JPH0344455A - Highly corrosion resistant roll and its production - Google Patents
Highly corrosion resistant roll and its productionInfo
- Publication number
- JPH0344455A JPH0344455A JP17986189A JP17986189A JPH0344455A JP H0344455 A JPH0344455 A JP H0344455A JP 17986189 A JP17986189 A JP 17986189A JP 17986189 A JP17986189 A JP 17986189A JP H0344455 A JPH0344455 A JP H0344455A
- Authority
- JP
- Japan
- Prior art keywords
- roll
- vacuum
- highly corrosion
- water glass
- corrosion resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000007797 corrosion Effects 0.000 title claims abstract description 17
- 238000005260 corrosion Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000000919 ceramic Substances 0.000 claims abstract description 20
- 238000007789 sealing Methods 0.000 claims abstract description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 15
- 238000007872 degassing Methods 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 21
- 239000011248 coating agent Substances 0.000 abstract description 10
- 238000000576 coating method Methods 0.000 abstract description 10
- 238000007747 plating Methods 0.000 abstract description 10
- 238000009713 electroplating Methods 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 230000008878 coupling Effects 0.000 abstract description 3
- 238000010168 coupling process Methods 0.000 abstract description 3
- 238000005859 coupling reaction Methods 0.000 abstract description 3
- 238000007751 thermal spraying Methods 0.000 abstract description 2
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 230000008595 infiltration Effects 0.000 abstract 1
- 238000001764 infiltration Methods 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000011148 porous material Substances 0.000 description 6
- 238000005524 ceramic coating Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 238000007654 immersion Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Landscapes
- Coating By Spraying Or Casting (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、高耐食性ロール、特に電気めっき槽設備内で
過酷な条件で使用される高耐食性ロールおよびその製造
法に関する。かかる高耐食性ロールは、主に電気めっき
用、ある腎）は溶融浸漬めっき用のジンクロール、ター
ンロール等に用いられる。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a highly corrosion resistant roll, particularly a highly corrosion resistant roll used under harsh conditions in electroplating tank equipment, and a method for manufacturing the same. Such highly corrosion resistant rolls are mainly used for electroplating, and some are used as zinc rolls, turn rolls, etc. for hot-dip plating.
（従来の技術）
従来、耐食性を向上させるため、ロールはステンレス、
高合金等の高耐食性金属を用いてきた。(Conventional technology) Conventionally, to improve corrosion resistance, rolls were made of stainless steel,
Highly corrosion resistant metals such as high alloys have been used.
しかし長期にわたり使用するとロール表面が腐食され凹
凸が激しくなってストリップに疵を生しさせる問題があ
った。However, when used for a long period of time, the roll surface corrodes and becomes extremely uneven, resulting in the formation of flaws in the strip.
このため、ロール表面にセラミックを溶射して更に耐食
性を高めたロールが使用されている。For this reason, rolls are used whose surfaces are thermally sprayed with ceramic to further improve corrosion resistance.
しかし、このようなセラミック溶射被膜は多孔性被膜で
あり、長期に使用していると、被膜の孔部分を通してロ
ール自身が腐食され、そのためにセラミック溶射被膜が
内側から剥離するという問題が生し、これもストリップ
に疵を生しさせる要因となった。However, such a ceramic sprayed coating is a porous coating, and when used for a long time, the roll itself corrodes through the pores of the coating, which causes the problem that the ceramic sprayed coating peels off from the inside. This also caused flaws in the strip.
（発明が解決しようとする諜８）
この多孔性被膜の孔を埋めるため、最近では、電子ビー
ム若しくはレーザービームをセラミック溶射被膜の表面
に照射し、セラミックを溶かして（再溶融）封孔する方
法や、有機剤を使用して封孔する方法等が用いられてい
る。(Spirit 8) In order to fill the pores in this porous coating, a method has recently been developed that irradiates the surface of the ceramic sprayed coating with an electron beam or laser beam to melt (re-melt) the ceramic and seal the pores. A method of sealing the pores using an organic agent is also used.
