JPS63172753A - Flame-retardant crosslinkable resin composition - Google Patents
Flame-retardant crosslinkable resin compositionInfo
- Publication number
- JPS63172753A JPS63172753A JP291287A JP291287A JPS63172753A JP S63172753 A JPS63172753 A JP S63172753A JP 291287 A JP291287 A JP 291287A JP 291287 A JP291287 A JP 291287A JP S63172753 A JPS63172753 A JP S63172753A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- ethylene
- resin composition
- density polyethylene
- blend
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims description 20
- 239000011342 resin composition Substances 0.000 title claims description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 17
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 12
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 12
- 238000004132 cross linking Methods 0.000 claims abstract description 8
- 229920006132 styrene block copolymer Polymers 0.000 claims abstract description 8
- -1 polyethylene Polymers 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 3
- 239000011347 resin Substances 0.000 claims abstract description 3
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 9
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 9
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 8
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 abstract description 18
- 239000002904 solvent Substances 0.000 abstract description 12
- 239000003921 oil Substances 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 4
- 229920005601 base polymer Polymers 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005977 Ethylene Substances 0.000 abstract description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 abstract description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract description 2
- 239000000347 magnesium hydroxide Substances 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000011810 insulating material Substances 0.000 abstract 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 238000010894 electron beam technology Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- RBJLLJVGABEKAJ-UHFFFAOYSA-N gold;styrene Chemical compound [Au].C=CC1=CC=CC=C1 RBJLLJVGABEKAJ-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、高耐熱性、高難燃性を要求される絶縁電線
の絶縁体、絶縁チューブ、収縮チューブなどに好適な難
燃架橋性樹脂組成物に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention provides a flame-retardant crosslinkable resin suitable for insulators of insulated wires, insulating tubes, shrinkable tubes, etc. that require high heat resistance and high flame retardancy. Regarding the composition.
従来、この種の難燃架橋性樹脂組成物としては、例えば
低密度ポリエチレン１００１ｆｆｉ部に、エチレン−酢
酸ビニル共重合体またはスチレンーエチレンープヂレン
ースチレンブロック共重合体を１０〜２０重量部をブレ
ンドし、さらに有機ハロゲン化物などの難燃剤を１０〜
２０重ご部を配合した樹脂組成物が使用されており、こ
れを所定の形状に成形し、電子線を照射して架橋させる
ようになっている。Conventionally, this kind of flame-retardant crosslinkable resin composition has been prepared by adding 10 to 20 parts by weight of ethylene-vinyl acetate copolymer or styrene-ethylene-propylene-styrene block copolymer to 1001 parts of low-density polyethylene. and then add flame retardants such as organic halides to
A resin composition containing 20 parts by weight is used, which is molded into a predetermined shape and crosslinked by irradiation with an electron beam.
ところが、近年より高度の難燃性が要求されるようにな
り、難燃性向上のために多けの難燃剤を配合する必要が
生じている。However, in recent years, higher flame retardancy has been required, and it has become necessary to incorporate a large amount of flame retardant in order to improve flame retardancy.
しかしながら、上述の配合組成の樹脂組成物において、
難燃剤を例えば４０重量部程度にまで増量すると、組成
物の耐油性、耐溶剤性が著しく低下する問題があった。However, in the resin composition having the above-mentioned composition,
When the amount of the flame retardant is increased to, for example, about 40 parts by weight, there is a problem in that the oil resistance and solvent resistance of the composition are significantly reduced.
この発明では、樹脂組成物のベースポリマーとして直鎖
状低密度ポリエチレンと低密度ポリエチレンとのブレン
ド物を使用することをその解決手段とした。In this invention, the solution is to use a blend of linear low-density polyethylene and low-density polyethylene as the base polymer of the resin composition.
