JPH02199168A - Transparent container for oil - Google Patents
Transparent container for oilInfo
- Publication number
- JPH02199168A JPH02199168A JP1018217A JP1821789A JPH02199168A JP H02199168 A JPH02199168 A JP H02199168A JP 1018217 A JP1018217 A JP 1018217A JP 1821789 A JP1821789 A JP 1821789A JP H02199168 A JPH02199168 A JP H02199168A
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- component
- oil
- aliphatic
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 18
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004952 Polyamide Substances 0.000 claims abstract description 17
- 229920003231 aliphatic polyamide Polymers 0.000 claims abstract description 17
- 229920002647 polyamide Polymers 0.000 claims abstract description 17
- 239000003365 glass fiber Substances 0.000 claims abstract description 13
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 7
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 13
- -1 aliphatic diamine Chemical class 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000011342 resin composition Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 abstract description 13
- 239000011347 resin Substances 0.000 abstract description 13
- 229920006012 semi-aromatic polyamide Polymers 0.000 abstract description 12
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract description 11
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract description 10
- 150000004985 diamines Chemical class 0.000 abstract description 4
- 238000000465 moulding Methods 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000010720 hydraulic oil Substances 0.000 description 3
- 150000003951 lactams Chemical class 0.000 description 3
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- PWSKHLMYTZNYKO-UHFFFAOYSA-N heptane-1,7-diamine Chemical compound NCCCCCCCN PWSKHLMYTZNYKO-UHFFFAOYSA-N 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 2
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- DPQHRXRAZHNGRU-UHFFFAOYSA-N 2,4,4-trimethylhexane-1,6-diamine Chemical compound NCC(C)CC(C)(C)CCN DPQHRXRAZHNGRU-UHFFFAOYSA-N 0.000 description 1
- JZUMVFMLJGSMRF-UHFFFAOYSA-N 2-Methyladipic acid Chemical compound OC(=O)C(C)CCCC(O)=O JZUMVFMLJGSMRF-UHFFFAOYSA-N 0.000 description 1
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
- BUGIFNPYQVKODR-UHFFFAOYSA-N 2-methylhexane-1,6-diamine Chemical compound NCC(C)CCCCN BUGIFNPYQVKODR-UHFFFAOYSA-N 0.000 description 1
- LTZQJVGOFCCDQA-UHFFFAOYSA-N 3-methylhexane-1,6-diamine Chemical compound NCCC(C)CCCN LTZQJVGOFCCDQA-UHFFFAOYSA-N 0.000 description 1
- GAYWCADKXYCKCG-UHFFFAOYSA-N 5-pyridin-3-yl-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1NC(=S)N=C1C1=CC=CN=C1 GAYWCADKXYCKCG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920000577 Nylon 6/66 Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 229920003233 aromatic nylon Polymers 0.000 description 1
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- SYEOWUNSTUDKGM-UHFFFAOYSA-N beta-methyladipic acid Natural products OC(=O)CC(C)CCC(O)=O SYEOWUNSTUDKGM-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- KLNPWTHGTVSSEU-UHFFFAOYSA-N undecane-1,11-diamine Chemical compound NCCCCCCCCCCCN KLNPWTHGTVSSEU-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Landscapes
- Transmission Of Braking Force In Braking Systems (AREA)
- Power Steering Mechanism (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、オイル用透明容器に関する。詳しくは内容物
たるオイル類の残存量が外部から確認可能な、自動車油
圧系オイル容器、具体的には１、自動車等のブレーキ液
リザーバータンク、パワーステアリングオイルリザーバ
ータンク、トランスミツシランオイルリザーバータンク
、ディファレンシャルギヤオイルリザーバータンクなど
として用いて好適なオイル用透明容器に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a transparent container for oil. In detail, automotive hydraulic oil containers whose remaining amount of oil can be confirmed from the outside, specifically: 1. Brake fluid reservoir tank for automobiles, power steering oil reservoir tank, Transmitsulin oil reservoir tank, The present invention relates to a transparent oil container suitable for use as a differential gear oil reservoir tank, etc.
ポリアミド６やポリアミド６−６は、耐油性と機械的特
性、及び熱的特性に優れるため、従来より自動車のオイ
ルリザーバータンク類を形成する材料として用いられて
いる。Polyamide 6 and polyamide 6-6 have excellent oil resistance, mechanical properties, and thermal properties, and have thus far been used as materials for forming oil reservoir tanks for automobiles.
