JPS58132100A - Detergent composition - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention provides a method for achieving superior cleaning power and optionally good fluorescent brightener efficacy and (1 fF,
, is a field that provides foam control and (11 light) corrosion inhibition.
1 active agent combination Kll. The composition of the fence can be in pill or non-elite granular or liquid form and can contain the usual auxiliary ingredients commonly used in this eaom anastomosis.

The surfactant Aldal I lidaricoside is described in U.S. Pat. No. 3,598,865, $13.721.63.
No. 3 #4 #l and No. L77! , No. 2H@Details. These patents cover alkyl 4 glycosilyl
Also disclosed are methods for making surfactants and complete liquid detergent compositions containing these surfactants.

1 rice! ! Patent No. 111!1,219.6s11@specification discloses 7% 7glucosyP and suggests its utility as an O foam stabilizer for gloss and other surfactants.

The structures of various 4-glycosylated surfactants and their production methods are described in U.S. Patent No. 3.840.998, 113.
, 839,318, 3,314.936, 113,346.558, 4.011
．． No. 389 and No. 4.22L129.

SUMMARY OF THE INVENTION The present invention relates to the discovery of a species combination of surfactants that provides very good cleaning power on a variety of fabrics, especially in cold water. In detail, the present invention is (9 formula % formula % () [wherein the wing is alkyl, kP oxyalkyl, aldarpheel, and fPaPa oxyalfurferal dalpenzyl or a hot metal derivative thereof (the aldal group marked with # is 4) 1" has 2 to 18 carbon atoms); 4) 1" has 2 to 18 carbon atoms
having about 4, preferably an ethoxyle group, pro I xy, 1
9 is a glycanyl group, and 1 is O to about 90%;
And each Z company carbon a519 has a 6-reduced alkyl polysaccharide (alkyl polysaccharide, Karai P) detergent surfactant rigid 1- to about 90-1 (no nonionic detergent surfactant Rigid 1- to about (4)-1 and (3) Washing capilgoo 0% to about 9011I ((1)
to (2) is from about 1:10 to about 10:1, preferably from about 3:1 to about 1:3).

A highly preferred variation is an anionic fluorescent brightener (optical brightener) from about 0.01 to about 2. Contains % O.

In another highly preferred V% engraving, the non-ionic anti-agent surfactant is selected from the group consisting of amine oxidized detergent surfactants, ado detergent surfactants and combinations thereof; The group Flt contains about ls to about 10 g II of unsaturated groups having from about 16 to about 4 carbon atoms.

and preferably synthetic anionic detergent surfactants on ~
Contains about 1096 in history.

It has been found that particularly one co-surfactant interacts with the Aldal IIWI agent of the present invention to provide good laundering detergency on a wide range of fabrics. Alkyl polysaccharides include polysaccharides having from about 6 to about 16 carbon atoms, preferably from about 10 to about 16 carbon atoms, and most preferably from about 1.6 to about 2.7 carbon atoms, such as polysaccharides having from about 1.6 to about 2.7 carbon atoms. /
Fe)llll water diet.

Any reducing sugar having a carbon number of 5 to 6 can be used,
For example, glucose moieties, I-lactose moieties and I-lactocles moieties can be used in place of glucosyl moieties (optionally the hydrophobic groups are attached at the 2-, 3-, 4-, etc.-positions, and thus the glucoside or galatatosi P as / lucose gives galactose)
, for example, one position of the additional shield unit and the anterior O1
The 2nd, 3rd, 4th and (i9) positions one unit above can be in conjunction with the 6th place.

In some cases, it is possible, although undesirable, to have freal;xy P chains attached to the hydrophobic moiety and the polysaccharide moiety. Preferred alkoxy P is ethylene oxyW
It is. Typical hydrophobic groups include, for example, about 8 to about 18
, preferably having about 10 to about 16 carbon atoms, is an unsaturated branched or unbranched alkyl group. Preferably, the alkyl group is a straight chain saturated alkyl group. The alkyl group can contain up to three hydroxyl groups, and (i9 is)I
I! The alkoxy r chains contain up to about 10 alkoxy r moieties, preferably less than 5 gM, and most preferably 0-. Good luck Alkyl multi-one is Octyl, Noelde V
ru, kundecil dodecyl, tridecyl, nato2 decyl,
Pentadecyl, hequinadecyl, to! Tadecyl, and Octadecyl's Gee, Tory, Tetra-1 Be/Tar, and to! Lukoshi r1 Zarakkoshi P1 Lukoshi? , dulcose, fructocyto, fructocyto, and/or galactose. Suitable hot metals are, for example, coconut alkyl di-, tri-, tetra-1 and penta-glucosides and tallow alkyl tetra-, penta-, and hex-t/lucito.

Preferred alkyl 4-glycosylation P has the formula R”O(CmB
g+10) t(glycodyl) preferably from #12 to about 14); l is 2 or 3, preferably from about 3, most preferably from about 1.6 to about 2.7. Glycodyl is preferably -4 derived from glucose. For those who want to generate compounds, first of all,
Glucose is then reacted with a source of dulcose to produce Ilucosy (linked at the 1-position). Additional guso-cosyl units with their 1st place and wi.

/IJ cosyl unit 2nd, 3rd, 4th and (9th)
The 6th position, preferably primarily the bond with the 2nd position, is broken.

Preferably, the alkyl monoglycoside loading is low, preferably less than about 60%, and more preferably less than about 58%.
less than.

Surprisingly, 1 normal ethoxylated nonionic detergent world w/
Anionic fluorescent brighteners, which are usually relatively ineffective in the presence of phosphorescent agents (in large amounts in the absence of substantial amounts of anionic detergents FP surfactants), When present, it is very effective.The effectiveness of the brightener is determined by the ratio of alkyl glycol detergent surfactant to nonionic detergent surfactant to non-ionic detergent surfactant about 1:4.
, preferably greater than about 1:3, most preferably about 1=4 greater than 1.

Nonionic surfactants, such as those having an I (Lm) of about 5 to about 17, are well known in the art of cleaning.