この発明の難燃架橋性樹脂組成物は、直鎖状低密度ポリ
エチレン（ＬＬＤＰ［Ｅ）と低密度ポリエチレン（１，
ＤＰＥ） とｔｒｍｍ比で１＝２〜１：６の割合でブレ
ンドし、このブレンド物１００重口部に対して、エチレ
ン−酢酸ビニル共重合体（ＥＶＡ）またはスヂレンーエ
チレンープチレンースチレンブロック共重合体（ＳＥＢ
Ｓ）を１０〜２０重吊部、難燃剤４０〜１５０畷吊部、
架橋助剤５〜１５重日部を配合したものである。The flame-retardant crosslinkable resin composition of this invention comprises linear low-density polyethylene (LLDP[E) and low-density polyethylene (1,
DPE) at a trmm ratio of 1=2 to 1:6, and ethylene-vinyl acetate copolymer (EVA) or styrene-ethylene-butylene copolymer is added to 100 parts by weight of this blend. Styrene block copolymer (SEB
S) 10-20 heavy hanging part, flame retardant 40-150 hanging part,
It contains 5 to 15 parts of a crosslinking aid.
この発明において使用される直鎖状低密度ポリエチレン
としては、炭素数が３〜１０の短鎖分枝を有する直鎖状
分子からなり、そのメルトインデックス（ｇ／ｌ ０分
、ＡＳ丁ＭＤ１２３８）が０゜１〜１０で、密度が０．
９１〜０．９４ｇ／ｃｄの範囲のものが使用できる。ま
た、低密度ポリエチレンとしては、長鎖分枝を右する分
子からなり、そのメルトインデックスが０．１〜１．０
で、密度が０．９１・〜０．９４９／ｃｎｌの範囲のも
のが使用される。この直鎖状低密度ポリエチレンと低密
度ポリエチレンとの混合比は重量比で１＝２〜１：６の
範囲とされる。直鎖状低密度ポリエチレンがこの範囲よ
りも少ないと得られる樹脂組成物の耐油性、耐溶剤性の
改善が達せられず、またこの範囲より多いと樹脂組成物
の成形加工性が低下して不都合である。The linear low-density polyethylene used in this invention consists of a linear molecule having 3 to 10 carbon atoms and short chain branches, and its melt index (g/l 0 min, AS Tine MD1238) is 0°1-10, density is 0.
Those in the range of 91 to 0.94 g/cd can be used. In addition, low-density polyethylene is composed of molecules with long chain branches and has a melt index of 0.1 to 1.0.
A material having a density in the range of 0.91 to 0.949/cnl is used. The mixing ratio of the linear low density polyethylene and the low density polyethylene is in the range of 1=2 to 1:6 by weight. If the amount of linear low-density polyethylene is less than this range, the oil resistance and solvent resistance of the resulting resin composition will not be improved, and if it is more than this range, the moldability of the resin composition will deteriorate, which is disadvantageous. It is.
この直鎖状低密度ポリエチレンと低密度ポリエチレンと
のブレンド物１００１８１部に対して、エチレン−酢酸
ビニル共重合体またはスチレン−エチレン−ブチレン−
スチレンブロック共重合体が１０〜２０重量部配合され
る。このエチレン−酢酸ビニル共重合体としては、酢酸
ビニル（ＶＡ）の金山が１５〜４５重量％で、メルトイ
ンデックスが１〜１００の範囲のものが好ましい。スチ
レン−エチレン−ブチレン−スチレンブロック共重合体
は、スチレン、エチレン、ブテン−１のブロック共重合
体であって、ここではスチレン金回１５〜３５％の組成
のものが好ましく、また密度が０．９０〜０．９４ｇ／
ｃｄのものが好ましい。エヂレンー酢酸ビニル共重合体
またはスチレン−エチレン−ブチレン−スチレンブロッ
ク共重合体の配合量が１０重置部未満では組成物の伸び
が低下し、２０重量部を越えると耐溶剤性、耐油性が低
下して不都合である。For 100,181 parts of this blend of linear low density polyethylene and low density polyethylene, ethylene-vinyl acetate copolymer or styrene-ethylene-butylene copolymer
10 to 20 parts by weight of a styrene block copolymer is blended. The ethylene-vinyl acetate copolymer preferably has a vinyl acetate (VA) content of 15 to 45% by weight and a melt index of 1 to 100. The styrene-ethylene-butylene-styrene block copolymer is a block copolymer of styrene, ethylene, and butene-1, preferably having a composition of 15 to 35% styrene gold, and a density of 0. 90~0.94g/
CD is preferred. If the amount of ethylene-vinyl acetate copolymer or styrene-ethylene-butylene-styrene block copolymer is less than 10 parts by weight, the elongation of the composition will decrease, and if it exceeds 20 parts by weight, solvent resistance and oil resistance will decrease. This is inconvenient.
