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KR100331124B1 - Manufacturing Method of Milk-Curd and Whey - Google Patents

Manufacturing Method of Milk-Curd and Whey Download PDF

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KR100331124B1
KR100331124B1 KR1019990026204A KR19990026204A KR100331124B1 KR 100331124 B1 KR100331124 B1 KR 100331124B1 KR 1019990026204 A KR1019990026204 A KR 1019990026204A KR 19990026204 A KR19990026204 A KR 19990026204A KR 100331124 B1 KR100331124 B1 KR 100331124B1
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whey
milk
coagulant
calcium chloride
manufacturing
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KR19990073292A (en
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이무환
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C21/00Whey; Whey preparations
    • A23C21/06Mixtures of whey with milk products or milk components
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C23/00Other dairy products

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Dairy Products (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • Beans For Foods Or Fodder (AREA)

Abstract

PURPOSE: Provided is a method for manufacturing fried bean curd and whey, thereby applying the taste and flavor and nutrients of milk to food products without the loss thereof. CONSTITUTION: In the manufacturing method of fried bean curd and whey by adding a coagulant to milk, followed by heating them, the coagulant is prepared by mixing calcium chloride and magnesium chloride in a mixing ratio of 1:1, and is added in the amount of 0.18-0.5%.

Description

유부 유청의 제조방법{Manufacturing Method of Milk-Curd and Whey }Manufacturing Method of Milk-Curd and Whey

종래의 기술로는 우유, 전지유,탈지유, 탈지분유를 가수한것 등을 단독으로 응고시킬 수 없었다. 이는 응고 우유 제조를 두부의 제조 방법에 의존하였기 때문이며, 종래에는 응고유 생산의 필요성이 희박했기 때문이었을 것이다. 서양인의 식사양식이 동양인의 식사 양식에로 접근하고 있다면, 우리는 서양인의 식사 양식으로 가는것을 생각하지 않을 수 없다. 본 유부와 유청의 제조 방법은 새로운 2천년대를 전망하는 국내 외용 발명이 될 수 있다.Conventional techniques cannot coagulate milk, whole milk, skim milk, skim milk powder, etc. alone. This is because the production of coagulated milk was dependent on the manufacturing method of tofu, which may have been due to the necessity of producing coagulated milk in the past. If the Western diet approaches the Asian diet, we must think of going to the Western diet. This method of manufacturing whey and whey can be a domestic and foreign invention foreseeing a new 2000s.

이 분야의 종래 기술과 문헌을 보면,응고유를 다량 제조하는 기술은 우유에 pH를 3.5-4.0 으로 초산을 가하여 응고시키고, CaCl2를 추가한 후 8-10시간 냉수에 재우기를 하는 것이며(발명특허 25905호), 유청은 취하지 아니한 내용이었다. 이 방법으로 건조 우유두부를 제조한 예가있다(공고번호 92-8852). 계란 우유두부 제조방법(공고번호 95-12613)은 우유를 초산 처리 후 중화제로 염화칼슘 0.4%를 사용했다. 콩 우유두부 제조방법(공고번호 92-3550)은 콩과 탈지유를 7:3으로 혼합한 후 rennet 응고와, 유청은 섭씨61.5 - 65.6도에서 30분간 가열 하면서 염화 마그네슘을 첨가하면서 서서히 저으면서 가열한다 고 했다.According to the prior art and literature in this field, a technique for preparing a large amount of coagulated oil is to coagulate milk by adding acetic acid to pH 3.5-4.0 with acetic acid, and then add CaCl 2 and soak in cold water for 8-10 hours (invention). Patent 25905), Whey was not taken. There is an example in which dried milk tofu is prepared in this way (Gob 92-8852). In the method for preparing egg milk tofu (Notice 95-12613), 0.4% of calcium chloride was used as a neutralizer after treating acetic acid. The soy milk tofu manufacturing method (Gun. did.

