JPS5889329A - Simultaneous molding by different materials - Google Patents
Simultaneous molding by different materialsInfo
- Publication number
- JPS5889329A JPS5889329A JP56187603A JP18760381A JPS5889329A JP S5889329 A JPS5889329 A JP S5889329A JP 56187603 A JP56187603 A JP 56187603A JP 18760381 A JP18760381 A JP 18760381A JP S5889329 A JPS5889329 A JP S5889329A
- Authority
- JP
- Japan
- Prior art keywords
- gap
- raw material
- heated
- heating
- mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/44—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form
- B29C44/445—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length in solid form in the form of expandable granules, particles or beads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3415—Heating or cooling
- B29C44/3426—Heating by introducing steam in the mould
Landscapes
- Laminated Bodies (AREA)
- Molding Of Porous Articles (AREA)
Abstract
Description
【発明の詳細な説明】
この発明は異種原料による同時成形方法IC関し1発泡
性熱可塑性樹脂粒子による異種原料を使用してそれぞれ
の原料を混合することなく一体KB、形融着できるよう
にした−ので、特に省エネルギー必要とするような場合
には2種類以上の発泡性熱可胆性樹脂粒子による原料を
用いて発泡成形品を別々KvL形し、嵌合戚は接着等の
手段にてl個の発泡成形品になるよう製造したり、発泡
成形品に別なものを補強のために嵌合或は接着していた
ものである0特に後者の例示としては工1−:Iンディ
ショナー等の電化製品に対する包装材として発泡ポリス
チレンによる成形品を用いた場合、下部コーナー個所で
の欠は等破損を考慮して下面にダンボールシート等を接
着していたが、接着が外れたりして一体性に劣る点があ
シ、シかも上記何れの従来技術によりても製造上の工数
が多くかかうて非能率的である等積々の問題点があり、
コストダクンの意味からも業界からは強く改良の要望が
なされている現状であった。[Detailed Description of the Invention] This invention relates to a simultaneous molding method for IC using different raw materials.1 Using different raw materials made of expandable thermoplastic resin particles, it is possible to integrally form KB and fuse the shapes without mixing the respective raw materials. - Therefore, in cases where energy saving is particularly required, foam molded products may be made into separate KvL shapes using raw materials made of two or more types of foamable thermoplastic resin particles, and the fitting parts may be formed by adhesive or other means. In particular, examples of the latter include conditioners, etc. When molded products made of foamed polystyrene were used as packaging materials for electrical appliances, cardboard sheets, etc., were glued to the bottom surface to prevent damage such as chipping at the lower corners, but the adhesive could come off and the integrity was compromised. Both of the above conventional techniques have a number of problems, such as high manufacturing man-hours and inefficiency.
There was a strong demand for improvements from the industry in terms of reducing costs.
そのため最近に至シ、異種原料となる発泡性熱可塑性樹
脂粒子を段階を分けて充填し、同時に成形することも提
案され出したが、全ての異種原料を充填した後に1はじ
めて加熱する場合に#i前記充填時に異種原料どうしが
混和されることがあるため明瞭な境界部分の形成が困難
となる欠点がありた。 また一旦充填した異種となる一
方の原料を先に加熱、冷却して仮融着させ、その後異種
となる他方の原料充填のために型l@きさせる成形方法
も提案されているが、この場合加熱後の冷却にて膨張圧
が抑制され、境界となる部分でも融看度程を経ると、仮
融着物および成形型も冷却状IIKあシ、次の異種とな
る他方の原料充填後の加熱工程に多(の熱エネルギーを
要することKなシ、発泡wL形上の効率の点でも好まし
いものではな(なる欠点かあ″)九〇
そζで、この発明方法にありては、上記の諸欠点を一挙
に解消できるような異種原料による同時成形方法を鋭意
研究の未開発したものでToりて、その方法としては、
成形型の型窩内へ発泡性熱可塑性樹脂粒子による原料を
充填し、該原料を蒸気等の加熱媒体によシ加熱膨張させ
て発泡成形品を得る方法において、先ず最初の原料を型
窩内へ充填した後、異種原料のための隙間を設けようと
する側から一方加熱を行ない、少なくとも境界部なる部
分については加熱融着仕上げをなした後、暫時型Nきせ
ずに発泡圧がなくなるまで放置し、次いで成形型を所要
間隔1だけ開いて境界になる部分側に隙間を設け、該隙
間内に前記原料とは異種になる原料を充填し、該異種原
料の充填側から一方加熱をなした後、これとは逆方向か
ら一方加熱を行ない、さらに両面加熱をなした後、保熱
、冷却を行ない、全体が一体に融着成形された同時成形
