JPH1015562A - Method and apparatus for producing mineral component dissolved water - Google Patents
Method and apparatus for producing mineral component dissolved waterInfo
- Publication number
- JPH1015562A JPH1015562A JP8169613A JP16961396A JPH1015562A JP H1015562 A JPH1015562 A JP H1015562A JP 8169613 A JP8169613 A JP 8169613A JP 16961396 A JP16961396 A JP 16961396A JP H1015562 A JPH1015562 A JP H1015562A
- Authority
- JP
- Japan
- Prior art keywords
- water
- carbon dioxide
- mineral component
- dissolved
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Non-Alcoholic Beverages (AREA)
- Physical Water Treatments (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、安全でおいしいミ
ネラル成分溶解水を簡便に得る方法に関するものであ
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for easily obtaining safe and delicious mineral component dissolved water.
【０００２】[0002]
【従来の技術】近年、水道水は、水源の汚染によりカル
キ臭やカビ臭が年々ひどくなり、まずくなる一方であ
る。安全衛生面でも、ビルやマンションの高架水槽の微
生物汚染や赤水の発生をはじめ、石綿やトリハロメタン
等の発ガン性物質の飲料水への混入問題が指摘され、安
全でおいしい水に対する要求は日増しに高くなっている
ため、浄水器やミネラルウォーターが広く普及してきて
いる。浄水器は、主に残留塩素やトリハロメタン等を除
去する活性炭と、濁度成分や細菌を濾過する中空糸膜か
らなるカートリッジで構成されており、安全な水は得ら
れるが、ミネラル成分の増加はない。又、ミネラルウォ
ーターは、湧き水や深井戸からの水をガラス瓶やポリエ
チレンテレフタレート等のボトルに詰めて販売されてお
り、飲用するたびに購入して家庭まで運ぶには重たく甚
だ不便である。2. Description of the Related Art In recent years, tap water has become worse and worsen year after year due to contamination of a water source due to a bad smell of mold and mold. In terms of health and safety, problems such as contamination of drinking water with carcinogenic substances such as asbestos and trihalomethane have been pointed out, including microbial contamination and red water generation in elevated water tanks of buildings and condominiums, and the demand for safe and delicious water is increasing daily. And water purifiers and mineral water have become widespread. The water purifier is composed of activated carbon, which mainly removes residual chlorine and trihalomethane, etc., and a cartridge consisting of a hollow fiber membrane that filters turbidity components and bacteria.Safe water is obtained, but the increase in mineral components Absent. In addition, mineral water is sold in the form of spring water or water from deep wells packed in glass bottles or bottles of polyethylene terephthalate, etc., and it is heavy and extremely inconvenient to purchase and carry it to a household every time it is drunk.
【０００３】この解決手段として、飲用水中への遊離炭
酸の添加や、難溶性のミネラル含有物質のミネラル成分
溶解を目的とし、飲用水中に炭酸ガスを添加させるミネ
ラル成分溶解水製造装置（特開昭５２−１４２５１号、
特開平５−２１２３８８号、実開平１−１２２８３３号
等）が提案されている。又、厚生省のおいしい水研究会
によれば、遊離炭酸と硬度に関するおいしいと感じる範
囲は、遊離炭酸が３〜３０ppm 、硬度が１０〜１００pp
m といわれており、遊離炭酸を酸度に、硬度をカルシウ
ム濃度に換算すると、酸度が３．４〜３４ppm 、カルシ
ウム濃度が４〜４０ppm となる。それぞれの換算式は以
下の通りである。 更に、炭酸カルシウムは、水に難溶性であるが、水中に
炭酸ガスが溶存する場合には、炭酸ガスと炭酸カルシウ
ムが反応し溶解することはよく知られている。[0003] As a solution to this problem, a mineral component dissolved water producing apparatus (additional method) for adding carbon dioxide gas to drinking water for the purpose of adding free carbonic acid to drinking water or dissolving a mineral component of a hardly soluble mineral-containing substance. No. 52-14251,
JP-A-5-212388, JP-A-1-122833, etc.) have been proposed. According to the Ministry of Health and Welfare's Delicious Water Research Group, the range of free carbonic acid and hardness that can be perceived as delicious is 3 to 30 ppm of free carbonic acid and 10 to 100 pp of hardness.
It is said that when the free carbonic acid is converted into the acidity and the hardness is converted into the calcium concentration, the acidity is 3.4 to 34 ppm and the calcium concentration is 4 to 40 ppm. The conversion formulas are as follows. Furthermore, although calcium carbonate is hardly soluble in water, it is well known that when carbon dioxide gas is dissolved in water, the carbon dioxide gas and calcium carbonate react and dissolve.
【０００４】[0004]
【発明が解決しようとする課題】従来のミネラル成分溶
解水製造方法は、飲用水をミネラル成分充填カートリッ
ジに循環通水する方法が殆どであった。しかしながら、
この方法では、難溶性ミネラル成分の溶解は殆どなく、
又、連続通水によるミネラル成分溶解水製造方法の場合
には、乳酸カルシウム等の水溶性の薬剤を添加する方法
が多く、カルシウムの濃度は上昇するが、薬剤を使用す
るため近年の消費者の自然、天然指向を満足させる方法
ではなかった。Most of the conventional methods for producing mineral component dissolved water circulate drinking water through a mineral component filling cartridge. However,
In this method, the hardly soluble mineral component is hardly dissolved,
In addition, in the case of a method for producing mineral component dissolved water by continuous water flow, a method of adding a water-soluble drug such as calcium lactate is often used, and the concentration of calcium increases. It was not a way to satisfy nature and nature.
