KR100530899B1 - Cleaner composition - Google Patents

Abstract

The present invention relates to a cleaning composition, and more particularly, to a cleaning composition comprising a water-insoluble nonvolatile silicone conditioning component, a pearling agent, and a quaternary ammonium salt as a stabilizer.

The present invention has excellent conditioning effect and appearance gloss, while maintaining a viscosity at low temperature (-5 ℃ to 15 ℃) and high temperature (35 ℃ to 50 ℃) 30 ps to 250ps excellent stability against phase separation phenomenon To provide a composition.

Description

Cleaner composition {CLEANER COMPOSITION}

[Industrial use]

The present invention relates to a cleaning composition, and more particularly, to a water-insoluble nonvolatile silicone conditioning component, a pearling agent, and a stabilizer having excellent conditioning effect and appearance gloss and excellent stability to phase separation. A detergent composition comprising a quaternary ammonium salt.

[Private Technology]

Detergents are used to remove contaminants attached to hair and skin to keep them clean and beautiful. The most basic function is to protect hair and skin from external damage and to make it easy to clean. However, recently, in order to improve the appearance of the contents of the detergent, or to look luxurious, it contains a substance such as a whitening agent, a pearl agent, and a pigment, and in addition to the basic functions and aesthetics of the appearance, the stability of the contents, in particular, over time Stability is an essential requirement. Therefore, various studies have been attempted to obtain a cleaning composition having excellent cleaning performance and excellent appearance and excellent stability.

For example, hair is easily damaged by various physical, chemical, and environmental damage factors, resulting in increased roughness, loss of gloss, and deterioration of softness and softening effect. In addition, as the frictional force of the hair surface is increased, it becomes difficult to clean the hair during the hair care process due to combing and the like, and problems such as hair is cut off or cracked occur.

In order to solve this problem, various conditioning ingredients, hair or skin protection ingredients are added to the shampoo cleaner, and these are widely used as water-insoluble non-volatile silicone oils, silicone fluorides, polymer silicone gums and their Derivatives and the like. However, these silicone components have a problem that it is very difficult to stabilize the compatibility in the shampoo composition compared to the effect, and the same tendency also appears in the cleaning composition for cleaning the skin.

Methods for imparting pearl luster to the cleaning composition include (1) pearlescent pigments, pigments such as iron oxides, metal salts, titanium dioxide and zinc oxide, (2) mono or diesters of ethylene glycol, propylene glycol, A method of imparting a pearly feeling to the contents by using a pearl obtained by directly melting a pulsing agent such as oligomeric alkylene glycol into the contents and then cooling and crystallizing it, (3) anion and non-ion to the pulsing agent described in the method (2) above. A method of preparing a pearl composition called “Cold Pearl” or “Liquid Pearl” by mixing only components such as a surfactant and injecting the same into a detergent composition may be added. Among them, a method using “cold pearl” or “liquid pearl” is mainly used in consideration of appearance, stability, and economical efficiency.

The detergent composition is most suitable to have a viscosity of about 40 ps to 90 ps at 25 ℃ in consideration of various aspects such as the maintenance and stability of the formulation and usability, and the decrease and rise of viscosity does not occur remarkably even at temperatures other than room temperature. Should not. In particular, in the case of detergent compositions containing water-insoluble components, the viscosity of the contents is very closely related to the stability and separation phenomena of these water-insoluble components.

In the case of using a pearl agent directly in a detergent composition including a conventional silicone conditioning component or using a liquid pearl to impart a pearly appearance to the contents, the detergent composition has a very excellent appearance of pearl luster and has a room temperature (15 ° C. to 35 ° C.). The viscosity at also represents a suitable state of about 40 ps to about 90 ps. However, at temperatures other than room temperature, the viscosity tends to drop below 30 ps (Brookfield, # 3, 12 rpm), so phase separation easily occurs, and within a few days, silicon, which is a water-insoluble nonvolatile conditioning component, is separated and used as a cleaning agent. Utility falls. In addition, when the viscosity is excessively higher than 250 ps, the stability is very good, but when pour out the contents from the container or massage the product applied to the skin or hair, it shows a disadvantage that it is not stiff and loose.

