[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

JPH0214879A - Clad material of carbon ceramic - Google Patents

Clad material of carbon ceramic

Info

Publication number
JPH0214879A
JPH0214879A JP63163908A JP16390888A JPH0214879A JP H0214879 A JPH0214879 A JP H0214879A JP 63163908 A JP63163908 A JP 63163908A JP 16390888 A JP16390888 A JP 16390888A JP H0214879 A JPH0214879 A JP H0214879A
Authority
JP
Japan
Prior art keywords
carbon
ceramic
sheet
clay
residue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63163908A
Other languages
Japanese (ja)
Inventor
Sadao Kumasaka
貞男 熊坂
Satomi Tada
多田 郷見
Ryoji Nagamine
長嶺 亮二
Koretoshi Katsuki
是利 香月
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Human Industry Corp
Original Assignee
Human Industry Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Human Industry Corp filed Critical Human Industry Corp
Priority to JP63163908A priority Critical patent/JPH0214879A/en
Publication of JPH0214879A publication Critical patent/JPH0214879A/en
Pending legal-status Critical Current

Links

Landscapes

  • Ceramic Products (AREA)

Abstract

PURPOSE:To make possible to form a carbon-ceramic clad material having excellent heat resistance, fire resistance and heat insulating properties, etc., and good moldability by joining in one body a carbon-ceramic baked material obtained by kneading residue after distillation of heavy fuel oil and clay, molding and baking and a sheet of metallic plate, etc. CONSTITUTION:A mixed oil of one or two or more oils selected from petroleum- based or coal-based lower oil is distilled in the presence of one or two or more metals or metallic compounds. Then, resultant residue is mixed with clay and molded to sheetlike material of any thickness or any shape, then heated and baked to obtain a carbon-ceramic baked material 3. Next, a carbon-ceramic clad material 4 is formed from said baked material 3 and a sheet 1 joined with said material in one body (2 is adhesive layer). The residual oil may be mixed glass fiber, filler or water (for control of viscosity), etc., together with clay. As a sheet to be joined, metallic plate such as steel plate or copper plate, inorganic material such as slate, cement or ceramic, wood or plastic sheet, etc., is used.

Description

【発明の詳細な説明】 「産業上の利用分野コ 本発明はカーボンセラミック複合体に関し、特に塗装、
接着剤等の溶剤として利用する精製面をする際、蒸溜せ
ずに残存した残留物や重油、コールタールなど重質油を
更に蒸溜した後の残留物等を用いたカーボンセラミック
複合体に係わる。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to carbon ceramic composites, particularly for coating,
It relates to carbon-ceramic composites made from residues left over from distillation and residues from further distillation of heavy oils such as heavy oil and coal tar when used as solvents for adhesives, etc.

[従来の技術と課題] 周知の如く、耐火材、断熱材、耐熱材などの材料として
鉄などの鋼板、スレートや石膏ボードなどの無機質から
なるボード、グラスウール、更には硬質ウレタンなどの
プラスチックが知られている。
[Prior art and issues] As is well known, steel sheets such as iron, inorganic boards such as slate and plasterboard, glass wool, and even plastics such as hard urethane are known as materials for fireproofing, heat insulation, and heat-resistant materials. It is being

いずれの場合も長所があるが、その一方で欠点を有して
いる。例えば、鉄板の場合、耐熱性、耐火性には強いが
、断熱性は極端に悪い、また、グラスウールは断熱性は
優れているが、耐火性に劣るという欠点を有する。この
ように、耐熱性、耐火性、断熱性等種々の特性を全て満
足する材料は未だに存在しないのが実状である。
Both cases have advantages, but they also have disadvantages. For example, iron plates have high heat resistance and fire resistance, but extremely poor heat insulation properties, and glass wool has excellent heat insulation properties, but has poor fire resistance. As described above, the reality is that there is still no material that satisfies all of the various properties such as heat resistance, fire resistance, and heat insulation.