【０００５】更に、炭酸ガスを飲用水中に添加し、難溶
性のミネラル成分を溶解させる方法では、炭酸ガスの添
加量が少ない場合には、炭酸カルシウムの溶解速度が遅
いため、目標のカルシウム濃度まで炭酸カルシウムを溶
解させるには、炭酸ガスを含んだ水を炭酸カルシウムに
長時間接触させる必要があり、その結果生成時間が長く
なる、或いは、ミネラル成分充填カートリッジが大きく
なってしまう等の問題点がある。又、炭酸ガス濃度が高
濃度である場合には、炭酸カルシウムの溶解は短時間に
行われるが、高濃度の炭酸ガスが残留し、厚生省のおい
しい水研究会によるおいしいと感じる範囲を超えてしま
うことが多い。Further, in the method of adding carbon dioxide gas to drinking water to dissolve the hardly soluble mineral components, when the amount of added carbon dioxide gas is small, the dissolution rate of calcium carbonate is low. In order to dissolve calcium carbonate, the water containing carbon dioxide gas must be brought into contact with calcium carbonate for a long time, resulting in a longer production time or a larger cartridge for filling with mineral components. There is. In addition, when the concentration of carbon dioxide is high, the dissolution of calcium carbonate is performed in a short time, but the high concentration of carbon dioxide remains, which exceeds the range in which the delicious water research group of the Ministry of Health and Welfare feels delicious. Often.
【０００６】[0006]
【課題を解決するための手段】本発明の要旨は、飲用水
中に炭酸ガスを添加し、難溶性ミネラル成分含有物質に
接触通水しミネラル成分を溶解させ、ミネラル成分溶解
後の飲用水中に溶存する過剰の炭酸ガスを除去し、ミネ
ラル成分溶解水を得ることを特徴とする、ミネラル成分
溶解水製造方法にあり、更に、ミネラル成分溶解後の飲
用水中に溶存する過剰の炭酸ガスの除去方法が、水と空
気の接触面積を大きくし、分圧差により液相から気相に
炭酸ガスを移動させ、飲用水中から炭酸ガスを除去する
方法であることを特徴とする、ミネラル成分溶解水製造
方法にある。また、少なくとも貯水タンク、送液ポン
プ、炭酸ガス添加装置、ミネラル成分充填カートリッジ
からなる循環通水によりミネラル成分溶解水を得る装置
において、吐水口に過剰の炭酸ガスを除去する装置を取
り付けてなることを特徴とするミネラル成分溶解水製造
装置、及び、少なくとも炭酸ガス添加装置、ミネラル成
分充填カートリッジからなる連続通水によりミネラル成
分溶解水を得る装置において、吐水口に過剰の炭酸ガス
を除去する装置を取り付けてなることを特徴とする、ミ
ネラル成分溶解水製造装置にある。SUMMARY OF THE INVENTION The gist of the present invention is to add carbon dioxide gas to drinking water, contact water through a substance containing a hardly soluble mineral component to dissolve the mineral component, and dissolve the mineral component in the drinking water. In the method for producing mineral component dissolved water, characterized in that excess carbon dioxide gas dissolved in the water is removed and mineral component dissolved water is obtained, furthermore, the excess carbon dioxide gas dissolved in the drinking water after dissolving the mineral component is removed. The removal method is a method of increasing the contact area between water and air, transferring carbon dioxide gas from a liquid phase to a gas phase by a partial pressure difference, and removing carbon dioxide gas from drinking water. In the water production method. In addition, at least a device for obtaining mineral component dissolved water by circulating water comprising a water storage tank, a liquid feed pump, a carbon dioxide gas adding device, and a mineral component filling cartridge, is provided with a device for removing excess carbon dioxide gas at a water discharge port. In a device for producing mineral component dissolved water, and a device for obtaining mineral component dissolved water by continuous flow of at least a carbon dioxide gas adding device and a mineral component filling cartridge, a device for removing excess carbon dioxide gas at a water discharge port is provided. An apparatus for producing a mineral component dissolved water characterized by being attached.
【０００７】更に、厚生省のおいしい水研究会による遊
離炭酸と硬度に関するおいしいと感じる範囲は、遊離炭
酸が３ppm から３０ppm （酸度として３．４ppm から３
４ppm ）、硬度が１０ppm から１００ppm （カルシウム
濃度として４ppm から４０ppm ）と言われており、装置
化の際に生成水質が上述の範囲内になるよう設定するこ
とは非常に好ましい。具体的な一例を挙げるならば、酸
度３ppm 、カルシウム濃度８ppm の水を使用し、貯水タ
ンク容量３Ｌ、循環流量０．５Ｌ／min 、炭酸ガスを酸
度として２００ppm 添加、石灰岩充填量２００ｇ、水温
２０℃で３分間循環通水を行った場合、遊離炭酸１５４
ppm （酸度１８０ppm ）、硬度７５ppm（カルシウム濃
度３０ppm ）の水を得ることが出来た。この場合、硬度
は厚生省のおいしい水研究会によるおいしいと感じる範
囲内であるが、遊離炭酸はそれを大きく超えているた
め、８０％から９８％の炭酸ガスを除去しおいしいと感
じる範囲内にする必要がある。[0007] Furthermore, according to the Ministry of Health and Welfare's Delicious Water Research Group, the range in which the free carbonic acid and the hardness are considered to be delicious is from 3 ppm to 30 ppm (the acidity is from 3.4 ppm to 3 ppm).
