JPH0219576A - 角質繊維染色組成物 - Google Patents
角質繊維染色組成物Info
- Publication number
- JPH0219576A JPH0219576A JP63169571A JP16957188A JPH0219576A JP H0219576 A JPH0219576 A JP H0219576A JP 63169571 A JP63169571 A JP 63169571A JP 16957188 A JP16957188 A JP 16957188A JP H0219576 A JPH0219576 A JP H0219576A
- Authority
- JP
- Japan
- Prior art keywords
- substance
- dyeing composition
- coupling
- dyeing
- hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000000835 fiber Substances 0.000 title claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 37
- 230000008878 coupling Effects 0.000 claims abstract description 21
- 238000010168 coupling process Methods 0.000 claims abstract description 21
- 238000005859 coupling reaction Methods 0.000 claims abstract description 21
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229960001755 resorcinol Drugs 0.000 claims abstract description 7
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 claims abstract description 4
- JQVAPEJNIZULEK-UHFFFAOYSA-N 4-chlorobenzene-1,3-diol Chemical compound OC1=CC=C(Cl)C(O)=C1 JQVAPEJNIZULEK-UHFFFAOYSA-N 0.000 claims abstract description 3
- CSNFMBGHUOSBFU-UHFFFAOYSA-N pyrimidine-2,4,5-triamine Chemical class NC1=NC=C(N)C(N)=N1 CSNFMBGHUOSBFU-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000003839 salts Chemical class 0.000 claims abstract description 3
- LWHVWLRDWAZQIS-UHFFFAOYSA-N 3,4-dimethylpyridine-2,6-diamine Chemical compound CC1=CC(N)=NC(N)=C1C LWHVWLRDWAZQIS-UHFFFAOYSA-N 0.000 claims abstract 2
- HMJNCEUYDWAONZ-UHFFFAOYSA-N 4-propylpyridine-2,6-diamine Chemical compound CCCC1=CC(N)=NC(N)=C1 HMJNCEUYDWAONZ-UHFFFAOYSA-N 0.000 claims abstract 2
- 102000011782 Keratins Human genes 0.000 claims 1
- 108010076876 Keratins Proteins 0.000 claims 1
- -1 organic acid salt Chemical class 0.000 abstract description 5
- 239000000839 emulsion Substances 0.000 abstract description 2
