JPH03261479A - Manufacture of deodorant - Google Patents
Manufacture of deodorantInfo
- Publication number
- JPH03261479A JPH03261479A JP2062267A JP6226790A JPH03261479A JP H03261479 A JPH03261479 A JP H03261479A JP 2062267 A JP2062267 A JP 2062267A JP 6226790 A JP6226790 A JP 6226790A JP H03261479 A JPH03261479 A JP H03261479A
- Authority
- JP
- Japan
- Prior art keywords
- family
- plant
- matter
- deodorant
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 241000196324 Embryophyta Species 0.000 claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000000605 extraction Methods 0.000 claims abstract description 15
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000284 extract Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000002798 polar solvent Substances 0.000 claims abstract description 5
- 241000218645 Cedrus Species 0.000 claims abstract description 3
- 235000013399 edible fruits Nutrition 0.000 claims abstract 2
- 241000219925 Oenothera Species 0.000 claims description 6
- 235000004496 Oenothera biennis Nutrition 0.000 claims description 6
- 241000208421 Ericaceae Species 0.000 claims description 4
- 241001093501 Rutaceae Species 0.000 claims description 4
- 244000291564 Allium cepa Species 0.000 claims description 3
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 241000207199 Citrus Species 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 235000020971 citrus fruits Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 claims 1
- 230000001877 deodorizing effect Effects 0.000 abstract description 18
- 239000007787 solid Substances 0.000 abstract description 15
- 239000007788 liquid Substances 0.000 abstract description 12
- 241000208422 Rhododendron Species 0.000 abstract description 9
- 239000002904 solvent Substances 0.000 abstract description 8
- 239000000706 filtrate Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 241001672694 Citrus reticulata Species 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 24
- 238000000034 method Methods 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000873 masking effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 240000001548 Camellia japonica Species 0.000 description 2
- 235000018597 common camellia Nutrition 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 241001061264 Astragalus Species 0.000 description 1
- 244000146493 Cryptotaenia japonica Species 0.000 description 1
- 235000004035 Cryptotaenia japonica Nutrition 0.000 description 1
- 244000062789 Rhododendron indicum Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000006533 astragalus Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 210000004233 talus Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、メチルメルカプタン臭気に対して有効な植物
抽出成分より得られる消臭剤の製造方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method for producing a deodorant obtained from plant extract components effective against methyl mercaptan odor.
〈従来の技術〉
今日、生活が豊かになり、人々の生活環境に対する関心
は高まりつつある。においに関しては、悪臭を除去し、
より快適に環境を保とうとする機運がおこってきている
。それに伴い、従来は特に悪臭事象としてとりあげられ
なかったものも悪臭事象として対策が望まれるようにな
りつつあり、悪臭発生源が多様化している。発生する臭
気も、単一物質が悪臭となる場合と、微量成分が多種混
合されて悪臭となる場合とがあり、問題は複雑化する一
方である。<Conventional Technology> Today, people's lives are becoming more affluent, and people's interest in the living environment is increasing. Regarding odors, removes bad odors,
There is a growing momentum to make the environment more comfortable. Along with this, it is becoming desirable to take countermeasures against malodor events that were not previously considered as malodor events, and the sources of malodor generation are diversifying. The problem is becoming more and more complex, as there are cases in which a single substance produces a bad odor, and cases in which a large number of trace components are mixed together to produce a bad odor.
従来、異臭悪臭除去の手法としては、臭気成分を多孔質
表面へ物理吸着させて除去する方法、これらを化学的結
合による吸着や反応により除去する方法、悪臭成分より
も強い芳香をもつものにより、悪臭を感じさせなくする
方法などが知られている。しかしながら、物理吸着によ
る方法では、吸着剤自身が短時間のうちに飽和状態に達
してしまうという欠点があり、化学吸着による方法では
、悪臭物質に対する選択性が大きく、複合臭気よりなる
実際の悪臭事象には適さないこと、化学物質が人体に悪
影響を及ぼす可能性があること、酸性臭気に対してはア
ルカリ処理を要することといった欠点が挙げられる。マ
スキングによる方法は、悪臭事象を覆い隠す芳香成分が
、必ずしも使用者の嗜好に合わなかったり、マスキング
剤の臭気が強ければ、かえって不快の原因になるという
欠点がある。Conventionally, methods for removing foul odors include methods of physically adsorbing odor components onto porous surfaces, methods of removing them through adsorption or reaction through chemical bonds, and methods of removing odor components with a stronger aroma than the foul odor components. There are known methods to eliminate bad odors. However, methods using physical adsorption have the disadvantage that the adsorbent itself reaches a saturated state in a short period of time, while methods using chemical adsorption have a high selectivity for malodorous substances and are used in actual malodor events consisting of complex odors. Disadvantages include the fact that it is not suitable for commercial use, that the chemical substances may have an adverse effect on the human body, and that it requires alkaline treatment to deal with acidic odors. Masking methods have the disadvantage that the aromatic components that mask the malodor event do not necessarily suit the taste of the user, or that if the masking agent has a strong odor, it may even cause discomfort.