また、難燃剤が配合される。ここで用いられる難燃剤と
しては、トリクレジルホスフェート、トリス（β−クロ
ロエチル）ホスフェート、トリス（ジクロロプロピル）
ホスフェート、トリス（ジブロモプロピル）ホスフェー
ト、塩素化パラフィン、デカブロモフェニルエーテルな
どの有機系難燃剤や水酸化アルミニウム、水酸化マグネ
シウム。Additionally, a flame retardant is blended. The flame retardants used here include tricresyl phosphate, tris (β-chloroethyl) phosphate, tris (dichloropropyl)
Organic flame retardants such as phosphate, tris(dibromopropyl) phosphate, chlorinated paraffin, decabromophenyl ether, aluminum hydroxide, and magnesium hydroxide.
ホウ酸亜鉛、三酸化アンチモン、赤リンなどが用いられ
、これらの２ａ以上の混合物も使用される。Zinc borate, antimony trioxide, red phosphorus, etc. are used, and mixtures of these 2a or more are also used.
難燃剤の配合化が４０重回部未満では、目的とする難燃
性（例えば、ＬＪＬ規格５ｕｂ７５８．ＶＷ−１など）
を得ることができず、１５０重量部を越えると樹脂組成
物の機械的強度が低下し、実用性を失う。If the flame retardant content is less than 40 parts, the desired flame retardance (for example, LJL standard 5ub758.VW-1) will not be achieved.
cannot be obtained, and if the amount exceeds 150 parts by weight, the mechanical strength of the resin composition decreases and practicality is lost.
さらに、架橋助剤が上記ブレンド物１００重量部に対し
て５〜１５＠畿部配合される。この架橋助剤としては、
トリメタクリル酸トリメチロールプロパン、ジメタクリ
ル酸１，３−ブチレン、ジメタクリル酸トリエチレング
リコール、ジアリルフタレート、トリアリルシアヌレー
トなどの多官能重合性七ツマ−が使用される。この架橋
助剤の添加量が５重量部未満では架橋が十分になされず
耐溶剤性が不十分となり、１５重股部を越えると難燃性
が低下する。Further, 5 to 15 parts of a crosslinking aid is added to 100 parts by weight of the blend. As this crosslinking aid,
Polyfunctional polymerizable heptamers such as trimethylolpropane trimethacrylate, 1,3-butylene dimethacrylate, triethylene glycol dimethacrylate, diallyl phthalate, and triallyl cyanurate are used. If the amount of the crosslinking aid added is less than 5 parts by weight, sufficient crosslinking will not be achieved and the solvent resistance will be insufficient, and if it exceeds 15 parts, the flame retardance will decrease.
このような樹脂組成物に対しては、必要に応じ酸化防止
剤、銅害防止剤１Ｍ色剤、紫外線吸収剤。For such a resin composition, an antioxidant, a copper damage inhibitor, a 1M colorant, and an ultraviolet absorber are added as necessary.
カーボンブラックなどの種々の配合剤をその目的に応じ
て添加することができる。Various compounding agents such as carbon black can be added depending on the purpose.