- 150000007522 mineralic acids Chemical class 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 7
- 235000019646 color tone Nutrition 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 238000005691 oxidative coupling reaction Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- YCOXTKKNXUZSKD-UHFFFAOYSA-N 3,4-xylenol Chemical compound CC1=CC=C(O)C=C1C YCOXTKKNXUZSKD-UHFFFAOYSA-N 0.000 description 2
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FJYWALZPRGPBBY-UHFFFAOYSA-N 1-amino-1-phenoxyethanol Chemical compound CC(N)(O)OC1=CC=CC=C1 FJYWALZPRGPBBY-UHFFFAOYSA-N 0.000 description 1
- NKTOLZVEWDHZMU-UHFFFAOYSA-N 2,5-xylenol Chemical compound CC1=CC=C(C)C(O)=C1 NKTOLZVEWDHZMU-UHFFFAOYSA-N 0.000 description 1
- AUFJTVGCSJNQIF-UHFFFAOYSA-N 2-Amino-4,6-dihydroxypyrimidine Chemical compound NC1=NC(O)=CC(=O)N1 AUFJTVGCSJNQIF-UHFFFAOYSA-N 0.000 description 1
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 description 1
- SWZVJOLLQTWFCW-UHFFFAOYSA-N 2-chlorobenzene-1,3-diol Chemical compound OC1=CC=CC(O)=C1Cl SWZVJOLLQTWFCW-UHFFFAOYSA-N 0.000 description 1
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical compound OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- PVKNQGWSRAGMNM-UHFFFAOYSA-N 5-amino-2-phenyl-1h-pyrazol-3-one Chemical compound N1C(N)=CC(=O)N1C1=CC=CC=C1 PVKNQGWSRAGMNM-UHFFFAOYSA-N 0.000 description 1
- LNDZXOWGUAIUBG-UHFFFAOYSA-N 6-aminouracil Chemical compound NC1=CC(=O)NC(=O)N1 LNDZXOWGUAIUBG-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241001474791 Proboscis Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- ZUVBIBLYOCVYJU-UHFFFAOYSA-N naphthalene-1,7-diol Chemical compound C1=CC=C(O)C2=CC(O)=CC=C21 ZUVBIBLYOCVYJU-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- VHNQIURBCCNWDN-UHFFFAOYSA-N pyridine-2,6-diamine Chemical compound NC1=CC=CC(N)=N1 VHNQIURBCCNWDN-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000000276 sedentary effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012192 staining solution Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4953—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Coloring (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
