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KR100271946B1 - Thermo-transfer film and preparing method thereof - Google Patents

Thermo-transfer film and preparing method thereof Download PDF

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Publication number
KR100271946B1
KR100271946B1 KR1019980050587A KR19980050587A KR100271946B1 KR 100271946 B1 KR100271946 B1 KR 100271946B1 KR 1019980050587 A KR1019980050587 A KR 1019980050587A KR 19980050587 A KR19980050587 A KR 19980050587A KR 100271946 B1 KR100271946 B1 KR 100271946B1
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transfer film
layer
resin
cellulose nitrate
wood
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KR1019980050587A
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Korean (ko)
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KR20000033639A (en
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김진규
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김진규
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/36Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/10Intaglio printing ; Gravure printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/38Printing on other surfaces than ordinary paper on wooden surfaces, leather, or linoleum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
  • Printing Methods (AREA)

Abstract

본 발명은 가공목재 피복용 전사 필름 및 그의 제조방법에 관한 것으로, 구체적으로 ⅰ) 폴리염화비닐 (Poly Vinyl Chloride; PVC)로 이루어지는 수지층, ⅱ) 폴리우레탄 수지 (Poly Urethane resin); 셀룰로오스 니트레이트; 에틸 알코올, 이소프로필 알코올 및 톨루엔 중에서 선택되는 유기용매로 이루어진 이형층 및 ⅲ) 폴리아미드 수지 (Polyamide resin); 셀룰로오스 니트레이트; 안료; 에틸 알코올, 이소프로필 알코올 및 톨루엔 중에서 선택되는 유기용매를 배합하여 이루어진 인쇄층으로 이루어지는 본 발명의 가공목재 피복용 전사 필름은 제조공정이 간단하고, 전사후 인쇄층이 탈색되지 않아 가공목재의 요철 및 측면에 특히 유용하게 적용될 수 있다.BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a transfer film for processing wood and a method for manufacturing the same, specifically iii) a resin layer made of polyvinyl chloride (PVC), ii) a polyurethane resin; Cellulose nitrate; A release layer composed of an organic solvent selected from ethyl alcohol, isopropyl alcohol and toluene, and iii) polyamide resin; Cellulose nitrate; Pigments; The transfer film for processing wood coatings of the present invention comprising a printing layer comprising an organic solvent selected from ethyl alcohol, isopropyl alcohol and toluene has a simple manufacturing process, and the printing layer is not discolored after transfer, so that unevenness of processed wood and It may be particularly useful to the side.

Description

전사 필름 및 그의 제조방법Transfer film and manufacturing method thereof

본 발명은 전사 필름 및 그의 제조방법에 관한 것으로, 보다 상세하게는 ⅰ) 수지층, ⅱ) 이형층 및 ⅲ) 인쇄층으로 이루어지는 가공목재 피복용 전사 필름 및 그의 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to a transfer film and a method for producing the same, and more particularly, to a transfer film for processing wood coating comprising a resin layer, ii) a release layer, and a printing layer, and a method for producing the same.

열전사 필름은 주로 중밀도 섬유판 (Medium Density Fiberboard; 이하 "MDF"라 약칭함)과 같은 기판에 피복되어 무늬를 형성하는데 사용되어 왔다. 가구부품으로 천연목재 그 자체를 사용하면 천연목재 고유의 무늬가 그대로 나타나며 필요에 따라 다양한 요철무늬로 조각하여도 무늬가 그대로 유지되어 아름다운 입체무늬를 가진 가구부품을 제조할 수 있었다. 그러나 가구의 수요는 급증하는 반면 목재의 공급은 극히 제한되어 있는 실정이므로 천연목재가 아닌 가공목재로서도 천연목재 고유의 무늬를 나타낼 수 있는 가구부품 등을 만드는 기술이 개발되어 왔다.Thermal transfer films have been mainly used to form patterns by coating on substrates such as Medium Density Fiberboard (abbreviated as "MDF"). When natural wood itself is used as a furniture part, the unique pattern of natural wood appears as it is, and even if carved into various uneven patterns, the pattern remains as it is, and thus furniture parts with beautiful three-dimensional patterns could be manufactured. However, since the demand for furniture is soaring but the supply of wood is extremely limited, technology has been developed to produce furniture parts that can exhibit the unique patterns of natural wood, not processed wood but natural wood.