品を得ることを特徴としている。For this reason, it has recently been proposed to fill expandable thermoplastic resin particles, which serve as different raw materials, in stages and mold them at the same time. i) Different types of raw materials may be mixed together during the filling process, which has the disadvantage that it is difficult to form clear boundaries. A forming method has also been proposed in which one of the different types of raw material is first heated and cooled to temporarily fuse it, and then molded to fill the other type of raw material, but in this case, The expansion pressure is suppressed by cooling after heating, and when the boundary part also undergoes a degree of fusion, the temporarily fused material and the mold also become cooled IIK reeds, and the next different type is heated after filling the other raw material. The process requires a large amount of thermal energy, which is not preferable in terms of efficiency in terms of foaming L shape. A method of simultaneous molding using different raw materials that can eliminate various drawbacks at once is an undeveloped method that has been extensively researched, and the method is as follows.
In a method of obtaining a foamed molded product by filling a raw material made of expandable thermoplastic resin particles into the mold cavity of a mold and heating and expanding the raw material with a heating medium such as steam, the first raw material is first poured into the mold cavity. After filling the mold, heat is applied from the side where the gap for the different materials is to be created, and at least the boundary part is finished by heat fusion, and then the foaming pressure is removed without forming the mold N for a while. Then, the mold is opened by the required interval 1 to create a gap on the side that will become the boundary, and a raw material different from the raw material is filled in the gap, and heating is performed from the side filled with the different raw material. After that, heating is performed on one side from the opposite direction, and after heating on both sides, heat retention and cooling are performed to obtain a simultaneous molded product in which the whole is fused and molded as one piece.
次いで、このl明の実施態様にりいて詳細に述ぺると、
キャビティ型とプア型とを11vUめ後、型窩内に先ず
興11原料のうち最初の原料となる発泡性熱可塑性樹脂
粒子を充填する・ 次に他の異種原料のための隙間を設
けようとする側、例えばキャビティ側から他の異種原料
を供給しようとする場合にはキャピテイ側から一方加、
熱を行ない、最初に充填されである前記樹脂粒子を互に
融着しtりな(とも境界になる部分については、加熱融
着仕上げをなし、型開きなせぬまま暫時発泡圧がなくな
るまで放置しておく。 この放置は保熱のために役立つ
こととなる・ 次いで、エジエクトエ1−を成形品側へ
噴きつけながらキャピテイ型を所要間隔だけ開いて境界
になる部分側、この場合光に融着されであるものとキャ
ピテイ型との闇に隙間を投砂ること忙なり、この隙間内
に一記最初の原料上は異種になる他方の発泡性熱可塑性
411m#粒子を充填する。そして他方の興a[原料の
充填側であるキャビティ側から一方加熱をなし、他方の
樹脂粒子相互の融着をはか)、この後、これとは逆KJ
ア側から一方加熱を行ない、さらにキャビを行なう。
冷却については、水冷をなし排水後放冷をなす0冷却後
はクイック型開きを行ない、離型させて完全にを開きを
行ない、同時成形品を取出せばよい0
図にはこの発明にて発泡成形された成形品の数例を例示
してお)、図でti機械、器具、装置141の梱包時に
これらの下部にて使用される緩衝材を同時成形品の具体
例として示しである。 この発泡vL形品(6)のうち
、 (、)(a)は互に異種となる発泡性熱可塑性樹脂
粒子による原料をもりて構成した部分であシ、特に(5
5は発泡成形品(2)の少なくとも底部の所要厚になる
部分であつて、第1図では底部の本であるが、第2vA
で紘鴎儒部の所要厚にも及んでお)、さらに第3図では
目側−部の所要厚に及んだ場合を示している。セして興
1[料をもって構成した(s) (a)の部分は互に異
種原料が混合することなく同時成形されていて、互の境
界部分が一体に融着されているものであるO 例えげ−
)の部分を発泡ポリスチレン系樹脂にて形成すると共に
(−の部分を発泡ポリオレアイン系樹脂にて形成してい
る場合をあげ得る0その理由としては、発泡ポリスチレ
ン系樹脂は価格的に比較的安価であるが、柔軟性および
弾性(復元性)ならびに耐油性において発泡ポリオレフ
ィン系樹脂の方が優れているため、これらの作用効果を
発泡成形品の少なくとも底部の所要厚部分に活かせるよ
うKしている点を指摘できる。 従って、発泡成形品と
しては、上記の場合少なくとも底部の所要厚に相当する
部分く対しその要求される機能に@応した多種多様なも
の、例えばこの部分に補強を施して角傷み、欠は等を解
消したもの、耐薬品性を付与させて耐久性を増大したも
の等充分発泡成形品に付加価値を付与できる。そのため
、エアーコンディショナー等の電化製品に対する前記包
