KR100260979B1 - A process of the treatment for waste smell by using microbe fixed cillium ball, and the bio-reactor therefor - Google Patents
A process of the treatment for waste smell by using microbe fixed cillium ball, and the bio-reactor therefor Download PDFInfo
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- KR100260979B1 KR100260979B1 KR1019970050921A KR19970050921A KR100260979B1 KR 100260979 B1 KR100260979 B1 KR 100260979B1 KR 1019970050921 A KR1019970050921 A KR 1019970050921A KR 19970050921 A KR19970050921 A KR 19970050921A KR 100260979 B1 KR100260979 B1 KR 100260979B1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C02F3/00—Biological treatment of water, waste water, or sewage
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- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Abstract
Description
본 발명은 제1도에서 보듯이 섬모상 접촉여재로 PP와 나일론으로 제조되어 견고성이 우수하며, 수많은 털(섬모, Cilium)로 이루어진 원형구조를 가진 3∼10mm 정도의 짧은 털의 섬모상 접촉여재로서 고농도 유기성 악취를 처리하는 장치 및 그 폐수처리 방법에 관한 것이다.The present invention is made of PP and nylon as the ciliary contact media as shown in FIG. 1, and has excellent rigidity, and has a short hairy ciliary contact media of about 3 to 10 mm with a circular structure composed of numerous hairs (cili and cilium). The present invention relates to an apparatus for treating high concentration organic odor and a wastewater treatment method thereof.
악취농도가 매우 높은 것으로는 분뇨, 축산, 주정, 식품폐기물 그리고 도축장이 있으며, 심한 경우에는 유기물 내 악취농도가 500ppm이상 되는 경우도 있다. 이처럼 유기물 내 악취 농도가 높으면 부패하여 흙, 자갈 등을 이용한 기존의 토양처리공법으로 악취처리를 할 경우 메디아의 기공을 막아버려 담체층 폐쇄현상 뿐 아니라 혐기성 세균증식으로 인해 악취농도가 분산되지 않아 처리효율 저하 및 많은 부지 면적이 필요하다.Very high odor concentrations include manure, animal husbandry, spirits, food waste and slaughterhouses. In severe cases, odor concentrations in organic matters may exceed 500 ppm. In this way, if the concentration of odor in organic matter is high, if the odor treatment is performed by the existing soil treatment method using soil and gravel, it prevents pores of the media and closes the carrier layer. Efficiency reduction and large site area are required.
따라서, 본 발명은 높은 유기물 농도에서도 잘 증식하여 부착성이 강한 세균, 곰팡이를 고정화한 원형섬모상 접촉여재를 이용한 고농도 유기성 악취와 난분해성 물질을 제거하여 처리하는 장치 및 방법을 제공함에 그 목적이 있다.Accordingly, an object of the present invention is to provide an apparatus and method for removing and treating high-concentration organic odor and hardly decomposable substances using a circular ciliated contact medium immobilized with high adhesion at a high organic matter concentration and having strong adhesiveness. have.
제1도는 본 발명에서의 원형 섬모상 접촉여재를 이용한 악취처리 공정도.1 is a odor treatment process chart using a circular ciliated contact medium in the present invention.
제2도는 본원 발명에서 사용되는 원형의 섬모상 접촉여재로 섬모의 길이가 3∼10mm 정도의 짧은 여재.2 is a circular cilia-like contact medium used in the present invention, wherein the length of the cilia is about 3 to 10 mm.
제3도는 본원 발명에서 사용되는 원형의 섬모상 접촉여재에 미생물 고정화된 섬모여재.3 is a microfilament immobilized on microorganisms in a circular ciliated contact media used in the present invention.
제4도는 본원 발명에서 사용되는 직경 5mm 내외의 다공성 퍼라이트 메디아.4 is a porous perlite media of about 5mm in diameter used in the present invention.
이하 본 발명에 대하여 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명은 기본적으로 2개의 공정으로 이루어져 있는데 첫 번째 공정은 투입구를 이용하여 순환 산기관을 이용하여 고농도의 산성과 알카리성 악취 유입물을 중화하는 공정이고,The present invention basically consists of two processes. The first process is to neutralize high concentrations of acidic and alkaline odor inflows using a circulating acid pipe using an inlet.