ところが、かかるポリアミド樹脂製の中空容器はもとも
と半透明もしくは白色不透明であり、内容物（オイル）
の量を外から目視で確認するのに不都合であった。However, such hollow containers made of polyamide resin are originally translucent or white and opaque, and the contents (oil)
It was inconvenient to visually check the amount from outside.
自動車油圧系のオイルは、容器中において、所定の上限
量を越えたり、下限量より減少したりすると、油圧系の
円滑な作動を損ない、ひいては事故を誘因する危険があ
るため、オイル量を外部から目視にて容易に確認出来る
ことが望まれていた。If the amount of oil in an automobile hydraulic system exceeds the upper limit or decreases below the lower limit in a container, it may impair the smooth operation of the hydraulic system and may even cause an accident. It was desired that the information could be easily confirmed visually.
一方、ナイロン樹脂の透明化のために、非晶質の芳香族
ナイロン樹脂が開発されているが、脂肪族ナイロンに比
べて耐薬品が大きく低下するために、オイル部品への適
用には限界があり、オイルリザーバータンクへの使用は
実質的に不可能であった。On the other hand, amorphous aromatic nylon resins have been developed to make nylon resins more transparent, but their chemical resistance is significantly lower than that of aliphatic nylons, so there is a limit to their application to oil parts. Therefore, it was virtually impossible to use it for oil reservoir tanks.
本発明者らは、上記問題を解決すべく鋭意研究を重ねた
結果、脂肪族ナイロン樹脂と、特定の部分芳香族ナイロ
ン樹脂、及び、ガラス繊維とを特定の配合比にて配合し
た組成物を使用すれば、耐薬品性に優れ、内容物を外か
ら確認するに充分な透明性を持った中空容器が得られる
ことを見出し、本発明に到達したものである。As a result of extensive research to solve the above problems, the present inventors have developed a composition containing an aliphatic nylon resin, a specific partially aromatic nylon resin, and glass fiber in a specific blending ratio. The present invention was achieved based on the discovery that a hollow container with excellent chemical resistance and sufficient transparency to confirm the contents from the outside can be obtained by using the method.
すなわち、本発明は内容物の量が外部から目視で確認出
来るほど透明な、自動車油圧系オイル容器を提供するこ
とを目的とするものであり、その要旨とするところは、
ポリアミド６、ポリアミド６−６、及びポリアミド６・
６−６のうちの少なくとも１種からなる脂肪族ポリアミ
ド（Ａ成分）と、脂肪族ジアミンとイソフタル酸及び／
又はテレフタル酸からなる部分芳香族ポリアミド１００
〜８５重量％、脂肪族ポリアミド０〜１５重量％からな
るポリアミド（Ｂ成分）からなり、Ａ成分とＢ成分との
混合重量比が、
（Ａ成分）：（Ｂ成分）＝９５：５〜４０：６０からな
るポリアミド組成物１００重量部と、ガラス繊維５〜２
５重量部とからなるポリアミド樹脂組成物から形成した
オイル用透明容器に存する。That is, an object of the present invention is to provide an automobile hydraulic oil container that is transparent enough to visually confirm the amount of contents from the outside, and the gist thereof is as follows:
polyamide 6, polyamide 6-6, and polyamide 6.
6-6, an aliphatic polyamide (component A), an aliphatic diamine, isophthalic acid and/or
or partially aromatic polyamide 100 consisting of terephthalic acid
~85% by weight, aliphatic polyamide 0-15% by weight (component B), and the mixing weight ratio of component A and component B is (component A): (component B) = 95:5-40. : 100 parts by weight of a polyamide composition consisting of 60 and 5 to 2 parts of glass fiber
The transparent container for oil is formed from a polyamide resin composition comprising 5 parts by weight.
本発明に用いる脂肪族ポリアミド樹脂（Ａ成分）とは、
ε−カプロラクタムの重縮合からなるポリアミド６（ナ
イロン６）、ヘキサメチレンジアミンとアジピン酸との
重縮合からなるポリアミド６−６（ナイロン６−６）、
及びε−カプロラクタムとへキサメチレンジアミンとア
ジピン酸とを共重合成分とするポリアミド６・６−６（
ナイロン６・６−６）の一種以上からなる。The aliphatic polyamide resin (component A) used in the present invention is:
Polyamide 6 (nylon 6) made of polycondensation of ε-caprolactam, polyamide 6-6 (nylon 6-6) made of polycondensation of hexamethylene diamine and adipic acid,
and polyamide 6/6-6 (
Consists of one or more types of nylon 6, 6-6).
