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JPS6015193A - Transfer type thermographic material - Google Patents

Transfer type thermographic material

Info

Publication number
JPS6015193A
JPS6015193A JP58121664A JP12166483A JPS6015193A JP S6015193 A JPS6015193 A JP S6015193A JP 58121664 A JP58121664 A JP 58121664A JP 12166483 A JP12166483 A JP 12166483A JP S6015193 A JPS6015193 A JP S6015193A
Authority
JP
Japan
Prior art keywords
heat
colloidal
base film
layer
recording material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58121664A
Other languages
Japanese (ja)
Inventor
Morio Sato
守夫 佐藤
Yasuzo Murata
村田 保三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pilot Corp
Original Assignee
Pilot Pen Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pilot Pen Co Ltd filed Critical Pilot Pen Co Ltd
Priority to JP58121664A priority Critical patent/JPS6015193A/en
Publication of JPS6015193A publication Critical patent/JPS6015193A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/426Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/44Intermediate, backcoat, or covering layers characterised by the macromolecular compounds

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PURPOSE:To provide the titled recording material with a better heat sticking prevention effect without hampering the heat sensitivity by arranging a heat sticking prevention layer comprising a specified colloidal particle and an organic binder on the other surface of a base film provided with a trans-thermo ink layer on one surface thereof. CONSTITUTION:In a trans-thermo type thermographic material provided with a trans-thermo ink layer 2 on one surface of a base film 1, a heat sticking prevention layer 3 comprising a composition of mixing (A) colloidal particles (normally, with the size of several 10mum) selected from among colloidal silica, colloidal silicate and colloidal alumina and (B) an organic binder (e.g. PVA, methylcellulose, polyvinylbutylal and cellulose acetate butylate) preferably at the ratio of 15:1-4:6 ( in terms of solid components) is provided on the other surface of the base film 1 preferably at the thickness of 0.5-5mum.

Description

【発明の詳細な説明】 本発明は新規な転写型感熱記録材に関し、さらに詳しく
は、感熱ヘッドに接触するベースフィルムの面に耐熱層
を設けてフィルムの面が感熱ヘッドに融着(熱ステイツ
ク)するのを防止した転写型感熱記録材に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a new transfer type thermal recording material, and more specifically, a heat-resistant layer is provided on the surface of a base film that comes into contact with a thermal head, so that the surface of the film is fused to the thermal head (thermal stick). ).Regarding a transfer type heat-sensitive recording material that prevents

近年9発色型の感熱記録方式が多用されているが、記録
の保持性が劣るなどの欠点がある。
In recent years, a nine-color thermal recording system has been widely used, but it has drawbacks such as poor recording retention.

この欠点を改良するものとして転写型の感熱記録方式が
検討されている。この方式は受容シート(例えば普通紙
)に転写型感熱記録材を介して感熱ヘッドの熱パルスに
より印字を行うものであり、受答シートに接する側の感
熱記録材の面に熱溶解性インキ層又は熱昇華性染料含有
層などを設けである。
A transfer type heat-sensitive recording system is being considered as a method to improve this drawback. This method prints on a receiving sheet (for example, plain paper) using heat pulses from a thermal head via a transfer-type thermal recording material. Alternatively, a layer containing a heat sublimable dye may be provided.

転写型感熱記録材の基材としてコンデンサ紙を使用し、
その一方の面にインキ層を設けたものが知られている。
Using capacitor paper as the base material for transfer type thermal recording material,
It is known that an ink layer is provided on one side.

この感熱記録材を使用して記録する場合、感熱ヘッドを
高温にして駆動しても感熱ヘッドと接する紙面は溶融し
ないため熱ステイツク現象は生じない。しかし、コンデ
ンサ紙は厚みが犬(10/jm以上)であり、しかも引
張り強度に欠け、また湿度の影響を受け易く、吸湿など
によりしわを生じ平滑性に欠ける欠点がある。したがっ
て、基材としては薄くて強いプラスチックフィルムが好
適でポリエステルフィルムが使用されているが、耐熱性
が不光分のため、印字中に熱パルスを発生する感熱ヘッ
ドにポリエステルフィルムが貼り付くので熱ステイツク
防止層を設けることが提案されている。
When recording using this heat-sensitive recording material, even if the heat-sensitive head is driven at a high temperature, the surface of the paper that comes into contact with the heat-sensitive head does not melt, so no heat stick phenomenon occurs. However, capacitor paper is thick (10/jm or more), lacks tensile strength, is susceptible to humidity, wrinkles due to moisture absorption, and lacks smoothness. Therefore, a thin and strong plastic film is preferable as a base material, and polyester film is used. However, because it is not heat resistant, the polyester film sticks to the thermal head that generates heat pulses during printing, so it cannot be used as a thermal station. It has been proposed to provide a protective layer.