종래에 MDF 등의 가공목재에 피복하는 필름은 폴리에스테르계 수지 또는 폴리비닐계 수지로 된 필름에 인쇄층이 형성된 것으로, 가공목재의 표면에 직접 부착하는 형태로 피복되었는데, 이는 인쇄층과 수지층이 분리되지 않아 가공 목재의 표면에 엠보싱면이 있거나 굴곡면이 있는 경우에는 전사가 불가능한 문제가 있었다. 이러한 문제점을 극복하기 위하여 엠보싱면이나 굴곡면이 있는 가공목재에 무늬모양을 피복할 수 있는 곡면피복용 열전사필름이 개발된 바 있다 (대한민국 특허출원 제 93-6918호 참조). 그러나 이러한 곡면피복용 열전사 필름은 제조공정이 번거롭고 장시간이 소요되며, 실제로 가공 목재에 피복하였을 때 인쇄층이 쉽게 탈색되는 문제점이 있었다.Conventionally, a film coated on processed wood such as MDF is formed of a printing layer on a film made of polyester resin or polyvinyl resin, and is coated in a form of directly adhering to the surface of the processed wood, which is a printing layer and a resin layer. There was a problem that the transfer is impossible if there is an embossed surface or curved surface on the surface of the processed wood is not separated. In order to overcome this problem, a thermal coating film for curved coating has been developed that can cover the pattern of the embossed or curved surface of the wood (see Korean Patent Application No. 93-6918). However, such a thermal coating film for the curved coating has a problem that the manufacturing process is cumbersome and takes a long time, when the printed layer is easily discolored when actually coated on the processed wood.

이에 본 발명자는 상기와 같이 종래의 전사 필름이 가지는 문제점을 해결하기 위하여 노력하여 오던 중, ⅰ) 수지층, ⅱ) 셀룰로오스 니트레이트를 포함하는 이형층 및 ⅲ) 폴리아미드 수지 및 셀룰로오스 니트레이트를 포함하는 인쇄층으로 이루어지는 전사 필름이, 제조공정이 간단하고 전사후 인쇄층이 쉽게 탈색되지 않아 가공목재에 유용하게 적용될 수 있음을 알아내어 본 발명을 완성하였다.The present inventors have been trying to solve the problems of the conventional transfer film as described above, i) a resin layer, ii) a release layer containing cellulose nitrate and iii) a polyamide resin and cellulose nitrate. The transfer film consisting of a printed layer to complete the present invention was found that the manufacturing process is simple and the post-transfer printing layer is not easily discolored and can be usefully applied to the processed wood.

본 발명의 목적은 가공목재의 요철이나 측면에 효과적으로 무늬를 형성할 수 있을 뿐만 아니라 전사 후에 인쇄층이 쉽게 탈색되지 않는 가공목재 피복용 전사 필름 및 그의 제조방법을 제공하는 것이다.SUMMARY OF THE INVENTION An object of the present invention is to provide a transfer film for processing wood coatings and a method of manufacturing the same, which can effectively form a pattern on unevenness or side surface of the processed wood, and which does not easily discolor the printed layer after transfer.

상기 목적을 달성하기 위하여 본 발명에서는 ⅰ) 수지층, ⅱ) 셀룰로오스 니트레이트를 포함하는 이형층 및 ⅲ) 폴리아미드 수지 및 셀룰로오스 니트레이트를 포함하는 인쇄층으로 이루어지는 가공목재 피복용 전사 필름 및 그의 제조방법을 제공한다.In order to achieve the above object, in the present invention, the transfer film for processing wood coating comprising the resin layer, ii) a release layer containing cellulose nitrate, and iii) a printing layer containing polyamide resin and cellulose nitrate, and the production thereof Provide a method.

이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명에서는 우선 ⅰ) 폴리염화비닐 (Poly Vinyl Chloride; PVC)로 이루어지는 수지층, ⅱ) 폴리우레탄 수지 (Poly Urethane resin); 셀룰로오스 니트레이트; 에틸 알코올, 이소프로필 알코올 및 톨루엔 중에서 선택되는 유기용매로 이루어진 이형층 및 ⅲ) 폴리아미드 수지 (Polyamide resin); 셀룰로오스 니트레이트; 안료; 에틸 알코올, 이소프로필 알코올 및 톨루엔 중에서 선택되는 유기용매를 배합하여 이루어진 인쇄층으로 이루어지는 가공목재 피복용 전사 필름을 제공한다.In the present invention, firstly, iii) a resin layer made of polyvinyl chloride (PVC), ii) a polyurethane resin; Cellulose nitrate; A release layer composed of an organic solvent selected from ethyl alcohol, isopropyl alcohol and toluene, and iii) polyamide resin; Cellulose nitrate; Pigments; Provided is a transfer film for processing wood coatings comprising a printing layer comprising an organic solvent selected from ethyl alcohol, isopropyl alcohol and toluene.

본 발명의 전사 필름은 이형층 성분으로 폴리우레탄 수지와 셀룰로오스 니트레이트를 포함하고, 인쇄층에 안료와 폴리아미드 수지 및 셀룰로오스 니트레이트를 포함함으로써 필름을 가공목재에 전사한 다음 인쇄층이 탈색되는 것을 방지할 수 있다.The transfer film of the present invention includes a polyurethane resin and cellulose nitrate as a release layer component, and includes a pigment, a polyamide resin and a cellulose nitrate in the printing layer, thereby transferring the film to the processed wood and then decolorizing the printed layer. You can prevent it.