It is said that the hardness is from 10 ppm to 100 ppm (calcium concentration is from 4 ppm to 40 ppm), and it is very preferable to set the quality of the produced water within the above-mentioned range when installing the apparatus. As a specific example, water having an acidity of 3 ppm and a calcium concentration of 8 ppm is used, a storage tank capacity of 3 L, a circulating flow of 0.5 L / min, an addition of carbon dioxide at an acidity of 200 ppm, a limestone filling amount of 200 g, and a water temperature of 20 ° C. Circulating water for 3 minutes at
ppm (acidity: 180 ppm) and water having a hardness of 75 ppm (calcium concentration: 30 ppm) were obtained. In this case, the hardness is within the range that tastes good by the Ministry of Health and Welfare's Delicious Water Research Group, but since free carbon dioxide greatly exceeds that, 80% to 98% of carbon dioxide is removed to make it within the range that tastes good. There is a need.
【０００８】水中から炭酸ガスを除去する方法として
は、減圧槽や中空糸膜を使用した真空脱気法、水の温度
を上げる方法等があるが、より簡便な方法として、水と
空気の接触面積を大きくし分圧差により液相から気相に
炭酸ガスを移動させ水中から炭酸ガスを除去する方法が
より好ましい方法として挙げられる。具体的な方法とし
て、空気吸入口を大気中に開放したアスピレーターを用
い、飲用水中に空気を混入させる方法、スプレーノズル
を取り付け霧状に噴霧する方法、多孔板を取り付けシャ
ワー状に吐水する方法等が挙げられる。これらの内、ス
プレーノズルを用いる方法では、圧力損失が大きいこ
と、処理水の広がりが大きいこと等、又、多孔板を用い
る方法では、吐水部分が大きくなること等、その使用に
際して若干の制約が生じるものの構造が簡便であること
等の利点もあり、飲用水中から炭酸ガスを除去する方法
としては有効である。更に、空気吸入口を大気中に開放
したアスピレーターを用いる方法は、圧力損失が低いこ
と、小型であること等から最も汎用性に富みより好まし
い方法である。これらの方法の内、装置化の際に最も適
する方法を選択すればよいが、厚生省のおいしい水研究
会により遊離炭酸のおいしいと感じる３ppm から３０pp
m （酸度として３．４ppm から３４ppm ）の範囲内まで
炭酸ガスが除去できる方法を選択することが重要であ
る。[0008] As a method for removing carbon dioxide from water, there are a vacuum degassing method using a decompression tank or a hollow fiber membrane, a method for increasing the temperature of water, and the like. A more preferable method is to increase the area, move carbon dioxide from a liquid phase to a gas phase by a partial pressure difference, and remove carbon dioxide from water. As a specific method, a method of mixing air into drinking water using an aspirator having an air intake port opened to the atmosphere, a method of attaching a spray nozzle to spray in a mist shape, a method of attaching a perforated plate and discharging water in a shower shape And the like. Among them, the method using a spray nozzle has some restrictions such as a large pressure loss and a large spread of treated water, and the method using a perforated plate has a large water discharge portion such as a large water discharge part. Although it is produced, it also has advantages such as simple structure, and is effective as a method for removing carbon dioxide from drinking water. Further, a method using an aspirator having an air suction port opened to the atmosphere is the most versatile and preferable method because of its low pressure loss and small size. Of these methods, the most suitable one may be selected when the equipment is installed, but from the Ministry of Health and Welfare's Delicious Water Research Group, 3 ppm to 30 pp that feel free carbon dioxide is delicious
It is important to select a method capable of removing carbon dioxide gas within the range of m (3.4 ppm to 34 ppm as the acidity).
【０００９】又、本発明に用いる難溶性ミネラル成分含
有物質は、近年の消費者の自然、天然指向の向上に伴
い、化学的合成品からなる薬剤の使用を避け、石灰岩、
コーラルサンド等炭酸カルシウムを主成分とする天然物
を使用することが望ましい。更に、石灰岩、コーラルサ
ンド等が食品添加物の認定を受けたグレードのものを使
用することは安全性の面からも非常に好ましい。[0009] In addition, with the improvement of consumers' natural and natural consciousness in recent years, the use of chemicals composed of chemically synthesized products has been avoided, and limestone,
It is desirable to use a natural product mainly composed of calcium carbonate such as coral sand. Further, it is very preferable from the viewpoint of safety to use limestone, coral sand and the like of a grade that has been certified as a food additive.
【００１０】又、本発明に用いる炭酸ガス添加方法は、
特にとらわれるものはなく、例えば多孔質中空糸膜或い
は散気管等を用いバブリングを行う方法、スタティック
ミキサー等を用い撹拌通水を行う方法、非多孔質の気体
透過膜を用い飲用水中に添加する方法、通水経路内に炭
酸ガス層を設け炭酸ガス層を通水する方法等が挙げられ
る。但し、処理量、ミネラル成分充填量、目標カルシウ
ム増加量等により、炭酸ガスの必要量は明らかとなり、
その必要量を添加可能な方法を選択することが重要であ
る。[0010] The method of adding carbon dioxide gas used in the present invention is as follows.
There is no particular limitation, for example, a method of bubbling using a porous hollow fiber membrane or a diffuser tube, a method of stirring and passing water using a static mixer, etc., and adding to drinking water using a non-porous gas permeable membrane. And a method in which a carbon dioxide layer is provided in the water passage and water is passed through the carbon dioxide layer. However, the required amount of carbon dioxide is clarified by the processing amount, mineral component filling amount, target calcium increase amount, etc.
It is important to select a method that can add the required amount.
【００１１】[0011]
【発明の実施の形態】図１は、本発明に用いる炭酸ガス
を除去する装置の、アスピレーターを模式図により示し
たものである。水の入り口１から導入された水は、空気
の入り口２から吸入された空気と混ざり合い水の出口３
から吐出される。FIG. 1 is a schematic diagram showing an aspirator of an apparatus for removing carbon dioxide used in the present invention. The water introduced from the water inlet 1 mixes with the air sucked from the air inlet 2 and the water outlet 3
Is discharged from.