次に、現在提案さ7′+7でいる押押の熱スデイツク防
11一層について検討する。
Next, we will discuss the currently proposed 7'+7 heat shield 11 layer.

特開昭54 1.43]、52月の提案に」:るアルミ
蒸着層は高価々蒸着処胛設備を必要とし、ベースフィル
ムへの密着性も充分でなく、さらに感熱ヘッドの給電端
子と接触してアルミ蒸着層が通電破壊されるJ・・それ
がある。特1yi′1昭56−] 55794号の提案
に、1:る無機粉末と面1熱性ポリマー」こりなる層は
加熱硬化処理に時間を要し完全硬化は難I〜く、さらに
無機粉末の粗粒(二次凝集粒イ)のため熱感度の低下、
感熱ヘッドの摩耗を生ずる。特開昭57−74195号
の提案による酸化ケイ素と多層部(メタ)アクリレ−1
・より々る層は紫外線硬化処理されるが、多官能(メタ
)アクリレートは大気中では未硬化:%を発生し易く、
さらに酸化ケイ素の粉末附、和粒と々り易く熱感度の低
下、感熱ヘッドの摩耗を生ずる。特開昭57−1297
89号の提案による活性剤又C!:有機塩類よりなる層
は本質的に耐熱性に乏L7<、さらにペー スフィルン
、への密着性も不良である。局開昭55 7467 ”
r−)の提案による/リコーノ樹脂、二i−「lセル「
I−スなどの面1熱性保護膜を使用1〜だものもあるが
、/リコーン樹脂を使Jf」する場合は150〜20 
oUの高温の加熱硬化処理を必要とし、ニトロセルロー
 スを使用する場合(り1、感熱ヘッドの発熱温度でご
l−ロセルロースの分ji14を生U、NO,のような
酸化1〈1:ガスを元!にし感熱−\ラドの相性を劣化
させる重大な欠点がある。
[Unexamined Japanese Patent Publication No. 1983-1.43], proposed in May 1989: The aluminum vapor-deposited layer requires expensive vapor-deposition processing equipment, does not have sufficient adhesion to the base film, and does not come into contact with the power supply terminal of the thermal head. There is a possibility that the aluminum vapor deposited layer will be destroyed by electrical current. In the proposal of No. 55794, it was proposed that 1: inorganic powder and 1 side thermal polymer. Decreased thermal sensitivity due to grains (secondary agglomerated grains),
This causes wear of the thermal head. Silicon oxide and multilayer (meth)acrylate 1 proposed in JP-A-57-74195
・Although more layers are cured by ultraviolet rays, polyfunctional (meth)acrylate tends to be uncured in the atmosphere.
Furthermore, particles attached to silicon oxide powder tend to break off, resulting in a decrease in thermal sensitivity and wear of the thermal head. Japanese Patent Publication No. 57-1297
The activator proposed in No. 89 is also C! : The layer made of organic salts essentially has poor heat resistance, and also has poor adhesion to the pace film. Bureau Opening 55 7467”
r-) / Ricono resin, 2 i- "l cell"
There are some products that use a thermal protective film such as I-S for 1 to 1, but if you use silicone resin, the cost is 150 to 20.
When using nitrocellulose, which requires high-temperature heat curing treatment of oU, oxidation such as U, NO, etc. is used. Since it is based on gas, it has a serious drawback of deteriorating the compatibility with heat-sensitive RAD.