装材の場合、従来のように発泡成形品の下面にダンボー
ルシートを接着せずとも部分的補強を実現できることK
なる。Next, to describe this embodiment in detail,
After filling the cavity mold and the pour mold with 11VU, the mold cavity was first filled with expandable thermoplastic resin particles, which will be the first raw material among the 11 raw materials.Next, a gap was created for other different raw materials. For example, when trying to supply other different raw materials from the cavity side, add one side from the cavity side,
Heat is applied to fuse the first filled resin particles to each other (both boundary areas are heated and fused, and the mold is left for a while without opening until the foaming pressure is removed). This will help retain heat.Next, while spraying ejector 1- onto the molded product side, open the capity mold by the required distance and place it on the boundary side, which in this case will be fused by light. I am busy trying to find a gap between the one type and the capacity type, and fill this gap with the other expandable thermoplastic 411m# particles, which are different in terms of the initial raw material. a [Heating is performed on one side from the cavity side, which is the side where the raw material is filled, and on the other side, the resin particles are fused together), and then the opposite KJ is applied.
Heating is performed from the A side, and then heating is performed.
For cooling, water cooling is performed, and after draining water, the mold is left to cool.After cooling, the mold is quickly opened, the mold is released, and the mold is completely opened to take out the molded product at the same time. In the figure, a cushioning material used at the bottom of machines, instruments, and devices 141 when they are packaged is shown as a specific example of a simultaneously molded product. Of this foamed VL-shaped product (6), (,) and (a) are parts composed of raw materials of foamable thermoplastic resin particles that are different from each other, especially (5).
Reference numeral 5 denotes a portion having the required thickness at least at the bottom of the foam molded product (2), and in FIG.
In addition, FIG. 3 shows a case in which the required thickness of the eye side portion is also reached. (s) The part (a) is molded at the same time without mixing different materials, and the boundary parts are fused together. Example-
The reason for this is that foamed polystyrene resin is relatively inexpensive. However, foamed polyolefin resin is superior in terms of flexibility, elasticity (restorability), and oil resistance, so these effects can be utilized at least in the required thickness at the bottom of the foamed molded product. Therefore, in the above case, a wide variety of foam molded products can be used, at least at the part corresponding to the required thickness of the bottom part, depending on the required function, for example, by reinforcing this part and making corners. It is possible to sufficiently add value to foamed molded products, such as those that have eliminated damage, chips, etc., and those that have increased durability by imparting chemical resistance.Therefore, in the case of the above-mentioned packaging materials for electrical appliances such as air conditioners, Partial reinforcement can be achieved without attaching a cardboard sheet to the bottom surface of the foam molded product as in the past.K
Become.
