특성상 부피는 크게 나타났으며. 물성특성에 따라 경도는 낮게 나타났다(표 2). 즉, SSL보다 sorbitan monosteate을 첨가하여 최종 제빵의 기공이 작고 균일하게 분포되게 함으로써 부피가 증대되고 crumb 조직이 부드럽게 된다. By adding 1% sorbitan monostearate (based on the weight of rice flour) in the emulsifier used in the present invention, the volume was larger in appearance than when Sodium Stearoyl Lactylate (SSL) was added. The hardness was low depending on the physical properties (Table 2). That is, by adding sorbitan monosteate rather than SSL, the pores of the final bakery are distributed evenly and the volume is increased and the crumb tissue is softened.
표 2. 유화제에 따른 쌀식빵의 영향Table 2. Effect of Rice Bread on Emulsifiers
이하 본 발명의 내용을 실시예 및 시험예를 통하여 구체적으로 설명한다. 그러나, 이들은 본 발명을 보다 상세하게 설명하기 위한 것으로 본 발명의 권리범위가 이들에 의해 한정되는 것은 아니다.Hereinafter, the content of the present invention will be described in detail through examples and test examples. However, these are intended to explain the present invention in more detail, and the scope of the present invention is not limited thereto.
<실시예 1-3><Example 1-3>
시중에 유통되는 쌀을 110±10메쉬(mesh)로 분쇄하여 함수율 14±1%의 쌀가루를 얻는다. Commercially available rice is ground to 110 ± 10 mesh to obtain rice flour having a water content of 14 ± 1%.
상기 쌀가루와 쌀가루 100중량%를 기준으로 복합효소(헤미셀루라제:글루코스 옥시다제=4:1의 중량비) 0.0018%와 난백파우더 1∼6%, 식용유 3∼9%, 건조효모 1∼3%, 설탕 6∼14%, 소금 1∼3% 및 유화제(솔비탄 모노스테아레이트(Sorbitan monostearate)) 0.2∼1.0%를 넣고 교반기에서 충분히 혼합시켜 쌀빵 프리믹스를 제조하였다. 쌀빵 프리믹스 교반기로 저속으로 1분간 교반시킨 후, 40℃의 온수를 첨가하여 30초간 중속으로 교반시킨 후, 10분간 고속으로 교반하여 1차 반죽으로 한 후, 35±5℃, 상대습도 77.5±2.5%의 발효기에 넣어 45분간 발효시킨 후 5분간 2차 반죽한 후, 300g으로 분할하여 식빵 틀에 담아 온도 35℃, 상대습도 87.5±7.5%인 조건에서 30분간 2차 발효한 후 오븐에 넣어 200±5℃에서 5분간 구워 윗면에 버터 칠을 한 후 온도 175℃로 낮춰 15분 동안 구워 쌀 식빵을 만든다. 또는 1차 반죽이 끝난 후, 즉시 300g으로 분할하여 식빵 틀에 담고 상기와 동일하게 1차 발효 후에 오븐에 넣어 식빵을 제조하였다. 0.0018% of complex enzyme (hemicellulase: glucose oxidase = 4: 1 weight ratio), egg white powder 1-6%, cooking oil 3-9%, dry yeast 1-3%, 6-14% of sugar, 1-3% of salt and 0.2-1.0% of an emulsifier (Sorbitan monostearate) were added and mixed in a stirrer to prepare a rice bread premix. Stir at low speed for 1 minute with a rice bread premix stirrer, add hot water at 40 ° C., stir at medium speed for 30 seconds, and stir at high speed for 10 minutes to form a primary dough, then 35 ± 5 ° C., relative humidity 77.5 ± 2.5 After fermentation in 45% fermenter for 45 minutes, and then kneaded for 2 minutes for 5 minutes, divided into 300g, put into bread molds, fermented for 30 minutes at a temperature of 35 ° C. and a relative humidity of 87.5 ± 7.5%, and then put in an oven 200 Bake for 5 minutes at ± 5 ℃, butter the top, and lower to 175 ℃ for 15 minutes to make rice bread. Or after the end of the first dough, immediately divided into 300g and put in a bread mold in the same manner as above to put in the oven after the first fermented bread was prepared.
