KR100407898B1 - liquid illite coating material for structure's surface - Google Patents
liquid illite coating material for structure's surface Download PDFInfo
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- KR100407898B1 KR100407898B1 KR10-2000-0040977A KR20000040977A KR100407898B1 KR 100407898 B1 KR100407898 B1 KR 100407898B1 KR 20000040977 A KR20000040977 A KR 20000040977A KR 100407898 B1 KR100407898 B1 KR 100407898B1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
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- C09D7/20—Diluents or solvents
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
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Abstract
본 발명은 건축물 마감 시공재에 관한 것으로, 더욱 상세하게는 원적외선 방출 물질인 일라이트의 극미세(極微細)화한 분말을 스프레이, 페인트 붓 또는 페인트 롤러등을 이용하여 건축물의 바닥, 벽, 천정등에 코팅할 수 있도록 액상으로 만든 건물 바닥 시공용 액상 일라이트 도포제에 관한 것이다.The present invention relates to a building finishing material, and more particularly to the floor, walls, ceilings, etc. of the building using a spray, paint brush or paint roller, etc. The present invention relates to a liquid illite coating agent for building floors made of a liquid to be coated.
본 발명에 따른 액상일라이트도포제는 2000 내지 3000메쉬로 극미세(極微細)하게 분쇄한 중량비 60% 내지 80%의 일라이트분말과, 상기 일라이트분말과 교반되어 액상을 유지하도록 하는 용재를 포함하여 구성되는 것을 특징으로 한다.Liquid illite coating agent according to the present invention includes an illite powder having a weight ratio of 60% to 80% pulverized very finely into 2000 to 3000 mesh, and a solvent to maintain a liquid phase by stirring with the illite powder Characterized in that the configuration.
또한 본 발명에 따른 액상일라이트도포제는 상기 일라이트분말에 2000 내지 3000메쉬로 극 미세 분쇄한 숯분말을 10% 내지 20%(중량비) 혼합한 후 상기 용제와 교반하여 형성하는 것을 특징으로 한다.In addition, the liquid illite coating agent according to the invention is characterized in that it is formed by stirring with the solvent after mixing 10% to 20% (weight ratio) of the finely ground charcoal powder to 2000 to 3000 mesh to the illite powder.
본 발명에 따를 경우, 인체에 원적외선을 방사하여 신진대사촉진 및 세포활성화기능을 하는 일라이트를 기성 건물이나, 신축건물에 스프레이 방법등을 통해 용이하게 도포할 수 있는 액상의 일라이트 함유제를 싼 값에 제공할 수 있다. 뿐만아니라, 일라이트를 건축물바닥재로 시공함에 있어서 종래의 모르타르 형식으로 하는 경우보다 시공 시간, 시공 비용을 줄이고 작업이 용이하며, 기성 건축물에 대하여도 간단하게 시공할 수 있어 원적외선 방사물질의 일반적 보급에 기여하는 효과가 있다.According to the present invention, a liquid containing an illite containing a liquid that can be easily applied to the existing building, or a new building by spraying an illite that promotes metabolism and cell activation by radiating far infrared rays to the human body. You can provide a value. In addition, when constructing an illite as a building floor material, the construction time and construction cost are reduced and the work is easier than in the case of the conventional mortar type. There is a contributing effect.
Description
본 발명은 건축물 마감 시공재에 관한 것으로, 더 상세하게는 원적외선 방출 물질인 일라이트의 극미세화(極微細化)한 분말을 스프레이, 페인트 붓 또는 페인트 롤러등을 이용하여 건축물의 바닥, 벽, 천정등에 코팅할 수 있도록 액상으로 만든 건축물 마감시공용 액상 일라이트 도포제에 관한 것이다.The present invention relates to a building finishing material, and more specifically, to the floor, wall, ceiling of a building using a spray, paint brush or paint roller, etc. It relates to a liquid illite coating for building finishing made of a liquid to be coated on the back.