本発明者は前述の熱スティック防1ト層の欠点を改良し
、(1)熱感度を1511害しない耐熱性で、スティッ
ク防止効果が犬きく 、 (2)ペースフィルン・への
密t’f 性が良好であり、(3)ヘースノイルj、へ
の処理が容易であるスティック防山崩について検FI′
ff:続けた結果、11付熱成分として無機材料が好適
で、スティック防止層を薄く(数11 yn以下)構成
するにd、無機材料を分散するのではなく無機材料のコ
ロイダル粒子を用いるのが最適であることを見出して本
発明を完成した。
The present inventor has improved the shortcomings of the heat stick prevention layer described above, and has achieved (1) heat resistance that does not impair thermal sensitivity and excellent stick prevention effect; (3) Inspection FI' for stick prevention landslides that have good properties and are easy to treat with Hessnoil j.
ff: As a result of continuing, an inorganic material is suitable as the heating component of 11, and in order to make the stick prevention layer thin (less than several 11 yn), it is better to use colloidal particles of an inorganic material instead of dispersing an inorganic material. The present invention was completed after discovering that this is optimal.

本発明は、ベースフィルムの一′方の面に熱転写性イン
ギ層を設けた転写型感熱記録材において、ベースフィル
ムの他方の面に、コロイダル/リカ、コロイダル/リケ
ード、コロイダルアルミナから選ばれたコロイダル粒子
と有機バインダーからなる熱スティック防tl−,層を
設けたことを特徴とする転写型感熱記録材である。
The present invention provides a transfer type heat-sensitive recording material in which a heat-transferable ink layer is provided on one surface of a base film, in which a colloidal material selected from colloidal/lyca, colloidal/licade, and colloidal alumina is coated on the other surface of the base film. This is a transfer type heat-sensitive recording material characterized in that it is provided with a heat stick-proof layer made of particles and an organic binder.

本発明の転写型感熱記録材の一実施例を図面に示スとベ
ースフィルム1の一方の面に、熱転写性インキ層2を設
け、ベースフィルム1の他方の簡に、熱ステイツク防止
層3を設けである。
An embodiment of the transfer type heat-sensitive recording material of the present invention is shown in the drawings. A heat transferable ink layer 2 is provided on one side of the base film 1, and a heat stick prevention layer 3 is provided on the other side of the base film 1. It is a provision.

本発明では、熱ステイツク防止層の耐熱成分としてコロ
イダル、/リカ、コロイダル/リカ−1・、コロイダル
アルミナから選ばれたコロイダル粒子を使用することを
特徴とする。寸だ。
The present invention is characterized in that colloidal particles selected from colloidal, /LiCa, colloidal/LiCa-1, and colloidal alumina are used as the heat-resistant component of the heat stick prevention layer. It's a size.

バインダーとして有機バインダーを使用することを特徴
とする。このコロイダル粒子と有機バインダーからなる
熱ステイツク防止層は耐熱性で、熱スティンク防止効果
が大きく、ベースフィルムへの密着性が良好であり、か
つ通常の塗工(幾、印刷機々どにより容易にベースフィ
ルムに層を形成できる。
It is characterized by using an organic binder as the binder. This heat stick prevention layer consisting of colloidal particles and an organic binder is heat resistant, has a large heat stink prevention effect, has good adhesion to the base film, and is easily coated by conventional coating (coating, printing, etc.). A layer can be formed on the base film.

本発明で使用するコロイダル粒子は、コロイダル/リカ
の水分散体又はアルコール分散体。
The colloidal particles used in the present invention are an aqueous dispersion or an alcohol dispersion of colloidal/lica.

コロイダル/l) 力、コロイダルリチウム/リケード
、コロイダルカリウム/リケード、コロイダルアミンン
リケート、コロイダルアルミナの水分散体などであり、
いずれも数10/2mの微粒子よりなる。たとえば、ス
ノーテックス(日産化学工業制)製)、カタロイド(触
媒化成工業■)。
colloidal/l) power, colloidal lithium/licade, colloidal potassium/licade, colloidal amine silicate, colloidal alumina water dispersion, etc.
All of them consist of fine particles of several 10/2 m. For example, Snowtex (manufactured by Nissan Chemical Industries) and Cataloid (manufactured by Catalyst Chemical Industry ■).

ルドツクス(テユボン社製)などが好適である。Ludotux (manufactured by Teyubon) and the like are suitable.