표 3. 프리믹스 구성비율(단위 : 중량%) 및 쌀빵의 식감Table 3. Composition ratio of premix (unit: weight%) and texture of rice bread
* E; Excellent, VG; Very Good, G; Good, NB; Not Bad * E; Excellent, VG; Very Good, G; Good, NB; Not bad
한편, 도면을 통해서 본 발명을 보다 상세히 설명하고자 한다.On the other hand, the present invention will be described in more detail with reference to the drawings.
도 2는 쌀 식빵 제조시 반죽의 교반속도에 따른 쌀 식빵을 비교한 사진으로서 (a)는 고속(650rpm)으로 반죽을 교반하여 제조한 쌀 식빵의 측면사진(비용적 4.00ml/g)이고, (b)고속으로 반죽을 교반하여 제조한 쌀 식빵의 단면사진이고, (c)는 저속(200rpm)으로 반죽을 교반하여 제조한 쌀 식빵의 측면사진(비용적 3.55ml/g)이고, (d)는 저속으로 반죽을 교반하여 제조한 쌀 식빵의 단면사진이다. 2 is a photograph comparing the rice bread according to the stirring speed of the dough during the manufacture of rice bread (a) is a side view of the rice bread prepared by stirring the dough at a high speed (650rpm) (cost 4.00ml / g), (b) is a cross-sectional photograph of a rice bread prepared by stirring the dough at high speed, (c) is a side view (cost 3.55ml / g) of the rice bread prepared by stirring the dough at a low speed (200rpm), (d ) Is a cross-sectional photograph of rice bread prepared by stirring the dough at low speed.
도 3은 쌀 식빵 제조시 버터를 사용한 쌀 식빵과 식용유를 사용한 쌀 식빵을 비교한 사진으로서 (a)는 버터(5.3%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 3.72ml/g)이고, (b)는 이의 단면사진이다. (c)는 버터(4.0%, 쌀가루 중 량기준)를 사용한 쌀 식빵의 측면사진(비용적 3.65ml/g)이고, (d)는 이의 단면사진이다. (e)는 식용유(5.3%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 4.03ml/g)이고, (f)는 이의 단면사진이다. (g)는 식용유(4.0%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 4.61ml/g)이고, (h)는 이의 단면사진이다. 3 is a photograph comparing rice bread using butter and rice bread using cooking oil when preparing rice bread (a) is a side view of rice bread using butter (5.3%, based on rice flour weight) (cost 3.72ml / g) (B) is a cross-sectional photograph thereof. (c) is a side photograph (cost 3.65 ml / g) of rice bread using butter (4.0%, based on rice flour weight), and (d) is a cross-sectional photograph thereof. (e) is a side photograph (expensive 4.03 ml / g) of rice bread using cooking oil (5.3%, by weight of rice flour), and (f) is a cross-sectional photograph thereof. (g) is a side photograph (cost 4.61 ml / g) of rice bread using cooking oil (4.0%, based on rice flour weight), and (h) is a cross-sectional photograph thereof.