또한, 본 발명은 일라이트의 극미세(極微細)분말에 숯의 극미세(極微細)분말을 적량 혼합하여 액상으로 만듬으로써 용이하게 원적외선 방출층 및 강력한 세균차단층을 건물 바닥에 형성할 수 있는 건물 바닥 시공용 액상 일라이트 도포제에 관한 것이다.In addition, the present invention can easily form a far-infrared emitting layer and a strong bacterial barrier layer on the floor of the building by mixing the fine powder of the illite with the fine powder of charcoal into a liquid phase. The present invention relates to a liquid illite coating agent for building floors.
근래, 원전외선 방사물질에 대한 관심과 연구가 고조되고 있는 바, 원적외선 방사물질중의 하나인 일라이트(illite)[KAℓ4(AℓSi7O20)(OH)4]는 점토모양의 연질운모 광물로서 바이오세라믹과 같이 원적외선과 음이온을 방출하는데, 이러한일라이트에서 방출되는 원적외선은 인체에 가장 좋은 5∼20마이크로 미터의 파장범위에 속하는 원적외선이기 때문에 인체에 가장 깊숙이 침투하여 신진대사를 촉진해주고 혈액순환을 좋게 하여 효소의 생성을 부활시키고 노화된 세포를 활성화시켜 인체내의 노폐물과 잉여 지방질의 배설을 촉진시키는 작용을 하는 것으로 알려져 있을 뿐만 아니라, 값싸게 고방사율(상온에서 5∼25㎛ 파장기준 88% ~ 93%)의 원적외선을 얻을 수 있는 물질로 각광 받고 있다.Recently, as interest and research on nuclear radiation emitters are increasing, one of the far infrared radiation emitters, illite [KAℓ 4 (AℓSi 7 O 20 ) (OH) 4 ], is a clay-like soft mica mineral. Like bioceramic, it emits far infrared rays and anions. Far infrared rays emitted from these lights are far infrared rays within the wavelength range of 5-20 micrometers, which is the best for the human body. It is known to act to promote the production of enzymes by activating the aging cells to promote the excretion of waste and excess fat in the human body, as well as inexpensive high emissivity (88% at 5-25㎛ wavelength at room temperature) ~ 93%) is gaining the spotlight as a material capable of obtaining far infrared rays.
일라이트의 이러한 효율을 활용하기 위하여 다양한 관련 개발이 이루어 지고 있는바, 각종 유독가스와 악취제거, 정균작용(바이러스, 박테리아 등을 제거)을 활용하여 냉장고나 축사의 탈취제가 개발되어 시판되고 있고, 동물의 사료에 섞어 먹일 경우 육질이 좋아지고 사료비를 절감할 수 있는 효능을 살려 일라이트함유 사료가 개발되어 있으며, 그 밖에도 생필품(비누, 치약등)등에 첨가 재료로 사용하거나 침대, 복대, 방석, 의류 등의 소재로 개발되어 시판되고 있는 실정입니다.Various related developments are being made to utilize the efficiency of the illite, and deodorants of refrigerators or houses are developed and marketed by utilizing various toxic gases, odor removal, bacteriostatic action (removal of viruses, bacteria, etc.), When mixed with animal feed, the meat is improved and the feed containing light has been developed to take advantage of the effect of reducing feed costs.In addition, it is used as an additive material for daily necessities (soap, toothpaste, etc.), or in bed, bags, cushions, It is developed and marketed using materials such as clothing.
뿐만 아니라, 일라이트가 인체의 혈액순환과 신진대사를 촉진시키는 점을 활용하여 주택, 아파트 또는 빌딩등 건축물의 바닥 마감재로도 사용되고 있는데, 이와 관련하여 그 시공 방법은 매우 다양하게 개발되고 있는 실정입니다.In addition, it is used as a floor finishing material for buildings such as houses, apartments, or buildings by taking advantage of the fact that illite promotes blood circulation and metabolism of the human body. In this regard, construction methods have been developed in various ways. .
