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JPH0369190A - Conductor paste for mullite multi-layer wiring board and mullite multi-layer wiring board using it - Google Patents

Conductor paste for mullite multi-layer wiring board and mullite multi-layer wiring board using it

Info

Publication number
JPH0369190A
JPH0369190A JP20463889A JP20463889A JPH0369190A JP H0369190 A JPH0369190 A JP H0369190A JP 20463889 A JP20463889 A JP 20463889A JP 20463889 A JP20463889 A JP 20463889A JP H0369190 A JPH0369190 A JP H0369190A
Authority
JP
Japan
Prior art keywords
mullite
conductor
wiring board
wiring
multilayer wiring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20463889A
Other languages
Japanese (ja)
Inventor
Takashi Kuroki
喬 黒木
Shosaku Ishihara
昌作 石原
Takeshi Fujita
毅 藤田
Seiichi Tsuchida
槌田 誠一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP20463889A priority Critical patent/JPH0369190A/en
Publication of JPH0369190A publication Critical patent/JPH0369190A/en
Pending legal-status Critical Current

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  • Production Of Multi-Layered Print Wiring Board (AREA)

Abstract

PURPOSE:To enable a flat printed-circuit board without any warpage to be produced by optimizing an average grain diameter of tungsten powder of conductor paste material used for forming a wiring conductor for filling through-hole and for wiring. CONSTITUTION:After forming a conductor 2 by filling a conductor paste of W powder into a through-hole of a sheet by the screen printing method, a surface wiring conductor 3, a rear surface wiring conductor, and an inner-layer wiring conductor 1 are formed on this sheet. In this case, an average grain diameter of the W powder of a conductor paste to be used is set to 0.7-0.8mum for filling through-hole and a mullite multi-layer wiring board 4 is produced for wiring by using 0.8-3mum.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はムライト多層配線基板に係シ、特に基板のそう
を小さくするに好適なムライト多層配線基板用導体ベー
ス)>よびこれを用いたムライト多層配線基板に関する
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a mullite multilayer wiring board, and in particular, a conductor base for a mullite multilayer wiring board suitable for reducing the size of the board) and a mullite using the same. It relates to a multilayer wiring board.

〔従来の技術〕[Conventional technology]

最近に電子計算機の演算速度を速くするために、薄膜と
厚膜を混成した多層基板が、米国特許第4221047
号や、アイ・イー・イー、トランザクシ冒ンズ オン 
コンポーネント、ハイブリッド。
Recently, in order to increase the calculation speed of electronic computers, a multilayer substrate made of a mixture of thin and thick films has been published in US Pat. No. 4,221,047.
No., I.E.E., Tranzakushi Adventures on
component, hybrid.

アンド マニエクアクチャリング テクノロジ。and mani-equacturing technology.

シー エイチ エム 7’−6(198s牟6月)$1
68頁から8172頁(I E B B 、  yra
ns。
C.H.M. 7'-6 (June 198s) $1
pages 68 to 8172 (IEB, yra
ns.

Components、 Hybrids、 and 
Manufaoturing’f:eQbnolQg7
t VOl、 CHMT−6,t’m2 (June 
1985)pp、 16B−172)にかいて論じられ
ている。
Components, Hybrids, and
Manufaoturing'f:eQbnolQg7
t VOl, CHMT-6, t'm2 (June
1985) pp. 16B-172).

第2図は従来のセ9ミック多層配線基板を例示する要部
断簡図である。これらの基板はガラスセラミックス等の
セラミック多層配線基板で、内層配線導体1と、層間接
続のためのスルーホールに充填された導体2と、表面配
線導体3とを形成したセラミック基板を2.5〜5μ溝
にラッピングして平坦化してから、薄膜プロセスで配線
層5を形成したのち、はんだ層6接続によj5LsIチ
ップ7を塔載する。
FIG. 2 is a sectional view of the main parts illustrating a conventional ceramic multilayer wiring board. These boards are ceramic multilayer wiring boards such as glass ceramics, and are made of ceramic boards on which inner layer wiring conductors 1, conductors 2 filled in through holes for interlayer connections, and surface wiring conductors 3 are formed. After lapping into a 5 μm groove and flattening it, a wiring layer 5 is formed by a thin film process, and then a j5LsI chip 7 is mounted by connecting a solder layer 6.