As a method of stabilizing oily conditioning components such as conventional silicone and oil, there is a method of using an acrylic synthetic polymer or an inorganic component magnesium aluminum silicate. However, the use of such a component has a disadvantage in that the pearl feel is noticeably inferior compared to the case of applying the pearl or liquid pearl alone.

Particularly, when these pearls or liquid pearls and acrylic synthetic polymers are mixed, the appearance of the contents may be remarkably lowered. In the case of mixing magnesium aluminum silicate and pearls or liquid pearls, a certain level of pearls may be provided. Poor stability In addition, the use of shampoo has the disadvantage of appearing rough when rinsing the hair.

In the case of not using a pearl agent or a liquid pearl, the stability of the contents shows a very excellent characteristic, but the appearance of the contents is significantly reduced.

In order to solve the problems of the prior art as described above, the present invention exhibits excellent conditioning effect, including a water-insoluble non-volatile silicone conditioning component, including a pearling agent (Pearling agent) and quaternary ammonium salts excellent appearance gloss and temperature conditions And a detergent composition excellent in stability over time, particularly at low temperatures.

In order to achieve the above object, the present invention is a detergent composition comprising a water-insoluble non-volatile silicone conditioning component, a pearl agent, and a quaternary ammonium salt, the composition is a low temperature (-5 ℃ to 15 ℃) and a high temperature (35 ℃ to 50 ° C.) relates to a cleaning composition having a viscosity of 30 ps to 250 ps.

Hereinafter, the present invention will be described in detail.

The inventors of the present invention, while performing a variety of studies on a detergent composition having a good appearance and good stability while showing excellent conditioning effect, including a water-insoluble non-volatile silicone conditioning component, when using a quaternary agent while using a quaternary ammonium salt In addition, the appearance of the cleaning composition is very excellent, and the viscosity at low temperature (-5 ° C to 15 ° C) and high temperature (35 ° C to 50 ° C) is maintained at 30 ps (Brookfield, # 3, 12 rpm) or more to maintain the low temperature and It was found that the stability to the phase separation phenomenon is improved significantly even at a high temperature, thereby completing the present invention.

The viscosity of the detergent composition according to the invention is a viscosity of 30 ps to 250 ps at low temperature (-5 to 15 ℃) and high temperature (35 to 50 ℃), preferably 70 ps to 250 at 0 ℃ ps, 30 ps to 100 ps at 50 ° C.

The water-insoluble nonvolatile silicone conditioning component used to provide the conditioning effect in the cleaning composition of the present invention has an average viscosity of about 5 cs (centistokes) to about 2,000,000 cs at 25 ° C., and the main chain is a siloxane-bonded Si-O. And fluids and gums of silicon or derivatives thereof. The silicone fluid refers to a flowable silicone material having a viscosity of less than 1,000,000 cs at 25 ° C., and a silicone gum refers to a flowable silicone material having a viscosity of at least 1,000,000 cs at a temperature of 25 ° C. or higher.

The silicone conditioning component of the present invention has a silicone conditioning component having a viscosity at 25 ° C. (measured by Dow Corning's glass capillary viscosity) of 5 cs to 2,000,000 cs, preferably 10,000 cs to 300,000 cs, more preferably 30,000 cs to 100,000 cs. Can be used.

Examples of silicone conditioning components suitable for the present invention include one or more selected from the group consisting of water-insoluble siloxane, water-insoluble aminated silicon, trimethylsilylamodimethicone, and amodimethicone. In the present invention, 'water insoluble' refers to a solution in which the concentration of 1% by weight in water is not substantially transparent when visually observed at 25 ° C.

The water insoluble siloxane is represented by the following formula (1).