응고제에 관하여는 치즈 제조시에 염화칼슘을 사용하여 유청중의 유단백질의 유실을 방지하고 있으나, 정통 유럽, 대양주에서 사용하는 경우가 보고되지 않고 있다. 버터 제조시에 10% Ca(OH)2및 NahCO3용액을 첨가하여 중화한다. 가공치즈는 치즈를 중화제로서 구연산나토륨과 인산나트륨을 첨가하여 가열하여 만든다.As a coagulant, calcium chloride is used to make cheeses to prevent loss of whey protein in whey, but it has not been reported to be used in orthodox European and oceanic wines. The butter is neutralized by the addition of 10% Ca (OH) 2 and NahCO 3 solutions. Processed cheese is made by heating the cheese as a neutralizer by adding sodium citrate and sodium phosphate.

원료 우유가 가지는 모든 영양소와 향기와 맛을 조금도 손실함이 없이 식품으로 이용할 수 있는 다량 제조방법을 발명한것이다.Invented a large amount of manufacturing method that can be used as a food without losing any nutrients, aromas and flavors of raw milk.

① 건강식품을 제조하기 위하여, 유부와 유청의 원료선택 문제.① Problems in choosing raw materials of whey and whey to make health food.

② 유부 제조용 응고제의 종류와 첨가수준의 결정.② Determination of the type and level of coagulant for dairy production.

③ 유부와 유청의 제조 공정에서, 신속, 단순, 다량 생산성 제고.③ In the manufacturing process of whey and whey, increase the speed, simplicity and mass productivity.

④ 식품으로서 기호성 향상을 위한 유부와 유청의 생산과 평가.④ Production and evaluation of whey and whey to improve palatability as food.

상기의 과제를 해결하기 위한 본 발명은 순수 우유를 응고제 첨가 후에 가열한 후 유부와 유청을 제조 하는 방법에 있어서, 염화칼슘(CaCl2) 단독 또는 염화칼슘과 염화마그네슘(MgCl2)을 1:1의 비율로 혼합한 응고제를 사용하며, 사용하는 우유 중량에 대하여 염화칼슘은 최저 0.15% 내지 0.5%, 염화칼슘과 염화마그네슘의 혼합 응고제는 0.18% 내지 0.5%의 범위에서 우유에 응고제를 먼저 첨가한 후에 가열을 시작하고 계속 끓임으로 우유를 다량 응고를 시켜고 유부와 유청을 분리하는 것을 특징으로 하는 유부, 유청의 제조방법을 제공함으로서 달성될 수 있다.① 분유의 종류별 조성분:In order to solve the above problems, the present invention provides a method for producing milk and whey after heating pure milk after coagulant addition, wherein calcium chloride (CaCl 2 ) alone or calcium chloride and magnesium chloride (MgCl 2 ) is in a ratio of 1: 1. Coagulant mixed with water, calcium chloride should be at least 0.15% to 0.5% based on the weight of the milk used, and the mixed coagulant of calcium chloride and magnesium chloride should be added to milk in the range of 0.18% to 0.5% before starting heating. It can be achieved by providing a method of manufacturing whey, whey, characterized in that the milk is solidified by continuing to boil, and separating the whey and whey.

전지분유에 비해 탈지분유는 열량은 72% 에 불과하며, 단백질은 137%이다. 지방함유량은 탈지분유는 1%인 반면 전지분유는 27.5배 많다. 탄수화물은 유당이 주종이며, 전지분유와 탈지분유는 각각 38%와 52.5%이다. 광물질인 회분은 각각 6.0%와 8.6%이며, 이 중에서 칼슘은 각각 890 mg 와 1200mg 으로서 탈지분유를 1일 100g만 섭하면 충분한 량이다. 인은 730mg 과 980mg, 철분은 1.0mg 씩, 비타민 D는 16 I.U. 미만, A는 700 I.U. 와 20 I.U., C는 5.0mg 씩, B 복합체 가 함유되어있다.Compared to whole milk powder, skimmed milk powder has only 72% of calories and 137% of protein. The fat content is 1% of skim milk powder and 27.5 times as much as whole milk powder. Carbohydrates are predominantly lactose, while whole milk and skim milk powder are 38% and 52.5%, respectively. Mineral ash is 6.0% and 8.6%, respectively, of which calcium is 890 mg and 1200 mg, respectively, which is sufficient if only 100 g of skim milk powder is fed per day. Phosphorus 730mg and 980mg, Iron 1.0mg each, Vitamin D 16 I.U. Less than A, 700 I.U. And 20 I.U., C each contain 5.0 mg of B complex.

