JPS5950264B2 - Stabilization method for anthraquinone and carotenoid pigments - Google Patents
Stabilization method for anthraquinone and carotenoid pigmentsInfo
- Publication number
- JPS5950264B2 JPS5950264B2 JP55043906A JP4390680A JPS5950264B2 JP S5950264 B2 JPS5950264 B2 JP S5950264B2 JP 55043906 A JP55043906 A JP 55043906A JP 4390680 A JP4390680 A JP 4390680A JP S5950264 B2 JPS5950264 B2 JP S5950264B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- anthraquinone
- carotenoid pigments
- stabilization method
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
Description
【発明の詳細な説明】
この発明は、色素に係るものであつて、工業的に有利に
その経時的褪色を防止すると共に、発色の良好化を図る
ことを目的とする。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to pigments, and aims to industrially advantageously prevent fading over time and improve color development.
色素中、アントラキノン系及びカロチノイド系のものは
、その資源が動植物中に多く見出され、入手容易である
こと、毒性が極めて少ないこと、発色が良好であること
、使用法が簡便であること等から工業的用途にまたは食
品に多く使用されているが、日光。酸化等により経時的
褪色が生じやすく、色調が不安定になるという欠点を示
す。これらの色素の不安定化を防止する方法は、多くが
知られているが、何れの防止度合いが低いという欠点が
ある。Among pigments, anthraquinones and carotenoids are found in many resources in animals and plants, and are easy to obtain, have extremely low toxicity, have good color development, and are easy to use. Although it is often used in industrial applications or in food products, it is exposed to sunlight. Discoloration tends to occur over time due to oxidation, etc., and the color tone becomes unstable. Many methods are known for preventing the destabilization of these dyes, but each method has the disadvantage that the degree of prevention is low.
この発明はこのような欠点のないものである。The present invention is free from such drawbacks.
この発明を以下に説明する。この発明の適用色素は、ア
ントラキノン系及びカロチノイド系のもの一般である。This invention will be explained below. The pigments applicable to this invention are generally anthraquinone and carotenoid pigments.
両者の均質な混合物についても適用することができる。
アントラキノン系色素としては、カルミン酸、ラツカイ
ン酸、ケルメシン酸等が代表例としてあげられる。It can also be applied to a homogeneous mixture of both.
Representative examples of anthraquinone dyes include carminic acid, latcaic acid, and kermesic acid.
カロチノイド系色素としては、β一カロチン、ビキシン
、ノルビキシン、カプサンチン、クロチン、ルテイン、
β−アポカロチナール、カッタキサンチン等が代表例と
してあげられる。Carotenoid pigments include β-carotene, bixin, norbixin, capsanthin, crotin, lutein,
Representative examples include β-apocarotenal and cattaxanthin.
この発明は、これらの色素に対して、安定化するための
組成物を使用する。This invention uses stabilizing compositions for these dyes.
その組成は、次の通りである。酒石酸ナトリウムとミヨ
ウバンと炭酸ナトリウムとの配合物である。Its composition is as follows. It is a combination of sodium tartrate, alum and sodium carbonate.
酒石酸ナトリウムは１０〜４５％（重量、以下同じ）、
ミヨウバン（焼ミヨウバン、アンモニウムミヨウバン等
、いずれも使用できる。）は２〜２５％、炭酸ナトリウ
ムは２〜２５％を使用する。これらの配合物がここにい
う安定化のための組成物である。Sodium tartrate is 10-45% (weight, same below),
Alum (burnt alum, ammonium alum, etc. can all be used) is used in an amount of 2 to 25%, and sodium carbonate is used in an amount of 2 to 25%. These formulations are the stabilizing compositions referred to herein.
このものを相手色素に配合する。配合割合は前者が９０
〜５０部（重量以下同じ）に対して、後者が１０〜５０
部である。配合系は、均質にする。この際、系が中性で
あれば最も良く目的が、達せられる。しかして、酒石酸
ナトリウム、ミヨウバン及び炭酸ナトリウムは、同時添
加の必要はなく、各別に添加しても良い。系が酸性ある
いはアルカリ性を示すときは、色素及び安定化組成物の
品質に悪影響を与えないｐＨ調整剤、例えば、希釈鉱酸
水溶液あるいは希釈水酸化ナトリウム水溶液を加えて、
系を微酸性ないし、微アルカリ性にする方が望ましい。
系は、ここに均質な水可溶系を示す。このものを所望の
食品、例えば砂糖、かまぼこなどの水産加工品、焼物菓
子、その他の物の表面あるいは内部に添加する。This material is blended with the mating dye. The blending ratio is 90 for the former.
~50 parts (same weight and below), while the latter is 10 to 50 parts
Department. The blend system should be homogeneous. At this time, the purpose is best achieved if the system is neutral. Therefore, sodium tartrate, alum, and sodium carbonate do not need to be added simultaneously, and may be added separately. When the system is acidic or alkaline, add a pH adjuster that does not adversely affect the quality of the dye and stabilizing composition, such as a dilute aqueous mineral acid solution or a dilute aqueous sodium hydroxide solution.
It is preferable to make the system slightly acidic or slightly alkaline.
The system here represents a homogeneous water-soluble system. This product is added to the surface or inside of desired foods, such as sugar, processed seafood products such as kamaboko, baked goods, and other objects.
添加する方法は、次に記す３つの態様の何れでもよい。
その１は、相手の色素にこの安定化のための組成物を添
加混合する方法である定その２は、先ず着色を要する物
、例えば、かまぼこを色素で着色してから、これにこの
安定化のための組成物の水溶液を噴霧し、あるいはその
水溶液中にかまぼこを浸漬する方法である。The method of addition may be any of the following three modes.