두 번째 공정은 세균, 곰팡이를 부착시킨 원형섬모상 접촉여재를 이용하여 고농도의 NH3, H2S, 메칠메르캅탄(CH3SH)를 제거하는 공정으로 구성된다.The second process consists of removing high concentrations of NH 3 , H 2 S, and methyl mercaptan (CH 3 SH) using circular ciliary contact media with bacteria and molds attached.
본 공정에서는 살수관을 설치하여 수분을 조절해 줌으로써 투입되는 종균제 또는 고정화된 세균, 곰팡이 등이 잘 활동하도록 한다.In this process, the water spray pipe is installed to control the water so that the spawning agent or immobilized bacteria, mold, etc. can be well-acted.
첫 번째 공정에서는 1개의 악취 유입구(1)와 고농도의 산, 알카리성 유기물이 투입되는 pH반응조(2)에 악취유입시 중화제 투입구(10)을 통해 pH조정제가 투입되고 pH 6 내지 8정도 범위내로 조정되고 순환산기관(11)에 의해 혼합되어 상부의 분산격벽판(3)을 통해 상부로 송풍기와 같은 동력장치에 의해 이송되는 공정이다.In the first process, the pH adjuster is introduced through the neutralizer inlet (10) when the malodor is introduced into the pH reaction tank (2) into which one odor inlet (1) and high concentrations of acids and alkaline organics are introduced. It is a process that is mixed by the circulation diffuser 11 and conveyed by a power unit such as a blower to the upper through the upper distribution partition plate (3).
두 번째 공정에서는 1개의 악취처리 생물분해조(14)를 원형의 고정화 섬모형 접촉여재(4)와 종균제를 투입하고, 상층부에는 살수관(5)이 설치되어 있다. 그리고 최종 처리된 악취의 유출을 위한 ∧자형 분리판(7)이 설치되어 있다. 또한, 필요에 따른 제2공정의 생물분해조를 2개이상 설치하기도 한다.In the second step, one odor treatment biodegradation tank 14 is introduced with a circular immobilized cilia contact medium 4 and a seed agent, and a watering pipe 5 is installed at the upper layer. And the U-shaped separator 7 for the outflow of the odor which was processed finally is provided. In addition, two or more biodegradation tanks of the second process may be installed as necessary.
본 발명에서 특징적인 기술적 구성으로는 첫 번째 공정의 악취유입 pH반응조(2)에 이어서 제2공정의 악취처리를 위한 생물분해조(14)의 내부는 원형의 섬모형 접촉여재(4) 및 다공성 퍼라이트(12)의 충진을 내장하고 있는 점이다. 첫 번째 공정의 반응조에 순환 산기관을 사용한 이유는 고농도의 산성 또는 알칼리성 악취유입물이 유입시 교반 및 순환하여 pH 6 내지 8정도의 중성으로 조정되어서 제2공정으로 악취유입물이 막바로 흘러 들어가는 것을 방지하기 위함이다. 또한 첫 번째 반응조에 투입되는 분산격벽판(3)은 다공질의 원판형으로 고농도의 악취원이 유입시 분산 안정화시켜서 악취 처리효율을 증대시킬 수 있다.Characteristic technical features of the present invention is that the inside of the biodegradation tank 14 for the malodor inflow pH reaction tank (2) of the first process, followed by the malodor treatment of the second process is a circular ciliary contact medium (4) and porous The point is that the filling of the ferrite 12 is incorporated. The reason for using the circulating acid pipe in the reaction tank of the first process is that the high concentration of acidic or alkaline odor influx is stirred and circulated at the inflow to adjust to a neutral pH of about 6 to 8 so that the odor inflow flows into the second process. To prevent this. In addition, the dispersion partition plate (3) introduced into the first reaction tank is a porous disk-shaped to increase the odor treatment efficiency by stabilizing dispersion when a high concentration of odor source is introduced.