【００１２】図２は、本発明に用いる炭酸ガスを除去す
る装置の、スプレーノズルを模式図により示したもので
ある。水の入り口１から導入された水は、スプレーノズ
ル４１より高流速の流体となり水の出口３から霧状に吐
出される。FIG. 2 is a schematic view showing a spray nozzle of an apparatus for removing carbon dioxide used in the present invention. The water introduced from the water inlet 1 becomes a fluid having a higher flow rate than the spray nozzle 41 and is discharged from the water outlet 3 in a mist state.
【００１３】図３は、本発明に用いる炭酸ガスを除去す
る装置の、多孔板を模式図により示したものである。水
は、吐出口に取り付けられた多孔板５のそれぞれの穴か
ら複数の流れとなって吐出される。FIG. 3 is a schematic diagram showing a perforated plate of the apparatus for removing carbon dioxide used in the present invention. Water is discharged as a plurality of flows from each hole of the perforated plate 5 attached to the discharge port.
【００１４】図４は、本発明によるミネラル成分溶解水
製造方法を用い、循環通水によりミネラル成分溶解水を
製造する装置の一例を示すフローである。貯水タンク６
内の飲用水は、送液ポンプ７により矢印Ａ及びＢに従
い、炭酸ガス添加部８に供給され炭酸ガスを溶解し、更
に、石灰岩充填部９を通過する際に飲用水中の炭酸ガス
の作用によりカルシウムを溶解し、三方コック１０によ
り矢印Ｃ及びＤに従い貯水タンク６に戻される。循環通
水によりカルシウムを溶解した水は、三方コック１０の
切り替え操作により矢印Ｅに従い炭酸ガス除去機能を有
する吐水口１１に通水され使用者に供給される。又、炭
酸ガスは矢印Ｆに従い、疎水性の多孔質中空糸膜モジュ
ール１２の中空部に供給され、多孔質膜の微細孔から微
少な気泡として炭酸ガス添加部８に放出され飲用水中に
溶解する。FIG. 4 is a flow chart showing an example of an apparatus for producing mineral component dissolved water by circulating water using the mineral component dissolved water producing method according to the present invention. Water storage tank 6
The drinking water inside is supplied to the carbon dioxide gas adding section 8 by the liquid sending pump 7 according to arrows A and B to dissolve the carbon dioxide gas, and furthermore, the action of the carbon dioxide gas in the drinking water when passing through the limestone filling section 9. To dissolve the calcium, and returned to the water storage tank 6 by the three-way cock 10 according to arrows C and D. The water in which the calcium has been dissolved by the circulating water is passed through the water outlet 11 having a carbon dioxide gas removing function according to the arrow E by the switching operation of the three-way cock 10 and supplied to the user. Further, the carbon dioxide gas is supplied to the hollow portion of the hydrophobic porous hollow fiber membrane module 12 according to the arrow F, and is released as fine bubbles from the fine pores of the porous membrane to the carbon dioxide gas adding portion 8 and dissolved in the drinking water. I do.
【００１５】図５は、本発明によるミネラル成分溶解水
製造方法を用い、連続通水によりミネラル成分溶解水を
製造する装置の一例を示すフローである。水は、矢印Ａ
に従い炭酸ガス添加部８に供給され炭酸ガスを溶解し、
更に、石灰岩充填部９を通過する際に飲用水中の炭酸ガ
スの作用によりカルシウムを溶解する。更に、矢印Ｂに
従い炭酸ガス除去機能を有する吐水口１１に通水され使
用者に供給される。又、炭酸ガスは、矢印Ｆに従い、疎
水性の多孔質中空糸膜モジュール１２の中空部に供給さ
れ、多孔質膜の微細孔から微少な気泡として炭酸ガス添
加部８に放出され飲用水中に溶解する。FIG. 5 is a flow chart showing an example of an apparatus for producing mineral component dissolved water by continuous water flow using the method for producing mineral component dissolved water according to the present invention. Water is arrow A
Is supplied to the carbon dioxide gas adding section 8 to dissolve the carbon dioxide gas,
Further, when passing through the limestone filling portion 9, calcium is dissolved by the action of carbon dioxide in the drinking water. Further, water is supplied to the user through the water outlet 11 having a carbon dioxide gas removing function according to the arrow B. Further, the carbon dioxide gas is supplied to the hollow portion of the hydrophobic porous hollow fiber membrane module 12 according to the arrow F, and is released as fine bubbles from the micropores of the porous membrane to the carbon dioxide gas addition portion 8 to be added to the drinking water. Dissolve.
【００１６】[0016]
【実施例】以下、実施例を用いて、本発明を更に詳細に
説明する。 （実施例１）図１に示されるアスピレーターの空気吸入
口２を大気中に開放し、水温２０℃の酸度１０１．２pp
m 調製水を水流量０．５Ｌ／min で通水し、吐水後の酸
度を測定した結果、酸度は４９．７ppm に減少し、除去
率は５０．８％であった。又、このときの圧力損失は、
０．０５kg／cm2 であった。The present invention will be described in more detail with reference to the following examples. (Example 1) The air suction port 2 of the aspirator shown in FIG. 1 was opened to the atmosphere, and the acidity was 101.2 pp at a water temperature of 20 ° C.
m The prepared water was passed at a flow rate of 0.5 L / min, and the acidity after water discharge was measured. As a result, the acidity was reduced to 49.7 ppm, and the removal rate was 50.8%. The pressure loss at this time is
It was 0.05 kg / cm 2 .
