KR100351627B1 - Colorless polyimides with good adhesion and their hybrids - Google Patents

Abstract

The present invention relates to a colorless transparent high-adhesion aliphatic polyimide resin and a polyimide / inorganic composite material using the same, and more particularly, to a soluble novel colorless transparent high-moiety containing an aliphatic ring structure and an adhesion improving functional group. The adhesive aliphatic polyimide resin and the aforementioned novel aliphatic polyimide resin are coated on inorganic materials such as glass, conductive glass, aluminum, copper, titanium, or oxides thereof, and thus the buffer coating plate of the color filter of the liquid crystal display device. The present invention relates to a polyimide / inorganic composite material suitable for application to a buffer coating layer, an insulating layer material between a glass substrate and a TFT, and a polymer barrier material of a liquid crystal display device for a touch panel.

Description

Colorless transparent high-adhesion aliphatic polyimide resin and polyimide / inorganic composite material using the same {Colorless polyimides with good adhesion and their hybrids}

The present invention relates to a colorless transparent high-adhesion aliphatic polyimide resin and a polyimide / inorganic composite material using the same, and more particularly, to a soluble novel colorless transparent high-moiety containing an aliphatic ring structure and an adhesion improving functional group. The adhesive aliphatic polyimide resin and the aforementioned novel aliphatic polyimide resin are coated on inorganic materials such as glass, conductive glass, aluminum, copper, titanium, or oxides thereof, and thus the buffer coating plate of the color filter of the liquid crystal display device. The present invention relates to a polyimide / inorganic composite material suitable for application to a buffer coating layer, an insulating layer material between a glass substrate and a TFT, and a polymer barrier material of a liquid crystal display device for a touch panel.

In Chemical Formula 1,

silver , , , , , , , , , And 1 type or 2 or more types of tetravalent groups chosen from these, Comprising: 1 or 2 or more types selected from (a), (b), (c), (d), and (e) must be included;

Is , , , , , , , , , , , , , , And Where R ^a and R ^b are the same or different and represent an alkylene group or an arylene group, and R ^c , R ^d , R ^e and R ^f are the same or different and represent an alkyl group or an aryl group, and l represents 1-20. Natural number), and one or two or more divalent groups selected from (f), (g), (h), (i), (j) and (k) must be selected. Includes;

However, 0 ≦ m / m + n ≦ 1.

In general, the polyimide (PI) resin refers to a high heat-resistant resin prepared by condensation polymerization of an aromatic tetracarboxylic acid or a derivative thereof with an aromatic diamine or an aromatic diisocyanate, followed by imidization. The polyimide resin may have various molecular structures depending on the type of monomer used, thereby exhibiting various physical properties.

Generally, pyromellitic dianhydride (PMDA) or biphenyltetracarboxylic dianhydride (BPDA) is used as the aromatic tetracarboxylic acid component for the production of polyimide resin, and oxydianiline (ODA) is used as the aromatic diamine component. Or p -phenylene diamine (p-PDA) or the like is used.

Representative polyimide resin has the following formula (2) as a repeating unit.

The polyimide resin having the above formula (2) as a repeating unit has the following characteristics: (1) excellent heat oxidation resistance, (2) temperature can be used very high, long-term use temperature is about 260 ℃, short-term use temperature Has excellent heat resistance at about 480 ℃, (3) excellent electrochemical and mechanical properties, (4) excellent radiation and low temperature properties, (5) inherent flame retardancy, and (6) excellent chemical resistance.

However, such aromatic polyimide resins have advantages in that they have excellent general properties, but have low transmittance in the visible region due to high aromatic ring density, and have disadvantages such as dielectric constant of 3.5 or higher and low adhesive properties.

As a method for improving the shortcomings of the polyimide resin, a method of introducing a bulky linking group or a pendant group into the polymer backbone or side chain, and a method of increasing the flexibility of the polymer main chain have been reported. It is.

