JPS6158304B2 - - Google Patents
Info
- Publication number
- JPS6158304B2 JPS6158304B2 JP17569983A JP17569983A JPS6158304B2 JP S6158304 B2 JPS6158304 B2 JP S6158304B2 JP 17569983 A JP17569983 A JP 17569983A JP 17569983 A JP17569983 A JP 17569983A JP S6158304 B2 JPS6158304 B2 JP S6158304B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- cement
- concrete
- epoxy resin
- rnh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004568 cement Substances 0.000 claims description 22
- 239000004567 concrete Substances 0.000 claims description 22
- 239000003822 epoxy resin Substances 0.000 claims description 19
- 229920000647 polyepoxide Polymers 0.000 claims description 19
- 239000004570 mortar (masonry) Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- -1 amine compound Chemical class 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 150000004985 diamines Chemical class 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000011083 cement mortar Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 230000002087 whitening effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 3
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- XBTRYWRVOBZSGM-UHFFFAOYSA-N (4-methylphenyl)methanediamine Chemical compound CC1=CC=C(C(N)N)C=C1 XBTRYWRVOBZSGM-UHFFFAOYSA-N 0.000 description 1
- GOLAKLHPPDDLST-HZJYTTRNSA-N (9z,12z)-octadeca-9,12-dien-1-amine Chemical compound CCCCC\C=C/C\C=C/CCCCCCCCN GOLAKLHPPDDLST-HZJYTTRNSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- BZUILZIKDIMXBK-UHFFFAOYSA-N 2-(oxiran-2-ylmethoxycarbonyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1C(=O)OCC1OC1 BZUILZIKDIMXBK-UHFFFAOYSA-N 0.000 description 1
- CJAYHOLRQJHSIP-NXVVXOECSA-N 2-[(z)-heptadec-2-enyl]-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCCCC\C=C/CC1=NCCN1 CJAYHOLRQJHSIP-NXVVXOECSA-N 0.000 description 1
- VNGLVZLEUDIDQH-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;2-methyloxirane Chemical compound CC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 VNGLVZLEUDIDQH-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ACYBVNYNIZTUIL-UHFFFAOYSA-N n'-benzylethane-1,2-diamine Chemical compound NCCNCC1=CC=CC=C1 ACYBVNYNIZTUIL-UHFFFAOYSA-N 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- CETWGWHVAKIHPW-UHFFFAOYSA-N pentadecane-2,3-diamine Chemical compound CCCCCCCCCCCCC(N)C(C)N CETWGWHVAKIHPW-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
Description
本発明はコンクリートブロツクの製法に関し詳
しくは疎水性のエポキシ樹脂及び硬化剤から成る
エポキシ樹脂モルタルを水セメント比が10〜40％
のまだ固まらないセメントコンクリートの上又は