本発明は上記事情に鑑みてなされたもので、重質油の蒸
溜時の残留物と粘土あるいは水、充填剤等を混練りした
後、必要ならば乾燥して加熱焼成することにより得られ
るカーボンセラミック焼成体に金属板等のシートを一体
的に接合することにより、耐熱性、耐火性、断熱性等に
著しく優れた成形性の良いカーボンセラミック 複合体
を提供することを目的とする。
The present invention was made in view of the above circumstances, and consists of carbon obtained by kneading residues from heavy oil distillation with clay or water, fillers, etc., followed by drying if necessary and heating and firing. The purpose of the present invention is to provide a carbon-ceramic composite with outstanding heat resistance, fire resistance, heat insulation, etc., and good formability by integrally bonding a sheet such as a metal plate to a fired ceramic body.

[課題を解決するための手段と作用コ 本発明は、先に出願した「精製油及びその製造方法」で
蒸溜の際に残留する残留物について種々実験を重ねたと
ころ、粘土、ガラス繊維、水等。
[Means and effects for solving the problem] The present invention has been made through various experiments regarding the residues remaining during distillation in the previously filed "Refined Oil and Process for Producing the Same". etc.

必要に応じて充填剤と上記残留物を混合させ焼成して得
られる焼成体にシートを一体的に接合することにより、
耐火性(1200〜3000℃)、断熱/断冷性、防音
、遮音性に優れるとともに、無煙無臭で衛生的に優れた
軽量で成形性のよいカーボンセラミック複合体が得られ
ることを究明した。
By integrally joining the sheet to the fired body obtained by mixing the filler and the above residue as necessary and firing,
It has been found that it is possible to obtain a lightweight, moldable carbon-ceramic composite that is excellent in fire resistance (1200 to 3000°C), heat/cool insulation, sound insulation, and sound insulation, as well as being smokeless, odorless, and hygienic.

即ち、本発明は、石油系又は石炭系の低級油から選ばれ
る1種又は2種以上の混合油を金属又は金属化合物の1
種又は2種以上の存在下に於いて蒸溜し、この残留物と
粘土を混合し、任意の厚さのシート状又は任意の形状と
した後、加熱焼成して得られる焼成体と、この焼成体と
一体的に接合したシートとを具備することを要旨とする
That is, the present invention combines one or more mixed oils selected from petroleum-based or coal-based low-grade oils with one of metals or metal compounds.
Distilled in the presence of a species or two or more species, mixed this residue with clay, formed into a sheet of any thickness or any shape, and heated and fired to obtain a fired body, and this fired body. The gist is to include a sheet that is integrally joined to the body.

本発明に係る石油系の低級油としては、例えば重油、廃
油、低級石油、原油、石油タール、ナフサなどをあげる
ことができ、石炭系低級油とじては例えば石炭タール、
コールタールなどを挙げることができる。
Examples of petroleum-based low-grade oils according to the present invention include heavy oil, waste oil, low-grade petroleum, crude oil, petroleum tar, and naphtha, and examples of coal-based low-grade oils include coal tar,
Examples include coal tar.

本発明に係る金属としては、例えば亜鉛、銅、鉄、アル
ミニウム、錫、亜鉛、白金、銀等を挙げることができ、
かつ前記金属化合物としては例えばこれら金属の塩化物
、硝酸化物、酸化物等を挙げることができる。これらの
うちで特に低融点である錫、亜鉛、これらの化合物が好
ましい。
Examples of metals according to the present invention include zinc, copper, iron, aluminum, tin, zinc, platinum, silver, etc.
Examples of the metal compounds include chlorides, nitrates, and oxides of these metals. Among these, tin, zinc, and compounds thereof, which have a particularly low melting point, are preferred.

本発明に係るシートとしては、鉄板、銅板、ステンレス
板、アルミ板、トタン板、ブリキ板等の金属板、あるい
は石膏、セメント、スレート、ガラス、陶磁器、セラミ
ック、無機質繊維等の無機質体、あるいは壁材、木材、
あるいは熱可塑性。
The sheet according to the present invention may be a metal plate such as an iron plate, a copper plate, a stainless steel plate, an aluminum plate, a galvanized iron plate, or a tin plate, or an inorganic body such as plaster, cement, slate, glass, china, ceramic, or inorganic fiber, or a wall. wood, wood,
Or thermoplastic.

熱硬化性のプラスチックシート、エンジニアリングプラ
スチックシートなどが挙げられる。なお、プラスチック
シート、エンジニアリングシートは発泡体、無発泡体の
いずれでもよい。
Examples include thermosetting plastic sheets and engineering plastic sheets. Note that the plastic sheet and the engineering sheet may be either foamed or non-foamed.