第3図は第2図の製作プロセスの焼結時のセラミック基
板4のそ#)aの発生を示す断面図である。
FIG. 3 is a cross-sectional view showing the generation of part a of the ceramic substrate 4 during sintering in the manufacturing process shown in FIG.

これらのセラミック基板4の製作プロセスにかける焼却
時にそpaが発生する。
When these ceramic substrates 4 are incinerated during the manufacturing process, sopa is generated.

第4図は第2図の製作プロセスのラッピング時のセラミ
ック基板4の表面配線導体3の欠損あるいは基板内部の
空孔8の露出による欠陥の発生を示す断面図である。こ
れらのセラミック基板4の製作におけるラッピング時に
A −A’までラッピングすると、表面配線導体3の欠
損あるいは基板4の空孔のない層すよシ内部に存在する
空孔8の露出による薄膜プロセスでの欠陥の発生に起因
するLSIチップ7のはんだ層6のはんだ付は不良など
が発生する。
FIG. 4 is a cross-sectional view showing the occurrence of defects due to defects in the surface wiring conductor 3 of the ceramic substrate 4 or exposure of holes 8 inside the substrate during lapping in the manufacturing process shown in FIG. When lapping to A-A' during the production of these ceramic substrates 4, defects may occur in the thin film process due to defects in the surface wiring conductor 3 or exposure of holes 8 existing inside the layer width of the substrate 4 without holes. Defects occur in the soldering of the solder layer 6 of the LSI chip 7 due to the occurrence of defects.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上記従来技術はムライトセラミックス基板の性質につい
て第3図に示す焼結時の基板4のそ夕aの発生や、第4
図に示すラッピング時の表面配線導体3の欠損あるいは
基板4の内部に存在する空孔8の露出による薄膜プロセ
スでの欠陥の発生の点について配慮がされてからす、L
SIチップ7のはんだ層6によるはんだ付は不良が発生
するなどの問題が多い。
The above-mentioned prior art is concerned with the properties of mullite ceramic substrates, such as the generation of sores a on the substrate 4 during sintering as shown in FIG.
Consideration has been given to the occurrence of defects in the thin film process due to loss of the surface wiring conductor 3 during lapping as shown in the figure or exposure of holes 8 existing inside the substrate 4.
Soldering the SI chip 7 using the solder layer 6 has many problems such as the occurrence of defects.

本発明の目的は上記従来技術の問題点を解決し、そシの
ない平坦な基板を製作できるムライト多層配線基板用導
体ペーストおよびこれを用いたムライト多層配線基板を
提供することにある。
An object of the present invention is to solve the above-mentioned problems of the prior art and to provide a conductive paste for a mullite multilayer wiring board that can produce a smooth and flat board, and a mullite multilayer wiring board using the same.

〔t!題を解決するための手段〕[t! Means to solve the problem]

上記目的を達成するために1本発明によるムライト多層
配線基板用導体ベース)>よびこれを用いたムライト多
層配線基板は、ムライト多層配線基板の作製にかいて配
線導体形成に用いる導体ペースト原料のW(タングステ
ン)粉末の平均粒径を、スルーホール充填用と配線用と
に最適化して、スルーホール充填用にa7〜l18μ情
で配線用に1〜t5μ喝、またはスルーホール充填用に
a9〜1.5μ情で配線用にa8〜3μ情としたもので
あシ、また上記の導体ペーストを用いて配線導体形成し
たムライト多層配線基板のメタライズ部分t−機械的な
研摩によう平滑にするようにしたものであう、これによ
う必要とする基板のそシをI、SIテップ塔載部分で2
0μ慣、基板全体で200μ岳以内にし、またメタライ
ズ部分の凸を7μ情以内にすることができる。
In order to achieve the above object, (1) a conductor base for a mullite multilayer wiring board according to the present invention and a mullite multilayer wiring board using the same are manufactured using W, which is a conductor paste raw material used for forming wiring conductors in the production of a mullite multilayer wiring board; The average particle size of the (tungsten) powder is optimized for through-hole filling and wiring, and the size is 1-t5μ for wiring, or A9-1 for through-hole filling. The metallized part of the mullite multilayer wiring board on which wiring conductors were formed using the above conductor paste was smoothed by mechanical polishing. This is probably the one that was used for this purpose.
0μ, the entire board can be kept within 200μ, and the convexity of the metallized portion can be kept within 7μ.

