JPH02214800A - Solvent composition - Google Patents
Solvent compositionInfo
- Publication number
- JPH02214800A JPH02214800A JP3365189A JP3365189A JPH02214800A JP H02214800 A JPH02214800 A JP H02214800A JP 3365189 A JP3365189 A JP 3365189A JP 3365189 A JP3365189 A JP 3365189A JP H02214800 A JPH02214800 A JP H02214800A
- Authority
- JP
- Japan
- Prior art keywords
- hcfc
- boiling point
- solvent composition
- composition
- isopentane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000002904 solvent Substances 0.000 title claims abstract description 15
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 20
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000009835 boiling Methods 0.000 abstract description 13
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 abstract description 11
- 239000004033 plastic Substances 0.000 abstract description 7
- 229920003023 plastic Polymers 0.000 abstract description 7
- 229920001971 elastomer Polymers 0.000 abstract description 5
- 230000001747 exhibiting effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 6
- 239000012046 mixed solvent Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- NDKGUMMLYBINOC-UHFFFAOYSA-N 1,2-dichloro-1-fluoroethane Chemical compound FC(Cl)CCl NDKGUMMLYBINOC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/5068—Mixtures of halogenated and non-halogenated solvents
- C11D7/5072—Mixtures of only hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning Or Drying Semiconductors (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は共沸乃至それに近い挙動を示すフッ素系溶剤組
成物に関するものであり、プリント基板製造時における
フラックス洗浄等に好適に使用される。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a fluorine-based solvent composition exhibiting azeotropic or similar behavior, and is suitably used for flux cleaning, etc. during the manufacture of printed circuit boards.
［従来の技術］
フッ素系溶剤は不燃性、低毒性、低腐食性等の利点があ
るために産業界で賞用されて来たが、オゾン層を破壊す
る懸念があるとの問題が鵡こり、従来広く使用されてい
たフロン−１１、フロン−１２、フロン−１１３は使用
が規制されることになった。[Prior Art] Fluorinated solvents have been widely used in industry due to their advantages such as nonflammability, low toxicity, and low corrosivity, but there is often a problem that they may destroy the ozone layer. The use of Freon-11, Freon-12, and Freon-113, which had been widely used in the past, has been restricted.
そこでオゾン層を破壊する恐れのないフッ素系溶剤とし
て１．１−シクロロ−１−フルオロエタンが注目される
ようになった。Therefore, 1,1-cyclo-1-fluoroethane has attracted attention as a fluorine-based solvent that does not have the risk of destroying the ozone layer.
１．１−シクロロ−１−フルオロエタンは下記の構造式
％式％
を有し、フロン−１４１ｂ或はＨＣＦＣ−１４ｌｂと呼
ばれ、溶剤として適当な沸点を有することから、フロン
１１３の代替品として期待されているが、油脂溶解力が
強くプラスチックスに対する影響が大きいため使用範囲
が限定される懸念がある。1.1-Cyclochloro-1-fluoroethane has the following structural formula (%) and is called Freon-141b or HCFC-14lb, and has a boiling point suitable for use as a solvent, so it is used as a substitute for Freon-113. Although it is promising, there are concerns that its range of use will be limited because it has a strong ability to dissolve fats and oils and has a large effect on plastics.
そこで他の溶剤と混合してプラスチックスやゴム等に対
する作用を緩和することが考えられる。Therefore, it may be possible to mix it with other solvents to reduce its effect on plastics, rubber, etc.
その場合、混合溶剤が共沸乃至それに近い挙動を示す組
成物となっていれば、沸点が低下すると共に、蒸発して
も成分変化がないので溶解力に変化がなく、また、溶剤
の回収・−再使用に好都合である。In that case, if the mixed solvent is a composition that exhibits azeotropic or similar behavior, the boiling point will be lowered and the components will not change even when evaporated, so there will be no change in the dissolving power. - Convenient for reuse.