脂肪族ポリアミド樹脂Ａ成分の末端は、前記原料に由来
するアミノ基又はカルボキシル基であるが、得られる中
空容器の透明性を向上せしめるためには、その末端基の
一部もしくは全部を炭化水素基で置換することが望まし
い。The terminals of the aliphatic polyamide resin component A are amino groups or carboxyl groups derived from the raw materials, but in order to improve the transparency of the resulting hollow container, some or all of the terminal groups must be replaced with hydrocarbon groups. It is preferable to replace it with
置換するのに用いる炭化水素基としては炭素数６〜２２
の炭化水素基が好ましく、具体的にはヘキシル基、ブチ
ル基、オクチル基、２−エチルヘキシル基、ノニル基、
デシル基、ウンデシル基、ドデシル基、トリデシル基、
テトラデシル基、テトラデシル基、ペンタデシル基、ヘ
キサデシル基、オクタデシル基、オクタデシル基、エイ
コシル基、トコシル基のような脂肪族炭化水素基、シク
ロヘキシル基、メチルシクロヘキシル基、シクロヘキシ
ルメチル基のような脂環式炭化水素基、フェニル基、ト
ルイル基、ベンジル基、β、フェニルエチル基のような
芳香族炭化水素基などが挙げられる。これらの炭化水素
基による置換は、ポリアミドの製造時に炭素数７〜２３
のモノカルボン酸を添加することによって行なわれる。The hydrocarbon group used for substitution has 6 to 22 carbon atoms.
Hydrocarbon groups are preferable, specifically hexyl group, butyl group, octyl group, 2-ethylhexyl group, nonyl group,
Decyl group, undecyl group, dodecyl group, tridecyl group,
Aliphatic hydrocarbon groups such as tetradecyl group, tetradecyl group, pentadecyl group, hexadecyl group, octadecyl group, octadecyl group, eicosyl group, tocosyl group, alicyclic hydrocarbon group such as cyclohexyl group, methylcyclohexyl group, cyclohexylmethyl group Examples include aromatic hydrocarbon groups such as phenyl, tolyl, benzyl, β, and phenylethyl groups. Substitution with these hydrocarbon groups is carried out during the production of polyamide with a carbon number of 7 to 23.
This is done by adding a monocarboxylic acid.
炭化水素基による置換を全末端の１００％近くにするの
は製造が容易ではなく、透明性、工業的生産性等から置
換は全末端の２５当量％以上、好ましくは４０〜９６％
当量％、より好ましくは５０〜９０当量％とするのがよ
い。It is not easy in production to substitute hydrocarbon groups to nearly 100% of all terminals, and from the viewpoint of transparency, industrial productivity, etc., substitution should be at least 25 equivalent %, preferably 40 to 96%, of all terminals.
The amount is preferably 50 to 90 equivalent %, more preferably 50 to 90 equivalent %.
本発明に使用される部分芳香族ポリアミド樹脂（Ｂ成分
）は、脂肪族ジアミンとして具体的には、エチレンジア
ミン、ペンタメチレンジアミン、プロピレンジアミン、
ブチレンジアミン、ヘキサメチレンジアミン、ノナメチ
レンジアミン、ヘプタメチレンジアミン、オクタメチレ
ンジアミン、ノナメチレンジアミン、デカメチレンジア
ミン、ウンデカメチレンジアミン、ドデカメチレンジア
ミン、２−及び／又は３−メチルへキサメチレンジアミ
ン、２．２，４−及び／又は、２．４．４−トリメチル
へキサメチレンジアミン等が使用されるが、最も好まし
いのはへキサメチレンジアミンである。The partially aromatic polyamide resin (component B) used in the present invention includes aliphatic diamines such as ethylene diamine, pentamethylene diamine, propylene diamine,
Butylene diamine, hexamethylene diamine, nonamethylene diamine, heptamethylene diamine, octamethylene diamine, nonamethylene diamine, decamethylene diamine, undecamethylene diamine, dodecamethylene diamine, 2- and/or 3-methylhexamethylene diamine, 2 2,4- and/or 2,4,4-trimethylhexamethylene diamine, etc. are used, but hexamethylene diamine is most preferred.
