JPH10102265A - Wear resistant material and its production - Google Patents
Wear resistant material and its productionInfo
- Publication number
- JPH10102265A JPH10102265A JP25445796A JP25445796A JPH10102265A JP H10102265 A JPH10102265 A JP H10102265A JP 25445796 A JP25445796 A JP 25445796A JP 25445796 A JP25445796 A JP 25445796A JP H10102265 A JPH10102265 A JP H10102265A
- Authority
- JP
- Japan
- Prior art keywords
- hard particles
- wear
- particles
- resistant material
- soft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、軸受部材などの摺
動部に用いられるものであって、アルミニウム等の軟質
・易加工金属の表面に、複数個の硬質粒子を埋め込み形
成して成る耐摩耗材料及びその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used for a sliding portion such as a bearing member, and is formed by embedding a plurality of hard particles on a surface of a soft and easily processed metal such as aluminum. The present invention relates to a wear material and a method for manufacturing the same.
【0002】[0002]
【従来の技術】この種の耐摩耗材料に近似する技術とし
て、従来、特開昭63−16106号公報に示されるも
のがある。この従来技術は、エンジンのバルブリフタに
関するものであり、そのバルブリフタの本体を、比較的
軟らかくて、機械加工しやすい軟質・易加工金属、例え
ばアルミニウム合金で構成し、バルブステムが当接する
バルブステム当接部を、耐摩耗面に構成してある。この
耐摩耗面は、本体を形成するアルミニウム合金の表面
に、角部を含む不規則形状から成り、粒径が30〜20
0μmの硬質粒子を、ポンチを用いて押圧して埋め込ん
で形成したものである。2. Description of the Related Art A technique similar to this kind of wear-resistant material is disclosed in Japanese Patent Application Laid-Open No. 63-16106. This prior art relates to a valve lifter of an engine, and the main body of the valve lifter is made of a soft and easy-to-machine metal, for example, an aluminum alloy, which is relatively soft and easy to machine, and the valve stem abuts against the valve stem. The part is configured as a wear-resistant surface. The wear-resistant surface has an irregular shape including a corner on the surface of the aluminum alloy forming the main body, and has a particle size of 30 to 20.
It is formed by pressing and embedding 0 μm hard particles using a punch.
【0003】[0003]
【発明が解決しようとする課題】上述した従来技術は、
本体をアルミニウム合金で構成したことによる軽量化
と、硬質粒子による耐摩耗性とを同時に実現できる利点
があるものの、本発明が対象としているような軸受部材
等の摺動部に用いられるものではないので、直線的摺動
運動あるいは回転的摺動運動に対する耐摩耗性は考慮さ
れていない。The prior art described above is
Although the main body is made of an aluminum alloy, there is an advantage that weight reduction and wear resistance due to hard particles can be realized at the same time, but it is not used for a sliding portion such as a bearing member as the object of the present invention. Therefore, no consideration is given to the abrasion resistance to linear sliding movement or rotational sliding movement.
【0004】すなわち、上述した従来技術では、硬質粒
子の形状が角部を含む不規則形状であることから、仮に
直線的摺動運動あるいは回転的摺動運動が実施される部
分に適用したときには、その角部から急激な損耗が進行
してしまう懸念がある。したがって、上述した従来技術
は、本発明が対象としているような摺動部には、そのま
ま適用することができない。That is, in the above-mentioned prior art, since the shape of the hard particles is irregular including a corner, if the hard particles are applied to a portion where a linear sliding motion or a rotary sliding motion is performed, There is a concern that rapid wear may progress from the corner. Therefore, the above-described prior art cannot be applied to a sliding portion as the object of the present invention as it is.
【0005】本発明は、上記した従来技術における実状
に鑑みてなされたもので、その第1の目的は、硬質粒子
の損耗がきわめて少なく、しかも円滑な摺動動作を実現
させることのできる耐摩耗材料を提供することにある。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned situation in the prior art, and a first object of the present invention is to provide a wear-resistant material capable of realizing a smooth sliding operation with very little wear of hard particles. It is to provide materials.
【0006】また、本発明の第2の目的は、軟質・易加
工金属の表面に球形状粒子から成る硬質粒子を埋め込ん
だ耐摩耗材料を製造することができる耐摩耗材料の製造
方法を提供することにある。A second object of the present invention is to provide a method for producing a wear-resistant material capable of producing a wear-resistant material in which hard particles composed of spherical particles are embedded in the surface of a soft and easily processed metal. It is in.
【0007】[0007]
【課題を解決するための手段】上記第1の目的を達成す
るために、本発明の請求項1に係る発明は、摺動部に用
いられ、比較的軟らかい金属材料から成り、しかも機械
加工の容易な軟質・易加工金属の表面に、この軟質・易
加工金属よりも硬い硬質粒子を複数個埋め込み、これら
の硬質粒子が埋め込まれた軟質・易加工金属の表面部分
を耐摩耗面とした耐摩耗材料において、上記硬質粒子が
球形状粒子から成るとともに、これらの硬質粒子間に形
成される間隙部分に潤滑剤を保有させた構成にしてあ
る。In order to achieve the first object, the invention according to claim 1 of the present invention is used for a sliding portion, is made of a relatively soft metal material, and is used for machining. A plurality of hard particles harder than the soft / easy-working metal are embedded on the surface of the easy-soft / easy-working metal, and the surface of the soft / easy-working metal in which the hard particles are embedded is used as a wear-resistant surface. In the wear material, the hard particles are formed of spherical particles, and a lubricant is held in a gap formed between the hard particles.
【0008】このように構成した請求項1に係る発明で
は、硬質粒子が球形状粒子から成るので、摺動部を形成
する他の移動部材が硬質粒子に摺動接触する際には、球
面摺動接触に近似した状態になり、これにより当該硬質
粒子の損耗を最少限度に抑えながらも良好な摺動動作を
おこなわせることができる。また、硬質粒子間の間隙部
分に潤滑剤を保有させてあるので、この潤滑剤によって
も硬質粒子の損耗が抑えられ、かつ、円滑な摺動動作を
実現させることができる。According to the first aspect of the present invention, since the hard particles are composed of spherical particles, when the other moving member forming the sliding portion comes into sliding contact with the hard particles, the spherical sliding member is used. A state similar to a dynamic contact is obtained, whereby a good sliding operation can be performed while minimizing the wear of the hard particles. In addition, since the lubricant is held in the gap between the hard particles, the wear of the hard particles can be suppressed by this lubricant, and a smooth sliding operation can be realized.
【0009】また上記第1の目的を達成するために、本
発明の請求項2に係る発明は、本発明の請求項1に係る
発明において、上記軟質・易加工金属が、アルミニウ
ム、銅、ニッケル、及びこれらのアルミニウム、銅、ニ
ッケルのいずれかを母材とする合金のうちの1つから成
る構成にしてある。In order to achieve the first object, the invention according to claim 2 of the present invention is directed to the invention according to claim 1, wherein the soft and easily workable metal is aluminum, copper, nickel, , And one of the alloys based on any of aluminum, copper and nickel.
【0010】このように構成した請求項2に係る発明で
は、特に、それぞれ比較的軟らかい金属材料で、しかも
機械加工しやすいので硬質粒子を埋め込ませる軟質・易
加工金属として好適であり、また、入手しやすい。[0010] In the invention according to claim 2 configured as described above, in particular, each is made of a relatively soft metal material and is easy to machine, so that it is suitable as a soft and easy-to-work metal in which hard particles are embedded. It's easy to do.
【0011】また上記第1の目的を達成するために、本
発明の請求項3に係る発明は、本発明の請求項1または
2に係る発明において、上記硬質粒子が、クロム、及び
コバルトのいずれかを母材とする合金から成る構成にし
てある。In order to achieve the first object, the invention according to claim 3 of the present invention is directed to the invention according to claim 1 or 2, wherein the hard particles are any one of chromium and cobalt. It is made up of an alloy with this as the base material.
【0012】このように構成した請求項3に係る発明で
は、特に、それぞれ耐摩耗性を有する硬質粒子として好
適であり、またこれらも比較的入手しやすい。The invention according to claim 3 having such a constitution is particularly suitable as hard particles each having wear resistance, and these are also relatively easily available.
【0013】また上記第1の目的を達成するために、本
発明の請求項4に係る発明は、本発明の請求項1〜3の
いずれかに係る発明において、上記摺動部が、直線運
動、及び回転運動の少なくとも一方をおこなう移動部材
と、この移動部材を保持する保持部材とから成り、上記
保持部材の上記移動部材に対向する面を、上記硬質粒子
が含まれる耐摩耗面とした構成にしてある。In order to achieve the first object, the invention according to claim 4 of the present invention is directed to the invention according to any one of claims 1 to 3 of the present invention, wherein the sliding portion is moved linearly. , And a moving member that performs at least one of the rotational movements, and a holding member that holds the moving member, wherein a surface of the holding member facing the moving member is a wear-resistant surface containing the hard particles. It is.