[Formula 1]

In Chemical Formula 1,

x is an integer from 1 to 8,000,

Each R is independently alkyl, aryl, alkylaryl, alkoxy, alkylamino, hydroxy, or hydroxy alkyl, preferably having 1 to 18 carbon atoms.

The water-insoluble siloxane represented by Formula 1 includes dimethicones each of which two silicon atoms positioned at the end of the main chain are terminated by three alkyl groups, and each of two alkyl groups and one OH-containing dimethicone. Include.

The water-insoluble aminated silicon is a substituent in which R in the repeating unit (-SiR ₂ -O) _X of Chemical Formula 1 has an amine group, and contains silicon containing at least one primary to tertiary amine or one quaternary ammonium group. Say. Water-insoluble aminated silicon is represented by the following formula (2)

[Formula 2]

Q-Si (OSiM ₂ ) _n -(OSiMR ') _m -O-SiQ

In Chemical Formula 2,

Q is hydroxy or alkyl of 1 to 18 carbon atoms,

M is hydrogen, phenyl, hydroxy or alkyl of 1 to 18 carbon atoms,

m and n are integers where m + n is 1 to 8000,

R 'is a monovalent radical of the formula -C _q H _2q D.

[q is an alkyl consisting of a straight chain or a side chain of an integer of 2 to 8, D is a quaternized amino group selected from the group consisting of

-N (R) -CH ₂ -CH ₂ -N (R ") _2,

-N (R) ₂

-N ⁺ (R) ₃ A ^-

_{^{-N + H (R) 2 A}} -

_{^{-N + H 2 (R) A}} -

_{-N (R) -CH 2 -CH 2} -N + RH 2 A -

(R is hydrogen, phenyl, benzyl, —CH ₂ CH (OH) CH ₂ OH or an alkyl radical having 1 to 20 carbon atoms, and A ⁻ is an organic or inorganic anion.]

The trimethylsilyl amodimethicone (International Cosmetic Ingredient Dictionary and Handbook, Seventh Edition, 1997) is represented by the following formula (3).

In Formula 3, n and m are integers of m + n 1 to 8000.

Amodimethicone (International Cosmetic Ingredient Dictionary and Handbook, Seventh Edition, 1997) is represented by the following formula (4).

[Formula 4]

In Formula 4, R is OH or methyl.

The silicone conditioning component may be contained in an amount of 0.1 wt% to 5.0 wt% with respect to the total amount of the detergent composition, and preferably 0.5 wt% to 3.5 wt% may be used alone or in combination. When the content of the conditioning component is less than 0.1% by weight, the effect of sufficient conditioning may not be obtained, and when it exceeds 5.0% by weight, there may be a problem in the formulation of the detergent composition.

In the present invention, the pearl agent used for imparting pearlescent metallic luster to the appearance may include monoesters of ethylene glycol having 12 to 22 carbon atoms, diesters of ethylene glycol, propylene glycol or oligomeric alkylene glycols having 12 to 22 carbon atoms. One or more can be selected and used.

Since these pearls are solid at room temperature, they are added to the cleaning composition through a conventional manufacturing method of melting and crystallizing the pearls. These pearls may be used in an amount of 0.1 wt% to 5.0 wt% with respect to the total amount of the detergent composition, preferably 0.5 wt% to 3.5 wt%, more preferably 1.0 wt% to 3.0 wt%.

When the liquid pearl is prepared by mixing anionic or nonionic surfactant with a pearl agent, and then adding the pearl liquid to the detergent composition, these pearl agents may be used in an amount of 0.1 wt% to 5.0 wt% with respect to the total amount of the detergent composition. May use from 0.5 wt% to 3.5 wt%, more preferably from 1.0 wt% to 3.0 wt%.

When the content of the pearl agent exceeds 5.0% by weight, the hair feels dry even after being very stiff and dry during rinsing, and when the weight ratio is less than 0.1%, the pearly feeling does not appear.