A nonionic surfactant may be incorporated into the composition of the present invention, for example, with the alkyl 4-ligusicoside surfactant. Nonionic surfactants useful alone or in combination with one or more of their preferred alcohol ethoxylate nonionic surfactants are useful in combination with alkyl glycosides. The proboscis is blocked by preparation. Examples of surfactants of this type are US Pat.
No. 17.630, and U.S. Patent No. 3.832.
Non-limiting examples of suitable non-ionic surfactants that can be used in the Ohon Yamei described in the '880 specification are as follows.

(1) 4-reprocessing of alkylphenols
PJII Compounds These compounds are, for example, condensates of aldarphenols with ethyleneoxyr having an aldal group with about 6 to 12 noble atoms in either configuration of the branched chain ( The aldal substituent within this compound can be removed, for example, from polymerized zolopyrene, diisoptylene, etc. An example of this cypress compound is nonylphenol 14L #IA71) about 9.5
Combined with ethylene oxide in the basket, nine nonylphenol:
P-decylphenol condensed with about 12 moles of ethyleneoxy P per mole of phenol; dinonylphenol condensed with about 15 moles of ethyleneoxy P per mole of phenol; and about 15 moles per mole of phenol. It is diisooctylphenol combined with ethylene oxide. Non-Ioyl'l that can be obtained from this company's business.
#The active agent is, for example, Ig@pal Co-630, marketed by GAF Co., Ltd.
7 (Trtt*m)X-
45,! -114, X-100 and X-102.

(- Condensation product of an aliphatic alcohol with about 1 to about δ moles of ethylene oxide 81t Group II al; - The alkyl in the alkali is either direct or branched, primary or secondary; and generally have a mole number of from about 8 to about n. An example of an ethoxylated alcohol in this context is one ester of listyl alcohol combined with about 10 J&l of ethylene oxide per mole of alcohol;
and -coalescence of about 9 moles of ethylene oxide with coconut alcohol (a mixture of fatty alcohols having an alkyl chain length of 10 to 14 carbon atoms). An example of this type of nonionic surfactant available is Union Carr/
Tergitol (T@rglryu@1) 15-8-9, marketed by Kando Co., Ltd., Neodol (N*edel) 45-9, marketed by Shell Chemical Kanno (nee), Neodoll 23-
6.5% Neodol 4B-7, and Neodol 4T]
, and Kyro EDl, marketed by Z.O.
It is l.

(The condensation of the hydrophobic base produced by the condensation of propylene oxide and propylene glycol with ethyleneoxy P - The hydrophobic part of these compounds is approximately 150 () - 1800
The addition of an O/lyoxyethylene moiety to this hydrophobic moiety, which has a molecular weight of The liquid properties are maintained at a point where the polyoxyethylene content is about 5011 of the total weight of the mixture (about 8 equivalents for condensation with up to 1 mole of ethylene oxide). An example of this complementary compound is Zollonik (P1wr+eml@) surfactant, available over $11#l, commercially available from Wyandotte Chemical Knee Fourage Carbon.

(4) A combination of ethylene oxide and the product produced from the reaction of propylene oxide and ethylene diamine. The hydrophobic portion of these products consists of the anti-56 product #yt- of ethylene diamine and propylene oxide in the beak; It has a molecular weight of about 2500 to about 5 ooo. This hydrophobic moiety is condensed with ethylene oxide to a degree where the condensation contains from about 10 to about 4 lyoxyethylene and has a molecular weight of from about s,ooo to about 11.0000. An example of this type of non-ionic rk Jr II agent is the Tetronic (T@tr
・1]) It is a compound.

(5) The bovine polar nonionic detergent surfactant has - one alkyl moiety having approximately 10 to L8 carbon atoms and 1 to approximately 3 carbon atoms;
and hydroxya.

alkyl group; one alkyl moiety having a carbon bulk number of about 10 to 18; and an alkyl group having about 1 to 3 carbon atoms; A water-soluble host containing two moieties selected from the group consisting of alkyl groups; and one alkyl moiety having a moiety of about 10 to 18 and carbon 116#1
A water-soluble sulfoxide containing one moiety selected from the group consisting of -3 aldal moieties and hydroxyalkyl moieties.

Preferred semipolar nonionic detergent realm rMffi agents have the formula (
In the formula, 8 is an alkyl group or hydroxyalkyl group having a longitudinal bulk of about 8 to about ρ, 9 is an aldal 7-El group, and 14 is a mixture thereof, and 14 is an alkylene group having 2 to 3 carbon atoms or a hydroxyalkyl group. A dialkylene group is a mixture thereof, and each R6 is an aldal group having from 1 to about 3 carbon atoms, and 9 is a hydroxyalkyl group or a hydroxyalkyl group. The R group is an ethyleneoxy P group containing about 3 ethyleneoxy P groups, and the R group is an amine oxy P group having, for example, oxygen atoms ★9 can be bonded to each other through a nitrogen atom to form a ring structure. It is a cutting interface activator.

Detergent world rMrI for preferred electronics! Class I agents are C
3°, 1. Alkyldimethylanoxide, CI, J
diethylamine oxy rSsr in l alkyldihyfa
"C), 1□alkoxyethyldihyde tetraxyethylamineoxy P.

Nonionic detergent surfactants (1) to (→ are ordinary ethoxylated nonionic detergent surfactants.

Preferred alcohol ethoxylate nonionic surfactants for use in the compositions of the present invention are biodegradable and have the formula % (% formula %), preferably from about 8 to about n1. primary or secondary alkyl chains of from about l[theta] to about +, and having an average number of from about 2 to about 12, particularly from about 2 to about 9. The nonionic surfactant has an at, m (II water aqueous lipophilicity) of about 5 to about 17, preferably about 6 to about 15. Agents'' (Marshal Detsker Inc. I Ratetsu IF, 1966, II 606 true-1
11613j()K detailed. In preferred non-ionic field 1fi activators, the number of graves is 3-7. Low-grade linear alcohol ethoxylates (e.g., alcohol ethoxylates produced from organic alcohols containing about 20-2-methyl fractional isomers, commercially available under the tradename Neodol from Shell Keckal Campfuni) Preferred from a performance standpoint.