なお、発泡ポリオレフィン系樹脂の例をあげると、エチ
レン単独重合体、エチレン−酢酸ビニρのどときエチレ
ン共重合体、プロピレン単独重合体等のポリオレフィン
系樹脂、または該ポリオレフィン系樹脂と、スチレン、
メチルスチレンの単独重合体、スチレンーアクリロニ′
PJA/4Iのポリスチレン系樹脂との混合樹脂をも包
含している。特にポリエチレン、ポリプロピレン等のポ
リオレフィン系粒子を核にしてスチレン系モノマーおよ
び該モノ!−を重合させる触媒とを前記#KQlj収さ
せ、この核内でスチレン系モノ!−を重合することによ
り、ポリオレフィン系樹脂とポリスチレン系樹脂とが少
なくとも一部グラフト結合(グラフト結合部分社ポリオ
レフ愕ン系樹脂とポリスチレン系樹脂との総和の1%以
上)した樹脂粒子に発泡剤を加えて発泡樹脂粒子となし
たもの〔商品名:ビオセラン(グラフト率4%)、積水
化成品工業株式会社製〕をもりて、実施すると、高い柔
軟性、・弾性のほか、優れた耐油性をも付与できて好ま
しい。Examples of foamed polyolefin resins include polyolefin resins such as ethylene homopolymer, ethylene-vinyl acetate copolymer, propylene homopolymer, or the polyolefin resin and styrene,
Homopolymer of methylstyrene, styrene-acryloni′
It also includes mixed resins of PJA/4I with polystyrene resins. In particular, styrenic monomers and monomers with polyolefin particles such as polyethylene and polypropylene as cores! The catalyst for polymerizing - is collected in the #KQlj core, and the styrene-based mono! - By polymerizing the polyolefin resin and the polystyrene resin, a blowing agent is added to the resin particles in which at least a portion of the polyolefin resin and the polystyrene resin are graft-bonded (1% or more of the total of the polyolefin resin and the polystyrene resin). In addition, when used with foamed resin particles [trade name: Biocelan (grafting rate 4%), manufactured by Sekisui Plastics Co., Ltd.], it has high flexibility and elasticity as well as excellent oil resistance. It is preferable that it can also be given.
さらに1上記のととく材質が互に異なるようにした同時
成形品のほか、粒径が互に異なるもの、発泡倍率が互に
異なるもの、着色が互に異なる等積々の同時成形品が製
造できる・
以上のように1この発明方法にて種々の態様をなす同時
発泡成形品が提供可能となるが、成形上特に1この発明
方法では異種原料のうち、最初に充填された一方の原料
に対しては従来のごとく加熱による仮融着段階で、積極
的な冷却を行なうものではなく、他の異種原料のための
隙間を設けようとする側から一方加熱を行ない、少なく
とも境界になる部分については加熱融着仕上げをなした
後、暫時型開きせずに発泡圧がなくなるまで放置してお
くゆえ、境界となる部分での融着度合が不充分となるこ
とをなくシ、次の原料充填のための所要間隔分の型開き
にようても境界となる部分での小崩れ現象をなくすこと
ができる。 また上記のとと(最初の充填原料に対する
加熱後に、冷却せぬため、最初の異種原料に対してなさ
れた加熱による熱エネルギーをa′#、させ、次回の原
料充填後に対する加熱を効率良く行なえることにな)、
省エネルギーの上でも効果的な方法であるほか、成形サ
イクルの短縮化にも役立ち、同時発泡成形を能率的に行
なえることになる。Furthermore, in addition to the above-mentioned co-molded products made of different materials, we also produce a large number of co-molded products with different particle sizes, different expansion ratios, and different colors. As described above, 1. With the method of this invention, it is possible to provide co-foamed molded products in various forms. In contrast, unlike conventional methods, active cooling is not performed at the stage of temporary fusion by heating, but instead heating is performed from the side where a gap for other different materials is to be created, at least for the part that will become the boundary. After completing the heat-fusion finish, the mold is left unopened for a while until the foaming pressure is released, so that the degree of fusion at the border area is not insufficient, and the next filling of raw materials is done. Even if the mold is opened for the required interval, it is possible to eliminate the phenomenon of small collapse at the boundary portion. In addition, as mentioned above (since the first filling raw material is not cooled after heating, the thermal energy from the heating applied to the first different type of raw material is a'#), and the next time after filling the raw material is heated efficiently. In fact),
In addition to being an effective method for saving energy, it also helps shorten the molding cycle, allowing simultaneous foaming molding to be carried out efficiently.