【0014】このように構成した請求項4に係る発明で
は、特に、摺動部を形成する部材として複雑な形状が要
求されるような場合に、軟質・易加工金属の部分を加工
することにより、容易に所望の形状とすることができ
る。According to the fourth aspect of the present invention, when a complicated shape is required as a member for forming the sliding portion, the soft and easily-workable metal portion is processed. The desired shape can be easily obtained.
【0015】また上記第1の目的を達成するために、本
発明の請求項5に係る発明は、本発明の請求項1〜4の
いずれかに係る発明において、上記耐摩耗面を、上記軟
質・易加工金属の表面と直交する方向に、上記硬質粒子
を複数段埋設して成る層状部に形成した構成にしてあ
る。In order to achieve the first object, the invention according to claim 5 of the present invention relates to the invention according to any one of claims 1 to 4 of the present invention, wherein -A configuration in which the hard particles are formed in a layered portion formed by embedding a plurality of steps in a direction orthogonal to the surface of the easily processed metal.
【0016】このように構成した請求項5に係る発明で
は、特に、複数段の硬質粒子により堅牢な耐摩耗面を形
成させることができる。According to the fifth aspect of the invention, a hard wear-resistant surface can be formed by a plurality of hard particles.
【0017】また上記第1の目的を達成するために、本
発明の請求項6に係る発明は、本発明の請求項5に係る
発明において、上記層状部の厚さ寸法を、10〜500
μmの範囲内、好ましくは20〜200μmの範囲内に
設定した構成にしてある。In order to achieve the first object, the invention according to claim 6 of the present invention relates to the invention according to claim 5 of the present invention, wherein the thickness of the layered portion is 10 to 500.
The configuration is set within the range of μm, preferably within the range of 20 to 200 μm.
【0018】このように構成した請求項6に係る発明で
は、特に、硬質粒子の埋め込みに伴う軟質・易加工金属
の変形を少なくし、これによりこの軟質・易加工金属に
生じる残留応力を小さくすることができ、しかも、この
軟質・易加工金属として必要とされる材料の量を抑える
ことができる。According to the sixth aspect of the present invention, particularly, the deformation of the soft / easy-working metal due to the embedding of the hard particles is reduced, thereby reducing the residual stress generated in the soft / easy-working metal. In addition, the amount of material required for the soft and easily processed metal can be reduced.
【0019】また上記第1の目的を達成するために、本
発明の請求項7に係る発明は、本発明の請求項1〜6の
いずれかに係る発明において、上記硬質粒子は、大径粒
子と小径粒子を混在させたものから成り、上記大径粒子
の径寸法と小径粒子の径寸法との比を「6/4」以上に
設定した構成にしてある。In order to achieve the first object, the invention according to claim 7 of the present invention is directed to the invention according to any one of claims 1 to 6 of the present invention, wherein the hard particles are large-diameter particles. And small diameter particles are mixed, and the ratio of the diameter of the large diameter particles to the diameter of the small diameter particles is set to “6/4” or more.
【0020】このように構成した請求項7に係る発明で
は、特に、耐摩耗面を形成する表面部分に配置される大
径粒子の数が多くなることから、主に大径粒子が、摺動
部を形成する他の移動部材に接触し、上述した請求項1
に係る発明について説明した球面摺動接触に近似した接
触状態の形成に役立つ。[0020] In the invention according to claim 7 configured as described above, in particular, the number of large-diameter particles disposed on the surface portion forming the abrasion-resistant surface increases, so that the large-diameter particles mainly slide. 2. The method according to claim 1, wherein the movable member contacts another moving member forming the portion.
It is useful for forming a contact state similar to the spherical sliding contact described in the invention according to the above.
【0021】また上記第1の目的を達成するために、本
発明の請求項8に係る発明は、本発明の請求項1〜7の
いずれかに係る発明において、上記軟質・易加工金属の
表面積に対する上記硬質粒子の投影面積の集合値の割合
である面積率を、25〜80%の範囲内に設定した構成
にしてある。In order to achieve the first object, the invention according to claim 8 of the present invention is directed to the invention according to any one of claims 1 to 7 of the present invention, wherein The area ratio, which is the ratio of the aggregate value of the projected area of the hard particles to the above, is set in the range of 25 to 80%.
【0022】このように構成した請求項8に係る発明で
は、特に、軟質・易加工金属部分に硬質粒子を保持させ
るスペースを確実に確保させることができ、これにより
硬質粒子を軟質・易加工金属に安定して保持させること
ができる。According to the eighth aspect of the present invention, particularly, a space for holding the hard particles in the soft / easy-to-work metal part can be reliably secured, whereby the hard particles can be made into the soft / easy-to-work metal. Can be held stably.
【0023】また上記第1の目的を達成するために、本
発明の請求項9に係る発明は、本発明の請求項1〜8の
いずれかに係る発明において、上記硬質粒子と、上記軟
質・易加工金属との境界部に、当該硬質粒子と当該軟質
・易加工金属との反応物を有する構成にしてある。In order to achieve the first object, the invention according to claim 9 of the present invention relates to the invention according to any one of claims 1 to 8 of the present invention, wherein the hard particles, The structure has a reactant of the hard particles and the soft and easily processable metal at the boundary with the easily processable metal.
【0024】このように構成した請求項9に係る発明で
は、特に、反応物が、硬質粒子を軟質・易加工金属に保
持させるものとして働き、これにより硬質粒子を軟質・
易加工金属により安定して保持させることができる。According to the ninth aspect of the present invention, the reactant functions to hold the hard particles on the soft and easy-to-work metal.
It can be stably held by the easily workable metal.
【0025】また上記第2の目的を達成するために、本
発明の請求項10に係る発明は、比較的軟らかい金属材
料から成り、しかも機械加工の容易な軟質・易加工金属
の表面に、この軟質・易加工金属よりも硬い球形状粒子
から成る硬質金属を複数個埋め込み、これらの硬質粒子
間に形成される間隙部分に潤滑剤を保有させた耐摩耗材
料を製造する耐摩耗材料の製造方法において、上記硬質
粒子の埋め込みを、上記軟質・易加工金属の所定の軟化
処理を施しておこなうようにしてある。Further, in order to achieve the second object, the invention according to claim 10 of the present invention relates to a method of forming a surface of a soft and easy-to-work metal made of a relatively soft metal material and easy to machine. A method for producing a wear-resistant material, in which a plurality of hard metals composed of spherical particles harder than soft and easily processed metal are embedded, and a lubricant is retained in a gap formed between these hard particles. In the above, the embedding of the hard particles is performed by performing a predetermined softening treatment on the soft and easily processed metal.
【0026】このように耐摩耗材料を製造する請求項1
0に係る発明では、所定の軟化処理により軟質・易加工
金属を常温時よりも軟らかくして硬質粒子の埋め込みを
おこなうので、この硬質粒子の埋め込み動作を確実にお
こなわせることができる。A method for producing a wear-resistant material as described above.
In the invention according to No. 0, the embedding of the hard particles is performed by making the soft / easy-working metal softer than at room temperature by the predetermined softening treatment, so that the embedding operation of the hard particles can be reliably performed.
【0027】[0027]
【発明の実施の形態】以下、本発明の耐摩耗材料及びそ
の製造方法の実施の形態を図に基づいて説明する。図1
は本発明の耐摩耗材料の製造方法の請求項10に対応す
る第1の実施形態を示す断面部分を含む側面図、図2は
図1に示す製造方法の第1の実施形態によって得られた
本発明の耐摩耗材料の請求項1,2,3,5,6,7,
8に対応する第1の実施形態を示す要部拡大断面図、図
3は図2に示す耐摩耗材料の第1の実施形態を摺動部に
適用させた状態を示す請求項4に対応する要部拡大断面
図である。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of a wear-resistant material and a method for manufacturing the same according to the present invention will be described below with reference to the drawings. FIG.
FIG. 2 is a side view including a cross section showing a first embodiment of a method for manufacturing a wear-resistant material according to the present invention, and FIG. 2 is obtained by the first embodiment of the manufacturing method shown in FIG. Claims 1, 2, 3, 5, 6, 7, of the wear-resistant material of the present invention.
FIG. 3 is an enlarged sectional view of a main part showing a first embodiment corresponding to FIG. 8, and FIG. 3 corresponds to claim 4 showing a state in which the first embodiment of the wear-resistant material shown in FIG. It is a principal part expanded sectional view.