Preferred nonionic surfactants for use in the compositions of the invention include, for example, the condensation of C1 alcohol with 3 moles of ethylene oxyto; the condensation of tallow alcohol with 9 moles of ethylene oxyP. product; linear product of coconut alcohol and 5 moles of ethylene oxy P; condensate of coconut alcohol and 64 moles of ethylene oxide; C18
Compound of alcohol and 5 moles of ethyleneoxy P; C
A combination of 12-1° alcohol and 6.5 moles of ethylene oxide, and the same combination stripped to remove substantially all lower ethoxylated and non-ethoxylated hookions; C alco 1! A condensate of S41 and 2.3 moles of ethylene oxide, stripped to remove substantially all of the lower ethoxylated products and non-ethoxylated hooks; C1! ~1. alcohol and 9 moles of ethylene oxyr
Combination of C14-%41 alcohol and 2.2 s mol of ethylene oxide; C alcohol and 4 mol of ethylene oxide 14-II and O-compound; C alcohol and 7 mol of ethylene oxide ~IS combination with Chirenohinoshito; and CI4~1. It is a combination of alcohol and 9 moles of ethylene oxide.

The compositions of the present invention can contain mixtures of preferred alcohol ethoxylate nonionic surfactants and other types of nonionic surfactants. One of the preferred nonionic surfactant mixtures contains at least one of the preferred alcohol ethoxylate nonionic surfactants and the preferred alcohol ethoxylate surfactant(s) versus the other nonionic surfactant. The active agent(s) have a ratio of 1:1 to about 5:1. Examples of surfactant mixtures useful in the present invention are C14-1. A mixture of alcohol and 3 moles of ethylene oxide (Neodol 45
-3) and a condensate of C alcohol and 9 moles of 14 to 1S of ethyleneoxy P (Neodol 6-9)
The ratio of lower ethoxylate nonionic surfactant to higher ethoxylate nonionic surfactant with 1 = 1 to about 3
: Warm mixture of 1: A mixture of C1 alcohol and 3 moles of ethylene oxide, and a condensate of secondary C1, allol and 9 moles of ethyleneoxy P (Targitol 1511
) of a lower ethoxylate nonionic surfactant to a higher ethoxylate nonionic surfactant in a ratio of 1=1 to about 4:1 mixture; Neodol 45-3 and Tergitol t
Ratio of lower ethoxylate nonionic surfactant to higher ethoxylate nonionic surfactant with s-g-t'
: a mixture of 1 to about 3=1; and Neodol 45-3
and a condensate of lysyl alcohol and 10@4 ethyleneoxy P in a ratio of 1:1 to about 3:1 of lower ethoxylates to higher ethoxylates.

Preferred nonionic surfactant steel compounds also contain aldal glyceryl ether compounds along with the preferred arsul ethoxylate surfactants.

formula % formula % (wherein C is about 8 to about 18 carbon atoms, preferably about 8 to 1 carbon atoms)
The aldal group of 2 is an alkenyl group which is an alkaryl group having about 5 to 14 carbons in the alkyl chain, and the latter is an alkaryl group having about 5 to about 6 carbon atoms in the alkyl chain) and the sylate compound in the preferred alcohol ethyl alcohol. alcohol ethoxylate to daliceryl ether ratio l:1
A mixture of about 4 to about 7:3 to IS% is highly preferred.

Glyceryl ethers of the '&sI class useful in the present invention are disclosed in US Patent No. 4,09L713.

The ratio of the alkyl/9/licosyl detergent world IfI #i to the nonionic detergent world rfJrII is about 10=1 to about 1:1O, preferably about 3:1 to about 1:3. .

The detergent composition of the present invention has a cleaning capacity of about 9
0%, preferably from about 5 to about 51)-1 l! It preferably contains about 10 Is to about 351 Is. This builder may be, for example, of the formula % (wherein and y are at least about 6, the 2 to 1 molar ratio is from about 1.0 to about 0.s, and X is about lθ
~about 264. ) is a crystalline alinosilicate ion exchange material.

Amorphous Hydrated Aluminosilicate Materials Useful in the Invention Empirical Formula % Formula % (Formula %) (% Formula %) (% Formula %) (% Formula %) (% Formula %) where 9 is substituted ammonium, sodium, potassium, ammonium, and l is from about 0.5 to about 2, and 1 is l), and the substance has the following formula: 1g of anhydrous alkinosilicate
aC01 Hard Length At least about 50cm Lidarum Mushi amount! Daneshikum has ion exchange capacity.

Alinosilicate ion-exchange pill I-Fi *If in hydrated form and crystalline, it contains from 10 to about 100 kg by weight, and in the non-9i form, it is commonly found to contain even more of water. Highly preferred crystalline aluminosilicon ions containing #IJ contain tSS ~ about n- within their crystalline matrix. Preferred crystalline aluminosilicate ion exchange materials have a
[K% is characterized by a grain liK of about 101 Kron.

Amorphous materials are often even smaller, e.g. less than about 0.01 microns, *Preferred ion-exchange materials are
Particles having a particle size of about 0.2 to about 4 mS, herein referred to as 1 particle size, can be measured using conventional analytical techniques, such as scanning electron JS values. Write down the average particle size of a given ion conversion substance measured by a standard method. The crystalline aluminosilicate ion exchange material has an aluminosilicate ion exchange material of at least about 200 liters, calculated on an anhydrous basis.
+g,・υj~about 35 sites・q/g 0lll! It is usually further characterized by its ossium ion exchange capacity. Alinosilicate ion exchange - actually extracts at least about 2 dalenes (+47 gal/min/1/gal alkinosilicate (ml water basis), generally about 2 g/gal/gal based on calcium ionic hardness) It is further characterized by a calcium ion exchange rate fK that is within the range of about 6 grains/kg/min/g/gal. Aluinosilicate of choice for pilgy is at least about 4 grains/gal/min/g/gal. Calcium ion exchange rate of 1 ron/min/1/gal is shown.