또한 두 번째 공정의 생물분해조에 원형 고정화 섬모형 접촉여재를 충진한 이유는 첫 번째 공정에서 중성으로 pH가 조정된 악취원이 유입하면 원형 섬모형 접촉여재에 흡착되도록 하여 여기서 세균 및 곰팡이의 증식을 유도하여 악취가 넓은 면적에 접촉되어 단시간 내에 처리되도록 하기 위함이고, 또한 제1공정에서 나오는 악취의 pH변화와 유기원의 농도 변화에 대한 부하변동에 대해서 부착생물을 이용하고 다공섬모상 타입의 충진을 통하여 접촉여재 표면 전체에 산소 전달과 악취원 분산 전달이 용이하여 정화된 처리공기를 배출하고자 함이다.In addition, the reason why the circular immobilized ciliary contact medium is filled in the biodegradation tank of the second process is that when the neutralized pH-adjusted odor source flows in the first process, it adsorbs to the circular ciliated contact medium, thereby preventing the growth of bacteria and mold. To induce the malodor to be treated in a short time by contacting a large area, and also to use the attachment microorganisms for the load variation on the pH change of the malodor from the first process and the concentration of the organic source Through this, it is easy to transfer oxygen to the entire surface of the contact medium and transfer odor distribution to purify the treated air.
따라서 본 발명은 악취처리 공정에 따라 섬모상 접촉여재를 생물분해조에 설치하고 고농도의 유기성 악취와 암모니아를 제거 처리함에 그 목적이 있다. 고농도의 유기성 악취는 일반적으로 활성탄 처리와 화학세정식 처리를 행하는 것이 보통인데, 본 발명에 있어서는 악취의 화학적 전처리없이 제1공정에 주입시킨다.Therefore, an object of the present invention is to install a ciliated contact medium in a biodegradation tank according to the odor treatment process and to remove high concentrations of organic odor and ammonia. In general, organic odors of high concentration are usually treated with activated carbon and chemical cleaning. In the present invention, the organic odor is injected into the first step without chemical pretreatment of the odor.
일반적으로 고농도의 악취는 pH 3정도의 산성악취이나, 본 발명에서는 pH 3∼8의 범위도 본 처리장치에 의해서 처리하기에 적합한 점을 볼 때 본 발명에서는 pH 조정에 필요한 약품비를 절감하고 촉매제도 필요없고, 자체 유입공기에 의한 것이므로 제1공정의 시설비와 유지관리비가 적게 든다. 그러나 이보다도 고농도의 산성 또는 알카리성 악취원은 pH가 불균형을 보여 적절한 조정제로써 가성소다, 황산 첨가를 해줌으로써 분해가 촉진되어 악취제거 효율을 높이게 된다.In general, high concentrations of odors are acidic odors of about pH 3, but in the present invention, the range of pH 3 to 8 is also suitable for treatment by the treatment apparatus. It is not necessary, and due to its own inlet air, the cost of facility and maintenance of the first process is low. However, higher concentrations of acidic or alkaline malodorous sources show disproportionate pH, so that the decomposition is promoted by adding caustic soda and sulfuric acid as appropriate regulators to increase the odor removal efficiency.
종균을 첨가하는 제2공정에서는 생물분해조 내 질소원과 황을 제거하는데 중요한 역할을 한다. 종균제로 사용되는 것으로는 Bacillus cercus, Bacillus subtilis, Bacillus licheniformis, Thiobacillus intermedius 등이 사용될 수 있다. 제2공정에서는 주입시켜 주면 이것이 미생물에 의한 탈질 및 산화가 섬모상 여재층에서 일어나 유기물을 분해하는 유기영양세균, 질소화합물을 산화시키는 아질산화에 관여하는 Nitrosomonas와 질산화에 관여하는 Nitrobacter균에 의해 암모니아가 제거될 뿐 아니라, 황화수소는 황박테리아에 의한 산화세균, Thiobacillus와 Filamentous Bacteria가 황원소를 황산염으로 변화시키며 Filamentous sulfur Bacteria는 Chemoautotrophic Bacteria로서 H2S를 에너지원으로 사용한다. 기타 Beggiatoa, Thiothrix와 곰팡이 증식이 촉진된다.The second step, which adds spawn, plays an important role in removing nitrogen sources and sulfur in the biodegradation tank. As a spawning agent, Bacillus cercus, Bacillus subtilis, Bacillus licheniformis, Thiobacillus intermedius, etc. may be used. In the second step, when injected, this is caused by the denitrification and oxidation caused by microorganisms in the ciliary media layer, and the ammonia by Nitrosomonas, which is involved in nitrous oxidation, which is responsible for oxidizing nitrogen, and nitrous oxidation, which oxidizes nitrogen compounds. In addition to the removal of hydrogen sulfide, sulfur bacteria are oxidative bacteria caused by sulfur bacteria, Thiobacillus and Filamentous Bacteria convert sulfur elements into sulfates, and Filamentous sulfur Bacteria uses H 2 S as an energy source. Other Beggiatoa, Thiothrix and fungus proliferate.
