JPH10167929A - Amber-white pigment particulate compounded cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prepare an amber-white pigment particulate compounded cosmetic that has sufficient hiding power, and is able to freely adjust opacifying effect and color tone and simultaneously form a uniform cosmetic film by compounding spherical white pigment particulates having features in average particle size, etc. SOLUTION: This amber-white pigment particulate compounded cosmetic contains spherical white pigment particulates which has average particle size in the range of 80-800nm and a coefficient of particle size variation (CV), which is expressed, for example, by CV=(σ/D)×100 (σ is standard deviation of particle size; D is average particle size), of 10% or less and the surfaces of which are coated with inorganic oxide having a refractive index of 1.8 or more, preferably titanium dioxide, zinc oxide, zirconium oxide, etc.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cosmetic in which spherical white pigment fine particles are blended, and more particularly, it can adjust concealing property and color at the time of makeup, and has good stretch and feel to the skin. The present invention relates to a cosmetic that can provide a natural finish and at the same time does not cause dullness or makeup loss due to the process after makeup.

[0002]

2. Description of the Related Art Conventionally, in order to obtain cosmetics having opacity, it has been practiced to blend inorganic oxide fine particles having a high refractive index such as titanium oxide and zinc oxide.

[0003] These conventionally used fine particles generally have an average particle size of about 300 nm and have a wide particle size distribution, so that the particles have a strong cohesive force and poor dispersibility when incorporated into cosmetics. Furthermore, its irregular shape and strong adhesion to the skin work as a synergistic effect,
Poor elongation during makeup. Therefore, the opacity tends to be uneven, and the compounding amount is increased to prevent the opacity.However, the opacity is increased more than necessary,
There is a problem that a thick makeup feeling and unnatural feeling at the time of finishing occur. In addition, since the fine particles have strong cohesiveness and low flowability, they cause a caking phenomenon in a container, and have a drawback such that when applied to the skin using an applied body such as a puff, the removal by the applied body becomes poor. doing.

[0004] In addition, inorganic oxide fine particles conventionally used as a white pigment usually show concealing properties due to a difference in refractive index from air, but the surface is mixed with water or oil when mixed with cosmetics. When wet, concealment may decrease.
This is because, when the surface of pigment fine particles is wetted with water or oil, which has a higher refractive index than air, the apparent refractive index of the fine particles becomes smaller, and as a result, the difference in refractive index from air becomes smaller than when not wet. This is because the light reflectance or scattering effect on the surface of the fine particles decreases. If a pigment is added in an amount larger than the required amount in order to avoid such a phenomenon, defects such as usability and elongation of makeup will be amplified.

[0005] Further, in the cosmetics containing such pigment fine particles, when the surface of the compounded pigment becomes wet with sweat or sebum secreted from the skin over time after makeup, sweat and sebum are refracted from air. Because the ratio is large, the reflectance or scattering coefficient of these pigment fine particles is reduced, and the color tone of the decorative film is changed, the concealment is reduced and the ability to cover the ground is reduced, such as makeup removal, The problem of dullness after makeup may occur.

[0006] Such problems of the conventional inorganic pigments have also been improved. For example, in order to improve the extensibility of the pigment, spherical particles in which the surfaces of resin beads are coated with titanium oxide or the like are blended. Although cosmetics are available, their extensibility has been improved, but their concealing properties are insufficient.

Further, Japanese Patent Publication No. 6-11872 discloses that
Cosmetics containing silica beads coated with titanium oxide on the surface have also been proposed. Although the cosmetics show improvement in elongation, smoothness, fineness, etc.,
Since the average particle size of the silica beads used is as large as 5 μm, the opacity is low.

In order to prevent the opacity of the white pigment particles from decreasing due to wetting of the surface, particles having a water-repellent or oil-repellent property obtained by subjecting the particle surface to a silicon treatment or a fluororesin treatment may be used. However, it is difficult to completely prevent a decrease in concealment due to imperfect water / oil repellent treatment.

By the way, the particle size of the fine particles greatly affects the scattering of light. It is said that the particle size at which light scattering is the highest in the white pigment fine particles having a large refractive index as described above is about の of the wavelength. Therefore, by appropriately selecting the particle size of the pigment to be mixed with the cosmetic, the hiding power of the cosmetic can be adjusted by the degree of light scattering by the pigment.