前者の封孔方法では、真空式または局部真空式で照射処
理が行われるが、装置本体のコストが高く、封孔処理コ
ストも当然高くなり、経済性の面で劣る。また、この方
法では表面のセラミックのみを溶融して封孔するが、そ
のときの真空度によって封孔処理結果にばらつきが生し
る。特に本発明が対象とするような大型ロールを処理す
る場合、高真空度を常に一定に確保することは極めて困
難であるため、めっき液に浸漬するジンクロールのよう
な過酷な環境で使用されるロールでは充分な耐食性が確
保できなかった。In the former method of sealing, the irradiation treatment is performed using a vacuum method or a local vacuum method, but the cost of the main body of the apparatus is high, and the cost of the sealing treatment is also naturally high, so it is inferior in terms of economic efficiency. Further, in this method, only the ceramic on the surface is melted to seal the hole, but the result of the sealing process varies depending on the degree of vacuum at that time. Especially when processing large rolls such as those targeted by the present invention, it is extremely difficult to always maintain a constant high degree of vacuum, so they are used in harsh environments such as zinc rolls immersed in plating solution. Sufficient corrosion resistance could not be ensured with rolls.
一方、後者の有機剤を使用する方法は、真空脱ガスを行
った後、Ｓ１樹脂のような有機剤溶液に浸漬させて、高
温乾燥させる方法である。On the other hand, the latter method of using an organic agent is a method of performing vacuum degassing, then immersing it in an organic agent solution such as S1 resin, and drying at a high temperature.
この方法で問題となるのは、脱ガス不充分のまま有機剤
溶液に浸漬させると、封孔が十分でなくなり、耐食性が
極端に劣ることである。また有機剤の種類によっても耐
食性が左右される。The problem with this method is that if the material is immersed in an organic solution with insufficient degassing, the pores will not be sealed sufficiently and the corrosion resistance will be extremely poor. Corrosion resistance is also influenced by the type of organic agent.
従って、本発明の目的は、例えば電気めっき用めっき液
のような厳しい腐食環境にも高耐食性を示すセラミック
溶射高耐食性ロールおよびその安価な製造法を提供する
ことである。Therefore, an object of the present invention is to provide a highly corrosion-resistant ceramic sprayed roll that exhibits high corrosion resistance even in a severe corrosive environment such as a plating solution for electroplating, and an inexpensive manufacturing method thereof.
（課題を解決するための手段）
上記目的を達成するため、本発明では、水ガラスにより
封孔処理されたセラミックス層をロール表面に設けるの
である。(Means for Solving the Problems) In order to achieve the above object, in the present invention, a ceramic layer sealed with water glass is provided on the roll surface.
かかるロールはロール表面にセラミックスを被覆してか
ら以下の方法で封孔を行うことにより製造される。つま
り、真空中で予熱して、その後真空中で水ガラス液に浸
漬させる。この場合、特に制限されないが、真空度は１
〜１０− ’Ｔｏｒｒ程度の低い真空度で十分である。Such a roll is manufactured by coating the roll surface with ceramics and then sealing the roll using the following method. That is, it is preheated in a vacuum and then immersed in a water glass solution in a vacuum. In this case, although not particularly limited, the degree of vacuum is 1
A low degree of vacuum on the order of ~10-' Torr is sufficient.
真空中での予熱処理は脱ガスを目的に行うのであって、
脱ガスが行われる限りその真空度は制限されないが、真
空中で脱ガスを行う場合、予めセラミックス被膜層を設
けたロールを真空中で予熱した後、脱ガスを行えば、さ
らに脱ガス効果が上がり良好な封孔を行うことができる
。Preheating treatment in vacuum is performed for the purpose of degassing,
The degree of vacuum is not limited as long as degassing is performed, but if degassing is performed in a vacuum, the degassing effect can be further improved by preheating a roll with a ceramic coating layer in vacuum before degassing. Good sealing can be performed.
水ガラスにより封孔を行ってからは所望により乾燥処理
を行ってもよい。After sealing with water glass, drying treatment may be performed as desired.
〈作用）
次に、本発明の構成についてさらに具体的にを説明する
。<Function> Next, the configuration of the present invention will be explained in more detail.
