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KR100489600B1 - The Composition and Manufacturing Method of Mortar for Construction using Hwangto, Zeolite and Ilite - Google Patents

The Composition and Manufacturing Method of Mortar for Construction using Hwangto, Zeolite and Ilite Download PDF

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Publication number
KR100489600B1
KR100489600B1 KR10-2002-0056188A KR20020056188A KR100489600B1 KR 100489600 B1 KR100489600 B1 KR 100489600B1 KR 20020056188 A KR20020056188 A KR 20020056188A KR 100489600 B1 KR100489600 B1 KR 100489600B1
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parts
mortar
zeolite
weight
illite
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KR10-2002-0056188A
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KR20030027669A (en
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김순호
오대민
성진경
진상환
진순한
황영석
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주식회사 대동그린산업
가부시기가이샤 오쿠다구미
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/047—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/30—Oxides other than silica
    • C04B14/305—Titanium oxide, e.g. titanates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/36—Inorganic materials not provided for in groups C04B14/022 and C04B14/04 - C04B14/34
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02—Treatment
    • C04B20/04—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10—Lime cements or magnesium oxide cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40—Porous or lightweight materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

본 발명은 천연의 풍부한 제올라이트, 황토와 일라이트를 이용하여 건자재인 제올라이트 모르타르를 제조하는데 적용하는 방법에 관한 것이다. 황토의 특성인 원적외선 방출, 온·습도조절, 탈취작용 등의 기능을 유지시키면서, 이온교환능력을 갖춘 천연의 제올라이트, 탈취성능이 우수한 일라이트를 주거공간의 쾌적한 건강소재로 개발하여 제올라이트와 황토, 일라이트는 전통적인 무기질 건축자재로서 오랜 세월동안 현대화된 시멘트 건축자재로 이용되기 전까지 사용되어 오고 있었다. 그러나 모르타르로서의 제반 결점을 보완하기 위해 높은 건조수축을 없애고, 높은 압축강도를 얻어 현대 건축재료로 환경친화적이며, 황토재료 및 제올라이트, 일라이트의 특성을 최대한 갖춘 제품을 개발한 것이다.The present invention relates to a method applied to the production of zeolite mortar as a building material using natural rich zeolites, ocher and illite. While maintaining functions such as far-infrared emission, temperature / humidity control, and deodorization, which are characteristic of ocher, natural zeolite with ion exchange ability and illite with excellent deodorization performance have been developed as a pleasant health material in residential spaces. Illite is a traditional mineral building material that has been used for many years before being used as a modern cement building material. However, in order to make up for the shortcomings of mortar, the company has developed a product that eliminates high drying shrinkage, obtains high compressive strength, is environmentally friendly with modern building materials, and has the best characteristics of ocher materials, zeolites and illites.

본 발명 천연의 제올라이트와 황토, 일라이트를 광산에서 채굴하여 수분제거하고, 조쇄한 후 건조로에서 100∼400℃로 1∼10℃/분의 승온속도로 승온하여 1∼6시간 유지 후 자연냉각하여 0.5∼4시간 건조하여 미분쇄기에서 200∼500mesh 이하의 입도로 분쇄하여 분말을 이용하여 제올라이트 모르타르 전체 복합물을 중량부 100을 기준으로 볼 때, 제올라이트 20∼60부, 황토는 20∼50부, 일라이트는 10∼30부 슬래그중량부는 5∼15부, 생석회는 5∼15부, 이산화티탄 중량부는 1∼10으로 조성되어 있는 건조모르타르의 제조방법이다.Natural zeolite, loess, and illite of the present invention are mined in a mine to remove moisture, and after pulverization, the temperature is increased to 100 to 400 ° C. at a temperature increase rate of 1 to 10 ° C./minute and maintained for 1 to 6 hours. 0.5 to 4 hours of drying, milling to a particle size of 200 to 500 mesh or less in a pulverizer, and using the powder as a whole based on 100 parts by weight of the zeolite mortar composite, 20 to 60 parts of zeolite, 20 to 50 parts of ocher 10-30 parts of slag is 5-15 parts of slag weight part, 5-15 parts of quicklime, and 1-10 parts of titanium dioxide are dry mortar manufacturing methods.