以下に緩衝用包装材として長さ40(1■×幅$00■
×厚さ1110mの発泡成形品について、sO倍発発泡
発泡ポリスチレン樹脂粒子と80倍発発泡発泡ポリスチ
レン樹脂粒子とを用いて同時成形する実施例を示す。Below is a length of 40cm (1■ x width $00■) as a cushioning packaging material.
An example will be shown in which a foam molded product having a thickness of 1110 m is simultaneously molded using sO times expanded polystyrene resin particles and 80 times expanded expanded polystyrene resin particles.
以下余白
(工程〕 c時間
〕(1) IJ!閉
(2) 第1回原料充填 60倍発発泡樹脂粒子
12秒(4) 放 置 発泡圧がな
くなるまで 60秒(0第2回原料充填 80
倍発発泡樹脂粒子 8秒■ 一方加熱
キャピテイ側より 6秒G、6即/jKて
e) 両面加熱 キャピテイ・コア双方
6秒側よシ 1.0即/jKて
(至) 保 熱 8
秒I 水 冷 16秒
@ 排 水 3秒O
放 冷0 10秒9 クイッ
ク開 29鑓 放
冷■ 120秒−離 型
0.1即/dKて(1?) !! 開
7秒(
II型閉待 2秒The following margins (process) c time] (1) IJ! Close (2) 1st raw material filling 60 times expanded resin particles
Leave for 12 seconds (4) Until foaming pressure disappears 60 seconds (0 2nd raw material filling 80
Double expanded resin particles 8 seconds■ On the other hand, heating
From the capitivity side: 6 seconds G, 6 instant/jKte) Double-sided heating Both capity and core
6 seconds side 1.0 Immediately/jKte (To) Heat retention 8
Second I Water cooling 16 seconds @ Drain 3 seconds O
Cooling 0 10 seconds 9 Quick open 29 yen Opening
Cool ■ 120 seconds - release mold
0.1 instant/dKte(1?)! ! Open 7 seconds (
Type II close 2 seconds
図はこの発明方決によシ成形された同時成形品の数例を
示してあり、第鳳図は底部のみに他部分とは異種の原料
を用いである場合の断面図、第2図は底部のほか、側部
に屯異種の原料を用いである場合の断面図、IM8図社
図郭側部部と底sK異種の原料を用いである場合の断面
図である。
(2)・−一同時成形による発泡m形品(−一)・・・
互に異種となる原料をもって構成した部分・The figures show several examples of simultaneously molded products molded by the method of this invention. Figure 2 is a cross-sectional view of a case where only the bottom part is made of a different type of raw material than the other parts. They are a cross-sectional view when different kinds of raw materials are used for the side parts as well as the bottom, and a cross-sectional view when different kinds of raw materials are used for the IM8 side part and the bottom sK. (2)・-M-shaped foamed product by simultaneous molding (-1)...