【発明の詳細な説明】
ｃ座業上の利用分野〕
本発明は染色組成物に関し、更に詳細には毛受等の角質
繊維を高彩度に染色することができる角質繊維染色組成
物に関する。
繊維を高彩度に染色することができる角質繊維染色組成
物に関する。
毛髪等の角質繊維の染色には、従来よシ顕色吻質とカツ
プリング物質を組み合せて用いる、いわゆる酸化染色剤
が広く使用されている。この酸化染色剤は顕色物質とカ
ツプリング物質の酸化カッｆリングによって生じる、い
わゆる酸化色素が毛髪等を強く染色することを利用した
ものでめる。そして顕色物質としては、一般にｐ−フェ
ニレンシアミン誘導体、ｐ−アミンフェノール銹導体、
シアミノビリシン誘導体、４−７ミノビラゾロン誘導体
、複素環状ヒドラゾン等が使用されている。
プリング物質を組み合せて用いる、いわゆる酸化染色剤
が広く使用されている。この酸化染色剤は顕色物質とカ
ツプリング物質の酸化カッｆリングによって生じる、い
わゆる酸化色素が毛髪等を強く染色することを利用した
ものでめる。そして顕色物質としては、一般にｐ−フェ
ニレンシアミン誘導体、ｐ−アミンフェノール銹導体、
シアミノビリシン誘導体、４−７ミノビラゾロン誘導体
、複素環状ヒドラゾン等が使用されている。
しかしながら、従来の酸化染色剤は、彩度、染着力およ
び盛ろう性において未だ満足すべきものではなかった。
び盛ろう性において未だ満足すべきものではなかった。
そこで本発明者らは前記問題点を解決すべく種々検討を
重ねた結果、顕色物質として特定のトリアミノビリミシ
ン誘導体を使用することによシ、角質繊維を高彩度で強
い色調に染色することが可能となり、かつその染色は優
れた堅ろう性を有することを見出し、本発明を完成した
。
重ねた結果、顕色物質として特定のトリアミノビリミシ
ン誘導体を使用することによシ、角質繊維を高彩度で強
い色調に染色することが可能となり、かつその染色は優
れた堅ろう性を有することを見出し、本発明を完成した
。
すなわち、本発明は顕色物質およびカップリング物質を
含有する染色組成物において、顕色物質が、次の一般式
（Ｉ）または（１′）で表わされるトリアミノピリミジ
ン誘導体く以下化合’ＩＩ！ｌ （Ｉ）と称する）であ
ることを特徴とする角質繊維染色組成物を提供するもの
である。
含有する染色組成物において、顕色物質が、次の一般式
（Ｉ）または（１′）で表わされるトリアミノピリミジ
ン誘導体く以下化合’ＩＩ！ｌ （Ｉ）と称する）であ
ることを特徴とする角質繊維染色組成物を提供するもの
である。
本発明に使用される化合物（１）の塩としては、塩酸、
硫酸、リン酸等の無機酸または、炭素数１〜２０の直鎖
もしくは分岐アルキル基を有するカルメン酸、ヒドロキ
シカルボン酸、−リヒドロキシカルボン嫉、スルホン酸
等の有機酸が挙げられ、塩酸、硫酸、リン酸、酢酸、プ
ロピオン酸、乳酸、クエン酸等が好ましい。
硫酸、リン酸等の無機酸または、炭素数１〜２０の直鎖
もしくは分岐アルキル基を有するカルメン酸、ヒドロキ
シカルボン酸、−リヒドロキシカルボン嫉、スルホン酸
等の有機酸が挙げられ、塩酸、硫酸、リン酸、酢酸、プ
ロピオン酸、乳酸、クエン酸等が好ましい。
本発明染色組成物に使用されるカップリング物質として
は、通常酸化染毛剤に慣用されているものであれば特に
制限されないが、例えばα−す７トール、０−クレゾー
ル、 ｍ −クレゾール、２，６−ジメチルフェノール
、２．５−ジメチルフェノール、３，４−ジメチルフェ
ノール、３，５−ジメチルフェノール、ベンズカテキン
、ピロガロール、１．５−ジヒドロキシナフタレン、１
，７−ジヒドロキシナフタレン、５−アミノ−２−メチ
ルフェノール、ヒドロキノン、２，４−ゾアミノアニン
ール、ｍ−トルイレンシアミン、４−アミンフェノール
、レゾルシン、レゾルシンモノメチルエーテル、ｍ−フ
ェニレンシアミン、１−フェニル−３−）ｆルー５−ピ
ラゾロン、１−フェニル−３−アミノ−５−ピラゾロン
、１−フェニル−３，５−ゾケトービラゾリゾン、１−
メチル−７−ゾメチル−アミノ−４−ヒドロキシキノロ