脂肪族ジアミンは、イソフタル酸及び／又はテレフタル
酸と重縮合されて、部分芳香族ポリアミド成形単位を形
成する。Aliphatic diamines are polycondensed with isophthalic acid and/or terephthalic acid to form partially aromatic polyamide molding units.
ここで、テレフタル酸とイソフタル酸を併用する場合は
、任意の割合で使用可能だが、好ましくは、イソフタル
酸：テレフタル酸＝８０：２０〜２０：８０である。Here, when terephthalic acid and isophthalic acid are used together, they can be used in any ratio, but preferably isophthalic acid:terephthalic acid=80:20 to 20:80.
また、（Ｂ成分）の部分芳香族ポリアミドには、必要に
応じて脂肪族ポリアミドを１種以上、０〜１５重量％の
割合で含有させることができ、その脂肪族ポリアミドと
は、ラクタム又は脂肪族ジアミンと脂肪族カルボン酸と
からなるポリアミド樹脂が好ましい、ラクタムとは具体
的には炭素数６〜１２のラクタムであり、カプロラクタ
ム、エナントラクタム、ラウリルラクタム等である。脂
肪族ジアミンとしては、具体的には、エチレンジアミン
、ペンタメチレンジアミン、プロピレンジアミン、ブチ
レンジアミン、ヘキサメチレンジアミン、ノナメチレン
ジアミン、ヘプタメチレンジアミン、オクタメチレンジ
アミン、ノナメチ、レンジアミン、デカメチレンジアミ
ン、ウンデカメチレンジアミン、ドデカメチレンジアミ
ン、２−メチルへキサメチレンジアミン、３−メチルへ
キサメチレンジアミン、２．２．４−トリメチルへキサ
メチレンジアミン、２．２．４−）リメチルへキサメチ
レンジアミン等である。また、脂肪族ジカルボン酸とし
ては、具体的にはコハク酸、グルタル酸、アゼライン酸
、セバシン酸、ウンデカンジオン酸、２−メチルアジピ
ン酸、３−メチルアジピン酸等である。In addition, the partially aromatic polyamide (component B) may contain one or more aliphatic polyamides in a proportion of 0 to 15% by weight, if necessary. A polyamide resin consisting of a group diamine and an aliphatic carboxylic acid is preferred.The lactam is specifically a lactam having 6 to 12 carbon atoms, such as caprolactam, enantholactam, and lauryllactam. Specifically, the aliphatic diamines include ethylenediamine, pentamethylenediamine, propylenediamine, butylenediamine, hexamethylenediamine, nonamethylenediamine, heptamethylenediamine, octamethylenediamine, nonamethylene, diamine, decamethylenediamine, and undecyldiamine. Methylenediamine, dodecamethylenediamine, 2-methylhexamethylenediamine, 3-methylhexamethylenediamine, 2.2.4-trimethylhexamethylenediamine, 2.2.4-)limethylhexamethylenediamine, etc. . Further, specific examples of aliphatic dicarboxylic acids include succinic acid, glutaric acid, azelaic acid, sebacic acid, undecanedioic acid, 2-methyladipic acid, and 3-methyladipic acid.
本発明のＢ成分においては、脂肪族ジアミンとイソフタ
ル酸及び／又はテレフタル酸よりなる部分芳香族ポリア
ミドが８５重量％以上であることが必要である０部分芳
香族ポリアミドが８５重量％未満では、Ａ成分と配合し
た場合に透明性が低下する。In component B of the present invention, it is necessary that the partially aromatic polyamide consisting of aliphatic diamine and isophthalic acid and/or terephthalic acid accounts for 85% by weight or more. Transparency decreases when combined with other ingredients.
本発明において使用される脂肪族ポリアミド（Ａ成分）
及び部分芳香族ポリアミド（Ｂ成分）は、当該業者に周
知の方法で製造される。すなわち、ラクタム及び／又は
ジアミン及びジカルボン酸からなるナイロン塩または水
溶液をオートクレーブにしこみ、必要に応じてモノカル
ボン酸もしくはモノアミン等のいわゆる一官能性化合物
を重合度調節剤として加え、常圧もしくは加圧状態で重
縮合せしめれば良い。Aliphatic polyamide used in the present invention (component A)
and partially aromatic polyamide (component B) are produced by a method well known to those skilled in the art. That is, a nylon salt or aqueous solution consisting of lactam and/or diamine and dicarboxylic acid is put into an autoclave, and if necessary, a so-called monofunctional compound such as a monocarboxylic acid or monoamine is added as a polymerization degree regulator, and the mixture is heated at normal pressure or under pressure. It is sufficient to carry out polycondensation in this state.
