KR100486656B1 - Heat transfer film coated by top hardenning and Manufacturing process thereof - Google Patents
Heat transfer film coated by top hardenning and Manufacturing process thereof Download PDFInfo
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- KR100486656B1 KR100486656B1 KR10-2002-0006246A KR20020006246A KR100486656B1 KR 100486656 B1 KR100486656 B1 KR 100486656B1 KR 20020006246 A KR20020006246 A KR 20020006246A KR 100486656 B1 KR100486656 B1 KR 100486656B1
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- methyl ethyl
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/405—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by layers cured by radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/36—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
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- Decoration By Transfer Pictures (AREA)
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Abstract
본 발명은 탑(Top)경화 코팅 열전사 필름 및 그 제조방법에 관한 것으로서, 상기 탑 경화 코팅 열전사 필름은 코로나 처리가 되지 않은 16-25㎛의 유광과 19-25㎛의 무광(Matt)필름을 사용한 폴리에틸렌테레프탈레이트(PET) 필름층, 아크릴 공중합체(acrylic copolymer), 합성 왁스, 톨루엔, 메틸 에틸 케톤(methyl ethyl ketone)을 구성성분으로 하는 제1 이형층, 아크릴 공중합체, 합성 왁스, 톨루엔, 메틸 에틸 케톤을 구성성분으로 하는 제2 이형층, 폴리우레탄 수지(polyurethane resin), 변성 아크릴 수지(modified acrylic resin), 실리카 분말(silica powder), 메틸 에틸 케톤으로 된 이액형 구성성분을 경화제와 혼합하여 이루어진 탑 경화 코팅층, 인쇄층, 사출물의 원료에 따라 ABS, PP, PE 등의 접착제를 도포한 접착제층으로 구성된다.The present invention relates to a top curing coated thermal transfer film and a method for manufacturing the same, wherein the top curing coated thermal transfer film has a gloss of 16-25 μm and a matt film of 19-25 μm that are not corona treated. Polyethylene terephthalate (PET) film layer, acrylic copolymer, synthetic wax, toluene, first release layer composed of methyl ethyl ketone as a component, acrylic copolymer, synthetic wax, toluene , A second release layer composed of methyl ethyl ketone as a component, a polyurethane resin, a modified acrylic resin, a silica powder, a two-component component composed of methyl ethyl ketone, and a curing agent. It consists of an adhesive layer coated with an adhesive such as ABS, PP, PE, depending on the top cured coating layer, the printing layer, and the raw material of the injection molded product formed by mixing.
상기 구성에 따른 본 발명은, 전사된 표면이 강하지 않아서 각종 용재로 4-5회만 닦아도 인쇄된 무늬가 지워질 뿐 아니라, 조그마한 긁힘에도 쉽게 스크래치가 발생하는 종래의 일반 전사필름의 단점을 제거하여, 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 월등히 우수할 뿐 만 아니라 내구성이 우수하여 경제성 또한 뛰어난 탑 경화 코팅 열 전사 필름의 제조방법 및 이 필름의 전사방법을 제공하는 유용한 발명이다.According to the present invention, the transferred surface is not strong, and the printed pattern is not only erased even if wiped 4-5 times with various solvents, but also eliminates the disadvantages of the conventional general transfer film that easily scratches even a small scratch, wear resistance It is a useful invention that provides a method for producing a top-curing coating thermal transfer film and a method for transferring the film, which are excellent in chemical resistance, solvent resistance, light resistance and scratch resistance, as well as excellent durability.
Description
본 발명은 탑(Top)경화 코팅 열전사 필름 및 그 제조방법에 관한 것으로, 보다 자세하게는 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 우수한 탑 경화 코팅 열전사필름 및 그 제조방법에 관한 것이다.The present invention relates to a top-curing coating thermal transfer film and a method for manufacturing the same, and more particularly, to a top-curing coating thermal transfer film excellent in abrasion resistance, chemical resistance, solvent resistance, light resistance and scratch resistance will be.