ン−２，１−アミノ−３−アセチル−アセトアミノ−４
−二トロベンゾール、１−アミノ−３−シアンアセチル
−アミノ−４−ニトロ−ペンゾール、ｍ−アミンフェノ
ール、４−クロロレゾルシン、２−メチルレゾルシン、
２．４−Ｐアミノフェノキシエタノール、２，６−ジア
ミノビリジン、３，５−シアミノ−トリフロロメチルベ
ンゼン、２，４−シアミノ−フロロベンゼン、３．５−
シアミノ−フロロベンゼン、２．４−シアミノ−６−ヒ
ドロキシピリミジン、２，４．６−トリアミノビリミシ
ン、２−アミノ−４，６−ジヒドロキシピリミジン、４
−アミノ−２，６−ジヒドロキシビリミジン、４，６−
ゾアミノー２−ヒドロキシピリミジン、ｐ−ニトロ−〇
−フェニレンシアミン、２−アミノ−５−ニトロフェノ
ール、ｐ−ニトロ−ｍ−フェニレンシアミン、〇−二ヒ
トローｐ−フェニレンシアミン２−アミノ−４−ニトロ
フェノール等が挙げられる。
は、通常酸化染毛剤に慣用されているものであれば特に
制限されないが、例えばα−す７トール、０−クレゾー
ル、 ｍ −クレゾール、２，６−ジメチルフェノール
、２．５−ジメチルフェノール、３，４−ジメチルフェ
ノール、３，５−ジメチルフェノール、ベンズカテキン
、ピロガロール、１．５−ジヒドロキシナフタレン、１
，７−ジヒドロキシナフタレン、５−アミノ−２−メチ
ルフェノール、ヒドロキノン、２，４−ゾアミノアニン
ール、ｍ−トルイレンシアミン、４−アミンフェノール
、レゾルシン、レゾルシンモノメチルエーテル、ｍ−フ
ェニレンシアミン、１−フェニル−３−）ｆルー５−ピ
ラゾロン、１−フェニル−３−アミノ−５−ピラゾロン
、１−フェニル−３，５−ゾケトービラゾリゾン、１−
メチル−７−ゾメチル−アミノ−４−ヒドロキシキノロ
ン−２，１−アミノ−３−アセチル−アセトアミノ−４
−二トロベンゾール、１−アミノ−３−シアンアセチル
−アミノ−４−ニトロ−ペンゾール、ｍ−アミンフェノ
ール、４−クロロレゾルシン、２−メチルレゾルシン、
２．４−Ｐアミノフェノキシエタノール、２，６−ジア
ミノビリジン、３，５−シアミノ−トリフロロメチルベ
ンゼン、２，４−シアミノ−フロロベンゼン、３．５−
シアミノ−フロロベンゼン、２．４−シアミノ−６−ヒ
ドロキシピリミジン、２，４．６−トリアミノビリミシ
ン、２−アミノ−４，６−ジヒドロキシピリミジン、４
−アミノ−２，６−ジヒドロキシビリミジン、４，６−
ゾアミノー２−ヒドロキシピリミジン、ｐ−ニトロ−〇
−フェニレンシアミン、２−アミノ−５−ニトロフェノ
ール、ｐ−ニトロ−ｍ−フェニレンシアミン、〇−二ヒ
トローｐ−フェニレンシアミン２−アミノ−４−ニトロ
フェノール等が挙げられる。
本発明に使用される顕色物質は、レゾルシン系のカップ
リング物質と組み合せることによシ高彩度の赤系色調が
得られ、特にレゾルシン、２−メチルレゾルシン、４−
クロロレゾルシンをカップリング物質とすると、高彩度
のオレンゾル赤の色調が得られる。また、本発明に使用
される顕色物質を、シアミノビリシン系のカップリング
物質と組み合わせることによシアざやかな黄色が得られ
、特に４−ゾロビル−２，６−ジアミノピリジン、３゜
４−ジメチル−２，６−ゾアミノビリジンをカップリン
グ物質として用いると高彩度の黄色が得られる。
リング物質と組み合せることによシ高彩度の赤系色調が
得られ、特にレゾルシン、２−メチルレゾルシン、４−
クロロレゾルシンをカップリング物質とすると、高彩度
のオレンゾル赤の色調が得られる。また、本発明に使用
される顕色物質を、シアミノビリシン系のカップリング
物質と組み合わせることによシアざやかな黄色が得られ
、特に４−ゾロビル−２，６−ジアミノピリジン、３゜
４−ジメチル−２，６−ゾアミノビリジンをカップリン
グ物質として用いると高彩度の黄色が得られる。
本発明の染色組成物中の顕色物質とカップリング物質の
配合割合は、一方の成分が他方に比べ過剰となっていて
もさしつかえないが、モル比で１：０．５〜１：２程度
であることが好ましい。また顕色物質およびカップリン
グ物質は、ともに単独でも二櫨以上を組み合せても使用
することができる。
配合割合は、一方の成分が他方に比べ過剰となっていて
もさしつかえないが、モル比で１：０．５〜１：２程度
であることが好ましい。また顕色物質およびカップリン
グ物質は、ともに単独でも二櫨以上を組み合せても使用
することができる。
また本発明の染色組成物には所望の色調を得るため必要