〔作用〕[Effect]

上記ムライト多層配線基板用導体ベース)>よびこれを
用いたムライト多層配線基板は、薄膜形成あるいはLS
Iチップ搭載のための微小パターンのはんだ接続が必要
であるため基板表面が平坦でなければならないが、一方
の配線導体には大きく分けて眉間の接続に用いるスルー
ホイール充填用と表面および内層配線ならびに封止キャ
ップ用メタライズやはんだ接続およびI10ビンのろう
付は用メタライズの表面パターン形式用とが必要であυ
、これらの配線導体を個々にムライト基板に形成しても
基板にそうが発生しないが同時に同じ面に混在するとそ
うが発生するためそシが発生し慶いよつな導体配線が要
求されるので、スルーホール充填用と配線用とに配線目
的に応じて導体ペーストの材料であるW粉末の平均粒径
を変えることによう基板のそシを小さくするように作用
せしめ、またW粉末の粒径の組合せによっては配線部の
導体が基板表面よシも高くなって該高さにも差異がある
ため、焼結後!たはめっきシンタ後あるいは双方ともメ
タライズ部分を研摩することにより基板表面を平坦にす
るようにしている。
The above conductor base for mullite multilayer wiring board)> and mullite multilayer wiring board using this can be formed by thin film formation or LS.
The surface of the board must be flat because solder connections with minute patterns are required to mount the I-chip, but one wiring conductor is broadly divided into one for filling through wheels used for connections between the eyebrows, and one for surface and inner layer wiring. Metallization for sealing caps, solder connections, and brazing of I10 bottles require surface pattern type metalization.
Even if these wiring conductors are individually formed on a mullite board, the problem will not occur on the board, but if they are mixed on the same surface at the same time, the problem will occur. By changing the average particle size of the W powder, which is the material of the conductor paste, depending on the purpose of wiring, whether for filling through holes or for wiring, the particle size of the W powder can be changed to reduce the warp of the board. Depending on the combination, the conductor of the wiring part will be higher than the board surface and there will be a difference in height, so after sintering! The substrate surface is made flat by polishing the metallized portion or after plating sintering or both.

〔実施例〕〔Example〕

以下に本発明による一実施例を第1図によう説明する。 An embodiment according to the present invention will be explained below as shown in FIG.

第1図は本発明によるムライト多層配線基板用導体ペー
ストおよびこれを用いたムライト多層配線基板の一実施
例を示す配線導体形成に用いるスルーホール充填用と表
面および内層配線用の導体ペーストのW粉末の平均粒径
(μm)と基板Oそシ量(μ慣)/1OHとの関係のグ
ラフである。スルーホール充填用の導体ベース)1.1
のW粉末の平均粒径はそれぞれ(17〜08μ倶・α9
〜1・5μ洛である。このムライト多層配線基板用導体
ペーストおよびこれを用いたムライト多層配線基板の作
製方法について説明する。
Fig. 1 shows an example of the conductor paste for a mullite multilayer wiring board according to the present invention and a mullite multilayer wiring board using the same.W powder of the conductor paste for filling through holes and for surface and inner layer wiring used in forming wiring conductors. It is a graph of the relationship between the average particle diameter (μm) and the substrate O stress amount (μm)/1OH. Conductor base for filling through holes) 1.1
The average particle size of the W powder is (17~08μ/α9), respectively.
~1.5μ Raku. This conductor paste for a mullite multilayer wiring board and a method for manufacturing a mullite multilayer wiring board using the same will be described.

ムライトセラミック基板4の作製は次に示す原料と配合
割合でボールミルを用いて混合してスリップを作製し、
ドクタブレード法によりα2〜(L5騙厚のシートを作
製した。
The mullite ceramic substrate 4 was prepared by mixing the following raw materials and proportions using a ball mill to prepare a slip.
A sheet having a thickness of α2 to (L5) was prepared by the doctor blade method.