上記混合物を焼成する方法は通常の手段で良く、電気炉
又は窯又はガスバーナーを利用する。その温度は800
〜2500℃程度が好ましい。また、上記残留物は常温
では固形又は粘調な液体であり、使用する低級油により
異なる。ここで、液状の場合でも固形の場合でもニーダ
−や押出機などの任意の混線機で粘土やガラス繊維と混
合すればよい。
The above mixture may be fired by any conventional means, such as an electric furnace, a kiln, or a gas burner. Its temperature is 800
The temperature is preferably about 2500°C. Further, the above-mentioned residue is a solid or a viscous liquid at room temperature, which varies depending on the lower grade oil used. Here, whether it is liquid or solid, it may be mixed with clay or glass fiber in any mixer such as a kneader or an extruder.

ここで、ガラス繊維は太さ、長さが任意のものを使用す
ることができる。また、残留物とガラス繊維の混合比率
は任意でよいが、残留物100重量部に対しガラス繊維
5〜60重量部が好ましい。更に、残留物と粘度の混合
比率は残留物100重量部に対し100〜800重量部
が好ましい。また、必要に応じて成形されたカーボンセ
ラミック°、に任意の塗料にて塗装すれば表面が美麗に
なる。
Here, glass fibers of any thickness and length can be used. Further, the mixing ratio of the residue and the glass fibers may be arbitrary, but preferably 5 to 60 parts by weight of the glass fibers per 100 parts by weight of the residue. Further, the mixing ratio of the residue and the viscosity is preferably 100 to 800 parts by weight per 100 parts by weight of the residue. Additionally, if necessary, the molded carbon ceramic can be painted with any paint to create a beautiful surface.

[実施例] 以下、本発明の一実施例について第1図を参照して説明
する。
[Example] Hereinafter, an example of the present invention will be described with reference to FIG.

図中の1は、シートとしての例えば鉄板である。1 in the figure is a sheet, for example, an iron plate.

この鉄板1には接着剤層2を介してカーボンセラミック
焼成体3が接着され、カーボンセラミック複合体4が構
成されている。次に、このカーボンセラミックun +
゛の製造方法について説明する。
A carbon ceramic fired body 3 is adhered to this iron plate 1 via an adhesive layer 2, thereby forming a carbon ceramic composite body 4. Next, this carbon ceramic un +
The manufacturing method of ゛ will be explained.

まず、図示しないか、三つロフラスコ内に200m1の
コールタールと塊状金属としての鉛eoog。
First, 200 ml of coal tar and lead eoog as lump metal were placed in a three-bottle flask (not shown).

白金5g及び錫LOOgを収納した。また、前記フラス
コの中央の口からモータで駆動される撹拌機を挿入し、
他の口から温度計を差込み、更に残りの管を介してアス
ピレータを接続し、該アスピレータに冷却水を流通させ
、撹拌機をモータで回転させて三つロフラスコ内のコー
ルタール及び塊状金属を撹拌しながら、バーナによりコ
ールタールを300℃(気体蒸気温度)まで加熱し、発
生した蒸気をアスピレータで冷却して回収用フラスコで
回収した。その結果、黒色の残留物が85m I三つロ
フラスコの底に残存した。この残存物は常温において固
化した。更に、前記残留物を粉粒化した後、これを10
0重量部に対しガラス繊維(長さ1amの短縮繊維)を
15重量部及び粘土を300重量部混合して均一に混練
した後、厚さ5IIIInにシート化した。次に、これ
を加熱ガスバーナーを用いて1000°C前後で15分
間焼成し、カーボンセラミック貰遺した。
5g of platinum and LOOg of tin were stored. Also, insert a stirrer driven by a motor from the center mouth of the flask,
Insert a thermometer from the other port, connect an aspirator through the remaining tube, flow cooling water through the aspirator, and rotate the stirrer with a motor to stir the coal tar and lump metal in the three-ring flask. Meanwhile, the coal tar was heated to 300° C. (gas vapor temperature) with a burner, and the generated vapor was cooled with an aspirator and collected in a recovery flask. As a result, a black residue remained at the bottom of the 85ml I three-necked flask. This residue solidified at room temperature. Furthermore, after pulverizing the residue, it was pulverized to 10
0 parts by weight, 15 parts by weight of glass fiber (shortened fibers with a length of 1 am) and 300 parts by weight of clay were mixed and kneaded uniformly, and then formed into a sheet with a thickness of 5IIIn. Next, this was fired for 15 minutes at around 1000°C using a heating gas burner, and a carbon ceramic was left behind.