이것을 물배합을 중량부 30∼40부로 혼련하여 시공하여 양생을 통하여 사용하면 자연 양생을 1일∼15일 정도로 실시한 후 제올라이트, 황토, 일라이트를 사용한 모르타르는 기존의 시멘트모르타르, 유기결합제 등을 이용한 모르타르와 비교시 원적외선 방사율이 92％로 높고, 실내공기정화 및 온·습도 조절기능과 탈취율 84％의 특성 압축강도는 180㎏f/㎠을 나타낸다.When water mixture is kneaded into 30 parts by weight to 40 parts by weight and used for curing, natural curing is carried out for about 1 to 15 days, and then mortar using zeolite, loess, and illite is prepared using conventional cement mortar and organic binder. Compared with mortar, far-infrared emissivity is high as 92%, indoor air purification, temperature and humidity control function, deodorization rate of 84%, and the characteristic compressive strength is 180kgf / ㎠.

Description

제올라이트와 황토, 일라이트를 활용한 건축용 모르타르 조성물 및 제조방법{The Composition and Manufacturing Method of Mortar for Construction using Hwangto, Zeolite and Ilite}Composition and Manufacturing Method of Mortar for Construction using Hwangto, Zeolite and Ilite}

본 발명은 제올라이트와 황토, 일라이트등의 천연광물과 석회등을 이용하여 제조하는 제올라이트 모르타르(또는 석회모르타르)와 그 제조방법에 관한 것이다.The present invention relates to a zeolite mortar (or lime mortar) prepared using natural minerals such as zeolite, ocher, and elite, and lime and a method of manufacturing the same.

종래의 황토모르타르에 관한 것으로서 한국특허등록 제0239853호 및 공개특허 제2000-0012566호, 공개특허 제2000-0033318호에서는 천연의 황토를 이용하여 볏짚, 유기결합제 등을 넣어 압축강도가 40∼50㎏f/㎠ 정도이어서 내수성이 없으며, 공개특허 제1999-0064871호 및 공개특허 제2000-0012566호에서는 강도를 보완하기 위하여 시멘트, 유기결합제 등을 첨가한 방법으로서 원적외선 방사율과 탈취·흡착, 온·습도 조절기능이 떨어지고 황토의 함유량도 제한된다. As related to the conventional loess mortar, Korean Patent Registration No. 0239853, Patent Publication No. 2000-0012566, Patent Publication No. 2000-0033318 put the rice straw, organic binder, etc. using natural loess, the compressive strength 40 ~ 50㎏ It is about f / cm 2, so it is not water-resistant, and in Patent Publication Nos. 1999-0064871 and 2000-0012566, a method of adding cement, an organic binder, and the like to supplement strength is far infrared emissivity, deodorization, adsorption, temperature and humidity. Inadequate control and limited ocher content.

또한, 황토, 시멘트 방수약, 적색 산화철 등을 혼합한 제조방법이 국내공개 특허공보 공개번호 제89-358호, 제85-5395호 및 제90-12862호에 기재되어 있으나 상기의 종래 방법은 원적외선 방사율 및 탈취 및 온·습도조절기능이 낮아 실용성이 부적절한 결점이 있다.In addition, the manufacturing method of the mixture of ocher, cement waterproofing agent, red iron oxide and the like is described in Korean Patent Publication Nos. 89-358, 85-5395 and 90-12862, but the conventional method is far infrared Low emissivity and deodorization and low temperature / humidity control have improper practicality.

기존의 황토, 맥반석을 사용하는 모르타르는 건조 및 경화과정에서 수분의 건조와 더불어 수축하여 균열이 가고 수축하게 되며, 또한, 낮은 압축강도를 가져오므로 고강도를 요구하는 곳에는 사용할 수 없으며, 항상 낮은 강도를 요구하는 곳만 사용되어 왔다. 다른 방법으로는 시멘트나 유기결합재를 사용하여 이러한 문제를 해결하려 했다. Mortar using ocher and elvan is contracted with drying of moisture during drying and hardening process, causing cracks and shrinkage. Also, it has low compressive strength and cannot be used where high strength is required. Only places where strength is required have been used. Alternatively, cement or organic binders were used to solve this problem.