Further, in a cosmetic in which such white pigment fine particles are blended, a so-called color tone having a white to reddish color is observed depending on the particle diameter and the blending amount of the blended fine particles. Such a tint is caused by scattering of light of a specific wavelength by pigment fine particles having a specific particle size to be blended. However, conventional fine particles of white pigment generally have a wide particle size distribution,
Since the particles having a particle size of about m are relatively large, when applied to the skin, the color becomes unnatural and has a bluish tint, and it is difficult to adjust the opacity by the particle size.

[0011]

DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems and has a sufficient concealing property, and the concealing property and the color can be freely adjusted, and the concealing property is not uniform. The purpose is to provide a cosmetic film that can form a cosmetic film without skin, has good skin elongation, feels good, and has a natural finish, does not have dullness after makeup and does not lose makeup, and has excellent light resistance. And

[0012]

The cosmetic of the present invention has a spherical white color having an average particle diameter in the range of 80 to 800 nm and a coefficient of variation (CV) of the particle diameter represented by the following formula of 10% or less. It is characterized by containing pigment fine particles. CV = (σ / D) × 100 [where, σ: standard deviation of particle diameter, D: average particle diameter]

The spherical white pigment fine particles have a refractive index of 1.8.
It is preferable to be composed of the above inorganic oxides. The spherical white pigment fine particles have a refractive index of 1.
It is preferably coated with at least 8 inorganic oxides. The inorganic oxide is titanium oxide, zinc oxide, zirconium oxide, cerium oxide, tin oxide, antimony oxide,
It is preferable to use one or more oxides selected from aluminum oxide and tantalum oxide.

The surface of the spherical white pigment fine particles is preferably coated with an inorganic oxide having a refractive index of less than 1.8.

[0015]

Preferred embodiments of the present invention will be described below. The fine white pigment particles used in the present invention have an average particle diameter of 80 to 800 nm, preferably 100 to 600 nm, and a coefficient of variation (CV) of the particle diameter represented by the following formula of 10% or less, preferably 5%. It is as follows. Where,
σ: standard deviation of particle diameter, D: average particle diameter. CV = (σ / D) × 100

[0016] In the present invention, the particle diameter in the above specific range, and
By blending pigment fine particles having a sharp particle size distribution into the cosmetic, a specific color can be given to the cosmetic by scattering light having a specific wavelength according to the particle size. In addition, by blending two or more kinds of pigment fine particles having different particle diameters, it becomes possible to adjust the concealing property or the color tone by utilizing light scattering according to the respective particle diameters.

When the average particle size is less than 80 nm, most of the visible light is transmitted, and therefore, no opacity is exhibited. 800n
If m is exceeded, the reflectance of visible light is reduced, so that sufficient concealment is not exhibited and a natural cosmetic finish is not obtained.
When the CV value exceeds 10%, it becomes difficult to control the appearance, opacity and color of the specific color as described above. In addition, the dispersibility in cosmetics and the feel during makeup are reduced.

The white pigment fine particles of the present invention have a refractive index of 1.
It is preferable that the surface has a refractive index of at least 1.8 or at least 1.8. If the ratio is less than 1.8, a sufficient visible light reflectance cannot be obtained, and a desired hiding property may not be exhibited.

As a white pigment having a refractive index of 1.8 or more,
There is no particular limitation as long as it is a conventionally used pigment.
For example, titanium oxide, zinc oxide, zirconium oxide, cerium oxide, tin oxide, antimony oxide, inorganic oxides such as aluminum oxide or tantalum oxide, or
A mixture of two or more of these or two or more of composite oxides is used. Further, perovskite-type composite oxides such as barium titanate, calcium titanate, and barium zirconate are also substances suitable for the purpose of the present invention.

In the present invention, the surface of spherical inorganic compound fine particles such as silica and alumina is coated with one or more of the above-mentioned inorganic oxides having a refractive index of 1.8 or more.
Spherical inorganic compound fine particles having a layer structure are also suitable as pigments capable of achieving the object of the present invention. The coating amount of the inorganic oxide at this time is sufficient as long as it can uniformly coat the surface of the fine particles, and the coating amount is preferably at least 5% by weight based on the total weight of the coated fine particles. If the content is less than 5% by weight, the coating layer becomes thin and transmits a part of the visible light to lower the reflectance, so that the concealing property is reduced.