［発明が解決しようとする課題］
本発明はそのような共沸またはそれに近い挙動を示す組
成物で、しかもプラスチックスやゴム等に対する作用が
緩和された溶剤組成物を提供することを目的とする。[Problems to be Solved by the Invention] An object of the present invention is to provide a solvent composition that exhibits such azeotropic or similar behavior, and that has a reduced effect on plastics, rubber, etc. .
［課題を解決するための手段］
本発明の溶剤組成物は３０〜６０重量％の１゜１−シク
ロロ−１−フルオロエタン及び７０〜４０重量％のイソ
ペンタンよりなる。[Means for Solving the Problems] The solvent composition of the present invention consists of 30-60% by weight of 1°1-cyclo-1-fluoroethane and 70-40% by weight of isopentane.
ｌ−シクロロ−１−フルオロエタン（以下ＨＣＦＣ−１
４ｌ ｂと略して記す）の沸点は３２℃前後、イソペン
タンの沸点は３０℃前後であるが、上記範囲の組成物の
沸点はインペンタンの沸点より約２℃低下することが認
められ、特に約４５重量％のＨＣＦＣ−１４１ｂと約５
５重量％のイソペンタンよりなる溶剤組成物の沸点は約
２６．７℃まで低下し、蒸留液及び残液の組成が同一で
。l-cyclo-1-fluoroethane (hereinafter referred to as HCFC-1)
The boiling point of isopentane (abbreviated as 4l b) is around 32°C, and the boiling point of isopentane is around 30°C, but it is recognized that the boiling point of the composition in the above range is about 2°C lower than the boiling point of impentane. 45% by weight of HCFC-141b and approx.
The boiling point of a solvent composition consisting of 5% by weight isopentane was reduced to about 26.7°C, with the composition of the distillate and bottom liquid being the same.
明らかに共沸組成物となっている。It is clearly an azeotropic composition.
また上記の組成物は、プラスチックスやゴムに対する作
用がＨＣＦＣ−１４１ｂ単独の場合よりも緩和されてい
る。Furthermore, the above composition has a milder effect on plastics and rubber than HCFC-141b alone.
以下実施例により本発明の詳細な説明する。The present invention will be explained in detail below with reference to Examples.
［実施例１］
ＨＣＦＣ−１４１ｂ （デュポン社製）：１５０ｇ及び
インペンクン（和光純薬■製：試薬特級）：１５０ｇの
混合物３００ｇを蒸溜フラスコに入れ、理論段数３０段
の精溜塔を用９いて蒸溜を行った。その結果２６．７℃
で共沸を呈し、その留分をガスクロマトグラフィーによ
り分析したところ組成はＨＣＦＣ−１４１ｂ＋４４．８
重量％、イソペンタン：５５−２重量％であった。[Example 1] 300 g of a mixture of 150 g of HCFC-141b (manufactured by DuPont) and 150 g of Inpenkun (manufactured by Wako Pure Chemical Industries, Ltd.: special grade reagent) was placed in a distillation flask, and the mixture was heated using a rectification column with 30 theoretical plates. Distilled. The result was 26.7℃
When the fraction was analyzed by gas chromatography, the composition was HCFC-141b+44.8.
% by weight, isopentane: 55-2% by weight.
ＨＣＦＣ−１４ｌ ｂとインペンタンとの混合溶剤組成
物の気液平衡曲線を第１図に示す。横軸は混合組成物中
のＨＣ，ＦＣ−１４１ｂの割合（重量％）、縦軸は混合
溶剤の沸点（”Ｃ）を表す。The vapor-liquid equilibrium curve of a mixed solvent composition of HCFC-14lb and impentane is shown in FIG. The horizontal axis represents the proportion (wt%) of HC and FC-141b in the mixed composition, and the vertical axis represents the boiling point ("C") of the mixed solvent.