有機バインター1d、ホl)ビニルアルコール。Organic binder 1d, hol) vinyl alcohol.

メチルセルロース、水性のポリビニルブチラールなどの
水溶性樹脂、エマルジョンなどの水分散性侮脂、油性の
ポリビニルブチラール、セルロースアセテートブチレー
トなどのアルコール溶性性・↑l旨などである。
These include water-soluble resins such as methylcellulose and water-based polyvinyl butyral, water-dispersible resins such as emulsions, and alcohol-soluble resins such as oil-based polyvinyl butyral and cellulose acetate butyrate.

コロイダル粒子と有機バインダーの混合比は固形分で約
15:1〜4:6の範囲が好適である。両者の溶液又は
分′#+、液をベースフィルムに塗布又は印刷々どによ
り均一に塗工し乾燥させ。
The mixing ratio of colloidal particles and organic binder is preferably in the range of about 15:1 to 4:6 based on solid content. Both solutions or solutions were uniformly applied to the base film by coating or printing, and then dried.

熱ステイツク防止層を形成する。この層の厚さは約05
〜5ttmが好適である。熱ステイツク防止層の形成は
塗工し乾燥するだけでよいので。
Forms a heat stick prevention layer. The thickness of this layer is approximately 0.5
-5ttm is suitable. To form a heat stick prevention layer, simply apply and dry.

ベースフィルムに熱転写性インキ層を設ける前でも後で
もよい。
It may be applied before or after providing the thermally transferable ink layer on the base film.

ベースフィルムは従来使用されているものが使用でき、
特に制限に1なく、たとえばポリエステルフィルム、ポ
リカーボネー1−フィルム、セルロースアセテートフィ
ルム、ポリプロピレンフィルム、セロハンなどである。
As the base film, conventionally used ones can be used.
There are no particular limitations, and examples include polyester film, polycarbonate film, cellulose acetate film, polypropylene film, cellophane, and the like.

熱転写性インク層は従来使用されている熱溶融性インク
層又は熱昇華性染料含有層であり。
The heat transferable ink layer is a conventionally used heat melt ink layer or a heat sublimable dye-containing layer.

従来公知の方法で塗工又は印刷によって形成する。It is formed by coating or printing using a conventionally known method.

次に1本発明りつ裂1告り11をのべる。Next, I will write about 1 invention, 1 report, 11.

製造1+!I 1 厚さ611mのポリエチレンテレフタレートのベースフ
ィルムの一方の而に、厚さ1.511mの熱転写性イン
ク層を設け、スノーテックスC(日量化学工業掬製のコ
ロイダル7す力(固形分20%)15部、W−201(
種水化学工業■製のポリビニルブチラール(固形分25
%)8部、MS−215(日本油脂■製のノニオン系界
面活性剤)01部、水5部よりなる被覆液をベースフィ
ルムの他方の面に塗布し加熱乾燥して厚さ1.511m
の熱ステイツク防止層を設け、熱転写性記録材をイ4I
だ。
Manufacturing 1+! I 1 A heat transferable ink layer with a thickness of 1.511 m was provided on one side of a base film of polyethylene terephthalate with a thickness of 611 m, and Snowtex C (Colloidal 7 strength (solid content 20%, manufactured by Nikki Kagaku Kogyo Kiki)) was applied. ) 15 copies, W-201 (
Polyvinyl butyral manufactured by Tanemizu Chemical Industry ■ (solid content 25
%), 01 parts of MS-215 (nonionic surfactant manufactured by NOF ■), and 5 parts of water was applied to the other side of the base film and dried by heating to a thickness of 1.511 m.
A heat stick prevention layer is provided, and the heat transferable recording material is
is.