The amorphous alinosilicate ion exchange material typically contains at least about 5 (hug * q CaCO5/g (12 m
g M4-1) -” exchange capacity and at least about 1
It has a 0 exchange moderation of gren/fron/min/g/galen. Amorphous substances have cwjl rays (units of 1,54 mm)
(Thus, it does not show an observable diffraction pattern in the case of -9.

Alinosilicate ion exchange materials useful in the present invention are commercially available.Alinosilicates useful in the present invention can be amorphous in structure;
And it can be a natural type of alkanosilicate, and it can be a synthetic KJ1.

A method for making aluminosilicon salt ion exchange materials is disclosed in U.S. Patent No. L985.669.

Preferred combinations useful in the present invention! IKM crystalline arunnosilicate ion exchange material has the names Zeolitem, Zeolite P (
B)% and Zeolite X.

In a preferred embodiment, the crystalline aluminosilicate ion exchange material has the formula % where X is about n from about I% to about I%41.

Another example of a detergent agent is a water-soluble neutral alkaline salt.

Other useful water-soluble groups are, for example, the compounds commonly known as detergent compounds. ♂ Rule I- generally comprises 4) species of water-soluble alkali metal, ammonium dimer or substituted ammonium phosphates, polyphosphates, phosphonates, polyphosphonates, sulfates, silicates, selected from borates, polyhyroxysulfoates, polyacetates, carboxylates, and 4-lycarponates. Preference is given to the alkali metal salts of said substances, especially the sodium salts.

Specific examples of inorganic phosphorus are tripolyphosphates, birophosphates of sodium and potassium, ca.
A 4-molecule metaphosphate with a compound #4r of 21, and an orthophosphate. 4 Rephosphonate building! - Examples are the sodium and potassium salts of ethylene-1,1-diphosphonic acid, the sodium and potassium salts of ethane-1-hydroxy-1,1-diphosphonic acid, and the sodium and potassium salts of ethane-1,1,2-triphosphonic acid. Sodium and potassium salts. Other Rinpilgoo compounds are disclosed in US Pat. No. 3,159,581, No. 51,213,110.
Specification No. 30, I@3.422.021 Mei S*, No. 3
．． 4!2.187 Specification, No. 3.400.176@
#dll and Maki 3.400,148.

Phosphorus-free llI4 Iso Pilgoo moth is sodium and potassium charcoal salt, 1 [charcoal fillX! i, cessed acid 1
, western borate decahydrate 1, and 810. Molar ratio of alkali metal oxide to 0. S to about 4.0, preferably about 1
．． 0 to about 2.41-.

Examples of the water-soluble non-containing aliiso building materials useful in the present invention include polyacetates, carboxylates, 4-carboxylic acid salts, and I-hydroxysulfone t'*tx of alkali metals, ammonium, and substituted ammonium in each building. It is. I vinegar#
! Salt pill! - and polycarbonlIl! Examples of Danvirgoo are ethylenediamine monoacetic acid, nitrilotriacetic acid, oxydisuccinic acid, mellitic acid, benzene Ilicarponic acid,
and sodium salts, potassium salts, lithium salts, ammonium salts, and substituted ammonium salts.

A highly preferred 1-pyl 4-carboxylic acid in the present invention is described in U.S. Pat. No. 3,308,067. itaconic acid, mesaconic acid, fumaric acid,
It is a water-soluble compound of polymers and copolymers of aconitic acid, ntraconic acid and methylenemalonic acid.

Other builders are, for example, rice 11% pigeon 3.723.822
It is a carboxylated hydrocarbon with a name of 1.

Other builders useful in the present invention are sodium, cyclopentanetetracarboxylic acid, and logglucinol trisulfone! Salt, water-bathable polyacrylic acid (e.g. approx.
．． 000 to about 200,000), and co-enriched salts of maleic anhydride and vinyl methyl ether or ethylene.

Other 4-recarboxylic acids suitable for use in the present invention are:
4 described in the specification of US 1ji1 tatami 1 FF Maki No. 4,144.226 and the US TS license @4,246.4 No. #4-
Reacetal carbon t#1m. These 4-lyacetal carboxylates can be produced as follows! For this purpose, an ester of dalioxylic acid and a polymerization initiator were added under polymerization conditions, and then the resulting I-lyasecur carboxylic acid ester was chemically bonded with a defined terminal group to form a 4-lyacetal carboxylate in an alkaline solution. Stabilizes against rapid 11s in the tlK of the opposite
Convert and add to surfactant.

Other cleaning power C-based substances useful in the present invention include the "species e-L"-
” composition. A specific example of a seed builder mixture of this type is a 3:1 mixture of sodium chloride and calcium carbonate having a particle size of 5 cm; I? 2. Sodium legate and leg calcic foot.
A 7:1 vt mixture and a 3:3:1 vt mixture of sodium carbonate, sodium aluminate and calcium oxide with a particle size of 5 cm.

Other Ingredients In addition to the above-mentioned essential detergent surfactants, this
The i11 composition is an organic surfactant selected from the group consisting of anionic surfactants, zwitterionic surfactants, amphoteric surfactants, cationic surfactants, and combinations thereof. The raising W activators useful in the present invention can contain from about 2 to about 8 Is. 11
1g3.4! $64,9811QliJI book &! and US Pat. No. 3,919.1B7@. Additionally, useful cationic surfactants are described, for example, in U.S. Pat. No. 4,222,90S and U.S. Pat.
There is also a note on issue 39.659 @ #4KIe4 [).

The following are representative examples of surfactants useful in the present compositions.

High @! II Fatty acid soluble salts, that is, "soap" are
It is an acid ionic surfactant useful in JIIItIII.

This includes alkali metal soaps, such as sodium, potassium, ammonium salts, and alcohol salts having about 8 to 18 carbon atoms, preferably about 12 to about 18 carbon atoms. 0 soap can be produced by direct saponification of fats and oils or by neutralization of fats and oils. Particularly useful are the sodium and potassium salts of fatty acids derived from coconut oil and tar, ie, sodium or potassium tallow and coconut soaps. 4! The preferred soaps described above and below in combination with semipolar or afrionic detergent surfactants are at least partially unsaturated.

