JPS6042364A - Preparation of vitamin d2 in seaweeds - Google Patents
Preparation of vitamin d2 in seaweedsInfo
- Publication number
- JPS6042364A JPS6042364A JP58152167A JP15216783A JPS6042364A JP S6042364 A JPS6042364 A JP S6042364A JP 58152167 A JP58152167 A JP 58152167A JP 15216783 A JP15216783 A JP 15216783A JP S6042364 A JPS6042364 A JP S6042364A
- Authority
- JP
- Japan
- Prior art keywords
- vitamin
- seaweeds
- irradiation
- algae
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MECHNRXZTMCUDQ-RKHKHRCZSA-N vitamin D2 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)/C=C/[C@H](C)C(C)C)=C\C=C1\C[C@@H](O)CCC1=C MECHNRXZTMCUDQ-RKHKHRCZSA-N 0.000 title claims abstract description 16
- 241001474374 Blennius Species 0.000 title abstract description 6
- MECHNRXZTMCUDQ-UHFFFAOYSA-N Vitamin D2 Natural products C1CCC2(C)C(C(C)C=CC(C)C(C)C)CCC2C1=CC=C1CC(O)CCC1=C MECHNRXZTMCUDQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229960002061 ergocalciferol Drugs 0.000 claims abstract description 15
- 235000001892 vitamin D2 Nutrition 0.000 claims abstract description 15
- 239000011653 vitamin D2 Substances 0.000 claims abstract description 15
- 230000001678 irradiating effect Effects 0.000 claims abstract description 3
- 241000195493 Cryptophyta Species 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 4
- OILXMJHPFNGGTO-UHFFFAOYSA-N (22E)-(24xi)-24-methylcholesta-5,22-dien-3beta-ol Natural products C1C=C2CC(O)CCC2(C)C2C1C1CCC(C(C)C=CC(C)C(C)C)C1(C)CC2 OILXMJHPFNGGTO-UHFFFAOYSA-N 0.000 abstract description 5
- RQOCXCFLRBRBCS-UHFFFAOYSA-N (22E)-cholesta-5,7,22-trien-3beta-ol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CCC(C)C)CCC33)C)C3=CC=C21 RQOCXCFLRBRBCS-UHFFFAOYSA-N 0.000 abstract description 5
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 abstract description 5
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 abstract description 5
- DNVPQKQSNYMLRS-NXVQYWJNSA-N Ergosterol Natural products CC(C)[C@@H](C)C=C[C@H](C)[C@H]1CC[C@H]2C3=CC=C4C[C@@H](O)CC[C@]4(C)[C@@H]3CC[C@]12C DNVPQKQSNYMLRS-NXVQYWJNSA-N 0.000 abstract description 5
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 abstract description 5
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 abstract description 5
- DNVPQKQSNYMLRS-SOWFXMKYSA-N ergosterol Chemical compound C1[C@@H](O)CC[C@]2(C)[C@H](CC[C@]3([C@H]([C@H](C)/C=C/[C@@H](C)C(C)C)CC[C@H]33)C)C3=CC=C21 DNVPQKQSNYMLRS-SOWFXMKYSA-N 0.000 abstract description 5
- 235000019155 vitamin A Nutrition 0.000 abstract description 5
- 239000011719 vitamin A Substances 0.000 abstract description 5
- 229940045997 vitamin a Drugs 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 241000206607 Porphyra umbilicalis Species 0.000 abstract 1
- 241000264279 Sargassum fusiforme Species 0.000 abstract 1
- 241000196251 Ulva arasakii Species 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 239000002932 luster Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 240000000599 Lentinula edodes Species 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- 241001261506 Undaria pinnatifida Species 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Electromagnetism (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cultivation Of Seaweed (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Edible Seaweed (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は藻類中にビタミンD2を生成させる方法に関し
、特に280〜320nmの範囲の紫外線を、あおさ、
あおのり、あまのり、あらめ、いわのり、おごのり、か
わのり、こんぶ、ひじき、わかめ、もずく等の藻類に照
射し、藻類中に存在するエルゴステロールをビタミンD
2に効率良く、かつ、経済的に生成させる点にある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing vitamin D2 in algae, and in particular, the present invention relates to a method for producing vitamin D2 in algae.
Algae such as Aonori, Amanori, Arame, Iwanori, Ogonori, Kawanori, Konbu, Hijiki, Wakame, and Mozuku are irradiated to convert the ergosterol present in the algae into vitamin D.
2, it can be produced efficiently and economically.