The quaternary ammonium salt used for the purpose of improving stability in the present invention may be used by selecting one or two or more of the dialkyl dimethyl ammonium halide having 12 to 22 carbon atoms of the alkyl group. For example, dicetyldimethylammonium halide, dididodecyldimethylammonium halide, or the like can be used. The halide ion of the dialkyldimethylammonium halide is preferably fluoride, chloride, bromide or iodide

The quaternary ammonium salt may be contained in an amount of 0.01 wt% to 5.0 wt% with respect to the total amount of the detergent composition, preferably 0.5 wt% to 3.5 wt%, and more preferably 1.0 wt% to 3.0 wt%. At this time, if the content of the quaternary ammonium salt is more than 5.0% by weight, it is difficult to maintain stability at high temperature over time, and when the weight ratio is less than 0.01% by weight, 30 ps (Brookfield, # 3, 12rpm) at low temperature (-5 ° C to 15 ° C) It becomes impossible to maintain stability by forming low viscosity of less than).

Meanwhile, in the present invention, anionic, amphoteric and nonionic surfactants may be mixed or used alone as a surfactant generally used in the detergent composition for formulation of the detergent, and may be used in an amount of 5 wt% to 50 wt% based on the total amount of the detergent composition. It is used to be.

Anionic surfactant is represented by the following formula (5).

[Formula 5]

RO (CH ₂ CH ₂ O) _n -SO ₃ M

In the above formula.

R is alkyl having 8 to 20 carbon atoms,

n is an integer from 0 to 4,

M may be selected from sodium, potassium, magnesium, triethanolamine and ammonium ions.

Representative examples of the compound of Formula 5 include sodium lauryl sulfate, lauryl ammonium sulfate, magnesium lauryl sulfate, lauryl triethanolamine, sodium polyoxyethylene lauryl sulfate, polyoxyethylene lauryl sulfate, etc. The main purpose is to clean various wastes in the composition.

Nonionic surfactants are represented by the formulas (6), (7) or (8).

[Formula 6]

In Chemical Formula 6, R ₁ is alkyl having 8 to 20 carbon atoms, and R2 and R3 are alkyl having 1 to 3 carbon atoms. Examples of the compound include lauryldimethylamine oxide, palm oil alkyldimethylamine oxide, and the like.

[Formula 7]

In Formula 7, R ₄ CO group is alkoxy having 8 to 20 carbon atoms, n is 0 or 1. Examples of the compound include lauryl acid diethanolamide, palm oil fatty acid diethanolamide, palm oil fatty acid monoethanolamide, and the like.

[Formula 8]

R ₅ (CH ₂ CH ₂ O) _m H

In Formula 8, R ₅ is alkyl having 8 to 20 carbon atoms or alkyl phenyl having 8 to 20 carbon atoms, and m is an integer of 3 to 50. Examples of the compound include polyoxyethylene lauryl ether, polyoxyethylene nonylphenyl ether, and the like.

In the cleaning composition of the present invention, the above-mentioned nonionic surfactants of the formulas (6), (7) and (8) may be used alone or in combination of two or more thereof. They give viscosity to the composition, auxiliary washing, solubilizing efficacy and the like.

The cleaning composition according to the present invention may further include one or more preservatives, thickeners and viscosity adjusting agents, pH adjusting agents, fragrances, dyes, conditioning agents and the like commonly used in the cleaning composition.

As the preservative, a mixture of methyl paraoxybenzoate, methylchloroisothiazolinone and methylisothiazolinone (trade name: Kathon CG, manufactured by Rohm & Haas, USA) may be used.

As the thickener and the viscosity modifier, hydroxypropylmethylcellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride, propylene glycol, hexylene glycol and the like can be used. Citric acid, sodium hydroxide, triethanolamine may be used as the pH adjuster, and a water-soluble tar pigment may be used as the dye.

Conditioning agents include conventional hair conditioning ingredients such as hydrocarbon oil, alkyl or benzyl esters, animal and vegetable extracts, protein and protein variants, chitosan and chitosan derivatives, and fatty acids. It may be used alone or in combination. Fragrances may also be used.