脂肪族ポリアミド（Ａ成分）と部分芳香族ポリアミド（
Ｂ成分）との混合比は、重量比にして（Ａ成分）： （
Ｂ成分）−９５：５〜４０：６０の範囲内で選択される
。この配合範囲を越えてＡ成分が多いと、得られる容器
の透明性が不十分であり、Ａ成分が少ないと、耐薬品性
が著しく低下する。Aliphatic polyamide (component A) and partially aromatic polyamide (
The mixing ratio with (component B) is expressed as a weight ratio (component A): (
B component) selected within the range of -95:5 to 40:60. If the amount of component A exceeds this range, the resulting container will have insufficient transparency, and if the amount of component A is too low, the chemical resistance will be significantly reduced.
本発明で使用されるガラス繊維は、特別なものである必
要はなく、熱可塑性樹脂強化用ガラス繊維として市販さ
れているロービングガラス、チョツプドストランドガラ
ス、ミルドガラスに到るまでの任意の形状のものが使用
出来る。ガラス繊維の配合比は、ポリアミド組成物（Ａ
成分とＢ成分との合計量）１００重量部に対し、５〜２
５重量部の範囲で選択される。５重量部より少ないと、
ガラス繊維の補強効果が少なく、２５重量部を越えると
、得られた容器の透明性が損なわれる。The glass fibers used in the present invention do not need to be special, and can be in any shape, including roving glass, chopped strand glass, and milled glass, which are commercially available as glass fibers for reinforcing thermoplastic resins. can be used. The blending ratio of glass fibers is as follows: polyamide composition (A
Total amount of component and B component) 5 to 2 parts per 100 parts by weight
The amount is selected within the range of 5 parts by weight. If it is less than 5 parts by weight,
The reinforcing effect of glass fiber is small, and if it exceeds 25 parts by weight, the transparency of the resulting container will be impaired.
本発明で用いられるポリアミド樹脂組成物（ガラス繊維
含有樹脂）には上記配合物以外に、透明性を損なわない
範囲内で、周知の種々の添加剤、例えば、ガラスバルー
ン、ガラスフレークのような補強剤、核剤として使用さ
れる少量の無機質充填剤、滑剤、酸化防止剤、難燃剤、
帯電防止剤、耐候性付与剤、染料や顔料などの着色剤等
を添加してもよい。In addition to the above-mentioned compounds, the polyamide resin composition (glass fiber-containing resin) used in the present invention may contain various well-known additives, such as reinforcement such as glass balloons and glass flakes, within a range that does not impair transparency. Small amounts of inorganic fillers used as additives, nucleating agents, lubricants, antioxidants, flame retardants,
Antistatic agents, weather resistance agents, coloring agents such as dyes and pigments, etc. may be added.
脂肪族ポリアミド樹脂（Ａ成分）及び、主成分が半芳香
族ポリアミド形成単位である（Ｂ成分）並びに、ガラス
繊維との配合は、当該業者に周知の方法が使用でき、な
かでも、エクストルーダーバンバリーミキサ−、スーパ
ーミキサーなどを使用して溶融混合することが好ましい
。The aliphatic polyamide resin (component A), the main component of which is a semi-aromatic polyamide forming unit (component B), and glass fiber can be blended using methods well known to those skilled in the art, including extruder Banbury. It is preferable to perform melt mixing using a mixer, super mixer, or the like.
中空容器の形成は、射出成形、ブロー成形、射出ブロー
成形、回転成形などの通常の熱可塑性樹脂の成形方法は
、いずれの方法も適用出来る。この際、中空容器の透明
性を保持するために、オイルの量を確認する部分の肉厚
は、０．２〜２ｍとすることが望ましい、また、成形加
工時に、透明性を損なわないように、型の温度は低く設
定して樹脂の過度の結晶化を避け、オイルの量を確認す
る部分の全光線透過率は、５０％以上を確保することが
望ましい。The hollow container can be formed by any conventional thermoplastic resin molding method such as injection molding, blow molding, injection blow molding, and rotational molding. At this time, in order to maintain the transparency of the hollow container, it is desirable that the wall thickness of the part where the amount of oil is checked is 0.2 to 2 m. It is desirable to set the temperature of the mold low to avoid excessive crystallization of the resin, and to ensure a total light transmittance of 50% or more in the area where the amount of oil is checked.