そして、このような樹脂組成物は、通常の混合もしくは
混線手段によって混練され、押出成形等の成形法によっ
て所望の形状に成形されたのち、リニアツク、バンデグ
ラークなどの電子線熱１Ｂ置を用いて電子線が照射され
、架橋されたのち、使用に供される。このような配合の
組成物にあっては、電子線による架橋後において、引張
強度１゜０〜１．８ｋｇ／ｍ、伸び２００〜４００％の
物性を有するものになる。Then, such a resin composition is kneaded by ordinary mixing or cross-mixing means, molded into a desired shape by a molding method such as extrusion molding, and then subjected to electronic heating using a 1B electron beam heating equipment such as a linear arc or Vandegrack. After being irradiated with radiation and crosslinked, it is ready for use. After crosslinking with an electron beam, a composition having such a composition has physical properties such as a tensile strength of 1.0 to 1.8 kg/m and an elongation of 200 to 400%.
このような組成の難燃架橋性樹脂組成物にあっては、難
燃剤を条冷に含んでいるにもかかわらず、耐油性、耐溶
剤性が優れている。これは、ペースポリマーの一部に耐
油性、耐溶剤性に優れた直鎮状低密度ポリエチレンを使
用していることによる。The flame-retardant crosslinkable resin composition having such a composition has excellent oil resistance and solvent resistance even though it contains a flame retardant in an air-cooled state. This is due to the fact that straight-cut low-density polyethylene, which has excellent oil and solvent resistance, is used as part of the pace polymer.
また、ベースポリマーの残部には加工性が良好な低密度
ポリエチレンを用いてい−るので、良好な加工性も維持
できる。したがって、この難燃架橋性樹脂組成物は高い
難燃性と加工性を保ちつつ、優れた耐溶剤性を有するも
のとなる。Moreover, since low density polyethylene with good processability is used for the remainder of the base polymer, good processability can also be maintained. Therefore, this flame-retardant crosslinkable resin composition has excellent solvent resistance while maintaining high flame retardancy and processability.
以下、実施例を示して作用効果を明確にする。 Hereinafter, examples will be shown to clarify the effects.
別表に示す配合組成を右する樹脂組成物を混線、押出成
形し、２０ＭＲａ ｄの電子線を照射して電子線架橋し
試験体とした。これら試験体について、押出加工性、難
燃性、引張強度、伸び、耐熱性、耐溶剤性を測定した。A resin composition having a compounding composition shown in the attached table was crosslinked and extruded, and then irradiated with an electron beam of 20 MRad to be crosslinked with an electron beam to obtain a test specimen. For these test specimens, extrusion processability, flame retardancy, tensile strength, elongation, heat resistance, and solvent resistance were measured.
難燃性は、ＵＬ規格５ｕｂ７５８．ＶＷ−１によって試
験を行い評価した。また、耐熱性は試験体を１５８℃で
７日１ｊｊ放置し、放置後の引張強度および伸びを求め
、未加熱の試験体の引張強度および伸びと比較し、それ
ぞれの残率で評価した。Flame retardancy is UL standard 5ub758. Tests and evaluations were made using VW-1. In addition, heat resistance was evaluated by leaving the test piece at 158° C. for 7 days, determining the tensile strength and elongation after being left, and comparing the results with the tensile strength and elongation of the unheated test piece, and evaluating the retention rate of each.
また、耐溶剤性については、試験体を試験油としてＡＳ
ＴＭ＃２オイルに１００℃で９６時間浸）δし、浸漬後
の引張強度および伸びを求め、未浸漬の試験体の引張強
度および伸びと比較し、それぞれの残率で表わした。押
出加工性は、良好な押出が可能なものをＯとし、そうで
ないものを×とした。In addition, regarding solvent resistance, AS
The specimen was immersed in TM#2 oil at 100° C. for 96 hours), the tensile strength and elongation after immersion were determined, compared with the tensile strength and elongation of the unimmersed specimen, and expressed as the respective residual percentages. For extrusion processability, those that could be extruded well were rated O, and those that could not be extruded were rated x.
結果を別表に示す。The results are shown in the attached table.
