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JPH0335868A - Refractory abrasion member for sliding stop- per in metallurgical vessel - Google Patents

Refractory abrasion member for sliding stop- per in metallurgical vessel

Info

Publication number
JPH0335868A
JPH0335868A JP13423890A JP13423890A JPH0335868A JP H0335868 A JPH0335868 A JP H0335868A JP 13423890 A JP13423890 A JP 13423890A JP 13423890 A JP13423890 A JP 13423890A JP H0335868 A JPH0335868 A JP H0335868A
Authority
JP
Japan
Prior art keywords
wear
molten steel
tar
sealing layer
sliding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13423890A
Other languages
Japanese (ja)
Inventor
Hans Rothfuss
ハンス・ロートフス
Georges Wernert
ゲオルゲス・ヴエルネルト
Raimund Brueckner
ライムント・ブリユツクネル
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Didier Werke AG
Original Assignee
Didier Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Didier Werke AG filed Critical Didier Werke AG
Publication of JPH0335868A publication Critical patent/JPH0335868A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/50Pouring-nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/14Closures
    • B22D41/22Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
    • B22D41/28Plates therefor
    • B22D41/36Treating the plates, e.g. lubricating, heating

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)

Abstract

PURPOSE: To prevent the deterioration of slidability of a sliding plate by evaporation of a lubricant, such as tar, with which the sliding plate of a sliding closure device for discharging molten steel disposed at a vessel for molten steel is impregnated at the time of tapping of molten steel by providing the surface of the sliding plate with a hermetic layer consisting of a specific heat resistant and airtight material. CONSTITUTION: The respective wear members of the sliding closure device which is used for a molten steel discharging device disposed at the large-capacity vessel for the molten steel or the like and comprises the wear members, such as an inflow sleeve 2, bottom plate 9, closure plate 11 and outflow sleeve 13, have outflow passages A1 to A4 for the molten steel, are impregnated with tar or the like as the lubricant and are provided with the hermetic layers consisting of granular Al2 O3 , SiO2 , MgO and materials having excellent refractoriness, such as carbon, hexagonal BN, graphite and clay, in order to prevent the evaporation of the tar at the high temp. of the molten steel. The evaporation of the tar or the like at the high temp. of the molten steel at the time of using the sliding closure device is prevented and the instability of the tapping work of the molten steel by the deterioration in the slidability of the closure plate 1 is prevented.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、摩耗部材が含浸剤、なるべくタール、を含浸
されており又は操業時の温度上昇の際に摩耗の危険にさ
らされた表面に含浸剤を供給する貯蔵部を持っている、
冶金容器にある摺動閉鎖装置用の、板及びスリーブのよ
うな、耐火摩耗部材に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention provides that wear parts are impregnated with an impregnating agent, preferably tar, or have surfaces exposed to the risk of wear during elevated operating temperatures. has a reservoir for supplying impregnating agent,
Refractory wear parts, such as plates and sleeves, for sliding closures in metallurgical vessels.

〔従来の技術〕[Conventional technology]

金属溶湯、特に溶鋼を含有する大容泉の容器の摺動閉鎖
装置において、摩耗部材の摩耗は比較的短い操業時間の
経過後にもう度々困難を引き起こすので、これらの摩耗
部材は頻繁に交換されなければならない。駒湯は原則的
に、作用を受Uる摩耗部材面の細孔に浸透しかつ例えば
互いに押圧される底板と摺動板との間にも達しそれによ
り銅ゲく材料の破壊が著しく早められる。
In sliding closing devices for containers of large springs containing molten metal, especially molten steel, wear of the wear parts often causes difficulties after a relatively short operating time, so that these wear parts must be replaced frequently. Must be. In principle, the hot water penetrates into the pores of the surfaces of the worn parts subjected to the action and also reaches, for example, between the bottom plate and the sliding plate which are pressed together, thereby significantly hastening the destruction of the copper oxide material. .

これを防ぐために、耐火摩耗部材にタールを含浸させる
ことは公知であり、この含浸の結果、開いている細孔は
炭化水素で詰まり、この炭化水素は同時に摺動板及び底
板の動作面の間の潤滑剤としても役立つ。しかしこの場
合は、かなりのタール量が蒸発しかつ摺動板ハウジング
内でキー、冷却通路及び他の機械的部分において凝縮し
かつ摺動閉鎖装置の操作員の作業場所の空気を汚す。
To prevent this, it is known to impregnate refractory wear parts with tar, and as a result of this impregnation, the open pores become clogged with hydrocarbons, which are simultaneously transported between the sliding plate and the working surface of the bottom plate. It also serves as a lubricant. In this case, however, considerable amounts of tar evaporate and condense in the slide plate housing on the keys, cooling passages and other mechanical parts and pollute the air in the working area of the operator of the slide closure.