본 발명은 기존의 제올라이트와 황토, 일라이트 고유의 특성을 유지하면서 기존 방식으로 제조된 시멘트 모르타르가 가지고 있는 문제점을 개선하여 압축강도가 높고, 원적외선 방사율 및 탈취흡착율이 높은 제품을 생산하는 것을 목적으로 삼고 있다.The present invention improves the problems of the cement mortar prepared by the existing method while maintaining the characteristics of the existing zeolite, ocher, and illite, the purpose of producing a product with high compressive strength, high far-infrared emissivity and deodorization adsorption rate. It is.

상기의 목적을 달성하기 위하여 본 발명은, 제올라이트 모르타르 전체 복합물을 중량부 100을 기준으로 볼 때, 제올라이트 20∼50중량부, 황토는 20∼50중량부, 일라이트는 10∼30중량부, 슬래그는 5∼15중량부, 생석회는 5∼15중량부, 이산화티탄은 1∼10중량부로 조성되는 것을 특징으로 한다.In order to achieve the above object, the present invention, based on 100 parts by weight of the total composite of zeolite mortar, 20 to 50 parts by weight of zeolite, 20 to 50 parts by weight of ocher, 10 to 30 parts by weight of illite, slag Is 5 to 15 parts by weight, quicklime is 5 to 15 parts by weight, titanium dioxide is characterized in that it is composed of 1 to 10 parts by weight.

상기의 목적을 달성하기 위하여 본 발명은, 천연의 제올라이트와 황토, 일라이트를 광산에서 채굴하여 수분을 제거하고, 조쇄한 후 건조로에서 100∼400℃로 1∼10℃/분의 승온 속도로 승온하면서 1∼6시간 유지시키고, 그 후 자연냉각으로 0.5∼4시간 건조한 후 미분쇄기에서 200∼500mesh이하의 입도로 분쇄하여 분말화 하는 것을 특징으로 한다.In order to achieve the above object, the present invention, mining natural zeolite, ocher, and elite in a mine to remove moisture, and after crushing, the temperature is raised to 100 to 400 ℃ in a drying furnace at a temperature rising rate of 1 to 10 ℃ / min While maintaining for 1 to 6 hours, and then dried by natural cooling for 0.5 to 4 hours, and then pulverized to a particle size of 200 to 500 mesh or less in a pulverizer.

상기의 목적을 달성하기 위하여 본 발명은, 천연의 제올라이트 20 ~ 50중량부와 황토 20 ~ 50중량부와 일라이트 10 ~ 중량부와 슬래그 5∼15중량부와 생석회 5∼15중량부와 이산화티탄 1∼10중량부를 혼합한 후 수분을 제거하고, 조쇄한 후 건조로에서 100∼400℃로 1∼10℃/분의 승온속도로 승온하여 1∼6시간 유지시키고, 자연냉각으로 0.5∼4시간 건조한 후 미분쇄기에서 200∼500mesh 이하의 입도로 분쇄하여 분말을 획득하는 것을 특징으로 한다.In order to achieve the above object, the present invention, 20 to 50 parts by weight of natural zeolite, 20 to 50 parts by weight of ocher, 10 to 10 parts by weight of illite, 5 to 15 parts by weight of slag, 5 to 15 parts by weight of quicklime and titanium dioxide After mixing 1 to 10 parts by weight, water was removed, and after pulverization, the temperature was raised to 100 to 400 ° C. at a heating rate of 1 to 10 ° C./min in a drying furnace and maintained for 1 to 6 hours, followed by drying for 0.5 to 4 hours by natural cooling. It is characterized by obtaining a powder by grinding to a particle size of 200 ~ 500mesh or less in a fine mill.