別表の結果から明らかなように、ペースポリマー中の直
鎖状低密度ポリエチレンが過多になると押出加工性が劣
り、低密度ポリエチレンが過多となると耐油性が低いこ
とがわかる。また、エヂレンー酢酸ビニル共重合体また
はスチレン−エチレン−ブチレン−スチレンブロック共
重合体が欠ｔＪると樹脂組成物の伸びが不足することが
わかる。As is clear from the results in the attached table, when the pace polymer contains too much linear low-density polyethylene, the extrusion processability is poor, and when the low-density polyethylene is too large, the oil resistance is poor. It is also seen that when the ethylene-vinyl acetate copolymer or the styrene-ethylene-butylene-styrene block copolymer is missing (tJ), the elongation of the resin composition is insufficient.
以上説明したように、この発明の難燃架橋性樹脂組成物
は、そのベースポリマーに直鎖状低密度ポリエチレンと
低密度ポリエチレンとのブレンド物を使用しているので
、多量の難燃剤を配合して高い難燃性を付与しても耐溶
剤性、耐油性が良好であり、しかも良好な成形加工性を
も有するものとなる。As explained above, the flame-retardant crosslinkable resin composition of the present invention uses a blend of linear low-density polyethylene and low-density polyethylene as its base polymer, and therefore contains a large amount of flame retardant. Even if high flame retardance is imparted, it has good solvent resistance and oil resistance, and also has good moldability.
よって、この難燃架橋性樹脂組成物は、高難燃性、高耐
熱性を要求される絶縁電線、絶縁チューブ等に好適なも
のとなる。Therefore, this flame-retardant crosslinkable resin composition is suitable for insulated wires, insulated tubes, etc. that require high flame retardancy and high heat resistance.
Claims (1)
：２〜１：６の重量比でブレンドされた樹脂分１００重
量部に、 エチレン−酢酸ビニル共重合体またはスチレン−エチレ
ン−ブチレン−スチレンブロック共重合体１０〜２０重
量部、 難燃剤４０〜１５０重量部、 架橋助剤５〜１５重量部を配合してなる難燃架橋性樹脂
組成物。[Claims] Linear low density polyethylene and low density polyethylene are 1
: 100 parts by weight of resin blended in a weight ratio of 2 to 1:6, 10 to 20 parts by weight of ethylene-vinyl acetate copolymer or styrene-ethylene-butylene-styrene block copolymer, and 40 to 150 parts by weight of flame retardant. A flame-retardant crosslinkable resin composition containing 5 to 15 parts by weight of a crosslinking aid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP291287A JPS63172753A (en) | 1987-01-09 | 1987-01-09 | Flame-retardant crosslinkable resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP291287A JPS63172753A (en) | 1987-01-09 | 1987-01-09 | Flame-retardant crosslinkable resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63172753A true JPS63172753A (en) | 1988-07-16 |
Family
ID=11542564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP291287A Pending JPS63172753A (en) | 1987-01-09 | 1987-01-09 | Flame-retardant crosslinkable resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63172753A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0269543A (en) * | 1988-09-02 | 1990-03-08 | Fujikura Ltd | Insulating composition and power cable |
| JPH02151642A (en) * | 1988-12-05 | 1990-06-11 | Sumitomo Electric Ind Ltd | Flame-retardant resin composition |
| JPH02187439A (en) * | 1989-01-17 | 1990-07-23 | Sumitomo Electric Ind Ltd | Flame-retardant resin composition |
| EP0490394A1 (en) * | 1990-12-13 | 1992-06-17 | Union Carbide Chemicals And Plastics Company, Inc. | Crush resistant cable insulation |
| KR100575467B1 (en) * | 1999-12-30 | 2006-05-03 | 삼성토탈 주식회사 | Self-adhesive resin composition for protection film |
| WO2014106928A1 (en) * | 2013-01-07 | 2014-07-10 | 矢崎総業株式会社 | Thermally resistant crosslinked wire |
| US8956706B2 (en) | 2009-12-29 | 2015-02-17 | Saint-Gobain Performance Plastics Corporation | Flexible tubing material and method of forming the material |
| US9987784B2 (en) | 2012-06-06 | 2018-06-05 | Saint-Gobain Performance Plastics Corporation | Thermoplastic elastomer tubing and method to make and use same |
-
1987