ドイツ連邦共和国特許出願公告第2830199号明細
書から摺動閉鎖装置用の開穴閉鎖板が公知であり、この
閉鎖板の流通開口に内環が配置されており、この円環と
閉鎖板との間に、絶縁するモルタル層により閉じられた
環状空間が残っており、この環状空間に少なくとも1つ
のタール環が配置されている。各タール環は下面及び側
面を金属板外皮により覆われ、この金属板外皮はタール
蒸気の流れをモルタル層を通してのみ許容しなければな
らず、このモルタル層は閉鎖板の動作面へ開口している
。それによりタール蒸気は環状流として閉鎖板対の動作
面の間に達し、そこにおいてタール蒸気は、浸透する金
属W3潟を防ぐために摩耗部材の開いている細孔の詰ま
りが起こることなしに、分解する。
From German Patent Application No. 28 30 199 a perforated closure plate for a sliding closure device is known, in which an inner ring is arranged in the flow opening of the closure plate, and the connection between this ring and the closure plate is In between, there remains an annular space closed off by an insulating mortar layer, in which at least one tar ring is arranged. Each tar ring is covered on the lower and side surfaces by a metal plate skin which must allow the flow of tar vapor only through the mortar layer, which opens onto the working surface of the closing plate. . The tar vapor thereby reaches in an annular flow between the working surfaces of the closing plate pair, where it decomposes without clogging of the open pores of the wear element to prevent metal W3 lagoon from penetrating. do.

ドイツ連邦共和国特許第3406941号明細書から当
該の摩耗部材は公知であり、これらの摩耗部材は、操業
の際に危険にさらされた摩耗部材に達する炭化水素の貯
蔵部として、含浸剤を封入されている、閉じられた少な
くとも1つの空間を持っており、この場合、細孔を通過
する含浸剤の装入用閉鎖装置を持ち、耐火材料の細孔網
にわたって摩耗部材の危険にさらされた面に通じている
貯蔵部が設けられている。これに゛よって操業時の温度
上昇の際に、特に危険にさらされた面の方向における含
浸剤の永続的な補給が達成されなければならない。外部
へのかなりのタール量の蒸発は、この場合にも回避でき
ない。
German Patent No. 3,406,941 discloses a wear element in question, which is encapsulated with an impregnating agent as a reservoir for hydrocarbons that reach the endangered wear element during operation. the exposed surface of the wear element across the pore network of the refractory material, having at least one closed space, in this case with a closure device for the charging of an impregnating agent passing through the pores; A reservoir is provided which is open to the. In this way, a permanent replenishment of the impregnating agent, especially in the direction of the exposed surfaces, must be achieved in the event of a temperature increase during operation. Evaporation of considerable amounts of tar to the outside cannot be avoided in this case either.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

本発明の課題は、冒頭に挙げた種類の摩耗部材を改良し
て、タールのような含浸剤の(9!弔にも拘らず、スラ
グ浸透の十分な減少、閉鎖及び摺動特性の改善又は耐温
度変化性の改善のために含浸剤蒸気、特にタール蒸気、
の不利な漏れが回避されるようにすることである。
It is an object of the present invention to improve a wear element of the type mentioned at the outset such that the slag penetration is sufficiently reduced, the closure and sliding properties are improved or Impregnant vapor, especially tar vapor, to improve temperature change resistance.
The objective is to ensure that disadvantageous leakage of

〔課題を解決するための手段〕[Means to solve the problem]

この課題は本発明によれば、摩耗部材が、摩耗の危険に
さらされた表面の外部に耐熱性の気密な密封層を持って
いることによって解決される。こうして、含浸剤を持つ
摩耗部材が、金属着湯により危険にさらされない自由表
面にわたって含浸剤蒸気、例えばタール蒸気、を周囲に
放出することが防止される。出湯操業lよ、発生する排
出物質に関して一層きれいになり、摺動閉鎖装置の汚損
は十分に回避される。
This problem is solved according to the invention in that the wear element has a heat-resistant gas-tight sealing layer outside the surface exposed to the risk of wear. In this way, wear parts with impregnating agents are prevented from emitting impregnating agent vapors, for example tar vapors, into the environment over their free surfaces which are not endangered by metal deposition. The tapping operation is cleaner with respect to the emissions generated, and fouling of the sliding closure device is largely avoided.