종래 플라스틱 표면, 가공목재의 표면 등에 원하는 무늬를 넣기 위해 상기 무늬가 인쇄된 필름지를 열과 압을 가하여 전사하는데, 이러한 종래의 일반 전사필름은 전사된 표면이 강하지 않아서 메틸 에틸 케톤, 에틸 아세테이트 등의 각종 용재로 4-5회만 닦아도 인쇄된 무늬가 지워질 뿐 아니라, 조그마한 긁힘에도 쉽게 스크래치가 발생하는 단점이 있었다. 즉 종래의 일반 전사지는 PET필름 내면에 이형층 - 인쇄층 - 접착층의 구조로 되어 있어 이 전사지를 플라스틱등의 피전사체에 열과 압력을 가해 전사시킨 다음 PET필름을 벗겨내어 인쇄층을 전사하였기 때문에 이형층 만이 인쇄층의 보호층으로 작용하였다. 따라서 유기 용재에 쉽게 인쇄층이 지워지고 내광성이 열등하며 인쇄컬러가 쉽게 변색될 뿐 아니라 스크래치성도 약하여 광범위하게 사용되지 못하고 사람의 손이 닿지 않는 곳 등에 극히 제한적으로 만 사용되는 단점이 있었다. In order to put a desired pattern on the surface of a conventional plastic, processed wood, etc., the film on which the pattern is printed is transferred by applying heat and pressure. Such a conventional transfer film is not strong enough to transfer various kinds of methyl ethyl ketone, ethyl acetate, etc. 4-5 times wiped with the material not only erased the printed pattern, but also had the disadvantage that the scratch easily occurs even a small scratch. In other words, the conventional transfer paper has a structure of a release layer-printing layer-adhesive layer on the inner surface of the PET film, and transferred the transfer paper by applying heat and pressure to a transfer object such as plastic, and then peeled off the PET film to transfer the printing layer. Only the layer served as a protective layer of the printed layer. Therefore, there is a disadvantage that the printing layer is easily erased on organic materials, the light resistance is inferior, the printing color is easily discolored, and the scratch color is also weak, so that it is not widely used and can be used in a very limited place.
따라서, 본 발명의 목적은 상기한 문제점을 해결하여 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 우수한 열전사 필름을 제공하기 위한 것이다. Accordingly, an object of the present invention is to solve the above problems to provide a thermal transfer film excellent in wear resistance, chemical resistance, solvent resistance, light resistance and scratch resistance.
본 발명의 또 다른 목적은 상기와 같은 열전사필름의 제조방법을 제공하기 위한 것이다. Still another object of the present invention is to provide a method of manufacturing a thermal transfer film as described above.
상기와 같은 본 발명의 목적은 폴리에틸렌테레프탈레이트(PET)필름층, 인쇄층의 분리를 용이하게 하는 제1 이형층, 탑 경화제가 상기 제1 이형층으로의 침투를 방지하는 제2 이형층, 탑 경화 코팅층, 인쇄층 및 접착층으로 구성된 탑 경화 코팅 열전사 필름 및 그 제조방법을 제공함으로서 달성되어질 수 있다. The object of the present invention as described above is a polyethylene terephthalate (PET) film layer, the first release layer to facilitate separation of the printing layer, the second release layer, the top curing agent to prevent penetration into the first release layer, the top It can be achieved by providing a top cured coating thermal transfer film composed of a cured coating layer, a printing layer and an adhesive layer and a method of manufacturing the same.
상기 목적을 달성하기 위한 본 발명은 The present invention for achieving the above object
a)코로나 처리가 되지 않은 16-25㎛의 유광과 19-25㎛의 무광(Matt)필름을 사용한 PET 필름;a) PET film using 16-25 μm gloss and 19-25 μm Matt film without corona treatment;
b)아크릴 공중합체(acrylic copolymer), 합성 왁스, 톨루엔, 메틸 에틸 케톤(methyl ethyl ketone)을 구성성분으로 하는 제1 이형층; b) a first release layer composed of an acrylic copolymer, synthetic wax, toluene, methyl ethyl ketone as a component;
c)아크릴 공중합체, 합성 왁스, 톨루엔, 메틸 에틸 케톤을 구성성분으로 하는 제2 이형층; c) a second release layer composed of acrylic copolymer, synthetic wax, toluene, methyl ethyl ketone as a component;
d)폴리우레탄 수지(polyurethane resin), 변성 아크릴 수지(modified acrylic resin), 실리카 분말(silica powder), 메틸 에틸 케톤(MEK)으로 된 이액형 구성성분을 경화제와 혼합하여 이루어진 탑 경화 코팅층; d) a top curing coating layer comprising a two-component component consisting of polyurethane resin, modified acrylic resin, silica powder, methyl ethyl ketone (MEK) and a curing agent;
e)인쇄층; 및 e) printing layer; And
f)사출물의 원료에 따라 아크릴로니트릴-부타디엔-스티렌(ABS), 폴리프로필렌(PP), 폴리에틸렌(PE) 등의 접착제를 도포한 접착제층으로 구성됨을 특징으로 하는 탑 경화 코팅 열전사 필름을 제공한다. f) providing a top hardened coating thermal transfer film comprising an adhesive layer coated with an adhesive such as acrylonitrile-butadiene-styrene (ABS), polypropylene (PP), polyethylene (PE), etc. do.