【００１７】（実施例２）図２に示されるスプレーノズ
ルに、水温２０℃の酸度９８．５ppm 調製水を水流量
０．５Ｌ／min で通水し、吐水後の酸度を測定した結
果、酸度は１１．７ppm に減少し、除去率は８８．１％
であった。又、このときの圧力損失は、０．３５kg／cm
2 であった。(Embodiment 2) 98.5 ppm of acidity at a water temperature of 20 ° C. was passed through a spray nozzle shown in FIG. 2 at a water flow rate of 0.5 L / min, and the acidity after water discharge was measured. Is reduced to 11.7 ppm and the removal rate is 88.1%
Met. The pressure loss at this time is 0.35 kg / cm
Was 2 .
【００１８】（実施例３）図３に示される多孔板を取り
付けた吐水口に、酸度１００．５ppm 調製水を水流量
０．５Ｌ／min で通水し、吐水後の酸度を測定した結
果、酸度は５８．４ppm に減少し、除去率は４１．９％
であった。又、このときの圧力損失は、０．０１kg／cm
2 であった。(Example 3) As a result of measuring the acidity after discharging water, a prepared water having an acidity of 100.5 ppm was passed at a water flow rate of 0.5 L / min through a water outlet provided with a perforated plate shown in FIG. Acidity reduced to 58.4 ppm, removal rate 41.9%
Met. The pressure loss at this time is 0.01 kg / cm
Was 2 .
【００１９】（実施例４）図４に示されるフローの吐水
口１１にスプレーノズルを取り付け、酸度３ppm 、カル
シウム濃度８ppm の水を酸度２００ppm に調製し、貯水
タンク容量３Ｌ、循環流量０．５Ｌ／min 、石灰岩充填
量２００ｇ、水温２０℃で３分間循環通水を行った後、
スプレーノズルを取り付けた吐水口より吐水し、処理水
の酸度及びカルシウム濃度を測定した結果、酸度２４pp
m 、カルシウム濃度３０ppm であり、酸度、カルシウム
濃度共に厚生省のおいしい水研究会によるおいしいと感
じる範囲内であった。(Embodiment 4) A spray nozzle is attached to the water discharge port 11 of the flow shown in FIG. 4, and water having an acidity of 3 ppm and a calcium concentration of 8 ppm is adjusted to an acidity of 200 ppm, a storage tank capacity of 3 L and a circulating flow of 0.5 L / min, 200 g of limestone filling, and water circulation at 20 ° C. for 3 minutes.
Water was spouted from a spout with a spray nozzle, and the acidity and calcium concentration of the treated water were measured.
m, the calcium concentration was 30 ppm, and both the acidity and the calcium concentration were within the range that was felt delicious by the Ministry of Health and Welfare's Delicious Water Research Group.
【００２０】（比較例１）実施例４に用いたフローの吐
水口に取り付けられたスプレーノズルを取り外し、酸度
３ppm 、カルシウム濃度８ppm の水を酸度２００ppm に
調製し、貯水タンク容量３Ｌ、循環流量０．５Ｌ／min
、石灰岩充填量２００ｇ、水温２０℃で３分間循環通
水を行った後、吐水口より吐水し処理水の酸度及びカル
シウム濃度を測定した結果、酸度１８０ppm 、カルシウ
ム濃度３０ppm であり、酸度が厚生省のおいしい水研究
会によるおいしいと感じる範囲を大きく超えていた。(Comparative Example 1) The spray nozzle attached to the outlet of the flow used in Example 4 was removed, and water having an acidity of 3 ppm and a calcium concentration of 8 ppm was adjusted to an acidity of 200 ppm, a storage tank capacity of 3 L, and a circulation flow rate of 0. .5L / min
After circulating water at a limestone filling amount of 200 g and a water temperature of 20 ° C. for 3 minutes, water was discharged from the water outlet and the acidity and calcium concentration of the treated water were measured. As a result, the acidity was 180 ppm and the calcium concentration was 30 ppm. It was far beyond the range that I felt delicious by the Delicious Water Study Group.
【００２１】（比較例２）実施例４に用いたフローの吐
水口に取り付けられたスプレーノズルを取り外し、酸度
３ppm 、カルシウム濃度８ppm の水を酸度６０ppm に調
製し、貯水タンク容量３Ｌ、循環流量０．５Ｌ／min 、
石灰岩充填量２００ｇ、水温２０℃で３０分間循環通水
を行った後、吐水口より吐水し処理水の酸度及びカルシ
ウム濃度を測定した結果、酸度２５ppm 、カルシウム濃
度３０ppm であり、酸度、カルシウム濃度共に厚生省の
おいしい水研究会によるおいしいと感じる範囲内ではあ
るが、生成時間が３０分もかかってしまった。(Comparative Example 2) The spray nozzle attached to the water outlet of the flow used in Example 4 was removed, and water having an acidity of 3 ppm and a calcium concentration of 8 ppm was adjusted to an acidity of 60 ppm. .5L / min,
After circulating water at a limestone filling amount of 200 g and a water temperature of 20 ° C. for 30 minutes, water was discharged from the water outlet and the acidity and calcium concentration of the treated water were measured. As a result, the acidity was 25 ppm and the calcium concentration was 30 ppm. Although it was within the range of feeling delicious by the Ministry of Health and Welfare Water Study Group, it took 30 minutes to generate.