본 발명의 제조 공정에서는 탈지유가 원유로서 선정되었다.In the manufacturing process of the present invention, skim milk was selected as crude oil.

②응고제의 종류와 첨가 수준:② Types and Levels of Coagulant:

두부제조에 사용되는 응고제는 염화칼슘(CaCl2), 염화마그네슘(MgCl2)가 있으며, 황산칼슘(CaSO4)은 우유를 응고시키지 못 하므로 본 발명에서는 제외했다. 응고제는 식품 안전에 중요하므로 두부에서 사용하는 염화칼슘과 염화마그네슘을 사용하고, 응고제 첨가 수준은 두부 제조시 사용량 보다 현저히 낮은 수준으로 했다. 성장기의 아동과 근육,신경 작용에 중요한 칼슘과 마그네슘을 보강 할 수 있다.Coagulants used to prepare tofu include calcium chloride (CaCl 2 ), magnesium chloride (MgCl 2 ), calcium sulfate (CaSO 4 ) is excluded from the present invention because it does not coagulate milk. Because coagulants are important for food safety, calcium chloride and magnesium chloride used in tofu were used, and the level of coagulant addition was significantly lower than the amount used for tofu production. It can reinforce calcium and magnesium, which are important for growing children, muscles and nerves.

가. 탈지유와 응고제 첨가 수준에 따른 응고성 시험:end. Coagulation test according to the level of skim milk and coagulant addition:

(수분함량 87%:첨가율:중량당 %: - 는 불응고; ±는 불완전한 응고; + 는 1/3 응고; ++는 2/3응고; +++는 완전응고 임.)(Moisture content 87%: Addition rate:% by weight:-is non-solidification; ± is incomplete solidification; + is 1/3 solidification; ++ is 2/3 solidification; +++ is complete solidification.)

탈지유는 탈지분유 134g에 대하여 물로 1000ml 될때까지 혼합하여 시유의 수분함량인 87%에 맞게 조절하였다. 염화칼슘의 최저 한계 첨가 수준은 0.15% 이고, 염화마그네슘은 0.18% 이다. 염화칼슘과 염화마그네슘을 1:1로 혼합한것은 0.18%이상 이다.The skim milk was mixed with 134 g of skim milk powder until it was mixed with water to 1000 ml, and adjusted to 87% of the milk content of the milk powder. The lowest threshold addition level of calcium chloride is 0.15%, and magnesium chloride is 0.18%. A 1: 1 mixture of calcium chloride and magnesium chloride is more than 0.18%.

나. 전유를 이용한 응고제 첨가율 시험:(수분함량 87%:중량당 %)I. Coagulant addition rate test using whole milk: (Water content 87%:% per weight)

전유는 염화칼슘 첨가 수준이 0.13%이상에서 응고개시 되었다. 염화마그네슘은 0.18% 수준에서 응고가 확실하다. 염화칼슘과 염화마그네슘을 1:1의 비율로 첨가한 것은 0.13%에서 응고는 가능하나 유부의 생산량을 많이 하려면 0.18% 수준이 안전하다.Whole milk began to coagulate with calcium chloride addition levels above 0.13%. Magnesium chloride is solidified at a level of 0.18%. The addition of calcium chloride and magnesium chloride in a ratio of 1: 1 allows for coagulation at 0.13%, but 0.18% is safe for high yields of milk.

③ 유부 유청의 제조공정③ Manufacturing process of whey

공정 1:Process 1:

탈지유를 준비한다. 탈지유는 탈지분유와 음료수의 비율을 135 g:870g로 하여 각반하면서 가열한다Prepare skim milk. The skimmed milk is heated with leggings with the ratio of skimmed milk powder and beverages at 135 g: 870 g.