상기 탑 경화 코팅층은 이액형 구성성분과 경화제의 혼합 비율을 4:1로 함이 바람직하다.상기 제1 이형층은 왁스, 충전제 등과 같은 통상의 부가제를 포함할 수 있다. The top cured coating layer preferably has a mixing ratio of the two-component component and the curing agent to 4: 1. The first release layer may include conventional additives such as waxes, fillers, and the like.
상기 접착제층의 PP 접착제는 폴리프로필렌 공중합체(polypropylene copolymer), 합성 왁스, 톨루엔을 구성성분으로 하고, ABS 접착제는 아크릴 공중합체, 합성 수지, 톨루엔, MEK를 구성성분으로 한다. 상기 PP 접착제 및 ABS 접착제는 통상의 부가제, 예를 들면 충전재 등을 포함할 수 있다. The PP adhesive of the adhesive layer includes polypropylene copolymer, synthetic wax, and toluene as components, and the ABS adhesive includes acrylic copolymer, synthetic resin, toluene, and MEK as components. The PP adhesive and the ABS adhesive may include conventional additives, for example fillers.
본 발명에 따른 탑 경화 코팅 열전사 필름을 원하는 판제 위에 올려놓고 170-210℃로 가열된 고무롤로 전사하여 원하는 무늬가 전사된 제품을 얻을 수 있다.The top cured coating thermal transfer film according to the present invention is placed on a desired plate and transferred to a rubber roll heated to 170-210 ° C. to obtain a product having a desired pattern transferred thereon.
본 발명의 일 구성인 상기 PET필름은 전사지를 약 170-210℃의 열 고무 롤로 전사 할 때 필름이 열에 강하여 쉽게 녹지 않을 뿐 아니라, 쉽게 변형이 가지 않는 작용효과가 있다.The PET film of one configuration of the present invention has a functional effect that the film is not easily melted due to heat, and is not easily deformed when the transfer paper is transferred to a thermal rubber roll of about 170-210 ° C.
또한, 제1 이형층을 형성시킴으로서, 전사 시 열과 압이 가해지면 필름과 인쇄층의 분리를 용이하게 하여 전사를 원활히 하게 할 수 있으며, 제2 이형층을 형성시켜 탑 경화층의 성분이 제1 이형층으로 침투함을 방지하여 열 전사 시 필름과 잉크층의 분리를 불가능하게 하는 현상을 방지하는 작용을 갖게 한다.In addition, by forming the first release layer, when heat and pressure are applied during the transfer, the separation of the film and the print layer can be facilitated to facilitate the transfer, and the second release layer is formed to form the first cured layer. By preventing penetration into the release layer has a function to prevent the phenomenon of the separation of the film and the ink layer during the thermal transfer.
한편, 탑 경화 코팅층은 전사된 인쇄층을 보호하여 유기용재나 마모 또는 스크래치에 잘 견딜 수 있게 한다.On the other hand, the top cured coating layer protects the transferred printing layer to be able to withstand organic materials or wear or scratch well.
인쇄층에는 다양한 무늬와 색상을 실현시킬 수 있으며, 접착제층은 사출물에 전사지의 접착을 보다 견고하고 용이하게 한다.Various patterns and colors can be realized in the printed layer, and the adhesive layer makes the transfer paper more firm and easy to adhere to the injection molded product.
특히, 접착제층은 동판 100호 목(目)으로 1번 접착하며, 두께는 20㎛정도로 함이 바람직하다.In particular, the adhesive layer is bonded once to the copper plate No. 100 (目), the thickness is preferably about 20㎛.
이하 본 발명의 바람직한 실시형태를 도면을 참고로 보다 자세히 설명하지만, 본 발명이 여기에 한정되는 것은 아니다.Preferred embodiments of the present invention are described in more detail below with reference to the drawings, but the present invention is not limited thereto.
