JPS5687555A - Manufacture of cyclohexene derivative - Google Patents
Manufacture of cyclohexene derivativeInfo
- Publication number
- JPS5687555A JPS5687555A JP16542480A JP16542480A JPS5687555A JP S5687555 A JPS5687555 A JP S5687555A JP 16542480 A JP16542480 A JP 16542480A JP 16542480 A JP16542480 A JP 16542480A JP S5687555 A JPS5687555 A JP S5687555A
- Authority
- JP
- Japan
- Prior art keywords
- manufacture
- cyclohexene derivative
- cyclohexen
- trimethyl
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 125000000596 cyclohexenyl group Chemical class C1(=CCCCC1)* 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- FDSDTBUPSURDBL-LOFNIBRQSA-N canthaxanthin Chemical compound CC=1C(=O)CCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)C(=O)CCC1(C)C FDSDTBUPSURDBL-LOFNIBRQSA-N 0.000 abstract 2
- JZWRJKCLOFWVKW-UHFFFAOYSA-N 3-(5-hydroxy-3-methylpent-3-en-1-ynyl)-2,4,4-trimethylcyclohex-2-en-1-one Chemical compound OCC=C(C)C#CC1=C(C)C(=O)CCC1(C)C JZWRJKCLOFWVKW-UHFFFAOYSA-N 0.000 abstract 1
- BVUBYYWRFBEIET-UHFFFAOYSA-N 3-(5-hydroxy-3-methylpenta-1,3-dienyl)-2,4,4-trimethylcyclohex-2-en-1-one Chemical compound OCC=C(C)C=CC1=C(C)C(=O)CCC1(C)C BVUBYYWRFBEIET-UHFFFAOYSA-N 0.000 abstract 1
- OOUTWVMJGMVRQF-DOYZGLONSA-N Phoenicoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)C(=O)C(O)CC1(C)C)C=CC=C(/C)C=CC2=C(C)C(=O)CCC2(C)C OOUTWVMJGMVRQF-DOYZGLONSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229940008033 canthaxanthin Drugs 0.000 abstract 1
- 235000012682 canthaxanthin Nutrition 0.000 abstract 1
- 239000001659 canthaxanthin Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/24—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by six-membered non-aromatic rings, e.g. beta-carotene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/04—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
- C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
- C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/54—Quaternary phosphonium compounds
- C07F9/5435—Cycloaliphatic phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1058179 | 1979-11-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5687555A true JPS5687555A (en) | 1981-07-16 |
Family
ID=4364723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16542480A Pending JPS5687555A (en) | 1979-11-28 | 1980-11-26 | Manufacture of cyclohexene derivative |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4323711A (ja) |
| EP (1) | EP0031875B1 (ja) |
| JP (1) | JPS5687555A (ja) |
| AT (1) | ATE3419T1 (ja) |
| DE (1) | DE3063354D1 (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6058934A (ja) * | 1983-08-23 | 1985-04-05 | エフ・ホフマン―ラ ロシユ アーゲー | エポキシドの異性化方法 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0077439B1 (de) * | 1981-10-16 | 1986-09-24 | F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft | Verfahren zur Herstellung von Cyclohexenderivaten, sowie ein neues Ausgangsprodukt und neue Zwischenprodukte in diesem Verfahren |
| ATE13876T1 (de) * | 1982-01-28 | 1985-07-15 | Hoffmann La Roche | Verfahren zur herstellung von cycloalkenonderivaten. |
| ATE13666T1 (de) * | 1982-02-09 | 1985-06-15 | Hoffmann La Roche | Verfahren zur herstellung von cyclohexenderivaten. |
| US4465567A (en) * | 1983-01-26 | 1984-08-14 | Hoffmann-La Roche Inc. | Process for the manufacture of 3-hydroxy-2-cycloalken-1-one derivatives |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51149249A (en) * | 1975-06-09 | 1976-12-22 | Hoffmann La Roche | Cyclic oxo compound |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3624105A (en) * | 1967-02-23 | 1971-11-30 | Hoffmann La Roche | Method for synthesizing rhodoxanthin |
| US4153805A (en) * | 1975-06-09 | 1979-05-08 | Hoffmann-La Roche Inc. | Preparation of food coloring agents |
| US4204073A (en) * | 1976-08-02 | 1980-05-20 | Hoffmann-La Roche Inc. | Process for producing carotenoids |
| US4098827A (en) * | 1977-01-17 | 1978-07-04 | Hoffmann-La Roche Inc. | 1-(2,6,6-Trimethyl-3-hydroxy-1-cyclohexen-1-yl)-3-methyl-penta-1,4-diene[or 1-yn-4-EN]-3-ols |
| DE2964401D1 (en) * | 1978-06-02 | 1983-02-03 | Hoffmann La Roche | Process for the preparation of cyclohexenyl derivatives, and intermediates produced in the synthesis |
-
1980
- 1980-10-03 EP EP80105995A patent/EP0031875B1/de not_active Expired
- 1980-10-03 DE DE8080105995T patent/DE3063354D1/de not_active Expired
- 1980-10-03 AT AT80105995T patent/ATE3419T1/de not_active IP Right Cessation
- 1980-11-10 US US06/205,410 patent/US4323711A/en not_active Expired - Lifetime
- 1980-11-26 JP JP16542480A patent/JPS5687555A/ja active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51149249A (en) * | 1975-06-09 | 1976-12-22 | Hoffmann La Roche | Cyclic oxo compound |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6058934A (ja) * | 1983-08-23 | 1985-04-05 | エフ・ホフマン―ラ ロシユ アーゲー | エポキシドの異性化方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0031875A1 (de) | 1981-07-15 |
| US4323711A (en) | 1982-04-06 |
| EP0031875B1 (de) | 1983-05-18 |
| DE3063354D1 (en) | 1983-07-07 |
| ATE3419T1 (de) | 1983-06-15 |
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