상기 전사 필름에서 가공목재는 중밀도 섬유판 (Medium Density Fiberboard ; MDF), 파티클 보드 (Particle Board; PB), 고압 멜라민 (High Pressure Melamine, HPM), 저압 멜라민 (Low Pressure Melamine, LPM) 중에서 선택된다.Processed wood in the transfer film is selected from Medium Density Fiberboard (MDF), Particle Board (PB), High Pressure Melamine (HPM), Low Pressure Melamine (LPM).

또한 본 발명에서는 상기 전사 필름의 제조방법을 제공한다.In addition, the present invention provides a method for producing the transfer film.

본 발명의 전사 필름은 수지층에 이형층을 바르는 단계 및 잉크로 무늬를 인쇄하는 공정으로 이루어지며, 이 때 인쇄는 그라비아 인쇄 방법으로 수행하는 것이 바람직하다. 이러한 제조방법은 종래의 전사 필름의 제조공정이 보호 프라이머 처리 공정과, 이를 24시간 정도 경화시키는 공정을 포함하는 것에 비하면 공정이 간단해 졌을 뿐만 아니라 시간도 단축된다.The transfer film of the present invention consists of a step of applying a release layer to the resin layer and a process of printing a pattern with ink, wherein printing is preferably performed by a gravure printing method. This manufacturing method is simpler as well as shorter in time than the conventional transfer film manufacturing process including a protective primer treatment step and a step of curing it for about 24 hours.

이하 본 발명을 실시예에 의하여 상세히 설명하기로 한다. 단 하기 실시예는 발명을 예시하는 것일 뿐 본 발명이 실시예에 의하여 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to Examples. However, the following examples are merely to illustrate the invention and the present invention is not limited by the examples.

<실시예 1> 전사 필름의 제조방법Example 1 Manufacturing Method of Transfer Film

이형제 성분인 폴리우레탄 수지와 셀룰로오스 니트레이트를 에틸 알코올에 녹인 용매를 PVC 시트에 도포하였다. 다음 폴리아미드 수지, 셀룰로오스 니트레이트, 안료 및 이소프로필 알코올을 배합하여 제조한 잉크를 이용하여 상기 이형제층에 그라비아 인쇄방법을 이용하여 나무무늬를 인쇄하여 본 발명의 전사 필름을 제조하였다.The solvent which melt | dissolved the polyurethane resin which is a mold release agent component, and cellulose nitrate in ethyl alcohol was apply | coated to the PVC sheet. Next, the transfer film of the present invention was prepared by printing a wood pattern on the release agent layer using a gravure printing method using an ink prepared by mixing polyamide resin, cellulose nitrate, pigment, and isopropyl alcohol.

<실시예 2> 전사 필름의 적용 (1)Example 2 Application of Transfer Film (1)

상기 실시예에서 제조한 전사 필름을 가공하고자 하는 MDF 표면의 모양과 동일하도록 재단한 다음 전사 필름의 인쇄층이 MDF의 표면에 접하도록 올려놓은 후 멤버링 프레스 (Membering Press)에서 약 80∼150 ℃ 정도의 온도를 가하여 150∼180초 정도 압착한 후 수지층을 벗겨내어 MDF 표면에 나무무늬가 전사되도록 하였다.The transfer film prepared in the above example was cut to have the same shape as the surface of the MDF to be processed, and then the printed layer of the transfer film was placed on the surface of the MDF, and then placed at about 80 to 150 ° C. in a membering press. After applying a temperature of about 150-180 seconds, the resin layer was peeled off so that the wood pattern was transferred onto the MDF surface.

<실시예 3> 전사 필름의 적용 (2)Example 3 Application of Transfer Film (2)

MDF 대신 PB를 사용하는 것을 제외하고는 상기 실시예 2와 동일한 방법을 이용하여 무늬가 전사되도록 하였다.The pattern was transferred using the same method as Example 2 except for using PB instead of MDF.

<실시예 4> 전사 필름의 적용 (3)Example 4 Application of Transfer Film (3)

MDF 대신 HPM를 사용하는 것을 제외하고는 상기 실시예 2와 동일한 방법을 이용하여 무늬가 전사되도록 하였다.The pattern was transferred using the same method as Example 2 except for using HPM instead of MDF.

<실시예 5> 전사 필름의 적용 (4)Example 5 Application of Transfer Film (4)

MDF 대신 LPM를 사용하는 것을 제외하고는 상기 실시예 2와 동일한 방법을 이용하여 무늬가 전사되도록 하였다.The pattern was transferred using the same method as Example 2 except for using LPM instead of MDF.