〔実施例］
以下に本発明について実施例により更に詳しく説明する
が、本発明は実施例に限定されるものではない。[Example] The present invention will be explained in more detail below with reference to Examples, but the present invention is not limited to the Examples.
実施例中の測定項目は、下記の方法で行った。The measurement items in the examples were carried out by the following methods.
（１） 全光線透過率 ＡＳＴＭ Ｄ−１００３に準拠して行った。(1) Total light transmittance It was conducted in accordance with ASTM D-1003.
（２）引張強度 ＡＳＴＭ Ｄ−６３８に準拠して行った。(2) Tensile strength It was performed in accordance with ASTM D-638.
（３）曲げ弾性率 ＡＳＴＭ Ｄ−７９０に準拠して行った。(3) Flexural modulus It was conducted in accordance with ASTM D-790.
（４） 耐薬品性
試験片を、エチルアルコール及び、パワーステアリング
オイルに浸漬し、下記の条件にて放置後、全光線透過率
、及び、引張強度を測定した。(4) Chemical resistance test pieces were immersed in ethyl alcohol and power steering oil, and after being left under the following conditions, the total light transmittance and tensile strength were measured.
エチルアルコール： ２３℃ ２４時間パワーステア
リングオイル：
８０°Ｃ４８時間
実施例１〜７
く脂肪酸ポリアミド（Ａ成分）の重合〉（Ａ成分■の製
造）
２００１のオートクレーブに、ε−カプロラクタムを６
０ｋｇ、水４ｋｇを仕込み、窒素雰囲気にして密閉し、
２７０℃、１４ｋｇ／ｃｊに昇温、昇圧し、撹拌下で３
時間加圧反応を行った後、徐々に放圧して減圧にし、２
時間減圧反応を行った。撹拌を止め、窒素を導入して常
圧に復帰後、スラランドとしてペレット化し、清水を用
いて未反応モノマーを抽出除去後、乾燥した。こうして
得られたポリマーは、オストワルド粘度計による相対粘
度が、η、１１． ｍ ３． Ｑであった。Ethyl alcohol: 23°C 24 hours Power steering oil: 80°C 48 hours Examples 1 to 7 Polymerization of fatty acid polyamide (component A) (manufacture of component A) In a 2001 autoclave, ε-caprolactam was added to
0 kg and 4 kg of water, sealed in a nitrogen atmosphere,
The temperature and pressure were increased to 270°C, 14 kg/cj, and the temperature was increased to 3.
After carrying out the pressurized reaction for an hour, the pressure was gradually released to reduce the pressure, and
A time vacuum reaction was carried out. After stopping the stirring and returning to normal pressure by introducing nitrogen, the mixture was pelletized as slurland, unreacted monomers were extracted and removed using fresh water, and then dried. The polymer thus obtained had a relative viscosity of η, 11. m 3. It was Q.
（Ａ成分■の製造）
ｅ−カプロラクタムを６０ｋｇ、水４ｋｇ仕込む際に、
３０μ当量／ｇｒのステアリン酸を更に配合したほかは
、Ａ成分■の製造と同様にポリマーを得た。(Production of component A ■) When preparing 60 kg of e-caprolactam and 4 kg of water,
A polymer was obtained in the same manner as in the production of component A, except that 30 μeq/gr of stearic acid was further blended.
〈半芳香族ポリアミド（Ｂ成分）の重合〉（Ｂ成分■の
製造）
８０重量％のへキサメチレン水溶液に１３．９ｋｇに、
水を５３ｋｇ、イソフタル酸９．８ｋｇ、テレフタル酸
４．９ ｋｇを加え、均一に撹拌溶解した後、酢酸。<Polymerization of semi-aromatic polyamide (component B)> (Production of component B) Add 13.9 kg to an 80% by weight aqueous hexamethylene solution,
Add 53 kg of water, 9.8 kg of isophthalic acid, and 4.9 kg of terephthalic acid, stir and dissolve uniformly, and then add acetic acid.
５３ｇｒを添加して、オートクレーブに仕込み、２゜５
ｋｇ／ｄに加圧に保ちながら、ナイロン塩の濃度が９
０重量％になるまで水を留出させ、次いで加熱しながら
１３ｋｇ／ｃｄまで昇圧した後、更に水を留出させ、内
温か２５０℃に達したならば、内圧をゆっくりと抜き、
最後は７００ ｔｏｒｒの圧力で１時間減圧重合を行っ
た後、スラランドとしてペレット化し、清水を用いて未
反応上ツマ−を抽出除去後、乾燥した。こうして得られ
たポリマーは、オストワルド粘度針による相対粘度が、
η１．ｌ＝２．２である。Add 53gr and put it in an autoclave to 2゜5.