トリクロルエチレン   61  wt%1ツキにこの
シートをホットプレスで平坦化したのち、NGパンチで
(L1〜(L21JLφのスルーホールを形成した。こ
のシートのスルーホールにスクリーン印刷法でW粉末の
導体ペーストを充填して導体2を形成したのち、このシ
ートに表面配線導体3と裏面配線導体と内層配線導体1
を形成するため、目的に合った導体ペーストを用いて配
線−くターンをスクリーン印刷法で形成した。ついでホ
ットプレスにより熱圧着後に、1640℃の還元雰囲気
で焼結した。この焼結した基板40表裏面を研摩剤を内
蔵したブラシ等で研摩して、表面のセラでツク〈ず等を
除去後に、再度サンドブラスト法で表面を粗化してから
、無電解ニッケルめっき法でめっき膜を形成したのち、
700〜800℃でクンタを行う。このあとサンドペー
パ等の研摩法によ多導体(メタライズ)のみを平滑にす
る。
After flattening this sheet with 61 wt% trichlorethylene using a hot press, through holes of (L1 to (L21JLφ) were formed using an NG punch. A conductive paste of W powder was applied to the through holes of this sheet by screen printing. After filling and forming conductor 2, surface wiring conductor 3, back surface wiring conductor, and inner layer wiring conductor 1 are placed on this sheet.
In order to form the circuit, wiring turns were formed using a screen printing method using a conductive paste suitable for the purpose. Then, after thermocompression bonding using a hot press, sintering was performed in a reducing atmosphere at 1640°C. The front and back surfaces of this sintered substrate 40 are polished with a brush containing an abrasive, etc. to remove scratches, etc. on the surface, and then the surface is roughened again by sandblasting, and then electroless nickel plating is applied. After forming the plating film,
Kunta is performed at 700-800 degrees Celsius. After this, only the multi-conductor (metallized) is smoothed by polishing with sandpaper or the like.

本実施例のスルーホールへの充填用と表面)よび内層配
線用の導体ペーストは次の原料と配合割合でボールミル
・3本ロールミルを用いて作製した。
Conductive pastes for filling through holes (for filling through holes, surface) and inner layer wiring were prepared using a ball mill and a three-roll mill using the following raw materials and mixing ratios.

W粉末         79〜86 −%ビヒクル 
       14〜21  wt%(エチルセルロー
ズ・ポリビニールブチラール等8〜12 wt%を溶剤
とした) nブチルカルピトールアセテート スルーホールへの充填用の導体ペーストは焼結助剤とゲ
ル化剤をそれぞれペーストに対して(L5〜3tt%添
加したものを使用した。
W powder 79-86 -% vehicle
14 to 21 wt% (8 to 12 wt% of ethyl cellulose, polyvinyl butyral, etc. used as a solvent) n-butylcarpitol acetate The conductor paste for filling through holes uses a sintering aid and a gelling agent as pastes, respectively. (L5 to 3tt% added) was used.

導体ペーストに用いるW粉末の平均粒径は第1図に示す
ように基板4の焼結収縮率に微妙に関係する。つまり平
均粒径α7〜I18μ情のW粉末を用いたスルーホール
充填用のペースト1と、平均粒径l1lL9〜1.53
mのW粉末を用いたスルーホール充填用のベース)Iと
、表面配線導体3シよび内層配線導体1等の配線用のペ
ーストに用いたW粉末の平均粒径と、基板4のそう量と
の関係から、スルホール充填用のペースト1.Iでは基
板4のそう量の仕様を満足する最適な配線用のペースト
のW粉末の平均粒径との組合せが異なる。
The average particle size of the W powder used in the conductive paste is delicately related to the sintering shrinkage rate of the substrate 4, as shown in FIG. In other words, paste 1 for through-hole filling using W powder with an average particle size of α7 to I18μ, and paste 1 for filling through holes using W powder with an average particle size of l1L9 to 1.53.
The average particle size of the W powder used in the paste for wiring such as the surface wiring conductor 3 and the inner layer wiring conductor 1, and the amount of the W powder on the substrate 4. From the relationship, paste 1 for filling through holes. In I, the combination with the average particle size of the W powder of the optimum wiring paste that satisfies the specification of the amount of the substrate 4 is different.

よって本実施例ではムライト多層配線基板の配線導体形
式に用いる導体ペーストのW粉末の平均粒径として、ス
ルーホール充填用に07〜&8μmlと配線用に1〜t
5μ情の組合せと、スルーホール充填用にCL9〜L5
μ情と配線用に(L8〜5μ情の組合せの導体ペースと
した。またこの組合せの導体ペーストを用いてムライト
多層配線基板を作製するようにした。
Therefore, in this example, the average particle size of the W powder of the conductor paste used for the wiring conductor type of the mullite multilayer wiring board is 07~&8μml for through hole filling and 1~t for wiring.
CL9 to L5 for the combination of 5μ and through hole filling
A combination of conductive pastes (L8 to 5 μm) was used for μ conductors and wiring. Also, a mullite multilayer wiring board was manufactured using this combination of conductor pastes.