Unsaturated Soaps The unsaturated fatty soaps of the present invention preferably have a KW prime number in the linear configuration of from about 16 to about n. The number of carbon atoms in unsaturated fatty acid soap is about 16 to about 18.

Unsaturated soaps, like other anionic detergents and other anionic materials within the detergent compositions of the present invention, have cations that make them water soluble and dispersible. Suitable cations are, for example, the cations of sodium, potassium, ammonium, monoethanolammonium, diethanolammonium, triethanolammonium, tetramethylammonium. Sodium ions are preferred, but in liquid formulations ammonium,
and triethanolammonium cations are useful.

An amount of at least about 1 - of unsaturated fatty acid soap is desirable to provide a modest reduction in sudsing and corrosion; preferred amounts of unsaturated fatty acid soap are from #1 to about 15-1, preferably 11.
．． <Hame 1- to about 10111i, most preferably about 2-
~about 5-. Unsaturated fatty acid soap is used for washing 1 [K#15pp ugly~
about 200 ppwz, preferably about 25 ppm to about 125
It is preferably present in an amount that will provide a ppm of about 1,000 ppm, and for example, from about 30 ppm to about 100 ppm, preferably from about 60 ppm to about 5 ooppm, for all levels.

Since seven-, -mono-, and tri-unsaturated fatty acids are all essentially equivalent, it is preferable to use monounsaturated soaps as raw to minimize the risk of RAII & the preferred unsaturated fatty acids. Such sources are well known, e.g.
See Bay 9's Industrial Conflict Oil, Engineering, P., Fat Products, 3rd Edition, Swarn, Interscience J. Zurirasha Publishing (1984, etc.).

Preferably keep the amount of saturated soap as low as possible, preferably about 601 of gold soap! less than, preferably about 501
Less than 1 is saturated soap. However, using a small amount of saturated soap will help. You can use Tayo-soap and Δ-goo oil.

Useful synthetic anionic surfactants include, for example, latent salts of organic sulfuric acid reaction products having in their molecular structure an alkyl group of about 10 to about 10 carbon atoms and a sulfonic acid ester group; Preferred are alkali metal salts, ammonium salts and alkylolamphentium salts.

This type of synthetic ion cleaning world rIJ activator increases the cleaning effect on the metal body and, if desired,
About 111 to about toIJ to increase 11! It is a toughening agent that is 100% thick in the amount of
acyl group O aldal moiety).

Examples of synthetic surfactants in this review include aldal sodium phosphate and potassium alkyl sulfate, and alcohols (carbon numbers c, -c, etc.), such as tallow, glycerin P, and chili oil. By this I was born.
and the alkyl group having from 9 to about 1 carbon atoms in a straight-chain or branched configuration.
Sodium aldarbenzenesulfonate and calicum alkylbenzenesulfonate having 5, eg, U.S. Pat. t2D, No. 099 1 nai book and No. L477
．． No. 383 @ OSm listed in the specifications. Bell-shaped linear alkyl heptaacid sulfonates, abbreviated as C11~, LAW, having an average number of carbon atoms in the alkyl group of about 11 to i3, are particularly valuable.

A preferred dazzling ionic detergent surfactant is alkyl 4-liethyl
? S/rate T tulfate, the number of alkyl molecules in the back is about W
~n1 preferably has about 1 to about 18 ethoxylate moieties; be. It is desirable to formulate liquid detergent compositions for these anionic detergents.
Other anionic surfactants include sodium alkyl glyceryl ether sulfonates, especially ethers of higher alcohols derived from linden and coconut oil; sodium coconut oil fatty acid monoglycerides P sulfonates and coconut oil fatty acid monoglycerides. Sodium sulfate; approximately 1 per molecule
An aldalphenol containing about 10 units of ethyleneoxy P and having an alkyl group of about 8 to about 8 carbon atoms [or potassium salt; Contains about 1 to about 10 units of ethylene oxide and has an alkyl group of about 10 to about 10 carbon atoms
Sodium tJ [or potassium nitrate] is a cytoether in alkyl ethylene with the addition of about 30%.

Other ionic surfactants useful in the present invention include 6 to 20 carbon atoms in the fatty acid group and KR in the ester group.
Water-soluble salts of esters of 1-sulfonated fatty acids having a prime number of about 1-10 2-acyloxy-alkane-1-sulfones having from 2 to 9 carbon atoms in the acyl group and from about 9 to about xtv carbon atoms in the alkane moiety Water-dissolvable salts of acids; alkyl ether nalphates having about 10 to 10 carbon atoms and about 1-(9)7 ethyleneoxy P in the alkyl group; water-soluble olefin sulfonic acids having a prime number of about u to 0. salt; and has 1 to 3 carbon atoms and an alkane subcircle Km prime number of about 8 to 20 in the alkyl group! -alkyloxyalkanesulfonate.

Amphoteric surfactants may be used, for example, in which the aliphatic moiety is linear or branched, and one of the aliphatic substituents has 8 to 1 carbon atoms.
8 and in which at least 41 aliphatic substituents contain subionic water-solubilizing groups. A tertiary aliphatic conductor and a 4-zwitterionic surfactant is, for example, an aliphatic JII No.
It is a derivative of the No. 1 Nikufu compound.

Particularly preferred cosurfactants in the present invention include, for example, linear alkylbenzene sulfonates having an enzymatic number of about 1 to 14 in the alkyl group; tallow alkyl sulfates; coconut alkyl glycanyl ether sulfonates; -18 and an average degree of ethoxylation of about 1 to 4; olefin sulfonates having a carbon number of 14 to 16;
aldaldimethylammonium zoloA sulfonate and alkyldimethylammonium and P-roxyzoloA sulfonate having xn about 14-18.