本発明の好ましい実施例によれば、密封層は硬化可能な
合成m脂又は天然樹脂、例えばエポキシ樹脂、を基材と
して形成されている。このような層は必要な耐温度変化
性を持っておりかつ所望の密封機能を確実に果す。
According to a preferred embodiment of the invention, the sealing layer is formed on the basis of a curable synthetic resin or natural resin, for example an epoxy resin. Such a layer has the necessary temperature resistance and reliably performs the desired sealing function.

本発明思想の拡張において、密封層が、AA203+S
j029MgO又は炭素粒子のような、微粒状の耐火材
料を含んでおり、粒度がほば20pm以下である場合は
有利である。
In an extension of the inventive idea, the sealing layer is AA203+S
It is advantageous if it contains finely divided refractory material, such as j029MgO or carbon particles, with a particle size of approximately 20 pm or less.

更に、密@層は所望の目的を達成するために、六方晶系
の窒化硼素、黒鉛又は粘土、特にカオリン、のような片
状耐火材料を含むことができる。
Furthermore, the dense layer can contain flaky refractory materials such as hexagonal boron nitride, graphite or clay, especially kaolin, to achieve the desired purpose.

密封層が、場合によっては耐熱性の無機着色顔料を封入
された、封ろうを基材として形成されている、すなわち
市販の材料である場合は、比較的費用を節約する解決策
が得られる。
A relatively cost-saving solution is obtained if the sealing layer is formed on the basis of a sealing wax, optionally encapsulating heat-resistant inorganic colored pigments, ie is a commercially available material.

密封層を例えば耐熱性インキを基材として形成すること
もでき、このインキは、閉鎖板の表面にある細孔を閉鎖
し、それにより含浸剤蒸気、例えばタール蒸気、の流出
を防ぐ十分な密封を行なう。
The sealing layer can also be formed, for example, based on a heat-resistant ink, which closes the pores on the surface of the closure plate and thus provides a sufficient seal to prevent the escape of impregnant vapors, e.g. tar vapors. Do this.

更に、2つ又はそれ以上の層、例えば耐火構成要素から
成る層及び封ろう層を、貯湯の作用を受けない摩耗部材
の面に被着することも可能である。この場合、異なる特
性を持つ層組合わせ、例えば良好に密封する表面層を持
つ、良好に付着する下塗り層が考えられる。
Furthermore, it is also possible to apply two or more layers, for example a layer of refractory components and a sealing layer, to the side of the wear element that is not subjected to the action of storing hot water. In this case, layer combinations with different properties are conceivable, for example a well-adhering subbing layer with a well-sealing surface layer.

〔実施例〕〔Example〕

図面に概略的に示された複数の実施例について本発明を
以下に説明する。
The invention will be explained below with reference to several embodiments shown diagrammatically in the drawings.

第1図ないし第4図はすべて、上から下への流通方向1
の溶湯用の流通路Aを持つ摺動閉鎖装置に存在し得るよ
うな耐火摩耗部材を示している。
Figures 1 to 4 all show the flow direction 1 from top to bottom.
2 shows a refractory wear member as may be present in a sliding closure device having a flow path A for molten metal.

第1図によれば、タールを含浸された流入スリーブ2が
モルタル継ぎ手4の介在のもとに穴あきれんが3の中に
配置されており、スリーブ2のこの穴あきれんが3から
下方へ突き出ている部分は、円錐状表面5に耐熱性の気
密な密封層6を持っており、この密封層はスリーブ表面
の自由範囲を閉鎖し、このスリーブ表面は、その他の部
分において穴あきれんが3により被覆されかつ@7にお
いて底板9のキー8により覆われている3層6は操業時
の温度上昇の際にスリーブの開いている細孔に生ずるタ
ール蒸気を外部に対して遮断し、これらの細孔が、内側
端面及び流通開口AIにある、溶湯の作用を受ける面範
囲からの流出のための唯1つの経路である。そこにおい
てタール蒸気は摩耗を減少させるように作用しかつ有害
な排出物質としては消失しない。
According to FIG. 1, an inlet sleeve 2 impregnated with tar is placed in a perforated brick 3 with the intervention of a mortar joint 4, and this perforated brick of the sleeve 2 extends downwardly from 3. The protruding part has a heat-resistant gas-tight sealing layer 6 on the conical surface 5, which sealing layer closes the free area of the sleeve surface, which in other parts is free from perforated bricks. 3 and covered by the key 8 of the bottom plate 9 at @7, the three layers 6 insulate from the outside the tar vapors that form in the open pores of the sleeve when the temperature rises during operation, and these The pores are the only route for the outflow from the area of the surface affected by the molten metal at the inner end face and the flow opening AI. There, the tar vapor acts to reduce wear and does not disappear as harmful emissions.