이하, 본 발명을 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

본 발명은 천연의 풍부한 제올라이트, 황토와 일라이트를 이용하여 건자재인 제올라이트 모르타르를 제조하는데 적용하는 방법에 관한 것으로, 황토의 특성인 원적외선 방출, 온·습도 조절, 탈취작용 등의 기능을 유지시키면서, 이온교환능력을 갖춘 천연의 제올라이트, 탈취성능이 우수한 일라이트를 주거공간의 쾌적한 건강소재로 개발한 것이다.The present invention relates to a method applied to the production of zeolite mortar, which is a dry material using natural rich zeolite, ocher and illite, while maintaining functions such as far-infrared emission, temperature / humidity control, deodorization, etc. Natural zeolite with ion exchange capacity and illite with excellent deodorizing performance have been developed as a pleasant health material in residential space.

제올라이트와 황토, 일라이트는 오랫동안 현대화된 시멘트 건축자재로 이용되기 전까지 전통적인 무기질 건축자재로서 오랜 세월동안 이용되고 있다. 그러면 모르타르로서 여러 가지 결점을 보완하기 위해 높은 건조수축을 없애고, 높은 압축강도와 환경에 친화성이 높은 황토의 재료 및 제올라이트, 일라이트의 특성을 최대한 갖추고 있는 제품을 제공한다.Zeolites, loess and illite have been used for many years as traditional mineral building materials until they are used as modernized cement building materials for a long time. As a mortar, this product eliminates high drying shrinkage to compensate for various defects, and provides products with high compressive strength and environment-friendly ocher materials, zeolites and elites.

본 발명에 있어서는, 천연의 제올라이트와 황토, 일라이트를 광산에서 채굴하여 수분제거하고, 조쇄한 후 건조로에서 100∼400℃로 1∼10℃/분의 승온속도로 승온하여 1∼6시간 유지 후 자연냉각하여 0.5∼4시간 건조하여 미분쇄기에서 200∼500mesh 이하의 입도로 분쇄하여 모르타르 분말을 제조하게 된다.여기서. 제올라이트 모르타르 전체 복합물을 중량부 100으로 기준할 때, 제올라이트 20∼50중량부, 황토는 20∼50중량부, 일라이트는 10∼30중량부, 슬래그는 5∼15중량부, 생석회는 5∼15중량부, 이산화티탄은 1∼10중량부로 조성된다.In the present invention, natural zeolites, ocher, and elite are mined in mines to remove moisture, and after pulverization, the temperature is raised to 100 to 400 ° C. at a temperature increase rate of 1 to 10 ° C./min, and maintained for 1 to 6 hours. It is naturally cooled, dried for 0.5 to 4 hours, and pulverized to a particle size of 200 to 500 mesh or less in a pulverizer to produce mortar powder. Based on 100 parts by weight of the entire zeolite mortar composite, 20 to 50 parts by weight of zeolite, 20 to 50 parts by weight of ocher, 10 to 30 parts by weight of elite, 5 to 15 parts by weight of slag, and 5 to 15 parts of quicklime The parts by weight and titanium dioxide are composed of 1 to 10 parts by weight.

상기 재료를 물배합을 중량부 30∼40부로 혼련하여 시공하여, 자연 양생을 1일∼15일 정도로 실시한 후, 기존의 시멘트 모르타르, 유기결합제 등을 이용한 모르타르와 비교시 원적외선 방사율이 92％로 높고, 실내공기정화 및 온·습도 조절기능과 탈취율 84％를 표시하고, 특성 압축강도는 180㎏f/㎠을 나타낸다.The material is kneaded with 30 to 40 parts by weight of water, and the natural curing is carried out for about 1 to 15 days, and the far-infrared emissivity is high as 92% compared with the mortar using conventional cement mortar and organic binder. , Indoor air purification and temperature / humidity control function and deodorization rate of 84% are displayed, and the characteristic compressive strength is 180kgf / ㎠.

본 발명의 실시형태는 결합재로 생석회, 고로슬래그, 천연석고를 사용하고 광촉매반응은 이산화티탄을 첨가하여 혼합한 후, 황토와 제올라이트, 일라이트를 를 혼합한다.In the embodiment of the present invention, quicklime, blast furnace slag, and natural gypsum are used as binders, and photocatalytic reaction is performed by adding titanium dioxide, followed by mixing ocher, zeolite and illite.