대한민국 특허공개공보 공개번호 특1999-98호에는 일라이트를 30내지 58중량% 함유하고, 여기에 경소 마그네시아(MgO), 황산 마그네슘(MgSO4)을 더하여 압축성형함으로 압축강도가 40-380Kgf/㎠인 원적외선방사 온돌바닥재가 개시되어 있다. 이러한 온돌 벽돌재는 그 성형 및 시공 과정에 많은 시간과 비용이 소요되고 전문적인 작업인원을 필요로 할 뿐만아리라, 특히 기성된 건축물에 적용하는데는원적외선방사 시공을 하는데는 많은 어려움이 따른다.Korean Patent Laid-Open Publication No. 1999-98 contains 30 to 58% by weight of illite, and the compression strength is 40-380 Kgf / ㎠ by adding compact magnesium (MgO) and magnesium sulfate (MgSO4). Far infrared radiation ondol flooring material is disclosed. Such ondol bricks will not only require a lot of time and money in the process of forming and constructing them, but will also require a professional workforce. In particular, it will be difficult to carry out far-infrared radiation construction for the existing buildings.
대한민국 특허공개공보 공개번호 특1999-0043936호에는 일라이트 모르타르의 제조방법이 개시되어 있고, 이러한 방법으로 실제 많은 시공이 이루어지고 있다. 즉, 일라이트(illite)분말 40-45%에 모래 30-35%, 백색시멘트 20-30비율로 배합하여 모르타르를 제조하여 바닥등의 마감 시공을 하는 방법이다. 이 방법도 공개번호 특1999-98호의 단점을 그대로 가지고 있는바, 시공하는데 비용과 시간을 과다하게 소요하고, 기성 건축물에는 용이하게 시공할 수 없다는 단점이 있다.Korean Patent Laid-Open Publication No. 1999-0043936 discloses a method for producing an illite mortar, and many constructions are made in this way. In other words, 40-45% of illite powder is mixed with 30-35% of sand and 20-30 of white cement to produce mortar and finish the flooring. This method also has the disadvantages of Publication No. 1999-98 as it is, it takes a lot of money and time to construct, and there is a disadvantage that it can not be easily installed in ready-made buildings.
뿐만 아니라 종래에는 일라이트를 액상도포제로 만드는데도 한계가 있었다.In addition, conventionally, there was a limit in making illite into a liquid coating agent.
즉, 일반적으로 시중에 공급되는 일라이트는 그 입자의 크기가 비교적 크고, 불균일하여 액상으로 할 경우에 스프레이등으로 도포하기가 곤란한 문제점이 있었다.That is, in general, the illite supplied on the market has a problem that the particle size is relatively large, and it is difficult to apply it with a spray or the like when it is a non-uniform liquid.
본 발명은 상기와 같은 문제점을 해결하기 위해 안출한 것으로, 본 발명의 제1목적은 건축물에의 바닥, 벽, 천정등에 마감시공을 하는 경우에 비용과 시간을 절감할 수 있고, 용이하게 시공할 수 있는 건축물 마감 시공용액상 일라이트 도포제를 제공하는 것이고, 본 발명의 제2목적은 종래의 도료의 용제와 교반하여 스프레이등으로 건축물의 바닥, 벽, 천정등에 용이하게 원적외선 방사층을 형성활 수 있는 건축물 마감 시공용 액상 일라이트 도포제를 제공하는 것을 목적으로 한다.The present invention has been made to solve the above problems, the first object of the present invention can reduce the cost and time when finishing the construction of the floor, wall, ceiling, etc. to the building, and can be easily installed The second purpose of the present invention is to stir the far-infrared radiation layer on the floor, wall, ceiling, etc. of the building by spraying, etc., by stirring with a solvent of a conventional coating material. It is an object of the present invention to provide a liquid illite coating agent for building finishing.