【0028】図1に示す製造方法の第1の実施形態は、
比較的軟らかい金属材料から成り、しかも機械加工の容
易な軟質・易加工金属として例えば、外径10mm、肉
厚1mmのアルミニウムから成るパイプ状体1を用いる
とともに、あらかじめこのパイプ状体1の内部に挿入可
能な棒状の芯金2を用意してある。この芯金2の表面す
なわち外周面に硬質粒子3を固定してある。この硬質粒
子3の固定は、アトマイズ法にて球形状粒子にしたコバ
ルト基の合金粉末、例えば、クロム29重量パーセン
ト、アルミニウム6重量パーセント、イットリウム1重
量パーセント、残コバルトの合金粉末に、ポリビニルア
ルコール水溶液を加えたものを芯金2の外周面に吹き付
け塗布し、次いで、脱湿、脱結合剤加熱処理を施すこと
によりなされる。A first embodiment of the manufacturing method shown in FIG.
For example, a pipe 1 made of aluminum having an outer diameter of 10 mm and a wall thickness of 1 mm is used as a soft / easy-to-work metal made of a relatively soft metal material and easily machined. A rod-shaped core 2 that can be inserted is prepared. Hard particles 3 are fixed to the surface of the core metal 2, that is, the outer peripheral surface. The hard particles 3 are fixed by using a cobalt-based alloy powder made into spherical particles by an atomizing method, for example, an alloy powder of 29% by weight of chromium, 6% by weight of aluminum, 1% by weight of yttrium, the remaining cobalt, and a polyvinyl alcohol aqueous solution. Is applied to the outer peripheral surface of the cored bar 2 by spraying, followed by dehumidification and heat treatment of a decoupling agent.
【0029】このように硬質粒子3が固定された芯金2
を、パイプ状体1の内部に挿入した後、硬質粒子3がパ
イプ状体1の外部に飛散しないように、当該パイプ状体
1の両端部と芯金2との間が、シール部材4によってシ
ールされる。これにより、芯金2、シール部材4、及び
パイプ状体1が一体構造物を形成する。この状態におい
て、例えば200°Cの温度でパイプ状体1を軟化処理
しながら、同図1に示すようにハンマ5で矢印6で示す
ようにパイプ状体1の外周面を叩打し、すなわち型鍛造
を実施し、しかも、このハンマ5を矢印7で示すように
少しずつ移動させるとともに、芯金2を矢印8で示すよ
うに少しずつ回転させてパイプ状体1を回転させ、パイ
プ状体1の全外周を叩打する処理をおこなう。これによ
り、芯金2に固定されていた硬質粒子3がパイプ状体1
の内周面に転写させられる。ここで、シール部材4を外
し、芯金2をパイプ状体1から抜き取る。最後に、硬質
粒子3の間隙部分にポリ4ふっ化エチレンの粉末等から
成る潤滑剤9(図2に示す)の塗布処理を施す。The core metal 2 to which the hard particles 3 are fixed as described above
Is inserted into the pipe-shaped body 1, the gap between both ends of the pipe-shaped body 1 and the core 2 is sealed by the sealing member 4 so that the hard particles 3 do not scatter outside the pipe-shaped body 1. Sealed. Thereby, the metal core 2, the seal member 4, and the pipe-like body 1 form an integrated structure. In this state, while the pipe-shaped body 1 is softened at a temperature of, for example, 200 ° C., the outer peripheral surface of the pipe-shaped body 1 is hit with a hammer 5 as shown by an arrow 6 as shown in FIG. Forging is performed, and furthermore, the hammer 5 is moved little by little as shown by an arrow 7 and the core 2 is rotated little by little as shown by an arrow 8 to rotate the pipe 1 The process of hitting the entire outer periphery of is performed. As a result, the hard particles 3 fixed to the metal core 2 become
Is transferred to the inner peripheral surface. Here, the sealing member 4 is removed, and the metal core 2 is pulled out of the pipe-like body 1. Finally, a lubricant 9 (shown in FIG. 2) made of polytetrafluoroethylene powder or the like is applied to the gaps between the hard particles 3.
【0030】図2は上述の製造方法の第1の実施形態に
よって製造した耐摩耗材料の第1の実施形態を拡大して
示したものであるが、この摩耗材料の第1の実施形態
は、パイプ状体1の表面と直交する方向に、硬質粒子3
を複数段埋設して成る層状部10に形成してある。ま
た、この層状部10の厚さ寸法を例えば20μmに設定
してある。硬質粒子3は、大径粒子3aと小径粒子3b
から成り、これらの径寸法の比を「6/4」以上に、例
えば大径粒子3aの直径を8μmに設定し、小径粒子3
aの直径を5μmに設定してある。また、パイプ状体1
の表面積に対する硬質粒子3の投影面積の集合値の割合
である面積率を80%に設定してある。FIG. 2 is an enlarged view of the first embodiment of the wear-resistant material manufactured according to the first embodiment of the above-described manufacturing method. In the direction orthogonal to the surface of the pipe-like body 1, the hard particles 3
Are formed in a layered portion 10 buried in a plurality of stages. The thickness of the layered portion 10 is set to, for example, 20 μm. Hard particles 3 are composed of large-diameter particles 3a and small-diameter particles 3b.
The ratio of these diameters is set to “6/4” or more, for example, the diameter of the large-diameter particles 3a is set to 8 μm,
The diameter of a is set to 5 μm. In addition, pipe-like body 1
The area ratio, which is the ratio of the aggregate value of the projected area of the hard particles 3 to the surface area of the hard particles 3, is set to 80%.
【0031】図3は、上述の図2に示す耐摩耗材料の第
1の実施形態を摺動部に適用した状態を示すもので、例
えば矢印11で示す回転運動をおこなうパイプ状体1か
ら成る移動部材12を保持する保持部材、すなわち軸受
部材13が上述した図2に示す耐摩耗材料の第1の実施
形態から成っている。FIG. 3 shows a state in which the first embodiment of the wear-resistant material shown in FIG. 2 described above is applied to a sliding portion, and is made of, for example, a pipe-like body 1 which makes a rotational movement indicated by an arrow 11. The holding member for holding the moving member 12, that is, the bearing member 13 is made of the above-described first embodiment of the wear-resistant material shown in FIG.
【0032】この図3に示す軸受部材13、すなわち硬
質粒子3をパイプ状体1の内周面に埋め込み形成して成
る耐摩耗材料の第1の実施形態では、硬質粒子3が球形
状粒子から成るので、摺動部を形成する他の部材、すな
わち移動部材12が硬質粒子3に回転摺動接触する際に
は、球面摺動接触に近似した状態になり、これにより硬
質粒子3の損耗を最少限度に抑えながらも良好な摺動動
作をおこなわせることができる。また、硬質粒子3間の
間隙部分に潤滑剤9を保有させてあるので、この潤滑剤
9によっても硬質粒子3の損耗が抑えられ、かつ、円滑
な摺動動作を実現させることができる。したがって、摺
動部構成部材として優れた耐久性を得ることができる。In the bearing member 13 shown in FIG. 3, that is, in the first embodiment of the wear-resistant material formed by embedding the hard particles 3 in the inner peripheral surface of the pipe-like body 1, the hard particles 3 are made of spherical particles. Therefore, when the other member forming the sliding portion, that is, the moving member 12 comes into rotational sliding contact with the hard particle 3, the state becomes similar to the spherical sliding contact, thereby reducing the wear of the hard particle 3. Good sliding operation can be performed while keeping it to the minimum. Further, since the lubricant 9 is held in the gap between the hard particles 3, the wear of the hard particles 3 can be suppressed by the lubricant 9 and a smooth sliding operation can be realized. Therefore, excellent durability can be obtained as a sliding member.
【0033】また、上述した耐摩耗材料の第1の実施形
態では、パイプ状体1がアルミニウムから成っている
が、アルミニウムは比較的軟らかい金属材料で、しかも
機械加工しやすいので硬質粒子3を埋め込ませる軟質・
易加工金属として好適であり、また、入手しやすい。こ
の点で実用性に富む。また、硬質粒子3がコバルト基か
ら成っているが、コバルトは耐摩耗性を有する硬質粒子
3として好適であり、また、これも比較的入手しやす
い。この点で実用性に富む。In the first embodiment of the wear-resistant material described above, the pipe-like body 1 is made of aluminum. However, since aluminum is a relatively soft metal material and is easily machined, the hard particles 3 are embedded. Soft
It is suitable as an easily workable metal and is easily available. In this respect, it is practical. The hard particles 3 are made of a cobalt group. Cobalt is suitable as the hard particles 3 having wear resistance, and these are also relatively easily available. In this respect, it is practical.
【0034】また、上述した耐摩耗材料の第1の実施形
態を図3に示す摺動部を形成する保持部材、すなわち軸
受部材13として採用したものでは、パイプ状体1の切
削加工が容易であることから、軸受部材13を複雑な外
形形状に形成する必要がある場合にも、容易に対応でき
る。したがって、軸受部材13の外形形状に対する大き
な自由度を確保できる。In the case where the first embodiment of the wear-resistant material described above is employed as the holding member forming the sliding portion shown in FIG. 3, ie, the bearing member 13, the pipe-shaped body 1 can be easily cut. Therefore, it is possible to easily cope with a case where the bearing member 13 needs to be formed in a complicated outer shape. Therefore, a large degree of freedom for the outer shape of the bearing member 13 can be secured.