でめれば、更に公知の顕色物質、通常の１染性染料等を
配合することができる。
でめれば、更に公知の顕色物質、通常の１染性染料等を
配合することができる。
本発明染色組成物は、空気中の酸素によっても酸化カッ
プリングを生起し、毛髪等を染色するが、化学的酸化剤
を添加することによシ酸化カツプリングを生起させるの
が好ましい。特に好ましい酸化剤としては、過酸化水素
：過酸化水素が尿素、メラミン又は５！ＩｒＩＲナトリ
ウムに付加した生成物；このような過酸化水素付加物と
過酸化カリウムー二硫酸との混合物等が挙げられる。
プリングを生起し、毛髪等を染色するが、化学的酸化剤
を添加することによシ酸化カツプリングを生起させるの
が好ましい。特に好ましい酸化剤としては、過酸化水素
：過酸化水素が尿素、メラミン又は５！ＩｒＩＲナトリ
ウムに付加した生成物；このような過酸化水素付加物と
過酸化カリウムー二硫酸との混合物等が挙げられる。
本発明の染色組成物は通常、クリーム、エマルション、
グル、溶液等の剤型で提供されるのが好ましい。このよ
うな剤型とするには、前記顕色物質およびカップリング
物質に、通常化粧品分野において用いられる湿潤剤（乳
化剤）、可溶化剤、増粘剤、安定化剤、感触向上剤、整
髪基剤、香料等を添加し、常法に従って製造すればよい
。ここで用いられる湿調剤（乳化剤）としては、例えば
アルキルベンゼンスルホネート、脂肪アルコールサルフ
ェート、アルキルスルホネート、脂肪酸アルカノールア
ミド、エチレンオキシドと脂肪アルコールとの付加生成
物等が挙げられる。また増粘剤としては、例えばメチル
セルロース、デンプン、高級脂肪アルコール、ノＱラフ
イン油、脂肪酸等が挙げられ、安定化剤としては、例え
ば亜硫酸塩等の還元剤、ヒドロキノン酵導体、キレート
剤等が挙げられ、感触向上剤、整髪基剤としては、例え
ばシリコーン、高級アルコール、各種非イオン界面活性
剤等の油剤、各種のカチオンビリマー等が挙げられる。
グル、溶液等の剤型で提供されるのが好ましい。このよ
うな剤型とするには、前記顕色物質およびカップリング
物質に、通常化粧品分野において用いられる湿潤剤（乳
化剤）、可溶化剤、増粘剤、安定化剤、感触向上剤、整
髪基剤、香料等を添加し、常法に従って製造すればよい
。ここで用いられる湿調剤（乳化剤）としては、例えば
アルキルベンゼンスルホネート、脂肪アルコールサルフ
ェート、アルキルスルホネート、脂肪酸アルカノールア
ミド、エチレンオキシドと脂肪アルコールとの付加生成
物等が挙げられる。また増粘剤としては、例えばメチル
セルロース、デンプン、高級脂肪アルコール、ノＱラフ
イン油、脂肪酸等が挙げられ、安定化剤としては、例え
ば亜硫酸塩等の還元剤、ヒドロキノン酵導体、キレート
剤等が挙げられ、感触向上剤、整髪基剤としては、例え
ばシリコーン、高級アルコール、各種非イオン界面活性
剤等の油剤、各種のカチオンビリマー等が挙げられる。
これらの剤をにおける顕色物質とカップリング物質の配
合量は、合計で０．２〜５重童チ（以下単にチで示す）
、特に１〜３チが好ましい。湿潤剤（乳化剤）は通常０
．５〜３０チ、増粘剤は０．１〜２５チ配合されるのが
好ましい。
合量は、合計で０．２〜５重童チ（以下単にチで示す）
、特に１〜３チが好ましい。湿潤剤（乳化剤）は通常０
．５〜３０チ、増粘剤は０．１〜２５チ配合されるのが
好ましい。
またこれらの剤槃において、組成物全体の−は８〜１０
程度に調整されるのが好ましい。
程度に調整されるのが好ましい。
本発明染色組成物を用いて角質繊維の染色を実施するに
は、例えば本発明染色組成物に酸化剤を添加して酸化カ
ップリングを行い染色液を調製し、この染色液を角質繊
維に適用し、１０〜５０分、好ましくは２５〜３５分前
後の作用時間をおいて角質繊維を洗浄した後乾燥するこ
とにより行なわれる。ここで染色液の適用は１５〜４０
℃で行なわれる。
は、例えば本発明染色組成物に酸化剤を添加して酸化カ
ップリングを行い染色液を調製し、この染色液を角質繊
維に適用し、１０〜５０分、好ましくは２５〜３５分前
後の作用時間をおいて角質繊維を洗浄した後乾燥するこ
とにより行なわれる。ここで染色液の適用は１５〜４０
℃で行なわれる。
本発明の染色組成物を用いて角質繊維を染色すれば、顕
色物質とカッｆ リング物質の組み合せにより黄〜赤〜
青さらに灰色〜黒褐色まで幅広い染色が可能であシ、そ
の色調は高彩度である。特に、レゾルシン系のカップリ