〈発明が解決しようとする課題〉
本発明は、上述の問題点を解決すべ〈発明されたもので
あり、消臭成分自身の臭気は弱く、天然物であるため人
体に対しても安全性が高く、安価に入手でき、かつ種々
の有臭物質に対して効果を有し、特に刺激硫黄臭、腐敗
タマネギ様の悪臭を発するメチルメルカプタン対して著
しい効果を有する消臭剤を提供せんとするものである。<Problems to be Solved by the Invention> The present invention was invented to solve the above-mentioned problems.The deodorizing ingredient itself has a weak odor and is a natural product, so it is not safe for the human body. An object of the present invention is to provide a deodorizing agent that can be obtained at a high price and is effective against various odorous substances, and is particularly effective against methyl mercaptan, which emits a pungent sulfur odor and a foul odor similar to rotting onions. It is.
く課題を解決するための手段〉
すなわち、本発明は、アカバナ科植物、詳しくはマツヨ
イグサ属の月見草、マツコイグサ、オオマツヨイグサ、
スギ科植物、詳しくはコウヤマキ属のコウヤマキ、ツツ
ジ科植物、詳しくはツツジ属のヒカゲッッジ、パイカッ
ッジ、レンゲツツジ、アケポノツツジ、ゴヨウツツジ、
ミツバツツジ、コバノミツバツツジ、ウンゼンツツジ、
キリシマ、ヤマツツジ、サツキツツジ、リュウキュウツ
ツジ、オオムラサキ、キシツツジ、ミカン科植物、詳し
くはミカン属のダイダイ、ユズ、キシュウミカン、ラン
シュウミカン、ニッポンタチバナ、スダチ、ナラミカン
、ザポンのうちから選択された少なくとも一種の葉もし
くは花びらの生物または乾燥物を極性溶媒の混合物を用
いて抽出を行い、得られた抽出物を有効成分とする消臭
剤の製造方法であり、望ましくは水とエタノールを1:
3〜6の容量比で混合した溶媒を用いて抽出を施す、好
ましくは、これを濃縮する過程で、溶液中の水の混合比
率を高めておき、遠心分離器にかけて不溶分を除去する
。これらの工程で植物特有の強い臭気の多くはとり除か
れる。さらに溶媒も除去して有効消臭成分を得る消臭剤
の製造方法である。Means for Solving the Problems> That is, the present invention is directed to the use of plants of the family Rusticaceae, specifically evening primrose of the genus Evening primrose, evening primrose, evening primrose,
Plants of the Cedar family, specifically Kouyamaki of the genus Kouyamaki, plants of the Ericaceae family, specifically of the genus Azalea, Hikagege, Paikadge, Astragalus azalea, Akepono azalea, Goyo azalea,
Azalea mitsuba, azalea kobanomitsuba, azalea unzen,
At least one species selected from Kirishima, Yamatsutsuji, Satsukitsutsuji, Ryukyutsutsuji, Omurasaki, Kishitsutsuji, Rutaceae plants, specifically, Citrus genus Daidai, Yuzu, Kishuumikan, Ranshuumikan, Nippon Tachibana, Sudachi, Naramikan, Zapon This is a method for producing a deodorant in which living organisms or dried leaves or petals are extracted using a mixture of polar solvents, and the obtained extract is used as an active ingredient. Preferably, water and ethanol are mixed in 1 part.
Extraction is performed using solvents mixed at a volume ratio of 3 to 6. Preferably, in the process of concentrating the solution, the mixing ratio of water in the solution is increased, and the solution is centrifuged to remove insoluble matter. These steps remove many of the strong odors characteristic of plants. This is a method for producing a deodorant in which an effective deodorizing ingredient is obtained by also removing the solvent.