エルゴステロールに紫外線を照射し、ビタミンD2を生
成するさいの化学変化は次の通りであところで、しいた
けにはエルゴステロールが存在し、紫外線によって、ビ
タミンD2が生成されることは特公昭51−26493
号等で公知であるが、本発明者等は、藻類中にエルゴス
テ占−ルが存在していることを確′認し、これに特定の
紫外線(波長280〜.320nm)を照射することに
より、薬品等の添加、反応なくして、効率良く゛、かつ
、i[中に存在するビタミンAを損失することなく、健
康上重要なビタミンD2を多量に生成することに成功し
た。The chemical changes that occur when ergosterol is irradiated with ultraviolet rays to produce vitamin D2 are as follows.By the way, ergosterol exists in shiitake mushrooms, and it was reported in Japanese Patent Publication No. 51-26493 that vitamin D2 is produced by ultraviolet rays.
The present inventors confirmed the existence of ergosteol in algae and irradiated it with specific ultraviolet light (wavelength 280 to 320 nm). We succeeded in efficiently producing a large amount of vitamin D2, which is important for health, without the addition of chemicals or reactions, and without losing the vitamin A present in i[.
屋外の太陽光の下で加工すれば、280〜320nmの
紫外線により、ビタミンD2は生成されるが、その量が
少なく、しがも長時間かがることも確認した。It was also confirmed that when processed outdoors under sunlight, vitamin D2 is produced by ultraviolet rays of 280 to 320 nm, but the amount is small and it takes a long time.
近年経済的に清潔で、均質な食用ののりを得るために、
加工作業は屋内で行われるようになり、原料である藻類
中のビタミンD2の含有量は更に少なくなっている。現
実に4訂日本食品標準成分表によると、藻類中のビタミ
ンD2の含有量は零になっている。In recent years, in order to obtain economically clean and homogeneous edible seaweed,
Processing operations are now carried out indoors, and the content of vitamin D2 in the raw material algae has become even lower. In fact, according to the 4th edition of the Japanese Standard Food Composition Table, the content of vitamin D2 in algae is zero.
280〜320nmの紫外線では照射による発熱はなく
、また、紅斑効果のあるlJ、長より長波長であるから
、一般にMRの表面には外観上変化がなく、適当な水分
の藻類に照射し乾燥すれば表面に光沢を生し□る。また
、照射は藻類を薄葉にし、水分は80%以下が好もしい
。水分が多いと紫外線が藻類表面の水に吸収されるから
である。Ultraviolet rays of 280 to 320 nm do not generate heat upon irradiation, and since the wavelength is longer than lJ, which has an erythema effect, there is generally no change in the appearance of the MR surface, and algae with an appropriate amount of moisture can be irradiated and dried. It creates a glossy surface. Further, it is preferable that the irradiation makes the algae into thin leaves and the moisture content is 80% or less. This is because when there is a lot of moisture, ultraviolet rays are absorbed by the water on the surface of the algae.
次に3つの実施例を挙げてその効果を示せば(1) 乾
燥機内を移動中の水分70%のあまのり15gを20c
m X 20cmの薄葉とし東芝製品の健康線ランプ(
20W)を並べて30cmの距離から10分間照射ずれ
ばあまのりのビタミンD2は320IU (100g乾
燥重量)から2,430 IIに増加した。尚水分1.
2%まで乾燥したあまのりは照射せずに乾燥したものよ
り光沢があり、乾燥の前後でビタミンAは13.000
11 (100g乾燥重量)で変化はなかった。Next, I will give three examples to show the effect.
m x 20cm thin leaves and Toshiba product health line lamp (
By irradiating them with 20W) from a distance of 30cm for 10 minutes, the vitamin D2 of Amanori increased from 320IU (100g dry weight) to 2,430 II. Moisture 1.
Amanori dried to 2% is more glossy than that dried without irradiation, and has 13.000% vitamin A before and after drying.
11 (100g dry weight), there was no change.
(2)次に前項と同し条件で照射時間を片面に対して1
5分間、両面に照射すると3,620 II(100g
乾燥重量)のビタミンD2を含有したあまのりを得て、
この場合もビタミンAは13.0OOIU (100g
乾燥重量)で変化はなかった。(2) Next, under the same conditions as in the previous section, the irradiation time is 1 for one side.
When irradiated on both sides for 5 minutes, 3,620 II (100g
Obtain Amanori containing vitamin D2 (dry weight),
In this case too, vitamin A is 13.0OOIU (100g
There was no change in dry weight).