【００２２】（実施例５）図５に示されるフローの吐水
口に空気吸入口を大気中に開放したアスピレーターを取
り付け、酸度３ppm 、カルシウム濃度８ppm の水を酸度
８０ppm に調製し、通水流量０．５Ｌ／min 、石灰岩充
填量２００ｇ、水温２０℃で連続通水を行い、アスピレ
ーターの吐水口より吐水した処理水の酸度及びカルシウ
ム濃度を測定した結果、酸度２４ppm 、カルシウム濃度
２９ppm であり、酸度、カルシウム濃度共に厚生省のお
いしい水研究会によるおいしいと感じる範囲内であっ
た。(Example 5) An aspirator having an air suction port opened to the air was attached to the water outlet of the flow shown in FIG. 5, water having an acidity of 3 ppm and a calcium concentration of 8 ppm was adjusted to an acidity of 80 ppm, and the flow rate of water was 0. 0.5 L / min, a limestone filling amount of 200 g, and a continuous water flow at a water temperature of 20 ° C. As a result of measuring the acidity and the calcium concentration of the treated water discharged from the water outlet of the aspirator, the acidity was 24 ppm and the calcium concentration was 29 ppm. Both calcium concentrations were within the range that we felt as delicious by the Ministry of Health and Welfare's Delicious Water Study Group.
【００２３】（比較例３）実施例５に用いたフローの吐
水口に取り付けられたアスピレーターを取り外し、酸度
３ppm 、カルシウム濃度８ppm の水を酸度８０ppm に調
製し、通水流量０．５Ｌ／min 、石灰岩充填量２００
ｇ、水温２０℃で連続通水を行い、吐水口より吐水した
処理水の酸度及びカルシウム濃度を測定した結果、酸度
５８ppm 、カルシウム濃度３１ppm であり、酸度が厚生
省のおいしい水研究会によるおいしいと感じる範囲を大
きく超えていた。(Comparative Example 3) The aspirator attached to the water outlet of the flow used in Example 5 was removed, water having an acidity of 3 ppm and a calcium concentration of 8 ppm was adjusted to an acidity of 80 ppm, and a flow rate of water was 0.5 L / min. Limestone filling 200
g, continuous water flow at a water temperature of 20 ° C., and the acidity and calcium concentration of the treated water spouted from the spout were measured. As a result, the acidity was 58 ppm and the calcium concentration was 31 ppm. It was far beyond the range.
【００２４】（比較例４）実施例５に用いたフローの吐
水口に取り付けられたアスピレーターを取り外し、酸度
３ppm 、カルシウム濃度８ppm の水を酸度５０ppm に調
製し、通水流量０．５Ｌ／min 、石灰岩充填量２０００
ｇ、水温２０℃で連続通水を行い、吐水口より吐水した
処理水の酸度及びカルシウム濃度を測定した結果、酸度
２６ppm 、カルシウム濃度２９ppm であり、酸度、カル
シウム濃度共に厚生省のおいしい水研究会によるおいし
いと感じる範囲内ではあるが、石灰岩の充填量が２００
０ｇも必要であった。(Comparative Example 4) The aspirator attached to the water outlet of the flow used in Example 5 was removed, and water having an acidity of 3 ppm and a calcium concentration of 8 ppm was adjusted to an acidity of 50 ppm, and a flow rate of water was 0.5 L / min. Limestone filling 2000
g, continuous water flow at a water temperature of 20 ° C., and the acidity and calcium concentration of the treated water spouted from the spout were measured. As a result, the acidity was 26 ppm and the calcium concentration was 29 ppm. Although it is within the range that tastes good, the filling amount of limestone is 200
0 g was also required.
【００２５】（実施例６）実施例４及び５、比較例１及
び３の四点の水を２０人に飲んでもらいおいしい順位を
つけたところ、以下の表１のように２０人中１７人が、
実施例４あるいは実施例５の水を一位に選んだ。(Example 6) When 20 people drink four points of water of Examples 4 and 5, and Comparative Examples 1 and 3, and rank them delicious, 17 people out of 20 as shown in Table 1 below. But,
The water of Example 4 or Example 5 was selected first.
【００２６】[0026]
【表１】 [Table 1]
【００２７】実施例１，２及び３の評価結果により、炭
酸ガス除去方法により炭酸ガス除去性能はそれぞれ異な
るため、必要に応じて適宜選択する必要があることが判
明した。又、実施例４及び比較例１及び２の評価結果よ
り、循環通水によりミネラル成分溶解水を製造する場合
には、本発明による実施例４は、比較例１及び２に比べ
非常に短時間に、厚生省のおいしい水研究会によるおい
しいと感じる遊離炭酸（酸度）及び硬度（カルシウム濃
度）範囲の水を使用者に提供することが出来ることが明
らかとなった。更に、実施例５及び比較例３及び４の評
価結果により、連続通水によりミネラル成分溶解水を製
造する場合には、本発明による実施例５は、比較例３及
び４に比べ非常に少ないミネラル成分充填量で、厚生省
のおいしい水研究会によるおいしいと感じる遊離炭酸
（酸度）及び硬度（カルシウム濃度）範囲の水を使用者
に提供することが出来ることが明らかとなった。又更
に、実施例６の評価結果より、厚生省のおいしい水研究
会によるおいしいと感じる遊離炭酸（酸度）の範囲を超
えた水は、おいしい範囲内の水に比べおいしくないと判
断する人が多いことが明らかとなった。From the evaluation results of Examples 1, 2, and 3, it was found that the carbon dioxide gas removal performance differs depending on the carbon dioxide gas removal method, and it is necessary to select an appropriate one as needed. Also, according to the evaluation results of Example 4 and Comparative Examples 1 and 2, when the mineral component-dissolved water is produced by circulating water, Example 4 according to the present invention is much shorter than Comparative Examples 1 and 2. In addition, it became clear that water with a range of free carbonic acid (acidity) and hardness (calcium concentration) that can be tasted by the Ministry of Health and Welfare's Delicious Water Research Group can be provided to users. Furthermore, according to the evaluation results of Example 5 and Comparative Examples 3 and 4, when the mineral component-dissolved water is produced by continuous water passing, Example 5 according to the present invention is much less mineral than Comparative Examples 3 and 4. It became clear that the amount of the ingredients can provide the user with water in the range of free carbonic acid (acidity) and hardness (calcium concentration), which is considered to be delicious by the Ministry of Health and Welfare's Delicious Water Research Group. Furthermore, from the evaluation results of Example 6, many people who judge that water exceeding the range of free carbonic acid (acidity) that tastes good by the Ministry of Health and Welfare's Delicious Water Research Group are not more delicious than water within the delicious range. Became clear.