In particular, as a study for increasing the transparency and solubility of polyimide resin, a method for preparing a soluble polyimide coating solution using alicyclic anhydride as a monomer has been published [Macromolecules, 1994, 27, 1117 and 1993, 26, 4961. However, most of the aliphatic polyimide resins modified by the above method have the advantage of improving the solubility and transparency by increasing the flexibility of the chain, but because they exhibit low adhesion characteristics in the adhesion with inorganic materials such as glass, etc. There is room for improvement.

As part of such research, in the present invention, a novel high adhesive aliphatic polyimide resin having excellent transparency and electrical insulation properties was prepared by polymerization of various kinds of aliphatic acid dianhydride and diamine containing an adhesion improving functional group. A polyimide / inorganic composite material having excellent interfacial adhesion using the prepared aliphatic polyimide resin was prepared.

In the present invention, in addition to the aromatic tetracarboxylic dianhydride used in the production of the existing polyimide resin, tetracarboxylic dianhydride having an aliphatic ring structure is introduced as an essential component, and the aromatic diamine contains an adhesion improving functional group. The present invention has been completed by polymerizing a specific aromatic diamine as an essential component to produce a novel polyimide resin having excellent heat resistance, transparency, electrical insulation and adhesion.

Therefore, the present invention is a novel polyimide resin that can be used as a core heat-resistant material of high-tech industries such as electric, electronics, aerospace and aviation, while maintaining the properties of the existing polyimide resin almost intact, and having excellent transparency, electrical insulation properties and adhesive properties. The purpose is to provide.

In addition, the present invention has another object to provide a composite material consisting of the novel polyimide resin and various inorganic materials.

1 is a graph showing light transmittance according to each wavelength of the polyimide resin (DPI-1) prepared in Example 1. FIG.

The present invention is characterized by a polyimide resin having the following formula 1 as a repeating unit, and a polyimide / inorganic composite material prepared using the same.

Formula 1

In Formula 1 above: , , m and n are as defined above, respectively.

Referring to the present invention in more detail as follows.

In the present invention, a novel aliphatic polyimide resin having a repeating unit of Chemical Formula 1 prepared by reacting a predetermined tetracarboxylic dianhydride having an aliphatic ring structure introduced therein with an aromatic diamine containing an adhesion improving functional group, and the aforementioned novel The present invention relates to a novel polyimide / inorganic composite material having improved mechanical properties such as heat resistance, transparency, electrical insulation, and adhesion produced by using an excellent adhesion property to an inorganic material of an aliphatic polyimide resin.

Aliphatic polyimide resins according to the present invention are prepared by solution polymerization of tetracarboxylic dianhydride and aromatic diamine compounds in polar solvents. Hereinafter, the monomers used for preparing the aliphatic polyimide resin will be described in detail.

The tetracarboxylic dianhydride into which the aliphatic ring structure which the present invention specifically uses as tetracarboxylic dianhydride is introduced is specifically 1,2,3,4-cyclobutanetetracarboxylic dianhydride (CBDA, 'a'). ), 1,2,3,4-cyclopentanetetracarboxylic dianhydride (CPDA, 'b'), 5- (2,5-dioxotetrahydrofuryl) -3-methyl-3-cyclohexene-1, 2-dicarboxylic acid anhydride (DOCDA, 'c'), 4- (2,5-dioxotetrahydrofuran-3-yl) -tetraline-1,2-dicarboxylic acid anhydride (DOTDA, ' d ') and bicyclooctene-2,3,5,6-tetracarboxylic dianhydride (BODA,' e '). Moreover, the aromatic tetracarboxylic dianhydride which this invention uses as needed with the tetracarboxylic dianhydride which introduce | transduced the aliphatic ring structure mentioned above is a conventional thing, for example, pyromellitic dianhydride (PMDA) Or benzophenone tetracarboxylic dianhydride (BTDA), oxydiphthalic dianhydride (ODPA), biphenyl tetracarboxylic dianhydride (BPDA), or hexafluoroisopropylidene diphthalic dianhydride (6FDA) More than species.