Conventional methods for producing these white pigment fine particles include a method of hydrolyzing an aqueous solution of a metal salt of a precursor such as the inorganic oxide and a method of hydrolyzing a similar metal alkoxide in an alcohol solution. There is no particular limitation as long as it is a method known as a method for preparing dispersed fine particles. Further, a method in which a metal salt such as titanium tetrachloride is added to a dispersion of spherical fine particles such as spherical silica, and the resultant is hydrolyzed in an alkaline atmosphere to precipitate a metal salt hydrolyzate on the surface of the spherical fine particles. . The spherical fine particles thus obtained can be converted into fine particles having a predetermined CV value by a classification operation as required.

In the case of the fine particles used in the present invention, as described above, a slight amount of water or oil is applied to the surface when the fine particles are incorporated into a cosmetic, and further, the surface of the fine particles is wetted by sweat or oil after makeup. A decrease in concealment may occur, resulting in dullness after makeup and problems with makeup removal.

In the present invention, in order to solve the above problem, the surface of the fine particles having a refractive index of 1.8 or more is coated with a substance having a refractive index equal to or close to that of water or oil, Spherical fine particles having a low apparent refractive index are used. Since the refractive index of such fine particles is close to the refractive index of water, oil, sebum, or the like, even if the surface is wet with water or the like, the decrease in the refractive index and the scattering coefficient is smaller or almost non-existent before the surface becomes wet. For this reason, cosmetics containing such pigment fine particles have very little change over time in the cosmetic effect, such as a decrease in concealing property or a loss of makeup or dullness.
Examples of the inorganic oxide having a refractive index of less than 1.8 include silica, alumina, and phosphorus oxide.

As a method of coating the inorganic oxide, for example,
When coating silica, an aqueous solution of an alkali metal silicate is added to the dispersion liquid of the spherical fine particles, and a polymer of silicic acid is attached to the surface of the fine particles to obtain a silica coating layer having a predetermined thickness. Methods can be mentioned. The coating amount of the inorganic oxide may be a thickness that can prevent a decrease in the reflectance of visible light due to surface wetting, and specifically, is at least 0.5% by weight based on the total weight of the coated fine particles. % Is sufficient.

In the present invention, a desired opacity and color cosmetic can be obtained by appropriately selecting the particle size of the fine white pigment particles to be blended. For example, when strict white and high opacity are desired, two or more kinds of fine particles having an average particle diameter in the range of 150 nm to 550 nm may be mixed at an appropriate ratio so that the average particle diameter becomes about 300 nm. Good. Further, when a cosmetic having a slightly reddish color is desired, although the concealing property is not so high, 500 nm
Particles having an average particle size of 400 nm, 500 nm
What is necessary is just to mix | blend the thing of a particle diameter of nm and 600 nm by a suitable ratio.

In the cosmetic of the present invention, the amount of the spherical fine particles is preferably 1 to 80% by weight. If the amount is less than 1% by weight, the compounding effect cannot be obtained. On the other hand, if it exceeds 80% by weight, the concealing property may be too strong, and a natural cosmetic finish is not obtained.

[0027] The cosmetic of the present invention includes various components blended in ordinary cosmetics, for example, oils such as higher aliphatic alcohols, higher fatty acids, ester oils, paraffin oils and waxes, ethyl alcohol, propylene glycol and sorbitol. , Alcohols such as glycerin, mucopolysaccharides,
Humectants such as collagens, PCA salts, lactates, nonionic, cationic, anionic or amphoteric surfactants, gum arabic, xanthan gum, polyvinylpyrrolidone, ethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, modified or Thickeners such as unmodified clay minerals, solvents such as ethyl acetate, acetone and toluene, inorganic face dyes, organic face dyes, antioxidants such as BHT and tocopherol, water, drugs, ultraviolet absorbers, p
It contains at least one kind of H buffer, chelating agent, preservative, fragrance and the like. Further, it may contain at least one or more of inorganic fillers such as silica, talc, kaolin, and mica, extenders, and various organic resins. The white pigment may be blended after surface treatment with a silicon compound or an organic resin.