Preferred surfactants for use in the present invention include, for example, C alkyl I ethoxylate-4-II sulfate, C alkyl heptaacid 1-S
! 91 toxylate, ~, potassium sulfate, C14~1. Furkyl polyethoxylate, ~, (II! Acid monoethanol ammonium” 14, II, Furkyl polyethoxylate,
~, am jetanol ammonium and CI4-8.
Alkyl I ethoxylate. ~, triethanolammonium sulfate; --like C11-1, alkylpe/zenesulfonate sodium; C11, □, alkylbenzenesulfonate triethanolane; sodium tallowalkyl sulfate; rudaliseryl ether sulfone esf tricum in coconut oil; ter-alcohol and ζ Approximately 4 moles of ethylene oxy r and OiI! Sodium salt of oxidized condensate; 3-(N.

5
-(N,)i-dimethyl-N-coconutual)! 4-1-sulfonate; 6-(N-dodecylbenzyl-N,N-dimethylammonio)-hexanoate; and coconut alkyl? It is methylamine ζ-oxygen VP.

Established on the technical paddle nine normal usage amounts (i.e. 0 to about 9011
) may be incorporated into the compositions of the invention, such as solvents, cupronickel, bleach activators, soil suspending agents, corrosion inhibitors, dyes, fillers, optical brighteners, These include additives, pH adjusters (sodium ethanol, sodium chloride, and sodium hydroxide), enzymes, enzyme stabilizers, fragrances, fabric softening ingredients, and static electricity control rules.

The fatty acid apfk agent surfactant useful in the present invention is, for example, a d-formula % formula % [wherein R6 has a carbon number of about 7 to about 21 (preferably a carbon number of about 9 to about 21]).
17) and each R7 is hydrogen, C8_4 alkyl, C1_4 hydroxyalkyl and -(C,H40)! selected from the group consisting of H (where true is about 1 to about 3).

Preferred ands are C an-nia and, s~30 heptanoethanolammonium, jetanolamine P and isopromenolamide.

The significant advantages of the detergent surfactant steel combination of the present invention are:
Excellent compatibility with anionic fluorescent copper brighteners or optical brighteners. Nonionic surfactants, especially ethoxylated nonionic detergent surfactants, usually reduce the effectiveness of this cypress brightener. Alkyl 4! When adding Rikosi P surfactant, the effectiveness of the brightener, especially on cotton, is dramatically improved. The optical weight stiffness ranges from 0.01 to about 2, preferably about 0.
1 to about 1- can be used.

Suitable brighteners include, for example:

Formula [wherein M is preferably Na, but also includes compatible cations such as potassium, ammonium, substituted ammonium,
For example, monoethanol amphibian ecum? ethanolammonium, triethanolammonium, etc.;
~4 alkyl, ~4 dialkyl) morpholino, hifa lifeshi; can be a mixture thereof; and wing a
In the above structural formula, R and X are as follows.

-NHCH,CI, #-NHC
H,CHOHCH,a-? JHC11140H# -N(CIls)CI! IC1,oHl-NlIC,H
,QC Town I-1”JHClB,OHa -NHC!lI40CH,# -〇H# -NHC,H40HNa0,8-, ”, -NH-\
,〆/1 (Decoy, α8)-C〉-Crows0-訃○倚-AnotherO brightener is,
4.4'-Bis[(4#-bis(τ''-Fudiethylamino-6'-(3''-sulfenyl)a-1',3',5'-)Ryazine-2 '-(ru)amino)-2,2'-tetrasodium stilbendisulfonate;
4-(6'-sulfonaphtho(1',!',l))lyazol-2-yl)-2-stilbenesulfonic acid disodium; middle siethyl aa])-6I'-anilino-1"*3'*
s'-) riazine-21-(#)7(1)-3,3'-
Stilbene? SulfoyWR disodium; 4e4'-
bis((4'-(2”'-hifaxietogoshi)-6
#-A quality no 1#, 3#.

5'-)riazin-21'-yl)amino) -2,2
'-Stilbene disulfonic acid disodium; 4*4'-
Bis(4-phenyl-1,L3-)lyazol-2-yl)-2,2'-stilbendisulfonic acid disodium; 4-(!H-naphtho(1,2-41)lyazol-2
-il)thben-2-sulfonesodium; disodium-4.4'-♂su(l-xle$xchilis,,
)ty Dimethoxybenzami I
P)-2,8-dibenzothio7ene disulfonate 1.
It is 5-dioxyP.

Lun O suitable *Self-enhancing agent is US tS% approval No. 3.537.911
No. 3 and No. 1113,953.38 (I).

The present composition can be prepared and used in various forms such as enclosures, powders, granules, pastes, and liquids. The parent proboscis in water is about 0.01-1 to about 1-1 preferably about O, OS* to about 0.5-1 most preferably about O,
The composition can be used in a washing machine by preparing an aqueous solution containing OS*~0.25 and stirring the soiled fabric in the aqueous solution.Then the fabric is rinsed; And let it dry. When used in this manner, the preferred compositions of the present invention exhibit very good detergency on a variety of fabrics.

In a preferred embodiment, the fluid bed detergent, preferably an aqueous heavy duty liquid, contains (a) an Aldal I Ridalikoshi P detergent surfactant with a surfactant of 1 to about 200 g (preferably about 41
(b) amine oxy to about 1% to about 10% (preferably about 2% to about 6%) of the detergent surface activity;
(・) A water-soluble soap sac of unsaturated fatty acids having a vertical prime number of about 16 to about 4 to about 1011 (preferably about 1 to about 6
1); (d) a water-soluble detersive power pill preferably selected from the group consisting of biphosphate, nitrilotriacetate, and their hot combinations/-alG to about 40% (preferably about 10 to about 31%); ) li); (・) water-soluble synthetic anionic detergent surfactant from about 0 to about 10 (good IL< is from about 0 to about! S); and preferably (f) fi part water. contains.

Jin no Kasu detergent composition provides excellent cleaning power, unacceptable IiK will not damage the washing machine, and changing the amount and type of synthetic ion detergent surfactant and the amount of Fubai Kei soap It is formulated to give different foaming A-turns depending on the product.

Preferably, the barrier formulation contains about 6 to 4 more conventional ethoxylated nonionic surfactants.