In addition, the aromatic diamine containing the adhesion-promoting functional group characteristically used as the aromatic diamine is specifically 3,5-diamino benzoic acid (f), 2,4-diaminobenzenesulfonic acid (g), 2 , 5-diaminobenzenesulfonic acid (g), 2,2-diaminobenzene disulfonic acid (h), 2,2-diamino dihydroxy biphenyl (i), 2,2-diamino dihydroxy ratio Phenyl hexafuluroisopropylidene (j) and At this time, R ^<a> , R <^b> , R <^c> , R <^d> , R <^e> , R <^f> and l are as defined above, respectively, 1 or 2 or more types selected from the siloxane group containing diamine (k). In addition, the aromatic diamine which this invention uses as needed with the adhesive improver containing aromatic diamine is a conventional thing, for example, p -phenylenediamine (p-PDA), m -phenylenediamine (m -PDA), 4,4-oxydianiline (ODA), 4,4-methylenedianiline (MDA), 2,2-bisaminophenylhexafuluropropane (HFDA), m -bisaminophenoxydiphenylsulfone (m-BAPS), p -bisaminophenoxydiphenylsulfone (p-BAPS), 1,4-bisaminophenoxybenzene (TPE-Q), 1,3-bisaminophenoxybenzene (TPE-R), One or two selected from 2,2-bisaminophenoxyphenylpropane (BAPP), 2,2-bisaminophenoxyphenylhexafuluropropane (HFBAPP) and 4,4-diamino benzanilide (DABA) That's it.

In the solution polymerization of the monomer, at least one polar solvent selected from m -cresol, N -methyl-2-pyrrolidone (NMP), dimethylformamide (DMF), dimethylacetamide (DMAc), and the like is used as a reaction solvent. do. In addition, an imidization catalyst may also be used. The imidization catalyst is selected from organic acids and organic amine derivatives such as p -toluenesulfonic acid, hydroxybenzoic acid, crotonic acid, and the like. Add in the range of 10% by weight. In addition, the solid diamine monomer of (f)-(k) which is essentially contained as a diamine compound can be added in 5-100 weight% range by solid content concentration.

The aliphatic polyimide resin according to the present invention described above has a weight average molecular weight (Mw) of about 20,000 to 300,000 g / mol, maintains intrinsic viscosity in the range of 0.3 to 2.0 dL / g, and glass of 200 to 400 ° C. It has a transition temperature (Tg).

On the other hand, the present invention includes a composite material composed of an aliphatic polyimide resin and an inorganic material having the formula (1) as a repeating unit. In the present invention, in forming a composite material, the surface of the inorganic material may be pretreated with a solution of a primer represented by the following Chemical Formula 2 to increase the adhesion between the polyimide resin and the inorganic material.

In Formula 3 above:

R ¹ , R ² and R ³ are the same as or different from each other and are selected from -R ⁴ NH ₂ , -R ⁴ NHR ⁵ NH ₂ , -R ⁴ COOH, -R ⁴ OH, , -R ⁴ -C (CH ₃ ) = CH ₂ or -R ⁴ SH, wherein R ⁴ and R ⁵ each represent an alkyl group or an aryl group; 0 ≦ p / p + q ≦ 1.

The solution of the primer represented by the formula (3) is water alone solvent or water and N -methyl-2-pyrrolidone (NMP), dimethylformamide (DMF), dimethylacetamide (DMAc), γ-butyrolactone as a solvent , A mixed solvent with an organic solvent selected from 2-butoxyethanol and 2-ethoxyethanol, and its concentration is preferably 0.10 to 1.0% by weight.

The aliphatic polyimide film having a repeating unit of Chemical Formula 1 according to the present invention has a thermal decomposition temperature of 350 to 450 ° C. and an optical transparency between 400 and 700 nm of 80% or more. Moreover, the dielectric constant measured at 1 kHz was in the range of 2.5-4.0, and the interface adhesive force with glass was excellent in 200 g / cm or more.