製造例2 厚さ61Lmのポリエチレンテレフタレートのベースフ
ィルムの一方の面に厚さ2.5/LmO熱転写性インク
層を設け、LSS−35(日本化学工業(作製のりチウ
ムンリケート、固形分25%)24部、ポリゾールMC
−5(昭和高分子■製のスチノンーアクリル共重合体樹
脂のエマルジョン、固形分50%)12部よりなる被覆
液をベースフィルムの他方の面に塗布し加熱乾燥して厚
さ4μmの熱ステイツク防止層を設け、熱転写性記録材
を得た。
Production Example 2 A 2.5/LmO thermal transferable ink layer was provided on one side of a polyethylene terephthalate base film with a thickness of 61Lm, and 24 parts of LSS-35 (Nihon Kagaku Kogyo Co., Ltd. (produced glue silicate, solid content 25%)) was applied. , Polysol MC
A coating solution consisting of 12 parts of -5 (emulsion of stinone-acrylic copolymer resin manufactured by Showa Kobunshi ■, solid content 50%) was applied to the other side of the base film and dried by heating to a thickness of 4 μm. A stick prevention layer was provided to obtain a thermally transferable recording material.

製造例3 厚さ61Lのポリエチレンテレフタレートのベースフィ
ルムの一方の面に厚さ211mの熱転写性インク層を設
け、メタノールンリカゲル(固形分30φ)20部、 
BL−1,(種水化学工業■製のポリビニルブチラール
)0.6部、イソプロピルアルコール9.4部より々る
被覆液をベースフィルムの他方の面に塗布し加熱乾燥し
て厚さ1/Amの熱ステイツク防止層を設け、熱転写性
記録材を得た。
Production Example 3 A 211 m thick thermal transferable ink layer was provided on one side of a 61 L thick polyethylene terephthalate base film, and 20 parts of methanol silica gel (solid content 30φ),
A coating solution consisting of BL-1, 0.6 parts of polyvinyl butyral (manufactured by Tanemizu Kagaku Kogyo ■) and 9.4 parts of isopropyl alcohol was applied to the other side of the base film and dried by heating to a thickness of 1/Am. A heat-transferable recording material was obtained by providing a heat stick prevention layer.

製造例4 厚さ611mのポリエチレンテレフタレートのベースフ
ィルムの一方の面に厚さ25μmの熱転写性インク層を
設け、アルミナゾル200(日量化学工業掬製のアルミ
ナゾル、固形分15%)12部、ポリゾールP−25(
昭和高分子■の酢ビ−アクリル共重合体の樹脂のエマル
ジョン。
Production Example 4 A heat transferable ink layer with a thickness of 25 μm was provided on one side of a base film of polyethylene terephthalate with a thickness of 611 m, and 12 parts of Alumina Sol 200 (alumina sol manufactured by Nikki Kagaku Kogyoki, solid content 15%) and Polysol P were added. -25(
Emulsion of Showa Kobunshi's acetic acid-vinyl acrylic copolymer resin.

固形分°50%)、水5部よりなる被tiWをベースフ
ィルムの他方の面に塗布し加熱乾燥して厚さ2.5/A
mの熱ステイツク防止層を設け、熱転写性記録材を得た
A coating material consisting of 50% solids) and 5 parts water was applied to the other side of the base film and dried by heating to a thickness of 2.5/A.
A heat-transferable recording material was obtained by providing a heat stick prevention layer of m.

(9) 製造例5 厚さ611mのポリエチレンテレフタレートのベースフ
ィルムの一方の面に厚さ2/Amの熱転写性インク層を
設け、ルドックスSM(デュポン社製のコロイダルンリ
力、固形分30%)60部、ポリゾールMC−5(昭和
高分子■のスチレン−アクリル共重合体樹脂のエマルジ
ョン、固形分50%)24部よりなる被覆液をベースフ
ィルムの他方の面に塗布し加熱乾燥して厚さ1、、51
1mの熱ステイツク防止層を設け、熱転写性記録材を得
た。
(9) Production Example 5 A thermally transferable ink layer with a thickness of 2/Am was provided on one side of a base film of polyethylene terephthalate with a thickness of 611 m, and 60 parts of Ludox SM (colloidal liquid, manufactured by DuPont, solid content 30%) was applied. A coating solution consisting of 24 parts of Polysol MC-5 (styrene-acrylic copolymer resin emulsion of Showa Kobunshi ■, solid content 50%) was applied to the other side of the base film and dried by heating to a thickness of 1. , 51
A 1 m thick heat stick prevention layer was provided to obtain a heat transferable recording material.