【００２８】[0028]
【発明の効果】かかる構成により、本発明のミネラル成
分溶解水製造方法によれば、炭酸ガスを溶解させ高酸度
水とした水を難溶性ミネラル成分含有物質に接触通水
し、短時間にミネラル成分を溶解し、更に、過剰の炭酸
ガスを空気中に放出させ低遊離炭酸水とし、厚生省のお
いしい水研究会によるおいしいと感じる遊離炭酸及び硬
度の飲用水を容易に得ることができる。又、通水経路に
残留塩素、トリハロメタン、臭い等を除去する活性炭
や、濁度成分、細菌等を濾過する中空糸膜等からなる浄
水装置を設けると、より衛生的なミネラル成分溶解水を
製造することができる。According to the method for producing mineral component dissolved water of the present invention, water having high acidity by dissolving carbon dioxide gas is brought into contact with the hardly soluble mineral component-containing substance, and the mineral component is dissolved in a short time. By dissolving the components, excess carbon dioxide gas is released into the air to make low free carbonated water, so that drinking water with free carbonic acid and hardness that feels delicious by the Delicious Water Research Society of the Ministry of Health and Welfare can be easily obtained. In addition, if a water purification device consisting of activated carbon that removes residual chlorine, trihalomethane, odor, etc., and a hollow fiber membrane that filters turbidity components, bacteria, etc. is installed in the water passage, more sanitary mineral component dissolved water can be produced. can do.
【図１】本発明に用いる過剰の炭酸ガスを除去する装置
の、アスピレーターを示す模式図。FIG. 1 is a schematic diagram showing an aspirator of an apparatus for removing excess carbon dioxide used in the present invention.
【図２】本発明に用いる過剰の炭酸ガスを除去する装置
の、スプレーノズルを示す模式図。FIG. 2 is a schematic view showing a spray nozzle of an apparatus for removing excess carbon dioxide gas used in the present invention.
【図３】本発明に用いる過剰の炭酸ガスを除去する装置
の、吐水口に取り付けられた多孔板を示す模式図。FIG. 3 is a schematic view showing a perforated plate attached to a water outlet of the apparatus for removing excess carbon dioxide gas used in the present invention.
【図４】本発明によるミネラル成分溶解水製造方法を用
い、循環通水によりミネラル成分溶解水を製造する装置
の一例を示すフロー。FIG. 4 is a flowchart showing an example of an apparatus for producing mineral component dissolved water by circulating water using the method for producing mineral component dissolved water according to the present invention.
【図５】本発明によるミネラル成分溶解水製造方法を用
い、連続通水によりミネラル成分溶解水を製造する装置
の一例を示すフロー。FIG. 5 is a flowchart showing an example of an apparatus for producing mineral component dissolved water by continuous water flow using the method for producing mineral component dissolved water according to the present invention.
Ａ，Ｂ，Ｃ，Ｄ，Ｅ…水の流れを示す矢印 Ｆ…炭酸ガスの流れを示す矢印 １…水の入り口 ２…空気の入り口 ３…水の出口 ４…スプレーノズル ５…多孔板 ６…貯水タンク ７…送液ポンプ ８…炭酸ガス添加部 ９…石灰岩充填部 １０…三方コック １１…吐水口 １２…多孔質中空糸膜モジュール A, B, C, D, E: Arrows indicating the flow of water F: Arrows indicating the flow of carbon dioxide gas 1 ... Inlet of water 2 ... Inlet of air 3 ... Outlet of water 4 ... Spray nozzle 5 ... Perforated plate 6 ... Reservoir tank 7 Liquid pump 8 Carbon dioxide gas adding section 9 Limestone filling section 10 Three-way cock 11 Water outlet 12 Porous hollow fiber membrane module
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｂ０１Ｆ 1/00 Ｂ０１Ｆ 1/00 Ｆ Ｃ０２Ｆ 1/20 Ｃ０２Ｆ 1/20 Ａ２３Ｌ 2/00 Ｖ ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 6 Identification number Office reference number FI Technical display location B01F 1/00 B01F 1/00 F C02F 1/20 C02F 1/20 A23L 2/00 V
Claims (9)
ネラル成分含有物質に接触通水しミネラル成分を溶解さ
せ、ミネラル成分溶解後の飲用水中に溶存する過剰の炭
酸ガスを除去し、ミネラル成分溶解水を得ることを特徴
とするミネラル成分溶解水製造方法。Claims: 1. A carbon dioxide gas is added to drinking water, and the mineral component is dissolved by contacting and passing through a substance containing a hardly soluble mineral component to remove excess carbon dioxide gas dissolved in the drinking water after dissolving the mineral component. A method for producing mineral component dissolved water, comprising obtaining mineral component dissolved water.
る過剰の炭酸ガスの除去方法が、水と空気の接触面積を
大きくし、分圧差により液相から気相に炭酸ガスを移動
させ飲用水中から炭酸ガスを除去する方法であることを
特徴とする請求項１記載のミネラル成分溶解水製造方
法。2. A method for removing excess carbon dioxide dissolved in drinking water after dissolving mineral components increases a contact area between water and air, and moves carbon dioxide from a liquid phase to a gas phase due to a partial pressure difference. The method for producing mineral component-dissolved water according to claim 1, wherein the method is a method for removing carbon dioxide from water.