상기의 점을 고려한 본 발명에 따른 액상 일라이트 도포제는 2000 내지 3000메쉬로 극미세(極微細)하게 분쇄한 중량비 60% 내지 80%의 일라이트 분말과, 상기 일라이트분말과 교반되어 액상을 유지하도록 하는 용제를 포함하여 구성 되는 것을 특징으로 한다.상기 일라이트 분말을 용제와 혼합하는데 있어 일라이트의 중량비를 60% 내지 80%로 한정하는 이유는 도포제로서 점도를 유지할 수 있는 일라이트의 최소 중량비는 60중량% 이고, 도포제로서 액상을 유지할 수 있는 최대 중량비는 80 중량%이기 때문이다.The liquid illite coating agent according to the present invention in consideration of the above point is maintained in a liquid state by stirring with the illite powder having a weight ratio of 60% to 80%, which is pulverized very finely at 2000 to 3000 mesh, and the illite powder. The reason for limiting the weight ratio of the illite to 60% to 80% in mixing the illite powder with the solvent is the minimum weight ratio of the illite capable of maintaining the viscosity as a coating agent. Is 60% by weight, and the maximum weight ratio that can maintain the liquid phase as the coating agent is 80% by weight.
또한 본 발명에 따른 액상 일라이트 도포제는 상기 일라이트에는 2000 내지 3000메쉬로 분쇄한 숯분말을 10% 내지 20%(중량비) 혼합하여 상기 용제와 교반하는 것을 특징으로 한다. 2000-3000 메쉬로 분쇄한 중량비 20%이상의 일라이트분말과 일라이트를 수용하는 증점제 및 물을 혼합하여 건축물의 바닥 또는 벽등에 스프레이등으로 도포 가능하도록 액상으로 된 것을 특징으로 한다.상기 일라이트 분말에 10% 내지 20%의 숯을 함유하는 이유는 흡착 및 항균을 할 수 있는 숯의 최소 중량비는 10%이고, 색상을 용이하게 첨가하기 위한 숯의 최대 중량비는 20%이기 때문이다.또한 상기 용제의 전색제는 실리콘 변성 에폭시 수지, 실리콘 변성 아크릴 수지, 실리콘 변성수지 중 어느 하나인 것을 특징으로 한다.In addition, the liquid illite coating agent according to the present invention is characterized in that the char is mixed with the solvent by mixing 10% to 20% (weight ratio) of the pulverized charcoal to 2000 to 3000 mesh. The illite powder having a weight ratio of 20% or more, which is pulverized into 2000-3000 mesh, and the thickener and water containing the illite are mixed to form a liquid to be applied to the floor or wall of the building by spraying. The reason for containing 10% to 20% of charcoal is because the minimum weight ratio of charcoal capable of adsorption and antibacterial is 10%, and the maximum weight ratio of charcoal for easily adding color is 20%. The colorant is characterized in that any one of silicone modified epoxy resin, silicone modified acrylic resin, silicone modified resin.
본 발명을 실시하기 위하여는 일라이트를 극미세분말로 형성하는 것이 필수적이다.In order to practice the present invention, it is essential to form the illite as an ultra fine powder.
본발명에 있어 필수적 요소인 일라이트 극미세(極微細)분말은 다음과 같은 공정을 이용하여 제조할 수 있다.Illite ultrafine powder, which is an essential element of the present invention, can be prepared using the following process.