【0035】また、上述した耐摩耗材料の第1の実施形
態では、硬質粒子3を層状部10に形成してあることか
ら、堅牢な耐摩耗面を形成させることができる。この観
点から耐久性の向上に貢献する。In the first embodiment of the wear-resistant material described above, since the hard particles 3 are formed in the layered portion 10, a robust wear-resistant surface can be formed. From this viewpoint, it contributes to improvement of durability.
【0036】また、層状部10の厚さ寸法を20μmに
設定してあることから、硬質粒子3の埋め込みに伴うパ
イプ状体1の変形を少なくし、これによりパイプ状体1
に生じる残留応力を小さくすることができ、しかも、こ
のパイプ状体1として必要とされる材料の厚さ、量を抑
えることができる。したがって、安定した摺動性能の確
保と、摺動部のコンパクト化を実現できるとともに、材
料の節約を図ることができる。Further, since the thickness of the layered portion 10 is set to 20 μm, deformation of the pipe-like body 1 due to the embedding of the hard particles 3 is reduced.
Can be reduced, and the thickness and amount of the material required for the pipe-shaped body 1 can be suppressed. Therefore, stable sliding performance can be ensured and the sliding portion can be made compact, and materials can be saved.
【0037】また、上述した耐摩耗材料の第1の実施形
態では、硬質粒子3を大径粒子3aと、小径粒子3bを
混在させたものとし、しかも大径粒子3aの径寸法と小
径粒子3bの径寸法との比を「6/4」以上に設定して
あることから、主に大径粒子3aが摺動部を形成する他
の部材、例えば図3の移動部材12に接触し、これによ
り球面摺動接触に近似した接触状態の形成に役立ち、上
述した硬質粒子3の損耗の抑制と円滑な摺動動作の実現
に貢献する。In the above-described first embodiment of the wear-resistant material, the hard particles 3 are made of a mixture of the large-diameter particles 3a and the small-diameter particles 3b. Since the ratio of the large diameter particles 3a to the diameter of the sliding member is set to “6/4” or more, the large diameter particles 3a mainly come into contact with another member forming the sliding portion, for example, the moving member 12 in FIG. This contributes to the formation of a contact state similar to spherical sliding contact, and contributes to the suppression of the wear of the hard particles 3 and the realization of a smooth sliding operation.
【0038】また、上述した耐摩耗材料の第1の実施形
態では、硬質粒子3による面積率を60%に設定してあ
るので、パイプ状体1の表面部分に硬質粒子3を保持さ
せるスペースを確実に確保させることができ、これによ
り硬質粒子3をパイプ状体1に確実に埋め込ませ、安定
した状態に保持させることができ、硬質粒子3のパイプ
状体1からの脱落を防止できる。したがって、この観点
から耐久性の向上に貢献する。In the first embodiment of the wear-resistant material described above, the area ratio of the hard particles 3 is set to 60%, so that the space for holding the hard particles 3 on the surface of the pipe-like body 1 is increased. As a result, the hard particles 3 can be securely embedded in the pipe-shaped body 1 and can be maintained in a stable state, and the hard particles 3 can be prevented from falling off from the pipe-shaped body 1. Therefore, it contributes to the improvement of durability from this viewpoint.
【0039】また、上述したような耐摩耗材料の第1の
実施形態を製造する図1で例示した製造方法の第1の実
施形態によれば、パイプ状体1を200°Cの温度で軟
らかくして硬質粒子3の埋め込みをおこなうので、この
硬質粒子3の埋め込み動作を確実におこなわせることが
でき、球形状粒子から成る硬質粒子3の耐摩耗面を有す
る所望の耐摩耗材料を得ることができる。また、パイプ
状体1の内周面に耐摩耗面を形成できるので、軸受部材
の製造に好適である。According to the first embodiment of the manufacturing method illustrated in FIG. 1 for manufacturing the above-described first embodiment of the wear-resistant material, the pipe-like body 1 is softened at a temperature of 200 ° C. Since the embedding of the hard particles 3 is performed, the embedding operation of the hard particles 3 can be reliably performed, and a desired wear-resistant material having a wear-resistant surface of the hard particles 3 composed of spherical particles can be obtained. it can. Further, since a wear-resistant surface can be formed on the inner peripheral surface of the pipe-shaped body 1, it is suitable for manufacturing a bearing member.
【0040】なお、本発明者らは、本発明の耐摩耗材料
の第1の実施形態を摺動部に適用した図3に示す状態に
おいて、耐摩耗試験をおこなった。このときの試験条件
は、室温に保った状態で、アルミニウム製の移動部材1
2との間で50Hzの振動を与えるものであった。この
本発明の第1の実施形態を適用した軸受部材13は、数
度の温度上昇の後、安定した温度状態となり、その後も
引き続いて円滑な摺動動作を繰り返しおこなうことがで
きた。このことから、上述した本発明の耐摩耗材料の第
1の実施形態では、安定した円滑な摺動性能が得られる
ことが分かる。また、上述の耐摩耗試験との比較のため
に、図3に示す状態において、軸受部材13の代わりに
硬質粒子3及び潤滑剤9を設けないアルミニウムから成
るパイプ状体を用意し、上述と同様に、室温で50Hz
の振動を与えたところ、数分でアルミニウム相互の焼き
付けを生じ、摺動動作が不能となったことが確認され
た。The present inventors conducted a wear resistance test in the state shown in FIG. 3 in which the first embodiment of the wear resistant material of the present invention was applied to a sliding portion. The test conditions at this time were as follows.
2 and a vibration of 50 Hz was applied. The bearing member 13 to which the first embodiment of the present invention was applied reached a stable temperature state after a temperature rise of several degrees, and was able to repeatedly perform a smooth sliding operation continuously thereafter. This indicates that the first embodiment of the wear-resistant material of the present invention described above can provide stable and smooth sliding performance. For comparison with the above-mentioned wear resistance test, in the state shown in FIG. 3, instead of the bearing member 13, a pipe-shaped body made of aluminum without the hard particles 3 and the lubricant 9 was prepared, and the same as above was prepared. And 50Hz at room temperature
When the vibration was given, it was confirmed that the aluminum was burned to each other within a few minutes, and the sliding operation became impossible.
【0041】なお、上述した耐摩耗材料の第1の実施形
態、及び製造方法の第1の実施形態では、軟質・易加工
金属の一例としてアルミニウムから成るパイプ状体1を
挙げたが、アルミニウムに代えて、銅、ニッケル、ある
いはアルミニウム、銅、ニッケルのいずれかを母材とす
る合金を用いてもよい。In the above-described first embodiment of the wear-resistant material and the first embodiment of the manufacturing method, the pipe-like body 1 made of aluminum is mentioned as an example of the soft and easily-workable metal. Instead, an alloy having copper, nickel, or any of aluminum, copper, and nickel as a base material may be used.
【0042】また、硬質粒子3を成す金属の一例として
コバルトを母材とする合金を挙げたが、これに代えてク
ロムを母材とする合金を用いてもよい。Although an alloy using cobalt as a base material has been described as an example of a metal forming the hard particles 3, an alloy using chromium as a base material may be used instead.
【0043】また、上述では図3において耐摩耗材料の
第1の実施形態から成る軸受部材13、すなわち保持部
材に保持される移動部材12が回転運動をおこなうもの
と説明したが、直線運動をおこなうものであってもよ
く、また、回転運動と直線運動の双方をおこなうもので
あってもよい。In the above description, it has been described in FIG. 3 that the bearing member 13 made of the first embodiment of the wear-resistant material, that is, the moving member 12 held by the holding member performs a rotary motion, but performs a linear motion. It may be one that performs both rotary motion and linear motion.
【0044】また、上述では硬質粒子3の大径粒子3a
の直径を8μm、小径粒子3bの直径を5μmに設定し
たが、本発明は、これに限られず5〜50μmの範囲内
に設定すればよい。In the above description, the large particles 3a of the hard particles 3
Is set to 8 μm and the diameter of the small-diameter particles 3b is set to 5 μm. However, the present invention is not limited to this, and may be set within a range of 5 to 50 μm.
【0045】また、上述ではパイプ状体1の内周面の硬
質粒子3の層状部10の厚さ寸法を20μmに設定した
が、本発明は、これに限られず、10〜500μmの範
囲内、好ましくは20〜200μmの範囲内に設定すれ
ばよい。In the above description, the thickness of the layered portion 10 of the hard particles 3 on the inner peripheral surface of the pipe-shaped body 1 is set to 20 μm. However, the present invention is not limited to this. Preferably, it may be set within the range of 20 to 200 μm.