酸ガス添加装置、ミネラル成分充填カートリッジからな
る、循環通水によりミネラル成分溶解水を得る装置にお
いて、吐水口に過剰の炭酸ガスを除去する装置を取り付
けてなることを特徴とするミネラル成分溶解水製造装
置。3. A device for obtaining mineral component dissolved water by circulating water, comprising at least a water storage tank, a liquid sending pump, a carbon dioxide gas adding device, and a mineral component filling cartridge. An apparatus for producing a mineral component-dissolved water, which is attached.
成分充填カートリッジからなる、連続通水によりミネラ
ル成分溶解水を得る装置において、吐水口に過剰の炭酸
ガスを除去する装置を取り付けてなることを特徴とする
ミネラル成分溶解水製造装置。4. A device for obtaining mineral component dissolved water by continuous water supply, comprising at least a carbon dioxide gas adding device and a mineral component filling cartridge, wherein a device for removing excess carbon dioxide gas is attached to a water discharge port. Mineral component dissolved water production equipment.
の酸度が３．４ppmから３４ppm 、カルシウム濃度が４p
pm から４０ppm の範囲であることを特徴とする請求項
３又は４記載のミネラル成分溶解水製造装置。5. The mineral acid dissolved water provided to the user has an acidity of 3.4 ppm to 34 ppm and a calcium concentration of 4 p.
5. The apparatus for producing a mineral component-dissolved water according to claim 3, wherein the content is in the range of pm to 40 ppm.
吸入口を大気中に開放したアスピレーターであることを
特徴とする請求項３，４又は５記載のミネラル成分溶解
水製造装置。6. The apparatus for producing dissolved mineral component water according to claim 3, wherein the apparatus for removing excess carbon dioxide is an aspirator having an air suction port opened to the atmosphere.
レーノズル状吐水口であることを特徴とする請求項３，
４又は５記載のミネラル成分溶解水製造装置。7. The apparatus according to claim 3, wherein the apparatus for removing excess carbon dioxide is a spray nozzle-shaped water outlet.
6. The apparatus for producing mineral component dissolved water according to 4 or 5.
ワーヘッド状多孔板であることを特徴とする請求項３，
４又は５記載のミネラル成分溶解水製造装置。8. The apparatus according to claim 3, wherein the apparatus for removing excess carbon dioxide is a showerhead-shaped perforated plate.
6. The apparatus for producing mineral component dissolved water according to 4 or 5.
ルシウムを主成分とする天然物であることを特徴とする
請求項３，４，５，６，７又は８記載のミネラル成分溶
解水製造装置。9. The apparatus for producing dissolved mineral component water according to claim 3, wherein the hardly soluble mineral component-containing substance is a natural product containing calcium carbonate as a main component. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8169613A JPH1015562A (en) | 1996-06-28 | 1996-06-28 | Method and apparatus for producing mineral component dissolved water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8169613A JPH1015562A (en) | 1996-06-28 | 1996-06-28 | Method and apparatus for producing mineral component dissolved water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1015562A true JPH1015562A (en) | 1998-01-20 |
Family
ID=15889752
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8169613A Pending JPH1015562A (en) | 1996-06-28 | 1996-06-28 | Method and apparatus for producing mineral component dissolved water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH1015562A (en) |
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| JP2004305472A (en) * | 2003-04-08 | 2004-11-04 | Mitsubishi Rayon Co Ltd | Apparatus and method for manufacturing weak acidic disinfectant |
| JP2009233668A (en) * | 2009-07-22 | 2009-10-15 | Japan Organo Co Ltd | Electrical deionized water manufacturing apparatus |
| JP2011217636A (en) * | 2010-04-06 | 2011-11-04 | Suntory Holdings Ltd | Liquid composition containing aromatic component derived from roasted coffee beans, solid, food and drink, and process of producing the liquid composition |
| JP2014184379A (en) * | 2013-03-22 | 2014-10-02 | Miura Co Ltd | Water treatment apparatus |
| RU2564336C2 (en) * | 2010-08-13 | 2015-09-27 | Омиа Интернэшнл Аг | System for feed of suspension of finely-ground caco3 for remineralisation of desalted and sweet water |
| CN118637789A (en) * | 2024-08-06 | 2024-09-13 | 杭州老板电器股份有限公司 | Mineralization-adjustable water purification system and control method thereof |
-
1996
- 1996-06-28 JP JP8169613A patent/JPH1015562A/en active Pending
Cited By (8)
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|---|---|---|---|---|
| US6811800B2 (en) | 1998-09-29 | 2004-11-02 | The Procter & Gamble Co. | Calcium fortified beverages |
| US6994877B2 (en) | 1998-09-29 | 2006-02-07 | The Procter + Gamble Co. | Calcium fortified beverages |
| JP2004305472A (en) * | 2003-04-08 | 2004-11-04 | Mitsubishi Rayon Co Ltd | Apparatus and method for manufacturing weak acidic disinfectant |
| JP2009233668A (en) * | 2009-07-22 | 2009-10-15 | Japan Organo Co Ltd | Electrical deionized water manufacturing apparatus |
| JP2011217636A (en) * | 2010-04-06 | 2011-11-04 | Suntory Holdings Ltd | Liquid composition containing aromatic component derived from roasted coffee beans, solid, food and drink, and process of producing the liquid composition |
| RU2564336C2 (en) * | 2010-08-13 | 2015-09-27 | Омиа Интернэшнл Аг | System for feed of suspension of finely-ground caco3 for remineralisation of desalted and sweet water |
| JP2014184379A (en) * | 2013-03-22 | 2014-10-02 | Miura Co Ltd | Water treatment apparatus |
| CN118637789A (en) * | 2024-08-06 | 2024-09-13 | 杭州老板电器股份有限公司 | Mineralization-adjustable water purification system and control method thereof |
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