The first method is to add and mix this stabilizing composition to the other dye.The second method is to first color an object that requires coloring, for example, a kamaboko, with a dye, and then add this stabilizing composition to the dye. This is a method of spraying an aqueous solution of the composition or immersing the kamaboko in the aqueous solution.
その３は、かまぼこを予めこの安定化のための組成物で
処理（例えば、その水溶液中に浸漬する、あるいは組成
物をかまぼこの組織中に均質に分散させる）した後、こ
れを相手の色素を用いて着色する方法である。Thirdly, after the kamaboko is pre-treated with this stabilizing composition (for example, immersed in its aqueous solution or the composition is homogeneously dispersed in the structure of the kamaboko), the other dye is added to the kamaboko. This is a method of coloring using
このようにすると、アントラキノン系及び又はカロチノ
イド系色素の退色及び色調を有効に安定化することがで
きる。In this way, fading and color tone of anthraquinone and/or carotenoid pigments can be effectively stabilized.
ここに、この発明は目的を達する。Here, the invention achieves its purpose.
この発明の色調及発色の安定化効果は、極めて大きい。
このことを、次の実験例によつて証明する。カロチノイ
ド色素１０部とアントラキノン系色素１部を、上記、安
定化剤に、１５％添加した。The effect of stabilizing color tone and color development of this invention is extremely large.
This will be proven by the following experimental example. 10 parts of carotenoid dye and 1 part of anthraquinone dye were added to the above stabilizer at 15%.
耐光性は直射日光・５日間の照射結果で、数字は強弱を
示し、１０を最高とし以下１を最低値とした。色調、発
色度合は、２０℃、８０℃、３０分処理後の総合結果を
示す。Light resistance is the result of irradiation with direct sunlight for 5 days, and the numbers indicate strength and weakness, with 10 being the highest and 1 being the lowest. The color tone and degree of color development are the overall results after treatment at 20°C and 80°C for 30 minutes.
上記結果から全てを満足し得る条件は、実験７であつた
。From the above results, Experiment 7 was the condition that satisfied all of the conditions.
実施例 １．
ｄ酒石酸ナトリウム３０部、炭酸ナトリウム１５部、焼
ミヨウバン１５部、ラツカイン酸粉末１０部、ノルビキ
シン粉末３０部を混合粉砕し、本発明の製剤となし、目
的食品（水産煉製品）の表面に２０〜５０％程度の水溶
液で塗布した。Example 1. d 30 parts of sodium tartrate, 15 parts of sodium carbonate, 15 parts of burnt alum, 10 parts of latsukaic acid powder, and 30 parts of norbixin powder were mixed and ground to form the formulation of the present invention, and 20 to 30 parts were applied to the surface of the target food (fried seafood product). It was applied using an approximately 50% aqueous solution.
このものは、耐光性において色調変化、劣化がなく非常
に優れたものであつた。実施例 ２．
酒石酸ナトリウム２０部、炭酸ナトリウム１５部、ミヨ
ウバン２５部を混合粉砕し、製剤化したものを５％水溶
液となし、これに魚介物を浸漬後カルミン酸粉末５部、
ノルビキシン粉末３０部、β一カロチン乳化粉末５部の
２％水溶液を塗布後乾燥したところ、目的の色調及安定
化効果が達成された。This product had excellent light resistance without any change in color tone or deterioration. Example 2. 20 parts of sodium tartrate, 15 parts of sodium carbonate, and 25 parts of alum were mixed and pulverized to form a 5% aqueous solution, and after immersing seafood in this, 5 parts of carminic acid powder,
When a 2% aqueous solution of 30 parts of norbixin powder and 5 parts of β-carotene emulsified powder was applied and dried, the desired color tone and stabilizing effect were achieved.
Claims (1)
〜５０部に対し、次の組成からなる組成物を９０〜５０
部用いることを特徴とするこれら色素の安定化法。 酒石酸ナトリウム１０〜４５％、ミヨウバン２〜２５％
及び炭酸ナトリウム２〜２５％からなる組成物。[Claims] 1. Anthraquinone and/or carotenoid pigments 10
~50 parts, 90 to 50 parts of a composition consisting of the following composition
A method for stabilizing these dyes, characterized by using Sodium tartrate 10-45%, alum 2-25%
and 2 to 25% sodium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55043906A JPS5950264B2 (en) | 1980-04-02 | 1980-04-02 | Stabilization method for anthraquinone and carotenoid pigments |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55043906A JPS5950264B2 (en) | 1980-04-02 | 1980-04-02 | Stabilization method for anthraquinone and carotenoid pigments |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56139561A JPS56139561A (en) | 1981-10-31 |
| JPS5950264B2 true JPS5950264B2 (en) | 1984-12-07 |
Family
ID=12676749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55043906A Expired JPS5950264B2 (en) | 1980-04-02 | 1980-04-02 | Stabilization method for anthraquinone and carotenoid pigments |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5950264B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60137261A (en) * | 1983-12-27 | 1985-07-20 | Seiwa Kasei Kk | Prevention of browning of edible coloring matter |
| US5164212A (en) * | 1991-08-23 | 1992-11-17 | Del Monte Corporation | Method for coloring fruits and vegetables with anthraquinones and product |
| KR100737340B1 (en) | 2000-09-11 | 2007-07-09 | 산에이겐 에후.에후. 아이. 가부시키가이샤 | Purified cochineal pigment and process for producing the same |
| JP6353407B2 (en) * | 2015-06-08 | 2018-07-04 | 毅臣 渡邉 | Alkaline composition or aqueous solution for preventing discoloration |
-
1980
- 1980-04-02 JP JP55043906A patent/JPS5950264B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56139561A (en) | 1981-10-31 |
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