While maintaining the pressure at kg/d, the concentration of nylon salt is 9.
Water was distilled out until it became 0% by weight, then the pressure was increased to 13 kg/cd while heating, and then water was further distilled out. When the internal temperature reached 250°C, the internal pressure was slowly released.
Finally, after vacuum polymerization was carried out at a pressure of 700 torr for 1 hour, the slurry was pelletized as slurland, unreacted slag was extracted and removed using fresh water, and then dried. The polymer obtained in this way has a relative viscosity determined by the Ostwald viscosity needle.
η1. l=2.2.
（Ｂ成分■の製造）
８０重量％のへキサメチレン水溶液に、１３．９ ｋｇ
に、水を５３ｋｇ、イソフタル酸９．８ｋｇ、テレフタ
ル酸４．９ｋｇを加え、更に、カプロラクタム２．５ｋ
ｇと酢酸を４０ｇｒ添加したほかは、上記Ｂ成分■の製
造と同様に行った。こうして得られたポリマーは、オス
トワルド粘度計による相対粘度が、η、。。(Production of component B) Add 13.9 kg to an 80% by weight aqueous hexamethylene solution.
To this, add 53 kg of water, 9.8 kg of isophthalic acid, 4.9 kg of terephthalic acid, and add 2.5 kg of caprolactam.
The procedure was the same as in the production of component B (2) above, except that 40 g of acetic acid and 40 g of acetic acid were added. The polymer thus obtained has a relative viscosity of η as measured by an Ostwald viscometer. .
＝２．０である。また、このポリマーの半芳香族ポリア
ミド形成単位と、脂肪族ポリアミド形成単位との重量比
は９０：１０である。=2.0. Further, the weight ratio of semi-aromatic polyamide forming units to aliphatic polyamide forming units of this polymer is 90:10.
前述のポリアミド成分■〜■と、市販の３１Ｉｌｌ長さ
のチョツプドガラス繊維（旭ファイバーグラス（株）製
Ｃ３０３ＭＡ４８６）を、表１の配合比で混合し、４０
麺φ押出機にて樹脂温２５０〜２８０℃の範囲で溶融混
合後ベレット化し、真空乾燥後にて１２０ ’Ｃ１２４
時間乾燥後、型締カフ５ｔｏｎの射出成形機にて、１．
６ ｍ厚みと３．２ｍ厚みの試験片を成形した。こうし
て得られた試験片の全光線透過率及び、引張強度、及び
、曲げ強度を測定した。結果は表−２に示した。また、
１．６ ａｓ厚みの試験片を、エタノール及び、パワー
ステアリングオイルに浸漬し、物性の変化を測定した。The above-mentioned polyamide components (■ to ■) and commercially available chopped glass fibers (C303MA486 manufactured by Asahi Fiberglass Co., Ltd.) having a length of 31 Ill were mixed at the blending ratio shown in Table 1.
After melting and mixing with a noodle φ extruder at a resin temperature in the range of 250 to 280°C, it is made into pellets, and after vacuum drying, it becomes 120'C124
After drying for a while, 1.
Test pieces with a thickness of 6 m and a thickness of 3.2 m were molded. The total light transmittance, tensile strength, and bending strength of the test piece thus obtained were measured. The results are shown in Table-2. Also,
A test piece with a thickness of 1.6 as was immersed in ethanol and power steering oil, and changes in physical properties were measured.
結果は表−３に示した。また、ｌｏＯＸ１００ｘ２００
ｍの金属製長方形の容器の側面の一部を切り欠き、本試
験片で代用後、パワーステアリングオイルを注ぎ、目の
高さに静置後、内部液の液面が目視で確認可能な最短距
離を測定した。結果は表−２に示した。The results are shown in Table-3. Also, loOX100x200
After cutting out a part of the side of a rectangular metal container of size m and replacing it with this test piece, pour in the power steering oil and leave it at eye level. The distance was measured. The results are shown in Table-2.