상기 모르타르의 특성중, 압축강도 시험은 시멘트 모르타르의 압축강도 시험법으로서 시험편(5×5×5㎝) 크기의 몰드(Mold)에서 성형하여 양생실에서 48시간 후에 탈형하였으며, 시험편은 상압상온 양생하여 28일 경과후에 재령별로 측정하였다.Among the characteristics of the mortar, the compressive strength test is a compression strength test method of cement mortar was molded in a mold (5 × 5 × 5 cm) size of the mold (Mold) and demoulded after 48 hours in the curing room, the test specimen is at room temperature curing After 28 days, it was measured by age.

건조수축률 시험은 시멘트 모르타르 및 콘크리트의 길이변화 시험방법에 의하여(2.5×2.5×25.4㎝) 시험체를 제작하여 재령 28일 후에 그 길이변화를 측정하였다.In the dry shrinkage test, the test specimens were prepared by the test method for changing the length of cement mortar and concrete (2.5 × 2.5 × 25.4㎝), and the length change was measured after 28 days of age.

유동성 시험은 지름 5㎝, 높이 5㎝의 철제 몰드(Mold)를 유리판 위에 설치한 후, 제조된 시료를 부어 넣은 후 Mold를 들어올려 펼쳐지는 지름의 크기를 측정하였다.In the fluidity test, an iron mold having a diameter of 5 cm and a height of 5 cm was installed on a glass plate, and then, the prepared sample was poured in, and then the size of the unfolded diameter was measured by lifting the mold.

원적외선 측정시험은 FT-IR의 방사률 측정장치로 측정하였다.Far-infrared measurement test was measured by the FT-IR emissivity measuring device.

본 발명에서 사용되는 재료의 정의 및 특성은 다음과 같다.Definitions and properties of materials used in the present invention are as follows.

(1)제올라이트(1) zeolite

구 분division 제올라이트 조성물의 특성Properties of Zeolite Composition 성인 및 산지Adult and Mountain 경북 포항지역, 천연상태 산출Gyeongbuk Pohang area, natural state calculation 주성분chief ingredient SiO2 20∼35%, Cao : 40∼60%, Al2O3: 5∼15SiO 2 20-35%, Cao: 40-60%, Al 2 O 3 : 5-15 범주 및 입자Categories and Particles 200mesh이하200mesh or less

(2)황토(2) ocher

구 분division 황토의 특성Ocher properties 성인 및 산지Adult and Mountain 암석 풍화에 의해 생성되고, 주로 채굴되는 장소는 산(山)It is produced by rock weathering, and the main mining place is mountain 주성분chief ingredient SiO2: 35∼50%, Al2O3: 25∼40%, Fe2O3: 3∼20%SiO 2 : 35-50%, Al 2 O 3 : 25-40%, Fe 2 O 3 : 3-20% 범주 및 입자Categories and Particles 넓게는 1차 점토에 속하며, 입자크기는 조립Widely belongs to primary clays, particle size is assembled

(3)일라이트(3) illite

구 분division 일라이트의 특성Characteristics of the illite 성인 및 산지Adult and Mountain 암석 풍화에 의해 생성되고, 주고 채굴되는 장소는 산(山)The place where it is produced by rock weathering, giving and mining is mountain 주성분chief ingredient SiO2: 55∼80%, Al2O3: 5∼30%, Fe2O3: 3∼20%SiO 2 : 55-80%, Al 2 O 3 : 5-30%, Fe 2 O 3 : 3-20% 범주 및 입자Categories and Particles 넓게는 1차 점토에 속하며, 입자크기는 조립Widely belongs to primary clays, particle size is assembled

(4)생석회(4) quicklime

구 분division 생석회의 특징Quicklime features 성인 및 산지Adult and Mountain 강원, 경북의 석회석Limestone in Gangwon, Gyeongbuk 주성분chief ingredient 탄산칼슘(CaCO3)Calcium Carbonate (CaCO 3 ) 범주 및 입자Categories and Particles 분말도:2400㎠/g이상, 염분:1%이하강열감량:5%이하, 산화칼슘: 45%이상Powder level: 2400 cm2 / g or more, salinity: 1% or less Loss on heating: 5% or less, calcium oxide: 45% or more