しかして、本発明に係るカーボンセラミック複合体は、
コールタールと塊状金属としての鉛、白金、錫を適宜撹
拌、加熱して蒸発した後、三つロフラスコに残存した残
留物に粘土、ガラス繊維を混合し、シート状とした後、
これを高温で焼成して得られるカーボンセラミック焼成
体3と、この焼成体3と接着剤層2を介して一体的に接
合された鉄板11とから構成されているため、耐火性(
1200〜3000℃)、断熱・断冷性、防音・遮音性
に優れるとともに、無縁無臭で衛生的に優れた軽量なカ
ーボンセラミック複合体を得ることができる。
Therefore, the carbon ceramic composite according to the present invention is
Coal tar and lump metals such as lead, platinum, and tin are appropriately stirred and heated to evaporate, and the residue remaining in the three-necked flask is mixed with clay and glass fiber and made into a sheet.
It is composed of a carbon ceramic fired body 3 obtained by firing this at high temperature, and an iron plate 11 integrally joined to this fired body 3 via an adhesive layer 2, so it has fire resistance (
1,200 to 3,000° C.), a lightweight carbon-ceramic composite that has excellent heat and cold insulation properties, sound insulation and insulation properties, is odorless, and is hygienic.

[発明の効果] 以上詳述した如く本発明によれば、重質油の蒸溜時の残
留物と粘土あるいは水、充填剤等を混練りした後、必要
ならば乾燥して加熱焼成することにより得られるカーボ
ンセラミック焼成体とシートを一体的に接合することに
より、耐熱性、耐火性、断熱性等に著しく優れた成形性
の良いカーボンセラミック′複合体を提供できる。
[Effects of the Invention] As detailed above, according to the present invention, after kneading the residue from heavy oil distillation with clay or water, filler, etc., if necessary, drying and heating and calcining. By integrally joining the obtained carbon ceramic fired body and sheet, it is possible to provide a carbon ceramic 'composite' having excellent heat resistance, fire resistance, heat insulation, etc., and good moldability.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の一実施例に係るカーボンセラミック
′複合体の断面図である。 1・・・鉄板、3・・・カーボンセラミック焼結体、4
・・・カーボンセラミック複合体。 出願人代理人 弁理士 鈴江武彦 第 図
FIG. 1 is a sectional view of a carbon-ceramic composite according to an embodiment of the present invention. 1... Iron plate, 3... Carbon ceramic sintered body, 4
...Carbon ceramic composite. Applicant's agent Patent attorney Takehiko Suzue

Claims (6)