【0046】同様に、上述ではパイプ状体1の内周面の
表面積に対する硬質粒子3の投影面積の集合値の割合で
ある面積率を60%に設定したが、本発明はこれに限ら
れず、25〜80%の範囲内に設定すればよい。Similarly, in the above description, the area ratio, which is the ratio of the set value of the projected area of the hard particles 3 to the surface area of the inner peripheral surface of the pipe-shaped body 1, is set to 60%. However, the present invention is not limited to this. What is necessary is just to set in the range of 25-80%.
【0047】また、上述では軟化処理の温度の一例とし
て200°Cを挙げたが、200〜350°Cの範囲で
適宜選定すればよい。また、この軟化処理を真空ガス雰
囲気下、及び不活性ガス雰囲気下のいずれかの雰囲気下
でおこなうようにしてもよい。In the above description, 200 ° C. is given as an example of the temperature of the softening treatment, but it may be appropriately selected within the range of 200 to 350 ° C. In addition, this softening treatment may be performed in either a vacuum gas atmosphere or an inert gas atmosphere.
【0048】図4は本発明の耐摩耗材料の製造方法の請
求項10に対応する第2の実施形態、及びこの製造方法
の第2の実施形態によって得られる耐摩耗材料の請求項
1,2,3,5,6に対応する第2の実施形態を示す断
面部分を含む側面図である。FIG. 4 shows a second embodiment corresponding to claim 10 of the method for producing a wear-resistant material of the present invention, and claims 1 and 2 of a wear-resistant material obtained by the second embodiment of this production method. FIG. 10 is a side view including a cross section showing a second embodiment corresponding to FIGS.
【0049】この図4に示す製造方法の第2の実施形態
は、例えば軟質・易加工金属としてアルミニウムから成
る板状体14を用いるとともに、この板状体14の圧延
加工をおこなわせる上下一対の圧延ローラ15,16
と、粉末状の球形状粒子例えばコバルト基から成る硬質
粒子3の上述した圧延ローラ15部分の巻き込み動作が
可能な巻き込みローラ17とを用意しておこなう。In the second embodiment of the manufacturing method shown in FIG. 4, a plate-like member 14 made of aluminum is used as a soft and easily workable metal, and a pair of upper and lower members for rolling the plate-like member 14 are used. Rolling rollers 15, 16
And a roll-in roller 17 capable of rolling-in the above-mentioned rolling roller 15 portion of the powdery spherical particles, for example, the hard particles 3 made of cobalt base.
【0050】例えば、板状体14を200°Cに加熱
し、軟化処理を施しつつ、巻き込みローラ17部分に硬
質粒子3を吹き付ける。これにより硬質粒子3は、矢印
18,19で示すようにそれぞれ回転する巻き込みロー
ラ17と圧延ローラ15とによって、板状体14の上面
に散布される。さらに、圧延ローラ15,16の回転に
より、板状体14が押圧されて、矢印14a方向に移動
しながら圧延加工され、このとき同時に上述した板状体
14の上面に散布された硬質粒子3が当該板状体14の
上面に押し込まれる。すなわち、この製造方法の第2の
実施形態は、温間ロール圧延を実施するものである。そ
の後、板状体14の上面に埋め込まれた硬質粒子3の間
隙部分に、所定の潤滑剤の塗布処理をおこなう。For example, the plate-like body 14 is heated to 200 ° C., and the hard particles 3 are sprayed on the winding roller 17 while performing the softening treatment. Thereby, the hard particles 3 are dispersed on the upper surface of the plate-like body 14 by the winding roller 17 and the rolling roller 15 which rotate as indicated by arrows 18 and 19, respectively. Further, the plate-like body 14 is pressed by the rotation of the rolling rollers 15 and 16 and is rolled while moving in the direction of the arrow 14a, and at the same time, the hard particles 3 dispersed on the upper surface of the plate-like body 14 described above. It is pushed into the upper surface of the plate-like body 14. That is, the second embodiment of the manufacturing method is to perform warm roll rolling. Thereafter, a predetermined lubricant application process is performed on the gaps between the hard particles 3 embedded in the upper surface of the plate-like body 14.
【0051】このようにして製造される耐摩耗材料の第
2の実施形態は、上述のように板状体14から成るとと
もに、この板状体14の一方の表面に硬質粒子3を含む
耐摩耗面を有する構成にしてある。The second embodiment of the wear-resistant material manufactured in this manner is composed of the plate-like body 14 as described above, and the hard-wearing material 3 includes the hard particles 3 on one surface of the plate-like body 14. It has a configuration having a surface.
【0052】なお、本発明者らは、板状体14の硬質粒
子3の層状部の厚さ寸法を10μm、20μm、100
μm、300μm、及び500μmを超えた寸法のそれ
ぞれに設定し、アルミニウムから成る板状体14とコバ
ルト基から成る硬質粒子3との圧着状況を観察したとこ
ろ、硬質粒子3の層状部の厚さ寸法が10〜300μm
のものでは、板状体14に対する硬質粒子3の圧着性が
良好で、硬質粒子3の脱落のおそれを生じないものであ
った。また、層状部の厚さ寸法が500μmを超えた寸
法のものは、局所に密着不良が認められ、硬質粒子3の
脱落のおそれを生じるものであった。The inventors of the present invention set the thickness of the layered portion of the hard particles 3 of the plate 14 to 10 μm, 20 μm, 100 μm,
μm, 300 μm, and over 500 μm were set, and the state of pressure bonding between the plate-like body 14 made of aluminum and the hard particles 3 made of cobalt was observed. Is 10 to 300 μm
In this case, the pressure resistance of the hard particles 3 to the plate-like body 14 was good, and there was no possibility that the hard particles 3 would fall off. When the thickness of the layered portion exceeded 500 μm, poor adhesion was recognized locally, and the hard particles 3 might fall off.
【0053】また、板状体14と硬質粒子3との境界部
に引っ張り応力を付与して硬質粒子3の剥離試験を実施
したところ、硬質粒子3の層状部の厚さ寸法が10〜3
00μmのものでは、上述のように板状体14に対する
硬質粒子3の圧着性が良好であることに伴って、板状体
14部分からの破断が認められたが、これに対して層状
部の厚さ寸法が500μmのものでは、当該層状部の一
部の剥離、破断が認められた。When a tensile test was applied to the boundary between the plate-like body 14 and the hard particles 3 to perform a peeling test of the hard particles 3, the thickness of the layered portion of the hard particles 3 was 10 to 3 mm.
In the case of 00 μm, breakage from the plate-like body 14 was observed due to the good pressure bonding property of the hard particles 3 to the plate-like body 14 as described above. When the thickness was 500 μm, peeling and breakage of part of the layered portion were observed.
【0054】このことから、板状体14の表面に形成す
る硬質粒子3の層状部の厚さ寸法を、10〜500μm
の範囲内に設定すれば、硬質粒子3の脱落を生じない安
定した耐摩耗材料を得ることができる。From this, the thickness of the layered portion of the hard particles 3 formed on the surface of the plate-like body 14 should be 10 to 500 μm.
If it is set in the range, a stable wear-resistant material that does not cause the hard particles 3 to fall off can be obtained.
【0055】上述のように構成した製造方法の第2の実
施形態にあっても、上述した図1に示す製造方法の第1
の実施形態と同様に、板状体14に軟化処理を施すこと
から、板状体14に硬質粒子3の埋め込み動作を確実に
おこなわせることができ、球形状粒子から成る硬質粒子
3の耐摩耗面を有する所望の耐摩耗材料を得ることがで
きる。また、板状体14の表面に耐摩耗面を形成できる
ことから、摺動部が直線的摺動関係を形成する場合に好
適である。In the second embodiment of the manufacturing method configured as described above, the first embodiment of the manufacturing method shown in FIG.
In the same manner as in the embodiment, the softening treatment is performed on the plate-like body 14, so that the embedding operation of the hard particles 3 in the plate-like body 14 can be surely performed. A desired wear-resistant material having a surface can be obtained. Further, since a wear-resistant surface can be formed on the surface of the plate-like body 14, it is suitable for a case where the sliding portions form a linear sliding relationship.
【0056】また、上述のように構成した耐摩耗材料の
第2の実施形態にあっても、上述した図2等に示す耐摩
耗材料の第1の実施形態と同様に、硬質粒子3が球形状
粒子から成るので、摺動部を形成する他の部材、例えば
図示しない移動部材が硬質粒子3に直線摺動接触する際
には、球面摺動接触に近似した状態になり、これにより
硬質粒子3の損耗を最小限度に抑えながらも良好な摺動
動作をおこなわせることができる。また、硬質粒子3間
の間隙部分に潤滑剤を保有させてあるので、この潤滑剤
9によっても硬質粒子3の損耗が抑えられ、かつ、円滑
な摺動動作を実現させることができる。したがって、摺
動部構成部材として優れた耐久性を得ることができる。Also, in the second embodiment of the wear-resistant material constructed as described above, similarly to the first embodiment of the wear-resistant material shown in FIG. Since it is made of shaped particles, when another member forming the sliding portion, for example, a moving member (not shown) comes into linear sliding contact with the hard particle 3, it comes into a state similar to spherical sliding contact, whereby the hard particle A good sliding operation can be performed while minimizing the wear of No. 3. Further, since the lubricant is held in the gap between the hard particles 3, the wear of the hard particles 3 can be suppressed by the lubricant 9 and a smooth sliding operation can be realized. Therefore, excellent durability can be obtained as a sliding member.