도 4는 쌀 식빵 제조시 복합효소의 사용유무에 따른 쌀 식빵을 나타낸 사진으로서 (a)는 복합효소를 사용하지 않은 대조구 쌀 식빵의 외관을 나타낸 사진(specific volume 3.59ml/g)이고, (b)는 이의 단면을 나타낸 사진이다. (c)는 복합효소(헤미셀루라제:글루코스 옥시다제)를 사용한 실험군 쌀 식빵의 외관을 나타낸 사진(specific volume 4.35ml/g)이고, (d)는 이의 단면을 나타낸 사진이다. 도 4(a) 내지 도 4(d)에서처럼 본 발명의 복합효소(헤미셀루라제:글루코스 옥시다제)를 포함하는 쌀빵 프리믹스로 제조한 실험군 쌀 식빵은 복합효소를 사용하지 않은 대조구 쌀 식빵에 비해 외관 및 단면이 우수하고, 소비자로 하여금 먹고 싶다는 느낌을 더 줄 수 있음을 알 수 있다.4 is a photograph showing the rice bread according to the presence or absence of the use of the complex enzyme in the manufacture of rice bread (a) is a photograph showing the appearance of the control rice bread without using the complex enzyme (specific volume 3.59ml / g), (b ) Is a photograph showing its cross section. (c) is a photograph showing the appearance of the experimental group rice bread using a complex enzyme (hemicellulase: glucose oxidase) (specific volume 4.35 ml / g), and (d) is a photograph showing its cross section. 4 (a) to 4 (d), the experimental group rice bread prepared with the rice bread premix containing the complex enzyme of the present invention (hemicellulase: glucose oxidase) was compared to the control rice bread without the complex enzyme. And the cross section is excellent, it can be seen that the consumer can give more feeling to eat.
도 5는 본 발명의 쌀빵 프리믹스로 제조한 쌀 식빵에 있어서, 쌀빵 프리믹스에 난백 첨가군, 난백+복합효소(헤미셀룰라제:글루코스 옥시다제) 첨가군, 난백 및 복합효소의 무첨가군에 따른 쌀 식빵의 저장기간에 따른 경도 변화를 나타낸 그래프이다. 도 5에서처럼 난백 및 복합효소의 무첨가군의 재료로 제조한 쌀 식빵은 저장기간이 증가함에 따라 경도가 증가하여 제품의 관능성이 감소하나, 본 발명의 난백 및 복합효소를 첨가한 쌀빵 프리믹스로 제조한 제품은 저장기간이 증가함에 따라 무첨가군에 비해 경도의 증가가 낮아 관능성 감소를 방지하여 제품의 저장성 향 상에 기여할 수 있음을 알 수 있다.5 is a rice bread prepared in the rice bread premix of the present invention, the rice white bread according to the egg white addition group, egg white + complex enzyme (hemicellulase: glucose oxidase) addition group, egg white and complex enzyme-free group in the rice bread premix This is a graph showing the change of hardness according to storage period. As shown in Fig. 5, the rice bread prepared from the ingredients of the egg white and the complex enzyme-free group is increased in hardness as the storage period increases, so that the functionality of the product decreases, but the rice bread premix is added with the egg white and the complex enzyme of the present invention. It can be seen that one product can increase the shelf life of the product by preventing the decrease in sensory properties due to the increase in hardness compared to the no addition group as the storage period increases.
도 6은 본 발명의 쌀빵 프리믹스와 밀가루로 제조한 케이크(cake)를 비교한 사진으로서 (a)는 본 발명의 쌀빵 프리믹스로 제조한 케이크를 나타낸 사진이고, (b)는 밀가루로 제조한 케이크를 나타낸 사진이다. 도 6에서처럼 본 발명의 쌀빵 프리믹스로 제조한 케이크가 밀가루를 제조한 케이크에 비해 외관이 우수하고, 소비자에게 먹고 싶다는 느낌을 더 줄 수 있음을 알 수 있다.6 is a photograph comparing the cake prepared with the rice bread premix and the flour of the present invention (a) is a photograph showing the cake made with the rice bread premix of the present invention, (b) is a cake made with flour The picture shown. As shown in Figure 6 it can be seen that the cake prepared with the rice bread premix of the present invention is superior in appearance than the cake made with flour and may give the consumer a feeling to eat more.
상기 도 2 내지 도 6을 통해서 알 수 있듯이 본 발명의 쌀빵 프리믹스로 제조한 제품은 종래 밀가루를 재료로 하는 제품에 비해 그 특성이 우수함을 알 수 있다.As can be seen through the Figure 2 to 6 it can be seen that the product manufactured by the rice bread premix of the present invention is superior in its properties as compared to products made of conventional flour.