상기 공정에 부가하여, 제1공정에서 세균 곰팡이 증식의 오니가 검은색으로 변하는 듯하면 반응조내 오니를 인출해 주어야 한다. 반응조 바닥에는 오니 인출관(13)을 장치한다.In addition to the above process, if the sludge of bacterial fungus growth turns black in the first step, the sludge in the reaction tank should be taken out. A sludge draw tube 13 is installed at the bottom of the reactor.
또는 제2공정에 사용하는 종균 미생물인 세균, 곰팡이류의 섬모여재에 공정화시키는 방법은 종균배양물을 60℃정도에서 통풍건조 시킨후 고정화시켜 사용한다. 물론 통상적인 고정화 방법인 반응조내에 종균을 투입하는 방법을 사용하여 고정화 할 수 있다.Alternatively, the method of making a process in the ciliary media of bacteria and fungi, which are spawn microorganisms used in the second process, is used after the spawn culture is ventilated at about 60 ° C. and then immobilized. Of course, it can be immobilized using a method of adding the seed in the reaction tank which is a conventional immobilization method.
본 발명에 의한 장치와 방법의 효과를 다음에 예시하는 실시예는 본 발명의 효과 및 기술적 구성을 예시할 목적으로 제시된 것이며, 이것으로 본 발명의 범위를 제한하고자 하는 것은 아니다.The following examples which illustrate the effects of the apparatus and method according to the present invention are presented for the purpose of illustrating the effects and technical configurations of the present invention, which are not intended to limit the scope of the present invention.
[실시예 1]Example 1
본원 발명의 악취처리 장치를 이용해서 폐수처리를 함에 있어서, 제1공정 및 제2공정상에서 안양시 분뇨처리장의 분뇨 악취를 연속적으로 주입하여 처리하였다. 분뇨 악취의 성상은 다음과 같다.In the wastewater treatment using the malodor treatment apparatus of the present invention, the manure odor of the Anyang municipal waste treatment plant was continuously injected and treated in the first and second processes. The appearance of manure odor is as follows.
상기 악취를 본 발명의 제1공정(pH반응조), 제2공정(생물분해조)으로 처리하였는데 pH반응조 1개의 용량은 150ℓ이고, 제2생물분해조 용량은 300ℓ로 전체와 생물분해조 전체 체류시간 24sec/day 기체 통과속도는 2.5m/min이었다. 또한 충진된 섬모상 접촉여재의 면적도 1,260m2였다.The odor was treated in the first step (pH reaction tank) and the second step (biodegradation tank) of the present invention. The capacity of one pH reaction tank was 150 l and the second biodegradation tank was 300 l. Time 24 sec / day The gas passage speed was 2.5 m / min. The area of the filled ciliary contact medium was also 1,260 m 2 .
본원 발명의 악취처리시에 우정미생물로 사용가능하고 본원 장치의 섬모상 접촉여재에 부착하는 미생물은 다음과 같다.Microorganisms that can be used as postal microorganisms in the malodor treatment of the present invention and adhere to the ciliary contact media of the present apparatus are as follows.
또한 본 실시예에서 사용된 고정화용 종균제로는 Bacillus cercus, Bacillus licheniformis, Bacillus megaterium, Achromobacter species, Thiobacillus intermedius이 사용되었다.In addition, the bactericide for immobilization used in the present embodiment was used Bacillus cercus, Bacillus licheniformis, Bacillus megaterium, Achromobacter species, Thiobacillus intermedius.
[실시예 2]Example 2
본원 발명의 폐수처리 공정의 제1공정 및 제2공정을 이용해서 다음의 축산악취를 연속적으로 주입하면서 악취처리하였다. 이천 하수처리장의 축산악취의 성상은 다음과 같다.The following livestock odors were inoculated continuously using the first step and the second step of the wastewater treatment step of the present invention. The characteristics of livestock odor at Icheon sewage treatment plant are as follows.