먼저 코로나 처리가 되지 않은 16-25㎛의 유광과 19-25㎛의 무광(Matt)필름을 사용하여 형성한 제1층인 PET 필름층(1)에 아크릴 공중합체 18%, 합성 왁스 1%, 톨루엔 40%, 메틸 에틸 케톤 36%로 구성된 제1 이형층(2)과 아크릴 공중합체 19%, 합성 왁스 3%, 톨루엔 42% 및 메틸 에틸 케톤 36%으로 구성된 제2 이형층(3)을 순차로 도포한 후, 폴리우레탄 수지 20%, 변성 아크릴 수지 10%, 실리카 분말 2%, 메틸 에틸 케톤 68%로 된 이액형 성분을 경화제와 4:1로 혼합하여 수득된 탑 경화 코팅층(4)을 도포 한다. 여기에 다양한 무늬를 갖는 인쇄층(5)을 형성한 후, 사출물의 원료에 따라서 PP 접착제로는 폴리프로필렌 공중합체 20%, 합성 왁스 2%, 톨루엔 75%로 구성된 접착제층(6)이나, ABS 접착제로 아크릴 공중합체 20%, 합성 수지 15%, 톨루엔 30%, MEK 30%로 구성된 접착제층(6)을 도포하여 본 발명의 탑 경화 코팅 열전사 필름을 제조할 수 있다. 이렇게 수득된 탑 경화 코팅 열전사 필름을 원하는 플라스틱 판제 위에 올려 놓고 170-210℃로 가열된 고무롤로 전사하여 원하는 제품을 얻을 수 있다. 상기 제1 이형층(2)은 왁스, 충전제 등과 같은 통상의 부가제를 포함할 수 있으며, 상기 PP 접착제 및 ABS 접착제는 충전제 등과 같은 통상의 부가제를 포함할 수 있다.First, 18% acrylic copolymer, 1% synthetic wax, and toluene in the PET film layer 1, which is the first layer formed using 16-25 µm glossy and 19-25 µm matt film without corona treatment. First release layer (2) consisting of 40%, methyl ethyl ketone (36) and 19% acrylic copolymer, second release layer (3) consisting of 3% synthetic wax, 42% toluene and 36% methyl ethyl ketone After coating, the top curing coating layer 4 obtained by mixing a two-component component of 20% polyurethane resin, 10% modified acrylic resin, 2% silica powder, and 68% methyl ethyl ketone with a curing agent was applied. do. After forming the printed layer 5 having various patterns therein, the adhesive layer 6 composed of 20% polypropylene copolymer, 2% synthetic wax, 75% toluene, or ABS, depending on the raw material of the injection molding An adhesive layer 6 composed of 20% of an acrylic copolymer, 15% of a synthetic resin, 30% of toluene, and 30% of MEK may be applied as an adhesive to prepare a top curing coated thermal transfer film of the present invention. The top cured coating thermal transfer film thus obtained is placed on a desired plastic sheet and transferred to a rubber roll heated to 170-210 ° C. to obtain a desired product. The first release layer 2 may include conventional additives such as wax, filler, and the like, and the PP adhesive and ABS adhesive may include conventional additives such as filler and the like.
상기 실시형태에 따라 수득된 제품은 탑 경화 코팅층이 잉크층을 효과적으로 보호함으로 하여 유기용제, 마모 및 습기에 강하여 다양한 건축 내장제나 마모나 스크래치 또는 습기의 위험이 있는 제품이나 장소에 다양하게 사용될 수 있어, 종래 유기용제, 마모, 스크래치 및 습기에 약하여 일부의 생활 용품이나 건축물의 천정등 사용자의 손길이 닿지 않는 극히 제한된 부분에만 사용될 수 있던 전사지의 단점을 해결하였다. 더욱이 근래 욕실장을 만들 때 PS 발포에 본 발명의 탑 경화 코팅 열전사 필름을 적용하면 종래의 PVC 랩핑지의 PVC 자체에 함유된 DOP 등의 유해성분은 물론 습기에 약하여 얼마 지나지 않아서 접착이 떨어져 사용이 불가능하게되는 등의 단점을 극복할 수 있다. The product obtained according to the above embodiment can be used in various building interiors or products or places where the risk of abrasion, scratches or moisture due to the top hardened coating layer effectively protects the ink layer and resistant to organic solvents, abrasion and moisture. In addition, it solves the drawbacks of the transfer paper, which was weak to organic solvents, abrasion, scratches, and moisture, which could be used only in extremely limited parts, such as some household items or ceilings of buildings, which are not touched by the user. Moreover, when the top curing coating thermal transfer film of the present invention is applied to PS foam when making bathrooms, it is not easy to use because it is weak due to moisture as well as harmful ingredients such as DOP contained in PVC itself of conventional PVC wrapping paper. It can overcome the disadvantages such as.