第2図による、タールを含浸された底板9においても、
同様なM置がとられ、この場合、外気に面した自由表面
範囲は密封層6によって気密にされているので、生じた
タール蒸気は上述の適切な使用のために閉鎖装置開口A
2及び滑り面10へ流れる。
Also in the tar-impregnated base plate 9 according to FIG.
A similar arrangement M is taken, in which case the free surface area facing the outside air is made gas-tight by the sealing layer 6, so that the resulting tar vapor is discharged into the closure device opening A for the appropriate use described above.
2 and the sliding surface 10.

底板9と異なり、滑り面12が底板滑り面10と密封す
るように共同作用する、第3図による、タールを含浸さ
れた摺動板11は、互いに重なる2つの密封層6及び6
aを持っており、これらの密封層は性質が異なっており
かつ特別な操業条件及び必要条件を顧慮することができ
る。
Unlike the base plate 9, the tar-impregnated sliding plate 11 according to FIG.
a, these sealing layers have different properties and can take special operating conditions and requirements into account.

第1図ないし第3図による摩耗部材の代わりに、第4図
による流出スリーブ13はタールを含浸されておらず、
環状タール貯蔵部14を持っており、このタール貯蔵部
から、開いているスリーブ細孔はタールを供給される。
Instead of the wear element according to FIGS. 1 to 3, the outflow sleeve 13 according to FIG. 4 is not impregnated with tar;
It has an annular tar reservoir 14 from which the open sleeve pores are supplied with tar.

この場合、スリーブ13の円錐状表面及び外側端面に被
着された密封層6は、揮発性のタール物質が流通開口A
4においてのみ流出することを強いる。
In this case, the sealing layer 6 applied to the conical surface and outer end face of the sleeve 13 prevents volatile tar substances from flowing through the flow opening A.
Forces outflow only in 4.

この関連において、タールを含浸されかつタール貯蔵部
を持つ摩耗部材も使用できることはもちろんである。
Of course, wear elements impregnated with tar and having a tar reservoir can also be used in this connection.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は流入スリーブの縦断面図、第2図は底板の縦断
面図、第3図は閉鎖板の縦断面図、第4図は流出スリー
ブの縦断面図である。
FIG. 1 is a longitudinal sectional view of the inlet sleeve, FIG. 2 is a longitudinal sectional view of the bottom plate, FIG. 3 is a longitudinal sectional view of the closure plate, and FIG. 4 is a longitudinal sectional view of the outflow sleeve.

Claims (1)