【0057】また、板状体14がアルミニウムから成
り、硬質粒子3がコバルト基から成るものであるので、
それぞれ入手しやすく、実用性に富む。また、板状体1
4がアルミニウムから成ることから、外形形状の加工が
容易であり、この外形形状に対する大きな自由度を確保
することができる。また、板状体14上に硬質粒子3の
層状部を形成してあることから、堅牢な耐摩耗面を形成
させることができ、この観点から耐久性の向上に貢献す
る。さらに、上述したように硬質粒子3の層状部を10
〜500μmの範囲内に設定すれば、板状体14からの
硬質粒子3の脱落のおそれがなく、この観点から耐久性
の向上に貢献する。Since the plate-like body 14 is made of aluminum and the hard particles 3 are made of cobalt,
Each is easily available and practical. In addition, plate-like body 1
Since 4 is made of aluminum, the processing of the outer shape is easy, and a great degree of freedom for this outer shape can be ensured. Further, since the layered portion of the hard particles 3 is formed on the plate-like body 14, a robust wear-resistant surface can be formed, and from this viewpoint, it contributes to improvement of durability. Further, as described above, the layer portion of the hard particles 3 is
When the thickness is set in the range of about 500 μm, there is no possibility that the hard particles 3 fall off from the plate-like body 14, which contributes to the improvement of the durability from this viewpoint.
【0058】図5は本発明の耐摩耗材料の製造方法の請
求項10に対応する第3の実施形態を示す断面部分を含
む側面図である。FIG. 5 is a side view including a cross section showing a third embodiment of the method for producing a wear-resistant material according to the present invention.
【0059】この図5に示す製造方法の第3の実施形態
では、軟質・易加工金属として複数枚、例えば2枚の板
状体20,21を用いてある。これらの板状体20,2
1は、例えばそれぞれ厚さ寸法が2mm、幅寸法が25
0mm、長さ寸法が450mmのアルミニウムから成っ
ている。これらの板状体20,21を互いに平行に隙間
をあけて配置し、その隙間を例えば1mmに設定してあ
る。そして、その隙間に例えばコバルト基の直径が30
μmの球形状粒子からなる硬質粒子3を振動充填すると
ともに、板状体20,21の両端部を硬質粒子3が飛散
しないようにシール部材22でシールする。In the third embodiment of the manufacturing method shown in FIG. 5, a plurality of, for example, two plate-like bodies 20 and 21 are used as the soft and easily-workable metal. These plate-like bodies 20, 2
1 is, for example, each having a thickness of 2 mm and a width of 25
It is made of aluminum having a length of 0 mm and a length of 450 mm. These plate-like bodies 20 and 21 are arranged parallel to each other with a gap therebetween, and the gap is set to, for example, 1 mm. In the gap, for example, the diameter of the cobalt base is 30.
Hard particles 3 composed of spherical particles of μm are vibration-filled, and both ends of the plate-like bodies 20 and 21 are sealed with a sealing member 22 so that the hard particles 3 do not scatter.
【0060】この状態において、板状体20,21を例
えば250°Cの温度で加熱して軟化処理を施しなが
ら、例えば0.5t/cm2の圧力で作動させたハンマ
式プレス23により、矢印24で示すように板状体2
0,21を互いに近づく方向に叩打して、硬質粒子3の
それぞれを板状体20の下面、板状体21の上面に埋設
する。ここで、シール部材22を外すと、硬質粒子3が
埋設した板状体20,21のそれぞれを取り出すことが
できる。その後、板状体20,21のそれぞれの硬質粒
子3の間隙部分に潤滑剤の塗布処理を施す。In this state, while the plate-like bodies 20 and 21 are heated at a temperature of, for example, 250 ° C. and subjected to a softening treatment, the hammer press 23 operated at a pressure of, for example, 0.5 t / cm 2 causes an arrow. 24, the plate-like body 2
The hard particles 3 are buried in the lower surface of the plate-shaped body 20 and the upper surface of the plate-shaped body 21 by hitting 0 and 21 in directions approaching each other. Here, when the seal member 22 is removed, each of the plate-like bodies 20 and 21 in which the hard particles 3 are embedded can be taken out. Thereafter, a lubricant is applied to the gaps between the hard particles 3 of the plate-like bodies 20 and 21.
【0061】このように形成した硬質粒子3を表面に有
する板状体20,21、すなわち耐摩耗材料について、
本発明者らは、板状体20,21それぞれの表面積に対
する硬質粒子3の投影面積の集合値の割合である面積率
を、特性X線の走査型電子顕微鏡写真の画像解析により
測定したところ75%であることを確認した。また、硬
質粒子3の層状部の厚さ寸法を断面組織の観察によって
確認したところ200μmであり、硬質粒子3が多段に
埋め込まれていることを確認した。With respect to the plate-like bodies 20 and 21 having the hard particles 3 thus formed on the surface, that is, the wear-resistant material,
The present inventors measured the area ratio, which is the ratio of the aggregate value of the projected area of the hard particles 3 to the surface area of each of the plate-like bodies 20 and 21, by image analysis of a scanning electron micrograph of characteristic X-rays. %. Further, the thickness of the layered portion of the hard particles 3 was confirmed by observation of the cross-sectional structure to be 200 μm, and it was confirmed that the hard particles 3 were embedded in multiple stages.
【0062】また、アルミニウムから成る板状体20,
21と硬質粒子3の境界部に引っ張り応力を付与して剥
離試験をおこなったところ、硬質粒子3の板状体20,
21への結合力が良好で、板状体20,21部分からの
破断が認められた。Further, the plate 20 made of aluminum,
When a peeling test was performed by applying a tensile stress to the boundary between the hard particles 3 and the hard particles 3,
The bonding strength to 21 was good, and breakage from plate-like bodies 20 and 21 was observed.
【0063】また、硬質粒子3から成る層状部の表面に
最大引っ張り応力が付与されるように、その層状部を外
側にして90°折り曲げた剥離試験をおこなったとこ
ろ、硬質粒子3の飛び出しは無く、層状部が健全に形成
されていることが確認された。Further, a peeling test was conducted by bending the layered portion 90 ° with the layered portion outside so that the maximum tensile stress was applied to the surface of the layered portion composed of the hard particles 3. It was confirmed that the layered portion was formed soundly.
【0064】このように構成した耐摩耗材料の製造方法
の第3の実施形態では、板状体20,21の表面に球形
状粒子から成る硬質粒子3の層状部を形成することか
ら、上述した図2に示す製造方法の第2の実施形態と同
様の作用効果を奏する他、硬質粒子3の耐摩耗面を有す
る2枚の板状体20,21を同時に製造することがで
き、量産性に優れている。In the third embodiment of the method for producing a wear-resistant material having the above-described structure, the layered portions of the hard particles 3 composed of spherical particles are formed on the surfaces of the plate-like bodies 20 and 21. In addition to the same operation and effect as the second embodiment of the manufacturing method shown in FIG. 2, the two plate-like bodies 20 and 21 having the wear-resistant surfaces of the hard particles 3 can be manufactured at the same time. Are better.
【0065】なお上記では、2枚の板状体20,21を
配置して製造するようにしたが、枚数は、これに限られ
ず、3枚以上のものを上記製造方法と同様にして製造す
ることも可能である。In the above description, the two plate-shaped members 20 and 21 are arranged and manufactured. However, the number is not limited to this, and three or more plates are manufactured in the same manner as the above-described manufacturing method. It is also possible.
【0066】図6は本発明の耐摩耗材料の製造方法の請
求項10に対応する第4の実施形態を示す断面部分を含
む側面図である。FIG. 6 is a side view including a cross section showing a fourth embodiment of the method for producing a wear-resistant material according to the present invention.
【0067】この図6に示す第4の実施形態は、軟質・
易加工金属としてアルミニウムから成るパイプ状体25
を用いるとともに、このパイプ状体25の内部に挿入可
能な芯金26と、パイプ状体25を移送させながらの絞
り加工、すなわちスェージング処理をおこなわせる加工
ローラ27,28とを用意してある。同図6に示すよう
に、芯金26をパイプ状体25の内部に挿入し、芯金2
6とパイプ状体25との隙間に、例えばコバルト基から
成る球形状粒子の硬質粒子3を供給した状態で、例えば
パイプ状体25を200°Cまで加熱して軟化処理をお
こなう。The fourth embodiment shown in FIG.