下に積層し、同時に加圧成型することを特徴とす
るコンクリートブロツクの製法に関するものであ
る。
各種コンクリート製歩道板は遊歩道、公園の広
場、建物前の広場などに使用されており、施工が
比較的容易であることや軟弱路盤の上に舗装して
も修理が容易であること等の利点を有するため
に、急速に普及している。また、花壇用コンクリ
ートブロツク及び建築用外壁用ブロツク等もプレ
キヤスト化による美観上の理由等から同様に普及
しつつある。しかし、これらの表面はカラー化さ
れている場合が多いが、カラーセメントを使用し
ているので、白色化してカラーの商品価値を低下
させるという問題を残している。カラーセメント
を使用する限りセメント中の消石灰成分が大気中
の炭酸ガスと反応して炭酸カルシウムを生成し、
これが白色化現象となるので白色化を防止するこ
とは基本的にむずかしい問題である。
本発明は、この白色化の欠点を改良すると同時
に、ワンシヨツトで着色したエポキシ樹脂モルタ
ルを表面に持つコンクリートブロツクの製法を提
供するものである。
まだ固まらないセメントコンクリートには水が
あるので、有機化合物であるエポキシ樹脂モルタ
ルは接着し難い。しかしながら、本発明者等の研
究によれば、疎水性エポキシ樹脂を使用しまだ固
まらないセメントコンクリート中の水分量が適切
であるように調節することによつて接着が可能と
なつた。エポキシ樹脂及び硬化剤の両者が共に水
溶性の場合は、まだ固まらないセメントコンクリ
ート中の水分量をどのようにコントロールして
も、接着力は極めて小さい。
本発明で使用する疎水性エポキシ樹脂としては
ビスフエノールＡジグリシジルエーテル、ビスフ
エノールＡ酸化プロピレン附加物ジグリシジルエ
ーテル、ポリオキシプロピレンジグリシジルエー
テル、ダイマー酸グリシジルエステル、フタール
酸グリシジルエステル、フエノールノボラツクグ
リシジルエーテルなどがあるが、ビスフエノール
Ａジグリシジルエーテルが特に好ましい。
本発明で使用するエポキシ樹脂硬化剤としては
オクチルアミン、ラウリルアミン、オレイルアミ
ン、リノレイルアミン、オクチルプロピレンジア
ミン、ラウリルプロピレンジアミン、オレイルプ
ロピレンジアミン、リノレイルプロピレンジアミ
ン、オクロジプロピレンジアミン、ラウロジプロ
ピレンジアミン、オレオジプロピレンジアミン、
ヘプタデセニルイミダゾリンポリアミン、ダイマ
ー酸ポリアミドアミン、キシレンジアミン、ポリ
メルカプタン、ポリスルフイド樹脂、エチレンジ
アミン、ジエチレントリアミン、ポリオキシプロ
ピレンジアミン、ポリエチレンイミン、ベンジル
エチレンジアミン等が使用できるが、特に次の一
般式(1)〜(5)で示される化合物が好ましい。
RNH2 (1)
RNH（CH2）oNH2 (2)
RNH（CH2）oNH（CH2）oNH2 (3)
（式(1)〜(4)中Ｒは炭素数８〜22のアルキル基又
は炭素数８〜22のアルケニル基、ｎは２〜３の整
数、ｍは１〜５の整数）
R′OAp（CH2）3NH（CH2）3NH2 (5)
（式(5)中R′は炭素数８〜22のアルキル基、炭
素数８〜22のアルケニル基又は炭素数８〜22のア
ルキル基を有するアルキルフエノール基、Ａはオ
キシプロピレン基、ｐは０〜20の整数）
特に好ましいものは、オレインプロピレンジア
ミン、リノレイルプロピレンジアミンなどの脂肪
ポリアミンである。
まだ固まらないセメントコンクリート中の水の
量はエポキシ樹脂モルタルとセメントコンクリー
トとの接着力に影響を与える。水セメント比が10
〜40％の範囲であることが必要である。水セメン
ト比が40％を越えると、セメントコンクリートの
液状性が高くなり、圧縮成型による強度の向上は
期待できないし、加圧成型コンクリートブロツク
でも即脱型ゆえに脱型後の型崩れの恐れがある。
水セメント比が10％より少ないと、セメントが硬
化するのに必要な水量が少なすぎて、硬化が不十
分となる。
エポキシ樹脂モルタルはコンクリートの表面に
0.3〜１cm程度の厚さに置くので、骨材の粒径は
５mm以下のものを使用することが好ましい。樹脂
量は強度を維持するのに必要な量以上であれば良
く、モルタル中に２％以上あれば良い。プライム
コートは使用しても良いし、使用しなくてもコン
クリートと樹脂モルタルの間で剥離することはな
い。
実施例 １
セメントモルタルの調製
セメント120Kg／m3、川砂230Kg／m3、水36Kg／
m3（水・セメント比30％）の配合組成のものを使
用した。
エポキシ樹脂モルタルの調製
各種のエポキシ樹脂10重量部、５号ケイ砂66重
量部、７号ケイ砂18重量部、フイラー６重量部を
よく混合して調製した。但しエポキシ樹脂は主剤
のエポキシ当量部と硬化剤の活性水素当量部を混
合したものである。
供試体の調製
深さ10cm、径12cmの鉄製のシリンダーに６cmの
厚さにセメントモルタルを入れ、ならした後に１
cmの厚さに樹脂モルタルを入れアムスラーを用い
て50Kg／cm2の圧力で30秒圧縮成型した。14日間室
温で養生し接着力測定用の供試体とした。
接着試験
セメントモルタル層と樹脂モルタル層との間の
接着力が測定できるようにアタツチメントを接着
した後、接着力をASTMD897に従つて測定し
た。結果は次の通り。
The present invention relates to a method for manufacturing concrete blocks, and more specifically, the epoxy resin mortar consisting of a hydrophobic epoxy resin and a hardening agent has a water-to-cement ratio of 10 to 40%.