The present invention as described above will be described in more detail based on the following Examples and Experimental Examples, but the present invention is not limited thereto.

Example 1 Preparation of Polyimide Resin (DPI-1)

Stirrer, temperature control device, in the reactor of 50 mL fitted with a nitrogen inlet, dropping funnel, and a condenser, was passed through a nitrogen gas slowly p - phenylene diamine (p-PDA; 1.08 g, 0.01 mol) and 3,5- Diaminobenzenesulfonic acid (DAS; 1.88 g, 0.01 mol) was dissolved in the reaction solvent N -methyl-2-pyrrolidone (NMP) / toluene (8/2, weight ratio). Then, 5- (2,5-dioxotetrahydrofuryl) -3-methyl-3-cyclohexene-1,2-dicarboxylic acid anhydride (DOCDA; 5.28 g, 0.02 mol) in solid phase while passing nitrogen gas Was added slowly at 15% by weight solid content. The reaction was carried out for 24 hours while maintaining the reaction temperature at 0 ~ 10 ℃ to prepare a polyamic acid (PAA). Subsequently, after raising the temperature inside the reactor to 160 ° C., an imidization reaction was performed for 4 hours to carry out dehydration polymerization. After the reaction was completed, the reaction mixture was washed three times or more with excess methanol using a Waring blender, and then dried under reduced pressure and dried at a temperature of 120 ℃ to obtain a polyimide resin (DPI-1). The yield of the polymerization reaction was confirmed to be quantitative, and the intrinsic viscosity measured at 30 ° C. at a concentration of 0.5 g / dL using NMP as a solvent was 0.79 dL / g.

Example 2. Preparation of Polyimide Resin (DPI-2)

In a 50 mL reactor equipped with a stirrer, temperature controller, nitrogen injector, dropping funnel and cooler, react p-PDA (1.08 g, 0.01 mol) and DAS (1.88 g, 0.01 mol) while slowly passing nitrogen gas. It was dissolved in m -cresol, a solvent. Then, DOCDA (5.28 g, 0.02 mol) in solid phase was added slowly at 15% by weight of solid content while passing through nitrogen gas. After raising the reaction temperature to 70 ℃, the reaction was allowed to proceed for 2 hours. Subsequently, the temperature was raised to the reflux temperature of the solvent, followed by stirring for 8 hours. After the reaction was completed, the reaction mixture was washed three times or more with excess methanol using a Waring blender, and then dried under reduced pressure and dried at a temperature of 120 ℃ to obtain a polyimide resin (DPI-2). The yield of the polymerization reaction was confirmed to be quantitative, and the intrinsic viscosity measured at 30 ° C. at a concentration of 0.5 g / dL using m -cresol as a solvent was 1.42 dL / g.

Example 3. Preparation of Polyimide Resin (DPI-3)

p-PDA instead of m - phenylenediamine (m-PDA; 1.08 g, 0.01 mol) was performed in the same manner as in Example 1 except for the use, and the inherent viscosity of the polyimide resin obtained is 0.76 dL / g.

Example 4. Preparation of Polyimide Resin (DPI-4)

The same procedure as in Example 1 was carried out except that 4,4-oxydianiline (ODA; 2.00 g, 0.01 mol) was used instead of p-PDA, and the inherent viscosity of the obtained polyimide resin was 1.31 dL / g.

Example 5. Preparation of Polyimide Resin (DPI-5)

The same procedure as in Example 1 was carried out except that 4,4-methylenedianiline (MDA; 1.98 g, 0.01 mol) was used instead of p-PDA, and the inherent viscosity of the obtained polyimide resin was 1.39 dL / g.

Example 6. Preparation of Polyimide Resin (DPI-6)

The procedure of Example 1 was repeated except that 2,2-bisaminophenylhexafuluropropane (HFDA; 3.34 g, 0.01 mol) was used instead of p-PDA. The viscosity was 0.60 dL / g.