Pipe-like body 25 made of aluminum as an easily processable metal
In addition, a core metal 26 that can be inserted into the inside of the pipe-like body 25 and working rollers 27 and 28 that perform a drawing process while transferring the pipe-like body 25, that is, a swaging process are prepared. As shown in FIG. 6, the core metal 26 is inserted into the pipe-shaped body 25 and the core metal 2 is inserted.
In a state where the spherical hard particles 3 composed of, for example, cobalt are supplied to the gap between the pipe 6 and the pipe 25, the pipe 25 is heated to, for example, 200 ° C. to perform a softening treatment.
【0068】この状態において、加工ローラ27を矢印
29,30方向に回転させ、また、加工ローラ28を矢
印31,32方向に回転させると、パイプ状体25が絞
られながら矢印33方向に回転し、同時に矢印34方向
に引き抜かれる。この動作により、パイプ状体25の内
周面に硬質粒子3が埋め込まれる。このようにして引き
抜かれたパイプ状体25は所定の内径となるように矯正
される。その後、パイプ状体25の内周面の硬質粒子3
の間隙部分に所定の潤滑剤の塗布処理をおこなう。In this state, when the processing roller 27 is rotated in the directions of arrows 29 and 30 and the processing roller 28 is rotated in the directions of arrows 31 and 32, the pipe 25 is rotated in the direction of arrow 33 while being throttled. , Are simultaneously pulled out in the direction of the arrow 34. By this operation, the hard particles 3 are embedded in the inner peripheral surface of the pipe 25. The pipe-like body 25 pulled out in this manner is corrected so as to have a predetermined inner diameter. Then, the hard particles 3 on the inner peripheral surface of the pipe 25
A predetermined lubricant application process is performed on the gap portion.
【0069】なお、このようにして製造したパイプ状体
25の内周面の硬質粒子3の層状部の厚さ寸法は40μ
mであった。本発明者らは、このパイプ状体25の内部
に、アルミナ棒から成る移動部材を挿入して摺動試験を
おこなったが、摩擦抵抗は十分に小さく、一万回の摺動
を繰り返しても、抵抗の上昇や摺動接触部の焼き付きは
認められなかった。The thickness of the layered portion of the hard particles 3 on the inner peripheral surface of the pipe 25 manufactured as described above is 40 μm.
m. The present inventors performed a sliding test by inserting a moving member made of an alumina rod into the inside of the pipe-shaped body 25, but the frictional resistance was sufficiently small, and even if the sliding was repeated 10,000 times. No increase in resistance or seizure of the sliding contact portion was observed.
【0070】この図6に示す製造方法の第4の実施形態
もパイプ状体25の内周面に耐摩耗面を形成するもので
あり、前述した図1に示す製造方法の第1の実施形態と
ほぼ同様の作用効果を奏する。The fourth embodiment of the manufacturing method shown in FIG. 6 also forms a wear-resistant surface on the inner peripheral surface of the pipe 25, and the first embodiment of the manufacturing method shown in FIG. It has almost the same function and effect.
【0071】なお、上述した耐摩耗材料の製造方法の第
1〜第4の実施形態において、所定の軟化処理と、潤滑
剤の塗布処理の間に、真空雰囲気下及び不活性ガス雰囲
気下のいずれかの雰囲気下で、軟化処理の温度よりも高
い所定の処理温度、例えば500〜550°Cで、20
〜30分程度の熱処理を施すようにしてもよい。この製
造方法によって製造された耐摩耗材料は請求項9に対応
する。In the above-described first to fourth embodiments of the method for producing a wear-resistant material, any one of a vacuum atmosphere and an inert gas atmosphere may be used between the predetermined softening treatment and the lubricant application treatment. In such an atmosphere, at a predetermined processing temperature higher than the temperature of the softening processing, for example, 500 to 550 ° C.,
The heat treatment may be performed for about 30 minutes. The wear-resistant material manufactured by this manufacturing method corresponds to claim 9.
【0072】このようにして耐摩耗材料を製造するもの
では、軟質・易加工金属と硬質粒子3との境界部に反応
物、すなわちAl−Co等の化合物相が形成されるの
で、上述の反応物が、硬質粒子3を軟質・易加工金属に
保持させるものとして働き、これにより硬質粒子3を軟
質・易加工金属に、より安定して保持させることがで
き、この観点から耐久性の向上に貢献する。In the case of producing a wear-resistant material in this manner, a reactant, that is, a compound phase such as Al—Co is formed at the boundary between the soft / easy-to-work metal and the hard particles 3. The material acts as a material for holding the hard particles 3 in the soft / easy-to-work metal, and thereby the hard particles 3 can be held in the soft / easy-to-work metal more stably. To contribute.
【0073】[0073]
【発明の効果】以上のように、本発明の耐摩耗材料の請
求項1〜9に係る発明によれば、硬質粒子が球形状粒子
から成るとともに、硬質粒子の間隙部分に潤滑剤を保有
することから、硬質粒子の損耗がきわめて少なく、しか
も円滑な摺動動作を実現させることができ、摺動部構成
部材として好適であるとともに、優れた耐久性が得られ
る。As described above, according to the first to ninth aspects of the wear-resistant material of the present invention, the hard particles are composed of spherical particles, and the lubricant is held in the gaps between the hard particles. Therefore, the hard particles are hardly abraded and a smooth sliding operation can be realized, which is suitable as a constituent member of the sliding portion and excellent durability can be obtained.
【0074】また特に請求項2,3に係る発明によれ
ば、軟質・易加工金属、あるいは硬質粒子として好適
で、かつ入手しやすく、実用性に富む。Further, according to the second and third aspects of the present invention, it is suitable as a soft / easy-to-work metal or hard particle, easily obtainable, and practical.
【0075】また特に請求項4に係る発明によれば、軸
受部材として好適であるとともに、切削加工が容易であ
ることから、その軸受部材の外形形状に対する大きな自
由度を確保することができる。According to the fourth aspect of the present invention, the bearing member is suitable as a bearing member, and can be easily cut, so that a large degree of freedom in the outer shape of the bearing member can be secured.
【0076】また特に請求項5に係る発明によれば、複
数段の硬質粒子により堅牢な耐摩耗面を形成させること
ができ、この観点から耐久性の向上に貢献する。In particular, according to the fifth aspect of the present invention, a hard wear-resistant surface can be formed by a plurality of stages of hard particles, and from this viewpoint, it contributes to improvement of durability.
【0077】また特に請求項6に係る発明によれば、硬
質粒子の埋め込みに伴う軟質・易加工金属の変形を少な
くし、これにより軟質・易加工金属に生じる残留応力を
小さくすることができ、しかもこの軟質・易加工金属と
して必要とされる材料の厚さ、量を抑えることができ
る。したがって、安定した摺動性能の確保と、摺動部の
コンパクト化を実現できるとともに、材料の節約を図る
ことができる。According to the invention of claim 6, in particular, the deformation of the soft / easy-to-work metal due to the embedding of the hard particles can be reduced, whereby the residual stress generated in the soft / easy-to-work metal can be reduced. In addition, the thickness and amount of the material required as the soft and easily processed metal can be suppressed. Therefore, stable sliding performance can be ensured and the sliding portion can be made compact, and materials can be saved.
【0078】また特に請求項7に係る発明によれば、主
に大径粒子が摺動部を形成する他の部材に接触し、これ
により球面摺動接触に近似した接触状態の形成に役立
ち、硬質粒子の損耗の抑制と円滑な摺動動作の実現に貢
献する。According to the present invention, the large-diameter particles mainly come into contact with other members forming the sliding portion, thereby helping to form a contact state similar to a spherical sliding contact. It contributes to the suppression of wear of hard particles and the realization of smooth sliding operation.
【0079】また特に請求項8に係る発明によれば、軟
質・易加工金属の表面部分に硬質粒子を保持させるスペ
ースを確実に確保させることができ、これにより、硬質
粒子を軟質・易加工金属に確実に埋め込ませ、安定した
状態に保持させることができ、硬質粒子の軟質・易加工
金属からの脱落を防止することができ、耐久性の向上に
貢献する。According to the present invention, a space for holding the hard particles can be reliably secured on the surface portion of the soft / easy-working metal. The hard particles can be reliably embedded and maintained in a stable state, and the hard particles can be prevented from falling off from the soft and easily processed metal, thereby contributing to an improvement in durability.
【0080】また特に請求項9に係る発明によれば、反
応物が硬質粒子を軟質・易加工金属に保持させるものと
して働き、これにより硬質粒子を軟質・易加工金属に、
より安定して保持させることができ、この観点から耐久
性の向上に貢献する。According to the ninth aspect of the present invention, the reactant functions to hold the hard particles on the soft / easy-to-work metal, thereby converting the hard particles into the soft / easy-to-work metal.