(5)슬래그(5) slag

구 분division 슬래그의 특성Slag properties 성인 및 산지Adult and Mountain 제철공정의 선철후 수냉 슬러지After-stage water-cooled sludge in the steelmaking process 주성분chief ingredient SiO2: 20∼35%, CaO: 40∼60%, Al2O3: 5∼15%SiO 2 : 20-35%, CaO: 40-60%, Al 2 O 3 : 5-15% 범주 및 입자Categories and Particles 분말도 3200㎠/g∼7600㎠/gPowder level 3200cm2 / g ~ 7600cm2 / g

(6)이산화티탄(6) titanium dioxide

구 분division 이산화티탄의 특성Properties of Titanium Dioxide 성인 및 산지Adult and Mountain 티탄철광형으로 산출 황산법·염소법으로 제조Calculation by titanium iron ore Manufacture by sulfuric acid method and chlorine method 주성분chief ingredient 주성분이 이산화티탄으로 결정상은 정방정으로 티탄철광형 금홍석형과 애주석형이 있다.The main component is titanium dioxide, and the crystal phase is tetragonal, and there are titanium iron ore rutile and adiolite. 범주 및 입자Categories and Particles 4.1㎛∼0.1㎛로서 광촉매, 향균, 탈취, 산화분해 작용4.1 to 0.1㎛ photocatalyst, antibacterial, deodorant, oxidative decomposition

상기 실시형태에 있어서, 믹서(Mixer)를 이용한 혼합은 전체적으로 균일해야만 시공시에 입도의 몰림현상 및 재료분리층을 없앨 수 있다. 이러한 제올라이트 모르타르의 조성물은 기존의 건축물의 내, 외벽에 적용할 수 있으며, 음이온의 방출기능을 위하여 토루말린을 첨가할 수 있다.In the above embodiment, the mixing using the mixer must be uniform throughout to eliminate the swelling of the particle size and the material separation layer during construction. The composition of the zeolite mortar can be applied to the inner and outer walls of the existing building, it can be added to the tourmaline for the release function of the anion.

상술한 방법에 있어 제올라이트, 황토, 일라이트는 채굴, 건조, 분쇄, 분급한 후, 생석회, 슬래그, 이산화티탄 등과 드라이믹싱한 후 계량하고, 포장, 저장, 출하한다.In the above-described method, the zeolite, loess, and elite are mined, dried, pulverized, classified, and then dry mixed with quicklime, slag, titanium dioxide and the like, weighed, packaged, stored and shipped.

이하, 본 발명의 모르타르와 종래의 시멘트모르타를의 특성, 성능비교를 실시예1 내지 5에서 나타낸다.Hereinafter, the characteristics and performance comparisons of the mortar of the present invention and the conventional cement mortar are shown in Examples 1 to 5.

(실시예 1)(Example 1)

제올라이트 모르타르의 시간경과에 따른 탈취율Deodorization Rate of Zeolite Mortar with Time

경과시간(분)Elapsed time (minutes) Blank농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율(%)Deodorization rate (%) 초기Early 500500 500500 -- 3030 480480 130130 7373 6060 470470 100100 7979 9090 450450 8080 8282 120120 440440 7070 8484

(실시예 2)(Example 2)

시멘트 모르타르의 시간 경과에 따른 탈취율Deodorization rate of cement mortar over time

경과시간(분)Elapsed time (minutes) Blank농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율(%)Deodorization rate (%) 00 500500 500500 -- 3030 480480 220220 5454 6060 470470 200200 5757 9090 450450 180180 6060 120120 440440 170170 6161

(실시예 3)(Example 3)

시험체의 흡방수량의 측정결과Measurement result of water absorption amount of test body

시험체Test body 방습비Moisture proof 제올라이트 모르타르Zeolite mortar 66%66% 시멘트 모르타르Cement mortar 13%13%