The cosmetic of the present invention can be produced by a conventional method, and is used in various forms such as powder, cake, pencil, stick, liquid, cream, and the like. , Emulsion, eyeshadow, makeup base, nail enamel, eyeliner, mascara, lipstick, pack, lotion, shampoo, rinse,
Includes hair cosmetics and the like.

[0029]

The present invention will be described more specifically with reference to the following examples.

Example 1 As white pigment fine particles, an average particle diameter of 300 n shown in Table 1 was used.
A cake-like foundation having the following composition was prepared using spherical titanium oxide fine particles (anatase type, refractive index 2.5) having m and CV values of 3%.

(1) Spherical titanium oxide 10 (parts by weight) (2) Talc 30 (3) Sericite 31 (4) Mica 10 (5) Bengala 0.4 (6) Iron oxide (yellow) 1.6 (7) ) Iron oxide (black) 0.05 (8) Sorbitan fatty acid ester 2.5 (9) Stearyl alcohol 6.0 (10) Lanolin 5.0 (11) Liquid paraffin 2.0 (12) Triethanolamine 1.0 (13) Ethyl paraben 0.45 (14) Perfume appropriate amount

First, a mixture of (1) to (7) is prepared. Further, (8) to (14) are sufficiently mixed while being heated to 70 ° C., and this is added to the above-mentioned mixture and uniformly mixed. This was dried and pulverized to make the particle size uniform, and then compression molded. About the obtained cake-like foundation,
The elongation, the uniformity of the decorative film, the hiding power, the tint, and the temporal stability (dullness) of the color tone were evaluated by a sensory test. Table 2 shows the results.

In Table 2, the meanings of the symbols in the columns of "elongation / feel", "uniformity" and "color tone stability" are as follows. ○ ・ ・ ・ Excellent △ ・ ・ ・ Slightly poor × ・ ・ ・ Poor

Example 2 As white pigment fine particles, an average particle diameter of 300 n shown in Table 1 was used.
m, spherical zirconium oxide having a CV value of 5% (refractive index 2.2
A cake-like foundation was prepared in the same manner as in Example 1 except that 0) was used. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

Example 3 A dispersion obtained by dispersing 200 g of spherical silica fine particles having an average particle size of 270 nm in 19.8 L of pure water was heated to 80 ° C., and an aqueous solution of titanium tetrachloride (133 g / TiO ₂₎ was added to the dispersion.
L) 1 L was added. After the addition, the mixture was aged at 80 ° C. for 1 hour, filtered, dried, and then calcined at 800 ° C. for 5 hours. As shown in Table 1, the surface of the spherical silica was coated with titanium oxide (refractive index: 2.52). Average particle size 300
nm, spherical white pigment fine particles having a CV value of 4% were obtained. The coating amount of titanium oxide was 40% by weight. A cake-like foundation was prepared in the same manner as in Example 1, except that the spherical white pigment fine particles obtained above were used. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

Example 4 A dispersion obtained by dispersing 200 g of spherical silica fine particles having an average particle size of 270 nm in 19.8 L of pure water was heated to 80 ° C., and an aqueous zinc chloride solution (133 g / L as Zn0) was added to the dispersion.
L and 2 L of an aqueous solution of sodium carbonate (concentration: 10% by weight) were added. After the addition, the mixture was aged at 80 ° C. for 1 hour, filtered, dried, and then calcined at 500 ° C. for 5 hours to coat zinc oxide (refractive index: 2.00) on the surface of the spherical silica as shown in Table 1. Thus, spherical white pigment fine particles having an average particle diameter of 300 nm and a CV value of 6% were obtained. The coating amount of zinc oxide was 40% by weight. A cake-like foundation was prepared in the same manner as in Example 1, except that the spherical white pigment fine particles obtained above were used. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