Hereinafter, preferred examples are provided to help understanding of the present invention, but the following examples are merely to illustrate the present invention, and the scope of the present invention is not limited to the following examples.

Example 1

20% by weight of sodium lauryl sulfate (30%), 20% by weight of polyoxyethylene lauryl sulfate (30%) and 3.0% by weight of palm oil fatty acid diethanolamide relative to the weight of the total detergent composition were heated to 80 ° C. At this time, the amount of water is such that the sum with the remaining composition is 100% by weight. Then, 0.5% by weight of ethylene glycol diester and 0.05% by weight of dicetyldimethylammonium chloride were added and stirred for 20 minutes while maintaining the temperature. Then, the mixture was slowly cooled to 45 ° C, cooled, and 0.2% by weight of preservative, 0.4% by weight of perfume, and 2.0% by weight of dimethicone (polydimethylsiloxanes) were added, followed by stirring for 60 minutes to prepare a cleaning composition.

Example 2

A detergent composition was prepared in the same manner as in Example 1, except that 0.05 wt% of dodecyldimethylammonium chloride was added instead of dicetyldimethylammonium chloride as a stabilizer in Example 1.

 Example 3

A detergent composition was prepared in the same manner as in Example 1, except that 3.5 wt% of the ethylene glycol diester and 1.0 wt% of the dicetyldimethylammonium chloride were prepared in Example 1. .

 Example 4

Cleaning agent compositions were prepared in the same manner as in Example 3, except that 1.0 wt% of dodecyldimethylammonium chloride was added instead of dicetyldimethylammonium chloride in Example 3.

Comparative Example 1

Using the same method as in Example 3, except that 0.5 wt% of the acrylate crosspolymer, which is known as a stabilizer for oily conditioning components such as silicone and oil, was added instead of the disetyldimethylammonium chloride in Example 3. Each detergent composition was prepared.

Comparative Example 2

The cleaning composition was prepared in the same manner as in Example 3, except that didecyldimethylammonium chloride was not added in Example 3.

The contents of the components of Examples 1 to 4 and Comparative Examples 1 and 2 are shown in Table 1 below, and the unit is weight%.

Raw material name Example Comparative Example One 2 3 4 One 2 Sodium Lauryl Sulfate (30%) 20.0 20.0 20.0 20.0 20.0 20.0 Sodium polyoxyethylene lauryl sulfate (30%) 20.0 20.0 20.0 20.0 20.0 20.0 Palm oil fatty acid diethanolamide 3.0 3.0 3.0 3.0 3.0 3.0 Ethylene Glycol Diester 0.5 0.5 3.5 3.5 3.5 3.5 Dicetyldimethylammonium chloride 0.05 - 1.0 - - - Didodecyldimethylammonium chloride - 0.05 - 1.0 - - Acrylate Crosspolymer - - - - 0.5 - antiseptic 0.2 0.2 0.2 0.2 0.2 0.2 Spices 0.4 0.4 0.4 0.4 0.4 0.4 Dimethicone (water insoluble siloxanes) 2.0 2.0 2.0 2.0 2.0 2.0 water Add until 100% by weight

The appearance and viscosity of the cleaning composition prepared according to the above Examples and Comparative Examples, and stability evaluation over time were carried out in accordance with Test Examples 1 to 3, respectively.

Test Example 1 Appearance Evaluation (Glossy and Pearl Preference)

Each of the cleaning compositions of Examples 1 to 4 and Comparative Examples 1 and 2 were placed in a UV Cell, and the content of gloss was measured using a gloss meter (Micro-gross meter, 85 ° C). This device measures the amount of light reflected from a light source irradiated on a measurement object. The less shiny object uses a larger reflection angle. When the pearly feeling is weak, it is opaque white, and when the pearly feeling is good, it is shiny white. Therefore, the intensity of the reflected light is increased. The ratio of the amount of reflected light to the amount of incident light is expressed as a percentage, and when this ratio is 100%, it corresponds to a perfect reflector. This experiment was repeated three times to take an average value.