【特許請求の範囲】 1 摩耗部材が含浸剤を含浸されており又は操業時の温
度上昇の際に摩耗の危険にさらされた表面に含浸剤を供
給する貯蔵部を持つている、冶金容器にある摺動閉鎖装
置用の、板及びスリーブのような、耐火摩耗部材におい
て、摩耗部材(2、9、11及び13)が、摩耗の危険
にさらされた表面の外部に少なくとも外気に接している
表面範囲に、耐熱性の気密な密封層(6)を持つている
ことを特徴とする、冶金容器にある摺動閉鎖装置用の耐
火摩耗部材。 2 密封層(6)が硬化可能な合成樹脂又は天然樹脂を
基材として形成されていることを特徴とする、請求項1
に記載の摩耗部材。 3 密封層(6)が、Al_2O_3、SiO_2、M
gO又は炭素粒子のような、微粒状の耐火材料を含んで
いることを特徴とする、請求項1又は2に記載の摩耗部
材。 4 密封層(6)が、六方晶系の窒化硼素、黒鉛又は粘
土のような片状耐火材料を含んでいることを特徴とする
、請求項1ないし3のうち1つに記載の摩耗部材。 5 微粒状材料がほぼ20μm以下の粒度を持つている
ことを特徴とする、請求項3に記載の摩耗部材。 6 密封層(6)が封ろうを基材として形成されている
ことを特徴とする、請求項1に記載の摩耗部材。 7 密封層(6)が耐熱性インキを基材として形成され
ていることを特徴とする、請求項1に記載の摩耗部材。 8 性質の異なる少なくとも2つの層(6及び6a)が
互いに上下に配置されていることを特徴とする、請求項
1ないし7のうち1つに記載の摩耗部材。
[Claims] 1. A metallurgical vessel in which the wear part is impregnated with an impregnating agent or has a reservoir for supplying the impregnating agent to surfaces exposed to the risk of wear during elevated operating temperatures. In fire-resistant wear parts, such as plates and sleeves, for certain sliding closures, the wear parts (2, 9, 11 and 13) are at least externally exposed to the atmosphere exposed to the surface exposed to wear. A fire-resistant wear element for a sliding closure in a metallurgical vessel, characterized in that it has a heat-resistant gas-tight sealing layer (6) in the surface area. 2. Claim 1, characterized in that the sealing layer (6) is formed using a curable synthetic resin or natural resin as a base material.
Wear parts described in . 3 The sealing layer (6) is made of Al_2O_3, SiO_2, M
Wear element according to claim 1 or 2, characterized in that it comprises particulate refractory material, such as gO or carbon particles. 4. Wear element according to one of claims 1 to 3, characterized in that the sealing layer (6) comprises a flaky refractory material, such as hexagonal boron nitride, graphite or clay. 5. Wear element according to claim 3, characterized in that the particulate material has a particle size of approximately 20 μm or less. 6. Wear element according to claim 1, characterized in that the sealing layer (6) is formed using a sealing wax as a base material. 7. The wear member according to claim 1, characterized in that the sealing layer (6) is formed using a heat-resistant ink as a base material. 8. Wear element according to one of claims 1 to 7, characterized in that at least two layers (6 and 6a) of different properties are arranged one above the other.
JP13423890A 1989-07-03 1990-05-25 Refractory abrasion member for sliding stop- per in metallurgical vessel Pending JPH0335868A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19893921794 DE3921794A1 (en) 1989-07-03 1989-07-03 FIRE-RESISTANT WEAR PARTS FOR SLIDING CLOSURES ON METALLURGICAL CASES
DE3921794.9 1989-07-03

Publications (1)

Publication Number Publication Date
JPH0335868A true JPH0335868A (en) 1991-02-15

Family

ID=6384173

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13423890A Pending JPH0335868A (en) 1989-07-03 1990-05-25 Refractory abrasion member for sliding stop- per in metallurgical vessel

Country Status (3)

Country Link
EP (1) EP0406531A3 (en)
JP (1) JPH0335868A (en)
DE (1) DE3921794A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10508384A (en) * 1995-08-30 1998-08-18 ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツング Seal for sensor element of gas sensor
JP2008080384A (en) * 2006-09-28 2008-04-10 Kurosaki Harima Corp Plate-shaped refractory for sliding nozzle

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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DE2830209B1 (en) * 1978-07-10 1979-09-06 Didier Werke Ag Process for repeated soaking of refractory parts of sliding closures that come into contact with molten metal
DE2830199C2 (en) * 1978-07-10 1979-11-08 Martin & Pagenstecher Gmbh, 5000 Koeln Refractory plate for a slide closure on vessels containing molten metal
JPS57152366A (en) * 1980-10-09 1982-09-20 Kurosaki Refract Co Ltd Method for performing prevention of damaging, repairing and other necessary treatments of plate slideway in sliding nozzle device
DE3406941C2 (en) * 1984-02-25 1986-05-07 Didier-Werke Ag, 6200 Wiesbaden Fireproof wear parts for slide locks
CH674813A5 (en) * 1987-07-31 1990-07-31 Stopinc Ag

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10508384A (en) * 1995-08-30 1998-08-18 ローベルト ボツシユ ゲゼルシヤフト ミツト ベシユレンクテル ハフツング Seal for sensor element of gas sensor
JP2008080384A (en) * 2006-09-28 2008-04-10 Kurosaki Harima Corp Plate-shaped refractory for sliding nozzle

Also Published As

Publication number Publication date
EP0406531A2 (en) 1991-01-09
EP0406531A3 (en) 1992-04-22
DE3921794A1 (en) 1991-01-17
DE3921794C2 (en) 1993-07-01

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