製造例6 厚さ6/Lmのポリエチレンテレフタレートノベースフ
イルムの一方の面に厚さ2μmの熱転写性インク層を設
け、カタロイド(触媒化成工業■製のコロイダルンリ力
、固形分ao%)20部、メトローズ65SH(信越化
学■製のメチルセルロース、固形分3%)20部よりな
る被覆液をベースフィルムの他方の面に塗布乾燥して厚
さ1μmの熱ステイツク防止層を設け、熱転(10) 写性記録拐を得/こ。
Production Example 6 A 2 μm thick heat transferable ink layer was provided on one side of a polyethylene terephthalate base film with a thickness of 6/Lm, and 20 parts of Cataloid (colloidal solid content ao% manufactured by Catalysts & Chemicals Co., Ltd.) and Metrose were applied. A coating liquid consisting of 20 parts of 65SH (methyl cellulose manufactured by Shin-Etsu Chemical ■, solid content 3%) was applied to the other side of the base film and dried to form a 1 μm thick heat stick prevention layer. I got the record.

次に各製造例で掛た熱転写性記録材を以下の性能につい
て試験[7た。
Next, the thermal transfer recording materials used in each production example were tested for the following performance [7].

1 耐熱スティック性 ノアクツミリ装置(日本電信醒話公社製のミニファクス
(送受兼用機))でテストチャー1・を使用し記録紙に
熱転写する際の熱ステイツク現象のイー」無をみた。
1. Heat-resistant stick properties We used Test Char 1 in a Nokkushimi device (a mini fax (sending/receiving machine) manufactured by Nippon Telegraph Seiba Corporation) to check whether there was any heat stick phenomenon during thermal transfer to recording paper.

2 塗工+’1 被覆液のベースフィルムへの均一塗工性の良否をみ/司
2 Coating+'1 Check the uniformity of coating of the coating liquid on the base film.

3 血1剥l1i11性 熱転写性記録材を手もみして熱スティック1坊11一層
のj)?11離のイ1無をみた。
3 Peel off the blood, rub the heat transferable recording material with your hands, and apply the heat stick 1 to 11 layers. I saw 11 nos.

試、験結果を次表に示す1、 本発明の熱転写性記録材は、その熱ステイツク防止層に
よってノアクツミリ装置での熱転写時に熱ステイツク現
象が起らず、被情液のベースフィルムへの均一塗工性が
良好であり、剥離も全くせずすぐれた長所を竹するもの
である。
The results of the tests are shown in the following table. 1. The thermal transfer recording material of the present invention has a heat stick prevention layer that prevents the heat stick phenomenon from occurring during thermal transfer using a NOACT milling device, and allows the liquid to be applied to the base film to be uniformly coated. It has good workability and does not peel at all, making it an excellent bamboo material.

【図面の簡単な説明】[Brief explanation of the drawing]

図面4月、本発明の熱転写性記録材の断面である。 19.ペースフィルl3,2・熱転写性インギ層。 3・・熱ステイツク防止層。 手続補正書(自発) 特許庁長官 若 杉 和 夫 殿 2、発明の名称 転写型感熱記録材 3補正をする者 6補正の内容 FIG. 4 is a cross-section of the thermal transferable recording material of the present invention. 19. PACE FIL 13,2/thermal transferable ingi layer. 3. Heat stick prevention layer. Procedural amendment (voluntary) Mr. Kazuo Wakasugi, Commissioner of the Patent Office 2. Name of the invention Transfer type thermal recording material 3 Person who makes corrections 6. Contents of amendment

Claims (1)

【特許請求の範囲】 ベースフィルムの一方の面に熱転写性インキ層を設けた
転写型感熱記録材において、前記ベースフィルムの他方
の面に、コロイダルノリ力。 コロイダルノリケート、コロイダルアルミナから選ばれ
たコロイダル粒子と有機バインダーからなる熱ステイツ
ク防止層を設けたことを特徴とする転写型感熱記録材。
[Scope of Claims] In a transfer-type heat-sensitive recording material in which a heat-transferable ink layer is provided on one surface of a base film, a colloidal adhesive is applied to the other surface of the base film. A transfer type heat-sensitive recording material characterized by being provided with a heat stick prevention layer made of colloidal particles selected from colloidal nolicates and colloidal alumina and an organic binder.
JP58121664A 1983-07-06 1983-07-06 Transfer type thermographic material Pending JPS6015193A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58121664A JPS6015193A (en) 1983-07-06 1983-07-06 Transfer type thermographic material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58121664A JPS6015193A (en) 1983-07-06 1983-07-06 Transfer type thermographic material