該消臭物質を得る方法としては、乾物として取り扱う場
合は、上記原料を60℃に設定したオーブン中で水分を
除去、乾燥させた後、ミキサーを用いてこれを粉末化し
、この1gに対しておよそ20−1の割合で上記溶媒を
加え、60℃にて1時間の温抽出ののち、15〜24時
間の室温抽出を施す、ろ過し、残渣にさらに同様の溶媒
を加えて60℃、1時間の温抽出ののちに分離ろ過し、
ろ液を先に分離したろ液と合わせてロータリーエバポレ
ーター等により濃縮操作を行う、濃縮液を遠心分離器に
かけて固形分と溶解物とを分離ののち、溶解物のみをメ
スフラスコにて、水を用いて一定濃度に希釈し、消臭液
が得られる。さらにこの消臭液を減圧下において乾燥さ
せて消臭固形物を得、これを実際の消臭に供する。To obtain the deodorizing substance, when handling it as a dry product, remove moisture from the above raw material in an oven set at 60°C, dry it, and then powder it using a mixer. Add the above solvent at a ratio of approximately 20-1, perform hot extraction at 60°C for 1 hour, perform room temperature extraction for 15 to 24 hours, filter, add the same solvent to the residue and incubate at 60°C for 1 hour. After hot extraction for several hours, it is separated and filtered.
The filtrate is combined with the previously separated filtrate and concentrated using a rotary evaporator, etc. After the concentrated liquid is centrifuged to separate solids and dissolved matter, only the dissolved matter is placed in a volumetric flask and water is added. A deodorizing liquid can be obtained by diluting it to a certain concentration. Further, this deodorizing liquid is dried under reduced pressure to obtain a deodorizing solid, which is used for actual deodorizing.
生物として取り扱う場合は、乾物1g相当の生物に対し
エタノール20−1を加え、ホモジナイザーで磨砕のの
ち、同様の抽出処理を施して消臭固形物を得る。When handling as a living organism, add 20-1 ethanol to the living organism equivalent to 1 g of dry matter, grind with a homogenizer, and perform the same extraction process to obtain a deodorized solid.
〈作用〉
この抽出固形物は、植物から容易に得られる安全性の高
いものであり、かつ種々の悪臭の除去に効果を有し、と
くに刺激硫黄臭、腐敗タマネギ臭を発するメチルメルカ
プタンに対してその効果が優れている。また、固形物自
身の臭気は極めて少ないため、従来のマスキング剤の様
に不快感をもたらすことがない、原料も安価である。<Effect> This extracted solid is highly safe and easily obtained from plants, and is effective in removing various bad odors, especially against methyl mercaptan, which gives off a pungent sulfur odor and rotting onion odor. The effect is excellent. Furthermore, since the solid substance itself has very little odor, it does not cause unpleasant sensations like conventional masking agents, and the raw materials are inexpensive.
臭気作用機構としては、植物抽出成分の多成分混成系中
のフラボノイド類、ポリフェノール類、アミノ酸類、ク
ロロフィル等との中和、分解、酸化還元、錯形成、包接
作用等が複合的に行なわれると推定されている。以下に
実施例を挙げてさらに詳しく本発明を説明する。The mechanism of odor action is a complex combination of neutralization, decomposition, redox, complex formation, and clathration with flavonoids, polyphenols, amino acids, chlorophyll, etc. in the multi-component hybrid system of plant extract components. It is estimated that The present invention will be explained in more detail with reference to Examples below.
実施例1
月見草の花の乾燥物5g粉末と、水;エタノール=1:
4の容量比である混合溶媒100m1とを三角フラスコ
に入れ、60℃で1時間湯浴ののち、室温にて15時間
の抽出を行った。吸引ろ過し、抽出液を分離して、残渣
には再び1001の同じ溶媒を加えて60℃で1時間、
再抽出を行った。Example 1 5g powder of dried evening primrose flowers, water; ethanol = 1:
4 and 100 ml of a mixed solvent with a volume ratio of 1.5 to 1.4 was placed in an Erlenmeyer flask, and after a hot water bath at 60° C. for 1 hour, extraction was performed at room temperature for 15 hours. After suction filtration and separating the extract, the same solvent of 1001 was added to the residue again and the mixture was heated at 60°C for 1 hour.
Re-extraction was performed.
吸引ろ過して、ろ液を先の抽出液とを合わせて、−a縮
ののち、遠心分離器にかけて固形分を分離した。液体分
をメスフラスコにて100m1に水で希釈し、消臭液と
した。このうち5mlを減圧乾燥し、固体消臭剤約60
−gを得た。After suction filtration, the filtrate was combined with the previous extract, subjected to -a condensation, and then centrifuged to separate the solid content. The liquid portion was diluted with water to 100 ml in a volumetric flask to obtain a deodorizing liquid. Dry 5 ml of this under reduced pressure to make a solid deodorant of about 60 ml.