またスルーホール充填用のベース)1.1とでは、焼結
後のスルーホール部分の導体2と基板40表面との段差
に差異があう、ベース)Iでは1〜3μmの凸でペース
ト亘では10〜15μ鴨の凸である。このためにスルー
ホール充填用のベース)1.1を用いた基板4では焼結
後の平坦化方法を異にした。つまシベース)1を用いた
場合にはスルーホール部分の導体20表面を8〜12μ
慣削シ取シ、ペーストIを用いた場合には基板4そのも
ののそbtを小さくするために荷重をかけて再度焼成し
てそシを修正した。
In addition, there is a difference in the level difference between the conductor 2 in the through-hole part after sintering and the surface of the substrate 40 in Base) 1.1 for filling through-holes; in Base) I, there is a convexity of 1 to 3 μm, and in the case of Paste, it is 10 μm. ~15μ duck convex. For this reason, the flattening method after sintering was different for the substrate 4 using the base 1.1 for filling through holes. When using Tsumashi base) 1, the surface of the conductor 20 in the through hole part is 8 to 12 μm.
When paste I was used, the thickness of the substrate 4 itself was corrected by applying a load and firing it again in order to reduce the thickness of the substrate 4 itself.

このように基板40表面を平坦化してから無電解ニッケ
ルめっきで1〜3μ情のニッケル膜を形成し、これをシ
ンタ処理した後に、めっき膜の粒状析出による表面の凹
凸の粗化を修正するために。
After flattening the surface of the substrate 40 in this way, a nickel film with a thickness of 1 to 3 μm is formed by electroless nickel plating, and after this is sintered, in order to correct the roughening of the surface irregularities caused by granular precipitation of the plating film. To.

めっき膜上をサンドペーパ等で研摩して平滑した。The plated film was polished and smoothed with sandpaper or the like.

その結果、基板40そ少量aはLSIチップ7の搭載部
分では20μ情以内で、基板4全体では200μ情以内
になった。また基板4のメタライズ部分の凸は2〜4μ
mとなう、メタライズ表面の粗さも1μs (Rmax
 )で良好であった。この場合にメタライズ部分のみを
研摩することを目的としているため、基板4のセラミッ
クを削る量が少なく、基板内部の空孔8が露出すること
もなかった。
As a result, the amount a of the substrate 40 was within 20μ in the area where the LSI chip 7 was mounted, and within 200μ in the entire substrate 4. Also, the convexity of the metallized part of the substrate 4 is 2 to 4 μm.
The roughness of the metallized surface is also 1μs (Rmax
) was in good condition. In this case, since the purpose was to polish only the metallized portion, the amount of ceramic of the substrate 4 to be removed was small, and the holes 8 inside the substrate were not exposed.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、ムライト多層配線基板を平坦に作製で
きるので、はんだ付けによるLSIチップ塔載および薄
膜形成の歩留シを従来の40%から95%程度に向上で
きる効果がある。
According to the present invention, since a mullite multilayer wiring board can be fabricated flat, the yield of LSI chip mounting and thin film formation by soldering can be improved from 40% to about 95%.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明によるムライト多層配線基板用導体ベー
ス)Thよびこれを用いたムライト多層配線基板の一実
施例を示すスルーホール充填用と表面および内層配線用
の導体ペーストのW粉末の平均粒径と基板のそシ量の関
係のグラフ、第2図は従来のセラミック多層配線基板を
例示する断面図、第3図は第2図の焼結時の基板のそう
の発生を示す断面図、第4図は第2図のラッピング時の
表面配線導体の欠損あるいは基板内部の空孔の露出によ
る欠陥の発生を示す断面図である。 1・・・内層配線導体、2・・・スルーホールに充填さ
れた導体、5・・・内層配線導体、4・・・セラミック
基板、5・・・薄膜層、6−・はんだ層、7・・・LS
Iチップ、8・・・基板内の空孔、a・・・そ多量、b
・・・空孔のない層、A−A’・・・研摩で削った面、
■・−・W粒径α7〜αB#1%のスルーホール充填用
ペースト、I・・・W粒径(L?〜1.5μ情のスルー
ホール充填用ペースト。 第 2L¥1 1 図 蔦 5図 第 4回 C画乙赤果、用へ°−入トノ
Fig. 1 shows an example of the conductor base for a mullite multilayer wiring board (Th) according to the present invention and a mullite multilayer wiring board using the same. A graph of the relationship between the diameter and the amount of deflection of the board, FIG. 2 is a cross-sectional view illustrating a conventional ceramic multilayer wiring board, and FIG. FIG. 4 is a cross-sectional view showing the occurrence of defects due to loss of the surface wiring conductor or exposure of holes inside the substrate during the lapping shown in FIG. 2. DESCRIPTION OF SYMBOLS 1... Inner layer wiring conductor, 2... Conductor filled in through hole, 5... Inner layer wiring conductor, 4... Ceramic substrate, 5... Thin film layer, 6-... Solder layer, 7...・・LS
I chip, 8...vacancies in the substrate, a...amount, b
... Layer without pores, A-A' ... Polished surface,
■...Paste for filling through holes with W grain size α7~αB#1%, I...Paste for filling through holes with W grain size (L?~1.5μ). 2nd L¥1 1 Figure Tsuta 5 Figure No. 4