【特許請求の範囲】[Claims] (1)石油系又は石炭系の低級油から選ばれる1種又は
2種以上の混合油を金属又は金属化合物の1種又は2種
以上の存在下に於いて蒸溜し、この残留物と粘土を混合
し、任意の厚さのシート状又は任意の形状とした後、加
熱焼成して得られるカーボンセラミック焼成体と、この
焼成体と一体的に接合したシートとを具備することを特
徴とするカーボンセラミック複合体。
(1) One or more mixed oils selected from petroleum-based or coal-based low-grade oils are distilled in the presence of one or more metals or metal compounds, and this residue and clay are distilled. Carbon characterized by comprising: a carbon ceramic fired body obtained by mixing, shaping into a sheet of any thickness or any shape, and heating and firing; and a sheet integrally joined to this fired body. Ceramic composite.
(2)前記残留物及び粘土の他にガラス繊維を混合する
ことを特徴とする請求項1記載のカーボンセラミック複
合体。
(2) The carbon ceramic composite according to claim 1, wherein glass fiber is mixed in addition to the residue and clay.
(3)前記残留物及び粘土の他に水を添加混合して粘度
を調整することを特徴とする請求項1記載のカーボンセ
ラミック複合体。
(3) The carbon ceramic composite according to claim 1, wherein water is added and mixed in addition to the residue and clay to adjust the viscosity.
(4)前記残留物及び粘土の他に充填剤を混合すること
を特徴とする請求項1記載のカーボンセラミック複合体
(4) The carbon ceramic composite according to claim 1, wherein a filler is mixed in addition to the residue and clay.
(5)前記焼成の前工程として乾燥を行うことを特徴と
する請求項1記載のカーボンセラミック複合体。
(5) The carbon ceramic composite according to claim 1, wherein drying is performed as a step before the firing.
(6)前記シートが、鉄板,銅板,ステンレス板,アル
ミ板,トタン板,ブリキ板等の金属板、あるいは石膏,
セメント,スレート.ガラス,陶磁器,セラミック,無
機質繊維等の無機質体、あるいは壁材,木材、あるいは
熱可塑性,熱硬化性のプラスチックシート,エンジニア
リングプラスチックシートであることを特徴とする請求
項1記載のカーボンセラミック複合体。
(6) The sheet is a metal plate such as an iron plate, copper plate, stainless steel plate, aluminum plate, galvanized iron plate, or tin plate, or plaster,
Cement, slate. 2. The carbon-ceramic composite according to claim 1, wherein the carbon-ceramic composite is an inorganic body such as glass, ceramic, ceramic, or inorganic fiber, or a wall material, wood, a thermoplastic or thermosetting plastic sheet, or an engineering plastic sheet.
JP63163908A 1988-06-30 1988-06-30 Clad material of carbon ceramic Pending JPH0214879A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63163908A JPH0214879A (en) 1988-06-30 1988-06-30 Clad material of carbon ceramic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63163908A JPH0214879A (en) 1988-06-30 1988-06-30 Clad material of carbon ceramic

Publications (1)

Publication Number Publication Date
JPH0214879A true JPH0214879A (en) 1990-01-18

Family

ID=15783111

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63163908A Pending JPH0214879A (en) 1988-06-30 1988-06-30 Clad material of carbon ceramic

Country Status (1)

Country Link
JP (1) JPH0214879A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012165208A1 (en) * 2011-05-27 2012-12-06 東洋炭素株式会社 Joint of metal material and ceramic-carbon composite material, method for producing same, carbon material joint, jointing material for carbon material joint, and method for producing carbon material joint

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012165208A1 (en) * 2011-05-27 2012-12-06 東洋炭素株式会社 Joint of metal material and ceramic-carbon composite material, method for producing same, carbon material joint, jointing material for carbon material joint, and method for producing carbon material joint
CN103596905A (en) * 2011-05-27 2014-02-19 东洋炭素株式会社 Joint of metal material and ceramic-carbon composite material, method for producing same, carbon material joint, jointing material for carbon material joint, and method for producing carbon material joint
EP2716618A4 (en) * 2011-05-27 2015-05-27 Toyo Tanso Co Joint of metal material and ceramic-carbon composite material, method for producing same, carbon material joint, jointing material for carbon material joint, and method for producing carbon material joint

Similar Documents

Publication Publication Date Title
Al-Saadi et al. Effect of graphite additions on the intumescent behaviour of alkali-activated materials based on glass waste
US2713787A (en) Refractory wall section and method of making the same
US3303031A (en) Carbonaceous ramming paste
JPH0214879A (en) Clad material of carbon ceramic
KR0126863B1 (en) Refractory ceramic mass
JPH0393942A (en) Manufacture of building material
JPH01172255A (en) Production of carbon ceramic
JPH0214878A (en) Production of carbon ceramic
JPS6213302B2 (en)
JPH0472787B2 (en)
JPS5826080A (en) Refractory mixture for dry thermal repairment
JPH0841426A (en) Refractory adhesive
JPH01150790A (en) Baking material for hot repair
JPH04357167A (en) Ceramics heater
JPH01286974A (en) Electrically energizable ceramic structure and production thereof
GB1336229A (en) Expanded natural grains cereal for lightweight building materials
JP2647910B2 (en) Non-combustible plate for building
JPS63307176A (en) Production of carbon ceramic foam
SU1004323A1 (en) Laminate structural and heat insulating member
CN106365599A (en) Method for preparing acid-resistant fireplace lining material
JPH0469116B2 (en)
US1288834A (en) Heat-insulating material and process for making the same.
US1092320A (en) Building material and process of making same.
JPH01157482A (en) Production of carbon ceramic
JPH0323499B2 (en)