ロール表面を被覆するセラミックス層は、例えば従来の
ような溶射被膜であってもよく、あるいは蒸着法、電気
泳動法等のような多孔質被膜であってもよい。組成的に
は八Ｑ２０．のようなアルミナ系、ＷＣ，ＴｉＣのよう
なカーバイト系等であってもよく、特定のものに制限さ
れない。かかるセラミックス層自体はすでに公知であり
、その製造法もすでに慣用的に行われているもので十分
であり、以下説明を簡潔にするためにこれ以上の説明を
省略する。The ceramic layer covering the roll surface may be, for example, a conventional thermal spray coating, or a porous coating formed by vapor deposition, electrophoresis, or the like. In terms of composition, it is 8Q20. It may be alumina-based such as WC, carbide-based such as TiC, etc., and is not limited to a specific one. Such a ceramic layer itself is already known, and the manufacturing method thereof is already conventionally used. Therefore, further explanation will be omitted for the sake of brevity.
封孔処理前にセラミックス被膜層からの脱ガスを行うた
め予熱を行うが、あまり高温で処理すると、ロール自体
の材質に影響を及ぼし、一方、余り低温でも脱ガス効果
がなくなることから、好ましくは１００〜３００″Ｃの
間で処理するのが良い。Preheating is performed to degas the ceramic coating layer before the sealing treatment, but if the treatment is performed at too high a temperature, it will affect the material of the roll itself, and on the other hand, if the temperature is too low, the degassing effect will be lost, so it is preferable. It is best to process at a temperature between 100 and 300''C.
脱ガス時間については、脱ガス効果に関係するため、長
い方が良いが、あまり長すぎても効果はそれ捏上がらな
いため好ましくは１時間以内で行うのが良い。Regarding the degassing time, it is related to the degassing effect, so the longer the better, but if it is too long, the effect will not be improved, so it is preferably carried out within 1 hour.
本発明においては、脱ガス処理時の真空度については、
高真空度は不要で、１〜１０−’Ｔｏｒｒ程度の低真空
度で十分であり、このため特殊な真空ポンプを使う必要
がないため、真空装置自体コストも低く、従って処理コ
ストも安価となる。In the present invention, the degree of vacuum during degassing treatment is as follows:
There is no need for a high degree of vacuum, and a low degree of vacuum of about 1 to 10-'Torr is sufficient.Therefore, there is no need to use a special vacuum pump, so the cost of the vacuum equipment itself is low, and therefore the processing cost is also low. .
次に、上述のように処理されたロールに封孔処理を施す
場合、ロール自体を水ガラス液に浸漬させる方法もある
が、好ましくは第１図に示すように一部分のみ浸漬させ
、ロールを回転させなから封孔処理を行うことも可能で
ある。Next, when performing sealing treatment on the roll treated as described above, there is a method of immersing the roll itself in water glass liquid, but preferably only a portion is immersed as shown in Figure 1, and the roll is rotated. It is also possible to perform pore sealing treatment without leaving it.
図中、セラミックス被覆層１０を備えたロール１２はカ
ップリング１４を経てモータＭで回転支持されながら容
器１６に収容された水ガラス液１８に浸漬され、封孔処
理が行われる。In the figure, a roll 12 provided with a ceramic coating layer 10 is immersed in a water glass liquid 18 contained in a container 16 while being rotatably supported by a motor M via a coupling 14, and a sealing process is performed.
このように、本発明による方法であれば、処理装置自体
もコンパクトになり、水ガラスの消費量も少なくなり、
処理コストも宮くなる。In this way, with the method according to the present invention, the processing equipment itself becomes compact, the amount of water glass consumed is reduced,
Processing costs will also go up.
本発明では処理液に水ガラス液を用いたが、他の処理液
、例えばＳｔ樹脂やエチルシリケート液では、得られる
ロールを高温でのめっき液に用いた際、耐食性に劣るこ
とが、発明者らのラボテストにより判明した。In the present invention, a water glass solution was used as the processing solution, but the inventors have discovered that other processing solutions, such as St resin or ethyl silicate solution, have poor corrosion resistance when the resulting roll is used in a high-temperature plating solution. This was revealed through laboratory tests.
水ガラスは、その上成分がＳｉｎｇ、Ｎａｎｏであるケ
イ酸ソーダであり、水で薄めて使用する。好ましい組成
は５ｉＯｉ：４〜５ ｗｔ％およびＮａｔＯ：１〜３
ｗｔ％である。Water glass is a sodium silicate whose additional ingredient is Sing, Nano, and is used diluted with water. The preferred composition is 5iOi: 4-5 wt% and NatO: 1-3
It is wt%.