상기 구성에 따른 본 발명은, 전사된 표면이 강하지 않아서 각종 용재로 4-5회만 닦아도 인쇄된 무늬가 지워질 뿐 아니라, 조그마한 긁힘에도 쉽게 스크래치가 발생하는 종래의 일반 전사필름의 단점을 제거하여, 내마모성, 내약품성, 내용제성, 내광성 및 내스크래치성이 월등히 우수할 뿐 만 아니라 내구성이 우수하여 경제성 또한 뛰어난 탑 경화 코팅 열 전사 필름의 제조방법 및 이 필름의 전사방법을 제공하는 유용한 발명이다. According to the present invention, the transferred surface is not strong, and the printed pattern is not only erased even after wiping only 4-5 times with various materials, but also eliminates the disadvantages of the conventional general transfer film, which easily scratches even a small scratch, and wear resistance. It is a useful invention that provides a method for producing a top-curing coating thermal transfer film and a method for transferring the film, which are excellent in chemical resistance, solvent resistance, light resistance and scratch resistance, as well as excellent durability.
도 1은 본 발명에 따른 탑 경화 코팅 열 전사 필름의 층 상 구조를 나타내는 개략도이다. 1 is a schematic view showing the layered structure of the top curing coating heat transfer film according to the present invention.
*도면의 주요 부호의 설명 * Explanation of the main signs in the drawings
1...PET필름층. 2...제1이형층. 1 ... PET film layer. 2. First release layer.
3...제2이형층. 4...탑 경화 코팅층. 3. Second release layer. 4 ... top hardened coating layer.
5...인쇄층. 6...접착제층.5 ... print layer. 6. Adhesive layer.
Claims (3)
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Cited By (2)
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KR101803414B1 (en) | 2015-05-21 | 2017-12-20 | 이걸구 | Transfer film |
KR102618862B1 (en) * | 2023-07-28 | 2023-12-27 | 민광표 | Edge Strip for Furniture Panel to Exert Matt Effect on PET Substrate and Method for Manufacturing the Same |
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KR100893698B1 (en) * | 2008-04-30 | 2009-04-20 | (주)디오텔레콤 | Thermal transfer film and method for fabricating case of electrical device using the same |
KR101146146B1 (en) * | 2010-02-26 | 2012-05-16 | (주)이네이쳐 | Eco-friendly tape with biodegradable film and water soluble adhesive |
KR101146145B1 (en) * | 2010-02-26 | 2012-05-16 | (주)이네이쳐 | Eco-friendly kraft tape writing well on the surface |
KR101146147B1 (en) * | 2010-02-26 | 2012-05-16 | (주)이네이쳐 | Eco-friendly same color aluminum tape |
KR101427197B1 (en) * | 2012-11-16 | 2014-08-07 | 신영페트 주식회사 | Polyethylen terephthalate having glue layer and Its methode |
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JPH111656A (en) * | 1997-06-12 | 1999-01-06 | Hodogaya Kenzai Kogyo Kk | Aqueous primer composition |
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KR200211973Y1 (en) * | 2000-08-25 | 2001-02-01 | 황석화 | Transfer paper |
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JPH07304275A (en) * | 1994-05-11 | 1995-11-21 | Dainippon Printing Co Ltd | Protective layer transfer film and printed material |
JPH0986095A (en) * | 1995-09-21 | 1997-03-31 | Toppan Printing Co Ltd | Transfer sheet, transfer decorative material, and manufacture thereof |
KR100282701B1 (en) * | 1996-12-03 | 2001-02-15 | 정종석 | Gravure transcripts used for nonabsorbable surfaces such as metal plates and transfer methods using them |
JPH111656A (en) * | 1997-06-12 | 1999-01-06 | Hodogaya Kenzai Kogyo Kk | Aqueous primer composition |
KR100272202B1 (en) * | 1998-07-29 | 2000-12-01 | 정종석 | Heating transcription film and method copyig of direct on the mdf plane and the edge part |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101803414B1 (en) | 2015-05-21 | 2017-12-20 | 이걸구 | Transfer film |
KR102618862B1 (en) * | 2023-07-28 | 2023-12-27 | 민광표 | Edge Strip for Furniture Panel to Exert Matt Effect on PET Substrate and Method for Manufacturing the Same |
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