공정 2:Process 2:

우유의 온도가 50℃ 전 후에, (ㄱ) 염화칼슘 유부 및 유청을 제조하는 경우는 염화칼슘을 0.15% 혼합하며, (ㄴ) 염화칼슘과 염화마그네슘 혼합(1:1혼합) 유부 및 유청 제조시에는 0.18%를 첨가한다.Before or after the temperature of milk is 50 ° C, (a) 0.15% of calcium chloride is mixed when preparing calcium chloride whey and whey, and (b) 0.18% when mixing calcium chloride and magnesium chloride (1: 1 mixture). Add.

공정 3:Process 3:

우유와 응고제를 서서히 저으면서 가온하면 93℃ 부터 98.4℃ 사이에서 4분이내에 응고를 마친다.Slowly stir the milk and coagulant and warm up within 4 minutes between 93 ° C and 98.4 ° C.

공정 4:Process 4:

유부와 유청은 20 x 20/cm 커즈로 2Kg 의 압력을 가하면서 분리 수거한다. 유부는 성형과 동시에 유수로 냉각한다.Whey and whey are separated and collected at 20 x 20 / cm curd under a pressure of 2 kg. The oil part cools with the flowing water at the same time as the molding.

④ 탈지유를 이용한 유부와 유청의 생산성과 평가.④ Productivity and evaluation of whey and whey using skim milk.

(가) 탈지유로부터 유부와 유청의 생산량(A) Production of whey and whey from skim milk

탈지유 1 리터로부터 염화칼슘 0.15% 첨가 유부 및 유청의 생산량은 각각 127g과 873g 로써, 치즈의 제조 공정에서는 우유 1 리터로부터 120g의 치즈생산 수율보다 7g 많다.The yield of 0.15% calcium chloride from 1 liter of skim milk is 127 g and 873 g, respectively, and the yield of cheese is 7 g more than the yield of 120 g of cheese from 1 liter of milk.

(나) 유부와 유청의 조성분(B) Composition of milk and whey

(ㄱ) 염화칼슘 응고제 0.15% 사용 구분 수분(%) 건물(%) 단백질(%) 지방(%) 당질(%) 회분(%) 열량(㎉) pH 비중 유부 58.25 41.75 30.63 2.42 5.23 3.47 163.6 - - 유청 89.95 10.05 0.5 4.80 3.84 0.91 60.6 5.99 1.023 (A) using 0.15% of calcium chloride coagulant division moisture(%) building(%) protein(%) Fat(%) Carbohydrate (%) Ash content (%) Calories pH importance Housewife 58.25 41.75 30.63 2.42 5.23 3.47 163.6 - - Whey 89.95 10.05 0.5 4.80 3.84 0.91 60.6 5.99 1.023

유부의 수분 함량은 58.25%, 건물량은 41.75%이다. 유부의 단백질 함량은 30.63%, 탄수화물은 5.23%, 지방질은 2.24%, 열량은 163.6kcal, 회분은 3.47%이다. 유부를 물에 넣고 끓인 결과 유부의 원형을 유지했다.The water content of the soybeans is 58.25%, and the dry matter amount is 41.75%. The protein content of married women is 30.63%, carbohydrate 5.23%, fat 2.24%, calories 163.6 kcal, and ash 3.47%. The housewife was put in water and boiled to maintain the circle of the housewife.

유청의 수분 함량은 89.95%이고, 건물량(dry matter)은 10.05% 이다. 유청중에 함유된 단백질은 0.5%, 탄수화물은 4.72%, 지방질은 3.83%, 열량은 60.6kcal, 회분은 0.91%이다. PH는 5.99, 비중은 1.023이다.Whey has a moisture content of 89.95% and dry matter 10.05%. Whey contains 0.5% protein, 4.72% carbohydrates, 3.83% fat, 60.6 kcal and 0.91% ash. PH is 5.99 and specific gravity is 1.023.

