JPS5681317A - Suspension polymerization of vinyl chloride - Google Patents
Suspension polymerization of vinyl chlorideInfo
- Publication number
- JPS5681317A JPS5681317A JP15836079A JP15836079A JPS5681317A JP S5681317 A JPS5681317 A JP S5681317A JP 15836079 A JP15836079 A JP 15836079A JP 15836079 A JP15836079 A JP 15836079A JP S5681317 A JPS5681317 A JP S5681317A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- suspension
- pvc
- cellulose derivative
- respect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
PURPOSE: To obtain a polyvinyl chloride resin having a fine, highly porous particle structure and excellent gelation properties, by suspension-polymerizing vinyl chloride in the presence of a modified polyvinyl chloride and a cellulose derivative.
CONSTITUTION: In suspension-polymerizing vinyl chloride, there are added simultaneously to the reaction mixture, a cellulose derivative and a partially saponified polyvinyl alcohol (saponification degree 60W80mol%) having, in the side chains, 0.02W5mol% of at least one member selected from the group consisting of a sulfate ester, a phosphate ester and a salt thereof. With respect to the amount of said sulfate ester, phosphate ester or the like, amounts below 0.02mol% can not give porosity to the PVC, whereas amounts exceeding 5mol% brings the vinyl chloride monomer suspension system to the emulsion system. This is not advantageous. With respect to the saponification degree of th PVA, the one below 60mol% can not maintain an enough stable suspension system, whereas the one exceeding 80mol% is difficult to provide a porous PVC.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15836079A JPS5681317A (en) | 1979-12-06 | 1979-12-06 | Suspension polymerization of vinyl chloride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15836079A JPS5681317A (en) | 1979-12-06 | 1979-12-06 | Suspension polymerization of vinyl chloride |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5681317A true JPS5681317A (en) | 1981-07-03 |
Family
ID=15669964
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15836079A Pending JPS5681317A (en) | 1979-12-06 | 1979-12-06 | Suspension polymerization of vinyl chloride |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5681317A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0195103A (en) * | 1987-10-06 | 1989-04-13 | Kuraray Co Ltd | Dispersion stabilizer for suspension polymerization of vinyl compound |
DE102007004511A1 (en) | 2007-01-19 | 2008-07-31 | Forschungsinstitut für Leder und Kunststoffbahnen gGmbH | Open-pore, microporous films, useful e.g. as filter membranes, are obtained by incorporating filler particles in non-thermoplastically prepared film and stretching |
CN102453175A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Preparation method of high-oil-absorption-rate polyvinyl chloride resin |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5424989A (en) * | 1977-07-26 | 1979-02-24 | Nippon Synthetic Chem Ind Co Ltd:The | Suspension polymerization of vinyl compound |
JPS5446284A (en) * | 1977-09-20 | 1979-04-12 | Denki Kagaku Kogyo Kk | Suspension polymerization of vinly chloride |
JPS54112985A (en) * | 1978-02-23 | 1979-09-04 | Nippon Synthetic Chem Ind Co Ltd:The | Suspension polymerization of vinyl compound |
-
1979
- 1979-12-06 JP JP15836079A patent/JPS5681317A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5424989A (en) * | 1977-07-26 | 1979-02-24 | Nippon Synthetic Chem Ind Co Ltd:The | Suspension polymerization of vinyl compound |
JPS5446284A (en) * | 1977-09-20 | 1979-04-12 | Denki Kagaku Kogyo Kk | Suspension polymerization of vinly chloride |
JPS54112985A (en) * | 1978-02-23 | 1979-09-04 | Nippon Synthetic Chem Ind Co Ltd:The | Suspension polymerization of vinyl compound |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0195103A (en) * | 1987-10-06 | 1989-04-13 | Kuraray Co Ltd | Dispersion stabilizer for suspension polymerization of vinyl compound |
DE102007004511A1 (en) | 2007-01-19 | 2008-07-31 | Forschungsinstitut für Leder und Kunststoffbahnen gGmbH | Open-pore, microporous films, useful e.g. as filter membranes, are obtained by incorporating filler particles in non-thermoplastically prepared film and stretching |
DE202007019212U1 (en) | 2007-01-19 | 2011-02-24 | Forschungsinstitut für Leder und Kunststoffbahnen gGmbH | Open-pore microporous film |
CN102453175A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Preparation method of high-oil-absorption-rate polyvinyl chloride resin |
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