The present invention relates to a method for manufacturing concrete blocks, which is characterized in that the concrete blocks are laminated on or under unhardened cement concrete and simultaneously pressure-molded. Various types of concrete sidewalk boards are used for promenades, park plazas, plazas in front of buildings, etc., and have the advantages of being relatively easy to construct and easy to repair even when paved on a soft roadbed. It is rapidly becoming popular due to its Concrete blocks for flower beds and blocks for external walls of buildings are also becoming popular due to aesthetic reasons due to precasting. However, although these surfaces are often colored, since colored cement is used, there remains the problem that they become white and reduce the commercial value of colored products. As long as colored cement is used, the slaked lime component in the cement will react with carbon dioxide gas in the atmosphere to produce calcium carbonate.
This results in a whitening phenomenon, so preventing whitening is fundamentally a difficult problem. The present invention aims to improve this drawback of whitening and at the same time provide a method for manufacturing concrete blocks having a one-shot colored epoxy resin mortar on the surface. Since cement concrete still contains water, it is difficult to bond with epoxy resin mortar, which is an organic compound. However, according to research conducted by the present inventors, adhesion has become possible by using a hydrophobic epoxy resin and adjusting the moisture content in cement concrete that has not yet hardened to an appropriate level. If both the epoxy resin and the curing agent are water-soluble, the adhesive force will be extremely low no matter how you control the amount of water in the unhardened cement concrete. Hydrophobic epoxy resins used in the present invention include bisphenol A diglycidyl ether, bisphenol A propylene oxide diglycidyl ether, polyoxypropylene diglycidyl ether, dimer acid glycidyl ester, phthalate glycidyl ester, and phenol novolac glycidyl ether. Among them, bisphenol A diglycidyl ether is particularly preferred. Epoxy resin curing agents used in the present invention include octylamine, laurylamine, oleylamine, linoleylamine, octylpropylene diamine, laurylpropylene diamine, oleylpropylene diamine, linoleylpropylene diamine, oclodipropylene diamine, laurodipropylene diamine, oleodipropylene diamine,
Heptadecenylimidazoline polyamine, dimer acid polyamide amine, xylene diamine, polymercaptan, polysulfide resin, ethylene diamine, diethylene triamine, polyoxypropylene diamine, polyethylene imine, benzyl ethylene diamine, etc. can be used, but in particular, the following general formula (1) ~ Compounds represented by (5) are preferred. RNH 2 (1) RNH (CH 2 ) o NH 2 (2) RNH (CH 2 ) o NH (CH 2 ) o NH 2 (3) (In formulas (1) to (4), R is an alkyl group having 8 to 22 carbon atoms or an alkenyl group having 8 to 22 carbon atoms, n is an integer of 2 to 3, and m is an integer of 1 to 5) R'OAp ( CH 2 ) 3 NH (CH 2 ) 3 NH 2 (5) (In formula (5), R' is an alkyl group having 8 to 22 carbon atoms, an alkenyl group having 8 to 22 carbon atoms, or an alkyl group having 8 to 22 carbon atoms. (A is an oxypropylene group, p is an integer of 0 to 20) Particularly preferred are fatty polyamines such as oleic propylene diamine and linoleyl propylene diamine. The amount of water in the cement concrete that has not yet set affects the adhesive strength between the epoxy resin mortar and the cement concrete. Water cement ratio is 10
It is necessary to be in the range of ~40%. If the water-cement ratio exceeds 40%, the liquid nature of the cement concrete becomes high, and no improvement in strength can be expected through compression molding, and even pressure-formed concrete blocks may lose their shape after demolding because they are easily demolded. .