(3) 又水分50%のいわのり10gを18cm X
18cmの薄葉にして表面から35C111の距離を
隔てて前記の健康線ランプ(20W)2灯を設置し、2
0分間照射した結果ビタミンD2が2,2201Uのい
わのり(100g乾燥重量)を得た。1月の山陰海岸の
貼天日に6時間暖外に置G″IたものばビタミンD2が
5701U(100g乾燥重量)であって、ビタミンA
は共に12,0OOIU (100g乾燥重量)であっ
た。(3) Also, 10g of Iwa nori with 50% moisture in 18cm x
Two health line lamps (20W) were installed at a distance of 35C111 from the surface of a thin 18cm leaf.
As a result of irradiation for 0 minutes, sardine seaweed (100 g dry weight) containing 2,2201 U of vitamin D2 was obtained. G''I Tamonoba left outside in the warm sun for 6 hours on a sunny day on the San'in coast in January contains 5701U (100g dry weight) of vitamin D2 and vitamin A.
Both were 12,0 OOIU (100 g dry weight).
しかも2等紫外線を照射したものは光沢1、色調は共に
満足すべきものであった。Furthermore, those irradiated with second grade ultraviolet rays had a gloss of 1 and a satisfactory color tone.
以上実施例から見てもこの様に市販の健康線ランプを以
て上記の藻類を適当に乾燥したものを薄葉として照射す
れば、その藻類中に含まれたビタミン八を失うことなく
藻類の有するエルゴステロールを容易に活性化してビタ
ミンD2になすことが可能であり、特に近年清潔と均質
な食用としての藻類の加工のために屋内で行われる作業
に対し、有効な品位向上のための手段となり、特に生産
上天候に左右されることのない有用な加工法として適切
なものであることは前記の実施例から容易に理解出来る
ものであり、特に蟇類にはカルシウム、カリウム、ナト
リウム、リン、鉄等の無機質の含有量が多く (4δ]
日本食品標準成分表)、健康上有効であり、なかんずく
、カルシウムの栄養ザイクルにはビタミン1〕2の存在
がはなはだ自助であることが明らかになり、貴重な健康
食品を提供し得るものである。Judging from the above examples, if you use a commercially available health line lamp to irradiate the above-mentioned algae as a thin leaf after drying it appropriately, you will not lose the vitamin 8 contained in the algae and the ergosterol that the algae has. can be easily activated to form vitamin D2, which has become an effective means of quality improvement, especially for operations carried out indoors for the processing of algae for clean and homogeneous food, especially in recent years. It can be easily understood from the above examples that it is suitable as a useful processing method that is not affected by the weather in terms of production. High inorganic content (4δ)
It has become clear that the presence of vitamins 1 and 2 in the nutritional cycle of calcium is extremely self-help, and can provide valuable health foods.
1
特h゛1・出廟大 東亜紡織株式会社 □ ・代理人
II原 省吾゛ 閣
江原 秀:、・14.jf、+4.’・1,1!・、1
、□、、ljj、。1 Special h゛1 Chumyo University Toa Boshoku Co., Ltd. □ ・Agent
II Shogo Hara, Hide Kakuehara:,・14. jf, +4. '・1,1!・,1
,□,,ljj,.
=49=49
Claims (1)
に照射することを特徴とする藻類中にビタミンD2を生
成させる方法。(11) A method for producing vitamin D2 in algae, which comprises irradiating the algae with ultraviolet light in the wavelength range of 280 to 320 nm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58152167A JPS6042364A (en) | 1983-08-19 | 1983-08-19 | Preparation of vitamin d2 in seaweeds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58152167A JPS6042364A (en) | 1983-08-19 | 1983-08-19 | Preparation of vitamin d2 in seaweeds |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6042364A true JPS6042364A (en) | 1985-03-06 |
JPS6121944B2 JPS6121944B2 (en) | 1986-05-29 |
Family
ID=15534491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58152167A Granted JPS6042364A (en) | 1983-08-19 | 1983-08-19 | Preparation of vitamin d2 in seaweeds |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6042364A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006224054A (en) * | 2005-02-21 | 2006-08-31 | Matsushita Electric Ind Co Ltd | Electric dust collecting unit |
-
1983
- 1983-08-19 JP JP58152167A patent/JPS6042364A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006224054A (en) * | 2005-02-21 | 2006-08-31 | Matsushita Electric Ind Co Ltd | Electric dust collecting unit |
Also Published As
Publication number | Publication date |
---|---|
JPS6121944B2 (en) | 1986-05-29 |
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