(ㄴ). 염화칼슘과 염화마그네슘 혼합 응고제 0.18% 사용 구분 수분(%) 건물(%) 단백질(%) 지방(%) 당질(%) 회분(%) 열량(㎉) pH 비중 유부 58.45 41.55 30.72 2.15 5.17 3.51 162.9 - - 유청 89.95 9.95 0.49 3.83 4.72 0.91 55.3 6.10 1.032 (N). 0.18% use of calcium chloride and magnesium chloride coagulant division moisture(%) building(%) protein(%) Fat(%) Carbohydrate (%) Ash content (%) Calories pH importance Housewife 58.45 41.55 30.72 2.15 5.17 3.51 162.9 - - Whey 89.95 9.95 0.49 3.83 4.72 0.91 55.3 6.10 1.032

탈지유 1 리터로부터 염화칼슘과 염화마그네슘 혼합(1:1비율)응고제 0.18% 중량을 첨가하여 제조한 유부 및 유청의 생산량은 126g 이고, 제조된 유부를 물에 넣고 5분간 끓인 후의 무게는 95% 회수 되었으나 유부의 원래 상태는 유지되었다. 유부의 수분 함량은 58.45% 이며 건함 량은 41.55%이다. 유부의 단백질 함량은 30.72%, 탄수화물은 5.17%, 지방질은 2.15%, 열량은 162.9kcal, 회분은 3.51%이다. 유청의 pH는 6.10 이어서 이 pH 에서는 음료 원료로서 가능하다. 유청의 비중은 1.032 이다. 유청의 수분 함량은 89.95% 이고, 건물(dry matter)함량은 9.95%이고, 유청의 단백질 함량은 0.49%, 탄수화물은 8.36%, 지방질은 3.83%, 열량은 55.31kcal, 회분은 0.91% 이다.The yield of whey and whey prepared by adding 0.18% by weight of a calcium chloride and magnesium chloride coagulant (1: 1 ratio) coagulant from 1 liter of skim milk was 126g, and the weight was 95% after boiling for 5 minutes. The married woman's original condition was maintained. The water content of the soybeans is 58.45% and the dry content is 41.55%. The protein content of married women is 30.72%, carbohydrates 5.17%, fat 2.15%, calories 162.9 kcal and ash 3.51%. Whey has a pH of 6.10 and at this pH it is possible to use as a beverage ingredient. Whey is 1.032. Whey content is 89.95%, dry matter content is 9.95%, whey protein content is 0.49%, carbohydrate is 8.36%, fat is 3.83%, calories is 55.31 kcal and ash is 0.91%.

(다) 유부의 평가(C) Evaluation of married women

유부의 물성 검사는 Sun Reo Meter로 하였다. 탈지유 염화칼슘 0.15% 유부는 탈지유 염화칼슘과 염화마그네슘 0.18% 유부에 비하여, 단단한 편이며, 저작력이 강하고, 제2차 저작력은 약간 강하고, 강인성은 약 2배 이며, 견고성이 많고, 응집력이 적다. 또한 탄력은 비슷한 수준이며, 점착력과 과민성이 크다.The physical properties of the married women were examined using a Sun Reo Meter. 0.15% skim milk calcium chloride is harder than skim milk calcium chloride and 0.18% magnesium chloride, and it has a strong chewing strength, a little secondary chewing power, about 2 times toughness, high rigidity and low cohesion. In addition, the elasticity is similar, cohesive and sensitive.

① Rheology data report( 기기명:SUN RHEO METER,COMPAC-100,SUN SCIENTIFIC CO,LTD)① Rheology data report (device name: SUN RHEO METER, COMPAC-100, SUN SCIENTIFIC CO, LTD)

② 유부의 관능 검사(여자대학 2,3년생 80명대상 조사)② Sensuality test of married women (investigation of 80 female students of 2-3 years)

유부의 관능검사는 신세대인 여자대학생 80명을 대상으로 실시했다. 유부는 두종류 모두 냄새와 맛은 향상되었다 고 하며, 질감은 약간 단단한 편으로 나타났다. 설탕이나 소금을 가하지 아니한 상태로 관능검사를 실시 했으므로 아주 좋다 라고 평가는 되지 아니했다. 종합적으로 보면 유부는 두부 보다 견고하며, 질긴감이 있으므로 동양 식사 양식에 가깝도록 느껴진 점이 본 발명의 의도와 일치했다.① 유청의 관능 평가(여자대학 2,3년생 80명대상 조사)The sensory test of married women was conducted on 80 female college students. Both types are said to have improved odor and taste, and the texture is slightly hard. The sensory test was performed without adding sugar or salt, so it was not evaluated as good. Taken together, tofu is more firm and tolerant than tofu, so it feels more like an oriental meal. This is in line with the intention of this invention.

