KR100471005B1 - Manufacturing method of magnetized Humus soil. - Google Patents
Manufacturing method of magnetized Humus soil. Download PDFInfo
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- KR100471005B1 KR100471005B1 KR10-2002-0068296A KR20020068296A KR100471005B1 KR 100471005 B1 KR100471005 B1 KR 100471005B1 KR 20020068296 A KR20020068296 A KR 20020068296A KR 100471005 B1 KR100471005 B1 KR 100471005B1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/10—Packings; Fillings; Grids
- C02F3/105—Characterized by the chemical composition
- C02F3/107—Inorganic materials, e.g. sand, silicates
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F2003/001—Biological treatment of water, waste water, or sewage using granular carriers or supports for the microorganisms
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00422—Magnetic properties
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- Inorganic Chemistry (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Biological Treatment Of Waste Water (AREA)
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Abstract
본 발명은 미생물배양공정 등에 사용하는 자성부식토(磁性腐植土)의 제조방법 을 제시하는 것을 목적으로 한다.An object of the present invention is to provide a method for producing magnetic corrosive soils for use in microbial culture.
이를 위하여 본 발명은. 부식물질(이탄)에 풍화작용을 받기 쉬운 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石), 각섬석(角閃石), 감람석(橄欖石), 흑운모(黑雲母), 유문암(流紋岩), 천매암(千枚岩), 거정석(巨晶石), 흑요석(黑曜石), 진주암(珠岩), 송지암(松脂岩), 맥반석(飯石) 등과 같이 광물의 분말과 자화자철광(磁鐵鑛 ; FeOㆍFe2 O3 )을 혼합한 다음 교반혼합을 하면서 2∼3개월이상 숙성하여 자성을 가진 분말상태의 부식토를 제조한 다음 이들에 알긴산소다(Sodium alginate), 키토산(Chitosan)수지, 셀룰로오스(Cellulose)계수지 등의 바인더(Binder)를 공급하여 교반혼합한 후 펠렛트(Pellet)사출기로 보내어 펠렛트 형태로 사출 한 후 건조공정으로 보내어 건조하여 펠렛트 형태의 자성부식토를 제조 한다.To this end, the present invention. Rhyolite or Dacite-like pumice, hornblende, olivine, biotite, and rhyolite that are susceptible to weathering by corrosive substances 매, cheonmaeam, giant stone, obsidian, pearlite 지, Songji-am, and Elvan After mixing mineral powder and magnetite magnetite (FeO · Fe 2 O 3 ), such as 飯 石, and aged by mixing for 2 ~ 3 months with stirring and mixing to prepare magnetic powdery corrosive soil. Binders such as Sodium Alginate, Chitosan Resin, Cellulose Resin, etc. are supplied, stirred and mixed. It is dried to prepare pellets of magnetic corrosion soil.
특이한 사항은 하ㆍ폐수처리, 악취처리의 미생물배양공정에 자성부식토를 이용하였을 때는 처리효율이 우수하며 설치비 및 운전비용도 종래의 처리방법에 비해서 월등히 우수하며, 가축음용수처리의 미생물배양공정에 적용하였을 때는 성장속도 및 육질의 향상효과가 있기 때문에 이들 분야에 널리 이용될 것으로 전망된다.Unique matters are excellent in treatment efficiency when magnetic corrosive soil is used in microbial culture process of sewage, wastewater treatment and odor treatment, and installation cost and operation cost are much better than conventional treatment methods, and applied to microbial culture process of livestock drinking water treatment. It is expected to be widely used in these fields because of the effect of improving the growth rate and meat quality.
Description
본 발명은 부식물질(이탄)에 풍화작용을 받기 쉬운 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石), 각섬석(角閃石), 감람석(橄欖石), 흑운모(黑雲母), 유문암(流紋岩), 천매암(千枚岩), 거정석(巨晶石), 흑요석(黑曜石), 진주암(珠岩), 송지암(松脂岩), 맥반석(飯石 ), 화산회토 등과 같은 풍화작용을 받기 쉬운 광물의 분말과 자화자철광(磁化磁鐵鑛 ; Fe3 O4 )을 혼합한 다음 교반혼합을 하면서 2∼3개월이상 숙성하여 분말상태의 자성부식토(磁性腐植土)를 제조한 다음 이들에 알긴산소다(Sodium alginate), 키토산(Chitosan)수지, 셀룰로오스(Cellulose)계수지 등의 바인더(Binder)를 공급하여 교반혼합한 후 펠렛트(Pellet)사출기로 보내어 펠렛트 형태로 사출 한 후 건조공정으로 보내어 건조하여 펠렛트 형태의 자성부식토를 제조 한다.The present invention is a pyrite (Dacite) pumice, hornblende, olivine, biotite, black mica, which is susceptible to weathering of corrosive substances (peat), Rhyolite, Cheonmae-am, Giant Stone, Obsidian, Pearl Rock 지, Songji-am, and Elvan Powders of magnetic corrosive soils after mixing for 2 ~ 3 months by mixing and mixing the mineral powder which is easy to weathering such as 飯 石), volcanic ash and magnetizing magnetite (Fe 3 O 4 ).腐植土) After supplying binders such as sodium alginate, chitosan resin, cellulose resin, etc., they are stirred and mixed, and then sent to pellet injection machine After injection in the form of a form, it is sent to a drying process and dried to prepare a pellet of magnetic corrosion soil.