第１図かられかるように、この系では気相線と液相線が
接近している部分が幅広いため、ＨＣＦＣ−１４１ｂが
３０〜６０重量％の範囲（矢印で示す）であれば共沸に
近い挙動を示し、液相洗浄及び気相洗浄を行う二槽式洗
浄機においても、そう大きな組成の崩れなしに工業的に
使用できる。As can be seen from Figure 1, in this system, the region where the gas phase line and liquidus line are close is wide, so if HCFC-141b is in the range of 30 to 60% by weight (indicated by the arrow), the azeotropic It can be used industrially without major compositional deterioration even in a two-tank cleaning machine that performs liquid phase cleaning and gas phase cleaning.
なお、アセトン、１．１−ジクロロエタン、ニトロメタ
ン、ｔｒａｎｓ−１，２−ジクロルエチレン、フロン１
１３、ｌ、１．１−トリクロロエタン、ｎ−ヘキサン、
ｌ−クロロプロパン、又はフロン１１２とＨＣＦＣ−１
４１ｂの混合組成物について沸点を測定したが、いずれ
も共沸現象を示さなかった。In addition, acetone, 1,1-dichloroethane, nitromethane, trans-1,2-dichloroethylene, Freon 1
13, l, 1,1-trichloroethane, n-hexane,
l-Chloropropane, or Freon 112 and HCFC-1
The boiling points of the mixed compositions of No. 41b were measured, but none showed an azeotropic phenomenon.
即ちＨＣＦＣ−１４１ｂとの共沸組成物を作るのはイソ
ペンタンに特有の現象である。That is, forming an azeotropic composition with HCFC-141b is a phenomenon unique to isopentane.
［実施例２］
ＨＣＦＣ−１４１ｂ：４５重量％及びインペンタン：５
５重量％よりなる組成物（本発明）、ＨＣＦＣ−１４１
ｂ単独（比較例）、イソペンタン単独（比較例）につい
て、プラスチックに対する影響を調べた。[Example 2] HCFC-141b: 45% by weight and impentane: 5
Composition consisting of 5% by weight (invention), HCFC-141
The effects on plastics were investigated for b alone (comparative example) and isopentane alone (comparative example).
１００ｍＪ２容量の耐圧ガラス瓶に上記各種溶剤を１０
０ｇづつ入れ、直鎖ポリエチレン、ボリブロヒレン、Ｔ
ＦＥ樹脂及びポリビニルアルコール樹脂の試験片（ｌ
ＯＸ５０Ｘ４ｍｍ）を入れて温度５４℃の恒温室に１０
０時間放置後取り出し、寸法変化を測定した。結果を第
１表に示す。10% of the above various solvents in a pressure-resistant glass bottle with a capacity of 100mJ2
Add 0g each, linear polyethylene, polybrohylene, T
Test pieces of FE resin and polyvinyl alcohol resin (l
OX50
After being left for 0 hours, it was taken out and dimensional changes were measured. The results are shown in Table 1.
第１表
第１表から明らかなように、ＨＣＦＣ−１４１ｂ：４５
重量％及びインペンタン：５５重量％よりなる本発明の
溶剤組成物は、ＨＣＦＣ−１４ｌｂ単独の場合に比べて
樹脂の溶・解性が弱められている。As is clear from Table 1, HCFC-141b:45
The solvent composition of the present invention, which is composed of 55% by weight of impentane, has weaker resin solubility and solubility than HCFC-14lb alone.
［実施例３］
１００ｍＩ２容量の耐圧ガラス瓶に、実施例１で用いた
各種溶剤を１００ｇづつ入れ、ウレタンゴム、パイトン
■、ニトリルゴム及びシリコーンゴムの試験片（１０Ｘ
５０Ｘ４ｍｍ）を入れて温度５４℃の恒温室に５分間放
置後取り出して寸法変化を測定した。結果を第２表に示
す。[Example 3] Put 100 g each of the various solvents used in Example 1 into a pressure-resistant glass bottle with a capacity of 100 mI2, and test pieces (10X
50 x 4 mm) was placed in a thermostatic chamber at a temperature of 54° C. for 5 minutes, and then taken out and dimensional changes were measured. The results are shown in Table 2.
