JPS57170911A - Continuous preparation of propylene-ethylene copolymer - Google Patents
Continuous preparation of propylene-ethylene copolymerInfo
- Publication number
- JPS57170911A JPS57170911A JP5633881A JP5633881A JPS57170911A JP S57170911 A JPS57170911 A JP S57170911A JP 5633881 A JP5633881 A JP 5633881A JP 5633881 A JP5633881 A JP 5633881A JP S57170911 A JPS57170911 A JP S57170911A
- Authority
- JP
- Japan
- Prior art keywords
- propylene
- polymerization
- carried out
- ethylene
- polymerizers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To prepare various grades of the titled copolymer having balanced physical properties such as impact strength, rigidity, etc., continuously, in high effeciency, by using a stereospecific catalyst, and controlling the rate of polymerization in the mutually connected polymerizers by adding an additive.
CONSTITUTION: The bulk polymerization of propylene and ethylene is carried out using a stereospecific catalyst composed of a solid catalyst containing at least Mg, Ti and Cl and an organic Al compound[e.g. (C2H5)2AlCl]and using propylene as the polymerization solvent, under the condition that there is at least one polymerizer in which the polymerization reaction is carried out at an ethylene/propylene reaction ratio of 15/85W95/5 by weight. For example, the homopolymerization of propylene is carried out in the polymerizers A and B controlling the rate of polymerization by adding an additive such as triethyl Al compound; the H2 concentration is controlled in the polymerizer C to the level necessary in the following polymerization steps; the copolymerization of ethylene and propylene is carried out in the polymerizers D and E; the catalyst is deactivated in the polymerizer F; the slurry is heated in the apparatus H; and the product is dried by flushing in the apparatus G to obtain the objective copolymer.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5633881A JPS57170911A (en) | 1981-04-16 | 1981-04-16 | Continuous preparation of propylene-ethylene copolymer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5633881A JPS57170911A (en) | 1981-04-16 | 1981-04-16 | Continuous preparation of propylene-ethylene copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57170911A true JPS57170911A (en) | 1982-10-21 |
JPH0253444B2 JPH0253444B2 (en) | 1990-11-16 |
Family
ID=13024420
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5633881A Granted JPS57170911A (en) | 1981-04-16 | 1981-04-16 | Continuous preparation of propylene-ethylene copolymer |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57170911A (en) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4926069A (en) * | 1972-07-03 | 1974-03-08 | ||
JPS5298045A (en) * | 1976-02-13 | 1977-08-17 | Mitsui Petrochem Ind Ltd | Polymer composition for molding and its preparation |
JPS5529517A (en) * | 1978-08-22 | 1980-03-01 | Mitsubishi Petrochem Co Ltd | Polymerization of propylene |
JPS55115417A (en) * | 1979-02-27 | 1980-09-05 | Showa Denko Kk | Manufacture of propylene copolymer |
JPS55135107A (en) * | 1979-04-09 | 1980-10-21 | Mitsubishi Petrochem Co Ltd | Polymerization of olefin |
JPS5620011A (en) * | 1979-07-27 | 1981-02-25 | El Paso Polyolefins | Manufacture of ethyleneepropylene block copolymer |
JPS56139520A (en) * | 1980-04-02 | 1981-10-31 | Mitsui Petrochem Ind Ltd | Preparation of block copolymer |
-
1981
- 1981-04-16 JP JP5633881A patent/JPS57170911A/en active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4926069A (en) * | 1972-07-03 | 1974-03-08 | ||
JPS5298045A (en) * | 1976-02-13 | 1977-08-17 | Mitsui Petrochem Ind Ltd | Polymer composition for molding and its preparation |
JPS5529517A (en) * | 1978-08-22 | 1980-03-01 | Mitsubishi Petrochem Co Ltd | Polymerization of propylene |
JPS55115417A (en) * | 1979-02-27 | 1980-09-05 | Showa Denko Kk | Manufacture of propylene copolymer |
JPS55135107A (en) * | 1979-04-09 | 1980-10-21 | Mitsubishi Petrochem Co Ltd | Polymerization of olefin |
JPS5620011A (en) * | 1979-07-27 | 1981-02-25 | El Paso Polyolefins | Manufacture of ethyleneepropylene block copolymer |
JPS56139520A (en) * | 1980-04-02 | 1981-10-31 | Mitsui Petrochem Ind Ltd | Preparation of block copolymer |
Also Published As
Publication number | Publication date |
---|---|
JPH0253444B2 (en) | 1990-11-16 |
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