Parts composed of mutually different raw materials
Claims (1)
よる原料を充填し、該原料を蒸気等の加熱媒体によ〉加
熱膨張させて発泡成形品を得る方法において、先ず最初
の原料を型窩内へ充填して後、他の異種原料のための隙
間を設けようとする側から一方加熱を行ない、少なくと
も境界になる部分にりいては加熱融着仕上げをなした後
、暫時型開きせずに発泡圧がなくなるまで放置し、次い
で成形型を所要間隔だけ開いて境界になる部分側に隙間
を設け、該隙間内に前記原料とは異種になる原料を充填
し、該異種原料の充填側から一方加熱をなした後、これ
とは逆方向から一方加熱を行ない、さらに両面加熱をな
した後、保熱、冷却を行ない、全体が一体に融着vt形
された同時成形品を得ることを特徴とする異種原料によ
る同時成形方法01. In the method of obtaining a foam molded product by filling the cavity of a U-shaped mold with a raw material consisting of a foamable thermoplastic resin layer and particles, and heating and expanding the raw material with a heating medium such as steam, the first step is After filling the raw material into the mold cavity, heat is applied from the side where a gap for other different materials is to be created, and at least the boundary area is heated and fused, and then heated for a while. The mold is left unopened until the foaming pressure is exhausted, then the mold is opened by the required distance to create a gap on the boundary side, and the gap is filled with a raw material that is different from the raw material, and After heating on one side from the filling side of the raw material, heating on one side from the opposite direction, then heating on both sides, heat retention and cooling, and simultaneous molding where the whole is fused into a VT shape. Simultaneous molding method using different raw materials characterized by obtaining a product 0
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56187603A JPS5889329A (en) | 1981-11-20 | 1981-11-20 | Simultaneous molding by different materials |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56187603A JPS5889329A (en) | 1981-11-20 | 1981-11-20 | Simultaneous molding by different materials |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5889329A true JPS5889329A (en) | 1983-05-27 |
Family
ID=16208994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56187603A Pending JPS5889329A (en) | 1981-11-20 | 1981-11-20 | Simultaneous molding by different materials |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5889329A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5546963A (en) * | 1978-09-29 | 1980-04-02 | Sekisui Plastics | Simultaneous moldings by raw material of different kind and their preparation |
-
1981
- 1981-11-20 JP JP56187603A patent/JPS5889329A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5546963A (en) * | 1978-09-29 | 1980-04-02 | Sekisui Plastics | Simultaneous moldings by raw material of different kind and their preparation |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3220902A (en) | Laminated container forming method and apparatus | |
JPS5855897B2 (en) | Simultaneous molding method using different raw materials | |
JPS5856337B2 (en) | Simultaneous molding equipment using different raw materials | |
JPS5889329A (en) | Simultaneous molding by different materials | |
JP3815084B2 (en) | Manufacturing method of in-mold molding die having uneven pattern | |
JPS6040372B2 (en) | Method for manufacturing simultaneous molded products using different raw materials | |
JP3189377B2 (en) | Molding method of foamed synthetic resin molded product | |
JPS5923549B2 (en) | Simultaneous molding method using different raw materials | |
JPS5829728B2 (en) | Simultaneous molding method using different raw materials | |
JPH10193375A (en) | Foam resin molding machine and foam resin molding method | |
JPS631529A (en) | Manufacture of polyolefin resin foamed molded material and mold | |
JP6247016B2 (en) | Bubble sheet, method for producing the same, and method for producing insulated food containers | |
JPH065159Y2 (en) | Polystyrene foam molding | |
JPH038585Y2 (en) | ||
JP3022621B2 (en) | Foam synthetic resin assembly box | |
JPS6054855B2 (en) | Method for manufacturing composite foam molded product | |
JPS6315138B2 (en) | ||
JPS589741B2 (en) | Simultaneous molding method and device using different raw materials | |
JPS6215165Y2 (en) | ||
JPS5812853B2 (en) | Double molding method for foam molded products | |
JPH0535672B2 (en) | ||
JPS5910296B2 (en) | Simultaneous molding method using raw materials with different materials and expansion ratios | |
JPS62242524A (en) | Manufacture of foaming resin molded product with skin | |
JP2001018250A (en) | Composite molding of synthetic resin | |
JPS58171946A (en) | Foamed resin shape |