상술한 바와 같이, 본 발명의 바람직한 실시예를 참조하여 설명하였지만 해당 기술 분야의 숙련된 당업자라면 하기의 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다. As described above, although described with reference to a preferred embodiment of the present invention, those skilled in the art will be variously modified and modified within the scope of the present invention without departing from the spirit and scope of the invention described in the claims below. It will be appreciated that it can be changed.
본 발명은 글루텐을 첨가하지 않고, 복합효소에 의해 산화적으로 겔화시켜 발효가스가 외부로 방출되는 것을 차단하여 쌀빵의 부풀기를 개선하고, 전분분해효소에 의하여 전분의 아밀로펙틴을 말토스 단위로 분해하여 망사조직을 형성시켜 노화현상을 지연시켜 밀가루 빵과 유사한 쌀빵의 용적밀도와 조밀한 기공을 얻을 수 있는 쌀빵 프리믹스를 제공하여 제과분야의 기술향상에 일조할 수 있다.The present invention does not add gluten, oxidatively gelled by a complex enzyme to block the release of fermentation gas to the outside to improve the swelling of rice bread, and by decomposing amylopectin of starch by maltose unit by starch degrading enzyme It can contribute to the improvement of technology in the confectionery field by providing a rice bread premix which can form the mesh structure and delay the aging phenomenon to obtain the bulk density and dense pores of the rice bread similar to the wheat bread.
도 1는 쌀빵 프리믹스를 이용한 쌀 식빵의 제조공정도이다.1 is a manufacturing process of the rice bread using a rice bread premix.
도 2는 쌀 식빵 제조시 반죽의 교반속도에 따른 쌀 식빵을 비교한 사진으로서 (a)는 고속(650rpm)으로 반죽을 교반하여 제조한 쌀 식빵의 측면사진(비용적 4.00ml/g)이고, (b)고속으로 반죽을 교반하여 제조한 쌀 식빵의 단면사진이고, (c)는 저속(200rpm)으로 반죽을 교반하여 제조한 쌀 식빵의 측면사진(비용적 3.55ml/g)이고, (d)는 저속으로 반죽을 교반하여 제조한 쌀 식빵의 단면사진이다. 2 is a photograph comparing the rice bread according to the stirring speed of the dough during the manufacture of rice bread (a) is a side view of the rice bread prepared by stirring the dough at a high speed (650rpm) (cost 4.00ml / g), (b) is a cross-sectional photograph of a rice bread prepared by stirring the dough at high speed, (c) is a side view (cost 3.55ml / g) of the rice bread prepared by stirring the dough at a low speed (200rpm), (d ) Is a cross-sectional photograph of rice bread prepared by stirring the dough at low speed.
도 3은 쌀 식빵 제조시 버터를 사용한 쌀 식빵과 식용유를 사용한 쌀 식빵을 비교한 사진으로서 (a)는 버터(5.3%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 3.72ml/g)이고, (b)는 이의 단면사진이다. (c)는 버터(4.0%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 3.65ml/g)이고, (d)는 이의 단면사진이다. (e)는 식용유(5.3%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 4.03ml/g)이고, (f)는 이의 단면사진이다. (g)는 식용유(4.0%, 쌀가루 중량기준)를 사용한 쌀 식빵의 측면사진(비용적 4.61ml/g)이고, (h)는 이의 단면사진이다. 3 is a photograph comparing rice bread using butter and rice bread using cooking oil when preparing rice bread (a) is a side view of rice bread using butter (5.3%, based on rice flour weight) (cost 3.72ml / g) (B) is a cross-sectional photograph thereof. (c) is a side photograph (cost 3.65 ml / g) of rice bread using butter (4.0%, by weight of rice flour), and (d) is a cross-sectional photograph thereof. (e) is a side photograph (expensive 4.03 ml / g) of rice bread using cooking oil (5.3%, by weight of rice flour), and (f) is a cross-sectional photograph thereof. (g) is a side photograph (cost 4.61 ml / g) of rice bread using cooking oil (4.0%, based on rice flour weight), and (h) is a cross-sectional photograph thereof.