-g was obtained.
実施例2
コウヤマキの乾燥葉物粉末7gと、水:エタノール−2
ニアの容量比である混合溶媒1501とを三角フラスコ
に入れ、実施例1と同様の操作を行い、100m1の消
臭液を得た。このうち5■l@減圧下にて乾燥し、固体
消臭剤約751gを得た。Example 2 7 g of dried leaf powder of Kouyamaki and water: ethanol-2
A mixed solvent 1501, which is a volume ratio of Nia, was placed in an Erlenmeyer flask, and the same operation as in Example 1 was performed to obtain 100 ml of deodorizing liquid. Of this, 5 liters were dried under reduced pressure to obtain about 751 g of solid deodorant.
実施例3
サツキツツジの花の乾燥物7gと水:エタノール=2:
9の容量比である混合溶媒150m1とを用い、実施例
1と同様の操作を行い1001の消臭液を得た。このう
ち51を減圧下にて乾燥し、固体消臭荊約150−gを
得た。Example 3 7 g of dried flowers of Satsuki azalea and water: Ethanol = 2:
The same operation as in Example 1 was performed using 150 ml of a mixed solvent having a volume ratio of 1,001 to 1,001 to obtain a deodorizing liquid of 1,001. Of these, 51 pieces were dried under reduced pressure to obtain about 150 g of solid deodorizing seeds.
実施例4
夏ミカンの乾燥葉7gと、水:エタノール=1:5の容
量比である混合溶媒150m1とを用い、実施例1と同
様の操作を行い100m1 の消臭液を得た。このうち
5−1を減圧下にて乾燥し、固体消臭剤約10(1+g
を得た。Example 4 Using 7 g of dried summer mandarin leaves and 150 ml of a mixed solvent having a volume ratio of water:ethanol=1:5, the same operation as in Example 1 was carried out to obtain 100 ml of deodorizing liquid. Of these, 5-1 was dried under reduced pressure, and approximately 10 (1+g) of solid deodorant was obtained.
I got it.
試験例
実施例1〜4で得た消臭液について、メチルメルカプタ
ンの消臭効果を測定した。Test Example The deodorizing effect of methyl mercaptan was measured for the deodorant liquids obtained in Examples 1 to 4.
・試験方法
消臭液5−1に相当する固体消臭剤とメチルメルカプタ
ンガス約1600μgを16f)+1容量のガラスビン
に入れて密栓した。ブランクとして固体消臭剤を入れな
いサンプルも用意した。これを20℃に設定した恒温槽
内で保存し、処理2.5時間後、各ビンに残存するガス
量を、ガスクロマトグラフを用いて測定し、消臭剤を入
れたビン中のガス減量(a)と、ブランクのビン中のガ
ス減量、すなわち、ガラス器壁に吸着された量(b)
とを求め、a−bより消臭剤自身により消臭されたガ
スの量を夏山した。-Test Method A solid deodorant corresponding to Deodorant Liquid 5-1 and about 1600 μg of methyl mercaptan gas were placed in a 16f)+1 capacity glass bottle and sealed. A sample without solid deodorant was also prepared as a blank. This was stored in a constant temperature bath set at 20°C, and after 2.5 hours of treatment, the amount of gas remaining in each bottle was measured using a gas chromatograph. a) and the gas loss in the blank bottle, i.e. the amount adsorbed on the glassware wall (b)
The amount of gas deodorized by the deodorant itself was calculated from a-b.
この計算結果から乾燥物1gあたりに換算した消臭剤の
ガス吸着量を求め第1図に示した。比較のため、同様の
抽出方法により得た他の植物成分のガス吸着量も載せた
。From this calculation result, the amount of gas adsorption of the deodorant per 1 g of dry matter was determined and shown in FIG. For comparison, the gas adsorption amounts of other plant components obtained using the same extraction method are also listed.
これまで植物成分を利用した消臭剤として効果が高いと
言われるツバキ科植物、その他同様の抽出方法により試
験した他の植物の吸着ガス量が430 μg/乾物1g
以下であるのに対し、本発明に用いた植物のそれはいず
れも450 μgを越え、より優れていることがわかる
。The adsorbed gas amount of Camellia family plants, which are said to be highly effective as deodorizers using plant ingredients, and other plants tested using the same extraction method was 430 μg/1g of dry matter.