일본 특허공보 평(平) 5-66199호 생물학적 폐수처리의 미생물배양조에 부식질(腐植質) 펠렛트(Pellet)와 유문암 또는 대사이드(Dacite)질의 부석(Pumice)을 충전한 생물반응기(Bio-reactor)를 설치하고 처리결과 일반 활성오니법에 비해서 처리효율이 향상되었으나 무기부석광물(無機浮石鑛物)을 사용하므로 미생물에 미네랄 공급능력이 떨어져 시운전 경우나 비정상운전의 경우 정상상태로 회복하는데 장시간 소요되는 문제점이 있었다.Japanese Patent Publication No. 5-66199 Bio-reactor packed with humus pellets and rhyolite or dulceum-like pumice in a microbial culture tank for biological wastewater treatment ), And as a result of treatment, the treatment efficiency is improved compared to the general activated sludge method, but because inorganic minerals are used, the ability to supply minerals to microorganisms decreases, so that it takes a long time to recover to a normal state in case of commissioning or abnormal operation. There was a problem.
본 발명은 생물학적 하ㆍ폐수처리, 생물학적 악취처리, 가축음용수처리 등의 미생물배양공정에 적용하여 미생물배양 효율을 향상할 수 있는 자성부식토의 제조방법을 제시하는 것이 목적이다.It is an object of the present invention to propose a method for producing magnetic corrosive soil which can be applied to microbial culture processes such as biological sewage and wastewater treatment, biological odor treatment and livestock drinking water treatment.
이와 같은 목적을 달성하기 위한 본 발명은, 전술한 부식물질(이탄)에 풍화가 용이한 광물인 유문암 또는 대사이드질 부석, 각섬석, 감람석, 흑운모, 유문암, 천매암, 거정석, 흑요석, 진주암, 송지암, 맥반석과 같은 광물의 분말과 자성자철광분말을 혼합교반하면서 2∼3개월 이상 숙성하여 미생물에 미네랄 공급이 용이한 자성부식토 제조방법을 제시 한다.In order to achieve the above object, the present invention is a mineral that is easy to weather in the above-mentioned corrosive substance (peat), rhyolite or large-scale pumice, hornblende, olivine, biotite, rhyolite, feldspar, macrorite, obsidian, pearlite and pine The present invention proposes a method for producing magnetic corrosive soils which is easy to supply minerals to microorganisms by mixing and stirring mineral powders such as rock and elvan, and magnetic magnetite powder.
부식물질(이탄)에 함수율이 50wt%이하인 경우에는 물을 가해서 함수율을 50∼60wt%로 조정한 다음에 교반혼합을 하면서 염산이나 황산과 같은 광산(鑛酸)을 주입하여 pH를 1.5∼2.5로 조정하여 부식물질 중 풀브산(Fulvic acid)을 유리(遊離)시킨 다음 이들에 가능한 자속밀도(磁束密度)가 200G(Gauss) 이상 자화된 자철광분말을 5∼15wt% 공급하여 교반 혼합하면서 유문암(流紋岩) 또는 대사이드(Dacite)질의 부석(浮石), 각섬석(角閃石), 감람석(橄欖石), 흑운모(黑雲母), 유문암(流紋岩), 석영안산암(石英安山岩), 천매암(千枚岩), 거정석(巨晶石), 흑요석(黑曜石), 진주암(眞珠岩), 송지암(松脂岩), 맥반석(麥飯石), 알로페인(Allophane)질화산회토 등과 같이 풍화작용을 받기 쉬운 조암광물(造岩鑛物) 성분이 다량 함유된 광물의 분말을 1종류 이상 유기물/무기물의 무게 비(比)가 0.8∼1.2의 범위로 주입하여 교반혼합을 하면서 60일 이상 숙성하여 부식물질과 광물질이 반응한 자성을 가진 자성부식토를 만든다.If the water content is 50wt% or less, the water content is adjusted to 50 ~ 60wt% by adding water. Then, the mixture is stirred and injected with a mineral acid such as hydrochloric acid or sulfuric acid to bring the pH to 1.5 ~ 2.5. After liberation of Fulvic acid among the corrosive materials, 5-15 wt% of magnetite powder with magnetized magnetic flux density of 200 G (Gauss) or higher was supplied to them. Pumice or Dacite stone, hornblende, olivine, biotite, rhyolite, rhyolite, quartz andesite, and natural stone Weathering processes such as gelatinite, obsidian, obsidian, pearlite, songjiam, elvan, allophane nitrate Weight ratio of one or more types of organic / inorganic minerals containing mineral powder containing a large amount of easy-to-receivable Injection in the range of 0.8 to 1.2 and the mixture aged for 60 days or more, with stirring to make the mold with a corrosion magnetic material and a magnetic minerals reaction.