比較例１〜３
前述のポリアミド成分■〜■と、チョツプドガラス繊維
を、表−１に示す割合で配合し、実施例と同様に、測定
を行った。結果は表−２，３に示した。Comparative Examples 1 to 3 The aforementioned polyamide components 1 to 3 and chopped glass fibers were blended in the proportions shown in Table 1, and measurements were conducted in the same manner as in the examples. The results are shown in Tables 2 and 3.
表
〔発明の効果〕
本発明で得られる容器、透明性に優れるため、内容液の
外部からの目視による確認が容易であり、しかも脂肪族
ポリアミド樹脂本来の、優れた機械的特性と耐薬品性を
保持する。したがって、自動車油圧系オイル容器等には
、極めて適しており、工業的にも非常に有用である。Table [Effects of the Invention] The container obtained by the present invention has excellent transparency, so it is easy to visually check the content from the outside, and it also has excellent mechanical properties and chemical resistance inherent to aliphatic polyamide resin. hold. Therefore, it is extremely suitable for automobile hydraulic oil containers and the like, and is also very useful industrially.
Claims (2)
ド６・６−６のうちの少なくとも１種からなる脂肪族ポ
リアミド（Ａ成分）と、脂肪族ジアミンとイソフタル酸
及び／又はテレフタル酸からなる部分芳香族ポリアミド
１００〜８５重量％、脂肪族ポリアミド０〜１５重量％
からなるポリアミド（Ｂ成分）よりなり、Ａ成分とＢ成
分との混合重量比が、 （Ａ成分）：（Ｂ成分）＝９５：５〜４０：６０とされ
たポリアミド組成物１００重量部と、ガラス繊維５〜２
５重量部とからなるポリアミド樹脂組成物から形成した
オイル用透明容器。(1) An aliphatic polyamide (component A) consisting of at least one of polyamide 6, polyamide 6-6, and polyamide 6/6-6, and a partial aroma consisting of an aliphatic diamine and isophthalic acid and/or terephthalic acid. Group polyamide 100-85% by weight, aliphatic polyamide 0-15% by weight
100 parts by weight of a polyamide composition (component B) in which the mixing weight ratio of component A and component B is (component A):(component B) = 95:5 to 40:60; Glass fiber 5-2
A transparent container for oil formed from a polyamide resin composition comprising 5 parts by weight.
において、Ａ成分である脂肪族ポリアミドは、全末端基
の数の２５当量％以上が炭素数６〜２２の炭化水素基で
置換されたポリアミド樹脂であることを特徴とするオイ
ル用透明容器。(2) In the transparent container for oil according to claim 1, in the aliphatic polyamide that is component A, 25 equivalent % or more of the total number of terminal groups is substituted with a hydrocarbon group having 6 to 22 carbon atoms. A transparent container for oil, characterized by being made of polyamide resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1018217A JPH02199168A (en) | 1989-01-28 | 1989-01-28 | Transparent container for oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1018217A JPH02199168A (en) | 1989-01-28 | 1989-01-28 | Transparent container for oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02199168A true JPH02199168A (en) | 1990-08-07 |
Family
ID=11965482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1018217A Pending JPH02199168A (en) | 1989-01-28 | 1989-01-28 | Transparent container for oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02199168A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE9216263U1 (en) * | 1992-11-30 | 1993-04-01 | Ems-Inventa AG, Zürich | Eyeglass frame parts |
| KR20190019878A (en) * | 2017-08-18 | 2019-02-27 | 이엠에스-패턴트 에이지 | Reinforced Polyamide Molding Compounds Having Low Haze and Molded Bodies Therefrom |
-
1989
- 1989-01-28 JP JP1018217A patent/JPH02199168A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE9216263U1 (en) * | 1992-11-30 | 1993-04-01 | Ems-Inventa AG, Zürich | Eyeglass frame parts |
| KR20190019878A (en) * | 2017-08-18 | 2019-02-27 | 이엠에스-패턴트 에이지 | Reinforced Polyamide Molding Compounds Having Low Haze and Molded Bodies Therefrom |
| CN109401293A (en) * | 2017-08-18 | 2019-03-01 | Ems专利股份公司 | Reinforced polyamide moulding compound with low haze and the moulding bodies being made from it |
| JP2019065260A (en) * | 2017-08-18 | 2019-04-25 | エムス−パテント アクツィエンゲゼルシャフト | Low haze reinforced polyamide molding material and molded body thereof |
| CN109401293B (en) * | 2017-08-18 | 2023-06-13 | Ems专利股份公司 | Reinforced polyamide molding compounds with low haze and molded bodies made therefrom |
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