It can be held more stably, and contributes to improvement of durability from this viewpoint.
【0081】また、本発明の耐摩耗材料の製造方法の請
求項10に係る発明によれば、軟質・易加工金属の表面
に球形状粒子から成る硬質粒子を埋め込んだ耐摩耗材料
を製造することができ、軟化処理により軟質・易加工金
属を軟らかくして硬質粒子の埋め込みをおこなうので、
この硬質粒子の埋め込みを容易かつ確実におこなわせる
ことができ、球形状粒子から成る硬質粒子と潤滑剤とを
含む耐摩耗面を有する所望の耐摩耗材料を得ることがで
きる。According to the tenth aspect of the method for producing a wear-resistant material of the present invention, it is possible to produce a wear-resistant material in which hard particles composed of spherical particles are embedded in the surface of a soft and easily processed metal. The softening process softens the soft / easy-to-work metal and embeds the hard particles.
The embedding of the hard particles can be easily and reliably performed, and a desired wear-resistant material having a wear-resistant surface containing the hard particles composed of spherical particles and the lubricant can be obtained.
【図1】本発明の耐摩耗材料の製造方法の第1の実施形
態を示す断面部分を含む側面図である。FIG. 1 is a side view including a cross section showing a first embodiment of a method for producing a wear-resistant material of the present invention.
【図2】図1に示す製造方法の第1の実施形態によって
得られた本発明の耐摩耗材料の第1の実施形態を示す要
部拡大縦断面図である。FIG. 2 is an enlarged vertical sectional view of a main part of the first embodiment of the wear-resistant material of the present invention obtained by the first embodiment of the manufacturing method shown in FIG.
【図3】図2に示す耐摩耗材料の第1の実施形態を摺動
部に適用させた状態を示す要部拡大断面図である。FIG. 3 is an enlarged sectional view of a main part showing a state in which the first embodiment of the wear-resistant material shown in FIG. 2 is applied to a sliding portion.
【図4】本発明の耐摩耗材料の製造方法の第2の実施形
態、及びこの製造方法の第2の実施形態によって得られ
る耐摩耗材料の第2の実施形態を示す断面部分を含む側
面図である。FIG. 4 is a side view including a cross section showing a second embodiment of the method for producing a wear-resistant material of the present invention, and a second embodiment of the wear-resistant material obtained by the second embodiment of the production method; It is.
【図5】本発明の耐摩耗材料の製造方法の第3の実施形
態を示す断面部分を含む側面図である。FIG. 5 is a side view including a cross section showing a third embodiment of the method for producing a wear-resistant material of the present invention.
【図6】本発明の耐摩耗材料の製造方法の第4の実施形
態を示す断面部分を含む側面図である。FIG. 6 is a side view including a cross section showing a fourth embodiment of the method for producing a wear-resistant material according to the present invention.
1 パイプ状体 2 芯金 3 硬質粒子 3a 大径粒子 3b 小径粒子 4 シール部材 5 ハンマ 9 潤滑剤 10 厚さ寸法 12 移動部材(摺動部) 13 軸受部材(摺動部) 14 板状体 15 圧延ローラ 16 圧延ローラ 17 巻き込みローラ 21 板状体 22 板状体 23 ハンマ式プレス 25 パイプ状体 26 芯金 27 加工ローラ 28 加工ローラ DESCRIPTION OF SYMBOLS 1 Pipe-shaped body 2 Core metal 3 Hard particle 3a Large-diameter particle 3b Small-diameter particle 4 Seal member 5 Hammer 9 Lubricant 10 Thickness dimension 12 Moving member (sliding part) 13 Bearing member (sliding part) 14 Plate member 15 Rolling roller 16 Rolling roller 17 Roll-in roller 21 Plate-shaped body 22 Plate-shaped body 23 Hammer-type press 25 Pipe-shaped body 26 Core metal 27 Processing roller 28 Processing roller
Claims (10)
易な軟質・易加工金属の表面に、この軟質・易加工金属
よりも硬い硬質粒子を複数個埋め込み、これらの硬質粒
子が埋め込まれた軟質・易加工金属の表面部分を耐摩耗
面とした耐摩耗材料において、 上記硬質粒子が球形状粒子から成るとともに、 これらの硬質粒子間に形成される間隙部分に潤滑剤を保
有させたことを特徴とする耐摩耗材料。1. A plurality of hard particles, which are used for a sliding portion and are made of a relatively soft metal material and which are easy to machine, are embedded in the surface of a soft / easy-to-work metal. In a wear-resistant material having a surface portion of a soft / easy-to-work metal in which these hard particles are embedded as a wear-resistant surface, the hard particles are composed of spherical particles, and a gap formed between these hard particles is formed. A wear-resistant material characterized by having a lubricant held therein.
ム、銅、ニッケルのいずれかを母材とする合金のうちの
1つから成ることを特徴とする請求項1記載の耐摩耗材
料。2. The soft and easy-to-work metal comprises one of aluminum, copper, nickel, and an alloy having any one of aluminum, copper, and nickel as a base material. The wear-resistant material according to 1.
成ることを特徴とする請求項1または2記載の耐摩耗材
料。3. The wear-resistant material according to claim 1, wherein the hard particles are made of an alloy containing any one of chromium and cobalt as a base material.
動部材と、この移動部材を保持する保持部材とから成
り、 上記保持部材の上記移動部材に対向する面を、上記硬質
粒子が含まれる耐摩耗面としたことを特徴とする請求項
1〜3のいずれかに記載の耐摩耗材料。4. The sliding portion includes a moving member that performs at least one of a linear motion and a rotational motion, and a holding member that holds the moving member, wherein a surface of the holding member that faces the moving member is provided. The wear-resistant material according to any one of claims 1 to 3, wherein the wear-resistant surface includes the hard particles.
質粒子を複数段埋設して成る層状部に形成したことを特
徴とする請求項1〜4のいずれかに記載の耐摩耗材料。5. The wear-resistant surface is formed in a layered portion formed by embedding the hard particles in a plurality of stages in a direction perpendicular to the surface of the soft and easily processed metal. A wear-resistant material according to any one of the above.
mの範囲内に設定したことを特徴とする請求項5記載の
耐摩耗材料。6. The thickness of the layered portion is in the range of 10 to 500 μm, preferably 20 to 200 μm.
6. The wear-resistant material according to claim 5, wherein the value is set within a range of m.
径粒子の径寸法と小径粒子の径寸法との比を「6/4」
以上に設定したことを特徴とする請求項1〜6のいずれ
かに記載の耐摩耗材料。7. The hard particles are composed of a mixture of large-diameter particles and small-diameter particles, and the ratio of the diameter of the large-diameter particles to the diameter of the small-diameter particles is “6/4”.
The wear-resistant material according to any one of claims 1 to 6, which is set as described above.
上記硬質粒子の投影面積の集合値の割合である面積率
を、25〜80%の範囲内に設定したことを特徴とする
請求項1〜7のいずれかに記載の耐摩耗材料。8. An area ratio, which is a ratio of a set value of a projected area of the hard particles to a surface area of the soft and easily processed metal, is set in a range of 25 to 80%. 8. The wear-resistant material according to any one of 7.
との境界部に、当該硬質粒子と当該軟質・易加工金属と
の反応物を有することを特徴とする請求項1〜8のいず
れかに記載の耐摩耗材料。9. The method according to claim 1, wherein a reaction product of the hard particles and the soft / easy-to-work metal is provided at a boundary between the hard particles and the soft / easy-to-work metal. A wear-resistant material according to crab.
かも機械加工の容易な軟質・易加工金属の表面に、この
軟質・易加工金属よりも硬い球形状粒子から成る硬質金
属を複数個埋め込み、これらの硬質粒子間に形成される
間隙部分に潤滑剤を保有させた耐摩耗材料を製造する耐
摩耗材料の製造方法において、 上記硬質粒子の埋め込みを、上記軟質・易加工金属の所
定の軟化処理を施してからおこなうことを特徴とする耐
摩耗材料の製造方法。10. A hard metal made of a relatively soft metal material, and a plurality of hard metals made of spherical particles harder than the soft / easy-working metal are embedded in the surface of the soft / easy-to-work metal which is easy to machine. A method for producing a wear-resistant material in which a lubricant is retained in a gap formed between hard particles of the above-mentioned hard particles. A method for producing a wear-resistant material, which is performed after the application.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25445796A JPH10102265A (en) | 1996-09-26 | 1996-09-26 | Wear resistant material and its production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25445796A JPH10102265A (en) | 1996-09-26 | 1996-09-26 | Wear resistant material and its production |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH10102265A true JPH10102265A (en) | 1998-04-21 |
Family
ID=17265293
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25445796A Pending JPH10102265A (en) | 1996-09-26 | 1996-09-26 | Wear resistant material and its production |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH10102265A (en) |
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