Example 7. Preparation of Polyimide Resin (DPI-7)

Except for using m -bisaminophenoxydiphenylsulfone (m-BAPS; 4.46 g, 0.01 mol) instead of p-PDA was carried out in the same manner as in Example 1, the intrinsic viscosity of the polyimide resin obtained 0.76 dL / g.

Example 8. Preparation of Polyimide Resin (DPI-8)

The same procedure as in Example 1 was carried out except that 1,4-bisaminophenoxybenzene (TPE-Q; 2.92 g, 0.01 mol) was used instead of p-PDA, and the intrinsic viscosity of the obtained polyimide resin was obtained. Was 0.78 dL / g.

Example 9. Preparation of Polyimide Resin (DPI-9)

The same procedure as in Example 1 was carried out except that 1,3-bisaminophenoxybenzene (TPE-R; 2.92 g, 0.01 mol) was used instead of p-PDA, and the intrinsic viscosity of the obtained polyimide resin was obtained. Was 0.74 dL / g.

Example 10. Preparation of Polyimide Resin (DPI-10)

Polyimide resin obtained in the same manner as in Example 1, except that 2,2-bisaminophenoxyphenylhexafuluropropane (HFBAPP; 5.18 g, 0.01 mol) was used instead of p-PDA. The intrinsic viscosity of was 1.12 dL / g.

Example 11. Preparation of Polyimide Resin (DPI-11)

Except for using 2,2-bisaminophenoxyphenylpropane (BAPP; 4.10 g, 0.01 mol) instead of p-PDA was carried out in the same manner as in Example 1, the intrinsic viscosity of the obtained polyimide resin 0.40 dL / g.

Example 12 Preparation of Polyimide Resin (DPI-12)

The procedure of Example 1 was repeated except that 4,4-diaminobenzanilide (DABA; 2.27 g, 0.01 mol) was used instead of p-PDA, and the inherent viscosity of the obtained polyimide resin was 0.70 dL. / g.

Example 13. Preparation of Polyimide Resin (DPI-14)

The same procedure as in Example 1 was carried out except that 3,5-diaminobenzoic acid (DAB; 1.52 g, 0.01 mol) was used instead of DAS, and the inherent viscosity of the obtained polyimide resin was 0.89 dL / g. .

Example 14 Preparation of Polyimide Resin (DPI-13)

The same procedure as in Example 1 was conducted except that 3,5-diamino benzoic acid (DAB; 1.52 g, 0.01 mol) was used instead of DAS, except that no imidization catalyst was used. The intrinsic viscosity of the obtained polyimide resin was 0.68 dL / g.

Example 15 Preparation of Polyimide Resin (DPI-15)

The same procedure as in Example 1 was carried out except that 2,2-diaminobenzene disulfonic acid (DABS; 3.44 g, 0.01 mol) was used instead of DAS, and the inherent viscosity of the obtained polyimide resin was 0.44 dL / g.

Example 16 Preparation of Soluble Polyimide Resin (DPI-16)

Except for using bisamino propyl dimethyl siloxane (DADS; NH ₂ (CH ₂ ) ₃ Si (CH ₃ ) ₂ OSi (CH ₃ ) ₂ (CH ₂ ) ₃ NH ₂ , 2.48 g, 0.01 mol) instead of DAS It carried out in the same manner as in Example 1, the intrinsic viscosity of the obtained polyimide resin was 0.56 dL / g.

Example 17 Preparation of Polyimide Resin (DPI-17)

The same procedure as in Example 1 was conducted except that 2,2-diamino dihydroxy biphenyl (DAHB; 2.16 g, 0.01 mol) was used instead of DAS, and the inherent viscosity of the obtained polyimide resin was 0.58. dL / g.

Example 18. Preparation of Polyimide Resin (DPI-18)

Except for using 2,2-diamino dihydroxy biphenyl hexafuluro isopropylidene (DADB; 3.66 g, 0.01 mol) instead of DAS was carried out in the same manner as in Example 1, the poly The intrinsic viscosity of the mid resin was 0.45 dL / g.