그리고, 필요에 따라서는 이 자성부식토에 알긴산소다(Sodium alginate), 키토산(Chitosan)수지, 셀룰로오스(Cellulose)수지 등의 수용액을 바인더로 3∼5wt% 가해서 교반 혼합한 후 구상의 펠렛트(Pellet)상이나 환상으로 가공한 다음 4∼5일간 자연 건조한 후 유기성바인더가 변성되지 않은 범위인 100∼250℃의 열풍으로 건조하여 자성부식토 펠렛트를 제조한다.If necessary, 3 to 5 wt% of an aqueous solution of sodium alginate, chitosan resin, cellulose resin, or the like is added to the magnetic corrosion soil with a binder, followed by stirring and mixing, and then spherical pellets. After processing in phase or annular form and naturally drying for 4 to 5 days, the organic binder is dried by hot air at 100-250 ° C. in which the organic binder is not denatured to prepare a magnetic corrosion soil pellet.
이때 원료 부식물질은 가능한 풀브산(Fulvic acid) 함량이 높은 해양성 플랑크톤(Plankton), 해조류(海藻類), 해초 및 어류와 같은 동ㆍ식물의 유체(遺) 등이 퇴적되어 생성된 해양성부식물질을 사용한다.At this time, the raw material corrosives are fluids of animals and plants such as marine plankton, seaweeds, seaweeds and fish with high content of fulvic acid. ) Use marine corrosive material produced by the accumulation of
자성부식토는 생물학적 하ㆍ폐수처리, 생물학적 악취처리, 가축음용수처리 등의 미생물배양공정과 유기성폐기물의 퇴비화공정의 발효촉진제 및 토양개량제 등에 널리 사용한다.Magnetic corrosive soils are widely used in microbial culture processes such as biological sewage and wastewater treatment, biological odor treatment, livestock drinking water treatment, fermentation accelerators, and soil improving agents in the composting process of organic waste.
전술한 기술내용으로부터 자명하듯이, 본 발명의 자성부식토는 생물학적 하ㆍ폐수처리, 생물학적 악취처리, 가축음용수처리 등의 미생물배양공정에 사용 하였을 때 미생물배양효율이 아주우수하며, 유기성폐기물의 퇴비화공정에 사용하였을 때는 발효숙성 효율이 향상되며, 토양개량제로 사용하였을 때는 토양 입단구조가 향상되는 등의 효과가 있기 때문에 이들 분야에 널리 보급 될 것으로 기대 된다.As is apparent from the foregoing description, the magnetic corrosive soil of the present invention has excellent microbial culture efficiency when used in microbial culture processes such as biological sewage, wastewater treatment, biological odor treatment, and animal drinking water treatment, and organic waste composting process. When it is used in the fermentation aging efficiency is improved, when used as a soil improving agent is expected to be widely spread in these fields because of the effect of improving the soil grain structure.
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JPS61211393A (en) * | 1985-03-18 | 1986-09-19 | Takezo Aonuma | Soil conditioner |
JPH07116683A (en) * | 1993-10-27 | 1995-05-09 | Esutemu:Kk | Silicate adding activated sludge method |
JPH10215684A (en) * | 1997-02-07 | 1998-08-18 | Gold Kosan Kk | Plant cultivation device |
JPH11104221A (en) * | 1997-09-30 | 1999-04-20 | Human Ecology Asutec:Kk | Production of liquid deodorant |
KR20010088932A (en) * | 2001-08-08 | 2001-09-29 | 서영준 | Method for sewage and wastewater treated use of the activated humic substance |
KR20040035539A (en) * | 2002-10-22 | 2004-04-29 | 서희동 | Production method of magnetized compost. |
KR20040037706A (en) * | 2002-10-29 | 2004-05-07 | 서희동 | Manufacturing and using method for pellet of magnetized oceanic humic acid colloidal micelle |
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS61211393A (en) * | 1985-03-18 | 1986-09-19 | Takezo Aonuma | Soil conditioner |
JPH07116683A (en) * | 1993-10-27 | 1995-05-09 | Esutemu:Kk | Silicate adding activated sludge method |
JPH10215684A (en) * | 1997-02-07 | 1998-08-18 | Gold Kosan Kk | Plant cultivation device |
JPH11104221A (en) * | 1997-09-30 | 1999-04-20 | Human Ecology Asutec:Kk | Production of liquid deodorant |
KR20010088932A (en) * | 2001-08-08 | 2001-09-29 | 서영준 | Method for sewage and wastewater treated use of the activated humic substance |
KR20040035539A (en) * | 2002-10-22 | 2004-04-29 | 서희동 | Production method of magnetized compost. |
KR20040037706A (en) * | 2002-10-29 | 2004-05-07 | 서희동 | Manufacturing and using method for pellet of magnetized oceanic humic acid colloidal micelle |
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