The cations of sodium, potassium, ammonium, and alkanol ammonium are preferred.

All -1 parts, and the proportions are 411 by weight.

The following examples illustrate the present O compositions and methods.

Example l 500 - 9.415.4 L9400 100
6.415.5 4.6300 200 6.317
．． 1 7.1 goose 00 300 4.417.41 7.
1100 400 L716.3 7.1- 500
-0.315J 6.8 Test conditions: 95”P with mixed hardness R6 grain (approximately 3
5.0℃) water and ? =Washing Machine As can be seen from the above results, alkyl I-glycoside surfactants have unexpected problems in cleaning I-reesters. In general, alkyl-4 glycosides are considered to be an alternative to nonionic surfactants, but in particular they are nonionic surfactants, optimized for cleaning relatively hydrophobic surfaces. Use it in conjunction with what is said to achieve the ultimate result. The alkyl I in these FIJKs is extracted from glucose, and results similar to those of other alkyl glycosides described above are obtained.

Example 1 300 ppm Oppwa
1G240 ppm 60
ppwa 201@Oppm
120 ppm 270
PP-300ppm 17 III and Oka conditions As can be seen from the above data, alkyl I! While lycoside surfactants generally give poor results in cleaning relatively hydrophobic surfaces, mixtures of alcoholic surfactants with nonionic surfactants provide a synergistic effect.

Example: Maintenance of whiteness (redeposition test) aoo ppm 0 73
68 36240ppwa 60 74
70 391801pm 120 79
73 4060ppm 240 73
73 390 300 71 13
The 0.39 barrel is non-ferrous and can be used under the same conditions as Example I and the amount 0 rating is the average of the two pole stains.

As can be seen from the above data, there is a synergistic improvement in cotton re-deposition in the case of the surfactant network mixture.

Example ■ C11~11 C11~1m / Recotton to alkyl poly 1kQhtml! y menstrual blood stain removal soo p, ugly 0
50240 ppts
60 60180 ppm
120 6360ppr
m 24G 7G0 p
pm 300 63 non-female)
The unexpectedly poor performance of the alkyl 4 glycosides against this stain was modified depending on the used and mortaring ratio by the addition of a nonionic surfactant, as seen from the data above. I was hated, and (
Or) A similar improvement can be obtained.

Example VC Alkylpo 13~IS Ligri Hi/Todo 4” 12.7 21.2 26
JC1m-□, alkyl I ethoxylate 6. .

The ratio of 1.1 to 4 was added with nitrile trichloride (8TP) and sodium carbonate as builders, and the total composition was used in an amount of 1200 ppwa O.

Test conditions: 6o〒 (approximately 1s,
As can be seen from the above data, the mixed surfactant system of this @Sushi is more effective on various fabrics than the conventional ionic surfactant system. Therefore, FIAt9 provides excellent clay removability.

Example ■ Glycoside Ethoxylate 3 + Coconut Tos, i + Cocoal Alkyl Alkyl 2 In Oxyl Dimethyl A P Citrus Oxide (1:1) (1:1) I Riester 59,0 55.
2 Removal rate (arrogant) Dirt 9 Motor oil 3037 Chicolate syrup 9393 Glass (Orass) 67 7
1 Bacon Grease 5753 Menstrual Blood Stains 83 73 S/Archive Stains 5067 Duties Liquid (Conte +1.56 +1.70 l) Boricotton 8685 4 Liesdel 4639 Surfactant Mixtures 13 of the formulation It is sushi, and the ruder is sodium nitrilotriacetate (lon).
*The test sample has a composition of 2100 ppm, 95”F (approximately 3
5, ffC), mixed hard f6 Darren and nine.

Patre18eo
r・Units), and there is no difference for professional equals O;
The value is fixed at 1 based on the criteria of difference 1; clear difference 2.

Example - Non-Pilt HDL Performance of the Inventive Mass Non-Built Commercial Liquid Detergent Composition (HDL) for Commercial Products
4 Rieko chill dirty motor oil +Q, 3 +0.4 Bacon grease +1.0 +o, s meat juice +1.4 +0.2 Su/kump sauce +Q, 3 +
0.9 glass +1.7 +1
．． 5chi■ Colate Shirotsuzo -Q, 4
+o,s test conditions: 450 ppm of active ingredient, water at 9rF (approximately 3!S, 0°C) with a mixed hardness of 6 grains and mini-washing machine original @O malformation product: C11-1.1 in a ratio l:1. Silate in Ruliet in alcohol 3/' 1! +-11 Alkyl Luridarikoshi P, -1 Example ■ Part C1, ~8. Alkyl I Ridarikoshi P8~. 1
3.3C1,~1. Alcoholic acid lyetochelate,
Sodium IL3 tritetralyphosphate
12. ONSCos
13, 84 Liacetaldehyde Detergent Building〆-2
8,8 anion whitening 11f! l”
1.0 Dishes: Bis(Aerinohyproxethylmethylainotriazinyl)) Stilbendisulfonate (sodium salt) Fluorescence brightening Copper effectiveness f light Non f light C alkyl I 11-, I I Dalicoside □ , 4/Neodo 79 111 22 8
7-R23-6.5 Technically Significant Difference: HWU-2; Noller 2A=2; and F
-1 Example■ MT shirt re-adhesion and white vertical/whitening test world thTW
The following results were obtained using a non-build mixture of I-shavings that improve the effectiveness of anionic brighteners in the presence of non-ionic surfactants. This clearly shows the effect of Reshir. There is a substantial improvement in the data, clearly indicating that at least about - of the surfactant system should be an alkyl 4 glycoside.

Non-P light” V18. Palm rate, before cleaning after cleaning Δ(
Horizontal thin--→Yu, 1 To, --,, -Knee-7□0. , middle side 1--14Zoo 0 120
110 1080 20 122
113 9@0 40 1
18 109 920 80
119 92! 70 100
118 91 27 buds: Adjustment of the effect of brightener Conditions: Zeta-washing side, mixed hardness 6I, 100"F (approximately 37.Hata ℃), IT cycle, total surfactant 300ppm
, svi enhancer LSppm Example
BIIi! ! Improve your performance!
.