(실시예 4)(Example 4)

제올라이트 모르타르와 시멘트 모르타르의 표면온도 변화Surface Temperature Changes of Zeolite Mortar and Cement Mortar

구 분division 시멘트모르타르 온도(℃)Cement mortar temperature (℃) 제오라이트 모르타르 온도(℃)Zeolite mortar temperature (℃) 가열진행중Heating process 34.9334.93 36.2936.29 가열종료 30분 후30 minutes after heating 28.1928.19 31.9131.91 가열종료 1시간 후1 hour after heating 25.9325.93 27.4027.40

(실시예 5)(Example 5)

제올라이트 모르타르와 시멘트 모르타르의 물리적 특성Physical Properties of Zeolite Mortars and Cement Mortars

구 분division 압축강도(kgf/㎤)Compressive strength (kgf / cm3) 기공율(%)Porosity (%) 원적외선 방사율(%)Far Infrared Emissivity (%) 제올라이트 모르타르Zeolite mortar 180180 20.920.9 92.592.5 시멘트 모르타르Cement mortar 200200 5.605.60 73.973.9

본 발명으로 제품화된 제올라이트 모르타르는 압축강도가 180kgf/㎠ 이상이며, 원적외선 방사율은 92%, 탈취흡착율은 84%로 건축용 자재의 물리적 특성을 충족시키며, 본 개발제품으로 시공된 건물은 타제품으로 시공된 건물보다 오랫동안 실내온도를 일정하게 유지시키며, 뛰어난 흡착력으로 악취를 제거하고 우수한 항균성으로 세균의 번식을 억제하는 것으로 나타났다. 전통적인 천연재료를 건축용 자재로 활용함으로서 현대건축에 우리의 주거환경의 변화를 도모하는 친환경적인 제품으로 제품의 경쟁성을 확보하였다.Zeolite mortar commercialized by the present invention has a compressive strength of more than 180kgf / ㎠, far-infrared emissivity of 92%, deodorization adsorption rate of 84% to meet the physical properties of the building material, the building constructed with the developed product is constructed with other products It has been shown to maintain a constant indoor temperature for longer than buildings, to remove odors with excellent adsorption, and to suppress the growth of bacteria with excellent antibacterial properties. By using traditional natural materials as building materials, we have secured product competitiveness with eco-friendly products that aim to change our residential environment in modern architecture.

이상에서와 같이 본 발명에 의한 제올라이트 모르타르는 압축강도와 흡방수량, 기공율 등이 건축용 내·외장용 자재에 적합한 물성을 충분히 만족시켰으며, 본 발명에 의한 마감재로 시공된 건물은 원적외선 복사에너지가 방사되고 알카리성 시멘트를 중화시키며 전통의 특성을 재현할 수 있으며 전체적으로 실내가 따뜻하고 습기가 차지 않으며 탁월한 흡착력으로 냄새를 제거하고 우수한 항균성으로 곰팡이 등 세균의 번식을 억제하며 우리의 주거환경에 적합하고 쾌적한 실내공간을 제공한다.As described above, the zeolite mortar according to the present invention satisfies physical properties suitable for interior and exterior materials for compressive strength, water absorption, porosity, etc., and the building constructed of the finishing material according to the present invention radiates far-infrared radiation energy. It can neutralize alkaline cements and reproduce the characteristics of the tradition, and the interior is warm and does not occupy moisture. to provide.

Claims (3)