ング物質と組み合せることによシ高彩度の赤系色調が、
またアミノビリシン系のカップリング物質と組み合せる
ことによシ高彩度の黄色が得られる。しかも得られた色
調は良好な耐光性、耐洗浄性及び耐摩擦性を有している
。
色物質とカッｆ リング物質の組み合せにより黄〜赤〜
青さらに灰色〜黒褐色まで幅広い染色が可能であシ、そ
の色調は高彩度である。特に、レゾルシン系のカップリ
ング物質と組み合せることによシ高彩度の赤系色調が、
またアミノビリシン系のカップリング物質と組み合せる
ことによシ高彩度の黄色が得られる。しかも得られた色
調は良好な耐光性、耐洗浄性及び耐摩擦性を有している
。
次に実施例を挙げて本発明の詳細な説明するが、本発明
はこれによって制限されるものではない。
はこれによって制限されるものではない。
実施例１
ベース組成：
（３ｂ）
オレイン酸
オレインはジェタノールアミド ８オ
レイルアルコール エタノール １５ゾロピレング
リコール １０塩化アンモニウ
ム ３２５チアンモニア
７水
３５上記組成からなる
ベース１００を中に４゜５．６−１リアミノ−２（１）
１）−ビリミシンチオン０．０１モル及び表１に示すカ
ツプリング物質０．０１モルを混入した。次いで組成物
の−をアンモニアにて９．５に調整することによシ、本
発明染色組成物を製造した。
レイルアルコール エタノール １５ゾロピレング
リコール １０塩化アンモニウ
ム ３２５チアンモニア
７水
３５上記組成からなる
ベース１００を中に４゜５．６−１リアミノ−２（１）
１）−ビリミシンチオン０．０１モル及び表１に示すカ
ツプリング物質０．０１モルを混入した。次いで組成物
の−をアンモニアにて９．５に調整することによシ、本
発明染色組成物を製造した。
本発明染色組成物１００ｔに対し、等重量の６％過酸化
水素水溶液を加えて染色液を調製した。この染色液を白
毛混じシの入毛に塗布し、３０℃で３０分間放置した。
水素水溶液を加えて染色液を調製した。この染色液を白
毛混じシの入毛に塗布し、３０℃で３０分間放置した。
次いで毛髪を通常のシャンプーで洗浄し、乾燥した。
得られた染色の色調を観察した結果を表１に示す。
以下余白
Claims (1)
- 【特許請求の範囲】 １、顕色物質およびカツプリング物質を含有する染色組
成物において、顕色物質が、次の一般式（ I ）または
（ I ′） ▲数式、化学式、表等があります▼（ I ） ▲数式、化学式、表等があります▼（ I ′） で表わされるトリアミノピリミジン誘導体またはその塩
であることを特徴とする角質繊維染色組成物。 ２、カツプリング物質が、レゾルシン、２−メチルレゾ
ルシン及び４−クロロレゾルシンからなる群より選ばれ
る１種もしくは２種以上を含有するものである請求項１
の角質繊維染色組成物。 ３、カツプリング物質が、４−プロピル−２，６−ジア
ミノピリジン、３，４−ジメチル−２，６−ジアミノピ
リジンの一方または両方を含有するものである請求項１
の角質繊維染色組成物。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63169571A JP2526099B2 (ja) | 1988-07-07 | 1988-07-07 | 角質繊維染色組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63169571A JP2526099B2 (ja) | 1988-07-07 | 1988-07-07 | 角質繊維染色組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0219576A true JPH0219576A (ja) | 1990-01-23 |
| JP2526099B2 JP2526099B2 (ja) | 1996-08-21 |
Family
ID=15888943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63169571A Expired - Fee Related JP2526099B2 (ja) | 1988-07-07 | 1988-07-07 | 角質繊維染色組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2526099B2 (ja) |
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