도 4는 쌀 식빵 제조시 복합효소의 사용유무에 따른 쌀 식빵을 나타낸 사진으로서 (a)는 복합효소를 사용하지 않은 대조구 쌀 식빵의 외관을 나타낸 사진(specific volume 3.59ml/g)이고, (b)는 이의 단면을 나타낸 사진이다. (c)는 복합효소(헤미셀루라제:글루코스 옥시다제)를 사용한 실험군 쌀 식빵의 외관을 나타낸 사진(specific volume 4.35ml/g)이고, (d)는 이의 단면을 나타낸 사진이다. 4 is a photograph showing the rice bread according to the presence or absence of the use of the complex enzyme in the manufacture of rice bread (a) is a photograph showing the appearance of the control rice bread without using the complex enzyme (specific volume 3.59ml / g), (b ) Is a photograph showing its cross section. (c) is a photograph showing the appearance of the experimental group rice bread using a complex enzyme (hemicellulase: glucose oxidase) (specific volume 4.35 ml / g), and (d) is a photograph showing its cross section.
도 5는 본 발명의 쌀빵 프리믹스로 제조한 쌀 식빵에 있어서, 쌀빵 프리믹스 에 난백 첨가군, 난백+복합효소(헤미셀룰라제:글루코스 옥시다제) 첨가군, 난백 및 복합효소의 무첨가군에 따른 쌀 식빵의 저장기간에 따른 경도 변화를 나타낸 그래프이다. 5 is a rice bread prepared in the rice bread premix of the present invention, the rice white bread according to the egg white addition group, egg white + complex enzyme (hemicellulose + glucose oxidase) addition group, egg white and complex enzyme-free group in the rice bread premix This is a graph showing the change of hardness according to storage period.
도 6은 본 발명의 쌀빵 프리믹스와 밀가루로 제조한 케이크(cake)를 비교한 사진으로서 (a)는 본 발명의 쌀빵 프리믹스로 제조한 케이크를 나타낸 사진이고, (b)는 밀가루로 제조한 케이크를 나타낸 사진이다.6 is a photograph comparing the cake prepared with the rice bread premix and the flour of the present invention (a) is a photograph showing the cake made with the rice bread premix of the present invention, (b) is a cake made with flour The picture shown.
Claims (6)
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Citations (5)
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JPH0568468A (en) * | 1991-07-15 | 1993-03-23 | Noriyuki Sugawara | Rice flour for bread dough |
KR960020690A (en) * | 1994-12-29 | 1996-07-18 | 김정재 | Manufacturing method of rice bread |
KR100425771B1 (en) | 2003-02-27 | 2004-04-01 | 주식회사 대두식품 | A method for manufacturing prepared mix using rice powder as a main ingredient |
JP2004208561A (en) * | 2002-12-27 | 2004-07-29 | National Agriculture & Bio-Oriented Research Organization | Rice flour bread manufacturing method and breads obtained by this method |
KR20070028756A (en) * | 2005-09-07 | 2007-03-13 | 김행중 | Manufacturing method of bread with rice as main ingredient, bread produced thereby and premix powder for making this bread |
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Publication number | Priority date | Publication date | Assignee | Title |
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JPH0568468A (en) * | 1991-07-15 | 1993-03-23 | Noriyuki Sugawara | Rice flour for bread dough |
KR960020690A (en) * | 1994-12-29 | 1996-07-18 | 김정재 | Manufacturing method of rice bread |
JP2004208561A (en) * | 2002-12-27 | 2004-07-29 | National Agriculture & Bio-Oriented Research Organization | Rice flour bread manufacturing method and breads obtained by this method |
KR100425771B1 (en) | 2003-02-27 | 2004-04-01 | 주식회사 대두식품 | A method for manufacturing prepared mix using rice powder as a main ingredient |
KR20070028756A (en) * | 2005-09-07 | 2007-03-13 | 김행중 | Manufacturing method of bread with rice as main ingredient, bread produced thereby and premix powder for making this bread |
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CN111574257A (en) * | 2020-05-25 | 2020-08-25 | 李娟� | Rapid fermentation decomposition agent for livestock and poultry manure treatment and preparation method thereof |
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