Publications (1)

Publication Number Publication Date
JPS6015193A true JPS6015193A (en) 1985-01-25

Family

ID=14816841

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58121664A Pending JPS6015193A (en) 1983-07-06 1983-07-06 Transfer type thermographic material

Country Status (1)

Country Link
JP (1) JPS6015193A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6082385A (en) * 1983-10-12 1985-05-10 Matsushita Electric Ind Co Ltd Thermal transfer recording body
JPS61175089A (en) * 1985-01-31 1986-08-06 Dainippon Printing Co Ltd Thermal transfer sheet
JPS61189992A (en) * 1985-02-20 1986-08-23 Toyo Ink Mfg Co Ltd Thermal transfer material
JPS6232091A (en) * 1985-08-06 1987-02-12 Oji Paper Co Ltd Ink sheet for thermal transfer printer
EP0262953A2 (en) * 1986-10-03 1988-04-06 Fuji Photo Film Co., Ltd. Heat-sensitive recording material
JPS63135290A (en) * 1986-11-28 1988-06-07 Victor Co Of Japan Ltd Transfer paper
JPH01271288A (en) * 1988-04-23 1989-10-30 Mitsubishi Paper Mills Ltd Thermal transfer film
US5223328A (en) * 1990-12-21 1993-06-29 Diafoil Hoechst Co., Ltd. Thermal ink transfer printing material
EP0580160A2 (en) * 1992-07-23 1994-01-26 Eastman Kodak Company Dye-donor binder for laser-induced thermal dye transfer
US6017611A (en) * 1998-02-20 2000-01-25 Felix Schoeller Technical Papers, Inc. Ink jet printable support material for thermal transfer
JP2006306089A (en) * 2005-03-31 2006-11-09 Dainippon Printing Co Ltd Thermal transfer sheet

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56155794A (en) * 1980-05-06 1981-12-02 Fuji Kagaku Kogyo Kk Thermo-sensitive transfer material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56155794A (en) * 1980-05-06 1981-12-02 Fuji Kagaku Kogyo Kk Thermo-sensitive transfer material

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6082385A (en) * 1983-10-12 1985-05-10 Matsushita Electric Ind Co Ltd Thermal transfer recording body
JPS61175089A (en) * 1985-01-31 1986-08-06 Dainippon Printing Co Ltd Thermal transfer sheet
JPS61189992A (en) * 1985-02-20 1986-08-23 Toyo Ink Mfg Co Ltd Thermal transfer material
JPH0378077B2 (en) * 1985-02-20 1991-12-12 Toyo Ink Mfg Co
JPS6232091A (en) * 1985-08-06 1987-02-12 Oji Paper Co Ltd Ink sheet for thermal transfer printer
EP0262953A3 (en) * 1986-10-03 1989-09-06 Fuji Photo Film Co., Ltd. Heat-sensitive recording material
EP0262953A2 (en) * 1986-10-03 1988-04-06 Fuji Photo Film Co., Ltd. Heat-sensitive recording material
JPS63135290A (en) * 1986-11-28 1988-06-07 Victor Co Of Japan Ltd Transfer paper
JPH01271288A (en) * 1988-04-23 1989-10-30 Mitsubishi Paper Mills Ltd Thermal transfer film
US5223328A (en) * 1990-12-21 1993-06-29 Diafoil Hoechst Co., Ltd. Thermal ink transfer printing material
EP0580160A2 (en) * 1992-07-23 1994-01-26 Eastman Kodak Company Dye-donor binder for laser-induced thermal dye transfer
EP0580160A3 (en) * 1992-07-23 1994-10-05 Eastman Kodak Co Dye-donor binder for laser-induced thermal dye transfer.
US6017611A (en) * 1998-02-20 2000-01-25 Felix Schoeller Technical Papers, Inc. Ink jet printable support material for thermal transfer
JP2006306089A (en) * 2005-03-31 2006-11-09 Dainippon Printing Co Ltd Thermal transfer sheet

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