封孔処理終了後、必要により乾燥処理を行ってもよく、
その場合の乾Ｒ温度については、水ガラスの成分により
、異なるため特に規制はしていないが、好ましくは３０
０〜５００ ”Ｃである。After completion of the sealing process, a drying process may be performed if necessary.
In that case, the drying R temperature is not particularly regulated as it varies depending on the components of the water glass, but it is preferably 30
0~500''C.
（実施例） 実施例により本発明を具体的に説明する。(Example) The present invention will be specifically explained with reference to Examples.
実施例１
０一ル寸法が直径２００ 開Ｘ胴長２００ 間のステン
Ｌ／ スＷＢ （ＳｔｌＳ４３０）製ロール表ｆｉｆ
ニ１００ ％ ＡＱ ｚ Ｏ３（７）組成をもったアル
ミナ系セラミックスを慣用手段で溶射して得られたセラ
ミックス溶射被膜にＩ Ｔｏｒｒの真空下で１５０℃Ｘ
３０分の予熱処理を行ってから、第１図に示すようにし
て以下の条件で封孔処理を行った。Example 1 Roll table made of stainless steel L/S WB (StlS430) between diameter 200 and open length x body length 200
A ceramic sprayed coating obtained by thermal spraying an alumina ceramic having a composition of 100% AQ z O3 (7) by a conventional method was heated at 150°C under a vacuum of I Torr.
After preheating for 30 minutes, sealing was performed under the following conditions as shown in FIG.
旦五ゑ往：
封孔液 ５Ｉｏｔ ２１ｗｔ％、Ｎａ１Ｏ１０ｗｔ
％の水ガラス溶液を５倍に水で希釈
して使用
真空度 Ｉ Ｔｏｒｒ
浸漬方法 ロール部分浸漬
ロール回転数 １ ｒｐｍ
処理時間 ３０分
得られたロールを３５０”ＣＸ２時間乾燥してから下記
＆１１戒のメツキ浴を使った実際の電気Ｎｉめっきライ
ンにジンクロールとして組み込んでその耐久性を見たと
ころ１年間の使用に耐えた。セラミックス被膜の剥離は
全くみられなかった。Dangoe: Sealing liquid 5Iot 21wt%, Na1O10wt
% water glass solution was diluted 5 times with water and used Vacuum degree I Torr Immersion method Partial immersion of the roll Roll rotation speed 1 rpm Processing time 30 minutes The obtained roll was dried at 350"C for 2 hours and then subjected to the following & 11 precepts. When it was incorporated as a zinc roll into an actual electrolytic Ni plating line using a plating bath, its durability was tested and it withstood one year of use.No peeling of the ceramic coating was observed.
めっき液組成 ： ＮｉＳＯ４・６Ｈｔｏ ２８０ｇ
／ ＩＮａｚＳＯａ １００ｇ／ ｌ
Ｚｎ５Ｏａ・７１２０ １２０ｇ／ ｊ！ｐＨ：２
浴温度 ：５０℃
実施例２
本例では実施例１で製造されたロールを下記組成の溶融
塩ＡＱめっきのジンクロールとして使用した。Plating solution composition: NiSO4・6Hto 280g
/ INazSOa 100g/ l Zn5Oa・7120 120g/ j! pH: 2 Bath temperature: 50°C Example 2 In this example, the roll manufactured in Example 1 was used as a zinc roll for molten salt AQ plating having the following composition.
メツキ液ｍ或 ： ６２ａ＋ｏＨＡＱｃＱｚ−１８ｍｏ
ＨＫＣＱ−２０ｍｏｌＸ ＮａＣＱ 混合溶融塩浴温
度 ： ２００ ’Ｃ
耐久性に関し実施例１と同様の結果を得た。Metsuki liquid m or: 62a+oHAQcQz-18mo
HKCQ-20molX NaCQ Mixed molten salt bath temperature: 200'C The same results as in Example 1 were obtained regarding durability.
（発明の効果）
本発明によるロールを１年間使用した結果、いずれもセ
ラミック層の剥離は認められず、良好な絶縁性を保って
おり、したがって、本発明により、電気めっき用および
溶融塩めっき用、さらに溶融金属めっき用ロールとして
最適なロールが開発できた。(Effects of the Invention) As a result of using the roll according to the present invention for one year, no peeling of the ceramic layer was observed in any of the rolls, and good insulation properties were maintained. Furthermore, we were able to develop a roll that is ideal for hot-dip metal plating.