If the water-cement ratio is less than 10%, the amount of water required to harden the cement is too small, resulting in insufficient hardening. Epoxy resin mortar on concrete surface
Since the thickness is about 0.3 to 1 cm, it is preferable to use aggregate with a particle size of 5 mm or less. The amount of resin may be at least the amount necessary to maintain strength, and may be at least 2% in the mortar. Prime coat may be used, or even if it is not used, it will not separate between the concrete and the resin mortar. Example 1 Preparation of cement mortar Cement 120Kg/m 3 , River sand 230Kg/m 3 , Water 36Kg/m 3
m 3 (30% water/cement ratio) was used. Preparation of epoxy resin mortar 10 parts by weight of various epoxy resins, 66 parts by weight of No. 5 silica sand, 18 parts by weight of No. 7 silica sand, and 6 parts by weight of filler were thoroughly mixed to prepare. However, the epoxy resin is a mixture of the epoxy equivalent part of the base resin and the active hydrogen equivalent part of the curing agent. Preparation of specimen Cement mortar was poured into a 6 cm thick iron cylinder with a depth of 10 cm and a diameter of 12 cm.
A resin mortar with a thickness of cm was placed and compression molded for 30 seconds using an Amsler at a pressure of 50 kg/cm 2 . It was cured at room temperature for 14 days and used as a specimen for measuring adhesive strength. Adhesion Test After the attachment was bonded so that the adhesive force between the cement mortar layer and the resin mortar layer could be measured, the adhesive force was measured according to ASTM D897. The results are as follows.
【表】【table】
【表】
この結果より明らかな如く、親水性のエポキシ
樹脂では使用不可能であるが、疎水性のエポキシ
樹脂であれば使用可能である。硬化剤も疎水性で
あることが好ましい。
実施例 ２
セメント150Kg／m3、川砂290Kg／m3、水60Kg／
m3（水・セメント比40％）の配合組成のセメント
モルタルを使用し、主剤がビスフエノールＡジグ
リシジエーテル、硬化剤がオレイルプロピレンジ
アミンであるエポキシ樹脂を使用して実施例１と
同様に行なつたところ、界面の破壊は見られなか
つた。
本製法により製造された着色コンクリートブロ
ツクにはその上層のエポキシ樹脂層により、下部
セメントコンクリートもしくはセメントモルタル
が、大気中の炭酸ガス及び水分と接触する事を防
止できるため、前述の白色化が起り難い。また、
それと同時に樹脂のもつ性能上、耐薬品性、耐久
性、耐摩耗性、すべり抵抗性等も一段と向上す
る。[Table] As is clear from the results, hydrophilic epoxy resins cannot be used, but hydrophobic epoxy resins can be used. Preferably, the curing agent is also hydrophobic. Example 2 Cement 150Kg/m 3 , River sand 290Kg/m 3 , Water 60Kg/m 3
The procedure was carried out in the same manner as in Example 1 using a cement mortar with a composition of m 3 (water/cement ratio 40%), using an epoxy resin with bisphenol A diglycidether as the main agent and oleyl propylene diamine as the hardening agent. After aging, no destruction of the interface was observed. The colored concrete block manufactured by this method has an upper epoxy resin layer that prevents the lower cement concrete or cement mortar from coming into contact with carbon dioxide gas and moisture in the atmosphere, making it difficult for the aforementioned whitening to occur. . Also,
At the same time, the properties of the resin such as chemical resistance, durability, abrasion resistance, and slip resistance are further improved.