제올라이트 20∼50중량부, 황토 20∼50중량부, 일라이트 10∼30중량부, 슬래그 5∼15중량부, 생석회 5∼15중량부, 이산화티탄 1∼10중량부로 조성되는 것을 특징으로 하는 제올라이트와 황토, 일라이트를 활용한 건축용 모르타르 조성물.Zeolite 20-50 parts by weight, ocher 20-50 parts by weight, illite 10-30 parts, slag 5-15 parts, quicklime 5-15 parts by weight, titanium dioxide 1-10 parts by weight Mortar composition for building using ocher, illite. 삭제delete 천연의 제올라이트 20 ~ 50중량부와 황토 20 ~ 50중량부와 일라이트 10 ~ 30중량부를 혼합한 후 수분을 제거하고 조쇄하는 제1공정과;A first step of removing water and pulverizing water after mixing 20 to 50 parts by weight of natural zeolite, 20 to 50 parts by weight of ocher, and 10 to 30 parts by weight of illite; 상기 제1공정에서 조쇄된 혼합물을 건조로에서 1∼10℃/분의 승온속도로 승온하면서 100∼400℃로 1∼6시간 유지시킨 후, 자연냉각하여 0.5∼4시간 건조하는 제2공정과;A second step of maintaining the mixture pulverized in the first step at 100 to 400 ° C. for 1 to 6 hours while raising the temperature at a temperature increase rate of 1 to 10 ° C./min in a drying furnace, followed by natural cooling and drying for 0.5 to 4 hours; 상기 제2공정에서 건조된 혼합물을 미분쇄기에서 200∼500mesh 이하의 입도로 분쇄하여 분말화하는 제3공정과;A third step of pulverizing the mixture dried in the second step to a particle size of 200 to 500 mesh or less in a mill; 상기 제3공정에서 획득된 분말과 슬래그 5∼15중량부와 생석회 5∼15중량부와 이산화티탄 1∼10중량부를 혼합하는 제4공정으로 제조되는 것을 특징으로 하는 제올라이트와 황토, 일라이트를 활용한 건축용 모르타르 제조방법.5 to 15 parts by weight of the powder and slag obtained in the third step, 5 to 15 parts by weight of quicklime and 1 to 10 parts by weight of titanium dioxide, the zeolite, ocher, and illite are utilized. A method of making mortar for construction.
KR10-2002-0056188A 2001-09-28 2002-09-16 The Composition and Manufacturing Method of Mortar for Construction using Hwangto, Zeolite and Ilite KR100489600B1 (en)

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KR100817796B1 (en) 2006-12-27 2008-03-31 크레아건설주식회사 Loess board and a method of preparing the same
KR100850037B1 (en) * 2008-04-10 2008-08-04 주식회사 동진산업 A functional dry cement mortar and manufacturing method thereof
KR100904248B1 (en) 2007-11-30 2009-06-25 (주)하희연플라워 Ocher perlite and manufactruing method thereof
WO2011087304A2 (en) * 2010-01-13 2011-07-21 전남대학교산학협력단 Alkali-activated binding material having no cement and comprising a complex alkali activator, and mortar or concrete using same
KR101142035B1 (en) 2012-03-20 2012-05-14 한국휴로드 (주) The method of treating the surface of construction with seramic's coatings of function that is dispersed in water
KR101144140B1 (en) 2011-06-30 2012-05-24 (주)새론테크 Environmental-friendly elastic paving material and method of preparing the paving material

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KR100694806B1 (en) * 2005-02-24 2007-03-14 (주)삼진토가 Make use of activated cardon illite making a method a block of dried mud
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100817796B1 (en) 2006-12-27 2008-03-31 크레아건설주식회사 Loess board and a method of preparing the same
KR100904248B1 (en) 2007-11-30 2009-06-25 (주)하희연플라워 Ocher perlite and manufactruing method thereof
KR100850037B1 (en) * 2008-04-10 2008-08-04 주식회사 동진산업 A functional dry cement mortar and manufacturing method thereof
WO2011087304A2 (en) * 2010-01-13 2011-07-21 전남대학교산학협력단 Alkali-activated binding material having no cement and comprising a complex alkali activator, and mortar or concrete using same
WO2011087304A3 (en) * 2010-01-13 2011-12-29 전남대학교산학협력단 Alkali-activated binding material having no cement and comprising a complex alkali activator, and mortar or concrete using same
KR101144140B1 (en) 2011-06-30 2012-05-24 (주)새론테크 Environmental-friendly elastic paving material and method of preparing the paving material
KR101142035B1 (en) 2012-03-20 2012-05-14 한국휴로드 (주) The method of treating the surface of construction with seramic's coatings of function that is dispersed in water

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