In addition, 25 men and women each were selected to compare the pearl feelings corresponding to the clarity of the pearl pattern with the compositions of Examples 1-4 and Comparative Examples 1 and 2 by comparing the metallic properties of the degree of reflecting light to investigate the overall feeling of pearl It was. To this end, 0.5 g thick, 30 cm wide, and 30 cm long black matt anodized aluminum plates were subjected to 3 g of each composition, followed by a pearl. Evaluation criteria are shown in Table 2, and the evaluation results are shown in Table 3. In the case of Comparative Example 1 containing 3.5% by weight of ethylene glycol diester and 0.5% by weight of acrylate crosspolymer, pearly shine (%) and pearl persimmon than Example 1 and 2 containing 0.5% by weight of ethylene glycol diester The preference was found to be low.

Appearance Evaluation grade Excellent pearly and metallic 5 Excellent pearly and inferior metallicity 4 is average 3 Although there is a feeling of pearl, it is not enough 2 There is no pearl One

Evaluation Shine (%)  Pearl persimmon preference Example One 76.5 3.7 2 75.8 3.5 3 83.2 4.3 4 82.7 4.3 Comparative example One 63.2 2.1 2 81.6 4.2

Test Example 2 Viscosity Measurement by Temperature Conditions

Each detergent composition prepared according to Examples 1-4 and Comparative Examples 1-2 was left in an incubator set at a temperature of low temperature (0 ° C.), room temperature (25 ° C.) and high temperature (50 ° C.) for at least 24 hours. Then, the viscosity was measured using a Brookfield Viscometer LVT model (Spindle # 3, 6rpm or 12rpm) at each temperature condition. The viscosity measurement results at each temperature are shown in Table 4, and the unit is ps. In the case of Comparative Example 2 using only ethylene glycol diester, which is a pearl agent, the content viscosity at low temperature (0 ° C.) and high temperature (50 ° C.) was found to be very low at 23 ps and 28 ps, respectively.

Evaluation division Low temperature (0 ℃) High temperature (50 ℃) Room temperature (25 ℃) Example One 180 53 64 2 184 51 64 3 196 64 78 4 196 66 76 Comparative example One 186 63 73 2 23 28 62

Test Example 3 Evaluation of Stability by Temperature Conditions

Each detergent composition prepared according to the above Examples and Comparative Examples was stored in a transparent container in an incubator set at a temperature of low temperature (0 ° C.), room temperature (25 ° C.) and high temperature (50 ° C.) while maintaining stability of the contents. Tested. The test results at low temperature and high temperature are shown in Table 5, and the stability evaluation was evaluated based on the stability days when the transparent layer separated at the lower part began to be visible. In Table 5 below, the result of one year or more is a result obtained by confirming stability at the low temperature (0 ° C.) for one year after the start of the test and ending the test. In the case of Examples 1 to 4, the stability at low temperature (0 ° C.) and high temperature (50 ° C.) was much superior to that of Comparative Example 2.

Evaluation Low temperature (0 ℃)   High temperature (50 ℃) Example One Over 1 year 152 days 2 Over 1 year 163 days 3 Over 1 year 270 days 4 Over 1 year 283 days Comparative example One Over 1 year 112 days 2 12 days 25 days

Summarizing the above results, when using a stabilizer such as an acrylate crosspolymer while using a pearl agent as in Comparative Example 1, the stability and viscosity characteristics and stability at each temperature condition were excellent, Appeared very falling.

In addition, in the case of using only the silicone conditioning component and the pearl agent as in Comparative Example 2, the pearl persimmon and the content gloss was excellent while the viscosity characteristics and stability was very poor.