- 1987-01-09 JP JP291287A patent/JPS63172753A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0269543A (en) * | 1988-09-02 | 1990-03-08 | Fujikura Ltd | Insulating composition and power cable |
| JPH02151642A (en) * | 1988-12-05 | 1990-06-11 | Sumitomo Electric Ind Ltd | Flame-retardant resin composition |
| JPH02187439A (en) * | 1989-01-17 | 1990-07-23 | Sumitomo Electric Ind Ltd | Flame-retardant resin composition |
| EP0490394A1 (en) * | 1990-12-13 | 1992-06-17 | Union Carbide Chemicals And Plastics Company, Inc. | Crush resistant cable insulation |
| US5180889A (en) * | 1990-12-13 | 1993-01-19 | Union Carbide Chemicals & Plastics Technology Corporation | Crush resistant cable insulation |
| KR100575467B1 (en) * | 1999-12-30 | 2006-05-03 | 삼성토탈 주식회사 | Self-adhesive resin composition for protection film |
| US8956706B2 (en) | 2009-12-29 | 2015-02-17 | Saint-Gobain Performance Plastics Corporation | Flexible tubing material and method of forming the material |
| US9133332B2 (en) | 2009-12-29 | 2015-09-15 | Saint-Gobain Performance Plastics Corporation | Flexible tubing material and method of forming the material |
| US9670351B2 (en) | 2009-12-29 | 2017-06-06 | Saint-Gobain Performance Plastics Corporation | Flexible tubing material and method of forming the material |
| US9987784B2 (en) | 2012-06-06 | 2018-06-05 | Saint-Gobain Performance Plastics Corporation | Thermoplastic elastomer tubing and method to make and use same |
| WO2014106928A1 (en) * | 2013-01-07 | 2014-07-10 | 矢崎総業株式会社 | Thermally resistant crosslinked wire |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2005123828A1 (en) | Resin composition resistant to thermal deformation and cut-through and the insulation material and the cable using thereit | |
| JPS63172753A (en) | Flame-retardant crosslinkable resin composition | |
| US5539052A (en) | Crosslinked thermoplastic elastomers | |
| US4001174A (en) | Incombustible polyolefin molding compositions and method of crosslinking same | |
| KR20100078821A (en) | Phosphorus-based polyolefin flame retardant composition containing nanoclay | |
| JPS62184042A (en) | Flame-retardant resin composition | |
| KR100874538B1 (en) | Composition and method for production flame retardant insulating material, insulating cable and materials | |
| JPH03199256A (en) | Flame retardant resin composition | |
| JP2858153B2 (en) | Phenylene oxide polymer composition | |
| JPH04154852A (en) | Flame retardant electrical insulating composition | |
| JP2585702B2 (en) | Flame-retardant resin composition, flame-retardant electric wire and flame-retardant heat-shrinkable tube using the same | |
| JPH03227337A (en) | Flame retardant composition and flame retardant cable | |
| BR112019008312B1 (en) | ADDITIVE CONCENTRATE COMPOSITION, MOISTURE CURABLE POLYOLEFIN COMPOSITION, METHOD OF PREPARING A MOISTURE CURABLE POLYOLEFIN COMPOSITION, MANUFACTURED ARTICLE, COATED CONDUCTOR AND METHOD OF CONDUCTING ELECTRICITY | |
| JPH0959392A (en) | Polyolefin-based resin composition and insulated wire and thermally contracting tube using the same | |
| JPH04122747A (en) | Flame-retardant resin composition and tube | |
| JP3178265B2 (en) | Radiation-resistant insulation composition for electric wires and cables | |
| JPS61225236A (en) | Resin composition | |
| JPS61228049A (en) | Resin composition | |
| JPH0615640B2 (en) | Flame-retardant polyethylene resin composition | |
| JPS61225235A (en) | Resin composition | |
| JPS61228048A (en) | Resin composition | |
| JPH0565374A (en) | Heat-resistant composition | |
| JPS61228051A (en) | Resin composition | |
| JPH04175352A (en) | Flame-retardant resin composition and tube | |
| JPS62131043A (en) | Polyolefin composition |