즉, 일정 크기로 파쇄한 일라이트 원료를 분쇄기에 투입하여 500-2000메쉬로 분쇄하고 분쇄실에 바람을 일으켜 닥터를 통해 사이클론으로 투입한후 필터로 여과하여 메쉬 1000이상의 미세입자로 분쇄된 것만 취득하고 미세분말체와 하이드로 셀파이드를 20 : 1의 체적비로 혼합한후 이를 밀개형 마찰분쇄기의 드럼에 적당량의 물과 함께 넣어 2시간 이상 마찰분쇄하여분쇄기를 회전시켜서 마찰분쇄를 통하여 반고체 상태를 얻고, 마찰분쇄기의 드럼 속에 물을 채워서 마찰분쇄기를 계속 회전시켜 불순물과 수황화된 물질을 일탈시킨후 분쇄작업을 중지하고, 물속에 침전제 및 수황화물 중화제를 투입하고 10시간 이내 방치하여 물을 뽑아내는 작업을 적어도 3회 이상 반복하여 잔유물을 얻고, 이를 방사기로 강제 방출하여 건조기에 투입시켜 200℃이상에서 10분내외로 건조시킨 후, 회전분쇄기에 투입하여 분쇄함으로써 함으로서 2000메쉬이상의 극미세(極微細) 일라이트분말을 얻을 수 있다.In other words, the crushed illite raw material is put into the crusher, pulverized into 500-2000 mesh, blown into the pulverizing chamber, introduced into the cyclone through the doctor, filtered through a filter, and only pulverized into fine particles over 1000 mesh. After mixing the fine powder and hydroselide at a volume ratio of 20: 1, put it together with a suitable amount of water in a drum of a compact friction grinding machine and friction grinding for more than 2 hours to rotate the grinding machine to obtain a semi-solid state through friction grinding. Fill the drum of the friction grinder with water to continuously rotate the friction grinder to dislodge impurities and sulphated materials, stop the grinding operation, add the precipitant and hydrosulfide neutralizer to the water, and leave it within 10 hours to extract the water. The operation is repeated at least three times to obtain a residue, which is forcibly discharged to a spinning machine and put into a drier, which is subjected to After drying in and out of powder, it is put into a rotary mill and pulverized, whereby an ultra fine illite powder of 2000 mesh or more can be obtained.
숯의 극미세(極微細)분말도 동일한 공정에 의하여 얻을 수 있다.이러한 극미세분말과 교반될 용제는 필요에 따라 다양하게 선택될 수 있다.The ultra fine powder of charcoal can also be obtained by the same process. The ultra fine powder and the solvent to be stirred can be variously selected as necessary.
상기 용제로는 무기용제나 유기용제를 사용할 수 있는데, 최근에는 오렌지 나무 추출물인 감귤유, 소나무의 추출물인 테레핀유, 유카립투스테레핀유 및 발산테레핀유를 용제등의 천연용재를 사용하기도 한다. 유기용제는 도포후 휘발 과정을 통해 냄새가 나는 결점이 있으나, 천연용제를 사용할 경우에는 이러한 문제점이 없다.As the solvent, an inorganic solvent or an organic solvent may be used. Recently, natural solvents, such as orange tree extract citrus oil, pine extract of terepin oil, yucriptus terpene oil and divergent terpene oil, may be used. Organic solvents have the drawback of smelling through the volatilization process after application, there is no such problem when using a natural solvent.
본원 발명에 따른 도포제는 일라이트 극미세분말을 일반도료의 열가소성수지, 열경화성수지를 전색제로 한 용제에 썩어 제작할 수도 있으나 방바닥등 온도가 높은 환경에서 일라이트분말이 부서지거나 탈리되지 않아야 하므로 가급적 내열성을 갖도록 제조함이 바람직하다.The coating agent according to the present invention may be produced by rotting the ultra fine powder of illite in a solvent containing a thermoplastic resin and a thermosetting resin of a general paint, but the illite powder should not be broken or detached in an environment where the temperature is high such as flooring, so that the heat resistance is as high as possible. It is preferable to manufacture so that it is.