On the other hand, in the case of the cleaning composition comprising a silicone conditioning component and a pulsing agent as in Examples 1 to 4, and using a quaternary ammonium salt such as dicetyldimethylammonium chloride or dididodecylmethylammonium chloride as a stabilizer, Very good results were obtained in terms of viscosity characteristics and stability under conditions, and pearly and content gloss.

The detergent composition prepared according to the present invention has excellent conditioning effect and appearance gloss, and has a viscosity of 30 ps to 250 ps at low temperature (-5 ° C to 15 ° C) and high temperature (35 ° C to 50 ° C), phase separation. The stability to the phenomenon has a remarkably improved characteristic.

Claims (10)

A cleaning composition comprising a silicone conditioning component and a pearl agent, a) 5 to 50 weight percent of a surfactant; b) 0.1 to 5.0 weight percent of a water insoluble nonvolatile silicone conditioning component; c) 0.1 to 5.0% by weight of a pearl agent; d) 0.01 to 5.0% by weight of a dialkyldimethylammonium halide having 12 to 22 carbon atoms of an alkyl group as a quaternary ammonium salt; And e) water balance And a viscosity of 30 ps to 250 ps at low temperature (-5 ° C to 15 ° C) and high temperature (35 ° C to 50 ° C). The method of claim 1, The water-insoluble nonvolatile silicone conditioning component is a water-insoluble siloxane represented by the following formula (1), a water insoluble aminated silicon represented by the formula (2), trimethylsilyl amodimethicone represented by the formula (3), and to the formula (4) Cleaner composition selected from the group consisting of the indicated amodimethicone. [Formula 1] In Chemical Formula 1, R is each independently alkyl, aryl, or alkylaryl, alkoxy, alkylamino, hydroxy, hydroxy alkyl having 1 to 18 carbon atoms, and x is an integer of 1 to 8,000.  [Formula 2] Q-Si (OSiM ₂ ) _n- (OSiMR ') _m -O-SiQ In Chemical Formula 2, Q is hydroxy or alkyl of 1 to 18 carbon atoms, M is hydrogen, phenyl, hydroxy or alkyl of 1 to 18 carbon atoms, m and n are integers where m + n is 1 to 8000, R 'is a monovalent radical of the formula -C _q H _2q D. [q is an alkyl consisting of a straight chain or a side chain of an integer of 2 to 8, D is a quaternized amino group selected from the group consisting of -N (R) -CH ₂ -CH ₂ -N (R ") _2, -N (R) ₂ -N ⁺ (R) ₃ A ^{- _{-N + H (R) 2 A}} - _{^{-N + H 2 (R) A}} - _{-N (R) -CH 2 -CH 2} -N + RH 2 A - (R is hydrogen, phenyl, benzyl, —CH ₂ CH (OH) CH ₂ OH or an alkyl radical having 1 to 20 carbon atoms, and A ⁻ is an organic or inorganic anion.] [Formula 3] [Formula 4] In Formula 4, R is hydroxy or methyl. delete The method of claim 1, The water-insoluble nonvolatile silicone conditioning component has a viscosity of 5 cs to 2,000,000 cs at 25 ℃. The method of claim 1, The water-insoluble nonvolatile silicone conditioning component has a viscosity of 10,000 cs to 300,000 cs at 25 ℃. The method of claim 1, The pulping agent is one or more selected from the group consisting of ethylene glycol monoester having 12 to 22 carbon atoms of the ester alkyl group, ethylene glycol diester, propylene glycol, oligomeric alkylene glycol having 12 to 22 carbon atoms. delete The method of claim 1, The dialkyl dimethyl ammonium halide is at least one selected from the group consisting of disetyl dimethyl ammonium halide and dididodecyl dimethyl ammonium halide. The method of claim 1, The dialkyldimethylammonium halide is at least one cleaning composition comprising a fluoride, chloride, bromide and iodide from the group consisting of. The method of claim 1, The detergent composition further comprises at least one additional ingredient selected from the group consisting of preservatives, thickeners, viscosity regulators, pH regulators, flavoring agents, dyes, and conditioning agents.