Percentage Clay cleaning performance Cit~
1. Al C1,11 Al Hunter whiteness unit 10
0 0 25.9 2.8 1.
280 20 27.0 3.3
2.56G 40 28.8 5
．． 2 3.620 80 29.1
5.0 4.20 100 28
．． 1 2.2 2.1 Conditions: Kenjirin #III machine, non-rut, mixed hardness [6 grains, 10 Cf'F (approx. 37.8°C)
, 300 ppvm of active ingredients.As can be seen from the above data, the 1 mixed proboscis is clearly superior. A HWU of 1-2 is a qualitative difference in this test.

Example 1 Alkyluridarkosi P improves the performance of oil-based (low HLB) nonionic detergent surfactants.

(HWU) (y'go) 100 0 23J O,80,28
020N4.9 -0.1 0.560
40! 44-11.9 0420
80 8.8-21.0 -0.40
100 -0.8-27.8 -OJ conditions; 1a washing machine, non-built, mixed hardness 6! Len, Zo
o〒 (approximately 37.8℃), goo pptm (L8D□-1,2HWυ for clay, and LIID□-0,4 for 7 Asial dirt (fa@iml 5ell)
P11υ) Obviously, the above results are normal (Etkinization)
The mixture shows an improvement from mixing a non-ionic detergent extrapolation activator and an alkyl I lidaricoside.
Gives the Kurui Award to Kai Arashi.

For example, the combination of an alkyl liglucoside with a semipolar nonionic and atr detergent surfactant is compatible with non-malt soaps, but not with saturated soaps.

Formulation ﾆ Sodium tallate -2,2--Stearic acid -4,4--Ram-Aradonitrilotriacetic acid 1B, 2 18,2 18,2
18.2 1g, 2 trichums 2.8 2.8 2.8 2.
8 2.8 Toluenesulfone 11!2 2 2
2 2 Sodium ethyl alcohol 33333 Water Residual part Cross part Remaining part Remaining part Horibe Kumiyimono 1 to 3 and 5 had less foaming than Formulation 4, and were compatible with the washed warm surface (less corrosion).
Despite the presence of substances known to inhibit the formation of scum (...1), Il product 3 remains in the rinsing ice.
formed a soap scum.

When mixed, Container 3 produced a gel rather than a free-flowing clear liquid. It is clear that there should be no substantial excess of saturated soap over unsaturated soap.The soap should be at least about 40% unsaturated soap.

The performance of these composition types is improved if the total number of free alcohols with noble numbers from about 8 to about 1 is less than about 516, preferably less than about 2, and most preferably less than about 1. I hope that it will be improved! ! It has a glossy finish.

Claims (1)

[Claims] 1. In the ((trans)formula RO(R10)y(Z)xC, R is alkyl, hydroxyalkyl, alkylphenyl, droxyalkylphenyl, alkylbenzyl, or a mixture thereof. (The alkyl group has about 8 to 8 carbon atoms.
18); each R1 has 2 to about 4 carbon atoms
, and y is from 0 to about 12; and %2 is 5 carbons.
or 6%: the moiety derived from reducing sugars having 1 to about 10 s of alkyl polysaccharide detergent surfactant rigidity, where X is a number from about 1 to about 1 O. (B) from about 1% to about 7% amine oxide detergent surfactant. (C) a water-soluble fatty acid soap containing at least about 40 cs of unsaturated soap having a carbon number of about 16 to about 22 t';
96 to about 15%. (D) Water-soluble cleaning Kapilgoo O.--about 351.degree. old water-soluble synthetic anionic detergent surfactant about 0.about.7%. 2. A detergent composition characterized in that the detergent composition comprises from 0 to about 804 g of Fl water. The composition according to Range 1. 3. The amine oxide detergent surfactant has the formula % (wherein R is an alkyl group, hydroxyalkyl group, or alkylphenyl group having about 10 to about 18 carbon atoms, or , R' is an alkylene group or hydroxyalkylene group having 2 to 3 carbon atoms or a mixture thereof, X is 0 to about 2, and %
R/I is an alkyl group or hydroxyalkyl group having 1 to about 3 carbon atoms or a polyethylene oxide group containing &X1 to about 1 to about ethylene oxide, and the C groups are bonded to each other through an oxygen atom or a nitrogen atom. A castle structure? The composition according to claim 2, which has the following properties: 4, pyrophosphate, nitrilotriacetate, citrate,
A special ifl containing about 10 to about 30 detergency builders selected from the group consisting of polymers/IJ carboxylates, and carbonates! F. The composition according to claim 3. 5. The composition of the above claim 3jJK machine, which contains a high quality cleaning agent. 6. R in furkyl polyglycoside detergent surfactants
is an alkyl group having a carbon number of about lθ to about 16”l,
4. The composition of claim 3, wherein X is from about 1Σ to about 3. 7. Pyrophosphate, nitrilotriacetate, citrate,
6. The composition of claim 6rA, wherein the composition contains from about 10'1 to about 300 mol of salt selected from the group consisting of polycarboxylic acid salts, and carbonates. 8. The cation of the unsaturated fatty acid is selected from the group consisting of sodium, potassium, ammonium, monoethanolammonium, jetanolammonium, triethanolammonium, and mixtures thereof. Composition. 9. R in furkyl polyglycoside detergent surfactants
is an alkyl group having about 10 to about 14 carbon atoms, and X is about 1.6 to about 2.7.
The composition described in Section. 10, from about 54 to about 35 detergency builders selected from the group consisting of pyrophosphates, nitrilotriacetates, citrates, polycarboxylates, and carbonates. Composition. 11. The composition according to claim 9, which essentially contains no detergent builder. 12. The cations of unsaturated fatty acids are sodium, potassium, ammonium, monoethanol ammonium,
Particularly selected from the group consisting of jetanolammonium, triethanolammonium, and mixtures thereof! The composition according to item 9. 13. The composition according to claim 3, 46, or 12, wherein the unsaturated fatty acid is an oleate salt.