Claims (4)

【特許請求の範囲】[Claims] 1. ムライト多層配線基板の配線導体形成に用いる導
体ペーストのタングステン粉末の平均粒径を、スルーホ
ール充填用に0.7〜0.8μmとし、配線用に1〜1
.5μmとしたムライト多層配線基板用導体ペースト。
1. The average particle size of the tungsten powder in the conductor paste used for forming wiring conductors on a mullite multilayer wiring board is 0.7 to 0.8 μm for through-hole filling, and 1 to 1 μm for wiring.
.. Conductive paste for mullite multilayer wiring boards with a thickness of 5 μm.
2. ムライト多層配線基板の配線導体形成に用いる導
体ペーストのタングステン粉末の平均粒径を、スルーホ
ール充填用に0.9〜1.5μmとし、配線用に0.8
〜3μmとしたムライト多層配線基板用導体ペースト。
2. The average particle diameter of the tungsten powder in the conductor paste used to form wiring conductors on a mullite multilayer wiring board is 0.9 to 1.5 μm for through-hole filling, and 0.8 μm for wiring.
A conductive paste for mullite multilayer wiring boards with a thickness of ~3 μm.
3. 請求項1または請求項2記載の導体ペーストを用
いて配線導体形成したムライト多層配線基板。
3. A mullite multilayer wiring board in which wiring conductors are formed using the conductive paste according to claim 1 or 2.
4. 請求項3記載のムライト多層配線基板および無電
解めっき後にシンタした基板のメタライズ部分のみを研
摩により平滑にしたムライト多層配線基板。
4. The mullite multilayer wiring board according to claim 3, and a mullite multilayer wiring board in which only the metallized portion of the board sintered after electroless plating is smoothed by polishing.
JP20463889A 1989-08-09 1989-08-09 Conductor paste for mullite multi-layer wiring board and mullite multi-layer wiring board using it Pending JPH0369190A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20463889A JPH0369190A (en) 1989-08-09 1989-08-09 Conductor paste for mullite multi-layer wiring board and mullite multi-layer wiring board using it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20463889A JPH0369190A (en) 1989-08-09 1989-08-09 Conductor paste for mullite multi-layer wiring board and mullite multi-layer wiring board using it

Publications (1)

Publication Number Publication Date
JPH0369190A true JPH0369190A (en) 1991-03-25

Family

ID=16493794

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20463889A Pending JPH0369190A (en) 1989-08-09 1989-08-09 Conductor paste for mullite multi-layer wiring board and mullite multi-layer wiring board using it

Country Status (1)

Country Link
JP (1) JPH0369190A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006331016A (en) * 2005-05-25 2006-12-07 Koha Co Ltd Lighting system for article for display and vending machine equipped with the same
JP2008075278A (en) * 2006-09-19 2008-04-03 Giken Seisakusho Co Ltd Excavating claw and auger head

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006331016A (en) * 2005-05-25 2006-12-07 Koha Co Ltd Lighting system for article for display and vending machine equipped with the same
JP2008075278A (en) * 2006-09-19 2008-04-03 Giken Seisakusho Co Ltd Excavating claw and auger head

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