Experimental Example 1 Preparation of Polyimide / Glass Composite Material

The glass substrate was pretreated with a 3-aminopropyltrimethoxysilane solution at 0.05% concentration dissolved in a methanol / water mixed solution, and then dried at a temperature of 90 ° C. for 10 minutes. The NMP solution of the polyamic acid or polyimide resin manufactured in the said Examples 1-18 was apply | coated uniformly so that the thickness might be 2-20 micrometers after drying to the said preprocessed glass substrate. Then, the mixture was slowly heated to a temperature of 100 to 300 ° C., and then dried for 1 hour. As a result, a high heat-resistant transparent polyimide / glass composite material in which the polyimide resin was uniformly thin coated.

The overall physical properties of the polyimide resin and the polyimide / glass composite material prepared in Examples 1 to 18 are shown in Table 1 below.

All of the aliphatic polyimide resins according to the present invention were amorphous transparent resins, and the inherent viscosity measured was about 0.36 to about 1.42, and the film formation by the solvent casting was also excellent.

The glass transition temperature was measured from secondary heat traces of the DSC measurement conducted by heating at a rate of 10 ° C./min under a nitrogen stream using a differential scanning calorimeter (DSC). As a result, the glass transition temperature is in the range of approximately 250 ~ 400 ℃, it was confirmed that the glass transition temperature can be adjusted in particular by the change in the molecular structure of the diamine used.

In addition, according to the results of the interfacial adhesion test of the polyimide / glass composite material, in the case of the polyimide resin containing the adhesion-improving functional group, the adhesion by the 90 ° peel test was about 200 to 1,500 g / cm. Excellent adhesion was shown. It has been found that the interfacial adhesion has a significant correlation with the molecular structure of the polymer, and thus, the polyimide resin having an acid functional group capable of chemically bonding with the primer or the primer used in the pretreatment process is introduced. This tended to increase.

In addition, according to the light transmittance measured using a visible-ultraviolet spectroscopy, the polyimide resin according to the present invention exhibited excellent light transmittance of 80% or more in the range of 400 to 700 nm [see FIG. 1].

As described above, the aliphatic polyimide resin according to the present invention not only has excellent heat resistance, but also exhibits electrical insulation, light transmittance, and excellent adhesion, so that the buffer coating layer of the color filter of the liquid crystal display device, It is suitable for application to an insulating layer material between a glass substrate and a TFT, and a polymer partition material of a liquid crystal display element for a touch panel. In particular, since the aliphatic polyimide resin according to the present invention has excellent adhesive properties to inorganic materials, it can be manufactured in a polyimide / inorganic composite material and applied to a wide range of fields.

Claims (8)