［発明の効果］
■共沸又はそれに近い挙動を示すので、液管理ｈ５容易
である。[Effects of the Invention] (1) Since it shows azeotropic or similar behavior, liquid management h5 is easy.
■プラスチックやエラストマーに対する作用力５、ＨＣ
ＦＣ−１４ｌ ｂ単独の場合よりも小さｌ／’。■Action force on plastics and elastomers 5, HC
FC-14l l/' smaller than that of b alone.
第１図はＨＣＦＣニー１４１ｂ （デュポン社製）とイ
ソペンクン（和光純薬味製：試薬特級）との混合溶剤組
成物の気液平衡曲線で、横軸は混合組成物中のＨＣＦＣ
−１４ｌ ｂの割合（重量％）、縦軸は混合溶剤の沸点
（’Ｃ）を表す。Figure 1 shows the vapor-liquid equilibrium curve of a mixed solvent composition of HCFC Nee 141b (manufactured by DuPont) and Isopenkune (manufactured by Wako Junyami: Reagent Special Grade), and the horizontal axis is the HCFC in the mixed composition.
-14lb ratio (wt%); the vertical axis represents the boiling point ('C) of the mixed solvent.
Claims (1)
タン及び７０〜４０重量％のイソペンタンよりなる溶剤
組成物。A solvent composition comprising 30-60% by weight of 1,1-cyclo-1-fluoroethane and 70-40% by weight of isopentane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3365189A JPH02214800A (en) | 1989-02-15 | 1989-02-15 | Solvent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3365189A JPH02214800A (en) | 1989-02-15 | 1989-02-15 | Solvent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02214800A true JPH02214800A (en) | 1990-08-27 |
Family
ID=12392351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3365189A Pending JPH02214800A (en) | 1989-02-15 | 1989-02-15 | Solvent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02214800A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5085798A (en) * | 1990-09-11 | 1992-02-04 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, cyclopentane and optionally an alkanol |
| US5106527A (en) * | 1990-04-06 | 1992-04-21 | Mobay Corporation | Azeotropes of 2-methylbutane and 1,1-dichloro-1-fluorethane and the use thereof in the production of rigid foams |
| FR2708935A1 (en) * | 1993-06-03 | 1995-02-17 | Lenglen Jean Luc | Liquid cleaning product, in particular for manual cleaning operations at room temperature |
| US5419849A (en) * | 1993-06-18 | 1995-05-30 | Fields; Paul B. | Cleaning fluids |
| US5454969A (en) * | 1993-06-18 | 1995-10-03 | Fields; Paul B. | Cleaning fluids |
| FR2741354A1 (en) * | 1995-11-16 | 1997-05-23 | Atochem Elf Sa | New composition comprising 1,1-di-chloro-1-fluoroethane |
-
1989
- 1989-02-15 JP JP3365189A patent/JPH02214800A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5106527A (en) * | 1990-04-06 | 1992-04-21 | Mobay Corporation | Azeotropes of 2-methylbutane and 1,1-dichloro-1-fluorethane and the use thereof in the production of rigid foams |
| US5085798A (en) * | 1990-09-11 | 1992-02-04 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, cyclopentane and optionally an alkanol |
| FR2708935A1 (en) * | 1993-06-03 | 1995-02-17 | Lenglen Jean Luc | Liquid cleaning product, in particular for manual cleaning operations at room temperature |
| US5419849A (en) * | 1993-06-18 | 1995-05-30 | Fields; Paul B. | Cleaning fluids |
| US5454969A (en) * | 1993-06-18 | 1995-10-03 | Fields; Paul B. | Cleaning fluids |
| FR2741354A1 (en) * | 1995-11-16 | 1997-05-23 | Atochem Elf Sa | New composition comprising 1,1-di-chloro-1-fluoroethane |
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