<실험예>Experimental Example

본 발명의 실시예 1에서 제조된 전사 필름과 특허출원 제 93-6918호에 기재된 열전사 필름을 가공목재에 전사하여 비교하여 본 결과, 1주일 경과 후 특허출원 제 93-6918호에 기재된 열전사 필름은 육안으로 보기에도 탈색정도가 심하였으나 본 발명의 실시예 1에서 제조된 전사 필름은 전사후 인쇄층의 탈색이 전혀 일어나지 않았다. 이는 이형층으로서 셀룰로오스 니트레이트와 폴리우레탄 수지를 사용하고, 인쇄층에 폴리아미드 수지를 안료와 배합하여 사용한 것이 작용한 결과로 보여진다.The transfer film produced in Example 1 of the present invention and the thermal transfer film described in Patent Application No. 93-6918 were compared to the processed wood, and as a result, after one week, the thermal transfer described in Patent Application No. 93-6918 was obtained. Although the film was severely discolored even with the naked eye, the transfer film produced in Example 1 of the present invention did not cause any discoloration of the printing layer after the transfer. This is seen as a result of using cellulose nitrate and a polyurethane resin as a release layer and using a polyamide resin in combination with a pigment in the printing layer.

이상에서 살펴본 바와 같이, 본 발명의 전사 필름은 보호 프라이머층 처리 공정 및 경화공정 등이 불필요하여 제조공정이 간단할 뿐만 아니라 필름을 가공목재에 전사하였을 때 인쇄층이 가공목재로부터 쉽게 탈색되지 않아 가공목재에 유용하게 적용될 수 있다.As described above, the transfer film of the present invention does not require a protective primer layer treatment process and a curing process, so that the manufacturing process is simple, and when the film is transferred to the processed wood, the printed layer is not easily discolored from the processed wood, and thus processed. It can be usefully applied to wood.

Claims (3)

ⅰ) 폴리염화비닐 (Poly Vinyl Chloride; PVC)로 이루어지는 수지층, ⅱ) 폴리우레탄 수지 (Poly Urethane resin); 셀룰로오스 니트레이트; 에틸 알코올, 이소프로필 알코올 및 톨루엔 중에서 선택되는 유기용매로 이루어진 이형층 및 ⅲ) 폴리아미드 수지 (Polyamide resin); 셀룰로오스 니트레이트; 안료; 에틸 알코올, 이소프로필 알코올 및 톨루엔 중에서 선택되는 유기용매를 배합하여 이루어진 인쇄층으로 이루어지는 것을 특징으로 하는 가공목재 피복용 전사 필름.Iii) a resin layer consisting of Poly Vinyl Chloride (PVC), ii) a Polyurethane resin; Cellulose nitrate; A release layer composed of an organic solvent selected from ethyl alcohol, isopropyl alcohol and toluene, and iii) polyamide resin; Cellulose nitrate; Pigments; A transfer film for processing wood coatings, comprising a printing layer comprising an organic solvent selected from ethyl alcohol, isopropyl alcohol, and toluene. 제 1항에 있어서, 가공목재는 중밀도 섬유판 (Medium Density Fiberboard ; MDF), 파티클 보드 (Particle Board; PB), 고압 멜라민 (High Pressure Melamine, HPM), 저압 멜라민 (Low Pressure Melamine, LPM) 중에서 선택되는 것임을 특징으로 하는 가공목재 피복용 전사 필름.The method of claim 1, the processed wood is selected from Medium Density Fiberboard (MDF), Particle Board (PB), High Pressure Melamine (HPM), Low Pressure Melamine (LPM) Transfer film for processing wood coatings, characterized in that. 수지층에 이형층을 바르는 단계 및 그라비아 인쇄 방법으로 무늬를 인쇄하는 공정으로 이루어지는 것을 특징으로 하는 제 1항의 전사 필름의 제조방법The method of manufacturing the transfer film of claim 1, comprising the step of applying a release layer to the resin layer and a step of printing a pattern by a gravure printing method.
KR1019980050587A 1998-11-25 1998-11-25 Thermo-transfer film and preparing method thereof KR100271946B1 (en)

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Publication number Priority date Publication date Assignee Title
KR100329660B1 (en) * 1999-12-01 2002-03-25 노도성 transfer paper

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KR100486657B1 (en) * 2002-02-04 2005-05-03 서울화학(주) Heat transfer film directly transfered to low pressure melamine and high pressure melamine, and Manufacturing process thereof
KR100482764B1 (en) * 2002-04-12 2005-04-14 최한탁 A manufacturing process and a product of a sublimation heating-transfer color print MDF
KR20040026154A (en) * 2002-09-23 2004-03-30 주식회사 한샘 A pattern printing method for boards

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100329660B1 (en) * 1999-12-01 2002-03-25 노도성 transfer paper

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