Example 5 A dispersion obtained by dispersing 200 g of the spherical titanium oxide fine particles used in Example 1 in 1.8 L of pure water was heated to 80 ° C., and an aqueous solution of sodium silicate (30 g / SiO ₂₎ was added to the dispersion.
L) 1177 g was added. After the addition, the mixture was aged at 80 ° C. for 1 hour, filtered, dried, and then calcined at 500 ° C. for 5 hours. As shown in Table 1, the surface of the spherical titanium oxide was coated with silica (refractive index: 1.47). Spherical white pigment fine particles having an average particle diameter of 310 nm and a CV value of 5% were obtained.
The silica coverage was 15% by weight. A cake-like foundation was prepared in the same manner as in Example 1, except that the spherical white pigment fine particles obtained above were used. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

Example 6 A dispersion obtained by dispersing 200 g of the spherical zirconium oxide fine particles used in Example 2 in 1.8 L of pure water was heated to 80 ° C., and an aqueous solution of sodium silicate (3% as SiO ₂₎ was added to the dispersion.
(0 g / L) 1177 g was added. After the addition, the mixture was aged at 80 ° C. for 1 hour, filtered, dried, and then calcined at 500 ° C. for 5 hours. As shown in Table 1, the surface of the spherical zirconium oxide was coated with silica (refractive index: 1.47). Thus, spherical white pigment fine particles having an average particle diameter of 310 nm and a CV value of 6% were obtained. The silica coverage was 15% by weight. A cake-like foundation was prepared in the same manner as in Example 1, except that the spherical white pigment fine particles obtained above were used. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

Example 7 The surface of the titanium oxide-coated silica fine particles obtained in Example 3 was coated with silica under the same conditions as in Example 5 to obtain silica / titanium oxide / silica shown in Table 1. Consisting of 3
Spherical white pigment fine particles having a layer structure were obtained (silica coating amount:
15% by weight). A cake-like foundation was prepared in the same manner as in Example 1, except that the spherical white pigment fine particles obtained above were used. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

Example 8 Instead of the spherical titanium oxide of Example 5, an average particle diameter of 500
Under the same conditions as in Example 5 except that a spherical titanium oxide having a refractive index of 1.4 nm was used.
7) coated with an average particle size of 510 nm shown in Table 1
Spherical white pigment fine particles having a value of 3% were obtained. Same as Example 1 except that a mixture of the spherical white pigment fine particles, the spherical white pigment fine particles obtained in Example 5 and the spherical white pigment fine particles obtained in Example 5 in a ratio of 1: 1 (weight ratio) was used. And then
A cake-like foundation was prepared. Example 1
Table 2 shows the results of the sensory test performed in the same manner as in the above.

Example 9 Instead of the spherical titanium oxide of Example 5, an average particle diameter of 180 was used.
Under the same conditions as in Example 5 except that a spherical titanium oxide having a refractive index of 1.4 nm was used.
7) coated with an average particle size of 190 nm shown in Table 1
Spherical white pigment fine particles having a value of 5% were obtained. Except that a mixture of the spherical white pigment fine particles, the spherical white pigment fine particles obtained in Example 5 and the spherical white pigment fine particles with an average particle diameter of 510 nm obtained in Example 8 in a ratio of 1: 1: 1 (weight ratio) was used. In the same manner as in Example 1, a cake-like foundation was prepared. Table 2 shows the results of the sensory test performed in the same manner as in Example 1.

[0042] Instead of the spherical titanium oxide fine particles of Comparative Example 1, a commercially available titanium oxide based white pigment shown in Table 1 (Ishihara Sangyo Co., C
A cake-like foundation was prepared in the same manner as in Example 1 except that R-50) was used. Table 2 shows the results of a sensory test performed on the obtained cake-like foundation in the same manner as in Example 1.

Example 10 Using the fine spherical white pigment particles obtained in Example 5, an emulsion foundation having the following composition was prepared. (1) pure water 58.6 (parts by weight) (2) triethanolamine 1.1 (3) carboxymethyl cellulose 0.2 (4) bentonite 0.5 (5) spherical white pigment 3.5 (6) talc 3.0 (7) Color pigment appropriate amount (8) Stearic acid 2.4 (9) Propylene glycol monostearate 2.0 (10) Cetostearyl alcohol 0.2 (11) Liquid paraffin 3.0 (12) Liquid lanolin 2.0 (13) Isopropyl myristate 8.5 (14) Proper amount of propyl parahydroxybenzoate (15) Perfume appropriate amount

First, (2) to (7) are dispersed in pure water and heated to 75 ° C. Also, (8) to (14) are 80
Mix well while heating to ℃, add this to the above dispersion and mix uniformly. After cooling, a perfume was added to obtain an emulsion foundation. Table 2 shows the results of the same sensory test as in Example 1 performed on the obtained emulsion base.