Claims (1)
ポキシ樹脂モルタルを水セメント比が10〜40％の
まだ固まらないセメントコンクリートに積層し、
同時に加圧成型することを特徴とするコンクリー
トブロツクの製法。 ２ 硬化剤が活性水素を２個以上有する疎水性の
アミン化合物である特許請求の範囲第１項記載の
コンクリートブロツクの製法。 ３ アミン化合物が次の一般式(1)〜(5)で示される
化合物から選ばれる１種又は２種以上である特許
請求の範囲第２項記載のコンクリートブロツクの
製法。 RNH2 (1) RNH（CH2）oNH2 (2) RNH（CH2）oNH（CH2）oNH2 (3) （式(1)〜(4)中Ｒは炭素数８〜22のアルキル基又
は炭素数８〜22のアルケニル基、ｎは２〜３の整
数、ｍは１〜５の整数） R′OAp（CH2）3NH（CH2）3NH2 (5) （式(5)中R′は炭素数８〜22のアルキル基、炭
素数８〜22のアルケニル基又は炭素数８〜22のア
ルキル基を有するアルキルフエノール基、Ａはオ
キシプロピレン基、ｐは０〜20の整数）[Claims] 1. An epoxy resin mortar made of a hydrophobic epoxy resin and a hardening agent is laminated on unhardened cement concrete with a water-cement ratio of 10 to 40%,
A method for manufacturing concrete blocks characterized by simultaneous pressure molding. 2. The method for producing a concrete block according to claim 1, wherein the curing agent is a hydrophobic amine compound having two or more active hydrogen atoms. 3. The method for producing a concrete block according to claim 2, wherein the amine compound is one or more selected from compounds represented by the following general formulas (1) to (5). RNH 2 (1) RNH (CH 2 ) o NH 2 (2) RNH (CH 2 ) o NH (CH 2 ) o NH 2 (3) (In formulas (1) to (4), R is an alkyl group having 8 to 22 carbon atoms or an alkenyl group having 8 to 22 carbon atoms, n is an integer of 2 to 3, and m is an integer of 1 to 5) R'OAp ( CH 2 ) 3 NH (CH 2 ) 3 NH 2 (5) (In formula (5), R' is an alkyl group having 8 to 22 carbon atoms, an alkenyl group having 8 to 22 carbon atoms, or an alkyl group having 8 to 22 carbon atoms. (A is an oxypropylene group, p is an integer from 0 to 20)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17569983A JPS6067144A (en) | 1983-09-22 | 1983-09-22 | Manufacture of concrete block |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17569983A JPS6067144A (en) | 1983-09-22 | 1983-09-22 | Manufacture of concrete block |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6067144A JPS6067144A (en) | 1985-04-17 |
| JPS6158304B2 true JPS6158304B2 (en) | 1986-12-11 |
Family
ID=16000697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17569983A Granted JPS6067144A (en) | 1983-09-22 | 1983-09-22 | Manufacture of concrete block |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6067144A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH031460Y2 (en) * | 1986-07-21 | 1991-01-17 | ||
| JPH0425845Y2 (en) * | 1986-10-17 | 1992-06-22 | ||
| JPH059161Y2 (en) * | 1988-09-21 | 1993-03-08 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6339331A (en) * | 1986-04-03 | 1988-02-19 | 中川ヒユ−ム管工業株式会社 | Concrete molded form and manufacture thereof |
| JPS63315583A (en) * | 1987-06-16 | 1988-12-23 | Yokohama Rubber Co Ltd:The | Method for repairing crack of concrete construction |
| DE69218571T2 (en) * | 1991-07-22 | 1997-08-14 | Toray Industries | Concrete structure and process for its manufacture |
| CA2312657A1 (en) | 1999-06-30 | 2000-12-30 | Shinichi Kaneko | Building boards, manufacturing apparatus and prefoamed plastics |
-
1983
- 1983-09-22 JP JP17569983A patent/JPS6067144A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH031460Y2 (en) * | 1986-07-21 | 1991-01-17 | ||
| JPH0425845Y2 (en) * | 1986-10-17 | 1992-06-22 | ||
| JPH059161Y2 (en) * | 1988-09-21 | 1993-03-08 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6067144A (en) | 1985-04-17 |
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