第１図は、本発明による封孔処理を行う１実施例を説明
する図面である。
ｌＯ： セラミックス被覆層
１２： ロール
１４ ：
カップリング
Ｍ ：
モータ
１６ ：
容器
１８ ：
水ガラス液FIG. 1 is a diagram illustrating an embodiment of the sealing process according to the present invention. lO: Ceramic coating layer 12: Roll 14: Coupling M: Motor 16: Container 18: Water glass liquid
Claims (2)
をロール表面に備えたことを特徴とする高耐食性ロール
。(1) A highly corrosion-resistant roll characterized by having a ceramic layer sealed with water glass on the roll surface.
空下にて予熱して脱ガス処理を行い、しかる後真空下で
ロール表面を水ガラス液に浸漬して封孔処理を施すこと
を特徴とする高耐食性ロールの製造法。(2) The roll surface is coated with ceramics, then preheated under vacuum to perform a degassing treatment, and then the roll surface is immersed in water glass liquid under vacuum to perform a sealing treatment. Manufacturing method for highly corrosion resistant rolls.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17986189A JPH0344455A (en) | 1989-07-12 | 1989-07-12 | Highly corrosion resistant roll and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17986189A JPH0344455A (en) | 1989-07-12 | 1989-07-12 | Highly corrosion resistant roll and its production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0344455A true JPH0344455A (en) | 1991-02-26 |
Family
ID=16073196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17986189A Pending JPH0344455A (en) | 1989-07-12 | 1989-07-12 | Highly corrosion resistant roll and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0344455A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06212379A (en) * | 1992-05-14 | 1994-08-02 | Purakusuea Kogaku Kk | Production of immersing member into hot dip galvanizing bath and its production |
| JPH06322499A (en) * | 1992-08-26 | 1994-11-22 | Purakusuea Kogaku Kk | Molten zinc erosion resistant alloy and its production and application |
| WO1996027694A1 (en) * | 1995-03-08 | 1996-09-12 | Tocalo Co., Ltd. | Member having composite coating and process for producing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5770275A (en) * | 1980-10-20 | 1982-04-30 | Mitsubishi Heavy Ind Ltd | Pore sealing treatment of ceramic sputtered film |
| JPS63100162A (en) * | 1986-10-16 | 1988-05-02 | Nittetsu Hard Kk | Roll for hot dipping in molten metal having superior metal pickup resistance |
| JPH01240677A (en) * | 1988-03-18 | 1989-09-26 | Nomura Tokin:Kk | Corrosion resistant spray coated metal |
-
1989
- 1989-07-12 JP JP17986189A patent/JPH0344455A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5770275A (en) * | 1980-10-20 | 1982-04-30 | Mitsubishi Heavy Ind Ltd | Pore sealing treatment of ceramic sputtered film |
| JPS63100162A (en) * | 1986-10-16 | 1988-05-02 | Nittetsu Hard Kk | Roll for hot dipping in molten metal having superior metal pickup resistance |
| JPH01240677A (en) * | 1988-03-18 | 1989-09-26 | Nomura Tokin:Kk | Corrosion resistant spray coated metal |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06212379A (en) * | 1992-05-14 | 1994-08-02 | Purakusuea Kogaku Kk | Production of immersing member into hot dip galvanizing bath and its production |
| JPH06322499A (en) * | 1992-08-26 | 1994-11-22 | Purakusuea Kogaku Kk | Molten zinc erosion resistant alloy and its production and application |
| WO1996027694A1 (en) * | 1995-03-08 | 1996-09-12 | Tocalo Co., Ltd. | Member having composite coating and process for producing the same |
| GB2313847A (en) * | 1995-03-08 | 1997-12-10 | Tocalo Co Limited | Member having composite coating and process for producing the same |
| GB2313847B (en) * | 1995-03-08 | 1998-12-09 | Tocalo Co Ltd | Member having composite coating and process for producing the same |
| US6129994A (en) * | 1995-03-08 | 2000-10-10 | Tocalo Co., Ltd. | Member having composite coating and process for producing the same |
| DE19681296C2 (en) * | 1995-03-08 | 2003-01-23 | Tocalo Co Ltd | Composite coating element and method of making the same |
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