Colorless transparent highly adhesive aliphatic polyimide characterized in that the following formula (1) as a repeating unit, an aliphatic ring selected from (a), (b), (c), (d) and (e) is essentially included Suzy. Formula 1 In Chemical Formula 1, silver , , , , , , , , , And 1 type or 2 or more types of tetravalent groups chosen from these, Comprising: 1 or 2 or more types selected from (a), (b), (c), (d), and (e) must be included; Is , , , , , , , , , , , , , , And Where R ^a and R ^b are the same or different and represent an alkylene group or an arylene group, and R ^c , R ^d , R ^e and R ^f are the same or different and represent an alkyl group or an aryl group, and l represents 1-20. Natural number), and one or two or more divalent groups selected from (f), (g), (h), (i), (j) and (k) must be selected. Includes; However, 0 ≦ m / m + n ≦ 1. The aliphatic polyimide resin according to claim 1, wherein the intrinsic viscosity of the polyimide resin is in the range of 0.3 to 2.0 dL / g. According to claim 1, wherein the light transmittance in the 400 to 700 nm range of the polyimide resin film is 80% or more, the dielectric constant (at 1 kHz) is 2.5 to 4.0, the thermal decomposition temperature is 350 to 450 ℃. Aliphatic polyimide resin characterized by the above-mentioned. The polyimide / inorganic composite material of claim 1, wherein the aliphatic polyimide resin is coated on a surface of an inorganic material selected from glass, conductive glass, and aluminum, copper, titanium, or oxides thereof. The polyimide / inorganic composite material according to claim 4, wherein the interfacial adhesion strength between the aliphatic polyimide resin and the inorganic material is 200 to 1,500 g / cm. The polyimide / inorganic composite material according to claim 4, wherein the inorganic material is pretreated with a primer represented by the following Chemical Formula 3. Formula 3 In Formula 3 above: R ¹ , R ² and R ³ are the same as or different from each other and are selected from -R ⁴ NH ₂ , -R ⁴ NHR ⁵ NH ₂ , -R ⁴ COOH, -R ⁴ OH, , -R ⁴ -C (CH ₃ ) = CH ₂ or -R ⁴ SH, wherein R ⁴ and R ⁵ each represent an alkyl group or an aryl group; 0 ≦ p / p + q ≦ 1. In the method of solution-polymerizing tetracarboxylic dianhydride and an aromatic diamine compound, and manufacturing a polyimide resin, The tetracarboxylic dianhydride includes 1,2,3,4-cyclobutanetetracarboxylic dianhydride (CBDA), 1,2,3,4-cyclopentanetetracarboxylic dianhydride (CPDA), 5- ( 2,5-dioxotetrahydrofuryl) -3-methyl-3-cyclohexene-1,2-dicarboxylic acid anhydride (DOCDA), 4- (2,5-dioxotetrahydrofuran-3-yl) One or two or more selected from tetralin-1,2-dicarboxylic acid anhydride (DOTDA) and bicyclooctene-2,3,5,6-tetracarboxylic dianhydride (BODA) as essential ingredients Pyromellitic dianhydride (PMDA), benzophenone tetracarboxylic dianhydride (BTDA), oxydiphthalic dianhydride (ODPA), biphenyltetracarboxylic dianhydride (BPDA) and hexafluoroisopropyl It contains one or two or more selected from aidene phthalic anhydride (6FDA), Examples of the aromatic diamine compound include 3,5-diamino benzoic acid, 2,4-diaminobenzenesulfonic acid, 2,5-diaminobenzenesulfonic acid, 2,2-diaminobenzene disulfonic acid, and 2,2-diamino Dihydroxy biphenyl, 2,2-diamino dihydroxy biphenyl hexafuluro isopropylidene, and Where R ^a and R ^b are the same or different and represent an alkylene group or an arylene group, and R ^c , R ^d , R ^e and R ^f are the same or different and represent an alkyl group or an aryl group, and l represents 1-20. containing one or more kinds selected from siloxane group-containing diamine represented by a natural number a) as essential components and, if necessary, p - phenylenediamine (p-PDA), m - phenylenediamine (m-PDA), 4,4-oxydianiline (ODA), 4,4-methylenedianiline (MDA), 2,2-bisaminophenylhexafuluropropane (HFDA), m -bisaminophenoxydiphenylsulfone (m-BAPS ), p -bisaminophenoxydiphenylsulfone (p-BAPS), 1,4-bisaminophenoxybenzene (TPE-Q), 1,3-bisaminophenoxybenzene (TPE-R), 2,2- Contains one or two or more compounds selected from bisaminophenoxyphenylpropane (BAPP), 2,2-bisaminophenoxyphenylhexafuluropropane (HFBAPP) and 4,4-diaminobenzanilide (DABA) The following method of preparing an aliphatic polyimide resin to the formula (I) a repeating unit characterized in that. Formula 1 In Chemical Formula 1, , , m and n are as defined in claim 1, respectively. The method of claim 7, wherein the solution polymerization is characterized in that carried out under one or more polar solvents selected from N -methyl-2-pyrrolidone (NMP), dimethylacetamide (DMAc) and dimethylformamide (DMF). Method for producing aliphatic polyimide resin.