유청의 관능 검사는 유부와 같은 방법으로 실시되었다. 유청은 두 종류 모두 맛이 고소하고, 유청 고유 향기가 보통 우유 보다 짙고, 약간 단맛이 있으며, 쓴맛이나 자극성의 느낌이 없는 음료로서의 개발이 가능한 평가 결과가 나왔다.Whey sensory tests were performed in the same manner as whey. Both types of whey are taste-flavored, have a whey specific scent that is thicker than regular milk, slightly sweeter, and have no bitter or irritating taste.

탈지분유는 지방이 1% 함유되어 건강에 좋은 유제품이므로 이것을 유부와 유청으로 제조한 후 가공하면 우리의 식생활에 맞는 식품으로 개발이 가능하다. 유부는 물에서 5분 이상 끓여도 흩어짐이 없이 고형상태를 유지하여 찌게나 국물에도 안전한 조리가 가능하다. 유부와 유청은 우유가 갖고 있는 향미가 더욱 발현되었다. 유부를 제2차 조제 가공하여 유아식과 노인용 식품을 개발 할 수 있는 전망이 밝다. 우유두부제조와 같은 콩 단백질 응고성에 의존한 우유 응고 방식은 본 제조과정으로 대치될 수 있고, 물로 씻어 가축의 사료나, 비료로 사용했던 유청을, 본 발명에서는 최저 수준의 응고제를 첨가하여 회수 한 후 식품으로 이용이 가능하다는 것이 본 발명의 효과이다. 본 제조방법에 의한 유청은 pH가 5.99-6.10 사이 이므로 드링크제 제조에 응용이 가능하다.Since skimmed milk powder is a healthy dairy product containing 1% fat, it can be developed into foods suitable for our diet by making it into processed milk and whey. Even if boiled in water for more than 5 minutes, it stays solid without being scattered, so it can be cooked safely to steam or broth. Whey and whey are more expressive of the flavor of milk. The prospects for developing infant foods and foods for the elderly are good. The milk coagulation method based on soy protein coagulation, such as milk tofu production, can be replaced by the present manufacturing process, and the whey used as animal feed or fertilizer washed with water is recovered by adding the lowest coagulant in the present invention. It is an effect of the present invention that it can be used as a food. Whey according to the present manufacturing method has an pH of 5.99-6.10 and thus can be applied to drink preparation.

Claims (1)

순수 우유를 응고제 첨가 후에 가열한 후 유부와 유청을 제조 하는 방법에 있어서, 염화칼슘(CaCl2) 단독 또는 염화칼슘과 염화마그네슘(MgCl2)을 1:1의 비율로 혼합한 응고제를 사용하며, 사용하는 우유 중량에 대하여 염화칼슘은 최저 0.15% 내지 0.5%, 염화칼슘과 염화마그네슘의 혼합 응고제는 0.18% 내지 0.5%의 범위에서 우유에 응고제를 먼저 첨가한 후에 가열을 시작하고 계속 끓임으로 우유를 다량 응고를 시켜고 유부와 유청을 분리하는 것을 특징으로 하는 유부, 유청의 제조방법.In the method of preparing milk and whey after heating pure milk after coagulant addition, a coagulant mixed with calcium chloride (CaCl 2 ) alone or calcium chloride and magnesium chloride (MgCl 2 ) in a ratio of 1: 1 is used. Calcium chloride is the minimum 0.15% to 0.5% by weight of milk, mixed coagulant of calcium chloride and magnesium chloride in the range of 0.18% to 0.5%, the coagulant is added to the milk first, then heating starts and the milk is solidified by continuous boiling Whey, whey manufacturing method characterized in that the separated whey and whey.
KR1019990026204A 1999-06-30 1999-06-30 Manufacturing Method of Milk-Curd and Whey KR100331124B1 (en)

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