In contrast, all of the plants used in the present invention exceeded 450 μg, which indicates that they are even better.
〈発明の効果〉
以上のように、本発明により得られる消臭剤は、原料の
入手が安価でかつ容易であり、製法も簡単なうえ、その
効果も大きい。消臭剤自身が極めて低臭であるため、不
快感を与えることなく様々な分野でその効果を発揮しう
るちのである。また、これまで植物成分を利用した消臭
剤、例えば、ツバキ科植物からの抽出物を利用したもの
に関する発明があったが、それらの効果を上まわること
が図中よりわかり、本発明は極めて効果の高い有効かつ
実用的な発明であるといえる。<Effects of the Invention> As described above, the deodorant obtained by the present invention has raw materials that are inexpensive and easy to obtain, a manufacturing method that is simple, and is highly effective. Since the deodorant itself has an extremely low odor, it can be effective in a variety of fields without causing discomfort. In addition, although there have been inventions related to deodorants using plant ingredients, for example, those using extracts from plants of the Camellia family, it can be seen from the figure that the effects are superior to those, and the present invention is extremely effective. It can be said that this is a highly effective and practical invention.
第1図は、乾燥物1gあたりに吸着される臭気ガスの量
を棒グラフで示したグラフ図である。
特 許 出 願 人
凸版印刷株式会社
代表者 鈴木和夫FIG. 1 is a bar graph showing the amount of odor gas adsorbed per gram of dry matter. Patent application: Kazuo Suzuki, Representative of Toppan Printing Co., Ltd.
Claims (4)
うちから選択された少なくとも一種の葉、花びらもしく
は果実の生物または乾燥物を、極性溶媒の混合物を用い
て抽出を行い、得られた抽出物を有効成分とする、刺激
硫黄臭もしくは腐敗タマネギ様の悪臭を発するメチルメ
ルカプタンに対して有効である消臭剤の製造方法。(1) At least one leaf, petal, or fruit organism or dried material selected from plants of the family Rubicaceae, Cedaraceae, Ericaceae, and Rutaceae is extracted using a mixture of polar solvents. A method for producing a deodorant containing an extract as an active ingredient, which is effective against methyl mercaptan, which emits a pungent sulfur odor or a foul odor similar to rotting onions.
コウヤマキ属、ツツジ科植物がツツジ属、ミカン科植物
がミカン属である請求項(1)記載の消臭剤の製造方法
。(2) The method for producing a deodorant according to claim (1), wherein the plant of the family Rutaceae is a plant of the genus Evening Primrose, the plant of the family Cedar family is a plant of the genus Koyama, the plant of the family Ericaceae is a plant of the genus Ericaceae, and the plant of the family Rutaceae is a plant of the genus Citrus.
6の容量比である請求項(1)記載の消臭剤の製造方法
。(3) The mixture of polar solvents is water:ethanol=1:3~
The method for producing a deodorant according to claim 1, wherein the volume ratio is 6.
工程を付加する請求項(1)記載の消臭剤の製造方法。(4) The method for producing a deodorant according to claim (1), further comprising adding a post-step of removing insoluble matter using a centrifuge after extraction.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2062267A JPH03261479A (en) | 1990-03-13 | 1990-03-13 | Manufacture of deodorant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2062267A JPH03261479A (en) | 1990-03-13 | 1990-03-13 | Manufacture of deodorant |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03261479A true JPH03261479A (en) | 1991-11-21 |
Family
ID=13195205
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2062267A Pending JPH03261479A (en) | 1990-03-13 | 1990-03-13 | Manufacture of deodorant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03261479A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010132634A (en) * | 2008-10-30 | 2010-06-17 | Lion Corp | Deodorant |
WO2018150992A1 (en) * | 2017-02-15 | 2018-08-23 | 住友精化株式会社 | Water-absorbing resin composition, absorbent body, and absorbent article |
-
1990
- 1990-03-13 JP JP2062267A patent/JPH03261479A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010132634A (en) * | 2008-10-30 | 2010-06-17 | Lion Corp | Deodorant |
WO2018150992A1 (en) * | 2017-02-15 | 2018-08-23 | 住友精化株式会社 | Water-absorbing resin composition, absorbent body, and absorbent article |
JPWO2018150992A1 (en) * | 2017-02-15 | 2019-12-12 | 住友精化株式会社 | Water-absorbent resin composition, absorbent body, and absorbent article |
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