[0045]

TABLE 1 Oxide particle size CV compounding ratio (nm) (%) (wt / wt) Example 1 TiO ₂ 300 3-Example 2 ZrO ₂ 300 5-Example 3 TiO ₂ / SiO ₂ 300 4- Example 4 ZnO / SiO ₂ 300 6-Example 5 SiO ₂ / TiO ₂ 310 5-Example 6 SiO ₂ / ZrO ₂ 310 6-Example 7 SiO ₂ / TiO ₂ / SiO ₂ 310 4-Example 8 SiO ₂ / TiO ₂ 510 3 1 〃 SiO ₂ / TiO ₂ 310 5 1 Example 9 SiO ₂ / TiO ₂ 190 5 1 〃 SiO ₂ / TiO ₂ 510 3 1 〃 SiO ₂ / TiO ₂ 310 5 1 Comparative example CR-50 ( TiO ₂ ) 280 20 <− Example 10 SiO ₂ / TiO ₂ 310 5 −

[0046]

TABLE 2 Elongation uniformity hiding color tone feeling Stability Example 1 ○ ○ Strength skin color △ Example 2 ○ ○稍強skin color △ Example 3 ○ ○ Strength skin color △ Example 4 ○ ○ weak skin color △ Example 5 ○ ○ Slightly soft skin color ○ Example 6 ○ ○ Weak skin color ○ Example 7 ○ ○ Slightly strong skin color ○ Example 8 ○ ○ Weak reddish color ○ Example 9 ○ ○ Extremely strong skin color ○ Comparative example × △ Extremely unnatural Blue color × Example 10 ○ ○ Strong flesh color ○

As shown in Table 2, cosmetics (Examples 1 to 4) in which a white pigment composed of titanium oxide, zirconium oxide, zinc oxide or the like having a refractive index of 1.8 or more was blended,
Although the color stability over time (dullness) is slightly inferior, other sensory test results are excellent. Further, a white pigment whose surface was coated with silica or the like having a refractive index of less than 1.8 (Example 5)
7) are also improved in terms of stability over time (dullness). Furthermore, in the cosmetics (Examples 8 and 9) in which two or more kinds of white pigment fine particles having different particle diameters are blended, it can be seen that the opacity and the color tone can be arbitrarily adjusted in comparison with the cosmetics prepared in Example 5. .

[0048]

The cosmetics according to claims 1 to 4 contain fine white pigment particles having an average particle diameter in the range of 80 to 800 nm and a coefficient of variation of the particle diameter of 10% or less. It is possible to adjust the concealment and color. Further, the white pigment fine particles are excellent in dispersibility at the time of compounding, and have good elongation to the skin, so that a uniform and uniform cosmetic effect having a natural finishing effect can be obtained. In addition, the cosmetic is excellent in stability after blending.

The cosmetic according to claim 5 has, in addition to the above-mentioned effects, an excellent effect that the cosmetic feeling is lowered with the elapse of time after makeup, that is, there is no dullness or makeup loss.

Claims (5)

[Claims] 1. A cosmetic comprising an average particle diameter in the range of 80 to 800 nm and spherical white pigment fine particles having a coefficient of variation in particle diameter of 10% or less. 2. The spherical white pigment fine particles have a refractive index of 1.
2. The method according to claim 1, wherein the inorganic oxide comprises at least eight inorganic oxides.
The cosmetic described. 3. The cosmetic according to claim 1, wherein the spherical white pigment fine particles are obtained by coating the surfaces of the spherical fine particles with an inorganic oxide having a refractive index of 1.8 or more. 4. The method according to claim 1, wherein the inorganic oxide is one or more oxides selected from titanium oxide, zinc oxide, zirconium oxide, cerium oxide, tin oxide, antimony oxide, aluminum oxide and tantalum oxide. The cosmetic according to claim 2 or 3, characterized in that: 5. The cosmetic according to claim 2, wherein the surface of the spherical white pigment fine particles is coated with an inorganic oxide having a refractive index of less than 1.8.