상기 악취를 제1공정(pH반응조), 제2공정(생물분해조) 원형 섬모형 접촉여재가 투입되어 있음과 제2공정으로 처리하는데 생물분해조의 용량은 300ℓ였다. 생물분해조 전체의 체류시간은 20sec/day이고, 기체 통과속도 3.0m/min이였다. 생물분해조 1개당 충진된 섬모형 접촉여재의 면적은 1,260m2였다.The odor was treated in the first step (pH reaction tank) and the second step (biodegradation tank) in the circular ciliary contact medium and in the second step. The capacity of the biodegradation tank was 300 liters. The residence time of the whole biodegradation tank was 20 sec / day, and the gas passage speed was 3.0 m / min. The area of the ciliated contact medium filled per biodegradation tank was 1,260 m 2 .
본원의 발명의 악취처리시 특히 축산 악취처리에 있어서 섬모형 접촉여재에 부착되는 악취처리에 우점미생물로서는 다음과 같다.In the malodor treatment of the present invention, in particular, in the livestock malodor treatment, the microorganisms which are dominant in the malodor treatment adhered to the ciliated contact media are as follows.
앞서 기술한 발명의 구성 및 작용항에서 살펴본 바와 같이 본원 발명의 폐수처리 장치 및 방법을 이용할 경우 고농도 유기성 악취의 경우에 NH3및 H2S등 유기물질의 제거가 현저한 것으로 나타났으며 메칠메르캅탄(CH3SH)도 제거되는 것으로 나타났다. 그 구체적인 처리효율은 본원 발명의 실시예에서도 상세히 기술되고 있다.As described in the above-described configuration and operation of the invention, when using the wastewater treatment apparatus and method of the present invention, it was shown that the removal of organic substances such as NH 3 and H 2 S was remarkable in the case of high concentration organic odor, and methyl mercaptan. (CH 3 SH) was also shown to be removed. The specific processing efficiency is also described in detail in the embodiments of the present invention.
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KR1019970050921A KR100260979B1 (en) | 1997-10-02 | 1997-10-02 | A process of the treatment for waste smell by using microbe fixed cillium ball, and the bio-reactor therefor |
CNB981243355A CN1165490C (en) | 1997-10-02 | 1998-10-02 | Process of treatment for waste smell by using microbe fixed cillium ball, and bio-reactor therefor |
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KR100360846B1 (en) * | 1999-11-15 | 2002-11-22 | 주식회사 태백종합환경기술단 | A floating biofilm media for odor control in wastewater treatment process |
CN104495879A (en) * | 2015-01-12 | 2015-04-08 | 武汉大学 | Integrated contact oxidation/nitrogen and phosphorus removal-filtering separation bioreactor |
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KR100324727B1 (en) * | 1999-04-15 | 2002-02-28 | 한기백 | Separating apparatus of suspended solid in liquid solution using flexible fiber |
KR100471385B1 (en) * | 2002-10-30 | 2005-03-10 | 한국과학기술연구원 | Purification apparatus and process for streamwater using Pearlite attached Polyethylene Net and Bulged Polypropylene media |
CN101076498B (en) * | 2004-11-22 | 2012-06-06 | 努比亚水系统有限公司 | Aeration type biofiltering system and waste water treatment method |
KR100971530B1 (en) * | 2009-09-08 | 2010-07-21 | 삼성엔지니어링 주식회사 | Wastewater treatment apparatus having bioreactor filled with media containing immobilized microbe and method of treating wastewater |
JP4565669B1 (en) * | 2010-04-19 | 2010-10-20 | 三菱重工環境・化学エンジニアリング株式会社 | Air diffuser and diffuser for sludge fluidized bed incinerator |
CN102826647B (en) * | 2012-08-15 | 2014-03-12 | 哈尔滨工业大学宜兴环保研究院 | Aerobic denitrification reactor with mycelium pellet as carrier and method for synchronous operation of nitrification and denitrification |
CN103922485B (en) * | 2014-04-04 | 2016-03-30 | 于美萍 | A kind of sewage deodorizing processing method |
CN103922472B (en) * | 2014-04-14 | 2016-03-02 | 北京工业大学 | The device and method of the denitrogenation of a kind of A/O process strengthening and biological deodorizing |
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Cited By (2)
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KR100360846B1 (en) * | 1999-11-15 | 2002-11-22 | 주식회사 태백종합환경기술단 | A floating biofilm media for odor control in wastewater treatment process |
CN104495879A (en) * | 2015-01-12 | 2015-04-08 | 武汉大学 | Integrated contact oxidation/nitrogen and phosphorus removal-filtering separation bioreactor |
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CN1165490C (en) | 2004-09-08 |
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