내열성 액상일라이트 도포제의 바람직한 일시례로 일라이트분말에 ,종래의 실리콘 변성에폭시수지 또는 실리콘 변성아크릴 수지를 전색제 또는 접착제로 한 용제를 사용하거나, 실리콘 변성수지를 전색제로 한 용제를 사용할 수 도 있다.As a preferable example of the heat-resistant liquid illite coating agent, a solvent made of conventional silicone modified epoxy resin or silicone modified acrylic resin as a colorant or adhesive may be used, or a solvent containing silicone modified resin as a colorant may be used. .
점도조절용으로 크실렌, 부탄올, MIBK 등의 유기성 용제를 사용함이 바람직하다.It is preferable to use organic solvents, such as xylene, butanol, and MIBK, for viscosity adjustment.
본 방법에 의하여 액상일라이트 도포제의 합성은 경화제를 사용하지 않고 행할 수 있으나 속건을 요할 경우에는 톨루엔디이소시아네이트, 에틸아세테이트, 트리메틸알콜 또는 푸로판을 혼합한 경화제를 사용할 수 있다.Synthesis of the liquid illite coating agent by the present method can be performed without using a curing agent, but when fast drying is required, a curing agent mixed with toluene diisocyanate, ethyl acetate, trimethyl alcohol or furopan can be used.
상기의 실리콘 변성수지는 크실렌 및 셀로솔브아세테이트 혼합용액에 부틸아크릴레이트, 스티렌모노머, 메틸메타크릴레이트, 2-히드록시에틸메타크릴레이트 및 아크릴산으로 된 액상 조성물을 120-130℃에서 반응시켜서얻은 수지용액에 실리콘수지를 반응시켜 얻을 수 있다.The silicone modified resin is a resin solution obtained by reacting a liquid composition consisting of butyl acrylate, styrene monomer, methyl methacrylate, 2-hydroxyethyl methacrylate and acrylic acid at a mixture of xylene and cellosolve acetate at 120-130 ° C. It can be obtained by reacting silicone resin with.
본 발명에 따를 경우, 인체에 원적외선을 방사하여 신진대사촉진 및 세포활성화기능을 하는 일라이트를 기성 건물이나, 신축건물에 스프레이 방법등을 통해 용이하게 도포할 수 있는 액상의 일라이트 함유제를 싼 값에 제공할 수 있다.또한 일라이트를 건축물바닥재로 시공함에 있어서 종래의 모르타르 형식으로 하는 경우보다 시공 시간, 시공 비용을 줄이고 작업이 용이하며, 기성 건축물에 대하여도 간단하게 시공할 수 있어 원적외선 방사물질의 일반적 보급에 기여하는 효과가 있다.According to the present invention, a liquid containing an illite containing a liquid that can be easily applied to the existing building, or a new building by spraying an illite that promotes metabolism and cell activation by radiating far infrared rays to the human body. In addition, when constructing an illite as a building floor material, the construction time and construction cost are reduced and work is easier than in the case of the conventional mortar type. It has the effect of contributing to the general dissemination of the substance.
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| CN107033635A (en) * | 2016-11-23 | 2017-08-11 | 郑州莉迪亚医药科技有限公司 | A kind of building coating for purifying air and its preparation method and application |
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| KR100421713B1 (en) * | 2001-03-09 | 2004-03-10 | 김명식 | Multi-fluid embrocation for build ing construction |
| KR100460945B1 (en) * | 2002-03-02 | 2004-12-09 | 장정모 | A resin composite for a negative ion mineral |
| KR100703883B1 (en) * | 2005-11-04 | 2007-04-04 | 박종수 | Method of manufacturing multifunctional flooring using natural material |
| KR101284028B1 (en) * | 2011-05-23 | 2013-07-09 | 그라스톤인터내셔날 주식회사 | Functional-Paint by Using Illite for removing radioactive substance |
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| US4859723A (en) * | 1986-04-14 | 1989-08-22 | The Celotex Corporation | Coating for roof surfaces |
| KR100191680B1 (en) * | 1997-01-30 | 1999-06-15 | 정순제 | Ink composition |
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